CHEM 1406 Revised 8/24/06 Study Guide #3, The Atom and Radioactivity www.delmar.edu/nsci/cgambill/sg0603.pdf Textbook (Timberlake, 9th ed) Chapter 3: pages 84 – 107 (skip s,p,d,f orbitals pgs 93 – 94) Know Table 3.8, pg 86 Know Key Terms, pgs 104 – 105 Know how to draw Lewis Dot Pictures for atoms, pgs 98 -99 Work problems 3.21 - 3.72, 3.81 – 3.98, 3.103, 3.104, 3.107, 3.108, 3.11 Chapter 9: pages 300 – 330 Know Table 9.2, pg 302; Table 9.4, pg 306 Know Key Terms, pgs 326 – 327; also PET, MRI, CAT, X-ray Know how to write and balance nuclear chemical equations Know equation – inverse square law Work problems: 9.1 – 9.76 Timberlake’s Chemistry Web Site: http://www.karentimberlake.com/ Laboratory Textbook: (www.delmar.edu/nsci/cgambill/labsch06061.pdf ) Experiment #4, Atomic Structure Experiment #5, Electron Configuration and Periodic Properties Experiment #6, Nuclear Radiation Turn in problems and exercises from lab textbook as directed in lab class (study graded/returned lab sets) The Chemistry Place: CD in textbook – Chapter 3 Guide, sections 3.4 – 3.8 Chapter 9 Guide, all sections Web site, www.aw-bc.com/chemplace (may require access code from textbook) Computer Problem Set, Radiation Chemistry, extra credit points; due at exam time Presentations, see also: http://mydmc.delamr.edu The Atom, see: http://www.delmar.edu/nsci/cgambill/atom.pdf Introduction to Radiochemistry, see: http://www.delmar.edu/nsci/cgambill/Radio.pdf MRI, CAT and PET, see: http://www.delmar.edu/nsci/cgambill/mricatpet.pdf Study Guide (optional) Chapter 3, sections 3.4 – 3.8; pages 36 – 47 Chapter 9, all sections; pages 139 - 150 CHEM 1406 Study Guide #3 page 2 For Discussion Figure: Periodic Trends From: http://cwx.prenhall.com/bookbind/pubbooks/hillchem3/medialib/media_portfolio/text_images/CH08/FG08_17.JPG CHEM 1406 Study Guide #3 page 3 Figure: Frequency, Wavelength and Energy for the Electromagnetic Spectrum. from: http://www.ndt-ed.org/EducationResources/CommunityCollege/Radiography/Physics/nature.htm Inverse square Law, http://www.ndt-ed.org/EducationResources/CommunityCollege/Radiography/Physics/inversesquare.htm http://www.physicalgeography.net/fundamentals/6f.html Inverse-Square-Law (Radiation intensity with distance) Since the initial beam travels in straight but divergent directions, geometry in a three dimensional world dictates that the radiation intensity will decrease with the inverse square of the distance. Consequently, the number of X-rays traveling through a unit area decreases with increasing distance. Likewise, radiation level decreases with increasing distance since exposure is directly proportional to the number of X-rays interacting in a unit area. The intensity of the radiation is described by the inverse square law equation: Where XA is the radiation exposure rate at distance DA compared with the exposure rate (XB) at some other distance (DB). From: http://www.e-radiography.net/index.htm CHEM 1406 Study Guide #3 page 4 Fig. 3: Inverse square law In general, the dose amounts to 1/x². Therefore, if you double the film-to-target distance, you will need four times as much radiation to achieve the same image blackening. If you did not change the patient's position, this would lead to radiation stress in the patient; thus, increasing the distance between X-ray tube and patient helps to reduce the dose. From: http://www.e-radiography.net/index.htm Web Resources, Radioactivity: 1. Theory, Radioactive Decay; see: http://www2.slac.stanford.edu/vvc/theory/nuclearstability.html 2. Types of Radioactive Decay; see http://library.thinkquest.org/3471/radiation_types_body.html 3. Half-life, A JAVA applet; see: http://www.colorado.edu/physics/2000/isotopes/radioactive_decay3.html 4. Other Modes of Radioactive Decay; see: http://www.epa.gov/radiation/understand/positron.htm CHEM 1406 Study Guide #3 page 5 5. Radiation Fact Sheets; see: http://www.hps.org/publicinformation/radfactsheets/index.html 6. Radioactivity; see: http://dbhs.wvusd.k12.ca.us/Radioactivity/Radioactivity.html 7. Nature of Penetrating Radiation; see: http://www.ndt-ed.org/EducationResources/CommunityCollege/Radiography/Physics/nature.htm Web Resources, Nuclear Medicine: 1. Nuclear Medicine and PET; see: http://www.palmcoastimaging.com/Services/s_nuclearmedicine.htm 2. Introduction to Radiologic Procedures and Therapies; see: http://www.radiologyinfo.org/ 3. Martindale's Health Science Guide, Radiology Center; see: http://wwwsci.lib.uci.edu/~martindale/MedicalRad.html 4. Radiation Therapy; see: http://www.ahealthyme.com/topic/topic100587381 5. How X-rays Work; see: http://science.howstuffworks.com/x-ray.htm 6. Computed Tomography; see: http://www.palmcoastimaging.com/Services/s_catscanning.htm 7. Computed Tomography Scans; see: http://www.ahealthyme.com/topic/topic100586642 8. Magnetic Resonance Imaging Scans; see: http://www.ahealthyme.com/topic/topic100587119 9. MRI; see: http://www.palmcoastimaging.com/Services/s_mrismras.htm 10. Mammography; see: http://www.ahealthyme.com/topic/topic100587125 11. Mammography; see: http://www.palmcoastimaging.com/Services/s_mammograms.htm 11. Positron Emission Tomography; see: http://www.ahealthyme.com/topic/topic100587327 12. Basic Principle of PET, an applet; see: http://www.austin.unimelb.edu.au/dept/nmpet/pet/detail/principle.html 13. Thallium Heart Scan; see: http://www.ahealthyme.com/topic/topic100587548 14. Radiation Safety Guidelines; see: http://extranet.urmc.rochester.edu/radiationSafety/mrt.pdf 15. Radiation Safety Manual, Nursing Procedures; http://www.xray.hmc.psu.edu/services/hphys/rsm/rsmtoc.html CHEM 1406 Study Guide #3 Page 6 16. Radiation Safety; see: http://www.safety.duke.edu/RadSafety/nurses/default.asp http://www.e-radiography.net/index.htm 17. Listing of some medically useful isotopes (old list, 1998), see: http://www.cbvcp.com/nmrc/mia.html 18. Medical Physics, see: http://science.uniserve.edu.au/school/curric/stage6/phys/medphys.html 19. The Search for the Heavy Elements, see: http://www.lbl.gov/abc/wallchart/chapters/08/0.html 20. Nuclear Medicine, see: http://en.wikipedia.org/wiki/Nuclear_medicine 21. Medical Imaging, see: http://en.wikipedia.org/wiki/Medical_imaging