safety data sheet

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SAFETY DATA SHEET
Issue Date 05-May-2015
Revision Date 07-Apr-2015
Version 1
1. PRODUCT AND COMPANY IDENTIFICATION
Product identifier
Product Name
NEUTRAL CITRUS DEGREASER
Other means of identification
Product Code
ATP 6881
Recommended use of the chemical and restrictions on use
All Purpose Degreaser.
Recommended Use
Use only as stated on label.
Uses advised against
Details of the supplier of the safety data sheet
Supplier
Emergency telephone number
Emergency Telephone
Alpha Tech Pet, Inc.
119 Russell Street, Suite 21
Littleton, MA 01460
Phone: (800) 222-5537 (Mon - Fri)
Chemtrec 1-800-424-9300
2. HAZARDS IDENTIFICATION
Classification
OSHA Regulatory Status
This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)
Acute toxicity - Oral
Acute toxicity - Dermal
Skin corrosion/irritation
Skin sensitization
Not classified
Not classified
Category 3
Category 1
Label elements
Emergency Overview
Warning
Hazard statements
Causes mild skin irritation
May cause an allergic skin reaction
Causes eye irritation
Appearance Clear Orange
Physical state Liquid
Odor Citrus
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Precautionary Statements - Prevention
Avoid breathing mist or spray
Contaminated work clothing should not be allowed out of the workplace
Wear protective gloves
Wash hands and any exposed skin thoroughly after handling.
Precautionary Statements - Response
Specific Treatment (See Section 4 on the SDS)
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
If eye irritation persists: Get medical advice/attention
IF ON SKIN: Wash with plenty of soap and water
If skin irritation or rash occurs: Get medical advice/attention
Wash contaminated clothing before reuse
Precautionary Statements - Disposal
Dispose of contents to an approved waste facility in accordance with local, state, and federal regulations
Hazards not otherwise classified (HNOC)
Other Information
Unknown Acute Toxicity
0% of the mixture consists of ingredient(s) of unknown toxicity
3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name
Orange Terpenes
Nonylphenol Ethoxylate
2-(2-butoxyethoxy)ethanol
Dodecylbenzenesulfonic Acid, Sodium Salt
CAS No.
5989-27-5
9016-45-9
112-34-5
68081-81-2
Weight-%
3-7
1-5
1-5
1-5
Trade Secret
*
*
*
*
*The exact percentage (concentration) of composition has been withheld as a trade secret.
4. FIRST AID MEASURES
First aid measures
Skin Contact
Wash off immediately with plenty of water for at least 15 minutes. If skin irritation persists,
call a physician. Wash off immediately with soap and plenty of water.
Eye contact
Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes If
symptoms persist, call a physician
Inhalation
Remove to fresh air. If symptoms persist, call a physician.
Ingestion
Do NOT induce vomiting. Drink plenty of water. Immediate medical attention is not required.
Rinse mouth.
Self-protection of the first aider
Use personal protective equipment as required.
Most important symptoms and effects, both acute and delayed
Symptoms
No Information available.
Indication of any immediate medical attention and special treatment needed
Note to physicians
May cause sensitization of susceptible persons.
5. FIRE-FIGHTING MEASURES
Suitable extinguishing media
Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.
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Unsuitable extinguishing media Caution: Use of water spray when fighting fire may be inefficient.
Specific hazards arising from the chemical
In the event of fire and/or explosion do not breathe fumes. May cause sensitization by inhalation and skin contact. Thermal
decomposition can lead to release of irritating and toxic gases and vapors.
Explosion data
Sensitivity to Mechanical Impact None.
Sensitivity to Static Discharge None.
Protective equipment and precautions for firefighters
As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full
protective gear.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Use personal protective equipment as required. Avoid contact with eyes and skin.
Personal precautions
Environmental precautions
Prevent entry into waterways, sewers, basements or confined areas. Do not flush into
surface water or sanitary sewer system.
Environmental precautions
Methods and material for containment and cleaning up
Methods for containment
Prevent further leakage or spillage if safe to do so.
Methods for cleaning up
Soak up with inert absorbent material. Pick up and transfer to properly labeled containers.
After cleaning, flush away traces with water. Prevent product from entering drains.
7. HANDLING AND STORAGE
Precautions for safe handling
Use personal protective equipment as required. Ensure adequate ventilation, especially in
confined areas.
Advice on safe handling
Conditions for safe storage, including any incompatibilities
Storage Conditions
Keep out of the reach of children. Keep container tightly closed. Keep containers tightly
closed in a cool, well-ventilated place.
Incompatible materials
None known based on information supplied.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Control parameters
This product, as supplied, does not contain any hazardous materials with occupational
exposure limits established by the region specific regulatory bodies.
Exposure Guidelines
Chemical Name
2-(2-butoxyethoxy)ethanol
112-34-5
ACGIH TLV
TWA: 10 ppm inhalable fraction
and vapor
OSHA PEL
-
NIOSH IDLH
-
Appropriate engineering controls
Engineering Controls
Showers, Eyewash stations & Ventilation systems.
Individual protection measures, such as personal protective equipment
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Eye/face protection
Tight sealing safety goggles.
Skin and body protection
No special technical protective measures are necessary.
Respiratory protection
If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved
respiratory protection should be worn. Positive-pressure supplied air respirators may be
required for high airborne contaminant concentrations. Respiratory protection must be
provided in accordance with current local regulations.
When using do not eat, drink or smoke. Wash contaminated clothing before reuse. Wear
suitable gloves and eye/face protection.
General Hygiene
9. PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties
Physical state
Appearance
Odor
Liquid
Clear Orange
Citrus
Property
pH
Melting point/freezing point
Boiling point / boiling range
Flash point
Evaporation rate
Flammability (solid, gas)
Flammability Limits in Air
Upper flammability limit:
Lower flammability limit:
Vapor pressure
Vapor density
Specific Gravity
Water solubility
Solubility in other solvents
Partition coefficient
Autoignition temperature
Decomposition temperature
Kinematic viscosity
Viscosity
Explosive properties
Oxidizing properties
Values
Odor threshold
No Information available
7.5 - 8.5
No Information available
No Information available
None
No Information available
No Information available
No Information available
No Information available
No Information available
No Information available
1.01
completely soluble
No Information available
No Information available
No Information available
No Information available
No Information available
No Information available
No Information available
No Information available
10. STABILITY AND REACTIVITY
Reactivity
No data available
Chemical stability
Stable under recommended storage conditions.
Possibility of Hazardous Reactions
None under normal processing.
Conditions to avoid
Extremes of temperature and direct sunlight.
Incompatible materials
None known based on information supplied.
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Hazardous Decomposition Products
None known based on information supplied.
11. TOXICOLOGICAL INFORMATION
Information on likely routes of exposure
No data available
Product Information
Inhalation
No data available.
Eye contact
No data available.
Skin Contact
No data available.
Ingestion
No data available.
Chemical Name
Orange Terpenes
5989-27-5
Nonylphenol Ethoxylate
9016-45-9
2-(2-butoxyethoxy)ethanol
112-34-5
Dodecylbenzenesulfonic Acid,
Sodium Salt
68081-81-2
Sodium Xylene Sulfonate
1300-72-7
Oral LD50
= 4400 mg/kg ( Rat )
Dermal LD50
> 5 g/kg ( Rabbit )
= 1310 mg/kg ( Rat ) = 2590 mg/kg = 1780 µL/kg ( Rabbit ) = 2 mL/kg (
( Rat )
Rabbit )
= 3384 mg/kg ( Rat )
= 2700 mg/kg ( Rabbit )
Inhalation LC50
-
> 1000 mg/kg ( Rat )
> 2000 mg/kg ( Rat )
-
= 1000 mg/kg ( Rat )
-
-
Information on toxicological effects
Symptoms
No Information available.
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Sensitization
Germ cell mutagenicity
Carcinogenicity
No Information available.
No Information available.
This product contains one or more substances which are classified by IARC as
carcinogenic to humans (Group I), probably carcinogenic to humans (Group 2A) or possibly
carcinogenic to humans (Group 2B).
Chemical Name
ACGIH
IARC
Orange Terpenes
Group 3
5989-27-5
IARC (International Agency for Research on Cancer)
Not classifiable as a human carcinogen
OSHA (Occupational Safety and Health Administration of the US Department of Labor)
X - Present
Reproductive toxicity
STOT - single exposure
STOT - repeated exposure
Chronic toxicity
Aspiration hazard
NTP
-
OSHA
X
No Information available.
No Information available.
No Information available.
Repeated contact may cause allergic reactions in very susceptible persons. Avoid repeated
exposure.
No Information available.
Numerical measures of toxicity - Product Information
0% of the mixture consists of ingredient(s) of unknown toxicity
Unknown Acute Toxicity
The following values are calculated based on chapter 3.1 of the GHS document .
12. ECOLOGICAL INFORMATION
Ecotoxicity
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6% of the mixture consists of components(s) of unknown hazards to the aquatic environment
Chemical Name
Orange Terpenes
5989-27-5
Algae/aquatic plants
-
Crustacea
-
-
Fish
0.619 - 0.796: 96 h Pimephales
promelas mg/L LC50 flow-through
35: 96 h Oncorhynchus mykiss
mg/L LC50
5: 96 h Fish mg/L LC50
Nonylphenol Ethoxylate
9016-45-9
2-(2-butoxyethoxy)ethanol
112-34-5
100: 96 h Desmodesmus
subspicatus mg/L EC50
1300: 96 h Lepomis macrochirus
mg/L LC50 static
100: 48 h Daphnia magna mg/L
EC50 2850: 24 h Daphnia magna
mg/L EC50
-
Persistence and degradability
No Information available.
Bioaccumulation
No Information available.
Other adverse effects
No Information available
13. DISPOSAL CONSIDERATIONS
Waste treatment methods
Disposal of wastes
Disposal should be in accordance with applicable regional, national and local laws and
regulations.
Contaminated packaging
Do not reuse container.
14. TRANSPORT INFORMATION
DOT
Not regulated
15. REGULATORY INFORMATION
International Inventories
TSCA
DSL/NDSL
EINECS/ELINCS
AICS
Complies
Complies
Complies
Complies
Legend:
TSCA - United States Toxic Substances Control Act Section 8(b) Inventory
DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List
EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances
AICS - Australian Inventory of Chemical Substances
US Federal Regulations
SARA 313
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical
or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372
Chemical Name
2-(2-butoxyethoxy)ethanol - 112-34-5
SARA 311/312 Hazard Categories
Acute health hazard
SARA 313 - Threshold Values %
1.0
Yes
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No
No
No
No
Chronic Health Hazard
Fire hazard
Sudden release of pressure hazard
Reactive Hazard
CWA (Clean Water Act)
This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40
CFR 122.42)
CERCLA
This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and
Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level
pertaining to releases of this material
US State Regulations
California Proposition 65
This product does not contain any Proposition 65 chemicals
U.S. State Right-to-Know Regulations
Chemical Name
2-(2-butoxyethoxy)ethanol
112-34-5
New Jersey
X
Massachusetts
-
Pennsylvania
X
U.S. EPA Label Information
EPA Pesticide Registration Number Not Applicable
16. OTHER INFORMATION
NFPA
Health hazards 2
Flammability 0
Instability 0
HMIS
Health hazards 2
Flammability 0
Physical hazards 0
Physical and Chemical
Properties Yes
Personal protection
N/A
05-May-2015
Issue Date
07-Apr-2015
Revision Date
Revision Note
No Information available
Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the
date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage,
transportation, disposal and release and is not to be considered a warranty or quality specification. The information
relates only to the specific material designated and may not be valid for such material used in combination with any other
materials or in any process, unless specified in the text.
End of Safety Data Sheet
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