SSRG International Journal of Civil Engineering (SSRG-IJCE) – volume 3 Issue 5 – May 2016 A Review on Cement Replacement in Construction Industry Savita Devi1, Nitish Gandhi 2, Mahipal 3, Nimisha Marmat 4, Balveer Manda5 , Mahesh Vaishnav 6 1 2,3,4,5,6 Asst. prof. , Poornima Institute of Engineering and Technology, Jaipur Students of civil engg., Poornima Institute of Engineering and Technology, Jaipur Abstract— This review paper emphasis on various suitable replacements of cement so as to reduce problems of global warming and to create sustainable environment. Cement manufacturing industry is one of major source of CO2 emission resulting in global warning. About 7 to 8% of greenhouse gas emission is only due to cement production. Solution of this global problem can be a boon for environment and ecosystem. In order to reduce these effects on environment, there is need for substitution of other waste material having same major constituents.The production of cement requires high energy input and one tonne of cement production is generating 0.55 tonnes of chemical CO2 as well as an additional 0.39 tonnes of CO2 in fuel emissions, hence a total of 0.94 tonnes of CO2. Concrete industry is one of the largest consumers of natural virgin materials Therefore, the replacement of cement in concrete by various wastes may create tremendous saving of energy and also leads to important environmental benefits. The study on various factors such as strength, durability, reuse and problem solution has been compared with previous investigations and approaches to most suitable replacement for cement concerning all parameters. Keywords—cement,concrete,environment ,durability Introduction Attempts to reduce the use of Portland cement in concrete are receiving much attention due to environment-related.As the industries waste is piling up every day, there is a pressure on industries to find a solution for its disposal. The advancement of concrete technology can reduce the consumption of natural resources. They have forced to focus on recovery, reuse of natural resources and find other alternatives. The various replacement such as ceramic waste, blast furnace slag, silica fume, fly ash, geopolymer, paper sludge. Waste from manufacturing industries is broadly classified into two types: industrial byproducts and recycled wastes. Industrial byproducts are ash, sludges and slags while later one includes different plastic and rubber waste. Hypo sludge About 300 kg of sludge is going to be produced for one tone of recycled paper. Paper sludge shows similar properties as cement because of silica and magnesium properties which improve the setting of the concrete. Paper fibers can be recycled only a limited number of times so as to make high quality papers. ISSN: 2348 – 8352 CERAMIC WASTE Ceramic waste powder is settled by sedimentation and it is dumped away which leads to environmental pollution, in addition to forming dust in summer and threatening both agriculture and public health. Indian ceramic production is 100 Million ton per year. In the ceramic industry, about 15%30% waste material generated from the total production. This waste is not recycled in any form at present. This ceramic waste is durable, hard and show resistant properties towards biological, chemical, and physical degradation forces. PAPER SLUDGE Paper pulp produced in mill was investigated to work in concrete as an alternative for land disposal. Paper pulp was replaced in concrete by cement in the ratio of 5%, 10%, 15%, and 20% by weight in M20 and M30 grade mix concrete. Compression test, split tensile strength test and flexure test were carried on the concrete after replacement by paper pulp. Tests were carried out on concrete till 28 days. As a result an increment of flexure and split tensile strength was observed till 10% replacement of paper pulp sludge, further increase in percentage of paper pulp sludge observed a decline in the values of flexure and split tensile strength. Paper fibers can be recycled up to a finite limit, till they became of low strength which produces paper of degraded quality. Every ton of recycled paper produces 300kg of sludge which becomes almost uneconomical to dispose by landfilling. Dry paper pulp sludge contains magnesium oxide, alumina, calcium oxide and silica. Concrete when prepared with replacement of paper pulp at 10%,20% show small decrease in compressive strength. Most suitable proposition of mix is in between 5% and 10%. As paper pulp is bulky so it consumes water when mixed in concrete which ultimately results in increase of water absorption of concrete. Use of paper pulp can become economical by decreasing in costs of disposal by landfilling. Waste paper sludge ash About 7% of the total greenhouse gas emission is caused by cement industry. For reducing the above mentioned greenhouse gas emission it is required to develop alternatives www.internationaljournalssrg.org Page 68 SSRG International Journal of Civil Engineering (SSRG-IJCE) – volume 3 Issue 5 – May 2016 to concrete industry for sustainable concrete production. Partial replacement of paper pulp sludge ash of cement in concrete can become an alternative. In the study sludge ash was added in percentages of 5,10,15,20 in concrete in place of cement for M20 mix. Tests were done to check the compressive strength, water absorption, dry density and tensile split strength up to 28 days of age. An increase of 10% compressive strength at 7 days and 15% increases in compressive strength at 28 days was observed when cement was replaced 5% by weight in concrete by paper ash sludge. So up to 5% replacement by weight of cement in concrete is recommended for better results. Waste glass powder Like PFA and GGBS a binder known as GLP i.e. waste glass powder can also be used as a partial replacement of cement in concrete which will take part in hydration reaction. For testing the effect in compressive strength replacement of cement is done at 10%, 20% and 30%. For testing the effect of glass powder, glass powder is divided into two grades: 1) 2) Size of powder less than 90 micron. Size of powder in between 90-150 micron. Glass consists of many chemical varieties such as ternary soda lime silicates, binary alkali silicates glass, and boro silicate glass. Stability of cementitious material and increase in strength of microstructure is observed after partial replacement with glass powder. In the research a total of four types of specimens were prepared: 1) Cement replacement with fine powder particle size less than 90 micron with replacement of 10%-30%. 2) Cement replacement with fine powder particle size in between 90 micron to 150 micron with replacement of 10%30%. 3) Normal cement concrete. 4) Normal cement concrete with 90% to 70% of cement that of design. optimum GGBFS replacement as cementation material is characterized by high compressive strength, low heat of hydration, resistance to chemical attack, better workability, good durability and cost-effectiveness. Blast furnace slag is a by-product of iron manufacturing industry. Iron ore, coke and limestone are fed into the furnace, and the resulting molten slag floats above the molten iron at a temperature of about 1500oC to 1600oC. The molten slag has a composition of 30% to 40% silicon dioxide (SiO2) and approximately 40% CaO, which is close to the chemical composition of Portland cement The production of GGBS requires little additional energy compared with the energy required for the production of Portland cement. The replacement of Portland cement with GGBS will lead to a significant reduction of carbon dioxide gas emission. GGBS is therefore an environmentally friendly construction material. It can be used to replace as much as 80% of the Portland cement when used in concrete. It has been reported that the manufacture of one tonne of Portland cement would require approximately 1.5 tonnes of mineral extractions together with 5000 MJ of energy, and would generate 0.95 tonne of CO2 equivalent . As GGBS is a by-product of iron manufacturing industry, it is reported that the production of one tonne of GGBS would generate only about 0.07 tonne of CO2 equivalent and consume only about 1300 MJ of energy. It is observed that GGBS-based concretes have achieved an increase in strength for 20% replacement of cement at the age of 28 days. Increasing strength is due to filler effect of GGBS. 2. The degree of workability of concrete was normal with the addition of GGBS up to 40% replacement level for M35 grade concrete. 3. From the above experimental results, it is proved that GGBS can be used as an alternative material for cement, reducing cement consumption and reducing the cost of construction. Use of industrial waste products saves the environment and conserves natural resources. All the specimens were prepared for M30 mix design. Specimens of size 150*150*150 were casted and compressive strength was tested for 7 days and 28 days. On addition of glass powder sludge initial strength is not very high but when tested for 28 days it meets the desired design strength. Ground Granulated Blast Furnace Slag Cement with GGBS replacement has emerged as a major alternative to conventional concrete and has rapidly drawn the concrete industry attention due to its cement savings, energy savings, cost savings, environmental and socio-economic benefits. This research evaluates the strength and strength efficiency factors of hardened concrete.From this study, it can be concluded that, since the grain size of GGBS is less than that of ordinary Portland cement, its strength at early ages is low, but it continues to gain strength over a long period. The ISSN: 2348 – 8352 www.internationaljournalssrg.org Page 69 SSRG International Journal of Civil Engineering (SSRG-IJCE) – volume 3 Issue 5 – May 2016 Sr. No Author,country & year Amitkumar D. Raval1, Dr.Indrajit N. Patel2, Prof. Jayeshkumar Pitroda3 Ref. No Mix proportion replacement Advantages Problem solution 1 w/c ratio-.52 replacement10%,20%,30%, 40%, 50% Ceramic waste powder To reduce the problem of pollution produced by ceramic waste Reduce the consumption of natural resources 2 Mr.R.Balamurugan1, Mr.R.Karthickraja2 2 Hypo sludge 3 Professor and HoD, Department of Civil Engineering, Educational and Research Institute, Dr.M.G.R. University, Chennai C Freeda Christy And D Tensing 3 Replacement50%,60%,70%, 80%,90%,100% Replacement20%,30%,40% To resolve the dumping problem of hypo sludge High strength of concrete is achieved. A low cost concrete can be formed. Better workability and good durability of concrete is achieved. 4 Cement mortar: 1:3,1:4.5,1:6 Glass fly ash Increase of masonry bond strength Solve problem of of disposal of fly ash. 5 Sumit A Balwaik; S P Raut 5 Replacement5%,10%,15%,20% M20 w/c =.50 M30 w/c =.45 Waste paper pulp Alternative to landfill disposal. 6 DHANARAJ MOHAN PATIL1, DR. KESHAV K. SANGLE2 6 Replacement10%,20%,30% M30 Waste glass powder Compressive strength, split tensile strength, flexure strength increase by 10% Overall performance of 20% replacement is better than 10% and 30% 7 Sajad Ahmad, M. Iqbal Malik, Muzaffar Bashir Wani, Rafiq Ahmad 7 Replacement5%,10%,15%,20% Waste paper sludge ash Replacement up to 5% by weight can be used for positive outcomes Sustainable concrete industry 8 Chandana Sukesh1, Bala Krishna Katakam1, P Saha2+ and K. Shyam Chamberlin2 8 Replacement10%,20%,30%, 40% Industrial waste Solution to the problem of land disposal. 9 Ivan Razl, Ph.D., P.Eng 9 M30 Flexible polymer 5% plastic partial replacement with cement achieves doubles the strength when compared to normal concrete Increases toughness, tensile and bending strength. 10 Prof. P.A. Shirulea*, Ataur Rahmanb , Rakesh D. Guptac 10 Replacement5%,10%,15%,20% Marble dust powder Compressive strength increases up to 10% replacement Sustainable developement 11 Prof. Jayeshkumar Pitroda1, Dr. L.B.Zala2, Dr.F.S.Umrigar3 11 Replacement10%,20%,30% ,40% Fly ash Fly ash use saves the disposal costs of coal industry Cost saving and saving of natural resources 12 Noor Faisal Abas 12 Replacement5%,10%,15% Waste paper sludge Best results came with 20% replacement after 40 days A step towards Green environment 13 G. Moriconi 13 Replacement25% to 30% Recyclable material Compressive strength can be improved to equal or even exceed the natural concrete. Do not show any deleterious effects. 1 4 ISSN: 2348 – 8352 GGBS www.internationaljournalssrg.org Environment friendly, energy sustainability and cost saving Water proofing and protection of concrete structures Page 70 SSRG International Journal of Civil Engineering (SSRG-IJCE) – volume 3 Issue 5 – May 2016 RESEARCH NEEDS: Research and current researches shows the following: 1. Further efforts are required to understand the properties of concrete primarily high strength comprising of silica fumes and fly ash. 2. Research work should be done on durability and workability of glass fly ash concrete. 3. Study should be done on adding of GGBS as partial replacement of concrete over 40% to know about strength characteristics. 4. Research should be done on compressive strength of flexible polymer concrete. SUMMARY AND CONCLUSION: In the paper, a study of many types of replacement materials has been done by comparing their 7, 14 and 28 day compressive strength, flexure strength and split ensile strength. Materials such as fly ash and silica fumes are used in the concrete industry from almost an decade as partial replacement of cement in concrete. Silica fume and fly ash potentials was well understood and they were utilized in huge quantities materials such as paper pulp, paper pulp sludge are produced in such huge quantities that it becomes almost impossible to dispose them economically , so to solve this problem we neeed to use paper pulp inn concrete industry. Waste such as glass powder and ceramic waste show good strength results when compared to natural concrete. GGBS i.e. Glass Granulated Blast Furnace Slag also produces significant results when added as partial replacement of cement in concrete. By comparison of compressive strength, flexure strength and split tensile strength we can conclude that GGBS ha s a lot of potencial as an supplement to cement and can give high strength, durability and workability when added in desired proportions to concrete. [10] Prof. P.A. Shirulea*, Ataur Rahmanb , Rakesh D. Guptac,” Partial Replacement of Cement with Marble Dust Powder”, International Journal of Advanced Engineering Research and Studies EISSN2249–8974 [11] Prof. Jayeshkumar Pitroda1, Dr. L.B.Zala2, Dr.F.S.Umrigar3,” Experimental Investigations On Partial Replacement Of Cement With Fly Ash In Design Mix Concrete”, Pitroda et al., International Journal of Advanced Engineering Technology,E-ISSN 0976-3945 [12] Noor Faisal Abas,” Waste Paper Sludge as a Cement Replacement Material in Green Concrete: Engineering Properties “, Australian Journal of Basic and Applied Sciences, 9(7) April 2015, Pages: 294-298 [13] G. Moriconi,” Recyclable materials in concrete technology: sustainability and durability”, [14]Bahoria B.V.*1, Parbat D.K.2 and Naganaik P.B.3,” Replacement of Natural Sand in Concrete by Waste Products: A State Of Art”, Journal of Environmental Research and Development Vol. 7 No. 4A, April-June 2013 [15]Mallikarjun Ganjigatti1, Kashinath B. R.2, K. B. Prakash3,” Effect of Replacement of Cement by Different Pozzolanic Materials on Heat of Hydration and Setting Time of Concrete,” International Journal of Environmental & Agriculture Research (IJOEAR) [Vol-1, Issue-4, August- 2015] [16]Chandana Sukesh1, Bala Krishna Katakam1, P Saha2+ and K. Shyam Chamberlin2,” A Study of Sustainable Industrial Waste Materials as Partial Replacement of Cement,” 2012 IACSIT Coimbatore Conferences IPCSIT vol. 28 (2012) © (2012) IACSIT Press, Singapore References [1]Amitkumar D. Raval1, Dr.Indrajit N. Patel2, Prof. Jayeshkumar Pitroda3,” Ceramic Waste : Effective Replacement Of Cement For Establishing Sustainable Concrete”, International Journal of Engineering Trends and Technology (IJETT) - Volume4 Issue6- June 2013 [2] Mr.R.Balamurugan1, Mr.R.Karthickraja2,” An Experimental Investigation of Partial Replacement of Cement by Industrial Waste (Hypo Sludge),” Mr. R. Balamurugan et al Int. Journal of Engineering Research and Applications www.ijera.com ISSN: 2248-9622, Vol. 4, Issue 4(Version 1), April 2014, pp.430-435 [3] 1) Professor and HoD, Department of Civil Engineering, Educational and Research Institute, Dr.M.G.R. University, Chennai, Tamil Nadu, India,” Sustainable Studies on Concrete with GGBS As a Replacement Material in Cement,” Jordan Journal of Civil Engineering, Volume 8, No. 3, 2014 [4] Jordan Journal of Civil Engineering, Volume 8, No. 3, 2014, [5] Sumit A Balwaik; S P Raut,” Utilization of Waste Paper Pulp by Partial Replacement of Cement in Concrete,” Sumit A Balwaik, S P Raut/ International Journal of Engineering Research and Applications Vol. 1, Issue 2, pp.300-309 [6] Dhanaraj Mohan Patil1, Dr. Keshav K. Sangle2,” Experimental Investigation of Waste Glass Powder as Partial Replacement of Cement in Concrete [7] Sajad Ahmad, M. Iqbal Malik, Muzaffar Bashir Wani, Rafiq Ahmad,” Study of Concrete Involving Use of Waste Paper Sludge Ash as Partial Replacement of Cement ,” IOSR Journal of Engineering (IOSRJEN) e-ISSN: 2250-3021, p-ISSN: 2278-8719 Vol. 3, Issue 11 (November. 2013), ||V3|| PP 06-15 [8] Chandana Sukesh1, Bala Krishna Katakam1, P Saha2+ and K. Shyam Chamberlin2,” A Study of Sustainable Industrial Waste Materials as Partial Replacement of Cement,” 2012 IACSIT Coimbatore Conferences IPCSIT vol. 28 (2012) © (2012) IACSIT Press, Singapore [9] Ivan Razl, Ph.D., P.Eng.” Flexible Polymer-Cement Repair Materials and Their Applications ISSN: 2348 – 8352 www.internationaljournalssrg.org Page 71