SAFETY DATA SHEET Issue Date 05-May-2015 Revision Date 07-Apr-2015 Version 1 1. PRODUCT AND COMPANY IDENTIFICATION Product identifier Product Name NEUTRAL CITRUS DEGREASER Other means of identification Product Code ATP 6881 Recommended use of the chemical and restrictions on use All Purpose Degreaser. Recommended Use Use only as stated on label. Uses advised against Details of the supplier of the safety data sheet Supplier Emergency telephone number Emergency Telephone Alpha Tech Pet, Inc. 119 Russell Street, Suite 21 Littleton, MA 01460 Phone: (800) 222-5537 (Mon - Fri) Chemtrec 1-800-424-9300 2. HAZARDS IDENTIFICATION Classification OSHA Regulatory Status This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200) Acute toxicity - Oral Acute toxicity - Dermal Skin corrosion/irritation Skin sensitization Not classified Not classified Category 3 Category 1 Label elements Emergency Overview Warning Hazard statements Causes mild skin irritation May cause an allergic skin reaction Causes eye irritation Appearance Clear Orange Physical state Liquid Odor Citrus _____________________________________________________________________________________________ Page 1 / 7 ATP 6881 NEUTRAL CITRUS DEGREASER Revision Date 07-Apr-2015 _____________________________________________________________________________________________ Precautionary Statements - Prevention Avoid breathing mist or spray Contaminated work clothing should not be allowed out of the workplace Wear protective gloves Wash hands and any exposed skin thoroughly after handling. Precautionary Statements - Response Specific Treatment (See Section 4 on the SDS) IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing If eye irritation persists: Get medical advice/attention IF ON SKIN: Wash with plenty of soap and water If skin irritation or rash occurs: Get medical advice/attention Wash contaminated clothing before reuse Precautionary Statements - Disposal Dispose of contents to an approved waste facility in accordance with local, state, and federal regulations Hazards not otherwise classified (HNOC) Other Information Unknown Acute Toxicity 0% of the mixture consists of ingredient(s) of unknown toxicity 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name Orange Terpenes Nonylphenol Ethoxylate 2-(2-butoxyethoxy)ethanol Dodecylbenzenesulfonic Acid, Sodium Salt CAS No. 5989-27-5 9016-45-9 112-34-5 68081-81-2 Weight-% 3-7 1-5 1-5 1-5 Trade Secret * * * * *The exact percentage (concentration) of composition has been withheld as a trade secret. 4. FIRST AID MEASURES First aid measures Skin Contact Wash off immediately with plenty of water for at least 15 minutes. If skin irritation persists, call a physician. Wash off immediately with soap and plenty of water. Eye contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes If symptoms persist, call a physician Inhalation Remove to fresh air. If symptoms persist, call a physician. Ingestion Do NOT induce vomiting. Drink plenty of water. Immediate medical attention is not required. Rinse mouth. Self-protection of the first aider Use personal protective equipment as required. Most important symptoms and effects, both acute and delayed Symptoms No Information available. Indication of any immediate medical attention and special treatment needed Note to physicians May cause sensitization of susceptible persons. 5. FIRE-FIGHTING MEASURES Suitable extinguishing media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. _____________________________________________________________________________________________ Page 2 / 7 ATP 6881 NEUTRAL CITRUS DEGREASER Revision Date 07-Apr-2015 _____________________________________________________________________________________________ Unsuitable extinguishing media Caution: Use of water spray when fighting fire may be inefficient. Specific hazards arising from the chemical In the event of fire and/or explosion do not breathe fumes. May cause sensitization by inhalation and skin contact. Thermal decomposition can lead to release of irritating and toxic gases and vapors. Explosion data Sensitivity to Mechanical Impact None. Sensitivity to Static Discharge None. Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Use personal protective equipment as required. Avoid contact with eyes and skin. Personal precautions Environmental precautions Prevent entry into waterways, sewers, basements or confined areas. Do not flush into surface water or sanitary sewer system. Environmental precautions Methods and material for containment and cleaning up Methods for containment Prevent further leakage or spillage if safe to do so. Methods for cleaning up Soak up with inert absorbent material. Pick up and transfer to properly labeled containers. After cleaning, flush away traces with water. Prevent product from entering drains. 7. HANDLING AND STORAGE Precautions for safe handling Use personal protective equipment as required. Ensure adequate ventilation, especially in confined areas. Advice on safe handling Conditions for safe storage, including any incompatibilities Storage Conditions Keep out of the reach of children. Keep container tightly closed. Keep containers tightly closed in a cool, well-ventilated place. Incompatible materials None known based on information supplied. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters This product, as supplied, does not contain any hazardous materials with occupational exposure limits established by the region specific regulatory bodies. Exposure Guidelines Chemical Name 2-(2-butoxyethoxy)ethanol 112-34-5 ACGIH TLV TWA: 10 ppm inhalable fraction and vapor OSHA PEL - NIOSH IDLH - Appropriate engineering controls Engineering Controls Showers, Eyewash stations & Ventilation systems. Individual protection measures, such as personal protective equipment _____________________________________________________________________________________________ Page 3 / 7 ATP 6881 NEUTRAL CITRUS DEGREASER Revision Date 07-Apr-2015 _____________________________________________________________________________________________ Eye/face protection Tight sealing safety goggles. Skin and body protection No special technical protective measures are necessary. Respiratory protection If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved respiratory protection should be worn. Positive-pressure supplied air respirators may be required for high airborne contaminant concentrations. Respiratory protection must be provided in accordance with current local regulations. When using do not eat, drink or smoke. Wash contaminated clothing before reuse. Wear suitable gloves and eye/face protection. General Hygiene 9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Physical state Appearance Odor Liquid Clear Orange Citrus Property pH Melting point/freezing point Boiling point / boiling range Flash point Evaporation rate Flammability (solid, gas) Flammability Limits in Air Upper flammability limit: Lower flammability limit: Vapor pressure Vapor density Specific Gravity Water solubility Solubility in other solvents Partition coefficient Autoignition temperature Decomposition temperature Kinematic viscosity Viscosity Explosive properties Oxidizing properties Values Odor threshold No Information available 7.5 - 8.5 No Information available No Information available None No Information available No Information available No Information available No Information available No Information available No Information available 1.01 completely soluble No Information available No Information available No Information available No Information available No Information available No Information available No Information available No Information available 10. STABILITY AND REACTIVITY Reactivity No data available Chemical stability Stable under recommended storage conditions. Possibility of Hazardous Reactions None under normal processing. Conditions to avoid Extremes of temperature and direct sunlight. Incompatible materials None known based on information supplied. _____________________________________________________________________________________________ Page 4 / 7 ATP 6881 NEUTRAL CITRUS DEGREASER Revision Date 07-Apr-2015 _____________________________________________________________________________________________ Hazardous Decomposition Products None known based on information supplied. 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure No data available Product Information Inhalation No data available. Eye contact No data available. Skin Contact No data available. Ingestion No data available. Chemical Name Orange Terpenes 5989-27-5 Nonylphenol Ethoxylate 9016-45-9 2-(2-butoxyethoxy)ethanol 112-34-5 Dodecylbenzenesulfonic Acid, Sodium Salt 68081-81-2 Sodium Xylene Sulfonate 1300-72-7 Oral LD50 = 4400 mg/kg ( Rat ) Dermal LD50 > 5 g/kg ( Rabbit ) = 1310 mg/kg ( Rat ) = 2590 mg/kg = 1780 µL/kg ( Rabbit ) = 2 mL/kg ( ( Rat ) Rabbit ) = 3384 mg/kg ( Rat ) = 2700 mg/kg ( Rabbit ) Inhalation LC50 - > 1000 mg/kg ( Rat ) > 2000 mg/kg ( Rat ) - = 1000 mg/kg ( Rat ) - - Information on toxicological effects Symptoms No Information available. Delayed and immediate effects as well as chronic effects from short and long-term exposure Sensitization Germ cell mutagenicity Carcinogenicity No Information available. No Information available. This product contains one or more substances which are classified by IARC as carcinogenic to humans (Group I), probably carcinogenic to humans (Group 2A) or possibly carcinogenic to humans (Group 2B). Chemical Name ACGIH IARC Orange Terpenes Group 3 5989-27-5 IARC (International Agency for Research on Cancer) Not classifiable as a human carcinogen OSHA (Occupational Safety and Health Administration of the US Department of Labor) X - Present Reproductive toxicity STOT - single exposure STOT - repeated exposure Chronic toxicity Aspiration hazard NTP - OSHA X No Information available. No Information available. No Information available. Repeated contact may cause allergic reactions in very susceptible persons. Avoid repeated exposure. No Information available. Numerical measures of toxicity - Product Information 0% of the mixture consists of ingredient(s) of unknown toxicity Unknown Acute Toxicity The following values are calculated based on chapter 3.1 of the GHS document . 12. ECOLOGICAL INFORMATION Ecotoxicity _____________________________________________________________________________________________ Page 5 / 7 ATP 6881 NEUTRAL CITRUS DEGREASER Revision Date 07-Apr-2015 _____________________________________________________________________________________________ 6% of the mixture consists of components(s) of unknown hazards to the aquatic environment Chemical Name Orange Terpenes 5989-27-5 Algae/aquatic plants - Crustacea - - Fish 0.619 - 0.796: 96 h Pimephales promelas mg/L LC50 flow-through 35: 96 h Oncorhynchus mykiss mg/L LC50 5: 96 h Fish mg/L LC50 Nonylphenol Ethoxylate 9016-45-9 2-(2-butoxyethoxy)ethanol 112-34-5 100: 96 h Desmodesmus subspicatus mg/L EC50 1300: 96 h Lepomis macrochirus mg/L LC50 static 100: 48 h Daphnia magna mg/L EC50 2850: 24 h Daphnia magna mg/L EC50 - Persistence and degradability No Information available. Bioaccumulation No Information available. Other adverse effects No Information available 13. DISPOSAL CONSIDERATIONS Waste treatment methods Disposal of wastes Disposal should be in accordance with applicable regional, national and local laws and regulations. Contaminated packaging Do not reuse container. 14. TRANSPORT INFORMATION DOT Not regulated 15. REGULATORY INFORMATION International Inventories TSCA DSL/NDSL EINECS/ELINCS AICS Complies Complies Complies Complies Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances AICS - Australian Inventory of Chemical Substances US Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 Chemical Name 2-(2-butoxyethoxy)ethanol - 112-34-5 SARA 311/312 Hazard Categories Acute health hazard SARA 313 - Threshold Values % 1.0 Yes _____________________________________________________________________________________________ Page 6 / 7 ATP 6881 NEUTRAL CITRUS DEGREASER Revision Date 07-Apr-2015 _____________________________________________________________________________________________ No No No No Chronic Health Hazard Fire hazard Sudden release of pressure hazard Reactive Hazard CWA (Clean Water Act) This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) CERCLA This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level pertaining to releases of this material US State Regulations California Proposition 65 This product does not contain any Proposition 65 chemicals U.S. State Right-to-Know Regulations Chemical Name 2-(2-butoxyethoxy)ethanol 112-34-5 New Jersey X Massachusetts - Pennsylvania X U.S. EPA Label Information EPA Pesticide Registration Number Not Applicable 16. OTHER INFORMATION NFPA Health hazards 2 Flammability 0 Instability 0 HMIS Health hazards 2 Flammability 0 Physical hazards 0 Physical and Chemical Properties Yes Personal protection N/A 05-May-2015 Issue Date 07-Apr-2015 Revision Date Revision Note No Information available Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet _____________________________________________________________________________________________ Page 7 / 7