Galilean relativity This file contains a summary of all classes covering Ch. 1-5 & lasers. I make these available in one file for your convenience but I strongly recommend to use the individual files for studying. The individual files contain all the concept tests with the answers at the end of each pdf file and some optimization for static viewing. Reference frames • Explore how things move with respect to things that are also moving • Where are you? Where are you going? Says who? Reference frames A reference frame is a set of coordinate axes that never move with respect to each other. y x Think about laying out a set of meter sticks in a pattern like this one, and never moving them again relative to each other. Q: Where do I put the origin, (0,0)? A: Anywhere you like! There is no “preferred place.” (0,0) I could choose it to be where I’m standing. And it goes on forever b/c you might want to measure things far away. Reference frames y Now I locate an object in my frame, at, say, (x,y) = (3m,2m). (3,2) x (0,0) Reference frames (3,2) The blue ball is at (3m,2m). The red ball is at (0m, -2m). In principle, somebody standing there yells out the coordinate. If I go myself to check, I’m moving in this reference frame! Distance from red ball to blue ball is (0,-2) 2 2 (3m) + (4m) = 25m = 5m Remark Reference frames In a different reference frame, the blue ball could be at (2m,0m) and the red ball is at (-1m,-4m). The balls are still 5m apart! (2,0) (2,0) We say this distance is an “invariant.” Where I stand doesn’t affect physical facts like distance. (-1,-4) Compare two reference frames (now in one-dimension only) The distance between two objects that are not moving in this reference frame is a constant. (-1,-4) Compare two reference frames (now in one-dimension only) Frame S has origin here. x ... -3 -2 -1 0 1 2 ... -3 -2 -1 x 3 ... ... -3 -2 -1 0 1 2 ... -3 -2 -1 3 ... x’ 0 1 2 3 ... Frame S’ has origin here, at x=3m according to reference frame S. (The frame S’ is drawn below S so you can read both axes.) Important conclusion Observer in S finds the ball at x = 2 m Observer in S’ finds the ball at x’ = -1 m Q: Who is right? a) b) c) d) Observer in S Observer in S’ Both are right Neither is right Two observers in different reference frames can give a different description of the same physical fact (in this case, the location of the ball.) And they’re both right! This is relativity! x’ 0 1 2 3 ... Observer in S measures ball at x = 2m. Observer in S’ measures ball at x’ = -1m. Reading Quiz (closed book, no discussions) An inertial reference frame is one: a) that is not moving b) that is not accelerating c) in which objects are a fixed distance apart d) in which observers are a fixed distance apart e) in which nothing is moving Inertial reference frames V Inertial reference frames TZD 1.3 Imagine a train car (it’s always a train!) moving on a straight track with constant velocity with respect to the ground. The train runs smoothly, so that you can’t tell it’s moving by feeling the bumps on the track. Would you expect the laws of Physics to be different inside this train compared to the labs here at CU? Inertial reference frames Inertial reference frames V Now, you’re playing pool on the train. The balls roll in straight lines on the table (assuming you put no English on them). In other words, the usual Newtonian law of inertia still holds. The frame as a whole is not accelerating. V As I’m lining up my shot, the train slows and approaches the station. I have not touched the cue ball. What does it do? This frame is no a) Rolls to the front of the train longer inertial! b) Rolls to the back of the train (Accelerated c) Remains motionless frame) (Is this still an inertial reference frame?) Comparing inertial frames To cut a long story short: An inertial reference frame is one that is not accelerating. x ... -3 -2 -1 0 1 2 ... -3 -2 -1 3 ... v x’ 0 1 2 3 ... Here are two inertial reference frames, moving with respect to one another. According to S, S’ is moving to the right, with v = 1 m/s. Comparing inertial frames v Important conclusion Observer in S measures velocity of S’ to be +1 m/s Observer in S’ measures velocity of S to be -1 m/s Q: Who is right? a) b) c) d) x ... -3 -2 -1 0 1 2 ... -3 -2 -1 3 ... x’ 0 1 2 3 ... Here are two inertial reference frames, moving with respect to one another. Observer in S Observer in S’ Both are right Neither is right Two observers in different reference frames can give a different description of the same physical fact (in this case, the relative velocity of the ‘other’ reference frame.) And they’re both right! The two frames are moving relative to each other. According to S’, S is moving to the left, with v = -1 m/s. Comparing inertial frames Which of these is an inertial reference frame (in good approximation)? A. My car without brakes rolling down a steep hill B. A rocket being launched C. A roller coaster going over the top of a hill D. A sky diver falling at terminal speed E. None of the above ... -3 -2 -1 0 1 2 3 ... ... -3 -2 -1 0 1 2 3 ... v At time t = 0, the two frames coincide. A ball is at rest in frame S. Its position is • x = 2 m in S • x’ = 2 m in S’ Comparing inertial frames ... -3 -2 -1 0 1 2 ... -3 -2 -1 v 3 ... 0 1 2 3 ... Frame S’ is moving to the right (relative to S) at v=1m/s. At time t = 3 sec, the position of the ball is • x = 2 m in S • x’ = -1 m in S’ Important conclusion • Where something is depends on when you check on it (and on the movement of your own reference frame). • Time and space are not independent quantities; they are related by rel. velocity. • Definition: An event is a measurement of where something is and when it is there. ( x, y , z , t ) Comparing inertial frames Galilean position transformation If S’ is moving with speed v in the positive x direction relative to S, then its coordinates in S’ are ... -3 -2 -1 0 1 2 ... -3 -2 -1 v 3 ... 0 1 2 x′ = x − vt y′ = y z′ = z t′ = t 3 ... At time 0, the ball was at x = x’. At time t later, the ball is still at x in S but where is it in S’ at the same time t? a) x’ = x b) x’ = x + vt Note: In Galilean relativity, time is measured the same in both reference frames; why wouldn’t it be? c) x’ = x-vt Galilean velocity transformation u Galilean velocity transformation x ... -3 -2 -1 0 1 2 ... -3 -2 -1 v 3 ... x’ 0 1 2 If an object has velocity u in frame S, and if frame S’ is moving with velocity v relative to frame S, then the position of object in S’ is: x ' (t ) = x (t ) − vt Velocity of the object is therefore: u' = u 3 ... dx (t ) dx′(t ) d = ( x (t ) − vt ) = −v =u−v dt dt dt ... -3 -2 -1 0 1 2 ... -3 -2 -1 v 3 ... 0 1 2 3 ... Same thing as before, but now the ball is moving in S, too, with velocity u = –1 m/s. Is the ball faster or slower, as measured in Frame S’? A – faster B – slower C – same speed Dynamics Important conclusion F Two observers in different reference frames can give a different description of the same physical fact (in this case, the velocity of the ball.) And they’re both right! F S ... -3 -2 -1 0 1 2 3 ... F v S’ ... -3 -2 -1 0 1 2 3 ... Dynamics Galilean relativity In inertial frame S, we have (in x-direction, say) F = ma How about in inertial frame S’? Well, F' = F since you’re still applying the same forces, and a' = du du ' d = (u − v ) = =a dt dt dt The laws of mechanics (good old F = ma) are the same in any inertial frame of reference. no additional acceleration in an inertial frame. Einstein’s First Postulate of Relativity But now we have a problem!! From PHYS 1120 you might recall that Mr. Maxwell told us the speed of light ‘c’ would be: c= If S is an inertial frame and if a second frame S’ moves with constant velocity relative to S, then S’ is also an inertial frame. 1 ε 0 µ0 = 3.00 × 108 m / s Now, Mr. Einstein tells us that ε0 and µ0 are the same in any inertial frame of reference. But Mr. Galileo just told us that c’ = c - v What gives?? Peculiar light-waves • A sound wave propagates through air, with a velocity relative to the air (~330 m / sec) • A water wave propagates through water, with a velocity relative to the water (1..100 m / sec) • “The wave” propagates through a crowd in a stadium, with a velocity relative to the audience. • An electromagnetic wave propagates through... Answer (19th century physics): The “luminiferous ether.” Ideas behind Einstein’s relativity Is there an ether ? (There where various other motivations for special relativity, but for simplicity we will focus here on the quest for detecting the ‘ether.’) Michelson and Morley… The ether v c Suppose the earth moves through the fixed ether with speed v. A light wave traveling at speed c with respect to the ether is heading in the opposite direction. According to Galilean relativity, what is the magnitude of the speed of the light wave as viewed from the earth? (Further assume the earth is not accelerating). a) |c| b) |c|+|v| c) |c|-|v| d) |v|-|c| e) something else …performed a famous*) experiment that effectively measured the speed of light in different directions with respect to the “ether wind.” *) some Frame of reference say, the most successful failure… Ether in the laboratory frame Observer on the sun: v ‘Ether’ v L u'-v v How can we measure the speed v of the ether? If the ether would be a river, we could measure the speed of the water using a boat that travels at a known speed u’. (u’ is the relative velocity between the boat and the water.) Ether ‘viewed’ in the laboratory on the earth: -v -v If the boat travels the distance L within the time t, then we know v: L=(u’-v)t, therefore v = u’ – L/t But: Very difficult with light! u’ = c t ~ 10ns and v ~ 0.0001*c. We would have to measure t with an absolute precision of ~0.0000000000001s and we have to know c very precisely! Measuring only differences in c -v B -v u’+v L A u’-v Michelson and Morley Mirrors L -v Detector -v L L Compare the round-trip times tA and tB for paths A and B. This has the great benefit, that we do not have to measure the absolute times tA and tB (which are only a few ns) and we are less sensitive to uncertainties in the speed of light. Semi-transparent mirror “Interferometer” Light source The detector measures differences in the position of the maxima or minima of the light-waves of each of the two beams. (Yes, light is a wave!) Intermezzo: Interferometers 1881 Michelson invented a device now known as the ‘Michelson Interferometer.’ 1907 he received the Nobel prize for it! The Michelson interferometer Mirrors Light source We will see it in action in the famous Michelson-Morley experiment, which will lead us to the special relativity theory. So the interferometer had a huge impact!! Such interferometers are nowadays widely used for various precision measurements. State-of-the-art visible-light interferometers achieve resolutions of ~100pm! (X-ray interferometers are ~1pm). Semi-transparent mirror (100pm = 1Å = diameter of a Hydrogen atom.) Detector Electromagnetic waves E-field (for a single color): E(x,t) = E0 sin(ωt+2πx/λ +φ) Light source E φ E λ Free physics simulations! http://phet.colorado.edu λ = 2πc/ω, ω = 2πf = 2π/T A0 x Wavelength λ of visible light is: λ ~ 350 nm … 750 nm. Radio Waves.jar Wave interference.jar x B EM-Waves in an interferometer Mirrors L Constructive interference Esum(x,t) = ½ ·E0 sin(ωt+2πx/λ +φ) + ½ ·E0 sin(ωt+2πx/λ +φ) = ? = Light source E0 sin(ωt+2πx/λ +φ) = Elight source(x,t) L + Semi-transparent mirror Screen: = ? Unequal arm lengths Destructive interference Esum(x,t) = ½ ·E0 sin(ωt+2πx/λ +φ) + ½ ·E0 sin(ωt+2π(x+∆x)/λ +φ) L = ½ ·E0 sin(ωt+2πx/λ +φ) - ½ ·E0 sin(ωt+2πx/λ +φ) = 0 Light source L+∆L/2 if ∆x = λ / 2: sin(x+π) = - sin(x) ∆L/ 2 + ∆L = ? Screen: Moving mirror: What do you see? Light source Tilted mirror: What do you see? Fringes! Light source ∆L Screen Intensity λ/ 2 Screen ∆L Application: Flatness measurement Michelson interferometer Ultrahigh power laser (>3.5kW average and 250MW peak power) Interference in daily life: Do you want a bigger ‘interferometer’? There you go… Gravitational wave detectors Do you remember this guy? Interference in ‘photonic crystals’ Summary The blue color originates from constructive interference of blue light and destructive interference of all other colors. Michelson interferometers allow us to measure tiny displacements. Displacements of less than 100 nm are made visible to the eye! Interferometers find many applications in precision metrology such as for displacement, distance and stress measurements as well as flatness measurements. Interferometers have played an important role in physics: Michelson-Morley experiment special relativity Testing general relativity: Gravitational wave detection Remember Michelson and Morley? Mirrors End of our little “interferometer intermezzo” L -v Detector -v L Semi-transparent mirror “Interferometer” Light source The detector measures differences in the position of the maxima or minima of the light-waves of each of the two beams. (Yes, light is a wave!) t2 = 2L ⋅ β c (Homework!) t1 = L L 2L + = ⋅ β , β = 1v 2 c −v c+v c 1− 2 c ∆t = t1 − t2 ≈ Last class: Michelson Morley 2 L v ⋅ , c c2 ∆L ≈ L ⋅ 2 v c2 Experimental results Over a period of about 50 years, the Michelson-Morley experiment was repeated with growing levels of sophistication. The overall result is a high level of confidence that the wavelength shift is consistent with zero. Michelson, 1881 Michelson & Morley 1887 Morley & Miller, 1902-04 Illingworth, 1927 Joos,1930 L (cm) 120 1100 3220 200 2100 Calc. 0.04 0.40 1.13 0.07 0.75 Meas. 0.02 0.01 0.015 0.0004 0.002 Shankland, et al., Rev. Mod. Phys. 27, 167 (1955) Ratio 2 40 80 175 375 Michelson and Morley They thought that the experiment was a complete failure because no effect was found. Yes, but... Q: What if the ether is “dragged along” the surface of the earth, like air flowing around a tennis ball? Michelson was awarded the Nobel Prize in 1907!! A: If so, this would require a “viscosity” of the ether, and would require rewriting Maxwell’s equations. True result: Speed of light is the same in all directions! Homework (part of your reading assignment): Work out the math for this experiment (TDZ, Chapter 1.5) There is no ether Remark: Lots of effort tried to save the idea of the ‘ether’, but none held up. Einstein’s Second Postulate of Relativity The speed of light is the same in all inertial frames of reference. Electromagnetic waves are special. A time-changing electric field induces a magnetic field, and vice-versa. A medium (“ether”) is not necessary. There is no ether! v c Suppose the earth moves through space with speed v. A light wave traveling at speed c with respect to faraway stars is heading in the opposite direction. According to Einstein’s relativity, what is the magnitude of the speed of the light wave as viewed from the earth? (Assume the earth is not accelerating). a) |c| b) |c|+|v| c) |c|-|v| d) |v|-|c| e) something else This was still new in 1905 when Einstein proposed it. Now it has been tested experimentally many times. Suppose you’re in a spaceship traveling through the solar system at at a constant speed of one-half impulse power, v = 1.5 X 108 m/s. You fire a pulse of laser light out the front of your vessel. (Speed of light = 3.0 X 108 m/s). Q: How fast do you see the pulse leave your ship? a)1.5 X 108 m/s b) 3.0 X 108 m/s c) 4.5 X 108 m/s d) none of these Suppose you’re in a spaceship traveling through the solar system at at a constant speed of one-half impulse power, v = 1.5 X 108 m/s. You fire a pulse of laser light out the front of your vessel. (Speed of light = 3.0 X 108 m/s). Q: How fast does an inertial observer on Mars see the pulse leave your ship? Conclusion The speed of light is the same in all inertial frames of reference. Einstein, 1905 a)1.5 X 108 m/s b) 3.0 X 108 m/s c) 4.5 X 108 m/s d) none of these Now it’s time to talk about time! • Measuring time in one frame • Synchronization of clocks • Measuring time in different frames Quiz on the reading Recall ‘event’ (x, y, z, t) Last Wednesday we have argued that to describe a physical event, we must specify both: where it is – say at (x, y, z) in some inertial coordinate system – and what time it occurs – say at time t according to some clock. But what clock? Time of an event (No discussions during this one) In a given reference frame, the time of an event is given by… a) The time the observer at the origin sees it. b) The time that any observer anywhere in the frame sees it. c) The time according to the clock nearest the event when it happens. d) The time according to a properly synchronized clock nearest the event when it happens. Lightning strikes the top of Bear Mountain, generating a clap of thunder. At what time did the lightning strike? A – At the instant you hear the thunder. B – At the instant you see the lightning. C – Very slightly before you see the lightning. D – Very slightly before you hear the thunder. E – Very slightly after you see the lightning. ‘Events’ in one reference frame ‘Events’ in one reference frame An observer at (0,0) has a clock; events there are covered. And there had better be clocks everywhere, so you don’t miss any event. An observer at (3m,2m) had better have a clock too, if we want to know about events there. And, the two clocks had better show the same time. Well, didn’t quite work… Synchronizing clocks ... -3 -2 -1 0 1 2 3 ... At the origin, at three o’clock, the clock sends out a light signal to tell everybody it’s three o’clock. ... -3 -2 -1 0 1 2 At the origin, at three o’clock, the clock sends out a light signal to tell everybody it’s three o’clock. 3 ... Time passes as the signal gets to the clock at x = 3m. Does this scheme work? When the signal arrives, the clock at x=3m is set to 3:00. Synchronizing clocks ... -3 -2 -1 0 1 2 3 ... At the origin, at three o’clock, the clock sends out a light signal to tell everybody it’s three o’clock. Time passes as the signal gets to the clock at x = 3m. When the signal arrives, the clock at x=3m is set to 3:00 plus the 10 ns delay. Time passes as the signal gets to the clock at x = 3m. If you do this, then the clock at x = 3m is 10 ns slow, because of the delay! When the signal arrives, the clock at x=3m is set to 3:00. Simultaneity in one frame ... -3 -2 -1 0 1 2 3 ... Using this procedure, it is now possible to say that all the clocks in a given inertial reference frame read the same time. Even if we don’t go out there to check it ourselves. Now I know when events really happen, even if I don’t find out until later (due to finite speed of light). Lucy 1 ... -4 -3 -2 -1 0 Ricky 2 1 2 3 1 Lucy 4 ... Two firecrackers sitting on the ground explode. This time, Lucy is sitting twice as far from firecracker 1 as from firecracker 2. She sees the explosions at the same time. Which firecracker exploded first in Lucy’s reference frame? Two firecrackers explode. Lucy, halfway between the firecrackers, sees them explode at the same time. Ricky (same reference frame as Lucy) is next to firecracker 2. According to Ricky, which firecracker explodes first? A. Both explode at the same time B. Firecracker 1 explodes first C. Firecracker 2 explodes first A. Both explode at the same time B. Firecracker 1 explodes first C. Firecracker 2 explodes first Even though Ricky sees the flash from 1 after the one from 2, she knows the local times at which each cracker went off. Event 1: (x1, y1, z1, t1) 2 Event 2: (x2, y2, z2, t2), with t1 = t2 Simultaneity in two frames Now we have time under control in one frame! v How about if there are two frames moving relative to each other? ... -3 -2 -1 0 ... -3 -2 1 -1 2 0 3 ... 1 2 3 ... A second frame has its own clocks, and moves past me. What happens now? L R L R v Lucy Lucy Now Lucy is the middle of a railroad car, and sets off a firecracker. (Boom goes the dynamite!) Light from the explosion travels to both ends of the car. Which end does it reach first according to Lucy? a) both ends at once b) the left end, L c) the right end, R These events are simultaneous in Lucy’s frame. Sure! After the firecracker explodes, a spherical wave front of light is emitted. (‘Spherical’, because the speed of light is the same in all directions in any inertial frame of reference). A little while later, it reaches both ends of the car. Sometime later, Lucy finds out about it – but that’s a different story. The synchronized clocks are all that matter. L R v L R v Lucy Ricky Ethel Lucy’s friends Ethel and Ricky are standing still next to the tracks, watching the train move to the right. According to Ethel and Ricky, which end of the train car does the light reach first? (As before the firecracker is still in the middle of the car.) a) both ends at once b) the left end, L c) the right end, R L -2 -2 0 1 0 1 2 R L v 2 3 ... Suppose Lucy’s firecracker explodes at the origin of Ethel’s reference frame. R -1 -1 Ethel In Ethel’s frame, these events are not simultaneous. Lucy ... -3 ... -3 3 ... Ethel The light spreads out in Ethel’s frame from the point she saw it explode. Because the train car is moving, the light in Ethel’s frame arrives at the left end first. An important conclusion Given two spacetime events: 1) Light hits the right end of the train car 2) Light hits the left end of the train car v Lucy ... -3 -2 -1 0 1 2 3 ... Ethel Sometime later, in Ethel’s frame, the light catches up to the right end of the train (assume the light is going faster than the train). Review: Lucy in the train plays with a firecracker. Ethel watches from the track L R v Lucy Lucy finds that the events are simultaneous. Ethel (in a different reference frame) finds that they are not simultaneous. Ethel And they’re both right! They want to know what time the light reaches the left and the right ends of the car (Two ‘events’ in each frame) From last class: Timing of events depend on the choice of the inertial frame!! Lucy: in the train L Ethel: on the platform LLLL L R x 0 RR RR R vvvv v 0 Event L: Event R: (x=-3, t=3s) (x=+3, t=3s) Lucy says: ‘Simultaneous!’ x’ Event L’: Event R’: (x’=-2, t’=2s) (x’=+5, t’=4s) Ethel says: ‘Not simultaneous!’ L R v Lucy ... -3 -2 -1 0 1 2 3 ... Ethel Now suppose Lucy’s firecracker is just slightly toward the right end of the train, so slightly that Ethel still measures the light hitting the left end first. According to Lucy, which end gets hit first? a) both at the same time b) the left end, L c) the right end, R An important conclusion Given two spacetime events: 1) Light hits the right end of the train car 2) Light hits the left end of the train car Lucy finds that the events are simultaneous. Ethel (in a different reference frame) finds that they are not simultaneous. And they’re both right! An important conclusion • In Lucy’s frame: – Firecracker explodes (event 1) – Light gets to the right end of the train (event R) – A little later, light gets to the left end (event L) • In Ethel’s frame: – Firecracker explodes (event 1) – Light gets to the left end of the train (event L) – A little later, light gets to the right end (event R) And they’re both right! An important conclusion Not only can observers in two different inertial frames disagree on whether two events are simultaneous, they may not even agree which event came first. Peep? Time dilation And that’s the relativity of simultaneity. Quiz on the reading What does Proper Time refer to? A – Time measured by an accurate clock that is at rest in a specific inertial frame B – Time measured by correctly synchronized clocks that are at rest in a specific inertial frame C – Time interval between any two events that take place in the same inertial frame, measured by two correctly synchronized clocks that are closest to these events. D – Time interval between two events that occur at the same place in a specific inertial frame measured by a clock that is at rest in that same inertial frame. E – Time measured by a Swiss watch. Proper time (see TZD p. 18) If two events have the same spatial coordinates in a specific inertial frame, then the time between them measured by a clock at rest in the same inertial frame is the proper time. Example: Any given clock never moves with respect to itself. It keeps proper time in its own frame. Any observer moving with respect to this clock sees it run slow (i.e., time intervals are longer). This is time dilation. Same location Mathematically: Event 1: (x1,y1,z1,t1) Event 2: (x1,y1,z1,t2) Proper time: ∆t = t2 - t1 Speed of light Comparing inertial frames S ... -3 -2 -1 0 1 2 3 ... x x An observer and a ball are at rest in reference frame S. At t = 0, the observer in S flashes a light pulse to be received at x = 3 m. At ∆t = 10 ns, the light is received. Observer S measures a distance ∆x = 3 m, so the speed of light in frame S is ∆x 3m u= = = 0.3m / ns ∆t 10ns ... -3 -2 -1 0 1 2 3 ... ... -3 -2 -1 0 1 2 3 ... x’ S’ is moving with respect to S at v = 0.2 m/ns. At t = 0, observer in S flashes a light pulse to be received at x = 3 m. Ten nanoseconds later ... -3 -2 -1 ... -3 0 1 2 3 ... -2 -1 0 1 v 2 3 ... S’ is moving with respect to S at v = 0.2 m/ns. At ∆t = 10 ns, the light is received. In Galilean realtivity, how far does the observer in S’ think the light has traveled? a) 3 m b) 2 m c) 1 m d) 0 m v Ten nanoseconds later ... -3 -2 -1 ... -3 0 1 2 3 ... -2 -1 0 1 v 2 3 ... S’ is moving with respect to S at v = 0.2 m/ns. At ∆t=10 ns, the light is received. In Galilean relativity, the observer in S’ would therefore measure the speed of light as ∆x′ 1m u= = = 0.1m / ns Uh-oh! ∆t ′ 10ns More ‘evidence’ for time Dilation Uh-oh! If we are to believe Einstein’s second postulate (and we do), then: In frame S In frame S’ Mirror ∆x c= ∆t c= Lucy h v ∆x′ ∆t ′ Conclusion: Since we accepted Einstein's second postulate of relativity (‘c’ is the same in all inertial frames) and we found that ∆x ≠ ∆x ' , we conclude that ∆t ≠ ∆t ′ . I.e., time passes at different rates in the two frames of reference!! More evidence for ‘Time Dilation’ Lucy measures the time interval: ∆t (Not a big surprise!) = 2h/c More evidence for ‘Time Dilation’ Mirror h v h v · ∆t’/2 Ricky Ethel Ethel and Ricky measure the time interval: Ethel Ricky Note: This experiment requires two observers. ∆t ' = 2h γ, c γ = 1 1− 2 v c2 But Lucy measured ∆t = 2h/c !! Time dilation in moving frames Lucy measures: ∆t Ethel and Ricky: ∆t’ = γ∆t, with 1 γ = v2 1− 2 c For Lucy time seems to run slower! (Lucy is moving relative to Ethel and Ricky) Intermezzo: Spacetime diagrams (very useful in SR!) Spacetime Diagrams (1D in space) Spacetime Diagrams (1D in space) c ·t In PHYS 1110: In PHYS 2130: v x x x x ∆x v = ∆x/∆t ∆t t Spacetime Diagrams (1D in space) t Recall: Lucy plays with a fire cracker in the train. Ethel watches the scene from the track. c· t In PHYS 2130: object moving with 0<v<c. ‘Worldline’ of the object -2 -1 0 1 2 L x R v object moving with 0>v>-c c·t c·t -2 -1 0 1 2 x Lucy object moving with v = -c. x=0 at time t=0 object at rest at x=1 -2 -1 0 1 2 x Ethel Example: Lucy in the train ct Example: Ethel on the tracks ct Light reaches both walls at the same time. Light travels to both walls L R x Lucy concludes: Light reaches both sides at the same time In Lucy’s frame: Walls are at rest Ethel concludes: Light reaches left side first. L R In Ethel’s frame: Walls are in motion x Frame S’ as viewed from S S ... -3 -2 -1 0 1 2 3 ... v=0.5c S’ ... -3 -2 -1 0 1 2 These angles are equal 3 ... ct Frame S’ is moving to the right at v = 0.5c. The origins of S and S’ coincide at t=t’=0. Which shows the world line of the origin of S’ as viewed in S? A B ct C ct x D ct x This is the time axis of the frame S’ ct’ x’ This is the space axis of the frame S’ x ct x x Frame S’ as viewed from S ct ct’ x’ In S: (3,3) In S’: (1.8,2) x Both frames are adequate for describing events – but will give different spacetime coordinates for these events, in general. Example: Lucy in the train ct Light reaches both walls at the same time. Light travels to both walls (End of Space time diagrams) Now back to Time dilation! L R x Lucy concludes: Light reaches both sides at the same time In Lucy’s frame: Walls are at rest Example: Ethel on the tracks ct Last class’ clicker question: S ... -3 Ethel concludes: Light reaches left side first. L R Frame S’ as viewed from S ct This is the time axis of the frame S’ ct’ -1 0 1 2 v=0.5c S’ ... -3 -2 -1 0 1 2 3 ... ct Frame S’ as viewed from S ct ct’ x’ This is the space axis of the frame S’ ct’ Frame S’ was moving to the right at v=0.5c. The origins of S and S’ coincided at t=t’=0. We found that the world line of the origin of S’ as viewed in S was represented by the blue line on the right: x’ x 3 ... x In Ethel’s frame: Walls are in motion These angles are equal -2 In S: (3,3) In S’: (1.8,2) x Both frames are adequate for describing events – but will give different spacetime coordinates for these events, in general. (End of Space time diagrams) Now back to Time dilation! x What we found so far: Time Dilation Simultaneity of two events depends on the choice of the reference frame L Time Dilation: Two observers (moving relative to each other) can measure different durations between two events. R v Lucy …-3 -2 -1 0 1 Ethel 2 v h 3... Ethel concludes: Light hits left side first. Lucy concludes: Light hits both ends at the same time. Lucy h Ethel Lucy measures: ∆t’ = 2h/c Here: ∆t’ is the proper time 1 Ethel and Ricky: γ = 2h v2 ∆t = γ /c , with 1− 2 c L R v Lucy Are your clocks really synchronized? Ricky ... -3 -2 -1 0 1 2 3 ... Ethel Now Lucy and Ethel each have a set of clocks. Lucy’s are synchronized in her frame (the train), while Ethel’s are synchronized in her frame (the tracks). How do the clocks of one frame read in the other frame? (Pay attention, now!) L R -2 -1 0 R RRR v Lucy ... -3 L L LL 1 2 3 ... Ethel At 3 o’clock in Ethel’s frame, two firecrackers go off to announce the time. It so happens that these firecrackers are at the left and right ends of the train, in Ethel’s frame. Event 1: firecracker 1 explodes at 3:00 Event 2: firecracker 2 explodes at 3:00 v vvv Lucy Lucy Lucy Lucy ... -3 -2 -1 0 1 2 3 ... Ethel Sometime later, the wavefronts meet. The meeting point is halfway between the firecrackers in Ethel’s frame, but is somewhere in the left of the train car, in Lucy’s frame. Event 3: two light pulses meet, shortly after 3:00. The situation as seen by Lucy L R Lucy L R Ethel Lucy In Lucy’s frame, light left first from the right end of the car. The light pulses both show clocks reading 3:00 in Ethel’s frame. According to Lucy’s reference frame, which of the following is true: A) Ethel’s clock on the left reads a later time than Ethel’s clock on the right. B) Ethel’s clock on the right reads a later time than Ethel’s clock on the left. C) Both of Ethel’s clocks read the same time. Ethel Important conclusion In Lucy’s frame: L Clocks in S’ (synchronized in S’) moving to the left with respect to S R Lucy v S Ethel S’ This clock reads a little after 3:00 in S If this clock reads 3:00 in S, then: This clock reads even a little later in S Clocks in S’ as seen by observer in S Even though the clocks in S’ are synchronized (in S’) the observer in S sees each clock showing a different time!! A little journey v Now let’s have some fun! The Twin ‘Paradox’ Vicki Carol Carol and Vicki are identical twins. While Vicki stays on Earth, Carol departs for the star Sirius, 8 lightyears away, traveling at a speed v = 0.8 c (Note γ = 5/3). According to Vicki, how long does the trip take? (Assume Earth and Sirius are not moving relative to each other.) a) 6 years b) 8 years c) 10 years d) 16.67 years A little journey A little journey v Vicki v Vicki Carol Carol and Vicki are identical twins. While Vicki stays on Earth, Carol departs for the star Sirius, 8 lightyears away, traveling at a speed v = 0.8 c (Note γ = 5/3). According to Carol, how long does the trip take? (Assume Earth and Sirius are not moving relative to each other.) a) 6 years b) 8 years c) 10 years d) 16.67 years A little journey Why? Because Carol’s clock is present at both the events: Carol is at Earth. Carol is at Sirius. So if ∆τ is Carol’s proper time between these events, and ∆t is the time in the Earth-Sirius system, we have ∆τ = ∆t γ = 10 y = 6y 5/3 Follow the proper time! But wait.... From Carol’s point of view, it was Vicki who was moving. So we should expect: v Vicki Carol Carol Upon arriving at Sirius, Carol immediately turns around and heads home at v = 0.8c. When she returns, she has aged 12 years, while Vicki has aged 20 years! In Vicki’s frame (the Earth), Carol ages 12 years while Vicki ages 20. In Carol’s frame (the spacecraft), Vicki ages 12 years while Carol ages 20. And they can’t both be right! Resolution: Carol has to turn around. Vicki Carol Spacetime diagram Carol and Vicky send out radio signals at the beginning of every year (measured by their respective local clocks) Vicky receives the last six signals from Carol within the last two (earth) years. Vicky receives the first signal from Carol after three (earth) years. Length contraction ct { Carol receives the first signal from Vicky after three (spaceship) years. Vicky’s signals Carol’s signals x (Consequence of time dilation and vice versa) Quiz on the reading Length of an object Proper length of an object is the length of the object measured… (see TDZ p. 23) A – …in its rest frame. B – …in any inertial frame. C – …in the inertial frame in which both ends of the object have the same event coordinates. D – …in the frame in which the object is not rotating. E – …by the speed of light. ... -3 -1 0 1 2 3 ... This length, measured in the stick’s rest frame, is its proper length. ‘Proper length’ Proper length: Length of object measured at rest / object measured in the frame where it is at rest (use a ruler) -2 This stick is 3m long. I measure both ends at the same time in my frame of reference. “Same time” or not doesn’t actually matter here, because the stick isn’t going anywhere. Remember ‘proper time’ Proper time: Time interval ∆t = t2 – t1 between two events measured in the frame, in which the two events occur at the same spatial coordinate, i.e. time interval that can be measured with one clock. v ... -3 -2 -1 0 1 2 3 ... Length of an object Observer in S measures the proper length L of the blue object. S ... -3 -2 Length of an object -1 S’ 0 0 1 2 3 ... v Another observer comes whizzing by at speed v. This observer measures the length of the stick, and keeps track of time. Event 1 – Origin of S’ passes left end of stick. S ... -3 -2 -1 0 1 S’ 2 3 ... v 0 Event 1 – Origin of S’ passes left end of stick. Event 2 – Origin of S’ passes right end of stick. A little math S S’ In frame S: (rest frame of the stick) length of stick = L (this is the proper length) time between events = ∆t speed of frame S’ is v = L/∆t A little math v In frame S’: length of stick = L’ (this is what we’re looking for) time between events = ∆t’ speed of frame S is v = L’/∆t’ Follow the proper time! Q: a) ∆t = ∆t’ b) ∆t = γ∆t’ c) ∆t’ = γ∆t Speeds are the same (both refer to the relative speed). And so | v |= L′ L L = = ∆t ′ ∆t γ∆t ' L′ = L γ Length in stick’s rest frame (proper length) Length in moving frame Length contraction is a consequence of time dilation (and vice-versa). Quiz on proper time/length v The Twin Paradox revisited Vicki Carol Sirius Carol travels from the Earth to Sirius. Which of the following statements is correct? (Assume that Earth and Sirius are not moving relative to each other) A – Vicky measures proper time and proper length of the journey. B – Carol measures proper time and proper length of the journey. C – Vicky measures proper time and Carol measures proper length of the journey. D – Carol measures proper time and Vicky measures proper length of the journey. E – none of the above Review: Proper length Proper length: Length of object measured in the frame, where it is at rest (use a ruler) Review: Proper length Proper time: Time interval ∆t = t2 – t1 between two events measured in the frame, in which the two events occur at the same spatial coordinate, i.e. time interval that can be measured with one clock. v ... -3 -2 -1 0 1 2 3 ... Proper time & proper length Length contraction vs. time dilation Vicky v Vicki Carol Sirius Now we know the following about this journey: - Vicki measures the proper length: 8 light-years. - Carol measures the proper time: 6 years. - Both agree that Carol travels at a speed of v=0.8c relative to the earth. ... -3 -2 -1 0 1 2 3 ... Vicky measures: Proper length: LVicky= 8 ly Time: ∆tVicky = γ ∆tCarol = 10y Carol v From Carol’s perspective: Carol finds that she traveled only 6y*0.8c = 4.8 ly. But why does she find herself at Sirius after 6 years?? Carol measures: Length: LCarol= LVicky /γ = 4.8 ly Proper time: ∆tCarol = 6 y 0 Length contraction!! The Lorentz transformation S Lorentz transformation (Relativistic version of Galileo transformation) v S’ x’ 0 A stick is at rest in S’. Its endpoints are the events (x,ct) = (0,0) and (x’,0) in S’. S’ is moving to the right with respect to frame S. Event 1 – left of stick passes origin of S. Its coordinates are (0,0) in S and (0,0) in S’. Lorentz transformation An observer at rest in frame S sees a stick flying past him with velocity v: S S x v S’ 0 The Lorentz transformation x’ As viewed from S, the stick’s length is x’/γ. Time t passes. According to S, where is the right end of the stick? (Assume the left end of the stick was at the origin of S at time t=0.) a) x = γvt b) x = vt + x’/γ c) x = -vt + x’/γ d) x = vt – x’/γ e) something else v S’ 0 x’ x = vt + x’/γ . This relates the spatial coordinates of an event in one frame to its coordinates in the other. Algebra x’ = γ(x-vt) A note of caution: Transformations If S’ is moving with speed v in the positive x direction relative to S, then the coordinates of the same event in the two frames are related by: Galilean transformation (classical) Lorentz transformation (relativistic) x′ = γ ( x − vt ) y′ = y x′ = x − vt y′ = y z′ = z S -1 1 2... 0 1 x2 x1 v S’ ... -3 -2 -1 2 3 ... An object moves from event A=(x1,t1) to event B =(x2,t2). ∆x with: ∆x = x1 - x2 As seen from S, its speed is u = ∆t ∆t = t1 - t2 ∆x′ with: ∆x’ = x’1 - x’2 As seen from S’, its speed is u ′ = ∆t ′ ∆t’ = t’1 - t’2 Velocity transformation in 3D y S S' x z S' (x',y',z',t') v x' z' Velocity transformation (1D) ∆x′ , where ∆x=x1 - x2, ∆x’=x’1 - x’2 ∆t ′ Use Lorentz: x’ =. γ(x-vt) 1 .. ∆x′ γ (∆x − v∆t ) ∆t × u′ = = ∆t ′ γ (∆t − (v / c 2 )∆x) 1 ∆t Galilean result ∆x , ∆t u′ = u′ = u −v 1 − uv / c 2 New in special relativity Velocity transformation (3D) The velocity u=(ux, uy, uz) measured in S is given by: y' (x,y,z,t) z u= ∆x 0 (x,y,z,t) x A B y' S Velocity transformation (1D) -2 y v t ′ = γ (t − 2 x ) c Note: This assumes (0,0,0,0) is the same event in both frames. ... -3 An observer in S would like to express an event (x,y,z,t) (in his frame S) with the coordinates of the frame S', i.e. he wants to find the corresponding event (x',y',z',t') in S'. The frame S' is moving along the x-axes of the frame S with the velocity v (measured relative to S) and we assume that the origins of both frames overlap at the time t=0. See homework #3 z′ = z t′ = t The way the Lorentz and Galileo transformations are presented here (and in the textbook) assumes the following: u ux=∆x/∆t , (x',y',z',t') uy=∆y/∆t , uz=∆z/∆t v x' z' In a more general case we want to transform a velocity u (measured in frame S) to u’ in frame S’. Note that u can point in any arbitrary direction, but v still points along the x-axes. , where ∆x=x1-x2 … To find the corresponding velocity components u’x, u’y, u’z in the frame S’, which is moving along the x-axes in S with the velocity v, we use again the Lorentz transformation: x’1=γ(x1-vt1), and so on… t’1=γ(t1-vx1/c2), and so on… Algebra Velocity transformation (3D) (aka. “Velocity-Addition formula”) u' x = ux − v 1 − ux v / c 2 Some applications uy u' y = γ (1 − u x v / c 2 ) u' z = uz γ (1 − u x v / c 2 ) Relativistic transformations x′ = γ ( x − vt ) v u −v x) 1c−2 uv / c 2 u−v u' = 1 − uv / c 2 u= t ′ = γu(′t =− u′ + v 1 + u ′v / c 2 b) 0.5 c u is what we were looking for! (i.e. velocity measured in S) y Suppose a spacecraft travels at speed v=0.5c relative to the Earth. It launches a missile at speed 0.5c relative to the spacecraft in its direction of motion. How fast is the missile moving relative to Earth? (Hint: Remember which coordinates are the primed ones. And: Does your answer make sense?) a) 0.8 c Velocity transformation: Which coordinates are primed? c) c d) 0.25 c y' u (x,y,z,t) S S' x Earth (x',y',z',t') z' z v x' Spacecraft e) 0 Lucy v x′ = γ ( x − vt ) ? u′ = u −v 1 − uv / c 2 u= u′ + v 1 + u ′v / c 2 The “object” could be light, too! Suppose a spacecraft travels at speed v=0.5c relative to the Earth. It shoots a beam of light out in its direction of motion. How fast is the light moving relative to the Earth? (Get your answer using the formula). a) 1.5c b) 0.5 c c) c d) d ... -3 -2 -1 0 George 1 2 3 ... t ′ = γ (t − v x) c2 George has a set of synchronized clocks in reference frame S, as shown. Lucy is moving to the right past George, and has (naturally) her own set of synchronized clocks. Lucy passes George at the event (0,0) in both frames. An observer in George’s frame checks the clock marked ‘?’. Compared to George’s clocks, this one reads e) e A) a slightly earlier time B) a slightly later time C) same time Lucy x′ = γ ( x − vt ) v ? ... -3 t ′ = γ (t − -2 -1 0 1 George 2 v x) c2 3 ... The event has coordinates (x = -3, t = 0) for George. In Lucy’s frame, where the ? clock is, the time t’ is t ′ = γ (0 − v 3γ v ( −3)) = 2 c2 c Spacetime interval , a positive quantity. ‘?’ = slightly later time Remember this? (from 1st class) Remember Lucy? The distance between the blue and the red ball is: 2 2 (3m) + (4m) = 25m = 5m If the two balls are not moving relative to each other, we find that the distance between them is “invariant” under Galileo transformations. Remember Ethel? c∆t’ h Event 1 – firecracker explodes Event 2 – light reaches detector Distance between events is h h = c∆t Spacetime interval Say we have two events: (x1,y1,z1,t1) and (x2,y2,z2,t2). Define the spacetime interval (sort of the "distance") between two events as: h (∆s )2 = (c∆t )2 − (∆x )2 − (∆y )2 − (∆z )2 ∆x’ Event 1 – firecracker explodes Event 2 – light reaches detector Distance between events is c∆t’ But distance between x-coordinates is ∆x’ and: (c∆t’)2 = (∆x’)2 + h2 We can write h 2 = (c∆t ′)2 − (∆x′)2 Lucy And Lucy got h 2 = (c∆t )2 − (∆x )2 since ∆x = 0 With: ∆x = x1 − x2 ∆y = y1 − y2 Spacetime interval ∆z = z1 − z 2 ∆t = t1 − t 2 The spacetime interval has the same value in all reference frames! I.e. ∆s2 is “invariant” under Lorentz transformations. (Homework #3!) Spacetime ct Here is an event in spacetime. Spacetime ct Here is an event in spacetime. Any light signal that passes through this event has the dashed world lines. These identify the ‘light cone’ of this event. x The blue area is the future on this event. x Spacetime ct Here is an event in spacetime. The yellow area is the “elsewhere” of the event. No physical signal can travel from the event to its elsewhere! A x The pink is its past. Spacetime Now we have two events A and B as shown on the left. ct B A x The space-time interval (∆s)2 of these two events is: a)Positive b)Negative c)zero If (∆s)2 is negative in one frame of reference it is also negative in any other inertial frame! ((∆s)2 is invariant under Lorentz transformation). Causality is fulfilled in SR. Spacetime Example: Wavefront of a flash z ct D C B A x (∆s)2 >0: Time-like events (A – D) (∆s)2 <0: Space-like events (A – B) (∆s)2 =0: Light-like events (A – C) t=0 t>0 y x Wavefront = Surface of a sphere with radius ct: (ct)2 - x2 - y2 - z2 = 0 Spacetime interval for light-like event: (∆s)2 = 0 (∆s)2 is invariant under Lorentz transformation. Einstein: 'c' is the same in all inertial systems. Therefore: (ct')2 - x'2 - y'2 - z'2 = 0 in all inertial systems! (Here we assumed that the origins of S and S' overlapped at t=0) Momentum The classical definition of the momentum p of a particle with mass m is: p=mu. This is the end of our excursion to the relativistic spacetime. In absence of external forces the total momentum is conserved (Law of conservation of momentum): n ∑p i =1 Questions? i = const. Due to the velocity addition formula, the definition p=mu is not suitable to obtain conservation of momentum in special relativity!! Need new definition for relativistic momentum! y Review: Transformation rules and conservation of momentum Conservation of momentum is extremely useful in classical physics. For the new definition of relativistic momentum we want: y' m u2 u1 m u'2 v = u1x u1y u'1 m m u1x S S' x Classical: x' Relativistic: u'x = ux – v u' x = u'y = uy u' y = ux − v 1 − ux v / c 2 uy γ (1 − u x v / c 2 ) Relativistic momentum Classical definition: p=m dr dt Say we measure the mass 'm' in its rest-frame ('proper mass' or 'rest mass'). Since we measure 'm' it's restframe we agree on the same value for 'm' in all frames. Assume we take the derivative with respect to the proper time tproper , which has the same meaning in all frames. Relativistic definition: p≡m 1. At low velocities the new definition of p should match the classical definition of momentum. 2. We want that the total momentum (Σp) of an isolated system of bodies is conserved in all inertial frames. Relativistic momentum The time dilation formula implies that dt = γdtproper We can therefore rewrite the definition of the relativistic momentum as follows: p≡γ m dr = γ mu dt dr dt proper This definition fulfills the conservation of momentum in SR! To prove it you can apply the relativistic velocity transformation. An important consequence of the Lorentz-factor γ is, that no object can be accelerated past the speed of light. L Example: Classical vs. Relativistic momentum Relativistic momentum An electron has a mass m ≈ 9·10-31kg. The table below shows the classical and relativistic momentum of the electron at various speeds (units are 10-22kg·m/s): ~52,000,000 mph only ~1% change! u 0.1c p=m·u classical 0.273 p=γm·u relativistic 0.276 difference [%] 1.1 0.5c 1.36 1.57 15.4 0.9c 0.99c 2.46 2.7 5.63 19.2 128.9 611.1 Particle A has half the mass but twice the speed of particle B. If the particles’ momenta are pA and pB, then a) pA > pB b) pA = pB c) pA < pB Relativistic force γ is bigger for the faster particle. Example: Relativistic force A charged particle (charge q) with mass m is at rest at x = 0 in a uniform electric field ℇ . Plot the velocity u of the particle as a function of time t (assume the particle is released at t = 0). We can define the classical force using Newton's law: F = ma This is equivalent to: F = dp/dt Force acting on the particle: F = q·ℇ Using the definition of the relativistic momentum we obtain a suitable definition for a relativistic force: Relativistic force F ≡ d(γ·m·u)/dt Therefore: dp d = (γ m u ) , with γ = dt dt 1 Or: yields: 1− u2 c2 yields: m·u = q·ℇ·t (1-u2/c2)0.5 Square both sides: m2·u2 = q2·ℇ2·t2(1-u2/c2) a) Bring u to the left: u2(m2c2 + q2·ℇ2·t2)= q2·ℇ2·t2·c2 Divide by term in bracket and take squareroot: u Classical c 0 0 qEct c u 0 c) ( qEt ) 2 + ( mc ) 2 0 t c u c u d) E u= b) E γ = Which graph best represents the total energy of a particle (particle's mass m>0) as a function of its velocity u, in special relativity? E Dividing by 1 q·ℇ · t = γ·m·u Quiz: On the reading for the velocity u. γ·m·u = q·ℇ·t q·ℇ dt = d(γ·m·u) Integrating both sides: ∫ q·ℇ dt = ∫ d(γ·m·u) u2 1− 2 c Example: Relativistic force (cont.) Now: Solve q·ℇ = d(γ·m·u)/dt E F≡ p = γmu B A 0 c u 0 Energy Similar to the definition of the relativistic momentum we want to find a definition for the energy E of an object that fulfills the following: 1. At low velocity, the value E of the new definition should match the classical definition. 2. The total energy (ΣE) of an isolated system of bodies should be conserved in all inertial frames. Kinetic energy The work done by a force F to move a particle from position 1 to 2 along a path s is defined by: 2 W12 = ∫ F ⋅ ds = K 2 − K1 1 K1,2 being the particle's kinetic energy at positions 1 and 2, respectively (true for frictionless system). Using our prior definition for the relativistic force we can now find the relativistic kinetic energy of the particle. (After some 'slightly involved' algebra.) Relativistic kinetic energy The relativistic kinetic energy K of a particle with a rest mass m is: Total energy We rewrite the equation for the relativistic kinetic energy and define the total energy of a particle as: K = γmc2 - mc2 = (γ-1)mc2 E = γmc2 = K + mc2 Note: This is very different from the classical K= ½mv2 . K = γmc2 - mc2 ≈ mc2 + ½ mc2v2/c2 - mc2 = ½ mv2 This definition of the relativistic mass-energy E fulfills the condition of conservation of total energy. (Not proven here, but we shall see several examples where this proves to be correct.) Quiz: Rest energy Equivalence of Mass and Energy For slow velocities the relativistic energy equation gives the same value as the classical equation! Remember the binomial approximation for γ: γ ≈ 1+ ½v2/c2 E = γmc2 = K + mc2 In the particle's rest frame, its energy is its rest energy, E0. What is the value of E0? A: B: C: D: E: 0 c2 mc2 (γ-1)mc2 ½ mc2 Note: This suggests an equivalence of mass and energy! m v -v m E2 = γmc2 = K + mc2 E1 = γmc2 = K + mc2 Total energy: Etot = E1+E2 = 2K + 2mc2 Equivalence of Mass and Energy v m -v Example: Rest energy of an object with 1kg m Conservation of the total energy requires that the final energy Etot,final is the same 2 as the energy Etot, before 2 tot Therefore: the collision. E0 = mc2 = (1 kg)·(3·108 m/s )2 = 9·1016 J E = γ2mc = 2K + 2mc Etot,final = Mc2 = 2K + 2mc2 = Etot,initial We find that the total mass M of the final system is bigger than the sum of the masses of the two parts! M>2m. Potential energy inside an object contributes to its mass!!! How does nuclear power work? Atomic cores are built from neutrons and protons. There are very strong attractive forces between them. The potential energy associated with the force keeping them together in the core is called the binding energy EB. We now know that the total rest energy of the particle equals the sum of the rest energy of all constituents minus the total binding energy EB: Mc2 = Σ(mi c2) – EB Or in terms of Mass per nucleon 9·1016 J = 2.5·1010 kWh = 2.9 GW · 1 year This is a very large amount of energy! (Equivalent to the yearly output of ~3 very large nuclear reactors.) Enough to power all the homes in Colorado for a year! Periodic table of elements Example: Deuterium fusion Isotopes of Hydrogen: Example: Deuterium fusion Relationship of Energy and momentum Recall: = γmc2 p = γmu Total Energy: E Momentum: use: Therefore: p2c2 = γ2m2u2c2 = γ2m2c4 · u2/c2 Isotope mass: Deuterium: 2.01355321270 u Helium 4: 4.00260325415 u (1 u ≈ 1.66·10-27 kg) u2 γ 2 − 1 = 2 c2 γ p2c2 = γ2m2c4 – m2c4 =E2 This leads us the momentum-energy relation: 1kg of Deuterium yields ~0.994 kg of Helium 4. Energy equivalent of 6 grams: E0 = mc2 = (0.006 kg)·(3·108 m/s )2 = 5.4·1014 J or: Enough to power ~20,000 American households for 1 year! Application: Massless particles From the momentum-energy relation E2 = p2c2 + m2c4 we obtain for mass-less particles (i.e. m=0): E = pc , (if m=0) p=γmu and E=γmc2 Using E=pc leads to: p/u = u=c E/c2 , (if m=0) Massless particles travel at the speed of light!! … no matter what their total energy is!! E2 = (pc)2 + (mc2)2 E2 = (pc)2 + E02 Example: Electron-positron annihilation Positrons (e+, aka. antielectron) have exactly the same mass as electrons (e-) but the opposite charge: me+ = me-= 511 keV/c2 (1 eV ≈ 1.6·10-19J) E1, p1 eBAM! e+ E2, p2 At rest, an electron-positron pair has a total energy E = 2 · 511 keV. Once they come close enough to each other, they will annihilate one other and convert into two photons. Conservation momentum: . photons? 1 = -p2two What can of you tell about pthose Conservation of energy: E1+E2 = 2mc2 , E1 = E2 = 511 keV Do neutrinos have a mass? Do neutrinos have a mass? (cont.) Neutrinos are elementary particles. They come in three flavors: electron, muon, and tau neutrino (νe,νµ, ντ). The standard model of particle physics predicted such particles. The prediction said that they were mass-less. Bruno Pontecorvo predicted the ‘neutrino oscillation,’ a quantum mechanical phenomenon that allows the neutriono to change from one flavor to another while traveling from the sun to the earth. The fusion reaction that takes place in the sun (H + H He) produces such νe. The standard solar model predicts the number of νe coming from the sun. All attempts to measure this number on earth revealed only about one third of the number predicted by the standard solar model. Why would this imply that the neutrinos have a mass? Massless particles travel at the speed of light! i.e. γ ∞, and therefore, the time seems to be standing still in the frame of the neutrino: ∆tneutrino = ∆tproper = ∆tEarth / γ In the HW: muon or pion experiments. The half-live time of the muons/pions in the lab-frame is increased by the factor γ. Summary SR • Classical relativity Galileo transformation • Special relativity (consequence of 'c' is the same in all inertial frames; remember Michelson-Morley experiment) – Time dilation & Length contraction, events in spacetime Lorentz transformation – Spacetime interval (invariant under LT) – Relativistic forces, momentum and energy – Lot's of applications (and lot's of firecrackers) … That’s it! Now go home and work on your time machine… … or on the warp-reactor. Everything we have discussed to this point will be part of the first mid-term exam (including reading assignments and homework.) If you have questions ask as early as possible!! Part 2: Quantum* Mechanics Actually: don’t go home quite yet! Part 2 of this course: 1. Basic properties of light (electromagnetic waves). 2. Photoelectric effect and how it shows light comes in quantum units of energy. When is a wave not a wave? (when it is a particle!) 2. Atomic spectra- quantized energy of electrons in atoms. 3. Bohr model of the atom. Where it works. Why it is wrong. 4. de Broglie idea- wave-particle duality of electrons etc. When is a particle not a particle? (when it’s a wave). Courtesy of IBM *We say something is quantized if it can occur only in certain discrete amounts. 5. Schrodinger Equation and quantum waves. 6. What they are, how to use. 7. Applications: chemistry, electronics, lasers, MRI, … Properties of light Interaction with matter Electrostatic fields http://phet.colorado.edu Electric fields exert forces on charges + + + + + + + + E + (e’s and p’s in atom) E F=qE - _ F=qE Force = charge • electric field F= qE Light is an oscillating E(and B)-field. It interacts with matter by exerting forces on the charges – the electrons and protons in atoms. Charges-and-fields.jar Light is an oscillating E (and B)-field Electromagnetic waves http://phet.colorado.edu • Oscillating electric and magnetic field • Traveling at speed of light (c) Snap shot of E-field in time: At t=0 A little later in time E c Emax Electromagnetic radiation This symbolizes a local disturbance of the electric field E(x,t) x The E-field is a function of position (x) and time (t): E(x,t) = Emaxsin(ax+bt) sin(ax-bt) , (here: b/a=c) Radio Waves.jar Remember this one? Making sense of the Sine Wave E-field (for a single color): E(x,t) = E0 sin(ωt+2πx/λ +φ) Light source E λ λ = 2πc/ω, ω = 2πf = 2π/T E0 φ E x Wavelength λ of visible light is: λ ~ 350 nm … 750 nm. x B CQ: What does the curve tell you? -For Water Waves? -For Sound Wave? -For E/M Waves? Electromagnetic Spectrum Snapshot of radio wave in air. Spectrum: All EM waves. Complete range of wavelengths. Length of vector represents strength of E-field Orientation represents direction of E-field What stuff is moving up and down in space as radio wave passes? a. electric field b. electrons c. air molecules d. light ray e. nothing Frequency (f) = # of times per second E-field at point changes through complete cycle as wave passes λ Red light λ Cosmic rays E. answer is nothing. Electric field strength increases and decreases – E-field does not move up and down. Electron oscillates with period of Τ Wavelength (λ) = distance (∆x) until wave repeats λ Blue light SHORT LONG Electromagnetic waves carry energy λ Emax=peak amplitude c Emax X How far away will the peak E-field be before the next peak is generated at this spot? b. c/Τ c. Τ/c e. none of the above a. cΤ d. sin(cΤ) Intensity = Power = energy/time α (Eavg)2 area area ans. is a. Distance = velocity * time Distance = cΤ = c/f = 1 wavelength so c/f = λ α (amplitude of wave)2 α Emax2 Intensity only depends on the E-field amplitude but not on the color (or frequency) of the light! Maxwell’s Equations: Describes EM radiation ∫E •d A= Qin ∫E •ds = − ε0 dΦ m dt ∫B•ds = µ I ∫B•d A= 0 E(x,t) = Emaxsin(ax-bt) Light shines on black tank full of water. How much energy absorbed? 0 through Maxwell’s Equations: Describes EM radiation ∫E •d A= + ε 0 µ0 dΦ e dt Qin ε0 ∫B•d A= 0 In 3-D: ∫E •ds = − ∫B•ds = µ I 1 ∂2E ∇E= 2 2 c ∂t 2 dΦ m dt 0 through In 1-D: + ε 0 µ0 dΦ e dt ∂2E 1 ∂2E = ∂x 2 c 2 ∂t 2 B Show that E(x,t) = Emaxcos(ax+bt) E is a solution (in 1-D) with b/a=c. How can we see that light really behaves like a wave? EM radiation is a wave What is most definitive observation we can make that tells us something is a wave? Ans: Observe interference. During 1600-1800s: lot’s of debate about what light really is. After ~1876 (Maxwell): Light = EM radiation viewed as a wave. How can it be tested? Constructive interference:(peaks are lined up and valleys are lined up) c What is most definitive observation we can make that tells us something is a wave? Observe interference!! (Remember the Michelson interferometer?) Two slit interference EM radiation is a wave What is most definitive observation we can make that tells us something is a wave? Ans: Observe interference. Destructive interference: (peaks align with valleys cancel each other) c E-fields wave interfarence online That's it about EM waves (for now) wave-interference_en.jar Review: How to generate light? Stationary charges constant E-field, no magnetic (B)-field (We don’t see charges glow in the dark) E + Charges moving at a constant velocity B Constant current through wire creates a B-field but B-field is constant. (We don’t see DC.) I Accelerating charges changing E-field and changing B-field B (EM radiation both E and B are oscillating) We talked briefly about Maxwell equations Questions? E The sun produces lots of light Light might simply heat up the plate X #1 Why? How? X + + + + Surface of sun- very hot! Whole bunch of free electrons whizzing around like crazy. Equal number of protons, but heavier so moving slower, less EM waves generated by protons. From last class: Intensity α Emax2 Emax=peak amplitude c Emax X E(x,t) = Emaxsin(ax-bt) Light shines on black tank full of water. How much energy absorbed? X #2 #3 (Use E1max=E2max>E3max) Which barrel will heat up the fastest? a. 2>1>3 b. 1>2>3 c. 1=2>3 d. 1=3>2 e. 2>1=3 Intensity = power/area α Emax2 Does not depend on frequency/color! Light is a wave interference! The definite check that light IS a wave Observe interference! Intensity = Power = energy/time α (Eavg)2 area area α (amplitude of wave)2 α Emax2 Intensity only depends on the E-field amplitude but not on the color (or frequency) of the light! So we found: light is a wave! …and things made a lot of sense: • EM waves can are described by Maxwell's theory • double slit experiment and other diffraction phenomena • explains grating spectrometers etc. •… The photoelectric effect (~1900) The photoelectric effect is a phenomenon in which electrons are emitted from matter as a consequence of their absorption of energy from light. But then there was this one, little experiment from Mr. Hertz (~1887) that just couldn’t be explained with EM waves! The effect was only observed with UV light, but not so with red or IR light. Effect is frequency dependent!? Actually, some other problems started to surface, such the lack of an accurate model for the black body radiation… But Maxwell told us that the light intensity doesn’t depend on frequency! (Intensity only depends on |E|2) The photoelectric effect The results from the photoelectric effect where inconsistent with the classical view of EM theory. (Discovered 1887 by Hertz, Explained by Einstein (using some of Plank's ideas) 1905. Nobel prize: 1921) Experimental apparatus: PE effect Metal surface Glass cylinder Einstein proposed: "…the energy in a beam of light is not distributed continuously through space, but consists of a finite number of energy quanta, which are localized at points, which cannot be subdivided, and which are absorbed “…” and emitted only as whole units." He took the energy of these single units to be hf, as proposed earlier by Planck. Vacuum What could it be? Experimental apparatus: PE effect What happens? A Metal surface B Glass cylinder 2 ohms - 10 V + Two metal plates in vacuum with a voltage between them. Vacuum Adjustable voltage Current meter What happens? A B 2 ohms - 10 V + Two metal plates in vacuum with a voltage between them. The potential difference between A and B is: A) 0 V B) 5 V C) 10 V D) infinite volts How much current is flowing through the resistor? A) 0A B) 0.2 A C) 5A D) 10 A E) infinite current Potential difference between A and B is 10 V Without light, no electrons can get across gap. But if we put an electron close to the surface of plate A it 'feels' the electric field between the two plates. The electron accelerates towards the positive plate (B) and picks up the energy = q(10V) = 1 electron charge x 10 V = 10 eV Uniform E-field between plates A Constant force on electron constant acceleration 0V F=qE E + + + + + - 10V + 0V Current==0.1 0 AA Current 10Volts 10V B A note about units of energy Joules are good for macroscopic energy conversions. But when talking about energy of single electrons, Joules are inconvenient… (way too big!) Define new energy unit: The electron-volt (eV) 1eV = kinetic energy gained by an electron when accelerated through 1 volt of potential difference How to put the e- close to plate A? Shine light on the plate!! Metal surface A Glass cylinder Electrons get pulled towards Vacuum plate B by F = E·q the electric field 1eV ≈ 1.6·10-19 J e- 1V + + + + 0V F E path Adjustable voltage + 1V Current meter Experimental apparatus: PE effect Play with color and intensity. Measure current I. (I ~ #e-/s) First we could argue that the light heats up the plate electrons pop-out Measure the current! BUT: # of electrons = constant Here, sec electrons So current is constant! are repelled by neg. electrode Current C 0 Voltage Current 0 Voltage D Current B Current Current What is the current vs. battery voltage? 0 Voltage Measure the current! What’s happening here? Each electron that pops out is accelerated and hits the plate on the right side. Hot plate. A few electrons get enough energy to just barely “splash” out. A + B + + + + 0 Voltage 0 reverse V, no electrons flow. not I = V / R !! Battery Voltage Vacuum tube diode. Works! - early electronic device. Vacuum tube diode Swimming Pool Analogy Current If no water slops over side of pool, no flow. Little pump or big pump, still no water current. If electrons stuck inside metal plate, no current for little or big V. pump voltage reverse V, no electrons flow. What do you think will actually happen? Optical power P - frequency f Now: Take out a piece of paper and draw the following graphs with what you expect will happen.) Voltage U ? Pool party: put bunch of energy into water, splash some out, get flow through pump. Put energy into metal by heating it very hot, gives electrons energy, some “splash” out. Gives current. Let's do the experiment! Play with color and intensity. Measure current I. (I ~ #e-/s) http://phet.colorado.edu Current I 1. Current vs. Voltage with the lamp on (fixed color, say UV light, and fixed intensity.) 2. Current vs. Frequency (color) at a fixed intensity and voltage (right plate is on positive potential) 3. Current vs. Intensity for fixed color (right plate is at fixed, positive voltage) 0 photoelectric online Measure the current! PE effect: A classical phenomena? Electrons NOT I=V/R !! Battery Voltage reverse V, no electrons flow. Looks kind off what we have seen in the experiment… Can we explain the PE effect with classical EM theory? Assume we could treat light as a classical wave. Predict the behavior (assume light puts energy into plate heats plate up get diode current voltage curve.) Takes time to heat up the plate. • Light on longer heat more, more e / s Current rises slowly over time. • Color light would not matter, only intensity! 0 Voltage Current Current Remember this? photoelectric_en.jar photoelectric_en.jar I I B A 0 Batt. V I 0 Batt. V D C 0 Batt. V I • Color does matter! The velocity (and number) of the electrons seems to increase with frequency (fUV > fblue > fred) • Positive voltages always yield the same current (at fixed color and intensity). • Large negative voltages make the current go to zero. • We never observe a negative current. • We have discussed that if we heat the metal, electrons could come out (slowly). Questions? Which graph represents low and high intensity curves best for a fixed color of the light? I What did we observe so far? 0 Batt. V F 0 Batt. V photoelectric_en.jar Remember definition of 'eV' Define electron-volt (eV): 1eV = kinetic energy gained by an electron when accelerated through 1 volt of potential difference path E I The lowest negative voltage required to stop the current multiplied by the electron charge qe corresponds to the kinetic energy of the fastest electrons! This lowest voltage is called the stopping potential. photoelectric_en.jar HIGH intensity LOW intensity e’s I I Fewer electrons pop out off metal Current decreases. Current proportional to light intensity. Same kinetic energy (KE). So same “stopping potential”. 0 Battery Voltage voltage to turn around most energetic electron: “stopping potential” I F e’s -U - 0 photoelectric_en.jar Predict what happens to the initial KE of the electrons as the frequency of light changes? (Light intensity is constant) Battery Voltage e’s I Predict shape of the graph Initial KE 0V 0 Frequency of light 0 Frequency Initial KE 0 D Correct answer is D. Frequency 0 There is a minimum frequency below which the light could not kick out electrons… even if we wait a long time e’s I Frequency E. something different Summary of Phot. Electric experiment results. (play with sim to check and thoroughly understand!) http://phet.colorado.edu/simulations/photoelectric/photoelectric.jnlp 1. Current linearly proportional to intensity. 2. Current appears with no delay. 3. Electrons only emitted if frequency of light exceeds a threshold. (same as “if wavelength short enough”). 4. Maximum energy that electrons come off increases linearly with frequency (=c/wavelength). (Max. energy = -stopping potential) 5. Threshold frequency depends on type of metal. As the frequency of light increases (shorter λ!), the KE of electrons being popped out increases. (it is a linear relationship) Initial KE C Frequency Initial KE 0 B Initial KE Initial KE A 0 What about different metals? (try sim) photoelectric_en.jar Frequency of light Classical wave predictions vs. experimental observations • Increase intensity current increases. Experiment matches with classical prediction • Current vs. voltage: step close to zero Volts, then flat. Flat part matches to classical pred., but experiment has 'tail' of energetic electrons Stopping potential, which depends on color (not only intensity). • Classical: Color of light does not matter, only intensity. Experiment shows strong dependence on color •Takes time to heat up ⇒ current initially low but increases with time. experiment: electrons come out immediately, no time delay to heat up how do these compare with classical wave predictions? Einstein: Need “photon” picture of light to explain observations: -Light comes in chunks of energy (“particle-like” We shall call those particles “photons”) Is light a stream of particles? Yes! Also…. E = hf -a photon interacts only with single electron - Photon energy depends on frequency of light, … for lower frequencies, photon energy not enough to free an electron (E = hf) Ekin,max=hf - φ “Work function” (I’ll explain later) What did you think would happen? Properties of photons Optical power P - frequency f The energy of a photon is The wavelength of a photon is The momentum of a photon is The mass of a photon is E = hf λ = c/f = hc/E p = hf/c = E/c m=0 Take out your paper again on which you drew following graphs. Voltage U Current I 1. Current vs. Voltage with the lamp on (fixed color of light, say UV). 2. Current vs. Frequency (color) at a fixed voltage (right plate is on positive potential) 3. Current vs. Intensity for fixed color (right plate is at positive voltage) h ≈ 6.626 ·10-34 J·s: Plank constant It sometimes is useful to define h = h/(2π) The energy of a photon is then: E = hf = hω That's what happened: high intensity low intensity U 0 A. There are more photons per second but each photon has less energy. B. There are more photons per second but each photon has more energy. C. There are fewer photons per second and each photon has less energy. D. There are fewer photons per second but each photon has more energy. E. Nothing happens to the photon number because light is a wave. F. I don’t do the reading assignments. Intensity or: Initial KE vs. f: I Initial KE 2. I vs. f: 0 The frequency of a beam of light is decreased but the light’s intensity remains unchanged. Which of the following is true? I I 1. Current vs. Voltage: 0 Photons 3. I vs. intensity: Frequency 0 Frequency Electromagnetic Waves and Photons are describing the same thing! Common confusion: Recap: Intensity ∝ Emax2 but does not depend on frequency! Need to have a model where these views/perspectives all fit together and are consistent with each other! X vs. X Interference was definitive test that light is a wave! “Why do higher frequency gamma rays carry more energy than lower frequency radio waves, but frequency has nothing to do with intensity, what gives?” “But Tom said that energy of light depends on frequency (∝ ∝ hf)!” Do not confuse the energy carried by a beam of light with the energy of a single quantum particle of light! 1. Light, Radio waves, X-rays are all electromagnetic waves! 2. The electromagnetic wave is made up from lots of photons. 3. Photons can be thought of as mini E/M wave segments (each has a specific energy hf and a wavelength c/f ) Electromagnetic Wave E Travels Straight Made up from lots photons of photons This picture can explain wave view and particle view. “Particle” = little chunk of the electromagnetic wave. Energy of photon (hf) is in its oscillating E and B fields. (Sometimes it also helps to think of a photon as a tiny particle/energy packet). When is it important to think about particle aspect of light? Only if your “detection system” is good enough to see individual photons! If you think of photons as particles you probably automatically think of them as perfectly localized - like a tiny billiard ball at a coordinate (x, y, z). This is what get's you into trouble in QM!! Examples where don’t need to think about particle behavior • Billiard balls never produce a diffraction pattern • Billiard balls have no wavelength/frequency • Billiard balls cannot go through two slits at the same time (photons can; electrons too! Will show later) Bright Red Laser Consistent descriptions: Lots of light means … • Big amplitude E/M wave • Made from many photons (mini E/M wave segments) When a photon interacts with something (e.g. an electron) all the energy of its wave segment ends up concentrated in one spot (like a particle!) Until a photon interacts with something (e.g. absorbed by an electron), it is a wave. How does the wavelength of the photon compare to the wavelength of the light in the red laser? a. Photon has a smaller wavelength b. Photon has same wavelength c. Photon has a larger wavelength d. Photons are points in space. They have no wavelength. What if the intensity is really small? Wimpy Laser beam: P = 10-19 W Examples where important to think about particle behavior: Photoelectric effect: Individual electrons popping out of metal Lasers: Electrons in atoms transitioning between energy levels Molecular bonds: Chemical bonds breaking First photon strikes here (detection system isn’t good enough and wave behavior is easier): Heating: Energy absorbed in microwave or by black asphalt. Optics: Light bending through lenses or passing through slits Laser beam: Treat it just like a beam of light… (Understanding the working principle of a laser requires photon picture.) Properties of photons The energy of a photon is The wavelength of a photon is The momentum of a photon is The mass of a photon is E = hf λ = c/f = hc/E p = hf/c = E/c m=0 h ≈ 6.626 ·10-34 J·s: Plank constant It sometimes is useful to define h = h/(2π) The energy of a photon is then: E = hf = hω Where’s the photon? Great question! But I can't answer it… It will strike the screen at an undetermined position! 3rd… Next photon strikes. here .. screen If the laser power is 10-19 W, we get only about one photon per second in the beam! (assuming λ ≈ 780 nm) Where's that one photon? Well, we don't know until it strikes the screen. Most photons seem to hit the screen where intensity is high. However: We do observe that more photons strike at the places where the intensity of the laser beam is largest. Important conclusion: The probability to find a photon at a specific location in a beam of light is proportional to the intensity of the beam at that location. Probability and randomness Photon is 3-D-spread-out-little-chunk of an EM wave. Gazillions of electrons in metal: Which one will be kicked out? Can’t tell, but photon uniformly spread out so equal probability everywhere. What if shape of single photon wave looked like this? Gazillion electrons Which one will be kicked out? Answer: Can’t tell, but probability of photon collapse at particular point (kicking out electron) related to intensity of wave (Emax2) How can light behave like a wave (interference etc), but be made up of little chunks (photons) that seem to hit at random places? Which is best answer, and why? (will randomly ask for reasons) If I shoot a photon through the two slits to hit the screen, it… a. cannot hit in the middle, because block is in the way. b. is completely random where it can hit. Has equal chance of hitting anywhere on the screen. c. must hit at the maximum of the interference pattern d. has some chance of being anywhere, but on average better chance of hitting at maximum of the interference pattern e. will hit anywhere it has a straight shot through either slit quantum-wave-interference_en.jar Probability of photon hitting is related to intensity at that location (electric field strength)2~Intensity & proportional to the probability of where photon will hit! Two slit interference standard electric field representation of light field Classical electric field wave pattern describes probability of where photons will be… Higher intensity means higher likelihood that photons will be detected there. If I shoot a photon through the two slits to hit the screen, it has some chance of being detected anywhere on screen, but on average better chance at being where interference pattern in brightest. Double slit experiment at low intensities Randomness in physics??! A completely new concept in QM is that the outcome of a measurement can often times not be predicted precisely. We can only predict the probability of obtaining a certain result! Examples: Where will a photon hit the screen? Well, we don’t know, but the probability is largest where the intensity of the light is largest ∝ (field amplitude)2 Where is the electron in a hydrogen atom? Well, we don’t know, but the probability to find it is largest at the location where the square of the matter wave amplitude is largest. (Matter waves: see TZT chapter 6) (Randomness is negligible for macroscopic objects but important on atomic scale!) Let's revisit the PE effect one last time! What actually happens in the metal when a photon strikes? What happens in the metal? Kicker analogy: Photon is like a kicker in a pit… Puts in energy. All concentrated on one ball/electron. Blue kicker has a fixed strength. Red kicker (photon) kicks less than blue one. Nothing gets out. ‘Photon’ Why do the emitted electrons have different velocities/kinetic energies? ‘Electron’ electrons metal different ‘pit depths’ mgh = energy needed to make it up hill and out. mgh for highest electron analogous to work function. For photons: KE = hf - Φ h What determines the work function ‘Φ’? Different metals Ball emerges with: KE = kick energy - mgh Fixed kick energy: Top ones get out… …bottom ones don’t. PE effect: Apply Conservation of Energy Energy in = Energy out Energy of photon = energy needed to kick Initial KE of electron electron out of metal + as exits metal h platinum, hard to kick out large work function ⇔ deep pit PE effect: Apply Conservation of Energy Electron Potential Energy Energy in = Energy out Energy of photon = energy needed to kick + Initial KE of electron electron out of metal as exits metal What happens if send in bunch of blue photons? Ephoton work function (Φ) Outside metal Photon gives electron “kick of energy”. Inside metal All electrons have about equal chance of absorbing photon: Max KE of electrons = photon energy - Φ Min KE = 0 Some electrons, not enough energy to pop-out, energy into heat. Electron Potential Energy sodium- easy to kick out small work function ⇔ shallow pit Loosely stuck electron, takes least energy to kick out Φ work function (Φ) = energy needed to kick Outside metal Inside metal highest electron out of metal Tightly stuck, needs more energy to escape Electrons over large range of energy have about equal chance of absorbing photons. Say you shine blue light on Ephot a metal plate the metal emits n electrons per sec. Ephot Electron potential energy h work function Φ Inside metal Now you change the frequency to violet light without changing the # of photons per second. What happens to the number of electrons/sec. coming out of the metal? a. fewer electrons b. same # of electrons but electrons are faster c. more electrons d. not enough information Electrons over large range of energy have equal chance of absorbing photons. Typical energies elect. potential energy photoelectric_en.jar Photon Energies: Each photon has: Energy = Planks constant * Frequency (Energy in Joules) Ephot (Energy in eV) E=hf=(6.626*10-34 J-s)*(f s-1) E=hc/λ = (1.99*10-25 J-m)/(λ m) work function Φ Red Photon: 650 nm metal c. more electrons come out with violet absorb blue light and have enough energy to leave absorb blue light, but don’t come out so the more energy the light has, the more electrons that come out, until so much energy that every electron comes out. (violet and ultraviolet would not be very different in this case) E=hf= (4.14*10-15 eV-s)*(f s-1) E= hc/λ = (1240 eV-nm)/(λ nm) Ephoton = 1240 eV-nm = 1.91 eV 650 nm Work functions of metals (in eV): Aluminum 4.08 eV Cesium 2.1 Lead 4.14 Potassium 2.3 Beryllium 5.0 eV Cobalt 5.0 Magnesium 3.68 Platinum 6.35 Cadmium 4.07 eV Copper 4.7 Mercury 4.5 Selenium 5.11 Calcium Carbon 2.9 4.81 Gold Iron 5.1 4.5 Nickel Niobium 5.01 4.3 Silver Sodium 4.73 2.28 Uranium 3.6 Zinc 4.3 Photomultiplier tubes: An application of photoelectric effect. Most sensitive way to detect visible light, see single photons (eye is incredibly good too; can see a few photons) Application of the PE effect: The photo multiplier tube (PMT) Metal plate big voltage Electron current electron amplifier: gives pulse of current for each photoelectron 1 2 3 4 5 Time (millisec) What would be the best choice of these materials to detect visible light? a. Platinum Φ = 6.35 eV b. Magnesium = 3.68 eV c. Nickel = 5.01 eV d. lead = 4.14 eV e. Sodium = 2.28 eV KE = photon energy-energy to get out = hf – Φ If λ is ½ then, f twice as big, Ephot150 = 2 hf300 V Old KE300 = hf300 - energy to get out New KEnew= 2hf300 - energy to get out so KEnew is more than twice as big. Energy A photon at 300 nm kicks out an electron with a maximum kinetic energy KE300. If the wavelength is halved to 150 nm and the photon hits an electron in the same metal what would be the maximum possible kinetic energy KE150 of an electron kicked out by this 150nm photon? a. less than ½ KE300. b. ½ KE300 c. = KE300 d. 2 x KE300 e. more than 2 x KE300 (remember hill/kicker analogy, draw pictures to reason out answer, don’t just pick answer without careful reasoning) hf150 hf300 KE300 KE300 KE300 V Shine in light of 300 nm. The most energetic electrons come out with kinetic energy, KE300. A voltage difference of 1.8 V is required to stop these electrons. What is the work function Φ for this plate? (e.g. the minimum amount of energy needed to kick electron out of metal?) a. 1.2 eV b. 1.8 eV c. 4.1 eV d. 5.9 eV e. none of the above Remember: The energy of a photon is hf (= hc/λ). In units of eV you can write: E= hc/λ = (1240 eV-nm)/(λnm) (Your answer should be within ~0.1eV) V CQ: Shine in light of 300 nm, most energetic electrons come out with kinetic energy, KE300. A voltage diff of 1.8 V is required to stop these electrons. What is the work function Φ for this plate? (e.g. the minimum amount of energy needed to kick e out of metal?) Energy is conserved so: a. 1.2 eV b. 2.9 eV Ephot= energy need to exit (Φ) + electron’s left over energy c. 6.4 eV d. 11.3 eV so Φ = Ephot – electron’s energy e. none of When electron stops, all of initial KE has been the above converted to electrostatic potential energy: electron energy = q*∆V = e x 1.8V = 1.8 eV, and Ephot = 1240 eV nm/300 nm = 4.1 eV. So Φ = 4.1eV - 1.8 eV = 2.3 eV Remember this picture? This is the end of our discussion about the PE effect Questions? Scanning tunneling microscope (STM) Measure current between tip and sample Electrons are wave packets too! The probability to find an electron that is trapped inside this ring of atoms is highest at the place, where the square of the amplitude of the electron wave function is largest. To all those students feeling confused now: You should be bothered and ask questions! QM can be kind of confusing in the beginning. QM: Fundamental change in the way to think about physics: Which slit did this photon go through? a. left b. right c. both d. neither e. either left or right we just cannot know which one Before (pre 1900, Physics I and II) -- everything could be known exactly, if measured and calculated carefully enough. Now-- physics behavior is fundamentally inexact. Talks only about probability; Can only predict probabilities for what will happen in a measurement. Einstein didn’t accept this fact for long! And he certainly was a pretty bright fellow! Today we fully accept the QM description of small things (This was not the case at first!) Photon before it goes through the slits Which slit did this photon go through? a. left b. right c. both! d. neither Photon as little segment of wave moving towards slits If one slit: Get single slit pattern (i.e. no interference) But: that photon is part of the two slit interference pattern, the probability pattern of where it lands is described by the 2 slit interference pattern, it must have gone through both slits i. e. as a wave! When it interacts with the screen it behaves particle-like! Intensity of wave in various places, indicates probability of finding the photon there if you looked at that moment. quantum-wave-interference_en.jar Photon after it went through the slits Photon after it goes through the slits When photon interacts with an electron or atom, all energy ends up in one spot… Behaves like a particle with energy = hc/λ Photon is a wave… It can interfere with itself. Photon is a wave… It can interfere with itself. Intensity of wave in various places indicates the probability of the photon concentrating at that spot if you had detector (e.g. a bunch of atoms or a sheet of metal) Intensity of wave in various places indicates probability of the photon concentrating at that spot if you had detector (e.g. a bunch of atoms or a sheet of metal) Which slit did this photon go through? a. left b. right c. both d. neither e. either left or right we just cannot know which one Which slit did this photon go through? If one slit: Get single slit pattern (i.e. no interference) Like this: or this: but not like this: But: that photon is part of the two slit interference pattern. The probability pattern of where it lands is described by the 2 slit interference pattern (the photon has to ‘know’ about both slits!) It must have gone through both slits, i. e. as a wave! (When it interacts with the screen it behaves particle-like!) quantum-wave-interference_en.jar Photon before it goes through the slits Photon as little segment of wave moving towards slits Photon after it went through the slits Still only one photon! (But this photon has a slightly complicated wave function.) Photon is a wave… It can interfere with itself. Intensity of wave in various places, indicates probability of finding the photon there if you looked at that moment. Photon after it went through the slits When photon interacts with an electron or atom, all energy ends up in one spot… Behaves like a particle with energy = hc/λ Intensity of wave in various places indicates the probability of finding the photon at that spot, if I had detector there (e.g. a bunch of atoms or a sheet of metal) Probability of photon hitting is related to intensity at that location (electric field strength)2 ~ Intensity & proportional to the probability of where photon will hit! standard electric field representation of light field Classical electric field wave pattern describes probability of where photons will be… Higher intensity means higher likelihood that photons will be detected there. If I shoot a photon through the two slits to hit the screen, it has some chance of being detected anywhere on screen, but on average better chance at being where interference pattern is brightest. Two slit interference Double slit experiment at low intensities Randomness in physics??! Remember this picture? A completely new concept in QM is that the outcome of a measurement can often times not be predicted precisely. We can only predict the probability of obtaining a certain result! Examples: Where will a photon hit the screen? Well, we don’t know, but the probability is largest where the intensity of the light is largest ∝ (field amplitude)2 Where is the electron in a hydrogen atom? Well, we don’t know, but the probability to find it is largest at the location where the square of the matter wave amplitude is largest. (Matter waves: see TZT chapter 6) (Randomness is negligible for macroscopic objects but important on atomic scale!) Scanning tunneling microscope (STM) Measure current between tip and sample Electrons are wave packets too! The probability to find an electron that is trapped inside this ring of atoms is highest at the place, where the square of the amplitude of the electron wave function is largest. To all those students feeling confused now: You should be bothered and ask questions! QM can be kind of confusing in the beginning. QM: Fundamental change in the way to think about physics: Before (pre 1900, Physics I and II) -- everything could be known exactly, if measured and calculated carefully enough. Questions? Now-- physics behavior is fundamentally inexact. Talks only about probability; Can only predict probabilities for what will happen in a measurement. Einstein didn’t accept this fact for long! And he certainly was a pretty bright fellow! Today we fully accept the QM description of small things (This was not the case at first!) What’s next? Atoms and atomic spectra! What happens if we bash atoms with electrons? In atomic discharge lamps, lots of electrons are given kinetic energy (accelerated by a high voltage). When they bash into atoms some of this kinetic energy is transferred to the atom Atom get's excited!! (“Neon” lights, Mercury street lamps) 120V Cathode (hot metal, so Anode (positive potential) electrons can come out) Hydrogen Na Hydrogen neon neon neon Hydrogen White light = whole spectrum. Each type of atom produces unique set of colors, called its “spectrum”. None of the atoms produces white light! Na Na Na NaNa Hg Hg Hg Hg Hg Hold grating only by edges...oil from hands ruins grating! Hold close to eye... See rainbow from lights. Turn grating so rainbow is horizontal. (Rainbow appears quite a bit to the side of the actual lamp. What colors from white light? What colors from neon? What colors from hydrogen? What from mercury? What from sodium? Hydrogen Hydrogen Hydrogen Use a grating to look at the spectrum of the discharge lamps 400 500 600 Wavelength (nanometers) 700 800 increasing energy What do the vertical arrows represent? allowed energies increasing energy allowed energies ground state ground state a. arrows on right represent absorption of light, arrows on left represent emission. b. arrows on both left and right represent emission c. arrows on both left and right represent absorption d. arrows on left represent absorption of light, arrows on right represent emission. e. I don’t know. I have never seen such a diagram. Announcements d. arrows on left represent absorption of light, arrows on right represent emission. Atoms and Atomic spectra • Reading for Friday: 5.8 – 5.10 • What are atoms made off? JELL–O? • Interested in becoming an LA, or simply interested in free food? Go to UMC, Room 235 tonight at 6pm. • What happens when we hit atoms with various stuff? Early ideas about atoms invisible! • Atom - Greek “indivisible unit” • The Blueberry-Muffin-Atom-Model (aka. ‘The Thomson model’): Uniform distribution of positive charges with negative electrons embedded in it. But wait! We can get electrons from them (scraping, chemical, or photoeffect) but no positive charges. Hmmm?!... - • How do atoms interact with light? Develop model of how light interacts with and is produced by individual atoms (Helps us learn how atoms ‘work’) Step 1: Shoot the JELL–O atom! Have a heavy blob that seems like grape JELL–O, and you have gun with rubber bullets. How to find out what the middle of the blob is like? Have a heavy blob that seems like grape JELL-O, and you have gun with rubber bullets. How to find out what the middle of the blob is like? Shoot bunch of bullets into it and see this. Have a heavy blob that seems like grape JELL-O, and you have gun with rubber bullets. How to find out what the middle of the blob is like? Shoot bunch of bullets into it and see this. What is the inside like? Hard heavy core surrounded by JELLO Only one thing is reflecting bullets, sending them straight back so must be hard and heavy. Essentially Rutherford experiment and conclusion (TZD 3.12). Rutherford shot alpha particles = 2 protons, 2 neutrons n pn Positive charge Bullets = p What is the inside like? The Rutherford experiment The Rutherford atom: Tiny nucleus with protons and neutrons (~99.99% of mass) Surrounded by large diffuse cloud of low mass electrons 10-10 m Detector n n pnp p p n p 10-14 m rutherford-scattering_en.jar The ‘Rutherford atom’ is a much better model than the ‘Thomson model’, but it is still far from helpful. A good model should: • explain how stuff works • predict the behavior of it • be quantitative • etc. Need a better model! Let’s see how atoms behave when shot-at! (with (with electrons) electrons) What happens if we bash atoms with electrons? Use a grating to look at the spectrum of the discharge lamps In atomic discharge lamps, lots of electrons are given kinetic energy (accelerated by a high voltage). When they bash into atoms some of this kinetic energy is transferred to the atom Atom get's excited!! (“Neon” lights, Mercury street lamps) - 120V + Cathode (hot metal, so electrons can come out) Hold grating only by edges...oil from hands ruins grating! Hold close to eye... See rainbow from lights. Turn grating so rainbow is horizontal. (Rainbow appears quite a bit to the side of the actual lamp. Anode (positive potential) Note: ‘Anode’ and ‘Cathode’ have different meanings in physics or chemistry. Remember ‘Cathode Ray Tube’ (CRT): Electrons leave the cathode (in physics). Hydrogen White light = whole spectrum. Each type of atom produces unique set of colors, called its “spectrum”. None of the atoms produces white light! Na Hydrogen neon neon neon Hydrogen Each type of atom produces unique set of colors. Discussion: What does this imply about electrons in atoms? Implies that electrons only change between very specific energies. Each time a photon is emitted an electron must be changing in energy by that amount (releasing energy). Only way for individual atoms to give off energy is as light. Atoms are lazy - always want to go back to lowest energy state. 2. Excited atom ..electron 3. Electron 1. Fast electron in atom goes to higher jumps back to hits atom energy Less KE low energy Na Na Na NaNa Hydrogen Hydrogen Hydrogen Hg Hg Hg Hg Hg What colors from white light? What colors from neon? What colors from hydrogen? What from mercury? What from sodium? 400 500 600 Wavelength (nanometers) 700 800 e Higher energy e e e e e Energy Energy level diagrams represent energy levels the electron can go to. Different height = different energy e ~10ns Excited state Ground state e An single electron bashes into an atom in a discharge lamp d 10 V D e For Hydrogen, transitions to ground state in deep ultraviolet! No light emitted with colors in this region because no energy levels spaced with this energy. -2 eV -3 eV -6 eV If atom fixed at this point in tube, -10eV list all the possible photon energies (colors) that you might see? A. 1eV, 2eV, 3eV, 4eV, 7eV, 8eV B. 4eV, 7eV, 8eV C. 1eV, 3eV, 4eV D. 4eV E. Impossible to tell. Electron energy = q∆V = e(Ed), where E is the electric field = (battery V)/(total distance D), and d is the distance it goes before a collision. An single electron bashes into an atom in a discharge lamp An single electron bashes into an atom in a discharge lamp -2 eV -3 eV - 10 V + d - 10 V + D -6 eV -6 eV If atom fixed at this point in tube, -10eV list all the possible photon energies (colors) that you might see? A. 1eV, 2eV, 3eV, 4eV, 7eV, 8eV B. 4eV, 7eV, 8eV C. 1eV, 3eV, 4eV D. 4eV E. Impossible to tell. -10eV If atom fixed at this point in tube, list all the possible photon energies (colors) that you might see? A. 1eV, 2eV, 3eV, 4eV, 7eV, 8eV B. 4eV, 7eV, 8eV C. 1eV, 3eV, 4eV D. 4eV E. Impossible to tell. -2 eV -3 eV Electron energy = q∆V = e(Ed), where E is the electric field = (battery V)/(total distance D), and d is the distance it goes before a collision. Remember the ‘Electron Volt’ (eV)? Some handy relations: Current flowing through a wire: Define new energy unit: The electron-volt (eV) 1eV = kinetic energy gained/lost by an electron when accelerated/decelerated by traversing an area with 1 Volt potential difference (such as in a plate capacitor) 1 Ampere = 1 Coulomb / Second 1 Watt = 1 Ampere · 1 Volt = 1 C/s · 1 V 1 Joule = 1 Watt · 1 Second = 1 C · 1 V 1eV ≈ 1.6 ·10-19 J 0V F E path 1V + + + + 1C 0V What we know so far: Rutherford: Atoms have a tiny, but heavy core surrounded by a cloud of electrons. Discharge lamps: Atoms struck by fast electrons emit light of distinct colors. Energy levels: Electrons in atoms are found only in discrete energy levels. When they jump down to a lower level, a photon is emitted carrying away the energy. i.e: An electric potential of 1 V puts in one Joule of energy into a charge of 1 C kinetic energy increases by 1 Joule. 1V + + + + An e- has a charge of 1.6·10-19C, therefore, it gains a kinetic energy of 1eV=1.6·10-19J Investigate energy levels in atoms p n nn p p p nn nn p 120V ∆E ∆E=hf e Different Atoms: Different types of atoms have different level structures (seen by the distinct set of colors they emit): Neon: Strong red line; Sodium: strong yellow line … energy levels of electron stuck in atom 3 energy 2 of colliding 1 electron G (ground) If the colliding electrons have an energy between that of level 2 and level 3 when they hit the atom how many different colors could be emitted by the atom? a. no levels will be excited, and so no light will come out. b. 1 color of light will come out c. 2 colors of light will come out d. 3 colors of light will come out e. 4 colors come out. ans. d. enough energy to excite level 2, then get 2⇒ ⇒1 followed by 1⇒ ⇒G, but also can go 2⇒ ⇒G. A neon lamp emits a strong red line. Sodium emits a strong yellow line. What accounts for this difference? a. The electrons in the discharge lamp hit the neon atoms with higher kinetic energy than the electrons hit the sodium atoms b. The electrons in the discharge lamp hit the neon atoms with less speed than the electrons hit the sodium atoms c. The energy spacing between the electronic energy levels that are responsible for these lines are smaller in the neon atom than in the sodium atom. d. The energy spacing between the electronic energy levels that are responsible for these lines is larger in the neon atom than in the sodium atom. Applications of atomic spectroscopy When an emission line appears very bright that means: 1. Detecting what kind of atoms are in a material. (excite by putting in discharge lamp or heating in flame to see spectral lines) a. Multiple photons are emitted for each single electron transition b. More electron transitions are occurring each second c. The electronic energy levels are farther apart and thus the line appears brighter d. a and b e. b and c Application: Designing a better light What is important? (Well, we have to be able to see the light!) What color(s) do you want? ( Choice of atom) How do you excite them to desired level? ( Electron collisions) How to get electrons with desired energy when hit atoms? What determines energy of electrons? 2. Detecting what the sun and the stars are made of: Look at the light from a star through a diffraction grating. See what lines there are; Match up to atoms on earth. telescope star diffraction grating 3. Making much more efficient lights! Incandescent light bulbs waste >90% of the electrical energy that goes into them! (<10% efficient) Streetlight discharge lamps (Na or Hg) ~80% efficient. Fluorescent lights ~ 40-60% efficent. Incandescent light (hot filament) Temperature = 2500-3000K Hot electrons jump between many very closely spaced levels (solid metal). Produce all colors. Mostly infrared at temp of normal filament. >90% is worthless Infrared radiation (IR = longer than ~700nm) IR P λ ~10% of energy is useful visible light Discharge lamp Energy levels in isolated atom: Only certain wavelengths emitted. HV Right atom, right pressure and voltage, mostly visible light. Streetlight discharge lamps (Na or Hg) 80% efficient. Florescent Lights. Discharge lamp, White= Red + green +blue 40-60% efficient (electrical power⇒visible light) Florescent Lights. Discharge lamp, but want to have it look white. White = red + green +blue 40-60% efficient (electrical power ⇒ visible light) Converting 180nm UV light into visible photons with “phosphor”. How to do this? phosphor coating Converting UV light into visible photons with “phosphor”. Phosphor converts 180 nm UV to red+ green+blue. Hg 180nm 6.9 eV energy per photon 633nm (red) 2 eV / photon 532nm (green) 2.3 eV / photon 475nm (blue) 2.6 eV / photon 180 nm far UV Hg } 6.9 eV Hg Hg Hg e Hg discharge lamp/flor. tube 120 V real phosphors more than just 3 phosphor wastes 20-30% energy ⇒ heat Summary of important Ideas 1) Electrons in atoms are found at specific energy levels 2) Different set of energy levels for different atoms 3) one photon emitted per electron jump down between energy levels. Photon color determined by energy difference. 4) If electron not bound to an atom: Can have any energy. (For instance free electrons in the PE effect.) Hydrogen Lithium Energy Electron energy levels in 2 different atoms: Levels have different spacing (explains unique colors for each type of atom. (not to scale) Atoms with more than one electron … lower levels filled. Now we know about the energy levels in atoms. But how can we calculate/predict them? Need a model Step 1: Make precise, quantitative observations! Step 2: Be creative & come up with a model. Step 3: Put your model to the test. energy of electron in phosphor molecule phosphor wastes 20-30% energy ⇒ heat Quiz on the reading (no talking and closed book) The Rydberg formula describes a. the colors of light emitted from all types of atoms. b. the angular distribution of particles scattering off of atoms that Rutherford observed in his famous experiment. c. the colors of light emitted by hydrogen atoms. d. the energy distribution of cathode rays e. the frequencies of light emitted by helium atoms. Balmer series: A closer look at the spectrum of hydrogen 656.3 nm 410.3 486.1 434.0 Balmer (1885) noticed wavelengths followed a progression λ= 91.19nm 1 1 − 22 n 2 where n = 3,4,5, 6, …. As n gets larger, what happens to wavelengths of emitted light? λ gets smaller and smaller, but it approaches a limit. Balmer series: A closer look at the spectrum of hydrogen Hydrogen atom – Rydberg formula Does generalizing Balmer’s formula work? Yes! It correctly predicts additional lines in HYDROGEN. Rydberg’s general formula 656.3 nm 410.3 486.1 434.0 Balmer (1885) noticed wavelengths followed a progression So this gets smaller λ= Balmer correctly predicted yet undiscovered spectral lines. 91.19nm where n = 3,4,5,6, …. 1 1 − 2 2 2 n gets smaller as n increase gets larger as n increase, but no larger than 1/4 λlimit = 4 * 91.19nm = 364.7nm Predicts λ of n m transition: n (n>m) m (m=1,2,3..) m=1, n=2 λ gets smaller and smaller, but it approaches a limit Hydrogen atom – Lyman Series Rydberg’s formula λ= 91.19nm 1 1 − 2 2 m n Hydrogen energy levels Balmer-Rydberg formula λ= 0eV Can Rydberg’s formula tell us what ground state energy is? (n>m) 0eV 91.19nm 1 1 − 2 2 m n 0 0eV Einitial − E final = m Hydrogen energy levels Look at energy for a transition between n=infinity and m=1 Predicts λ of n m transition: n Hydrogen energy levels 91.19nm λ= 1 1 − 2 2 2 m2 n (m=1,2,3..) m=1 -?? eV Balmer/Rydberg had a mathematical formula to describe hydrogen spectrum, but no mechanism for why it worked! Why does it work? Hydrogen energy levels − E final = hc λ = hc 1 1 2− 2 91.19nm m n 1 hc 91.19nm m 2 Em = −13.6eV -?? eV 1 m2 The Balmer/Rydberg formula is a mathematical representation of an empirical observation. It doesn’t explain anything, really. Balmer’s formula 656.3 nm 410.3 486.1 434.0 λ= How can we calculate the energy levels in the hydrogen atom? 91.19nm 1 1 − 2 2 m n where m=1,2,3 and where n = m+1, m+2 A semi-classical explanation of the atomic spectra (Bohr model) m=1, n=2 Rutherford shot alpha particles at atoms and he figured out that a tiny, positive, hard core is surrounded by negative charge very far away from the core. • One possible model: Atom is like a solar system: electrons circling the nucleus like planets circling the sun… • The problem is that accelerating electrons should radiate light and spiral into the nucleus: A. Well, they do, but very, very slowly. B. Because planets obey quantum mechanics, not classical mechanics. C. Because planets obey classical mechanics, not quantum mechanics. D. Because gravitational forces work differently than electrical forces and there is no such a thing as gravitational radiation. E. Because planets are much bigger than electrons. *Elapsed time: ~10-11 seconds Electrostatic potential energy Nucleus - Higher Energy Potential energy of the electron in hydrogen D F + Electron ++ ++ Why don't planets spiral into the sun? - Energy levels Force on electron is less, but Potential Energy is higher! Electrons at higher energy levels are further from the nucleus! Potential energy of a single electron in an atom PE of an electron at distance D from the proton is PE = − ke 2 D Coulomb’s constant D D ∞ ∞ potential energy 0 distance from proton kqelect q prot r2 dr D D 1 dr ke 2 =− PE = kqelect q prot ∫ 2 = kqelect q prot r r∞ D ∞ -e e (k = 1/( 4πε0 ): Coulomb force const.) (for hydrogen) How can we calculate the energy levels in hydrogen? λ= , ke2 = 1.440eV·nm PE = -ke(Ze) + + + D + (For Z protons) E r We define electron’s PE as 0 when far, far away from the proton! Electron's PE = -work done by electric field from r1=∞…r2=D ∫ F • dr = ∫ When an electron moves to location further away from the nucleus its energy increases because energy is required to separate positive and negative charges, and there is an increase in the electrostatic potential energy of the electron. - 91.19nm 1 1 − m2 n2 Step 1: Make precise, quantitative observations! Step 2: Be creative & come up with a model. How to avoid the Ka-Boom? *Elapsed time: ~10-11 seconds Bohr Model Bohr's approach: • When Bohr saw Balmer’s formula, he came up with a new model that would predict it and 'solve' the problem of electrons spiraling into the nucleus. • The Bohr model has some problems, but it's still useful. • Why doesn’t the electron fall into the nucleus? #1: Treat the mechanics classical (electron spinning around a proton): – According to classical physics, It should! – According to Bohr, It just doesn’t. – Modern QM will give a satisfying answer, but you’ll have to wait till next week. - Newton's laws assumed to be valid - Coulomb forces provide centripetal acceleration. #2: Bohr's hypothesis (Bohr had no proof for this; he just assumed it – leads to correct results!): - The angular momentum of the electrons is quantized in multiples of ћ. - The lowest angular momentum is ћ. Original paper: Niels Bohr: On the Constitution of Atoms and Molecules, Philosophical Magazine, Series 6, Volume 26, p. 1-25, July 1913.) Bohr Model. # 1: Classical mechanics The centripetal acceleration a = v2 / r is provided by the coulomb force F = k·e2/r2. Bohr Model. #2: Quantized angular momentum F=k e2/r2 v (k = 1/( 4πε0 ): Coulomb force const.) Newton's second law mv2/r = k·e2/r2 or: mv2 = k·e2/r The electron's kinetic energy is KE = ½ m v2 The electron's potential energy is PE = - ke2/r E= KE + PE = -½ ke2/r = ½ PE + E Bohr Model. Results h2 = 52.9 pm , rB: Bohr radius ke 2m En = E R / n 2 , with E R = F=k e2/r2 v rn = rB n 2 , with rB = h2 = 52.9 pm ke 2m En = E R / n 2 , with E R = , rB: Bohr radius m( ke 2 ) 2 = 13.6 eV , ER: Rydberg 2 Energy 2h Only discrete energy levels possible. Electrons hop down towards lowest level, giving off photons during the jumps. Atoms are stable in lowest level. 0 distance from proton 2 2 m( ke ) = 13.6 eV , ER: Rydberg Energy 2h 2 The Bohr model not only predicts a reasonable atomic radius rB, but it also predicts the energy levels in hydrogen to 4 digits accuracy! Possible photon energies: Bohr assumed that the angular momentum of the electron could only have the quantized values of: L= nћ And therefore: mvr = nћ, (n=1,2,3…) or: v = nћ/(mr) Substituting this into mv2 = k·e2/r leads to: Therefore: If we know r, we know E and v, etc… r = rB n 2 , with rB = ћ = h/2π 1 1 Eγ = En − Em = E R 2 − 2 n m (n > m) The Bohr model 'explains' the Rydberg formula!! potential energy Bohr couldn't explain why the angular momentum is quantized but his model lead to the Rydberg-Balmer Lmin = h formula, which matched to the experimental observations very well! He also predicted atomic radii reasonably well and was able to calculate the Rydberg constant. Successes of Bohr Model Shortcomings of the Bohr model: • 'Explains' source of Balmer formula and predicts empirical constant R (Rydberg constant) from fundamental constants: R=1/91.2 nm=mk2e4/(4πch3) Explains why R is different for different single electron atoms (called hydrogen-like ions). • Predicts approximate size of hydrogen atom • Explains (sort of) why atoms emit discrete spectral lines • Explains (sort of) why electron doesn’t spiral into nucleus • Why is angular momentum quantized yet Newton’s laws still work? • Why don’t electrons radiate when they are in fixed orbitals yet Coulomb’s law still works? • No way to know a priori which rules to keep and which to throw out… • Can't explain shapes of molecular orbits and how bonds work • Can’t explain doublet spectral lines Questions? Which of the following principles of classical physics is violated in the Bohr model? A. B. C. D. E. Opposite charges attract with a force inversely proportional to the square of the distance between them. The force on an object is equal to its mass times its acceleration. Accelerating charges radiate energy. Particles always have a well-defined position and momentum. All of the above. Ideas for how to resolve these problems? Matter waves: TZD Chapter 6 Note that both A & B are used in derivation of Bohr model. What’s so special about LASER light? A) It doesn't diffract when it goes through two slits. B) It can be collimated very well. C) The photons in the laser beam travel a little bit faster because they all go the same direction. D) Laser light is pure quantum light, and therefore, cannot be described with classical EM theory. E) Laser light is purely classical light, and therefore, it is incompatible with the photon picture. What’s so special about LASER light? Remember the word 'coherence'? (We used it occasionally in context with interferometers, diffraction and with photons.) There are two types of coherence: - Spatial coherence - Temporal coherence LASERs produce light with excellent spatial and temporal coherence. Spatial coherence Temporal coherence Collimating lens Flashlight (incoherent) Flashlight (incoherent) 'Mach-Zehnder' interferometer c ·τ 1 Laser (coherent) Laserpointer (coherent) c ·τ 2 For very stable lasers: (τ1- τ2)max ~ 1 second. (This corresponds to 300’000 km path difference!) Remember this one (from class 3): Let's make a coherent light pulp! Bad: Throw away most of the light and individual photons still have random phases φ E-field (for a single color): E(x,t) = A0 sin(ωt+(x ·ω)/c +φ) LASER ω = 2πf E λ A0 φ x Temporal coherence: ω and φ are very well defined constants (i.e. time independent). How can we make identical photons? Aperture Color filter (passes only certain colors, ω) Remember: Coherent light requires that ω and φ are constants. How light interacts with atoms e out Clone them! 2 1 spontaneous emission of light: Excited atom emits one photon. in 2 e 1 absorption of light: Atom absorbs one photon in e 2 out 1 stimulated emission: clone the photon -- A. Einstein Surprising fact. Chance of stimulated emission of excited atom EXACTLY the same as chance of absorption by lower state atom. Critical fact for making a laser. Laser: Stimulated emission to clone photon many times (~1020/s) Light Amplification by Stimulated Emission of Radiation Spontaneous emission Stimulated emission Random phase Random direction Similar energy (as absorbed photon) Legend: Photon Identical phase Identical energy Identical momentum Legend: Atom in ground state Atom in excited state e Photon Atom in ground state e Atom in excited state e e Chance of stimulated emission of excited atom is EXACTLY the same as chance of absorption by ground state atom. Glass tube below contains 9 atoms. Some are excited some not excited (as shown). Light enters the tube on the left: b. less come out right 3 excited atoms can emit photons, 6 ground state atoms can absorb. Absorption wins. For the condition above: what do you expect? a. More photons will come out (on the right) than go in. b. Fewer photons will come out (on the right) than go in. c. Same number as go in, d. None will come out. To increase the number of photons when going through the atoms, more atoms need to be in the upper energy level than in the lower. Need a “Population inversion” (This is the hard part of making laser, b/c atoms jump down so quickly.) Think about statistics / probabilities Ok, if we have 'population inversion' we get 'gain'. But where are these photons coming from? out } Nupper > Nlower, more cloned than eaten. From here! Some fraction of the photons are 'recycled' through the amplifier (feedback!). The rest is used as the laser's output. Nupper < Nlower, more eaten than cloned. This is done with an 'optical resonator/cavity' Optical resonator Semiconductor lasers are tiny! Partially-silvered mirror Mirror out Continuously supply energy to the atoms to maintain population inversion. But others can be fairly ‘involved’ …or very involved… All the energy of this laser is focused into this! (Trigger Nuclear fusion.) How to get population inversion? No population inversion in 2 level atom! e out 1 spontaneous emission of light: Excited atom emits one photon. e A) Use photons with hf < ∆E B) Use photons with hf = ∆E 2 C) Use photons with hf > ∆E D) Use very strong lamp with hf ≈ ∆E. E) Will never get population inversion in this system. 2 e 1 absorption of light: Atom absorbs one photon in e 2 out 1 stimulated emission: clone the photon Equal probability ∆E excited in e not excited Population inversion means: More atoms are in the excited state than in the ground state. As soon as we have the same number of atoms in the excited state as in the ground state, the probability of creating an excited atom is same (or smaller, when considering spontaneous emission) as the probability of having stimulated emission! Can never reach population inversion in 2-level atom! Need at least 3 energy levels! Now, let's play! Use a second color of light to create population inversion 2 2 t2 t1 1 1 t3t1<>t2t2 3 G 2 G t1 < t2 t2 1 “Pumping” process produces population inversion t 1< t 2 G http://phet.colorado.edu/simulations/lasers/lasers.jnlp Various 'flavors' of Lasers Summary Mirror Gas lasers Half-silvered mirror Dye lasers (liquid) out Chemical lasers Solid state lasers Fiber lasers LASERs need: • Population inversion Gain • Optical feedback (optical resonator) Diode lasers Coherent light Gas dynamic lasers … Practically unlimited numbers of applications for lasers Just to name a few: Medicine: Surgery (no bleeding, noncontact eye) Diagnostics (TP-Microscopy, tomography) Machining: Tight focus allows very high intensity. (100 W cut through hardened steel like butter) Science: Huge variety of applications (Ultra precise spectroscopy / light matter interaction...) Commercial: DVD/CD, range finding, leveling telecommunication… Sharks with frickin' laser beams attached to their heads…