Quantum transport in nanostructures-I Prof. Ilari Maasilta Nanoscience Center, Department of Physics, University of Jyväskylä YN 215, maasilta@phys.jyu.fi Fundamentals of nanoscience 8.2.2008 What is quantum transport • How is current (charge) and energy transported in devices where quantum mechanics matters • In microscopic physics (such as atoms) the laws of physics, as we know them now, are governed by quantum mechanics (QM) • QM is important also size scales a bit larger than atoms and molecules = nanostructures Fundamentals of nanoscience 8.2.2008 How to study quantum transport? • 1. 2. 3. There is no way to learn quantum transport in 2 lectures…. (let’s go home?) learn quantum mechanics+solid state physics (FYSA230, FYSM300, books) After that take my course on quantum transport (FYSM530) or Study a good book say Datta, Quantum Transport: Atom to Transistor, Cambridge 2005 Datta, Electronic Transport in Mesoscopic Systems, Cambridge 1995 Fundamentals of nanoscience 8.2.2008 Some topics in electric quantum transport • Top-down nanofabrication • Semiconducting low-D devices • Quantized conductance and fabricated quantum dots • Metallic nanostructures; tunnel junctions • Applications of tunnel junctions etc. in detectors,SET etc. Fundamentals of nanoscience 8.2.2008 Nanofabrication • Either you let Nature self-organize (magic or sometimes know as chemistry) • Or you use the physicists method=brute force. This is how transistor size has shrunk by many orders of magnitude in past decades (Moore’s law) Fundamentals of nanoscience 8.2.2008 Gordon E. Moore (b. 1929) • • • • Gordon Earle Moore is the co-founder and Chairman Emeritus of Intel Corporation and the author of Moore's Law (published in an article 19 April 1965 in Electronics Magazine). He received a B.S. degree in Chemistry from the University of California, Berkeley in 1950 and a Ph.D. in Chemistry and Physics from the California Institute of Technology (Caltech) in 1954. In 2001, Moore and his wife donated $600 million to Caltech On December 6, 2007, Gordon Moore and his wife donated $200 million to Caltech and the University of California for the construction of the world's largest optical telescope. Moore is more (for Caltech at least) Fundamentals of nanoscience 8.2.2008 Lithography • • • Photolithography: Use UV light to expose sensitive resist in certain areas (use mask). Limited in principle by the wavelength of light, can improve with expensive optics down to 50 nm Electron-beam lithography: Write an e-beam resist directly with an e-gun. Not limited by the wavelength of electrons (Å), but by the resolution of the resist (~10 nm) We have both at NSC Fundamentals of nanoscience 8.2.2008 Example: Self-supporting (hanging) metallic lines ~200 nm wide (= nanomechanics) Fundamentals of nanoscience 8.2.2008 Semiconducting low-D structures • • • • 2D electron gas 1D electron gas 0D electron gas! -1D electron gas is hard to fathom… Fundamentals of nanoscience 8.2.2008 2D electron gas-I • Used commercially in High Electron Mobility Transistor (HEMT), Fujitsu etc. • Less scattering=higher mobility=faster operation (up to 600 GHz) => needed in satellite communcations, radar etc. microwave applications Fundamentals of nanoscience 8.2.2008 2D electron gas-II • • • Condensed matter physicists love 2D electron gas (I did my PhD on it..) because of Quantum Hall effect (2 Nobel prizes, integer+fractional) QHE is a new highly correlated state of ”matter” in high magnetic fields, where weird phenomena take place (for example quantized non-integer charge!) Don’t believe particle physicists if they say that they can explain everything with quarks and leptons= ”fundamental” particles. A piece of semiconductor can have it’s own fundamental particles!!! Fundamentals of nanoscience 8.2.2008 1D electron gas • Known as a quantum wire (2D gas can be made from a quantum well) • Carbon nanotubes, semiconducting nanowires, semiconductor heterostructure nanowires • Intense active research, not too many applications yet Fundamentals of nanoscience 8.2.2008 Transport in 1D systems-I • Usual piece of metal obeys Ohm’s law (this is something even a biologist should remember from high school…) Notion of resistance, which depends on material dimensions and a material parameter, resistivity ρ I =V R , V = RI R = ρL / A Fundamentals of nanoscience 8.2.2008 1D transport-II • In quantum limit-shockingly- Ohm’s law doesn’t work! • Sorry Ohm, but your law is not a law of nature… • It requires a lot of scattering, so that a continuous model works (scattering length is microscopic ~ 1nm) • Quantum wires etc can be made so pure that nothing disturbs the electron inside the nanosample = coherent and/or ballistic transport (in analogy with usual waves) Fundamentals of nanoscience 8.2.2008 1D transport -III • A new ”law” by Rolf Landauer IBM (19271999): • Each 1D channel conducts exactly G0 • This is the maximum conducting capacity • Conductance can be lowered by introducing scatterers 2e 2 G0 = = (12.906404kΩ) −1 h The measurement of G0 via Quantum Hall effect is more accurate (10-8) than the direct measurements of e and h. Therefore metrological labs agreed on a value by convention. Fundamentals of nanoscience 8.2.2008 1D transport 2 • If there is a scatterer with transmission probability T, then • Why is there resistance at all???? (No dissipation inside nanostructure) • Resistance arises because the 1D channel must be contacted with the outside world to be able to conduct (contact with leads+battery) The energy is disspated in the contacts, so 1/G0 is a contact resistance Fundamentals of nanoscience 2e G= T h Van Wees 8.2.2008 et al. Phys. Rev. Lett. 60, 848 - 850 (1988) 0D transport • • • As mentioned by prof. Manninen, it is possible to engineer devices where electron states are fully quantized (discrete), like ”artificial atoms”-also known as quantum dots. 0D means that the electron inside the dot has no freedom to move But you can still couple current through it, it can be weakly coupled to leads by tunnel barriers (T very small) Fundamentals of nanoscience 8.2.2008 Tunneling • Quantum mechanical tunneling is a process where particles (electrons) can travel through classically prohibited areas! • ”Walking through doors” • In practice the barrier has to be of thickness 1-100 nm for electrons depending on the barrier height Fundamentals of nanoscience 8.2.2008 Conductance through a quantum dot Fundamentals of nanoscience 8.2.2008 Metallic nanostructures • You can also make intersting nanostructure devices from metals,but with a typical metal there are no low-D effects (electron wavelength is ~ 1 nm instead of ~100 nm in semiconductors) • Also, metals can become superconducting (= zero resistance for current flow) at low enough temperatures, typically < 10 K • In the superconducting state, we again have new ”quasiparticles”, Cooper pairs, which consist of pairs of two electrons (charge 2e). • These Cooper pairs ”condense” into a collective state, which is coherent across marcoscopic distances => no scattering, no resistance Fundamentals of nanoscience 8.2.2008 Resistance (Ω) A superconducting Nb bridge 40 35 30 25 20 15 10 5 0 -5 4 A sub-mm radiation detector 5 6 7 8 9 10 Temperature (K) 11 12 M. Nevala, K. Kinnunen, I. Maasilta, unpublished Fundamentals of nanoscience 8.2.2008 A superconducting junction 6 4 N S I (mA) 2 S 0 T = 4.2 K T = 4.7 K T = 5.1 K T = 5.9 K T = 6.8 K T = 7.6 K T = 8.7 K T = 11.0 K -2 -4 Normal metal layer 10 nm thick -6 -0.10 -0.05 0.00 0.05 0.10 V (mV) M. Nevala, I. Maasilta unpublished The resistance of the normal metal does not show at all for currents below certain value (critical current), here ~ 3.5 mA at 4.2 K (No voltage drop !!!) This is the supercurrent, which is carried by Cooper pairs only Fundamentals of nanoscience 8.2.2008 SNS Josephson junctions director of the Mind-Matter Unification Project I = I c sin φ Brian Josephson Nobel in 1973 "for his theoretical predictions of the properties of a supercurrent through a tunnel barrier, in particular those phenomena which are generally known as the Josephson effects" Fundamentals of nanoscience 8.2.2008 Applications of Josephson junctions • Can be used for ultra-high frequency digital electronics COOL... FAST... RELIABLE... RAPID Typical speed of RSFQ devices fabricated using an obsolete 3.5um technology is close to 100GHz (20GHz clock). The ultimate speed of an RSFQ device ever measured experimentally is 770GHz. The Intel® Core™2 Extreme processor QX9650 running at 3.0 GHz Fundamentals of nanoscience 8.2.2008 Commercial applications in the works ? + 2nd Stage: 1W @ 4.2K 1st Stage: 40W @ 45K Minimum Temperature: 0W @ 2.8K Type: Pulse Tube Cooling: liquid =? Fundamentals of nanoscience 8.2.2008 Single electron transistor charge variations of 2 x10-6 e can be detected in a measurement period of just one second and with a bandwidth of several hundred megahertz. Fundamentals of nanoscience 8.2.2008 Summary of part I • Classical laws of conduction do not work if devices are in the nanoscale • Need quantum mechanics • Quantum transport can be utilized for novel devices such as ultrasensitive radiation detectors (more on that next time), ultrafast electronics and ultrasensitive electrometry Fundamentals of nanoscience 8.2.2008