DATE: 07/07/2011
Date:
COMPANY NAME:
GIANI, Inc.
07/07/2011
MATERIAL SAFETY DATA SHEET
PREPARED BY: Environmental, Health and Safety Department
MSDS PREPARATION DATE: 07/07/2011, Version 1
-----------------------------------------------------------------------------------------Section 1 - Chemical Product and Company Identification
-----------------------------------------------------------------------------------------MANUFACTURER
Giani,Inc.
ADDRESS
2216 North Broadway
St. Louis, MO 63102
INFORMATION
314-241-3500
EMERGENCY
CHEMTREC 800-424-9300 or 703-527-3887
TRADE NAME
Ironcore Primer
PRODUCT CODE
EX 1111-2
HMIS Classification: Health 1, Flammability 0, Reactivity 0, Personal Protection Code
NFPA
0,
1,
0
-----------------------------------------------------------------------------------------Section 2 - Composition, Information on Ingredients
-----------------------------------------------------------------------------------------1 Non hazardous Acrylic CAS# trade secret, EINECS# , Non hazardous Acrylic
Pct By Wt: <20.0% Vapor Pressure: 17.500
ACGIH TLV-TWA
NE
ACGIH TLV-STEL/C
NE
OSHA PEL-TWA
NE
OSHA PEL-STEL
NE
OSHA PEL-CEILING
NE
LD50 (INGESTION)
NE
LC50 (INHALATION)
NE
AUTOIGNITION TEMP.
NA
SARA: NO/NO
Other Limits: IARC-NO, NTP-NO, OSHA-NO, ACGIH-NO, NIOSH-NO HAPS-NO
-----------------------------------------------------------------------------------------2 Non hazardous Urethane CAS# trade secret, EINECS# , Non hazardous Acrylic
Pct By Wt: <20.0% Vapor Pressure: 17.500
ACGIH TLV-TWA
NE
ACGIH TLV-STEL/C
NE
OSHA PEL-TWA
NE
OSHA PEL-STEL
NE
OSHA PEL-CEILING
NE
LD50 (INGESTION)
NE
LC50 (INHALATION)
NE
AUTOIGNITION TEMP.
NA
SARA: NO/NO
Other Limits: IARC-NO, NTP-NO, OSHA-NO, ACGIH-NO, NIOSH-NO HAPS-NO
-----------------------------------------------------------------------------------------3 WATER CAS# 7732-18-5, EINECS# 231-791-2, Water
Pct By Wt: 45.74 Vapor Pressure: 17.500
ACGIH TLV-TWA
NE
ACGIH TLV-STEL/C
NE
OSHA PEL-TWA
NE
OSHA PEL-STEL
NE
OSHA PEL-CEILING
NE
LD50 (INGESTION)
NE
LC50 (INHALATION)
NE
AUTOIGNITION TEMP.
NA
SARA: NO/NO
Other Limits: IARC-NO, NTP-NO, OSHA-NO, ACGIH-NO, NIOSH-NO HAPS-NO
-----------------------------------------------------------------------------------------4 GLYCOL CAS# 57-55-6 PROPYLENE GLYCOL
Pct By Wt:
< 2.0% LEL: 2.6
ACGIH TLV-TWA
NE
ACGIH TLV-STEL/C
NE
OSHA PEL-TWA
NE
OSHA PEL-STEL
NE
OSHA PEL-CEILING
NE
LD50 (INGESTION)
>2000 mg/kg
LC50 (INHALATION)
NE
AUTOIGNITION TEMP.
790 F
FLASH POINT
99 °C / 210 °F
SARA: NO/NO
Other Limits: IARC-NO. NTP-NO, OSHA-NO, ACGIH-NO, NIOSH-NO HAPS-NO
-----------------------------------------------------------------------------------------5 Calcium Carbonate CAS# 1317-65-3 EINECS# Calcium Carbonate
Pct By Wt: < 4.0%
ACGIH TLV-TWA
10 mg/m3
OSHA PEL-TWA
10 mg/m3
LD50 (INGESTION)
NE
LC50 (INHALATION)
NE
Other Limits: IARC-NO, NTP-NO, OSHA-NO, ACGIH-NO, NIOSH-NO HAPS-NO
-----------------------------------------------------------------------------------------6 TITANIUM DIOXIDE CAS# 13463-67-7 Titanium Dioxide
Pct By Wt: < 5.0%
ACGIH TLV-TWA
5 mg/m3
OSHA PEL-TWA
2 mg/m3
LD50 (INGESTION)
NE
LC50 (INHALATION)
NE
Other Limits: IARC-NO, NTP-NO, OSHA-NO, ACGIH-NO, NIOSH-NO HAPS-NO
Titanium Dioxide contains, Aluminum Hydroxide CAS# 21645-51-2, EINECS# 244-492-7 (0-9% of
Ti02), Amorphous Silica CAS# 7631-86-9, EINECS# 231-545-4 (0-11% of Ti02).
-----------------------------------------------------------------------------------------7 Magnesium Silicate Hydrade CAS# 14807-96-6
Pct By Wt: <12.0%
ACGIH TLV-TWA
2 mg/m3 ACGIH TLV-STEL/C
OSHA PEL-TWA
NE
OSHA PEL-STEL
2 mg/m3
OSHA PEL-CEILING
NE
LD50 (INGESTION)
> 10g/kg (rat)
LC50 (INHALATION)
NE
AUTOIGNITION TEMP.
NA
SARA: NO/NO
Other Limits: NTP-NO, IARC-NO, OSHA-NO, ACGIH-NO, NIOSH-NO HAPS-NO
-----------------------------------------------------------------------------------------8 CARBON BLACK CAS# 1333-86-4 CARBON BLACK
Pct By Wt:
< 5.0%
ACGIH TLV-TWA
3.5 MG/M3
ACGIH TLV-STEL/C
3.5MG/M3
OSHA PEL-TWA
3.5 MG/M3
OSHA PEL-STEL
NE
OSHA PEL-CEILING
NE
LD50 (INGESTION)
NE
PRODUCT CODE: CHOCOLATE BROWN KIT
LC50 (INHALATION)
NE
SARA: NO/NO/
Other Limits: IARC-YES (GROUP 2B),
Page 1
AUTOIGNITION TEMP.
NTP-NO OSHA-NO,
ACGIH-NO,
NA
NIOSH-NO HAPS-NO
Other Limits: IARC-YES WARNING: The Carbon Black pigment in this product contains less than 0.1% polynuclear aromatic
hydrocarbons (PAH), some of which, in non-adsorbed form, have been found to be carcinogens in animal studies. Carbon
Black has not been listed by the NTP or OSHA. NIOSH criteria recommends that only carbon blacks with PAH levels greater
than 0.1% be considered suspect carcinogens. In April 1996, the International Agency for Research on Cancer
(IARC) published Monograph 65 wherein IARC’s overall evaluation is that Carbon Black is possibly carcinogenic to humans
(Group 2B).
-----------------------------------------------------------------------------------------Section 3 - Hazards Identification
-----------------------------------------------------------------------------------------Routes of Entry: Inhalation, Skin Contact, Eye Contact
Effects of Overexposure: (No hazardous solvent present)
Inhalation – ACUTE (Pigments): Irritation of the nose, throat and eyes: Asthma-like breathing
may be a delayed reaction. Other possible symptoms of overexposure may include headache,
nausea, narcosis, fatigue and loss of appetite.
Eye Contact: Liquid is irritating to the eyes and can cause pain, tearing, reddening and
swelling.
Skin Contact: Repeated or prolonged skin contact can result in dry, defatted and cracked skin
causing increased susceptibility to infection.
Ingestion: Ingestion can result in irritation in the mouth, stomach tissue and digestive
tract. Symptoms can include sore throat, abdominal pain, nausea, vomiting and diarrhea.
Vomiting may cause aspiration resulting in chemical pneumonitis.
-----------------------------------------------------------------------------------------Section 4 - First Aid Measures
-----------------------------------------------------------------------------------------PRIMARY ROUTE(S) OF ENTRY: Inhalation, Dermal, Ingestion.
EMERGENCY FIRST AID PROCEDURES: When exposed always get medical attention.
EYE CONTACT: Flush with water for 15 minutes.
SKIN CONTACT: Wash with soap and water. Remove contaminated clothing and clean before reuse.
INHALATION: Remove to fresh air. Provide oxygen if breathing is difficult. Use artificial
respiration if not breathing. Get medical attention.
IF SWALLOWED: DO NOT INDUCE VOMITING!! Always get medical attention.
-----------------------------------------------------------------------------------------Section 5 - Fire Fighting Measures
-----------------------------------------------------------------------------------------FIRE AND EXPLOSIVE PROPERTIES OF THE CHEMICAL: (Unless otherwise noted, data are derived from
ingredients existing in this formula at concentrations of 1% by weight or greater, i.e., the
flashpoint given is the lowest flashpoint of the ingredients listed in section 2.)
Flashpoint - - - - - - - - - - - - - - -: >99 °C / >210 °F PENSKY MARTENS (CLOSED CUP)
Explosion Level - - - - - - - - - - - - : Low
2.6
High
15.3
Flammability Limits - - - - - - - - - - : Low N/A
High N/A
Auto-ignition Temperature - - - - - - - : N/A
Extinguishing Media: Not required
Hazard Class: DOT: Not regulated
OSHA: Not regulated
Water may be used to cool fire-exposed structures and vessels.
UNUSUAL FIRE AND EXPLOSION HAZARDS: Keep away from heat, sparks, and flame. Do not smoke.
Extinguish all pilot lights and turn off all sources of ignition, including heaters, fans and
other non-explosion proof electrical equipment, during use and until all vapors are gone.
Vapors may ignite explosively. Vapors may spread long distances and beyond closed doors.
Prevent build up of vapors by maintaining a continuous flow of fresh air.
FIRE-FIGHTING PROCEDURES AND EQUIPMENT: Self-contained breathing apparatus with full
facepiece operated in pressure-demand or other positive pressure mode. In case of fire, use
Dry chemical, Foam, CO2 or other approved method for treating a Class B fire. Summon
professional firefighters. Extreme dust conditions due to sanding or abrading may be a source
of autoignition in the presence of a flame. Closed container may explode when exposed to
extreme heat.
-----------------------------------------------------------------------------------------Section 6 - Accidental Release Measures
-----------------------------------------------------------------------------------------Steps to take in case of spills:
· Remove all sources of ignition. Ventilate area (refer to extinguishing media in section 4)
· Remove with inert absorbent material
Waste Disposal Method: If discarded this material and containers should be treated as a
hazardous waste, based on the Ignitability characteristics as defined under Federal RCRA
Regulations (40 CFR 261). Dispose of in accordance with local, state, and federal regulations.
DO NOT INCINERATE IN CLOSED CONTAINERS. For further information, contact the United States
Environmental Protection Agency RCRA hotline (800) 242-9342.
-----------------------------------------------------------------------------------------Section 7 - Handling and Storage
-----------------------------------------------------------------------------------------Handling and Storage: Keep away from heat. When storing, tightly
close containers to prevent evaporation. Do not reseal if contamination
is suspected. Do not take internally.
DATE: 07/07/2011
COMPANY NAME:
GIANI, Inc.
-----------------------------------------------------------------------------------------Section 8 - Exposure Controls, Personal Protection
-----------------------------------------------------------------------------------------Respiratory Protection: If personal exposure cannot be controlled below applicable limits by
ventilation, use an air-purifying respirator demonstrated to be effective for organic
vapor/particulate and approved by NIOSH for protection against materials in section 2.
Ventilation: Local exhaust is preferable. General exhaust is acceptable if the exposure to
materials in section 2 is maintained below acceptable
exposure limits. Protective Gloves: Wear gloves which are recommended by glove
supplier for protection against Materials in Section 2.
Eye Protection: Wear safety glasses with unperforated side shields
-----------------------------------------------------------------------------------------Section 9 - Physical and Chemical Properties
-----------------------------------------------------------------------------------------Physical Appearance - - - - - - - - - - : Black Liquid
Odor - - - - - - - - - - - - - - - - - -: Odorless
Physical State - - - - - - - - - - - - -: Liquid
pH - - - - - - - - - - - - - - - - - - -: 8.0 - 10.50
Vapor Density - - - - - - - - - - - - - : Heavier than air
Boiling Range Lower - - - - - - - - - - :
192.0 °F
Higher - - - - - - - - - -:
396.0 °F
Freezing Point - - - - - - - - - - - - -: Not Established
Melting Point - - - - - - - - - - - - - : Not Established
Water Solubility - - - - - - - - - - - -: Soluble
Specific Gravity - - - - - - - - - - - -:
1.21
Formula Weight per Volume - - - - - - - :
10.11 Pound/Gallon
VOC - - - - - - - - - - - - - - - - - - : < 101 g/l, < 0.84 lb/gal
Viscosity - - - - - - - - - - - - - - - :
Evaporation Rate - - - - - - - - - - - -: Slower than ether
Percent Volatile by Weight - - - - - - -:
68.00
Percent Volatile by Volume - - - - - - -:
82.50
-----------------------------------------------------------------------------------------Section 10 - Stability and Reactivity
-----------------------------------------------------------------------------------------Stability: This material is stable
Materials to avoid: Unknown.
Hazardous Polymerization: Will not occur.
Decomposition Products: By high heat and fire: CO2, CO
-----------------------------------------------------------------------------------------Section 11 - Toxicological Information
-----------------------------------------------------------------------------------------Propylene Glycol
:
CAS# 57-55-6
oral
:
LD50 : > 20,000 mg/kg (rat)
dermal
:
LD50 : > 20,000 mg/kg (rabbit)
Carbon Black Pigment
Oral
Dermal
edema)
Inhalation (as dust)
:
:
:
CAS# 1333-86-4, EINECS# 215-609-9
LD50: >8,000 mg/kg (rat)
LD50: non-irrative, index score 0.6/8 (4.0+severe
:
LC50: NOEL + 1.1 mg/m3 (rat 90 days)
Target organ (as dust): Lungs
:
Effect: inflammation, hyperplasia, fibrosis.
-----------------------------------------------------------------------------------------Section 12 - Ecological Information
-----------------------------------------------------------------------------------------Propylene Glycol
:
CAS# 57-55-6
Toxicity to other organisms:
Fish toxicity
:
LC50, rainbow trout (Oncorhynchus mykiss),
:
96 h: 44,000 - 51,600 mg/l
Daphnia toxicity
:
EC50: (48 h) > 34,000 mg/l
Algae toxicity
:
EC50: (72 h) > 19,000 mg/l
:green alga Selenastrum capricornutum, biomass growth
inhibition)
Persistance and degradability :
Mobility
:
Not soluble in water
Bioaccumulation
:
Not expected because of physiochemical properties of
substance.
-----------------------------------------------------------------------------------------Carbon Black Pigment
:
CAS# 1333-86-4
Toxicity to other organisms:
Fish toxicity
:
LC50: (96 h) >10,000 mg/l Branchdanio rerio (zebra
fish)
Daphnia toxicity
:
EC50: (24 h) > 5600 mg/l
Algae toxicity
:
EC50: (72 h) > 10,000 mg/l,
:
NEOC 50≥ 10,000 mg/l (Scenedesmus subspicatus)
Persistance and degradability :
Mobility
:
Not soluble in water
Bioaccumulation
:
Not expected because of physiochemical properties of
substance.
PRODUCT CODE: CHOCOLATE BROWN KIT
Page 2
Section 13 - Disposal Considerations
-----------------------------------------------------------------------------------------WASTE DISPOSAL METHOD: Dispose of contaminated absorbent, container and unused contents in
accordance with local, state and federal regulations. Do not incinerate closed containers.
-----------------------------------------------------------------------------------------Section 14 - Transport Information
-----------------------------------------------------------------------------------------DOT – NOT REGULATED
Canadian TDGA – NOT REGULATED
-----------------------------------------------------------------------------------------Section 15 - Regulatory Information
-----------------------------------------------------------------------------------------FEDERAL REGULATIONS:
SARA SECTION 302-304. The superfund amendments and reauthorization act of 1986 (SARA) title
III requires facilities subject to subparts 303 and 304 to submit emergency planning and
notification information based on threshold planning quantities (TPQs) and reportable
quantities (RQs) for "Extremely Hazardous Substances" listed in 40 CFR 302.4 and 40 CFR 355.
SARA (311,312) HAZARD CLASS. The superfund amendments and reauthorization act of 1986 (SARA)
title III requires facilities subject to subpart to submit aggregate information on chemicals
by "Hazard Category" as defined in 40 CFR 370.2
Immediate (Acute) Yes Health Hazard see Section 11
Delayed (Chronic) Health Hazard No
Fire Hazard No
Reactive Hazard No Sudden Release of Pressure Hazard No
SARA (313) CHEMICALS. Components in concentrations above the de minimus levels that are listed
as toxic chemicals in 40 CFR Part 372 pursuant to the requirements in section 313 of SARA.
Superfund Amendments and Reauthorization Act of 1986 Title III
(Emergency Planning and Community Right-to-Know Act of 1986) Section 313
To the best of our knowledge, this product does not contain chemicals at levels which require
reporting under this statute.
Pennsylvania (Worker and Community Right-To-Know Act): Pennsylvania HazardousSubstances List
and/or Pennsylvania Environmental Hazardous Substance List:
The following product components are cited in the Pennsylvania Hazardous Substance List and/or
the Pennsylvania Environmental Substance List, and are present at levels which require
reporting.
Component CAS # Amount
To the best of our knowledge, this product does not contain chemicals at levels which require
reporting
under this statute.
Comprehensive Environmental Response, Compensation, and Liability Act of 1980 (CERCLA)
Section 103
To the best of our knowledge, this product does not contain chemicals at levels which require
reporting under this statute.
US. EPA Emergency Planning and Community Right-To-Know Act (EPCRA) SARA Title III
Section 302 Extremely Hazardous Substance (40 CFR 355, Appendix A)
To the best of our knowledge, this product does not contain chemicals at levels which require
reporting under this statute.
California Proposition 65 (Safe Drinking Water and Toxic Enforcement Act of 1986)
This product contains listed substances known to the State of California to cause cancer,
birth defects or other reproductive harm, at levels which would require a warning under the
statute.
US. Toxic Substances Control Act
All components of this product are on the TSCA Inventory or are exempt from TSCA Inventory
requirements under 40 CFR 720.30
CEPA - Domestic Substances List (DSL)
All substances contained in this product are listed on the Canadian Domestic Substances List
(DSL) or are not required to be listed.
Section 16 - Other Information
-----------------------------------------------------------------------------------------NOTE: Read MSDS completely before use and follow all label instructions.
The information contained in this MSDS is based on the present state of knowledge and is based
on sources believed to be reliable.
However, since the data safety standards and government regulations are subject to change and
the conditions of handling and use or misuse are beyond our control, Giani, Inc. makes no
warranty, either express or implied, with respect to the information contained
Date: 07/07/2011
DATE: 07/07/2011
Date:
COMPANY NAME:
GIANI, Inc.
07/07/2011
MATERIAL SAFETY DATA SHEET
PREPARED BY: Environmental, Health and Safety Department
MSDS PREPARATION DATE: 07/07/2011, Version 1
-----------------------------------------------------------------------------------------Section 1 - Chemical Product and Company Identification
-----------------------------------------------------------------------------------------MANUFACTURER
Giani,Inc.
ADDRESS
2216 North Broadway
St. Louis, MO 63102
INFORMATION
314-241-3500
EMERGENCY
CHEMTREC 800-424-9300 or 703-527-3887
TRADE NAME
Inca Gold
PRODUCT CODE
EX 919-5
HMIS Classification: Health 1, Flammability 0, Reactivity 0, Personal Protection Code
NFPA
0,
1,
0
-----------------------------------------------------------------------------------------Section 2 - Composition, Information on Ingredients
-----------------------------------------------------------------------------------------1 Non hazardous Acrylic CAS# trade secret, EINECS# , Non hazardous Acrylic
Pct By Wt: <20.0% Vapor Pressure: 17.500
ACGIH TLV-TWA
NE
ACGIH TLV-STEL/C
NE
OSHA PEL-TWA
NE
OSHA PEL-STEL
NE
OSHA PEL-CEILING
NE
LD50 (INGESTION)
NE
LC50 (INHALATION)
NE
AUTOIGNITION TEMP.
NA
SARA: NO/NO
Other Limits: IARC-NO, NTP-NO, OSHA-NO, ACGIH-NO, NIOSH-NO HAPS-NO
-----------------------------------------------------------------------------------------2 Non hazardous Urethane CAS# trade secret, EINECS# , Non hazardous Acrylic
Pct By Wt: <20.0% Vapor Pressure: 17.500
ACGIH TLV-TWA
NE
ACGIH TLV-STEL/C
NE
OSHA PEL-TWA
NE
OSHA PEL-STEL
NE
OSHA PEL-CEILING
NE
LD50 (INGESTION)
NE
LC50 (INHALATION)
NE
AUTOIGNITION TEMP.
NA
SARA: NO/NO
Other Limits: IARC-NO, NTP-NO, OSHA-NO, ACGIH-NO, NIOSH-NO HAPS-NO
-----------------------------------------------------------------------------------------3 WATER CAS# 7732-18-5, EINECS# 231-791-2, Water
Pct By Wt: 45.74 Vapor Pressure: 17.500
ACGIH TLV-TWA
NE
ACGIH TLV-STEL/C
NE
OSHA PEL-TWA
NE
OSHA PEL-STEL
NE
OSHA PEL-CEILING
NE
LD50 (INGESTION)
NE
LC50 (INHALATION)
NE
AUTOIGNITION TEMP.
NA
SARA: NO/NO
Other Limits: IARC-NO, NTP-NO, OSHA-NO, ACGIH-NO, NIOSH-NO HAPS-NO
-----------------------------------------------------------------------------------------4 GLYCOL CAS# 57-55-6 PROPYLENE GLYCOL
Pct By Wt:
< 2.0% LEL: 2.6
ACGIH TLV-TWA
NE
ACGIH TLV-STEL/C
NE
OSHA PEL-TWA
NE
OSHA PEL-STEL
NE
OSHA PEL-CEILING
NE
LD50 (INGESTION)
>2000 mg/kg
LC50 (INHALATION)
NE
AUTOIGNITION TEMP.
790 F
FLASH POINT
99 °C / 210 °F
SARA: NO/NO
Other Limits: IARC-NO. NTP-NO, OSHA-NO, ACGIH-NO, NIOSH-NO HAPS-NO
-----------------------------------------------------------------------------------------5 Calcium Carbonate CAS# 1317-65-3EINECS# Calcium Carbonate
Pct By Wt: 4.0%
ACGIH TLV-TWA
10 mg/m3
OSHA PEL-TWA
10 mg/m3
LD50 (INGESTION)
NE
LC50 (INHALATION)
NE
Other Limits: IARC-NO, NTP-NO, OSHA-NO, ACGIH-NO, NIOSH-NO HAPS-NO
-----------------------------------------------------------------------------------------6 TITANIUM DIOXIDE CAS# 13463-67-7 Titanium Dioxide
Pct By Wt: 5.0%
ACGIH TLV-TWA
10 mg/m3
OSHA PEL-TWA
15 mg/m3
LD50 (INGESTION)
NE
LC50 (INHALATION)
NE
Other Limits: IARC-NO, NTP-NO, OSHA-NO, ACGIH-NO, NIOSH-NO HAPS-NO
Titanium Dioxide contains, Aluminum Hydroxide CAS# 21645-51-2, EINECS# 244-492-7 (0-9% of
Ti02), Amorphous Silica CAS# 7631-86-9, EINECS# 231-545-4 (0-11% of Ti02).
-----------------------------------------------------------------------------------------7 IRON OXIDE CAS# 51274-00-1 C.I. Pigment Yellow 42
Pct By Wt: <0.5%
ACGIH TLV-TWA
5 mg/m3 ( Iron Oxide Fume )
ACGIH TLV-STEL/C
NE
OSHA PEL-TWA
NE
OSHA PEL-STEL
10 ppm ( Iron Oxide Fume as Fe )
OSHA PEL-CEILING
NE
LD50 (INGESTION)
> 10g/kg (rat)
LC50 (INHALATION)
NE
AUTOIGNITION TEMP.
NA
SARA: NO/NO
Other Limits: NTP-NO, IARC-NO, OSHA-NO, ACGIH-NO, NIOSH-NO HAPS-NO
-----------------------------------------------------------------------------------------8 IRON OXIDE CAS# 1309-37-1, EINECS# 215-168-2, RED IRON OXIDE
Pct By Wt: < 0.5%
ACGIH TLV-TWA
5 MG/M3
ACGIH TLV-STEL/C
10MG/M3
OSHA PEL-TWA
10 MG/M3
OSHA PEL-STEL
NE
OSHA PEL-CEILING
NE
LD50 (INGESTION)
>5000 mg/l RAT
PRODUCT CODE: CHOCOLATE BROWN KIT
Page 3
LC50 (INHALATION)
NE
AUTOIGNITION TEMP.
NA
SARA: NO/NO/
Other Limits: IARC-NO; NTP-NO; OSHA-NO ACGIH-NO; NIOSH-NO HAPS-NO
-----------------------------------------------------------------------------------------9 CARBON BLACK CAS# 1333-86-4 CARBON BLACK
Pct By Wt:
< 0.1%
ACGIH TLV-TWA
3.5 MG/M3
ACGIH TLV-STEL/C
3.5MG/M3
OSHA PEL-TWA
3.5 MG/M3
OSHA PEL-STEL
NE
OSHA PEL-CEILING
NE
LD50 (INGESTION)
NE
LC50 (INHALATION)
NE
AUTOIGNITION TEMP.
NA
SARA: NO/NO/
Other Limits: IARC-YES (GROUP 2B), NTP-NO OSHA-NO, ACGIH-NO, NIOSH-NO HAPS-NO
Other Limits: IARC-YES WARNING: The Carbon Black pigment in this product contains less than 0.1% polynuclear aromatic
hydrocarbons (PAH), some of which, in non-adsorbed form, have been found to be carcinogens in animal studies. Carbon
Black has not been listed by the NTP or OSHA. NIOSH criteria recommends that only carbon blacks with PAH levels greater
than 0.1% be considered suspect carcinogens. In April 1996, the International Agency for Research on Cancer
(IARC) published Monograph 65 wherein IARC’s overall evaluation is that Carbon Black is possibly carcinogenic to humans
(Group 2B).
-----------------------------------------------------------------------------------------Section 3 - Hazards Identification
-----------------------------------------------------------------------------------------Routes of Entry: Inhalation, Skin Contact, Eye Contact
Effects of Overexposure: (No hazardous solvent present)
Inhalation – ACUTE (Pigments): Irritation of the nose, throat and eyes: Asthma-like breathing
may be a delayed reaction. Other possible symptoms of overexposure may include headache,
nausea, narcosis, fatigue and loss of appetite.
Eye Contact: Liquid is irritating to the eyes and can cause pain, tearing, reddening and
swelling.
Skin Contact: Repeated or prolonged skin contact can result in dry, defatted and cracked skin
causing increased susceptibility to infection.
Ingestion: Ingestion can result in irritation in the mouth, stomach tissue and digestive
tract. Symptoms can include sore throat, abdominal pain, nausea, vomiting and diarrhea.
Vomiting may cause aspiration resulting in chemical pneumonitis.
-----------------------------------------------------------------------------------------Section 4 - First Aid Measures
-----------------------------------------------------------------------------------------PRIMARY ROUTE(S) OF ENTRY: Inhalation, Dermal, Ingestion.
EMERGENCY FIRST AID PROCEDURES: When exposed always get medical attention.
EYE CONTACT: Flush with water for 15 minutes.
SKIN CONTACT: Wash with soap and water. Remove contaminated clothing and clean before reuse.
INHALATION: Remove to fresh air. Provide oxygen if breathing is difficult. Use artificial
respiration if not breathing. Get medical attention.
IF SWALLOWED: DO NOT INDUCE VOMITING!! Always get medical attention.
-----------------------------------------------------------------------------------------Section 5 - Fire Fighting Measures
-----------------------------------------------------------------------------------------FIRE AND EXPLOSIVE PROPERTIES OF THE CHEMICAL: (Unless otherwise noted, data are derived from
ingredients existing in this formula at concentrations of 1% by weight or greater, i.e., the
flashpoint given is the lowest flashpoint of the ingredients listed in section 2.)
Flashpoint - - - - - - - - - - - - - - -: >99 °C / >210 °F PENSKY MARTENS (CLOSED CUP)
Explosion Level - - - - - - - - - - - - : Low
2.6
High
15.3
Flammability Limits - - - - - - - - - - : Low N/A
High N/A
Auto-ignition Temperature - - - - - - - : N/A
Extinguishing Media: Not required
Hazard Class: DOT: Not regulated
OSHA: Not regulated
Water may be used to cool fire-exposed structures and vessels.
UNUSUAL FIRE AND EXPLOSION HAZARDS: Keep away from heat, sparks, and flame. Do not smoke.
Extinguish all pilot lights and turn off all sources of ignition, including heaters, fans and
other non-explosion proof electrical equipment, during use and until all vapors are gone.
Vapors may ignite explosively. Vapors may spread long distances and beyond closed doors.
Prevent build up of vapors by maintaining a continuous flow of fresh air.
FIRE-FIGHTING PROCEDURES AND EQUIPMENT: Self-contained breathing apparatus with full
facepiece operated in pressure-demand or other positive pressure mode. In case of fire, use
Dry chemical, Foam, CO2 or other approved method for treating a Class B fire. Summon
professional firefighters. Extreme dust conditions due to sanding or abrading may be a source
of autoignition in the presence of a flame. Closed container may explode when exposed to
extreme heat.
-----------------------------------------------------------------------------------------Section 6 - Accidental Release Measures
-----------------------------------------------------------------------------------------Steps to take in case of spills:
· Remove all sources of ignition. Ventilate area (refer to extinguishing media in section 4)
· Remove with inert absorbent material
Waste Disposal Method: If discarded this material and containers should be treated as a
hazardous waste, based on the Ignitability characteristics as defined under Federal RCRA
Regulations (40 CFR 261). Dispose of in accordance with local, state, and federal regulations.
DO NOT INCINERATE IN CLOSED CONTAINERS. For further information, contact the United States
Environmental Protection Agency RCRA hotline (800) 242-9342.
-----------------------------------------------------------------------------------------Section 7 - Handling and Storage
DATE: 07/07/2011
COMPANY NAME:
GIANI, Inc.
-----------------------------------------------------------------------------------------Handling and Storage: Keep away from heat. When storing, tightly
close containers to prevent evaporation. Do not reseal if contamination
is suspected. Do not take internally.
-----------------------------------------------------------------------------------------Section 8 - Exposure Controls, Personal Protection
-----------------------------------------------------------------------------------------Respiratory Protection: If personal exposure cannot be controlled below applicable limits by
ventilation, use an air-purifying respirator demonstrated to be effective for organic
vapor/particulate and approved by NIOSH for protection against materials in section 2.
Ventilation: Local exhaust is preferable. General exhaust is acceptable if the exposure to
materials in section 2 is maintained below acceptable
exposure limits. Protective Gloves: Wear gloves which are recommended by glove
supplier for protection against Materials in Section 2.
Eye Protection: Wear safety glasses with unperforated side shields
-----------------------------------------------------------------------------------------Section 9 - Physical and Chemical Properties
-----------------------------------------------------------------------------------------Physical Appearance - - - - - - - - - - : Tan Liquid
Odor - - - - - - - - - - - - - - - - - -: Odorless
Physical State - - - - - - - - - - - - -: Liquid
pH - - - - - - - - - - - - - - - - - - -: 8.0 - 10.50
Vapor Density - - - - - - - - - - - - - : Heavier than air
Boiling Range Lower - - - - - - - - - - :
192.0 °F
Higher - - - - - - - - - -:
396.0 °F
Freezing Point - - - - - - - - - - - - -: Not Established
Melting Point - - - - - - - - - - - - - : Not Established
Water Solubility - - - - - - - - - - - -: Soluble
Specific Gravity - - - - - - - - - - - -:
1.10
Formula Weight per Volume - - - - - - - :
9.18 Pound/Gallon
VOC - - - - - - - - - - - - - - - - - - : < 101 g/l, < 0.84 lb/gal
Viscosity - - - - - - - - - - - - - - - :
Evaporation Rate - - - - - - - - - - - -: Slower than ether
Percent Volatile by Weight - - - - - - -:
68.00
Percent Volatile by Volume - - - - - - -:
82.50
-----------------------------------------------------------------------------------------Section 10 - Stability and Reactivity
-----------------------------------------------------------------------------------------Stability: This material is stable
Materials to avoid: Unknown.
Hazardous Polymerization: Will not occur.
Decomposition Products: By high heat and fire: CO2, CO
-----------------------------------------------------------------------------------------Section 11 - Toxicological Information
-----------------------------------------------------------------------------------------Propylene Glycol
:
CAS# 57-55-6
oral
:
LD50 : > 20,000 mg/kg (rat)
dermal
:
LD50 : > 20,000 mg/kg (rabbit)
Carbon Black Pigment
Oral
Dermal
edema)
Inhalation (as dust)
:
:
:
CAS# 1333-86-4, EINECS# 215-609-9
LD50: >8,000 mg/kg (rat)
LD50: non-irrative, index score 0.6/8 (4.0+severe
:
LC50: NOEL + 1.1 mg/m3 (rat 90 days)
Target organ (as dust): Lungs
:
Effect: inflammation, hyperplasia, fibrosis.
-----------------------------------------------------------------------------------------Section 12 - Ecological Information
-----------------------------------------------------------------------------------------Propylene Glycol
:
CAS# 57-55-6
Toxicity to other organisms:
Fish toxicity
:
LC50, rainbow trout (Oncorhynchus mykiss),
:
96 h: 44,000 - 51,600 mg/l
Daphnia toxicity
:
EC50: (48 h) > 34,000 mg/l
Algae toxicity
:
EC50: (72 h) > 19,000 mg/l
:green alga Selenastrum capricornutum, biomass growth
inhibition)
Persistance and degradability :
Mobility
:
Not soluble in water
Bioaccumulation
:
Not expected because of physiochemical properties of
substance.
-----------------------------------------------------------------------------------------Carbon Black Pigment
:
CAS# 1333-86-4
Toxicity to other organisms:
Fish toxicity
:
LC50: (96 h) >10,000 mg/l Branchdanio rerio (zebra
fish)
Daphnia toxicity
:
EC50: (24 h) > 5600 mg/l
Algae toxicity
:
EC50: (72 h) > 10,000 mg/l,
:
NEOC 50≥ 10,000 mg/l (Scenedesmus subspicatus)
Persistance and degradability :
Mobility
:
Not soluble in water
PRODUCT CODE: CHOCOLATE BROWN KIT
Bioaccumulation
substance.
:
Page 4
Not expected because of physiochemical properties of
Section 13 - Disposal Considerations
-----------------------------------------------------------------------------------------WASTE DISPOSAL METHOD: Dispose of contaminated absorbent, container and unused contents in
accordance with local, state and federal regulations. Do not incinerate closed containers.
-----------------------------------------------------------------------------------------Section 14 - Transport Information
-----------------------------------------------------------------------------------------DOT – NOT REGULATED
Canadian TDGA – NOT REGULATED
-----------------------------------------------------------------------------------------Section 15 - Regulatory Information
-----------------------------------------------------------------------------------------FEDERAL REGULATIONS:
SARA SECTION 302-304. The superfund amendments and reauthorization act of 1986 (SARA) title
III requires facilities subject to subparts 303 and 304 to submit emergency planning and
notification information based on threshold planning quantities (TPQs) and reportable
quantities (RQs) for "Extremely Hazardous Substances" listed in 40 CFR 302.4 and 40 CFR 355.
SARA (311,312) HAZARD CLASS. The superfund amendments and reauthorization act of 1986 (SARA)
title III requires facilities subject to subpart to submit aggregate information on chemicals
by "Hazard Category" as defined in 40 CFR 370.2
Immediate (Acute) Yes Health Hazard see Section 11
Delayed (Chronic) Health Hazard No
Fire Hazard No
Reactive Hazard No Sudden Release of Pressure Hazard No
SARA (313) CHEMICALS. Components in concentrations above the de minimus levels that are listed
as toxic chemicals in 40 CFR Part 372 pursuant to the requirements in section 313 of SARA.
Superfund Amendments and Reauthorization Act of 1986 Title III
(Emergency Planning and Community Right-to-Know Act of 1986) Section 313
To the best of our knowledge, this product does not contain chemicals at levels which require
reporting under this statute.
Pennsylvania (Worker and Community Right-To-Know Act): Pennsylvania HazardousSubstances List
and/or Pennsylvania Environmental Hazardous Substance List:
The following product components are cited in the Pennsylvania Hazardous Substance List and/or
the Pennsylvania Environmental Substance List, and are present at levels which require
reporting.
Component CAS # Amount
To the best of our knowledge, this product does not contain chemicals at levels which require
reporting
under this statute.
Comprehensive Environmental Response, Compensation, and Liability Act of 1980 (CERCLA)
Section 103
To the best of our knowledge, this product does not contain chemicals at levels which require
reporting under this statute.
US. EPA Emergency Planning and Community Right-To-Know Act (EPCRA) SARA Title III
Section 302 Extremely Hazardous Substance (40 CFR 355, Appendix A)
To the best of our knowledge, this product does not contain chemicals at levels which require
reporting under this statute.
California Proposition 65 (Safe Drinking Water and Toxic Enforcement Act of 1986)
This product contains no listed substances known to the State of California to cause cancer,
birth defects or other reproductive harm, at levels which would require a warning under the
statute.
US. Toxic Substances Control Act
All components of this product are on the TSCA Inventory or are exempt from TSCA Inventory
requirements under 40 CFR 720.30
CEPA - Domestic Substances List (DSL)
All substances contained in this product are listed on the Canadian Domestic Substances List
(DSL) or are not required to be listed.
Section 16 - Other Information
-----------------------------------------------------------------------------------------NOTE: Read MSDS completely before use and follow all label instructions.
The information contained in this MSDS is based on the present state of knowledge and is based
on sources believed to be reliable.
However, since the data safety standards and government regulations are subject to change and
the conditions of handling and use or misuse are beyond our control, Giani, Inc. makes no
warranty, either express or implied, with respect to the information contained
Date: 07/07/2011
DATE: 07/07/2011
Date:
COMPANY NAME:
GIANI, Inc.
07/07/2011
MATERIAL SAFETY DATA SHEET
PREPARED BY: Environmental, Health and Safety Department
MSDS PREPARATION DATE: 07/07/2011, Version 1
-----------------------------------------------------------------------------------------Section 1 - Chemical Product and Company Identification
-----------------------------------------------------------------------------------------MANUFACTURER
Giani,Inc.
ADDRESS
2216 North Broadway
St. Louis, MO 63102
INFORMATION
314-241-3500
EMERGENCY
CHEMTREC 800-424-9300 or 703-527-3887
TRADE NAME
Feldspar Brown
PRODUCT CODE
EX 918-5
HMIS Classification: Health 1, Flammability 0, Reactivity 0, Personal Protection Code
NFPA
0,
1,
0
-----------------------------------------------------------------------------------------Section 2 - Composition, Information on Ingredients
-----------------------------------------------------------------------------------------1 Non hazardous Acrylic CAS# trade secret, EINECS# , Non hazardous Acrylic
Pct By Wt: <20.0% Vapor Pressure: 17.500
ACGIH TLV-TWA
NE
ACGIH TLV-STEL/C
NE
OSHA PEL-TWA
NE
OSHA PEL-STEL
NE
OSHA PEL-CEILING
NE
LD50 (INGESTION)
NE
LC50 (INHALATION)
NE
AUTOIGNITION TEMP.
NA
SARA: NO/NO
Other Limits: IARC-NO, NTP-NO, OSHA-NO, ACGIH-NO, NIOSH-NO HAPS-NO
-----------------------------------------------------------------------------------------2 Non hazardous Urethane CAS# trade secret, EINECS# , Non hazardous Acrylic
Pct By Wt: <20.0% Vapor Pressure: 17.500
ACGIH TLV-TWA
NE
ACGIH TLV-STEL/C
NE
OSHA PEL-TWA
NE
OSHA PEL-STEL
NE
OSHA PEL-CEILING
NE
LD50 (INGESTION)
NE
LC50 (INHALATION)
NE
AUTOIGNITION TEMP.
NA
SARA: NO/NO
Other Limits: IARC-NO, NTP-NO, OSHA-NO, ACGIH-NO, NIOSH-NO HAPS-NO
-----------------------------------------------------------------------------------------3 WATER CAS# 7732-18-5, EINECS# 231-791-2, Water
Pct By Wt: 45.74 Vapor Pressure: 17.500
ACGIH TLV-TWA
NE
ACGIH TLV-STEL/C
NE
OSHA PEL-TWA
NE
OSHA PEL-STEL
NE
OSHA PEL-CEILING
NE
LD50 (INGESTION)
NE
LC50 (INHALATION)
NE
AUTOIGNITION TEMP.
NA
SARA: NO/NO
Other Limits: IARC-NO, NTP-NO, OSHA-NO, ACGIH-NO, NIOSH-NO HAPS-NO
-----------------------------------------------------------------------------------------4 GLYCOL CAS# 57-55-6 PROPYLENE GLYCOL
Pct By Wt:
< 2.0% LEL: 2.6
ACGIH TLV-TWA
NE
ACGIH TLV-STEL/C
NE
OSHA PEL-TWA
NE
OSHA PEL-STEL
NE
OSHA PEL-CEILING
NE
LD50 (INGESTION)
>2000 mg/kg
LC50 (INHALATION)
NE
AUTOIGNITION TEMP.
790 F
FLASH POINT
99 °C / 210 °F
SARA: NO/NO
Other Limits: IARC-NO. NTP-NO, OSHA-NO, ACGIH-NO, NIOSH-NO HAPS-NO
-----------------------------------------------------------------------------------------5 Calcium Carbonate CAS# 1317-65-3 EINECS# Calcium Carbonate
Pct By Wt: < 4.0%
ACGIH TLV-TWA
10 mg/m3
OSHA PEL-TWA
10 mg/m3
LD50 (INGESTION)
NE
LC50 (INHALATION)
NE
Other Limits: IARC-NO, NTP-NO, OSHA-NO, ACGIH-NO, NIOSH-NO HAPS-NO
-----------------------------------------------------------------------------------------6 TITANIUM DIOXIDE CAS# 13463-67-7 Titanium Dioxide
Pct By Wt: < 5.0%
ACGIH TLV-TWA
10 mg/m3
OSHA PEL-TWA
15 mg/m3
LD50 (INGESTION)
NE
LC50 (INHALATION)
NE
Other Limits: IARC-NO, NTP-NO, OSHA-NO, ACGIH-NO, NIOSH-NO HAPS-NO
Titanium Dioxide contains, Aluminum Hydroxide CAS# 21645-51-2, EINECS# 244-492-7 (0-9% of
Ti02), Amorphous Silica CAS# 7631-86-9, EINECS# 231-545-4 (0-11% of Ti02).
-----------------------------------------------------------------------------------------7 IRON OXIDE CAS# 51274-00-1 C.I. Pigment Yellow 42
Pct By Wt: <1.5%
ACGIH TLV-TWA
5 mg/m3 ( Iron Oxide Fume )
ACGIH TLV-STEL/C
NE
OSHA PEL-TWA
NE
OSHA PEL-STEL
10 ppm ( Iron Oxide Fume as Fe )
OSHA PEL-CEILING
NE
LD50 (INGESTION)
> 10g/kg (rat)
LC50 (INHALATION)
NE
AUTOIGNITION TEMP.
NA
SARA: NO/NO
Other Limits: NTP-NO, IARC-NO, OSHA-NO, ACGIH-NO, NIOSH-NO HAPS-NO
-----------------------------------------------------------------------------------------8 IRON OXIDE CAS# 1309-37-1, EINECS# 215-168-2, RED IRON OXIDE
Pct By Wt: < 1.5%
ACGIH TLV-TWA
5 MG/M3
ACGIH TLV-STEL/C
10MG/M3
OSHA PEL-TWA
10 MG/M3
OSHA PEL-STEL
NE
OSHA PEL-CEILING
NE
LD50 (INGESTION)
>5000 mg/l RAT
PRODUCT CODE: CHOCOLATE BROWN KIT
Page 5
LC50 (INHALATION)
NE
AUTOIGNITION TEMP.
NA
SARA: NO/NO/
Other Limits: IARC-NO; NTP-NO; OSHA-NO ACGIH-NO; NIOSH-NO HAPS-NO
-----------------------------------------------------------------------------------------9 CARBON BLACK CAS# 1333-86-4 CARBON BLACK
Pct By Wt:
< 1.0%
ACGIH TLV-TWA
3.5 MG/M3
ACGIH TLV-STEL/C
3.5MG/M3
OSHA PEL-TWA
3.5 MG/M3
OSHA PEL-STEL
NE
OSHA PEL-CEILING
NE
LD50 (INGESTION)
NE
LC50 (INHALATION)
NE
AUTOIGNITION TEMP.
NA
SARA: NO/NO/
Other Limits: IARC-YES (GROUP 2B), NTP-NO OSHA-NO, ACGIH-NO, NIOSH-NO HAPS-NO
Other Limits: IARC-YES WARNING: The Carbon Black pigment in this product contains less than 0.1% polynuclear aromatic
hydrocarbons (PAH), some of which, in non-adsorbed form, have been found to be carcinogens in animal studies. Carbon
Black has not been listed by the NTP or OSHA. NIOSH criteria recommends that only carbon blacks with PAH levels greater
than 0.1% be considered suspect carcinogens. In April 1996, the International Agency for Research on Cancer
(IARC) published Monograph 65 wherein IARC’s overall evaluation is that Carbon Black is possibly carcinogenic to humans
(Group 2B).
-----------------------------------------------------------------------------------------Section 3 - Hazards Identification
-----------------------------------------------------------------------------------------Routes of Entry: Inhalation, Skin Contact, Eye Contact
Effects of Overexposure: (No hazardous solvent present)
Inhalation – ACUTE (Pigments): Irritation of the nose, throat and eyes: Asthma-like breathing
may be a delayed reaction. Other possible symptoms of overexposure may include headache,
nausea, narcosis, fatigue and loss of appetite.
Eye Contact: Liquid is irritating to the eyes and can cause pain, tearing, reddening and
swelling.
Skin Contact: Repeated or prolonged skin contact can result in dry, defatted and cracked skin
causing increased susceptibility to infection.
Ingestion: Ingestion can result in irritation in the mouth, stomach tissue and digestive
tract. Symptoms can include sore throat, abdominal pain, nausea, vomiting and diarrhea.
Vomiting may cause aspiration resulting in chemical pneumonitis.
-----------------------------------------------------------------------------------------Section 4 - First Aid Measures
-----------------------------------------------------------------------------------------PRIMARY ROUTE(S) OF ENTRY: Inhalation, Dermal, Ingestion.
EMERGENCY FIRST AID PROCEDURES: When exposed always get medical attention.
EYE CONTACT: Flush with water for 15 minutes.
SKIN CONTACT: Wash with soap and water. Remove contaminated clothing and clean before reuse.
INHALATION: Remove to fresh air. Provide oxygen if breathing is difficult. Use artificial
respiration if not breathing. Get medical attention.
IF SWALLOWED: DO NOT INDUCE VOMITING!! Always get medical attention.
-----------------------------------------------------------------------------------------Section 5 - Fire Fighting Measures
-----------------------------------------------------------------------------------------FIRE AND EXPLOSIVE PROPERTIES OF THE CHEMICAL: (Unless otherwise noted, data are derived from
ingredients existing in this formula at concentrations of 1% by weight or greater, i.e., the
flashpoint given is the lowest flashpoint of the ingredients listed in section 2.)
Flashpoint - - - - - - - - - - - - - - -: >99 °C / >210 °F PENSKY MARTENS (CLOSED CUP)
Explosion Level - - - - - - - - - - - - : Low
2.6
High
15.3
Flammability Limits - - - - - - - - - - : Low N/A
High N/A
Auto-ignition Temperature - - - - - - - : N/A
Extinguishing Media: Not required
Hazard Class: DOT: Not regulated
OSHA: Not regulated
Water may be used to cool fire-exposed structures and vessels.
UNUSUAL FIRE AND EXPLOSION HAZARDS: Keep away from heat, sparks, and flame. Do not smoke.
Extinguish all pilot lights and turn off all sources of ignition, including heaters, fans and
other non-explosion proof electrical equipment, during use and until all vapors are gone.
Vapors may ignite explosively. Vapors may spread long distances and beyond closed doors.
Prevent build up of vapors by maintaining a continuous flow of fresh air.
FIRE-FIGHTING PROCEDURES AND EQUIPMENT: Self-contained breathing apparatus with full
facepiece operated in pressure-demand or other positive pressure mode. In case of fire, use
Dry chemical, Foam, CO2 or other approved method for treating a Class B fire. Summon
professional firefighters. Extreme dust conditions due to sanding or abrading may be a source
of autoignition in the presence of a flame. Closed container may explode when exposed to
extreme heat.
-----------------------------------------------------------------------------------------Section 6 - Accidental Release Measures
-----------------------------------------------------------------------------------------Steps to take in case of spills:
· Remove all sources of ignition. Ventilate area (refer to extinguishing media in section 4)
· Remove with inert absorbent material
Waste Disposal Method: If discarded this material and containers should be treated as a
hazardous waste, based on the Ignitability characteristics as defined under Federal RCRA
Regulations (40 CFR 261). Dispose of in accordance with local, state, and federal regulations.
DO NOT INCINERATE IN CLOSED CONTAINERS. For further information, contact the United States
Environmental Protection Agency RCRA hotline (800) 242-9342.
------------------------------------------------------------------------------------------
DATE: 07/07/2011
COMPANY NAME:
GIANI, Inc.
Section 7 - Handling and Storage
-----------------------------------------------------------------------------------------Handling and Storage: Keep away from heat. When storing, tightly
close containers to prevent evaporation. Do not reseal if contamination
is suspected. Do not take internally.
-----------------------------------------------------------------------------------------Section 8 - Exposure Controls, Personal Protection
-----------------------------------------------------------------------------------------Respiratory Protection: If personal exposure cannot be controlled below applicable limits by
ventilation, use an air-purifying respirator demonstrated to be effective for organic
vapor/particulate and approved by NIOSH for protection against materials in section 2.
Ventilation: Local exhaust is preferable. General exhaust is acceptable if the exposure to
materials in section 2 is maintained below acceptable
exposure limits. Protective Gloves: Wear gloves which are recommended by glove
supplier for protection against Materials in Section 2.
Eye Protection: Wear safety glasses with unperforated side shields
-----------------------------------------------------------------------------------------Section 9 - Physical and Chemical Properties
-----------------------------------------------------------------------------------------Physical Appearance - - - - - - - - - - : Tan Liquid
Odor - - - - - - - - - - - - - - - - - -: Odorless
Physical State - - - - - - - - - - - - -: Liquid
pH - - - - - - - - - - - - - - - - - - -: 8.0 - 10.50
Vapor Density - - - - - - - - - - - - - : Heavier than air
Boiling Range Lower - - - - - - - - - - :
192.0 °F
Higher - - - - - - - - - -:
396.0 °F
Freezing Point - - - - - - - - - - - - -: Not Established
Melting Point - - - - - - - - - - - - - : Not Established
Water Solubility - - - - - - - - - - - -: Soluble
Specific Gravity - - - - - - - - - - - -:
1.10
Formula Weight per Volume - - - - - - - :
9.18 Pound/Gallon
VOC - - - - - - - - - - - - - - - - - - : < 101 g/l, < 0.84 lb/gal
Viscosity - - - - - - - - - - - - - - - :
Evaporation Rate - - - - - - - - - - - -: Slower than ether
Percent Volatile by Weight - - - - - - -:
68.00
Percent Volatile by Volume - - - - - - -:
82.50
-----------------------------------------------------------------------------------------Section 10 - Stability and Reactivity
-----------------------------------------------------------------------------------------Stability: This material is stable
Materials to avoid: Unknown.
Hazardous Polymerization: Will not occur.
Decomposition Products: By high heat and fire: CO2, CO
-----------------------------------------------------------------------------------------Section 11 - Toxicological Information
-----------------------------------------------------------------------------------------Propylene Glycol
:
CAS# 57-55-6
oral
:
LD50 : > 20,000 mg/kg (rat)
dermal
:
LD50 : > 20,000 mg/kg (rabbit)
Carbon Black Pigment
Oral
Dermal
edema)
Inhalation (as dust)
:
:
:
CAS# 1333-86-4, EINECS# 215-609-9
LD50: >8,000 mg/kg (rat)
LD50: non-irrative, index score 0.6/8 (4.0+severe
:
LC50: NOEL + 1.1 mg/m3 (rat 90 days)
Target organ (as dust): Lungs
:
Effect: inflammation, hyperplasia, fibrosis.
-----------------------------------------------------------------------------------------Section 12 - Ecological Information
-----------------------------------------------------------------------------------------Propylene Glycol
:
CAS# 57-55-6
Toxicity to other organisms:
Fish toxicity
:
LC50, rainbow trout (Oncorhynchus mykiss),
:
96 h: 44,000 - 51,600 mg/l
Daphnia toxicity
:
EC50: (48 h) > 34,000 mg/l
Algae toxicity
:
EC50: (72 h) > 19,000 mg/l
:green alga Selenastrum capricornutum, biomass growth
inhibition)
Persistance and degradability :
Mobility
:
Not soluble in water
Bioaccumulation
:
Not expected because of physiochemical properties of
substance.
-----------------------------------------------------------------------------------------Carbon Black Pigment
:
CAS# 1333-86-4
Toxicity to other organisms:
Fish toxicity
:
LC50: (96 h) >10,000 mg/l Branchdanio rerio (zebra
fish)
Daphnia toxicity
:
EC50: (24 h) > 5600 mg/l
Algae toxicity
:
EC50: (72 h) > 10,000 mg/l,
:
NEOC 50≥ 10,000 mg/l (Scenedesmus subspicatus)
Persistance and degradability :
Mobility
:
Not soluble in water
PRODUCT CODE: CHOCOLATE BROWN KIT
Bioaccumulation
substance.
:
Page 6
Not expected because of physiochemical properties of
Section 13 - Disposal Considerations
-----------------------------------------------------------------------------------------WASTE DISPOSAL METHOD: Dispose of contaminated absorbent, container and unused contents in
accordance with local, state and federal regulations. Do not incinerate closed containers.
-----------------------------------------------------------------------------------------Section 14 - Transport Information
-----------------------------------------------------------------------------------------DOT – NOT REGULATED
Canadian TDGA – NOT REGULATED
-----------------------------------------------------------------------------------------Section 15 - Regulatory Information
-----------------------------------------------------------------------------------------FEDERAL REGULATIONS:
SARA SECTION 302-304. The superfund amendments and reauthorization act of 1986 (SARA) title
III requires facilities subject to subparts 303 and 304 to submit emergency planning and
notification information based on threshold planning quantities (TPQs) and reportable
quantities (RQs) for "Extremely Hazardous Substances" listed in 40 CFR 302.4 and 40 CFR 355.
SARA (311,312) HAZARD CLASS. The superfund amendments and reauthorization act of 1986 (SARA)
title III requires facilities subject to subpart to submit aggregate information on chemicals
by "Hazard Category" as defined in 40 CFR 370.2
Immediate (Acute) Yes Health Hazard see Section 11
Delayed (Chronic) Health Hazard No
Fire Hazard No
Reactive Hazard No Sudden Release of Pressure Hazard No
SARA (313) CHEMICALS. Components in concentrations above the de minimus levels that are listed
as toxic chemicals in 40 CFR Part 372 pursuant to the requirements in section 313 of SARA.
Superfund Amendments and Reauthorization Act of 1986 Title III
(Emergency Planning and Community Right-to-Know Act of 1986) Section 313
To the best of our knowledge, this product does not contain chemicals at levels which require
reporting under this statute.
Pennsylvania (Worker and Community Right-To-Know Act): Pennsylvania HazardousSubstances List
and/or Pennsylvania Environmental Hazardous Substance List:
The following product components are cited in the Pennsylvania Hazardous Substance List and/or
the Pennsylvania Environmental Substance List, and are present at levels which require
reporting.
Component CAS # Amount
To the best of our knowledge, this product does not contain chemicals at levels which require
reporting
under this statute.
Comprehensive Environmental Response, Compensation, and Liability Act of 1980 (CERCLA)
Section 103
To the best of our knowledge, this product does not contain chemicals at levels which require
reporting under this statute.
US. EPA Emergency Planning and Community Right-To-Know Act (EPCRA) SARA Title III
Section 302 Extremely Hazardous Substance (40 CFR 355, Appendix A)
To the best of our knowledge, this product does not contain chemicals at levels which require
reporting under this statute.
California Proposition 65 (Safe Drinking Water and Toxic Enforcement Act of 1986)
This product contains no listed substances known to the State of California to cause cancer,
birth defects or other reproductive harm, at levels which would require a warning under the
statute.
US. Toxic Substances Control Act
All components of this product are on the TSCA Inventory or are exempt from TSCA Inventory
requirements under 40 CFR 720.30
CEPA - Domestic Substances List (DSL)
All substances contained in this product are listed on the Canadian Domestic Substances List
(DSL) or are not required to be listed.
Section 16 - Other Information
-----------------------------------------------------------------------------------------NOTE: Read MSDS completely before use and follow all label instructions.
The information contained in this MSDS is based on the present state of knowledge and is based
on sources believed to be reliable.
However, since the data safety standards and government regulations are subject to change and
the conditions of handling and use or misuse are beyond our control, Giani, Inc. makes no
warranty, either express or implied, with respect to the information contained
Date: 07/07/2011
DATE: 07/07/2011
Date:
COMPANY NAME:
GIANI, Inc.
07/07/2011
MATERIAL SAFETY DATA SHEET
PREPARED BY: Environmental, Health and Safety Department
MSDS PREPARATION DATE: 07/07/2011, Version 1
-----------------------------------------------------------------------------------------Section 1 - Chemical Product and Company Identification
-----------------------------------------------------------------------------------------MANUFACTURER
Giani,Inc.
ADDRESS
2216 North Broadway
St. Louis, MO 63102
INFORMATION
314-241-3500
EMERGENCY
CHEMTREC 800-424-9300 or 703-527-3887
TRADE NAME
Chocolate Brown
PRODUCT CODE
EX 987-6
HMIS Classification: Health 1, Flammability 0, Reactivity 0, Personal Protection Code
NFPA
0,
1,
0
-----------------------------------------------------------------------------------------Section 2 - Composition, Information on Ingredients
-----------------------------------------------------------------------------------------1 Non hazardous Acrylic CAS# trade secret, EINECS# , Non hazardous Acrylic
Pct By Wt: <20.0% Vapor Pressure: 17.500
ACGIH TLV-TWA
NE
ACGIH TLV-STEL/C
NE
OSHA PEL-TWA
NE
OSHA PEL-STEL
NE
OSHA PEL-CEILING
NE
LD50 (INGESTION)
NE
LC50 (INHALATION)
NE
AUTOIGNITION TEMP.
NA
SARA: NO/NO
Other Limits: IARC-NO, NTP-NO, OSHA-NO, ACGIH-NO, NIOSH-NO HAPS-NO
-----------------------------------------------------------------------------------------2 Non hazardous Urethane CAS# trade secret, EINECS# , Non hazardous Acrylic
Pct By Wt: <20.0% Vapor Pressure: 17.500
ACGIH TLV-TWA
NE
ACGIH TLV-STEL/C
NE
OSHA PEL-TWA
NE
OSHA PEL-STEL
NE
OSHA PEL-CEILING
NE
LD50 (INGESTION)
NE
LC50 (INHALATION)
NE
AUTOIGNITION TEMP.
NA
SARA: NO/NO
Other Limits: IARC-NO, NTP-NO, OSHA-NO, ACGIH-NO, NIOSH-NO HAPS-NO
-----------------------------------------------------------------------------------------3 WATER CAS# 7732-18-5, EINECS# 231-791-2, Water
Pct By Wt: 45.74 Vapor Pressure: 17.500
ACGIH TLV-TWA
NE
ACGIH TLV-STEL/C
NE
OSHA PEL-TWA
NE
OSHA PEL-STEL
NE
OSHA PEL-CEILING
NE
LD50 (INGESTION)
NE
LC50 (INHALATION)
NE
AUTOIGNITION TEMP.
NA
SARA: NO/NO
Other Limits: IARC-NO, NTP-NO, OSHA-NO, ACGIH-NO, NIOSH-NO HAPS-NO
-----------------------------------------------------------------------------------------4 GLYCOL CAS# 57-55-6 PROPYLENE GLYCOL
Pct By Wt:
< 2.0% LEL: 2.6
ACGIH TLV-TWA
NE
ACGIH TLV-STEL/C
NE
OSHA PEL-TWA
NE
OSHA PEL-STEL
NE
OSHA PEL-CEILING
NE
LD50 (INGESTION)
>2000 mg/kg
LC50 (INHALATION)
NE
AUTOIGNITION TEMP.
790 F
FLASH POINT
99 °C / 210 °F
SARA: NO/NO
Other Limits: IARC-NO. NTP-NO, OSHA-NO, ACGIH-NO, NIOSH-NO HAPS-NO
-----------------------------------------------------------------------------------------5 Calcium Carbonate CAS# 1317-65-3 EINECS# Calcium Carbonate
Pct By Wt: < 4.0%
ACGIH TLV-TWA
10 mg/m3
OSHA PEL-TWA
10 mg/m3
LD50 (INGESTION)
NE
LC50 (INHALATION)
NE
Other Limits: IARC-NO, NTP-NO, OSHA-NO, ACGIH-NO, NIOSH-NO HAPS-NO
-----------------------------------------------------------------------------------------6 TITANIUM DIOXIDE CAS# 13463-67-7 Titanium Dioxide
Pct By Wt: < 5.0%
ACGIH TLV-TWA
10 mg/m3
OSHA PEL-TWA
15 mg/m3
LD50 (INGESTION)
NE
LC50 (INHALATION)
NE
Other Limits: IARC-NO, NTP-NO, OSHA-NO, ACGIH-NO, NIOSH-NO HAPS-NO
Titanium Dioxide contains, Aluminum Hydroxide CAS# 21645-51-2, EINECS# 244-492-7 (0-9% of
Ti02), Amorphous Silica CAS# 7631-86-9, EINECS# 231-545-4 (0-11% of Ti02).
-----------------------------------------------------------------------------------------7 IRON OXIDE CAS# 51274-00-1 C.I. Pigment Yellow 42
Pct By Wt: <1.5%
ACGIH TLV-TWA
5 mg/m3 ( Iron Oxide Fume )
ACGIH TLV-STEL/C
NE
OSHA PEL-TWA
NE
OSHA PEL-STEL
10 ppm ( Iron Oxide Fume as Fe )
OSHA PEL-CEILING
NE
LD50 (INGESTION)
> 10g/kg (rat)
LC50 (INHALATION)
NE
AUTOIGNITION TEMP.
NA
SARA: NO/NO
Other Limits: NTP-NO, IARC-NO, OSHA-NO, ACGIH-NO, NIOSH-NO HAPS-NO
-----------------------------------------------------------------------------------------8 IRON OXIDE CAS# 1309-37-1, EINECS# 215-168-2, RED IRON OXIDE
Pct By Wt: < 1.5%
ACGIH TLV-TWA
5 MG/M3
ACGIH TLV-STEL/C
10MG/M3
OSHA PEL-TWA
10 MG/M3
OSHA PEL-STEL
NE
PRODUCT CODE: CHOCOLATE BROWN KIT
Page 7
OSHA PEL-CEILING
NE
LD50 (INGESTION)
>5000 mg/l RAT
LC50 (INHALATION)
NE
AUTOIGNITION TEMP.
NA
SARA: NO/NO/
Other Limits: IARC-NO; NTP-NO; OSHA-NO ACGIH-NO; NIOSH-NO HAPS-NO
-----------------------------------------------------------------------------------------9 CARBON BLACK CAS# 1333-86-4 CARBON BLACK
Pct By Wt:
< 1.0%
ACGIH TLV-TWA
3.5 MG/M3
ACGIH TLV-STEL/C
3.5MG/M3
OSHA PEL-TWA
3.5 MG/M3
OSHA PEL-STEL
NE
OSHA PEL-CEILING
NE
LD50 (INGESTION)
NE
LC50 (INHALATION)
NE
AUTOIGNITION TEMP.
NA
SARA: NO/NO/
Other Limits: IARC-YES (GROUP 2B), NTP-NO OSHA-NO, ACGIH-NO, NIOSH-NO HAPS-NO
Other Limits: IARC-YES WARNING: The Carbon Black pigment in this product contains less than 0.1% polynuclear aromatic
hydrocarbons (PAH), some of which, in non-adsorbed form, have been found to be carcinogens in animal studies. Carbon
Black has not been listed by the NTP or OSHA. NIOSH criteria recommends that only carbon blacks with PAH levels greater
than 0.1% be considered suspect carcinogens. In April 1996, the International Agency for Research on Cancer
(IARC) published Monograph 65 wherein IARC’s overall evaluation is that Carbon Black is possibly carcinogenic to humans
(Group 2B).
-----------------------------------------------------------------------------------------Section 3 - Hazards Identification
-----------------------------------------------------------------------------------------Routes of Entry: Inhalation, Skin Contact, Eye Contact
Effects of Overexposure: (No hazardous solvent present)
Inhalation – ACUTE (Pigments): Irritation of the nose, throat and eyes: Asthma-like breathing
may be a delayed reaction. Other possible symptoms of overexposure may include headache,
nausea, narcosis, fatigue and loss of appetite.
Eye Contact: Liquid is irritating to the eyes and can cause pain, tearing, reddening and
swelling.
Skin Contact: Repeated or prolonged skin contact can result in dry, defatted and cracked skin
causing increased susceptibility to infection.
Ingestion: Ingestion can result in irritation in the mouth, stomach tissue and digestive
tract. Symptoms can include sore throat, abdominal pain, nausea, vomiting and diarrhea.
Vomiting may cause aspiration resulting in chemical pneumonitis.
-----------------------------------------------------------------------------------------Section 4 - First Aid Measures
-----------------------------------------------------------------------------------------PRIMARY ROUTE(S) OF ENTRY: Inhalation, Dermal, Ingestion.
EMERGENCY FIRST AID PROCEDURES: When exposed always get medical attention.
EYE CONTACT: Flush with water for 15 minutes.
SKIN CONTACT: Wash with soap and water. Remove contaminated clothing and clean before reuse.
INHALATION: Remove to fresh air. Provide oxygen if breathing is difficult. Use artificial
respiration if not breathing. Get medical attention.
IF SWALLOWED: DO NOT INDUCE VOMITING!! Always get medical attention.
-----------------------------------------------------------------------------------------Section 5 - Fire Fighting Measures
-----------------------------------------------------------------------------------------FIRE AND EXPLOSIVE PROPERTIES OF THE CHEMICAL: (Unless otherwise noted, data are derived from
ingredients existing in this formula at concentrations of 1% by weight or greater, i.e., the
flashpoint given is the lowest flashpoint of the ingredients listed in section 2.)
Flashpoint - - - - - - - - - - - - - - -: >99 °C / >210 °F PENSKY MARTENS (CLOSED CUP)
Explosion Level - - - - - - - - - - - - : Low
2.6
High
15.3
Flammability Limits - - - - - - - - - - : Low N/A
High N/A
Auto-ignition Temperature - - - - - - - : N/A
Extinguishing Media: Not required
Hazard Class: DOT: Not regulated
OSHA: Not regulated
Water may be used to cool fire-exposed structures and vessels.
UNUSUAL FIRE AND EXPLOSION HAZARDS: Keep away from heat, sparks, and flame. Do not smoke.
Extinguish all pilot lights and turn off all sources of ignition, including heaters, fans and
other non-explosion proof electrical equipment, during use and until all vapors are gone.
Vapors may ignite explosively. Vapors may spread long distances and beyond closed doors.
Prevent build up of vapors by maintaining a continuous flow of fresh air.
FIRE-FIGHTING PROCEDURES AND EQUIPMENT: Self-contained breathing apparatus with full
facepiece operated in pressure-demand or other positive pressure mode. In case of fire, use
Dry chemical, Foam, CO2 or other approved method for treating a Class B fire. Summon
professional firefighters. Extreme dust conditions due to sanding or abrading may be a source
of autoignition in the presence of a flame. Closed container may explode when exposed to
extreme heat.
-----------------------------------------------------------------------------------------Section 6 - Accidental Release Measures
-----------------------------------------------------------------------------------------Steps to take in case of spills:
· Remove all sources of ignition. Ventilate area (refer to extinguishing media in section 4)
· Remove with inert absorbent material
Waste Disposal Method: If discarded this material and containers should be treated as a
hazardous waste, based on the Ignitability characteristics as defined under Federal RCRA
Regulations (40 CFR 261). Dispose of in accordance with local, state, and federal regulations.
DO NOT INCINERATE IN CLOSED CONTAINERS. For further information, contact the United States
Environmental Protection Agency RCRA hotline (800) 242-9342.
------------------------------------------------------------------------------------------
DATE: 07/07/2011
COMPANY NAME:
GIANI, Inc.
Section 7 - Handling and Storage
-----------------------------------------------------------------------------------------Handling and Storage: Keep away from heat. When storing, tightly
close containers to prevent evaporation. Do not reseal if contamination
is suspected. Do not take internally.
-----------------------------------------------------------------------------------------Section 8 - Exposure Controls, Personal Protection
-----------------------------------------------------------------------------------------Respiratory Protection: If personal exposure cannot be controlled below applicable limits by
ventilation, use an air-purifying respirator demonstrated to be effective for organic
vapor/particulate and approved by NIOSH for protection against materials in section 2.
Ventilation: Local exhaust is preferable. General exhaust is acceptable if the exposure to
materials in section 2 is maintained below acceptable
exposure limits. Protective Gloves: Wear gloves which are recommended by glove
supplier for protection against Materials in Section 2.
Eye Protection: Wear safety glasses with unperforated side shields
-----------------------------------------------------------------------------------------Section 9 - Physical and Chemical Properties
-----------------------------------------------------------------------------------------Physical Appearance - - - - - - - - - - : Brown Liquid
Odor - - - - - - - - - - - - - - - - - -: Odorless
Physical State - - - - - - - - - - - - -: Liquid
pH - - - - - - - - - - - - - - - - - - -: 8.0 - 10.50
Vapor Density - - - - - - - - - - - - - : Heavier than air
Boiling Range Lower - - - - - - - - - - :
192.0 °F
Higher - - - - - - - - - -:
396.0 °F
Freezing Point - - - - - - - - - - - - -: Not Established
Melting Point - - - - - - - - - - - - - : Not Established
Water Solubility - - - - - - - - - - - -: Soluble
Specific Gravity - - - - - - - - - - - -:
1.10
Formula Weight per Volume - - - - - - - :
9.18 Pound/Gallon
VOC - - - - - - - - - - - - - - - - - - : < 101 g/l, < 0.84 lb/gal
Viscosity - - - - - - - - - - - - - - - :
Evaporation Rate - - - - - - - - - - - -: Slower than ether
Percent Volatile by Weight - - - - - - -:
68.00
Percent Volatile by Volume - - - - - - -:
82.50
-----------------------------------------------------------------------------------------Section 10 - Stability and Reactivity
-----------------------------------------------------------------------------------------Stability: This material is stable
Materials to avoid: Unknown.
Hazardous Polymerization: Will not occur.
Decomposition Products: By high heat and fire: CO2, CO
-----------------------------------------------------------------------------------------Section 11 - Toxicological Information
-----------------------------------------------------------------------------------------Propylene Glycol
:
CAS# 57-55-6
oral
:
LD50 : > 20,000 mg/kg (rat)
dermal
:
LD50 : > 20,000 mg/kg (rabbit)
Carbon Black Pigment
Oral
Dermal
edema)
Inhalation (as dust)
:
:
:
CAS# 1333-86-4, EINECS# 215-609-9
LD50: >8,000 mg/kg (rat)
LD50: non-irrative, index score 0.6/8 (4.0+severe
:
LC50: NOEL + 1.1 mg/m3 (rat 90 days)
Target organ (as dust): Lungs
:
Effect: inflammation, hyperplasia, fibrosis.
-----------------------------------------------------------------------------------------Section 12 - Ecological Information
-----------------------------------------------------------------------------------------Propylene Glycol
:
CAS# 57-55-6
Toxicity to other organisms:
Fish toxicity
:
LC50, rainbow trout (Oncorhynchus mykiss),
:
96 h: 44,000 - 51,600 mg/l
Daphnia toxicity
:
EC50: (48 h) > 34,000 mg/l
Algae toxicity
:
EC50: (72 h) > 19,000 mg/l
:green alga Selenastrum capricornutum, biomass growth
inhibition)
Persistance and degradability :
Mobility
:
Not soluble in water
Bioaccumulation
:
Not expected because of physiochemical properties of
substance.
-----------------------------------------------------------------------------------------Carbon Black Pigment
:
CAS# 1333-86-4
Toxicity to other organisms:
Fish toxicity
:
LC50: (96 h) >10,000 mg/l Branchdanio rerio (zebra
fish)
Daphnia toxicity
:
EC50: (24 h) > 5600 mg/l
Algae toxicity
:
EC50: (72 h) > 10,000 mg/l,
:
NEOC 50≥ 10,000 mg/l (Scenedesmus subspicatus)
Persistance and degradability :
Mobility
:
Not soluble in water
PRODUCT CODE: CHOCOLATE BROWN KIT
Bioaccumulation
substance.
:
Page 8
Not expected because of physiochemical properties of
Section 13 - Disposal Considerations
-----------------------------------------------------------------------------------------WASTE DISPOSAL METHOD: Dispose of contaminated absorbent, container and unused contents in
accordance with local, state and federal regulations. Do not incinerate closed containers.
-----------------------------------------------------------------------------------------Section 14 - Transport Information
-----------------------------------------------------------------------------------------DOT – NOT REGULATED
Canadian TDGA – NOT REGULATED
-----------------------------------------------------------------------------------------Section 15 - Regulatory Information
-----------------------------------------------------------------------------------------FEDERAL REGULATIONS:
SARA SECTION 302-304. The superfund amendments and reauthorization act of 1986 (SARA) title
III requires facilities subject to subparts 303 and 304 to submit emergency planning and
notification information based on threshold planning quantities (TPQs) and reportable
quantities (RQs) for "Extremely Hazardous Substances" listed in 40 CFR 302.4 and 40 CFR 355.
SARA (311,312) HAZARD CLASS. The superfund amendments and reauthorization act of 1986 (SARA)
title III requires facilities subject to subpart to submit aggregate information on chemicals
by "Hazard Category" as defined in 40 CFR 370.2
Immediate (Acute) Yes Health Hazard see Section 11
Delayed (Chronic) Health Hazard No
Fire Hazard No
Reactive Hazard No Sudden Release of Pressure Hazard No
SARA (313) CHEMICALS. Components in concentrations above the de minimus levels that are listed
as toxic chemicals in 40 CFR Part 372 pursuant to the requirements in section 313 of SARA.
Superfund Amendments and Reauthorization Act of 1986 Title III
(Emergency Planning and Community Right-to-Know Act of 1986) Section 313
To the best of our knowledge, this product does not contain chemicals at levels which require
reporting under this statute.
Pennsylvania (Worker and Community Right-To-Know Act): Pennsylvania HazardousSubstances List
and/or Pennsylvania Environmental Hazardous Substance List:
The following product components are cited in the Pennsylvania Hazardous Substance List and/or
the Pennsylvania Environmental Substance List, and are present at levels which require
reporting.
Component CAS # Amount
To the best of our knowledge, this product does not contain chemicals at levels which require
reporting
under this statute.
Comprehensive Environmental Response, Compensation, and Liability Act of 1980 (CERCLA)
Section 103
To the best of our knowledge, this product does not contain chemicals at levels which require
reporting under this statute.
US. EPA Emergency Planning and Community Right-To-Know Act (EPCRA) SARA Title III
Section 302 Extremely Hazardous Substance (40 CFR 355, Appendix A)
To the best of our knowledge, this product does not contain chemicals at levels which require
reporting under this statute.
California Proposition 65 (Safe Drinking Water and Toxic Enforcement Act of 1986)
This product contains no listed substances known to the State of California to cause cancer,
birth defects or other reproductive harm, at levels which would require a warning under the
statute.
US. Toxic Substances Control Act
All components of this product are on the TSCA Inventory or are exempt from TSCA Inventory
requirements under 40 CFR 720.30
CEPA - Domestic Substances List (DSL)
All substances contained in this product are listed on the Canadian Domestic Substances List
(DSL) or are not required to be listed.
Section 16 - Other Information
-----------------------------------------------------------------------------------------NOTE: Read MSDS completely before use and follow all label instructions.
The information contained in this MSDS is based on the present state of knowledge and is based
on sources believed to be reliable.
However, since the data safety standards and government regulations are subject to change and
the conditions of handling and use or misuse are beyond our control, Giani, Inc. makes no
warranty, either express or implied, with respect to the information contained
Date: 07/07/2011
DATE: 07/07/2011
Date:
COMPANY NAME:
GIANI, Inc.
07/07/2011
MATERIAL SAFETY DATA SHEET
PREPARED BY: Environmental, Health and Safety Department
MSDS PREPARATION DATE: 07/07/2011, Version 1
-----------------------------------------------------------------------------------------Section 1 - Chemical Product and Company Identification
-----------------------------------------------------------------------------------------MANUFACTURER
Giani,Inc.
ADDRESS
2216 North Broadway
St. Louis, MO 63102
INFORMATION
314-241-3500
EMERGENCY
CHEMTREC 800-424-9300 or 703-527-3887
TRADE NAME
CLEAR TOP COAT
PRODUCT CODE
EX 982-29
HMIS Classification: Health 1, Flammability 0, Reactivity 0, Personal Protection Code
NFPA
0,
1,
0
-----------------------------------------------------------------------------------------Section 2 - Composition, Information on Ingredients
-----------------------------------------------------------------------------------------1 Non hazardous Acrylic CAS# trade secret, EINECS# , Non hazardous Acrylic
Pct By Wt: <20.0% Vapor Pressure: 17.500
ACGIH TLV-TWA
NE
ACGIH TLV-STEL/C
NE
OSHA PEL-TWA
NE
OSHA PEL-STEL
NE
OSHA PEL-CEILING
NE
LD50 (INGESTION)
NE
LC50 (INHALATION)
NE
AUTOIGNITION TEMP.
NA
SARA: NO/NO
Other Limits: IARC-NO, NTP-NO, OSHA-NO, ACGIH-NO, NIOSH-NO HAPS-NO
-----------------------------------------------------------------------------------------2 Non hazardous Urethane CAS# trade secret,
Pct By Wt: <20.0% Vapor Pressure: 17.500
ACGIH TLV-TWA
NE
ACGIH TLV-STEL/C
NE
OSHA PEL-TWA
NE
OSHA PEL-STEL
NE
OSHA PEL-CEILING
NE
LD50 (INGESTION)
NE
LC50 (INHALATION)
NE
AUTOIGNITION TEMP.
NA
SARA: NO/NO
Other Limits: IARC-NO, NTP-NO, OSHA-NO, ACGIH-NO, NIOSH-NO HAPS-NO
-----------------------------------------------------------------------------------------3 WATER CAS# 7732-18-5, EINECS# 231-791-2, Water
Pct By Wt: 45.74 Vapor Pressure: 17.500
ACGIH TLV-TWA
NE
ACGIH TLV-STEL/C
NE
OSHA PEL-TWA
NE
OSHA PEL-STEL
NE
OSHA PEL-CEILING
NE
LD50 (INGESTION)
NE
LC50 (INHALATION)
NE
AUTOIGNITION TEMP.
NA
SARA: NO/NO
Other Limits: IARC-NO, NTP-NO, OSHA-NO, ACGIH-NO, NIOSH-NO HAPS-NO
-----------------------------------------------------------------------------------------4 GLYCOL CAS# 34590-94-8 DI PROPYLENE GLYCOL
Pct By Wt:
< 8.0% LEL: 2.6
ACGIH TLV-TWA
NE
ACGIH TLV-STEL/C
NE
OSHA PEL-TWA
NE
OSHA PEL-STEL
NE
OSHA PEL-CEILING
NE
LD50 (INGESTION)
>2000 mg/kg
LC50 (INHALATION)
NE
AUTOIGNITION TEMP.
790 F
FLASH POINT
99 °C / 210 °F
SARA: NO/NO
Other Limits: IARC-NO. NTP-NO, OSHA-NO, ACGIH-NO, NIOSH-NO HAPS-NO
----------------------------------------------------------------------------------------------------------------------------------------------------------------------------------5 GLYCOL CAS# 107-98-2 GLYCOL PM
Pct By Wt:
< 1.0% LEL: 2.6
ACGIH TLV-TWA
NE
ACGIH TLV-STEL/C
NE
OSHA PEL-TWA
NE
OSHA PEL-STEL
NE
OSHA PEL-CEILING
NE
LD50 (INGESTION)
>2000 mg/kg
LC50 (INHALATION)
NE
AUTOIGNITION TEMP.
790 F
FLASH POINT
99 °C / 210 °F
SARA: NO/NO
Other Limits: IARC-NO. NTP-NO, OSHA-NO, ACGIH-NO, NIOSH-NO HAPS-NO
----------------------------------------------------------------------------------------------------------------------------------------------------------------------------------Section 3 - Hazards Identification
-----------------------------------------------------------------------------------------Routes of Entry: Inhalation, Skin Contact, Eye Contact
Effects of Overexposure: (No hazardous solvent present)
Inhalation – ACUTE (Pigments): Irritation of the nose, throat and eyes: Asthma-like breathing
may be a delayed reaction. Other possible symptoms of overexposure may include headache,
nausea, narcosis, fatigue and loss of appetite.
Eye Contact: Liquid is irritating to the eyes and can cause pain, tearing, reddening and
swelling.
Skin Contact: Repeated or prolonged skin contact can result in dry, defatted and cracked skin
causing increased susceptibility to infection.
Ingestion: Ingestion can result in irritation in the mouth, stomach tissue and digestive
tract. Symptoms can include sore throat, abdominal pain, nausea, vomiting and diarrhea.
Vomiting may cause aspiration resulting in chemical pneumonitis.
-----------------------------------------------------------------------------------------Section 4 - First Aid Measures
------------------------------------------------------------------------------------------
PRODUCT CODE: CHOCOLATE BROWN KIT
Page 9
PRIMARY ROUTE(S) OF ENTRY: Inhalation, Dermal, Ingestion.
EMERGENCY FIRST AID PROCEDURES: When exposed always get medical attention.
EYE CONTACT: Flush with water for 15 minutes.
SKIN CONTACT: Wash with soap and water. Remove contaminated clothing and clean before reuse.
INHALATION: Remove to fresh air. Provide oxygen if breathing is difficult. Use artificial
respiration if not breathing. Get medical attention.
IF SWALLOWED: DO NOT INDUCE VOMITING!! Always get medical attention.
-----------------------------------------------------------------------------------------Section 5 - Fire Fighting Measures
-----------------------------------------------------------------------------------------FIRE AND EXPLOSIVE PROPERTIES OF THE CHEMICAL: (Unless otherwise noted, data are derived from
ingredients existing in this formula at concentrations of 1% by weight or greater, i.e., the
flashpoint given is the lowest flashpoint of the ingredients listed in section 2.)
Flashpoint - - - - - - - - - - - - - - -: >99 °C / >210 °F PENSKY MARTENS (CLOSED CUP)
Explosion Level - - - - - - - - - - - - : Low
2.6
High
15.3
Flammability Limits - - - - - - - - - - : Low N/A
High N/A
Auto-ignition Temperature - - - - - - - : N/A
Extinguishing Media: Not required
Hazard Class: DOT: Not regulated
OSHA: Not regulated
Water may be used to cool fire-exposed structures and vessels.
UNUSUAL FIRE AND EXPLOSION HAZARDS: Keep away from heat, sparks, and flame. Do not smoke.
Extinguish all pilot lights and turn off all sources of ignition, including heaters, fans and
other non-explosion proof electrical equipment, during use and until all vapors are gone.
Vapors may ignite explosively. Vapors may spread long distances and beyond closed doors.
Prevent build up of vapors by maintaining a continuous flow of fresh air.
FIRE-FIGHTING PROCEDURES AND EQUIPMENT: Self-contained breathing apparatus with full
facepiece operated in pressure-demand or other positive pressure mode. In case of fire, use
Dry chemical, Foam, CO2 or other approved method for treating a Class B fire. Summon
professional firefighters. Extreme dust conditions due to sanding or abrading may be a source
of autoignition in the presence of a flame. Closed container may explode when exposed to
extreme heat.
-----------------------------------------------------------------------------------------Section 6 - Accidental Release Measures
-----------------------------------------------------------------------------------------Steps to take in case of spills:
· Remove all sources of ignition. Ventilate area (refer to extinguishing media in section 4)
· Remove with inert absorbent material
Waste Disposal Method: If discarded this material and containers should be treated as a
hazardous waste, based on the Ignitability characteristics as defined under Federal RCRA
Regulations (40 CFR 261). Dispose of in accordance with local, state, and federal regulations.
DO NOT INCINERATE IN CLOSED CONTAINERS. For further information, contact the United States
Environmental Protection Agency RCRA hotline (800) 242-9342.
-----------------------------------------------------------------------------------------Section 7 - Handling and Storage
-----------------------------------------------------------------------------------------Handling and Storage: Keep away from heat. When storing, tightly
close containers to prevent evaporation. Do not reseal if contamination
is suspected. Do not take internally.
-----------------------------------------------------------------------------------------Section 8 - Exposure Controls, Personal Protection
-----------------------------------------------------------------------------------------Respiratory Protection: If personal exposure cannot be controlled below applicable limits by
ventilation, use an air-purifying respirator demonstrated to be effective for organic
vapor/particulate and approved by NIOSH for protection against materials in section 2.
Ventilation: Local exhaust is preferable. General exhaust is acceptable if the exposure to
materials in section 2 is maintained below acceptable
exposure limits. Protective Gloves: Wear gloves which are recommended by glove
supplier for protection against Materials in Section 2.
Eye Protection: Wear safety glasses with unperforated side shields
-----------------------------------------------------------------------------------------Section 9 - Physical and Chemical Properties
-----------------------------------------------------------------------------------------Physical Appearance - - - - - - - - - - : Claer Liquid
Odor - - - - - - - - - - - - - - - - - -: Odorless
Physical State - - - - - - - - - - - - -: Liquid
pH - - - - - - - - - - - - - - - - - - -: 8.0 - 10.50
Vapor Density - - - - - - - - - - - - - : Heavier than air
Boiling Range Lower - - - - - - - - - - :
192.0 °F
Higher - - - - - - - - - -:
396.0 °F
Freezing Point - - - - - - - - - - - - -: Not Established
Melting Point - - - - - - - - - - - - - : Not Established
Water Solubility - - - - - - - - - - - -: Soluble
Specific Gravity - - - - - - - - - - - -:
1.04
Formula Weight per Volume - - - - - - - :
8.68 Pound/Gallon
VOC - - - - - - - - - - - - - - - - - - : < 275 g/l, < 2.29 lb/gal
Viscosity - - - - - - - - - - - - - - - :
Evaporation Rate - - - - - - - - - - - -: Slower than ether
Percent Volatile by Weight - - - - - - -:
70.00
Percent Volatile by Volume - - - - - - -:
85.0
------------------------------------------------------------------------------------------
DATE: 07/07/2011
COMPANY NAME:
GIANI, Inc.
Section 10 - Stability and Reactivity
-----------------------------------------------------------------------------------------Stability: This material is stable
Materials to avoid: Unknown.
Hazardous Polymerization: Will not occur.
Decomposition Products: By high heat and fire: CO2, CO
-----------------------------------------------------------------------------------------Section 11 - Toxicological Information
-----------------------------------------------------------------------------------------Not established
:
CAS#
oral
:
LD50 : > mg/kg (rat)
dermal
:
LD50 : > mg/kg (rabbit)
-----------------------------------------------------------------------------------------Section 12 - Ecological Information
-----------------------------------------------------------------------------------------Not established
:
CAS#
Toxicity to other organisms:
Fish toxicity
:
LC50,
:
96 h: 44,000 mg/l
Daphnia toxicity
:
EC50: (48 h) >
mg/l
Algae toxicity
:
EC50: (72 h) >
mg/l
Persistance and degradability :
Mobility
:
Not soluble in water
Bioaccumulation
:
Not expected because of physiochemical properties of
substance.
-----------------------------------------------------------------------------------------Section 13 - Disposal Considerations
-----------------------------------------------------------------------------------------WASTE DISPOSAL METHOD: Dispose of contaminated absorbent, container and unused contents in
accordance with local, state and federal regulations. Do not incinerate closed containers.
-----------------------------------------------------------------------------------------Section 14 - Transport Information
-----------------------------------------------------------------------------------------DOT – NOT REGULATED
Canadian TDGA – NOT REGULATED
-----------------------------------------------------------------------------------------Section 15 - Regulatory Information
-----------------------------------------------------------------------------------------FEDERAL REGULATIONS:
SARA SECTION 302-304. The superfund amendments and reauthorization act of 1986 (SARA) title
III requires facilities subject to subparts 303 and 304 to submit emergency planning and
notification information based on threshold planning quantities (TPQs) and reportable
quantities (RQs) for "Extremely Hazardous Substances" listed in 40 CFR 302.4 and 40 CFR 355.
SARA (311,312) HAZARD CLASS. The superfund amendments and reauthorization act of 1986 (SARA)
title III requires facilities subject to subpart to submit aggregate information on chemicals
by "Hazard Category" as defined in 40 CFR 370.2
Immediate (Acute) Yes Health Hazard see Section 11
Delayed (Chronic) Health Hazard No
Fire Hazard No
Reactive Hazard No Sudden Release of Pressure Hazard No
SARA (313) CHEMICALS. Components in concentrations above the de minimus levels that are listed
as toxic chemicals in 40 CFR Part 372 pursuant to the requirements in section 313 of SARA.
Superfund Amendments and Reauthorization Act of 1986 Title III
(Emergency Planning and Community Right-to-Know Act of 1986) Section 313
To the best of our knowledge, this product does not contain chemicals at levels which require
reporting under this statute.
Pennsylvania (Worker and Community Right-To-Know Act): Pennsylvania HazardousSubstances List
and/or Pennsylvania Environmental Hazardous Substance List:
The following product components are cited in the Pennsylvania Hazardous Substance List and/or
the Pennsylvania Environmental Substance List, and are present at levels which require
reporting.
Component CAS # Amount
To the best of our knowledge, this product does not contain chemicals at levels which require
reporting
under this statute.
Comprehensive Environmental Response, Compensation, and Liability Act of 1980 (CERCLA)
Section 103
To the best of our knowledge, this product does not contain chemicals at levels which require
reporting under this statute.
US. EPA Emergency Planning and Community Right-To-Know Act (EPCRA) SARA Title III
Section 302 Extremely Hazardous Substance (40 CFR 355, Appendix A)
To the best of our knowledge, this product does not contain chemicals at levels which require
reporting under this statute.
California Proposition 65 (Safe Drinking Water and Toxic Enforcement Act of 1986)
This product contains no listed substances known to the State of California to cause cancer,
birth defects or other reproductive harm, at levels which would require a warning under the
statute.
PRODUCT CODE: CHOCOLATE BROWN KIT
Page 10
US. Toxic Substances Control Act
All components of this product are on the TSCA Inventory or are exempt from TSCA Inventory
requirements under 40 CFR 720.30
CEPA - Domestic Substances List (DSL)
All substances contained in this product are listed on the Canadian Domestic Substances List
(DSL) or are not required to be listed.
Section 16 - Other Information
-----------------------------------------------------------------------------------------NOTE: Read MSDS completely before use and follow all label instructions.
The information contained in this MSDS is based on the present state of knowledge and is based
on sources believed to be reliable.
However, since the data safety standards and government regulations are subject to change and
the conditions of handling and use or misuse are beyond our control, Giani, Inc. makes no
warranty, either express or implied, with respect to the information contained
Date: 07/07/2011