SWAT Modeling of Water Quantity and Quality in the Tennessee River Basin: Spatiotemporal Calibration and Validation Supplement Gangsheng Wang1,2,*, Henriette I. Jager1,2, Latha M. Baskaran1, Tyler F. Baker3, Craig C. Brandt4 1 Environmental Sciences Division, Oak Ridge National Laboratory, Oak Ridge, TN 37831 USA 2 Climate Change Science Institute, Oak Ridge National Laboratory, Oak Ridge, TN 37831 USA 3 Tennessee Valley Authority, Knoxville, TN 37902 USA 4 Biosciences Division, Oak Ridge National Laboratory, Oak Ridge, TN 37831 USA *Corresponding Author: Gangsheng Wang Bldg 4500N, Room F129S, MS-6301 Oak Ridge National Laboratory Oak Ridge, TN 37831-6301 wangg@ornl.gov 1 Table S1. Types of SWAT Calibration Type ID 0 2 3 10 11 20 21 22 23 24 30 31 32 33 34 Response variables Daily streamflow Daily reservoir storage Daily soil water content Monthly streamflow Monthly runoff: subbasin or HUC8 Monthly Flux: nutrient • NO3+NO2 • NO3 • TN • TP • Sediment Monthly Flux: Sediment Monthly Flux: N • TN • NO3+NO2 • NO3 Monthly Flux: TP Monthly Flux: Sediment + TP Monthly Concentration: nutrient • NO3+NO2 • NO3 • TN • TP • Sediment Monthly Concentration: Sediment Monthly Concentration: N • TN • NO3+NO2 • NO3 Monthly Concentration: TP Monthly Concentration: Sediment + TP 2 Units m3/s 104 m3 mm m3/s mm Metric tons Notes Parameter 1–14 Parameter 1–14 Parameter 1–14 Parameter 1–14 Parameter 1–14 Parameter 15–39 • TP=OrgP+SolP • TN=NO3+NO2 +NH4+OrgN Metric tons Metric tons Parameter 15–21 Parameter 22–30 Metric tons Metric tons mg/L Parameter 15–21, 31–39 Parameter 15–21, 31–39 Parameter 15–39 mg/L mg/L Parameter 15–21 Parameter 22–30 mg/L mg/L Parameter 15–21, 31–39 Parameter 15–21, 31–39 Table S2. Model performance in calibration and validation of water quality Analyte Sediment Calibration (1997–2006) Validation (2007–2013) All (1997–2013) NSE PBIAS (%) r2 0.06 21 0.32 −0.50 18 0.06 −0.18 20 0.19 NSE PBIAS (%) r2 0.44 2 0.47 −2.54 −75 0.44 0.09 −25 0.27 NSE PBIAS (%) r2 0.38 −11 0.40 −0.32 −54 0.44 0.09 −28 0.35 NSE PBIAS (%) r2 −0.25 −80 0.27 −2.79 −157 0.27 −1.15 −109 0.22 Metrics a TP TN NO3+NO2 a NSE: Nash-Sutcliffe Efficiency; PBIAS: Percent Bias; r2: squared correlation coefficient. 3 Figures (a) (b) 4 (c) (d) 5 (e) Figure S1. Fractions of land-cover types in 55 subbasins of the Tennessee River Basin. (a) Forest, (b) Grassland/Pasture, (c) Hay, (d) Other Crops, and (e) Switchgrass. Data source: Cropland Data Layer (CDL) 2009. 6 Obs 400 Sim Monthly Runoff (mm) 350 Calibration: (1986–1995) Validation (1996–2013) 300 250 200 150 100 50 94 19 95 19 96 19 97 19 98 19 99 20 00 20 01 20 02 20 03 20 04 20 05 20 06 20 07 20 08 20 09 20 10 20 11 20 12 20 13 20 14 93 19 92 19 91 19 90 19 89 19 88 19 87 19 19 19 86 0 Year Figure S2. Comparison between SWAT-simulated (Sim) and USGS (Obs) monthly runoff in HUC8-06040006 7 Deviation (%) from average value at HUC6 20 MAP 15 MAR_USGS MAR_SWAT 10 5 0 06010108 06010204 -5 -10 -15 -20 HUC8 Figure S3. Percentage deviation between two HUC8s (06010108 and 06010204) and their respective HUC6 units (060101 and 060102) in mean annual precipitation (MAP) and USGS-estimated and SWAT-simulated mean annual runoff (MAR) 8 Sediment: Monthly Flux (103 kg TSS) (a) 200,000 Obs: 95% CI Sim Calibration (1997-2006 ) 150,000 Validation (2007-2013) 100,000 50,000 0 1997 1998 1999 2000 2001 2002 2003 2004 2005 2006 2007 2008 2009 2010 2011 2012 2013 2012 2013 2012 2013 Year TP: Monthly Flux (103 kg P) (b) 5,000 Obs: 95% CI Sim 4,000 Calibration (1997-2006 ) Validation (2007-2013) 3,000 2,000 1,000 0 1997 1998 1999 2000 2001 2002 2003 2004 2005 2006 2007 2008 2009 2010 2011 Year TN: Monthly Flux (103 kg N) (c) 25,000 Obs: 95% CI Sim 20,000 Calibration (1997-2006 ) Validation (2007-2013) 15,000 10,000 5,000 0 1997 1998 1999 2000 2001 2002 2003 2004 2005 2006 Year 9 2007 2008 2009 2010 2011 NO3+NO2 :Monthly Flux (103 kg N) 20,000 Obs: 95% CI Sim Calibration (1997-2006 ) Validation (2007-2013) 15,000 10,000 5,000 0 1997 1998 1999 2000 2001 2002 2003 2004 2005 2006 2007 2008 2009 2010 2011 2012 2013 Year Figure S4. Comparison between SWAT-simulated (Sim) and LOADEST-estimated (Obs) monthly nutrient flux through the outlet of the Tennessee River Basin. (a) Sediment, (b) TP, (c) TN, (d) NO3+NO2. 95% CI denotes the 95% confidence interval on LOADEST estimates (Obs). 10 (a) (b) 11 (c) (d) 12 (e) (f) Figure S5. Spatial distribution of SWAT-simulated mean annual loads at 55 subbasins: (a) runoff (mm), (b) runoff coefficient (RC), (c) sediment loading (kg TSS/ha), (d) TP loading (kg P/ha), (e) TN loading (kg N/ha), (f) NO3 (kg N/ha) 13