hv photonics Review Progress in Rapidly-Tunable External Cavity Quantum Cascade Lasers with a Frequency-Shifted Feedback Arkadiy Lyakh 1,2,3, *, Rodolfo Barron-Jimenez 1 , Ilya Dunayevskiy 1 , Rowel Go 1,2,3 , Eugene Tsvid 1 and C. Kumar N. Patel 1, * 1 2 3 * Pranalytica, Inc., 1101 Colorado Ave., Santa Monica, CA 90401, USA; rbarron@pranalytica.com (R.B.-J.); idunay@pranalytica.com (I.D.); rowel.go@knights.ucf.edu (R.G.); etsvid@pranalytica.com (E.T.) NanoScience Technology Center, University of Central Florida, 12424 Research Pkwy, Orlando, FL 32826, USA College of Optics and Photonics, University of Central Florida, Scorpius St 304, Orlando, FL 32826, USA Correspondence: arkadiy.lyakh@ucf.edu (A.L.); patel@pranalytica.com (C.K.N.P.); Tel.: +1-407-823-0699 (A.L.); +1-310-458-4493 (C.K.N.P.) Received: 21 March 2016; Accepted: 13 April 2016; Published: 18 April 2016 Abstract: The recent demonstration of external cavity quantum cascade lasers with optical feedback, controlled by an acousto-optic modulator, paves the way to ruggedized infrared laser systems with the capability of tuning the emission wavelength on a microsecond scale. Such systems are of great importance for various critical applications requiring ultra-rapid wavelength tuning, including combustion and explosion diagnostics and standoff detection. In this paper, recent research results on these devices are summarized and the advantages of the new configuration are analyzed in the context of practical applications. Keywords: quantum cascade laser; tunable laser; spectroscopy; combustion and explosion diagnostics; standoff detection 1. Introduction The development of quantum cascade laser (QCL) configurations with a broad spectral coverage, and compatible with ultra-fast spectroscopic measurements, is an area of active research, primarily driven by QCL applications in infrared standoff detection and combustion/explosion diagnostics. One of the most promising developments in the field has been the demonstration of QCL-based frequency combs [1] and ultra-fast dual-comb QCL sensors [2]. The dual-comb QCL approach promises lab-on-a-chip sensors with a short measurement time. These sensors can potentially be integrated in various compact infrared platforms. The biggest drawback of this approach is a relatively small spectral coverage, on the order of tens of wavenumbers. This coverage may be insufficient to uniquely identify compounds with broad absorption spectra. The widest wavelength tunability, covering a substantial fraction of the QCL gain bandwidth, has been demonstrated for lasers in the external cavity configuration with a mechanical grating controlling a wavelength-dependent feedback [3]. This configuration has been in wide use with all types of gain media including solids, liquids and gases for over forty years. Such lasers are easy to construct and utilize using proven optical components. Such systems, however, suffer from two important disadvantages arising from the need to physically rotate a macroscopic spectral dispersive component—the diffraction grating. These disadvantages are (1) slow wavelength tuning and (2) sensitivity to mechanical vibrations and shocks. The highest tuning rate reported for traditional external cavity (EC) QCLs with a mechanical grating is 5 kHz, achieved by tilting a small intracavity mirror [4]. However, the tuning range is limited. Using a micro opto-electro-mechanical systems Photonics 2016, 3, 19; doi:10.3390/photonics3020019 www.mdpi.com/journal/photonics Photonics 2016, 3, 19 Photonics 2016, 3, 19 2 of 12 2 of 12 mirror [4]. However, the tuning range is limited. Using a micro opto-electro-mechanical systems (MOEMS)scanning scanninggrating, grating,Grahmann Grahmannetetal.al.achieved achieveda scanning a scanning rate 1 kHz The improvement (MOEMS) rate ofof 1 kHz [5].[5]. The improvement in in tuning speed demonstrated for devices, these devices, while impressive, is still insufficient for many tuning speed demonstrated for these while impressive, is still insufficient for many important important applications, laboratory applications, including combustion/explosion a full spectral laboratory including combustion/explosion diagnosticsdiagnostics where a fullwhere spectral scan needs scan to be performed onof the order of tens of microseconds (see, for example, Inpractical practical to be needs performed on the order tens of microseconds (see, for example, ReferenceRef.6). [6]). In situations,for forapplications applications involving optical detection of improvised explosive devicesdemand (IEDs) situations, involving optical detection of improvised explosive devices (IEDs) demand sub-millisecond spectral scan of a remote object. Sensitivity to vibrations and shocks, sub-millisecond spectral scan of a remote object. Sensitivity to vibrations and shocks, especially during especially the tunable laser operation precludes the theQCLs traditional EC QCLs the tunableduring laser operation precludes the consideration of consideration the traditionalofEC in applications in applications where the tunable laser is deployed on moving platforms, such as a vehicle travelling where the tunable laser is deployed on moving platforms, such as a vehicle travelling on unpaved on unpaved typical ofenvironment a battlefieldwhere environment where thecan tunable lasers can be to significant roads, typicalroads, of a battlefield the tunable lasers be significant help soldiers help to soldiers in from protecting them from the dangers of IEDs. Deployment on aircraft including in protecting them the dangers of IEDs. Deployment on aircraft including helicopters and helicopters and unmanned aerial vehicles (UAVs) also requires ruggedness derived from immunity unmanned aerial vehicles (UAVs) also requires ruggedness derived from immunity to vibrations to vibrations and shocks. and shocks. Both of of the the above above needs needs require require aa novel novel tuning tuning mechanism, mechanism, which which does does not not rely rely on on physical physical Both rotation of a macroscopic optical element. An ideal tunable laser system would be one which is rotation of a macroscopic optical element. An ideal tunable laser system would be one which is electronically tuned tuned with with no no moving moving parts. parts. Moreover, Moreover, to to fully fully exploit exploit the the QCL QCL gain gain bandwidth, bandwidth, the the electronically new approach to a rapid QCL wavelength control should be compatible with the EC configuration. new approach to a rapid QCL wavelength control should be compatible with the EC configuration. Use Use of electronic key tuning to fastand tuning and of absence ofparts moving parts can assure of electronic tuningtuning could could be the be keythe to fast absence moving can assure immunity immunity to and vibrations to vibrations shocks.and shocks. 2. Experimental 2. ExperimentalSection Section We have have recently recently demonstrated demonstrated aa significantly significantly increased increased scanning scanning rate rate using using an an all-electronic all-electronic We grating as as aa wavelength wavelength selective element. The configuration grating configuration explored explored in in [7,8] is shown in Figure 1. As with the ofof a single Fabry-Perot (FP)(FP) QCL chipchip withwith an ARAs the EC EC approach, approach,emission emissionwavelength wavelength a single Fabry-Perot QCL an coated back facet is controlled using a dispersive AR-coated back facet is controlled using a dispersiveoptical opticalelement elementlocated locatedoutside outsidethe the laser laser chip. However, in traditional ECEC QCLs withwith a moving grating, the rapid tuning However, in contrast contrasttotothe the traditional QCLs a moving grating, the wavelength rapid wavelength in the demonstrated externalexternal cavity configuration is achieved using anusing electrically controlled acoustotuning in the demonstrated cavity configuration is achieved an electrically controlled optic modulator (AOM). In the AOM, anAOM, acoustic at awave radioatfrequency is generated by applying acousto-optic modulator (AOM). In the an wave acoustic a radio frequency is generated by the RF electronic signal to a piezoelectric transducer attached to anto optical crystal, which is applying the RF electronic signal to a piezoelectric transducer attached an optical crystal, which transparent atatthe is transparent thewavelength wavelengthatatwhich whichthe thelaser laserneeds needstotooperate operateand andalso alsohas has low low acoustic acoustic losses. The acoustic acoustic wave wave (alternate (alternate compressions compressions and rarefactions rarefactions in the crystal) represents a phase grating, The from which which the the optical optical beam beam traversing traversing the the AOM AOM crystal crystal can canbe bediffracted diffracted(see (seeFigure Figure1). 1). from Figure 1. 1. Schematic Schematic of of travelling travelling wave wave acousto-optic acousto-optic modulator modulator tuned tuned quantum quantum cascade cascade laser. laser. Figure The angle of diffraction, θB, is given by: The angle of diffraction, θ B , is given by: πππ0 mnλ0 sinβ‘π = π΅ sin θ B “ ΛΛ (1) (1) where m is the order of diffraction, n is the optical refractive index of the AOM material, λ0 is the where m is the order of diffraction, n is the optical refractive index of the AOM material, λ0 is the optical wavelength and Λ is the acoustic wavelength. For an optical wavelength, λ0 = 10 μm, refractive optical wavelength and Λ is the acoustic wavelength. For an optical wavelength, λ0 = 10 µm, refractive Photonics 2016, 3, 19 3 of 12 index of ~4.0 for the germanium AOM crystal, and an acoustic wavelength of ~135 µm (assume an acoustic driving frequency of 35 MHz), we get a diffraction angle of θ B = ~7.5Λ . Typical diffraction efficiency of 85% is possible for an acoustic power level of ~30 W into a germanium AOM crystal, which is comparable to the diffraction efficiency of a mechanical diffraction grating. AOMs have been successfully used for rapid and random access discreet tuning of CO2 lasers on their 9.6 µm and 10.6 µm laser bands [9] and continuous tuning of Ti-sapphire lasers [10]. Reference [10] also provides earlier data on tuning of dye lasers using acousto-optic modulators. For practical applications, the demonstrated approach has several key advantages, over either the QCL arrays or the traditional EC QCLs with a mechanical grating. ‚ ‚ ‚ ‚ ‚ Tuning speed. Typical modulation bandwidth for commercially available AO modulators is in the range of tens of MHz. Hence, the required switching time, between arbitrary wavelengths, of under 1 µs can be achieved. This switching time is approximately three orders of magnitude faster than that for EC QCLs with a moving grating. The scanning rate is also much faster than characteristic mechanical vibrational frequencies of the system. As a consequence, the mirror vibration does not influence single sweep measurement results. Ruggedness. In contrast to the EC QCLs with a moving grating, the wavelength tuning mechanism does not require any mechanical motion. The module can therefore be ruggedized to meet the most stringent requirements for field applications. Yield (cost). The module comprises a single QCL chip. The standard single-QCL fabrication process has a relatively high yield, exceeding 50% for watt-level long-wave infrared devices (LWIR) devices. In the case of QCL DFB arrays, an alternative approach to fast wavelength tuning with a broad spectral coverage, however, the yield quickly drops with an increase in number of elements. For comparison, even a 10-element array processed from the same material would have a yield of less than 10%. As a consequence, DFB QCL arrays with a broad spectral coverage are projected to have low yield, making this technical approach impractical for some applications. Reliability and manufacturability. All the components in the proposed module have been commercially used for an extended period of time and have proven their long-term reliability. The high power FP QCLs have been in commercial production for nearly a decade and theAOMs for LWIR region have been commercially deployed for several decades. Thus, the two critical components in the proposed configuration, namely FP QCLs and AOMs, represent mature technologies compatible with a large throughput production. Practical Implications: Since dispersion is provided by the acoustic grating, the same mechanical construction can be used for QCLs with different center wavelengths (and different tuning ranges) unlike the mechanical diffraction grating where a different grating is needed for a different wavelength range. 3. Results 3.1. Response Time The response time of the change in the optical wavelength with a change in the AOM frequency is the main advantage of the new configuration. The response time has two components: (1) propagation time of the acoustic wave from the piezoelectric transducer to the edge of the optical beam going through the AOM (this propagation distance is designated here as L); and (2) the propagation time for the acoustic wave across the optical beam (diameter of the beam is designated as Db ). The first “delay” is the latency time and does not represent the response time of the change of the optical wavelength when AOM frequency is changed. The latency time can be shortened, almost arbitrarily, by reducing the distance between the acoustic transducer and the position of the optical beam. The actual response time, therefore, is determined by the acoustic wave transit time across the optical beam. For the Photonics 2016, 3, 19 4 of 12 present case, the time it takes an acoustic wave to propagate from the piezoelectric transducer across the germanium material to the edge of the optical beam is t1 and time for the acoustic wave to cross the optical beam is t2 . The time t2 is the actual response time of the AOM for changing the optical wavelength. As mentioned above, t1 can be shortened to almost zero. However, there are limitations on how short t2 can be. If t2 is made too short by making the optical beam diameter small, the optical wave will interact with a fewer number of acoustic waves and therefore the linewidth of the output will increase. The linewidth of the optical output can be reduced by making the optical beam diameter larger, but that occurs at the expense of the response time. The optimal linewidth/response time Photonics 2016, 3, 19 4 of 12 balance is application driven. the acoustic wave to cross the optical beam is t2. The time t2 is the actual response time of the AOM Figure 2forshows measured response time of the system as AOM frequency switches from 35 MHz for changing the optical wavelength. As mentioned above, t1 can be shortened to almost zero. (outside of the tuning curve) to 45 on MHz ofbe.the curve). The blue However, there are limitations how (center short t2 can If t2tuning is made too short by making thecurve optical in Figure 2 beam diameter small, the optical waveand will the interact a fewer number acoustic signal waves and shows the AOM frequency control signal redwith curve shows theofoptical from the laser therefore the linewidth of the output will increase. The linewidth of the optical output can be reduced measured with a room temperature mercury-cadmium-telluride (MCT) detector, which consists of by making the optical beam diameter larger, but that occurs at the expense of the response time. The pulses of duration ns and repetition period of 200 ns. AOM frequency is initially equal to 35 MHz, optimal 100 linewidth/response time balance is application driven. Figure 2curve shows measured response timeoptical of the system as AOM switches 35 MHz outside of the tuning of the laser. The signal levelfrequency from the laserfrom is at zero level since (outside of the tuning curve) to 45 MHz (center of the tuning curve). The blue curve in Figure 2 shows the Bragg condition is not satisfied anywhere in the laser gain spectrum. AOM frequency is abruptly the AOM frequency control signal and the red curve shows the optical signal from the laser measured changed to 45 MHz at time t = 0. AOM frequency of 45 MHz the peak of the with a room temperature mercury-cadmium-telluride (MCT) corresponds detector, which to consists of pulses of gain curve. duration 100 ns repetition period of 200 ns. AOM frequency is initially equal to 35 MHz, outside It takes approximately t1and = L/v = 1.25 µs for the acoustic signal with the new frequency to reach the s of the tuning curve of the laser. The optical signal level from the laser is at zero level since the Bragg area where the optical beam is incident on the crystal (vs is sound velocity). When the sound signal condition is not satisfied anywhere in the laser gain spectrum. AOM frequency is abruptly changed with the newto frequency reaches that area, the signal starts growing. Itcurve. reaches its maximum 45 MHz at time t = 0. AOM frequency of 45 optical MHz corresponds to the peak of the gain It takes value at t2 = approximately 550 ns + t1 , tin a good agreement with thewith calculated travelling time the beam area 1 = L/v s = 1.25 μs for the acoustic signal the new frequency to reach theacross area where beam ismm/µs) incident on~the crystal (vs is sound velocity). When frequency the sound signal with the back new to 35 MHz t2 = DB /vs =the 3.4optical mm/(5.5 600 ns (Figure 2a). The AOM switches frequency reaches that area, the optical signal starts growing. It reaches its maximum value at t2 = 550 at t = 3 µs. The process is repeated: It takes about t1 + t2 =1.8 µs for the laser to completely shut down ns + t1, in a good agreement with the calculated travelling time across the beam area t2 = DB/vs = 3.4 (Figure 2b). mm/(5.5 mm/μs) ~ 600 ns (Figure 2a). The AOM frequency switches back to 35 MHz at t = 3 μs. The process is repeated: It takes about t1 + t2 =1.8 μs for the laser to completely shut down (Figure 2b). Figure 2. Switching time data for the AOM-controlled EC QCL setup. (a) AOM frequency switches Figure 2. Switching time datathe for the AOM-controlled EC QCLtosetup. (a)ofAOM frequency switches from 35 MHz outside tuning curve to 45 MHz corresponding the center the tuning curve. from 35 MHz the the tuning curvewith to a451.8MHz corresponding thewave center of the tuning curve. Theoutside laser follows AOM signal μs delay, resulting from a to sound propagation to the edge of the lasersignal beam (1.25 μs) a and the laserresulting beam (550 ns); (b) a when AOMwave signal propagation switches The laser follows the AOM with 1.8across µs delay, from sound to the back to 35 MHz the process is repeated and it takes 1.8 μs for the laser to shut down. edge of the laser beam (1.25 µs) and across the laser beam (550 ns); (b) when AOM signal switches back to 35 MHz the process is repeated and it takes 1.8 µs for the laser to shut down. Photonics 2016, 3, 19 5 of 12 As mentioned above, the latency time t1 is proportional to L and can be almost arbitrarily minimized by designing the AOM so that the piezoelectric transducer generating the sound wave is positioned closer to the beam area. Time t2 , which is the actual wavelength switching time, on the other hand, is determined by the AOM material and beam size. It is, however, already well below 1 µs. Thus, if we change the AOM frequency between two values, say f1 and f2 , the laser wavelength will switch between two corresponding values in a time less than 1 µs, the latency time notwithstanding. 3.2. Continuous Wave Operation Two variations of the AOM approach are possible. The first one is when the acoustic wave reflects from the side opposite to the sound wave transducer, which creates a standing sound wave in the crystal. The standing acoustic waves occur at discrete acoustic frequencies defined by crystal dimensions and sound wave speed. Therefore, corresponding laser wavelengths are also discrete. A more interesting approach, explored in References [7,8], is when a sound wave absorber is positioned opposite end of the AOM crystal from the transducer. This is the travelling sound wave case. Since the standing wave resonance does not need to be satisfied, continuous wavelength tuning is available for this configuration. A corollary property of the travelling wave approach is a frequency-shifted feedback. As the laser beam propagates through the crystal, it experiences the Doppler shift equal to the sound wave frequency. The frequency shift is doubled when the beam reflected by the high reflectivity back mirror propagates through the crystal again before coupling back into the laser waveguide. The frequency shift prevents constructive interference and formation of axial optical modes in the laser (corresponding to the round trip time for the overall laser cavity) when zero-reflectivity anti-reflection coating is used on the laser facet facing the AOM. As a consequence, emission spectrum for the AOM controlled lasers in the travelling wave configuration is expected to be different from that for traditional Fabry-Perot and external cavity devices. Emission spectrum of lasers, including AOM-controlled QCLs, is seeded by spontaneous emission events in the gain medium. Therefore, phase consideration between these random events is not important. Each of the spontaneous emission events results into the formation of a broad spectral line as the beam propagates back and forth in the cavity. The resultant (integrated) spectrum is defined by the gain/loss spectrum, the AOM frequency response, and the frequency shift. It was shown in Reference [11] that the integrated emission spectrum for an AOM-controlled laser, seeded by a broad spontaneous emission, has a nearly Gaussian shape with an estimated spectral full width at half maximum δϑ given by ´ ¯1{3 δϑ « β¨ Γ2f (2) where β is the roundtrip frequency shift and Γ f is the spectral width of the AOM frequency response. The expression in Equation (2) was derived assuming that material gain/loss spectral width was much larger than Γ f . As a consequence, Equation (2) is independent of gain spectrum width. In addition, it was also assumed in Equation (2) that Γ f was much larger than both β and free spectral range of the external cavity setup. These assumptions are generally applicable to AOM-controlled QCLs. For the external cavity setup described in the present work, β = 2 ˆ 45 MHz = 90 MHz and Γ f « 25 cm´1 . Both parameters are calculated assuming that the beam propagated twice through the modulator during the roundtrip. For these values of β and Γ f , calculated value for δϑ is approximately 1.3 cm´1 . Figure 3 shows that measured continuous-wave (CW) linewidth for a 3 mm ˆ 10 µm AOM-controlled QCL epi-down mounted on an AlN submount at a high power level (output power ~100 mW; driving conditions 1.17 A, 9.3 V, 300 K; AOM frequency 45 MHz) was approximately equal to 1.7 cm´1 , in a good agreement with the model results. The spectra were measured using a Bruker FTIR spectrometer with approximately 30 s scanning time. The inset for Figure 3 also shows that linewidth narrowed to ~1 cm´1 in the vicinity of laser threshold as the spectral region where laser gain equals mirror losses becomes comparable to or less than the spectral width of the AOM response. Linewidth Photonics 2016, 3, 19 Photonics 2016, 3, 19 6 of 12 6 of 12 did not change appreciably with power level when the laser operated significantly above threshold. did not change Photonics 2016, 3, 19 appreciably with power level when the laser operated significantly above threshold. 6 of 12 The emission spectrum is slightly asymmetric, asaspredicted [12],and and modulated at free The emission spectrum is slightly asymmetric, predicted in in Reference Reference [12], modulated at free didspectral not change appreciably level when the laser operated significantlycoated above threshold. range of the laser chip due a residual reflectivity of the the anti-reflection facet. For aFor a spectral range of the laser chipwith duepower to atoresidual reflectivity of anti-reflection coated facet. Thezero emission spectrum is slightly asymmetric, asline predicted in Reference [12], and modulated at free reflectivity coating, a broad single emission line expected. zero reflectivity coating, a broad single emission isisexpected. spectral range of the laser chip due to a residual reflectivity of the anti-reflection coated facet. For a zero reflectivity coating, a broad single emission line is expected. Figure 3. Emission line of the CW AOM-controlled QCL. Inset shows linewidth variation with change Figure 3. Emission line of the CW AOM-controlled QCL. Inset shows linewidth variation with change in optical power. in optical power. Figure 3. Emission line of the CW AOM-controlled QCL. Inset shows linewidth variation with change The relatively large linewidth could be a limitation for the usefulness of AOM-controlled EC in optical power. with alarge frequency shifted feedback for some applications. This linewidth is, however, EC TheQCLs relatively linewidth could be a limitation for the usefulness of AOM-controlled sufficiently narrow for numerous other applications, including improvised explosive device (IED) QCLs with a frequency shifted feedback for be some applications. This linewidth is, however, sufficiently The relatively large linewidth could a limitation for the usefulness of AOM-controlled EC detection and combustion/explosion diagnostics, where absorption features are typically in the range narrow for numerous other applications, including improvised explosive (IED) QCLs with a frequency shifted feedback for some applications. This device linewidth is, detection however, and of tens of wavenumbers. If necessary, the linewidth can be significantly reduced employing the sufficiently narrow for numerous other applications, including improvised explosive combustion/explosion diagnostics, where absorption featurestime. are typically in the device range (IED) of tens of standing wave configuration, without sacrificing the response detection and combustion/explosion diagnostics, where absorption features are typically instanding the rangewave wavenumbers. If necessary, the linewidth can be significantly reduced employing the The CW tuning curve for the laser at a 100-mW power level is shown in Figure 4. The data were of tens of without wavenumbers. If necessary, the linewidth can be significantly reduced employing the configuration, sacrificing the response collected under the same conditions as the time. data in Figure 3. The laser tuning range under these standing wave configuration, without sacrificing the1070 response time. parameters covered spectral from cm−1level to 1135 cm−1 when AOM frequency waswere Thedriving CW tuning curve for thea laser at range a 100-mW power is shown in Figure 4. The data The CW tuning curve for the laser at a 100-mW power level is shown in Figure 4. The data were 43.5 MHz to 46.5 as MHz. collectedchanged under from the same conditions the data in Figure 3. The laser tuning range under these driving collected under the same conditions as the data in Figure 3. ´ The laser tuning range under these 1 parameters a spectral fromrange 1070 from cm´11070 to 1135 AOMAOM frequency was was changed drivingcovered parameters coveredrange a spectral cm−1 cm to 1135when cm−1 when frequency from changed 43.5 MHz to 46.5 MHz. from 43.5 MHz to 46.5 MHz. Figure 4. Tuning curve of the CW AOM-controlled laser under the same laser driving conditions as the ones listed in Figure 3. Figure 4. Tuning curve of the CW AOM-controlled laser under the same laser driving conditions as Figure 4. Tuning curve of the CW AOM-controlled laser under the same laser driving conditions as the the ones listed in Figure 3. ones listed in Figure 3. Figure 5 compares transmission spectra for refrigerant R134a (CAS no. 811-97-2) collected with a slow (1 ms) and fast (16 μs) sweep time. It is evident from the figure that the measured spectrum gets smoother as sweep time reduces. The effect can be explained noting that the effective linewidth is expected to increase for short sweep times. The increase in the linewidth required to match the Photonics 2016, 3, 19 7 of 12 simulated and experimental results is due to the chirp in the sound wave frequency across the area on the crystal illuminated by the beam. The chirp is caused by the continuous frequency sweep from oneFigure edge of the tuningtransmission curve to thespectra other one a short period time. This leads to a spatial 5 compares for within refrigerant R134a (CASofno. 811-97-2) collected with in and the fast phase grating period created by from the sound wave. frequency spectrum spread is a variation slow (1 ms) (16 µs) sweep time. It is evident the figure thatThe the measured approximately product of scanning rate effect and time for sound to cross the illuminated gets smoother asasweep time reduces. The can required be explained notingwave that the effective linewidth In terms of the parameters controlled in the broadening πΏπthe can isarea. expected to increase for short sweep times. Theexperiment, increase in the theadditional linewidth line required to match be estimated simulated and as: experimental results is due to the chirp in the sound wave frequency across the area on the crystal illuminated by the beam. The chirp is caused byπ‘ the continuous frequency sweep from one π‘π πΏπ ≈ aβ‘π₯π (3) edge of the tuning curve to the other one within short ππ β‘period of time. This leads to a spatial variation ππ π€πππ in the phase grating period created by the sound wave. The frequency spread is approximately a −1), T product andrange time required for sound wave tosweep cross thetime illuminated In terms of where of π₯πscanning tuning for the laser (~70 cm is the taken toarea. sweep emission ππ is the rate the parameters controlled in tuning the experiment, thettradditional linewave broadening δϑ can be estimated frequency across the entire range, and is the sound transit time across the beam.as: Comparison between the experimental and simulation data (Figure 5) shows that Equation (3) ttr well describes the additional line broadening reduction in sweep time: the additional (3) line δϑ « βϑwith TR Tsweep −1 broadening for 16 μs sweep time compared to the 1-ms case is estimated to be 2.5 cm , in a good agreement with 2.1 cm−1 deduced from Figure 5. Therefore, the effective line broadening effect can be where βϑTR is the tuning range for the laser (~70 cm´1 ), Tsweep is the time taken to sweep emission taken into account using Equation (3) when ultra-short scanning rates are used. frequency across the entire tuning range, and ttr is the sound wave transit time across the beam. Figure Figure5.5.Comparison Comparisonbetween betweenR134a R134aabsorption absorptionspectra spectrameasured measuredfor forfast fast(16 (16µs; μs;top) top)slow slow(1(1ms; ms; bottom) sweep times. bottom) sweep times. 3.3. Comparison Quasi-Continuous Wave between theOperation experimental and simulation data (Figure 5) shows that Equation (3) well describes lineactive broadening reductionrise in sweep thethe additional line broadening Duethe to additional a significant regionwith temperature (up totime: 100 K), tuning range of CW EC ´1 , in a good agreement for 16 µs sweep time compared to the 1-ms case is estimated to be 2.5 cm QCLs is limited. It can be significantly extended by operating the QCL in a quasi-cw (QCW), as ´1 deduced from Figure 5. Therefore, the effective line broadening effect can be taken into with 2.1 cmto opposed CW, mode of operation with a MHz-scale repetition rate and a duty cycle in the range of account using Equation (3) when allows ultra-short scanning rates are used. 20%–60%. The QCW operation the laser active region to cool down during the “off-cycles”, which in turn leads to a reduced average active region temperature and a higher laser performance 3.3. Quasi-Continuous Wave Operation [13]. The change of the QCL operation from the CW regime to the QCW regime is expected to lead to Due to in a significant (up to 100 K), the tuning range ofpower CW ECcycling. QCLs a change linewidthactive due region to the temperature wavelengthrise (thermal) chirp during electrical isWavelength limited. It can be significantly extended operating the QCL in a quasi-cw (QCW), as opposed to tuning and linewidth for theby QCW operation are separately discussed below. CW, mode of operation with a MHz-scale repetition rate and a duty cycle in the range of 20%–60%. The QCW operation allows the laser active region to cool down during the “off-cycles”, which in turn leads to a reduced average active region temperature and a higher laser performance [13]. The change of the QCL operation from the CW regime to the QCW regime is expected to lead to a change in Photonics 2016, 3, 19 8 of 12 linewidth due to the wavelength (thermal) chirp during electrical power cycling. Wavelength tuning and linewidth for the QCW operation are separately discussed below. Photonics 2016, 3, 19 8 of 12 Figure 6 shows a measured tuning curve for the same laser in QCW mode (350 ns pulses and 50% duty cycle) as AOM frequency was changed from MHz to 48.5 MHz (approximately 1/3 of the Figure 6 shows a measured tuning curve for 41.7 the same laser in QCW mode (350 ns pulses and duty cycle) as AOM frequency was changed from 41.7 MHz to 48.5 MHz (approximately 1/3 available50% frequency range). AOM input power was fixed at 35 W, which corresponded to approximately Photonics 2016, 3, 19 8 ofof 12 the available frequency range). AOM input power was fixed at 35 W, which corresponded to 90% diffraction efficiency and estimated 70% effective coupling efficiency of the external cavity. The approximately 90% diffraction efficiency and for estimated 70% effective coupling efficiency of and the ´ 1 (9.8 ´1pulses Figure 6 shows a measured tuning curve the same laser in µm) QCW mode emission wavelength for the EC laser tuned from 1020 cm to 1170(350 cmns (8.5 µm), twice −1 external cavity. emission wavelength for the EC laser tuned from 1020MHz cm−1 (approximately (9.8 μm) to 11701/3 cmof 50% duty cycle)The as AOM frequency was changed from 41.7 MHz to 48.5 that of CW operation for the same laser. These results clearly demonstrate that a much wider tuning (8.5 twicefrequency that of CWrange). operation for the same laser. was Thesefixed results that a much the μm), available AOM input power at clearly 35 W, demonstrate which corresponded to range can be achieved in can QCW mode without sacrificing average optical power. wider tuning range be achieved in QCWand mode without sacrificing average optical power. of the approximately 90% diffraction efficiency estimated 70% effective coupling efficiency external cavity. The emission wavelength for the EC laser tuned from 1020 cm−1 (9.8 μm) to 1170 cm−1 (8.5 μm), twice that of CW operation for the same laser. These results clearly demonstrate that a much wider tuning range can be achieved in QCW mode without sacrificing average optical power. Figure 6. Tuning curve of the QCW AOM-controlled laser. Figure 6. Tuning curve of the QCW AOM-controlled laser. Measured QCL emission spectrum linewidth for AOM central frequency of 45 MHz was 4.7 cm−1. The increase linewidth compared to curve that for CW mode of operation is attributed the thermal Measured QCLinemission spectrum linewidth forQCW AOM central frequency of 45toMHz was 4.7 cm´1 . Figure 6. Tuning of the AOM-controlled laser. wavelength chirp. The linewidth can be changed by aligning the system so that it operates at athermal The increase in linewidth compared to that for CW mode of operation is attributed to the different AOMQCL central frequency (different Bragg condition). a higher Measured emission spectrum linewidth for AOM central Employment frequency of 45ofMHz was 4.7AOM cm−1. wavelength chirp. The linewidth can be changed by aligning the system so that it operates at a different frequency willinresult into acompared larger number of for illuminated acoustic gratingisperiods and,totherefore, to The increase linewidth to that CW mode of operation attributed the thermal AOM central frequency (different Bragg condition). Employment of a higher AOM will awavelength proportionately linewidth. effect we for frequency different chirp.narrower The linewidth canTo bedemonstrate changed bythis aligning themeasured system solinewidth that it operates at a result into a larger number of illuminated acoustic grating periods and, therefore, to a proportionately AOM central frequencies. The increase in the central frequency from 35 MHz MHz led to different AOM central frequency (different BraggAOM condition). Employment of toa 55 higher AOM afrequency linear reduction emission linewidth cm−1measured to 3.9acoustic cm−1, as shown in Figures 7 and 8. During narrower linewidth. Toindemonstrate thisfrom effect we linewidth for different AOMto central will result into a larger number of5.7 illuminated grating periods and, therefore, these measurements, the position of the high frequency reflectivity mirror adjusted to keep the lasing a proportionately narrower linewidth. To demonstrate this effect wewas measured linewidth for different frequencies. The increase in the central AOM from 35 MHz to 55 MHz led to a linear wavelength unchanged. ´ 1 ´ 1 AOM central frequencies. The increase in the central AOM frequency from 35 MHz to 55 MHz led reduction in emission linewidth from 5.7 cm to 3.9 cm , as shown in Figures 7 and 8.toDuring a linear reduction in emission linewidth from 5.7 cm−1 to 3.9 cm−1, as shown in Figures 7 and 8. During these measurements, the position of the high reflectivity mirror was adjusted to keep the lasing these measurements, the position of the high reflectivity mirror was adjusted to keep the lasing wavelength unchanged. wavelength unchanged. Figure 7. Spectral measurements at three AOM drive frequencies, keeping laser wavelength constant by adjusting the back reflecting mirror tilt. Figure 7. Spectral measurements at three AOM drive frequencies, keeping laser wavelength constant Figure 7.bySpectral at mirror three AOM drive frequencies, keeping laser wavelength constant adjustingmeasurements the back reflecting tilt. by adjusting the back reflecting mirror tilt. Photonics 2016, 3, 19 Photonics 2016, 3, 19 Photonics 2016, 3, 19 -1 -1 Linewidth, [cm Linewidth, [cm] ] 9 of 12 9 of 12 9 of 12 5.5 5.5 5.0 5.0 4.5 4.5 4.0 4.0 35 35 40 45 50 40 45 50 AOM frequency, [MHz] AOM frequency, [MHz] 55 55 Figure 8. 8. Linewidth Linewidth dependence dependence on on AOM AOM frequency. frequency. Figure Figure 8. Linewidth dependence on AOM frequency. 3.4. Preliminary Stand-Off Detection Studies 3.4. Preliminary Preliminary Stand-Off Stand-Off Detection Detection Studies Studies 3.4. One of the potential applications for the AOM tuned QCLs is stand-off detection. We have One of forfor thethe AOM tuned QCLs is stand-off detection. We have One of the thepotential potentialapplications applications AOM tuned QCLs is stand-off detection. Wecarried have carried out preliminary studies of short-range stand-off detection utilizing the experimental out preliminary studies of short-range stand-off detection utilizing the experimental geometry shown carried out preliminary studies of short-range stand-off detection utilizing the experimental geometry shown in Figure 9. The target was placed at a distance of 50 cm from the laser source. The in Figure 9. The target was 9. placed at a distance of 50atcm from theoflaser source. laser source. output was geometry shown in Figure The target was placed a distance 50 cm from The the laser The laser output was attenuated using an appropriate neutral density filter to assure that the detector was attenuated using an appropriate neutral density filter to assure that the detector was not saturated. laser output was attenuated using an appropriate neutral density filter to assure that the detector was not saturated. A 1 cm diameter, 50 mm focal length lens, located 12 cm from the target was used to A 1 saturated. cm diameter, mm focal length lens, located 12lens, cm from the 12 target was used to collect laser not A 150cm diameter, 50 mm focal length located cm from the target wasthe used to collect the laser light scattered from the target and focus light on a cooled MCT detector. The total light scattered target and focus light on a cooled MCTon detector. The totaldetector. distanceThe fromtotal the collect the laserfrom lightthe scattered from the target and focus light a cooled MCT distance from the target to the detector was 25 cm. target to from the detector wasto25 cm. distance the target the detector was 25 cm. Figure 9. Schematic of an AOM-controlled QCL setup for short-range standoff detection. Figure 9. 9. Schematic Schematic of of an an AOM-controlled AOM-controlled QCL setup for short-range standoff detection. Figure Figure 10 shows the data collected for a dextrose tablet (top graph), dissolved in water dextrose Figure 10 shows the collected for tablet (top dissolved in water Figure 10an shows the data data collected for aa dextrose dextrose tablet (top graph), graph), dissolved indeposited water dextrose dextrose deposited on aluminum substrate (middle graph), and dissolved in water aspirin on an deposited on an aluminum substrate (middle graph), and dissolved in water aspirin deposited on deposited on an aluminum substrate (middle graph), and dissolved in water aspirin deposited on an an aluminum substrate (bottom graph). For the latter two samples, after they were dissolved in water, aluminum substrate (bottom graph). For the latter two samples, after they were dissolved in water, aluminum (bottom graph). the latter twoComposition samples, afterof they dissolved in water, they weresubstrate subsequently dried out For before testing. thewere tested substances wasthey not they were subsequently dried outtesting. before Composition testing. Composition of substances the tested was substances was not were subsequently dried out before of the tested not controlled in controlled in this prove-of-concept experiment. The measured spectra for the dextrose tablet and controlled in this prove-of-concept experiment. The measured spectra for the dextrose tablet and this prove-of-concept experiment. measured substrate spectra forare thedifferent dextrose because tablet and dextrose dissolved dextrose deposited on The an aluminum of dissolved binders and other dissolved dextrose deposited on an aluminum substrate are binders differentand because of binders impurities and other deposited an aluminum different because unknown unknown on impurities in the substrate tablet. Theare scan time for each ofofthe traces wasother approximately 700 μs. The unknown impurities in time the tablet. Theof scan time forwas each of the traces was approximately 700 μs.data, The in the tablet. The scan for each thefilter, traces 700 µs. The preliminary preliminary data, obtained using an ND2 clearly approximately demonstrate the “single shot” data gathering preliminary data, obtained using an ND2 filter, clearly demonstrate the shot” data gathering obtained ND2 filter, clearly demonstrate the “single data“single gathering made capabilityusing madeanpossible using the AOM tuned QCL system.shot” The data also show capability that even at this capability made possible using the AOM tuned QCL system. The data also show that of even atearly this possible using the AOM tuned QCL system. The data also show that even at this stage very stage of very early demonstration of the capability of AOM-controlled QCLs (VeloXscan), it is very stage of very early demonstration the capability of AOM-controlled QCLs (VeloXscan), it is very demonstration of the capability of of AOM-controlled QCLs (VeloXscan), it is very easy to distinguish easy to distinguish between various compounds in Figure 10. easy to distinguish between various compounds in Figure 10. between various compounds in Figure 10. Photonics 2016, 3, 19 Photonics 2016, 3, 19 10 of 12 10 of 12 Figure10.10. Measured short-range stand-off detection signal for dextrose tablet (top),dissolved dextrose Figure Measured short-range stand-off detection signal for dextrose tablet (top), dextrose dissolved in water (middle), and aspirin dissolved in water (bottom). in water (middle), and aspirin dissolved in water (bottom). Using the present setup we estimate that data of comparable quality can be easily obtained for Using the present setup we estimate that data of comparable quality can be easily obtained for a a stand-off distance of 2 meters by simply removing the ND2 filter and using a 12′ diameter scattered stand-off distance of 2 meters by simply removing the ND2 filter and using a 2 diameter scattered light-collecting lens. light-collecting lens. 3.5. Future Directions for AOM Tuned QCLs 3.5. Future Directions for AOM Tuned QCLs For the configuration shown in Figure 1, a substantial fraction of the optical power is lost with For the configuration shown in Figure 1, a substantial fraction of the optical power is lost with the undiffracted beam (diffraction efficiency ~80%). The undiffracted beam can be used as the output the undiffracted beam (diffraction efficiency ~80%). The undiffracted beam can be used as the output beam, as shown in Figure 11. A very interesting aspect of the new configuration is that AOM RF beam, as shown in Figure 11. A very interesting aspect of the new configuration is that AOM RF power power can be used to balance the laser feedback and output power. For example, AOM RF power can be used to balance the laser feedback and output power. For example, AOM RF power can be can be (dynamically) tuned to reach the optimal efficiency for each emission wavelength under the (dynamically) tuned to reach the optimal efficiency for each emission wavelength under the tuning tuning curve. This is analogous to controlling front facet reflectivity for the traditional Fabry-Perot curve. This is analogous to controlling front facet reflectivity for the traditional Fabry-Perot chips. chips. However, instead of being fixed by coating layers thicknesses, in this case, the effective However, instead of being fixed by coating layers thicknesses, in this case, the effective reflectivity can reflectivity can be easily electronically adjusted on a microsecond scale. be easily electronically adjusted on a microsecond scale. In contrast to the mechanical grating configuration, a single AOM can control several lasers emitting at different wavelengths at the same time. As shown in Figure 12, two or more emitters with complementary spectral coverages can be combined in a single system without increasing system size and weight. Each of these emitters can be designed to have a broad gain and, therefore, broad tuning range capability [14,15]. Their output optical beams can be combined in a single beam using either the polarization beam combining approach or the dichroic beam combining approach. The multiple-emitter configuration is projected to result into a tunable laser source with an ultra-broad coverage (4–12 μm) and ultra-rapid wavelength tuning. Additionally, unlike mechanical grating tuned QCLs, the AOM-tuned QCLs can be made to operate at more than one wavelength at a time by driving the AOM crystal with a combination of frequencies. Each one of the RF drive frequency sets up an independent grating period, which forces the QCL to operate at different wavelengths simultaneously. As a consequence, several absorption features2016, can3,be19tracked at the same time. Again, the wavelengths can be changed, independently, Photonics 11 ofon 12 a microsecond time scale. Photonics 2016, 3, 19 11 of 12 Additionally, unlike mechanical grating tuned QCLs, the AOM-tuned QCLs can be made to operate at more than one wavelength at a time by driving the AOM crystal with a combination of frequencies. Each one of the RF drive frequency sets up an independent grating period, which forces the QCL to operate at different wavelengths simultaneously. As a consequence, several absorption features can be tracked at the same time. Again, the wavelengths can be changed, independently, on a microsecond time scale. Figure 11. 11. Configuration for extracting extracting higher higher power power output output form form the the AOM-tuned AOM-tuned QCL. QCL. Figure Configuration for In contrast to the mechanical grating configuration, a single AOM can control several lasers emitting at different wavelengths at the same time. As shown in Figure 12, two or more emitters with complementary spectral coverages can be combined in a single system without increasing system size and weight. Each of these emitters can be designed to have a broad gain and, therefore, broad tuning range capability [14,15]. Their output optical beams can be combined in a single beam using either the polarization beam combining approach or the dichroic beam combining approach. The multiple-emitter configuration is projected to result into a tunable laser source with an ultra-broad coverage (4–12 and ultra-rapid tuning. Figureµm) 11. Configuration for wavelength extracting higher power output form the AOM-tuned QCL. Figure 12. Dual-laser AOM-tuned QCL setup. The AOM that was used in References [7,8] required water-cooling. However, our experimental results showed that input RF power of only 20–25 W was sufficient for efficient module operation. That level of power dissipated in the crystal can be removed using thermo-electrical cooling (TEC)/air-cooling, a much more compact and power efficient approach. The air-cooled AOMcontrolled QCL can be packaged in a “shoebox-size” platform designed for handheld applications. 4. Conclusions Figure 12. Dual-laser AOM-tuned QCL setup. The control of an all electronically tuned external cavity QCL using an AOM opens up unique Figure 12. Dual-laser AOM-tuned QCL setup. opportunities in the infrared spectroscopy field. A compact (handheld), reliable, ruggedized Additionally, unlike mechanical grating tuned QCLs, the AOM-tuned QCLs and can be made to tunable system can be designed to cover the entire MWIR and LWIR spectral regions with an ultraTheat AOM was used in References water-cooling. However, experimental operate morethat than one wavelength at a [7,8] time required by driving the AOM crystal with our a combination of fast tuning time and a of very flexible (multi) wavelength control. All the blocks of the system results showed that input RF power of only 20–25 sufficient forbuilding efficientperiod, module operation. frequencies. Each one the RF drive frequency setsWupwas an independent grating which forces represent technologies with highAs yield, large thermo-electrical throughput production. That leveltomature of power inare thecompatible crystal can bea removed using cooling the QCL operate at dissipated differentthat wavelengths simultaneously. a consequence, several absorption (TEC)/air-cooling, a much and power efficient approach. Thecontract air-cooled AOMfeatures can be tracked atreported themore same time. Again, wavelengths can changed, independently, on a Acknowledgments: Work incompact this paper wasthe supported, in part, bybe Army STTR #W911SR-14C-0067 under the oversight of Alan Samuels (Edgewood Chemical Biological Center). controlled QCL can be packaged in a “shoebox-size” platform designed for handheld applications. microsecond time scale. The AOM that was used in References required water-cooling. our experimental Author Contributions: A. Lyakh and C. Kumar [7,8] N. Patel conceived and designedHowever, the experiments, A. Lyakh, R. 4. Conclusions results showed that input RF power of only 20–25 W was sufficient for efficient module Barron-Jimenez, I. Dunayevskiy, R. Go, and E. Tsvid performed the experiment and analyzed data. operation. ThatThe level of power dissipated in the crystal can be removed using an thermo-electrical of an electronically external cavity QCL using AOM opens up cooling unique Conflicts control of Interest: Theall authors declare notuned conflict of interest. (TEC)/air-cooling, a much more compact and power efficient approach. The air-cooled AOMopportunities in the infrared spectroscopy field. A compact (handheld), reliable, and ruggedized controlled QCL can be packaged in a “shoebox-size” platform designed for handheld applications. tunable system can be designed to cover the entire MWIR and LWIR spectral regions with an ultrafast tuning time and a very flexible (multi) wavelength control. All the building blocks of the system represent mature technologies that are compatible with a high yield, large throughput production. Acknowledgments: Work reported in this paper was supported, in part, by Army STTR contract #W911SR-14C-0067 under the oversight of Alan Samuels (Edgewood Chemical Biological Center). Author Contributions: A. Lyakh and C. Kumar N. Patel conceived and designed the experiments, A. Lyakh, R. Barron-Jimenez, I. Dunayevskiy, R. Go, and E. Tsvid performed the experiment and analyzed data. Conflicts of Interest: The authors declare no conflict of interest. Photonics 2016, 3, 19 12 of 12 4. Conclusions The control of an all electronically tuned external cavity QCL using an AOM opens up unique opportunities in the infrared spectroscopy field. A compact (handheld), reliable, and ruggedized tunable system can be designed to cover the entire MWIR and LWIR spectral regions with an ultra-fast tuning time and a very flexible (multi) wavelength control. All the building blocks of the system represent mature technologies that are compatible with a high yield, large throughput production. 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