LESSON 5. SOLAR PHOTOVOLTAIC ENERGY ⇒ 1 Energy Technology A. Y. 2006-07 Contents (I) • Introduction. • The photovoltaic effect. – – – – – – Semiconductors. The p-n junction. The PV effect in the solar cells. PV cell response curve. Voc and Isc. Point of maximum power, SF and η. 2 Energy Technology A. Y. 2006-07 Contents (II) • Manufacturing technologies and types of PV cells. – Crystalline silicon cells. – Thin film cells. – Tandem cells. • The photovoltaic panel. – – – – Series connection. Parallel connection. Mathematical models. Components of PV panels. 3 Energy Technology A. Y. 2006-07 Contents (III) • Other components of PV systems. – Accumulation subsystem. – Control subsystem. – Inverter and converter. • Array design. – – – – – Sun intensity. Sun angle. Shadow effect. Temperature effect. Effect of climate. 4 Energy Technology A. Y. 2006-07 Contents (IV) • Array design. – Electrical load matching. – Sun tracking. • Peak power point operation. • Isolated PV systems. – Simplified method. – Calculation of the storage subsystem. – Simulation method. • Bibliography. 5 Energy Technology A. Y. 2006-07 Introduction (I) • PV effect: generation of e.m.f. (electrical current) in a semiconductor due to absorption of light radiation. • Discovered by Becquerel in 1839. • First selenium cell made in 1941 with an efficiency of 1%. • Since then, space race has improved technology. • Current PV cells efficiency: 30% under laboratory conditions (17% under working conditions). Energy Technology 6 A. Y. 2006-07 Introduction (II) • Main problem: high manufacturing and installation costs. 1980 Cost ($/Wp) 1998 Cost ($/Wp) 1998 Cost ($1980/Wp) 30 6 3 Panel Other Panel Other Panel Other 10 20 3.5 2.5 1.75 1.25 • Main application: isolated systems. • But during the last few years there has been a large growth in installed power: from 15 MWp in 1980 to 150 MWp in 1998. 7 Energy Technology A. Y. 2006-07 Introduction (III) Photovoltaic power installed in EU (2000) 87,5 Alemania 19,5 Italia 12,2 12,1 10,6 6,7 2,8 2,5 1,7 1,6 1 0,5 Países Bajos España Francia Austria Suecia Finlandia Dinamarca Gran Bretaña Grecia Portugal 0 20 40 60 MWp Energy Technology 80 100 8 A. Y. 2006-07 The photovoltaic effect (I) • The PhotoVoltaic effect is the conversion of the energy of the light photons into electric energy. • The PV effect can occur in gasses, liquids and solids. • Maximum solar radiation: between 0.35 and 3 µm of wavelength ⇒ materials for solar cells must be sensitive to that radiation ⇒ semiconductor materials, like silicon. 9 Energy Technology A. Y. 2006-07 The PV effect (II) • Semiconductors: – Atoms: electrons in orbital shells around nucleus. There are allowed levels (minimum energy) and forbidden levels. – When one atom is in a crystalline structure it interacts with other atoms and the energy levels form energy bands. – Outermost energy band is called the conduction band and e- are free to move from one atom to another. – Outermost level of an atom occupied by e- is called the valence band. Energy Technology 10 A. Y. 2006-07 The PV effect (III) • Semiconductors: – Relation between bands gives a classification of materials: • • • Conductors: valence band empty of e-. Insulators (Eg > 3 eV): valence band full of e-. Semiconductors (Eg ≈ 1 eV): valence band partly filled with e-. 11 Energy Technology A. Y. 2006-07 The PV effect (IV) • Semiconductors: – Pure semiconductors: intrinsic semiconductors. – Semiconductors doped with impurities: extrinsic semiconductors. • • Dopant material with more e- in valence band than semiconductor: n-type semiconductor. Dopant material with less e- in valence band than semiconductor: p-type semiconductor. – Example: silicon have 4 e- in valence band. In pure Si each atom shares 2 e- to form stable structure. 12 Energy Technology A. Y. 2006-07 The PV effect (V) • Semiconductors: – Example: Antimony (5 valence e-) as impurity ⇒ n-type silicon with excess of electrons available for conduction. 13 Energy Technology A. Y. 2006-07 The PV effect (VI) • Semiconductors: – Example: Boron (3 valence e-) as impurity ⇒ p-type silicon with a missing electron or positive hole. 14 Energy Technology A. Y. 2006-07 The PV effect (VII) • Semiconductors: – A n-type semiconductor has: • • • majority charge carriers (free e- in conduction band); positive ions belonging to the dopant element; minority charge carriers (e- and holes created by thermal agitation). – A p-type semiconductor has: • • • majority charge carriers (holes in valence band); negative ions belonging to the dopant element; minority charge carriers (e- and holes created by thermal agitation). 15 Energy Technology A. Y. 2006-07 The PV effect (VIII) • The p-n junction: – When p- and n-type semiconductors are joined together, in the contact zone free e- of n-type semiconductor jump to fill the holes of the p-type semiconductor (diffusion movement). – It behaves like a diode: an electric field is generated in the junction zone opposite to the electric field of the difussion. 16 Energy Technology A. Y. 2006-07 The PV effect (IX) • The p-n junction under equilibrium conditions: – To neutralise charges: • Free e- in n-type diffuse across junction to p-type. • Free holes in p-type diffuse to n-type. • e- and holes close to junction recombine. – A depletion (agotamiento) region (free of mobile charge carriers) develops on either side of junction with fixed negative ions on pside and fixed positive ions on n-side preventing further diffusion so that recombination between holes and electrons 17 is inhibited. Energy Technology A. Y. 2006-07 The PV effect (X) • The p-n junction under equilibrium conditions: – A potential difference develops across the junction called the equilibrium potential V0. • The behaviour of the p-n junction may be altered on application of an external voltage across its ends: – Direct polarization: forward potential difference. Positive pole on p side and negative pole on n side. – Inverse polarization: reverse potential difference. Negative pole on p side and positive pole on n side. Energy Technology 18 A. Y. 2006-07 The PV effect (XI) • The p-n junction under direct polarization: – The p region made positive with respect to n region. – The created field (Edp) is opposite to the one of the junction (Eo), but is in the same direction that the diffusion field (Edif) . – The equilibrium condition is disturbed. – The junction potential is reduced to V0 - V. – The width of the depletion region is also reduced. 19 Energy Technology A. Y. 2006-07 The PV effect (XII) • The p-n junction under direct polarization: – The electrons in n-type can fall down the potential barrier to p-type. – The holes in p-type likewise fall down to the n-type . – There is a net flow of current from p to ntype. The diffusion movement can continue. – We can consider the majority carriers on each side as being injected across the junction. 20 Energy Technology A. Y. 2006-07 The PV effect (XIII) • The p-n junction under inverse polarization: – The p-type is made negative with respect to the n-type. – The external voltage adds to the internal voltage. – The potential barrier is increased. – The width of the depletion region increases. – Majority carriers are repelled further from junction. 21 Energy Technology A. Y. 2006-07 The PV effect (XIV) • The p-n junction under inverse polarization: – Electrons in n-type and holes in p-type find it difficult to cross over junction. They move away from the junction. – The only current present is that due to a few thermally-generated minority carriers on each side of junction ⇒ holes in n-type and e- in ptype ⇒ it produces a reverse leakage current from n to p. 22 Energy Technology A. Y. 2006-07 The PV effect (XV) • The p-n junction: N P IL id Eo + id Vo - Vdirect polarization Energy Technology 23 A. Y. 2006-07 The PV effect (XVI) • The p-n junction: qV mKT − 1 i = I e – Total current in the diode: d D – ID current: appears with inverse polarization and relatively high negative tensions ⇒ exponential term nought (zero). – Taking into account the internal resistance of the diode: q (V − Rs id ) id = I D e mKT − 1 24 Energy Technology A. Y. 2006-07 The PV effect (XVII) • Diode equation representation: – Negative tension increases ⇒ junction becomes conductor ⇒ avalanche current. 25 Energy Technology A. Y. 2006-07 The PV effect (XVIII) • The PV effect in the solar cells: – A photon of light is absorbed by a valence e⇒ its energy increases. – If photon energy > band gap ⇒ e- jumps into conduction band. – If photon energy < band gap ⇒ e- increases its kinetic energy ⇒ increases its T. – Free e- generated in n layer can follow three ways: • • • An external circuit. Recombine with positive holes in lateral direction. Move toward the p layer. Energy Technology 26 A. Y. 2006-07 The PV effect (XIX) • The PV effect in the solar cells: – Negative charges in the p layer of the p-n junction restrict this last movement. – Recombination in lateral direction is reduced making the layer extremely thin. – If external circuit open ⇒ e- recombines with holes ⇒ increase of cell temperature. – If external circuit closed ⇒ The effect is equivalent to a hole passing from the n zone to the p zone, generating a current, IL, of positive charges in the direction of the electric field. Energy Technology 27 A. Y. 2006-07 The PV effect (XX) • The PV effect in the solar cells: 28 Energy Technology A. Y. 2006-07 The PV effect (XXI) • The PV effect in the solar cells: 29 Energy Technology A. Y. 2006-07 The PV effect (XXII) • The PV effect in the solar cells: 30 Energy Technology A. Y. 2006-07 The PV effect (XXIII) • The PV effect in the solar cells: 31 Energy Technology A. Y. 2006-07 The PV effect (XXIV) • The PV effect in the solar cells: – The energy content of the photon is related to its wavelength: E = h·ν and c = λ·ν ⇒ there is a maximum cut-off wavelength necessary to excite one valence e-. 32 Energy Technology A. Y. 2006-07 The PV effect (XXV) • PV cell response curve: – Equivalent circuit of a PV cell: IL I + RS P Eo Vout RSH N id ISH - – Equation: q (V + Rs I ) I = I L − id − I sh = I L − I D e mKT − 1 − I sh Energy Technology 33 A. Y. 2006-07 The PV effect (XXVI) • PV cell response curve: – Rs: series resistance depending on p-n junction depth, impurities and contact resistance. – Rsh: shunt-leakage resistance, inversely related to leakage current to the ground. – Ideal PV cell: Rs = 0 and Rsh = ∞. – Silicon cell: Rs = 0.05 - 0.1 Ω and Rsh = 200 – 300 Ω ⇒ Ish ≈ 0. – PV conversion efficiency is sensitive to small variations in Rs, but insensitive to variations in Rsh. Energy Technology 34 A. Y. 2006-07 The PV effect (XXVII) • PV cell response curve: 35 Energy Technology A. Y. 2006-07 The PV effect (XXVIII) • PV cell response curve: 36 Energy Technology A. Y. 2006-07 The PV effect (XXIX) • PV cell response curve: – Standard Test Conditions, STC (Condiciones de Ensayo Estándar): • • • Solar Irradiance: 1 kW/m2. Air mass: AM 1.5. Cell temperature: 25 ºC. – Standard Operating Conditions, SOC (Condiciones de Operación Estándar): • • • Solar Irradiance: 0.8 kW/m2. Wind speed: 1 m/s. Ambient temperature: 20 ºC. – Nominal Operating Cell Temperature, NOCT. 37 Energy Technology A. Y. 2006-07 The PV effect (XXX) • Open circuit voltage and short circuit current: – Voc: when I = 0 (IL >> ID). qVoc I qVoc I = 0 ⇒ I L = I D e mKT − 1 ⇒ ln L + 1 = ⇒ ID mKT I mKT I L ln = mVT ln L Voc = q ID ID – Isc: short-circuiting output terminals with a resistance almost null (Rload ≈ 0)⇒ Isc ≈ IL. In the response curve corresponds to V = 0. 38 Energy Technology A. Y. 2006-07 The PV effect (XXXI) • Open circuit voltage and short circuit current: 39 Energy Technology A. Y. 2006-07 The PV effect (XXXII) • Point of maximum power, shape factor and efficiency: – Development: on blackboard. – Maximum power = area of the rectangle defined by Vmp and Imp. The product is smaller than Voc·Isc. – The relation is the shape factor: Vmp · I mp SF = Voc · I sc – Efficiency of the cell: P η= GA 40 Energy Technology A. Y. 2006-07 The PV effect (XXXIII) • Point of maximum power, shape factor and efficiency: 41 Energy Technology A. Y. 2006-07 The PV effect (XXXIV) • Point of maximum power, shape factor and efficiency: – The efficiency increases linearly with level of radiation and cell size and decreases linearly with cell temperature. – Increase of working temperature ⇒ increase of Isc and decrease of Voc. – There is also an influence of the gap band. – Maximum theoretical efficiency ≈ 60%. – Silicon solar cell max. efficiency ≈ 25%. – Commercial PV panels efficiency ≈ 10-17%. 42 Energy Technology A. Y. 2006-07 The PV effect (XXXV) • Point of maximum power, shape factor and efficiency: 43 Energy Technology A. Y. 2006-07 The PV effect (XXXVI) • Point of maximum power, shape factor and efficiency: 44 Energy Technology A. Y. 2006-07 The PV effect (XXXVII) • Point of maximum power, shape factor and efficiency: – Variation of efficiency with temperature: η = η ref [1 + β (Tref − Tcell )] 45 Energy Technology A. Y. 2006-07 Manuf. techn. and types of PV cells (I) • Silicon used in solar cells: single crystal, polycrystalline and amorphous. • Amorphous silicon cells ⇒ thin film cells. • Manufacturing technology of crystalline silicon cells: – Mature, well developed and reliable. – Highly complex, high tech equipments and important energy costs. – It is an outgrowth of manufacturing of microchips. 46 Energy Technology A. Y. 2006-07 Manuf. techn. and types of PV cells (II) • Stages in the manufacturing process of crystalline silicon cells : 1. 2. 3. 4. 5. 6. 7. 8. 9. Obtaining of metallurgic grade silicon. Silicon purification. Growing of silicon crystals in ingots. Slicing wafers of p-silicon (base material) from the ingots. Polishing and cleaning the surface. Doping with n material to form the p-n junction. Deposition of electrical contacts. Application of antireflection coating. Encapsulation. 47 Energy Technology A. Y. 2006-07 Manuf. techn. and types of PV cells (III) 1. Obtaining of metallurgic grade silicon. • Obtained in arc furnaces (1,800 ºC) from SiO2 with a purity of 98%. 48 Energy Technology A. Y. 2006-07 Manuf. techn. and types of PV cells (IV) 2. Silicon purification. • • • Reaction with hydrochloric acid obtaining silicon bars of 2 m length and 30 cm diameter. Purity for electronic use: 2 atoms of impurity by 107 atoms of silicon. Purity for PV cells: 1 atom of impurity by 106 atoms of silicon. 49 Energy Technology A. Y. 2006-07 Manuf. techn. and types of PV cells (V) 2. Silicon purification. 50 Energy Technology A. Y. 2006-07 Manuf. techn. and types of PV cells (VI) 2. Silicon purification. 51 Energy Technology A. Y. 2006-07 Manuf. techn. and types of PV cells (VII) 3. Growing of silicon crystals in ingots. • Czochralsky process: most common method used for single crystal silicon. • • Cylindrical ingots of D = 10 cm and L = 1 m. Cell efficiencies: 22% (laboratory) and 17% (commercial). 52 Energy Technology A. Y. 2006-07 Manuf. techn. and types of PV cells (VIII) 3. Growing of silicon crystals in ingots. • • • • Polycrystalline silicon is obtained in molds where the molten silicon is cooled in a given direction so as to orient the crystal structures in that direction. Ingots size: 400x40x40 cm. Cell efficiencies: 18% (laboratory) and 13% (commercial). Addition of a controlled quantity of contaminant (boron or phosphorous) to the molten mass to obtain type p or type n silicon. Energy Technology 53 A. Y. 2006-07 Manuf. techn. and types of PV cells (IX) 3. Growing of silicon crystals in ingots. 54 Energy Technology A. Y. 2006-07 Manuf. techn. and types of PV cells (X) 4. Slicing wafers from the ingots. • To give desired cross-section shape and thickness (0.2 – 0.5 mm). 55 Energy Technology A. Y. 2006-07 Manuf. techn. and types of PV cells (XI) 5. Polishing and cleaning the surface. • • • • • To eliminate damages and to clean the wafers. Chemical attack with acids: isotropic, rapid, expensive, dangerous and contaminant. It gives very smooth surfaces. Chemical attack with bases: anisotropic. Different attacks depending on directions: the surfaces obtained are rough and reduce reflection losses but the surface of the junction is wider and the series resistance too. Dry chemical attack: with plasma; slow and expensive. 56 Energy Technology A. Y. 2006-07 Manuf. techn. and types of PV cells (XII) 6. Doping with n material. • • • n material is diffused into the top layer of the silicon wafer. Most commom method: thermal diffusion of phosphorous in vapor phase at 850-900 ºC. Backside of wafer covered to prevent recombination: creation of zones with high concetration of p-type dopant or with SiO2. 7. Deposition of electrical contacts. • • Top surface: grid pattern covering less than 10% of the surface. Width about 300 µm. Methods: vacuum metal vapor deposition or screenprinting. Bottom surface: solid metallic sheet. Energy Technology 57 A. Y. 2006-07 Manuf. techn. and types of PV cells (XIII) 58 Energy Technology A. Y. 2006-07 Manuf. techn. and types of PV cells (XIV) 8. Application of antireflection coating. • TiO2 and Ta2O5 are deposited to reduce • reflection from 30% of untreated silicon to 3%. Methods: vacuum metal vapor deposition or spraying. 9. Encapsulation. • • In transparent material to protect PV cells from the environment. Materials: PVB and EVA. 59 Energy Technology A. Y. 2006-07 Manuf. techn. and types of PV cells (XV) 60 Energy Technology A. Y. 2006-07 Manuf. techn. and types of PV cells (XVI) e- 61 Energy Technology A. Y. 2006-07 Manuf. techn. and types of PV cells (XVII) 62 Energy Technology A. Y. 2006-07 Manuf. techn. and types of PV cells (XVIII) • Thin film cells: – Crystalline silicon cells: high thickness because they have low absorption coefficient and to reduce transmission losses. – Thin film cells: thickness of 10 to 50 µm. – Principal types: • • • • • Amorphous silicon cells. GaAs cells. TeCd cells. CIS cells. Silicon crystalline thin film cells. 63 Energy Technology A. Y. 2006-07 Manuf. techn. and types of PV cells (XIX) • Amorphous silicon cells: – a-Si: atoms not forming structure ⇒ incomplete bonds ⇒ high density of permissible states into the gap band (1.7 eV). – Problems with doping because the grid readapts ⇒ H added to avoid this problem. – Cells: made from an a-Si:H alloy doped with P and B to make the n and p layers. – Cell consist of an n layer, an intermediate undoped a-Si layer (intrinsic zone) an a p layer as a substrate. There is a p-i-n junction. 64 Energy Technology A. Y. 2006-07 Manuf. techn. and types of PV cells (XX) • Amorphous silicon cells: – Advantages: • • • The material base is inexhaustible. The manufacturing process is cheaper and requires less material and energy than that of crystalline silicon. Series connection of cells can be made during the manufacturing process. – Disadvantages: • • Instability: degradation by exposure to light ⇒ the efficiency drops to 4%. Specifications recovered by subjecting the cell to temperatures over 100 ºC. 65 Energy Technology A. Y. 2006-07 Manuf. techn. and types of PV cells (XXI) • GaAs cells: – Band gap = 1.42 eV ⇒ close to maximum efficiency point. – High costs but high efficiency ≈ 25%. – High absorption coefficient. – Problem of toxic components. – Used in space applications and concentration systems. • TeCd cells: – Mean efficiencies: 10%. – Band gap = 1.45 eV. – Also high absorption coefficient and toxicity. Energy Technology 66 A. Y. 2006-07 Manuf. techn. and types of PV cells (XXII) • CuInSe2 cells: – Band gap = 1 eV. – Highest absorption coefficient. – Mean efficiencies: 9%. • Silicon crystalline thin film cells: – Thinner than conventional cells but thicker than previously described thin film cells. – Advantages: No toxicity and abundance of base material and stable efficiency. – Efficiencies with multi-layer cells of 10 to 20 µm are about 17%. 67 Energy Technology A. Y. 2006-07 Manuf. techn. and types of PV cells (XXIII) • Tandem cells: – In single-junction cells the efficiencies are very close to the theoretical limits. – To increase efficiency: multi-junction or tandem cells. – Superimposition of cells manufactured with semiconductors of different band gaps to obtain better use of the photon’s energy. – Wider band gap cells at the top and smaller band gap cells at the bottom. – Efficiency of 2-junction cells: 35%. – Efficiency of 3-junction cells: 50%. – Good combination: GaAs and GaSb. 68 Energy Technology A. Y. 2006-07 The photovoltaic panel (I) • The solar cell is the base of a PV power system. • It is a few square milimeters in size and produces 1 - 5 W of power. • Module or panel: several cells connected in series or parallel circuits. • Array (serie o conjunto de paneles, generador fotovoltaico): group of several modules connected in series-parallel combinations to generate the required current or voltage. 69 Energy Technology A. Y. 2006-07 The PV panel (II) 70 Energy Technology A. Y. 2006-07 The PV panel (III) • Tension supplied by one cell ≈ 0.6 V. • Direct current circuit tensions > 5 V. • Usual PV panel: 30 to 36 (or a multiple) cells in series connection. • Curves of series or parallel connections: on blackboard. • PV module is characterised by its peak power: power at maximum power operation point under Standard Test Conditions (STC) of 1 kW/m2 of irradiance, 25 ºC of cell temperature and air spectrum of AM 1.5 (air mass). 71 Energy Technology A. Y. 2006-07 The PV panel (IV) • The maximun efficiency of a PV panel is 1-2% smaller than that of individual cells due to the spaces between cells and to the frame. • Maximum power of the connection ≠ sum of maximum powers of the cells due to dispersion of values of characteristic parameters. • PV cells are fragile and sensitive to dust and humidity ⇒ transparent surface of hardening glass with low content of iron. • Frame usually made of aluminium. 72 Energy Technology A. Y. 2006-07 The PV panel (V) 73 Energy Technology A. Y. 2006-07 The PV panel (VI) 74 Energy Technology A. Y. 2006-07 The PV panel (VII) • Series connection: – Characteristic curve of 3 cells connected in series: on blackboard. – Manufacturing defect or a shadow effect on c3 ⇒ Isc of a cell is reduced ⇒ Intensity of the connection higher ⇒ this cell working with negative tension ⇒ dissipating power instead of generating. – I of series connection must be lower than Isc of every cell to avoid negative V and power dissipation. – To avoid this: by-pass diodes installed in order to short-circuit groups of cells. 75 Energy Technology A. Y. 2006-07 The PV panel (VIII) • Parallel connection: – Of several groups of cells connected between them in series. – It is most common to make the parallel connection between panels. – If working tension of a group of cells connected in series goes beyond the Voc ⇒ intensity is reversed and works as a receptor ⇒ To avoid this: block or blocking diode. – Usually the tensions for maximum power are not the same for all the cells ⇒ maximum power of the connection is smaller than the sum of the individual maximum powers: diagram on blackboard blackboard. 76 Energy Technology A. Y. 2006-07 The PV panel (IX) • Series and parallel connection: 77 Energy Technology A. Y. 2006-07 The PV panel (X) • Mathematical models: – Determination of V and I supplied in the different working conditions. – Equivalent circuit of a PV generator formed by Ns cells in series with a diode as a parallel current source ⇒ characteristic equation. IL I + RS P Eo N Vout RSH id ISH - Energy Technology 78 A. Y. 2006-07 The PV panel (XI) • Mathematical models: V + Rs I V +R I s I = I L − I D e a − 1 − R sh mKT a= Ns q – where [V], IL is the resultant of the photon current, ID is the inverse polarization current of the diode, Rs is the series resistance and Rsh is the parallel resistance. This last one can be assumed to be infinite. – The model is characterised by these 5 parameters: a, IL, ID, Rs and Rsh ≈ ∞. 79 Energy Technology A. Y. 2006-07 The PV panel (XII) • Mathematical models: – Parameters supplied by manufacturers: Voc, Isc and the peak power point in standard conditions (Vmp and Imp). – This implies 3 equations. – It is necessary an additional independent equation to determine the 4 parameters. – In short circuit the diode current is null ⇒ IL= Isc. – In open circuit the exponential term is greater V than 1 and I is null ⇒ − oc I D = I Le a Energy Technology 80 A. Y. 2006-07 The PV panel (XIII) • Mathematical models: – Rs is obtained by applying the characteristic equation to the peak power point (neglecting the 1): I a ·ln 1 − mp − Vmp + Voc IL Rs = I mp – This expression limits the values of a and Rs: both must be positive. – The fourth equation is obtained considering the effect of temperature. Equations of Townsend on blackboard. 81 Energy Technology A. Y. 2006-07 The PV panel (XIV) • Mathematical models: – Application example: on blackboard. – Data from a panel (at Tref): Isc, Voc, Imp, Vmp, µi,sc, µv,oc ⇒ we can determine IL,ref, ID,ref, aref and Rs. – To calculate the curve of the panel at other temperature the Townsend’s equations are used. 82 Energy Technology A. Y. 2006-07 The PV panel (XV) • Components of PV panels: – Principal components: 1. 2. 3. 4. 5. 6. 7. 8. Frame. Weatherproof junction box. Rating plate. Weather protection for 30-year life. PV cells. Tempered high transmissivity cover glass. Outside electrical bus. Frame clearance. 83 Energy Technology A. Y. 2006-07 The PV panel (XVI) 84 Energy Technology A. Y. 2006-07 The PV panel (XVII) 85 Energy Technology A. Y. 2006-07 The PV panel (XVIII) • Components of PV panels: – Cells: • Connected with metallic ribbon containing silver (high conductivity) and welded. – Cover glass: • • Tempered to resist hail and other impacts. With low content of iron (more transparency). – Encapsulating material: • • • Protect against water and dust. Reduce reflection losses. Maintain plasticity to absorb tensions from hits and dilatations. 86 Energy Technology A. Y. 2006-07 The PV panel (XIX) • Components of PV panels: – Encapsulating material: • Material: EVA (etileno vinil acetato). Not used for concentrating systems. – Bottom cover: • • Usually made of Tedlar (PVF, fluoruro de polivinilo): flexible and high mechanical, chemical and thermal resistance. In panels for buildings another glass cover is used. – Frame: • Usually made of aluminium. Energy Technology 87 A. Y. 2006-07 Other components of the PV system (I) • Working point in the I-V characteristic curve: on blackboard. • Accumulation system: – Non grid-connected or stand-alone or isolated systems ⇒ energy storage ⇒ to assure the supply during night and cloudy periods. – Possible energy storage systems: compressed air; hydrogen; flywheels; hydraulic potential energy; electrochemical batteries. – The last one the cheapest and the most widely used. Energy Technology 88 A. Y. 2006-07 Other components of the PV system (II) • Accumulation system: – The most common are the lead-acid batteries. – Characteristics of PV systems: • • Under partial load for long periods. Slow discharges during more than 100 hours. – Required batteries with low autodischarge and maintenance. – With transparent container for visual control of electrolyte level. 89 Energy Technology A. Y. 2006-07 Other components of the PV system (III) • Accumulation system: – The capacity, C, of a battery is reduced with the accumulated cycles ⇒ end of life when C decreases by 80% of nominal value. – Discharge depth: % of full charge used. Recommended value for PV systems: 40%. – The higher the discharge depth, the longer the life. 90 Energy Technology A. Y. 2006-07 Other components of the PV system (IV) • Accumulation system: 91 Energy Technology A. Y. 2006-07 Other components of the PV system (V) • Control system: – To regulate and protect elements and to guarantee good performance of the system. – Functions: • • • Open circuit between PV panel and batteries during night, when panels are working as a receptor. Blocking diode. Tension regulator: when panel is generating more intensity than the necessary to charge the batteries ⇒ dissipation element. To avoid the total discharge of the battery disconnecting the load. 92 Energy Technology A. Y. 2006-07 Other components of the PV system (VI) 93 Energy Technology A. Y. 2006-07 Other components of the PV system (VII) 94 Energy Technology A. Y. 2006-07 Other components of the PV system (VIII) 95 Energy Technology A. Y. 2006-07 Other components of the PV system (IX) • Control system: – Peak power tracker: adjusts the operating point to extract maximum power under the given climatic conditions. – Inverter: converts DC current into AC current. – Battery charger: DC-DC converter. – Da: blocking diode. – Db: battery discharge diode: to prevent the charge of the battery when it is full. 96 Energy Technology A. Y. 2006-07 Other components of the PV system (X) • Inverter: – The inverter converts DC current from PV array into AC current for AC loads or for feeding the electrical grid. – Two types: • • Natural commutation type: triggered by external grid frequency. Self commutating inverters: used in isolated systems. – AC-PV modules: the inverter is integrated with the module. 97 Energy Technology A. Y. 2006-07 Other components of the PV system (XI) • Converter: – DC-DC converters use capacitors, coils and commutation devices. – Transform DC current into DC current with other values of V and I, maintaining P. 1. Inversor/cargador. 2. Regulador. 3. Convertidor CC/CC 24/12V. 98 Energy Technology A. Y. 2006-07 Other components of the PV system (XII) 99 Energy Technology A. Y. 2006-07 Other components of the PV system (XIII) 100 Energy Technology A. Y. 2006-07 Array design (I) • Major factors influencing electrical design of the solar array: – – – – – – – Sun intensity. Sun angle. Shadow effect. Temperature effect. Effect of climate. Electrical load matching. Sun tracking. 101 Energy Technology A. Y. 2006-07 Array design (II) • Sun intensity: – Current is directly proportional to sun intensity. – More reduction in Isc than in Voc. 102 Energy Technology A. Y. 2006-07 Array design (III) • Sun intensity: – Photoconversion efficiency of the cell is insensitive to solar radiation in the working range. – We get lower power on a cloudy day only because of the lower solar energy. 103 Energy Technology A. Y. 2006-07 Array design (IV) • Sun angle: – Cell output current: I = I0 cos θ, where I0 is the normal sun current and θ is the angle of the sunline measured from the normal. – Cosine law: valid for angles from 0º to 50º. – Beyond 50º the electrical output deviates the former law. – There is no power generation beyond 85º. – Kelly cosine value: actual (experimental) current-angle curve of the cell. 104 Energy Technology A. Y. 2006-07 Array design (V) • Sun angle: 105 Energy Technology A. Y. 2006-07 Array design (VI) • Shadow effect: – An array of series-connected cells gets shadowed due to a structure interfering with the sunline ⇒ some cells get shadowed ⇒ they lose photovoltage ⇒ they must carry current to other cells ⇒ without V, not P produced ⇒ they act as a load, producing local heat loss, I2·R. – The remaining cells must work at higher V to make up for the losses. – Higher V means less I ⇒ diagram. – With several cells shadowed the I-V curve gets below operating V ⇒ current falls down to zero ⇒ No power. 106 Energy Technology A. Y. 2006-07 Array design (VII) • Shadow effect: 107 Energy Technology A. Y. 2006-07 Array design (VIII) • Shadow effect: – To eliminate losses due to shadow effect the circuit is subdivided into several segments with bypass diodes. 108 Energy Technology A. Y. 2006-07 Array design (IX) • Temperature effect: – Tcell increases ⇒ Isc increases and Voc decreases. 109 Energy Technology A. Y. 2006-07 Array design (X) • Temperature effect: – Effect of temperature on the power: on blackboard. P = Pref [1 + (α − β )∆T ] – For single crystal silicon cells: α = 500·10-6 1/ºC and β = 5·10-3 1/ºC. P = Pref [1 − 0.0045∆T ] – Net effect is a power decrease at high operating temperatures. – PV system designed so that module output V can increase at low Tcell and can decrease at high Tcell. 110 Energy Technology A. Y. 2006-07 Array design (XI) • Temperature effect: V1 V2 111 Energy Technology A. Y. 2006-07 Array design (XII) • Effect of climate: – Reduction in power from partly cloudy day to extremely overcast day: from 80% to 30%. – Modules designed to resist golf ball size hail. • Electrical load matching: – Operating point: intersection of source and load line. P 112 Energy Technology A. Y. 2006-07 Array design (XIII) • Electrical load matching: – Operation with constant power: – Condition for electrical operating stability: dP dP > dV dV source load 113 Energy Technology A. Y. 2006-07 Array design (XIV) • Electrical load matching: – Heaters: constant R and P ∝ V2. – Induction motors: constant power loads. – Large systems with mix loads: P ∝ V. • Sun tracking: – PV array with an actuator to follow the sun path. – Two types: • • One-axis tracker: follows sun from E to W. Two-axis tracker: follows sun from E to W during the day and from N to S throughout the year. 114 Energy Technology A. Y. 2006-07 Array design (XV) • Sun tracking: 115 Energy Technology A. Y. 2006-07 Array design (XVI) • Sun tracking: – Increase in energy: up to 40% over the year. – Suntracker design: on blackboard. 116 Energy Technology A. Y. 2006-07 Peak power point operation (I) • PV module must operate at a certain voltage which corresponds to the peak power point under the given operating conditions. • Peak power point operation electrical principle: on blackboard. Vmp dV dPmáx = 0 ⇒ =− I mp dI mp • Zd = dV / dI: dynamic impedance of the source. • Zs = V / I: static impedance. • Three methods to extract the peak power from the module. Energy Technology 117 A. Y. 2006-07 Peak power point operation (II) 1. Small signal current injected to the array to measure Zd and Zs. Operating voltage increased or decreased until Zd = -Zs, where the maximum power is extracted (dP = 0). 2. Operating voltage is increased as long as dP / dV is positive. If dP / dV is negative, we must decrease the operating voltage. Voltage is kept where dP / dV is near zero. 3. For most PV cells the ratio Vmp / Voc is constant, K. For crystalline silicon cells K = 0.72. The Voc of an unloaded cell is measured and the operating voltage is set to K·Voc. 118 Energy Technology A. Y. 2006-07 Isolated PV systems (I) • Two types: – Installations using solar energy only. – Installations using an auxiliary electric generating system, the so-called hybrid systems. • Two methods to calculate PV installations: – Simplified method based on number of equivalent hours of sun. – Method based on simulation. 119 Energy Technology A. Y. 2006-07 Isolated PV systems (II) • In both methods it is necessary to know: – Current (present) energetic demand. – Power. – Working times of the different loads or receptors. – Losses in batteries (energy efficiency ≈ 80%). – Losses in inverters (energy efficiency ≈ 90%). – Losses in conductors (important due to low tensions and high currents). – Efficiency of the electrical installation (≈ 85%). 120 Energy Technology A. Y. 2006-07 Isolated PV systems (III) • Simplified method: – Energy balance established for the most unfavourable period, determining how far the PV surface has to tilt (incline) in order to decrease its size the most. – System oversized the rest of the year. – Procedure: 1. The monthly average daily sun radiation matrix,[H T ], is obtained, where the element H T , jk [kWh/m2·day] corresponds to the month k and the inclination j. 121 Energy Technology A. Y. 2006-07 Isolated PV systems (IV) • Simplified method: – Procedure: 2. The demand vector, [D ], is established, where the element Dk [kWh/day] is the monthly average daily demand. 3. The matrix of theoretical capture area, [A], is determined, considering an efficiency equal to 1. The element Ajk = Dk / H T , jk is the necessary theoretical area for the month k and the inclination j. 4. The higher value of each row, affected by the conversion efficiency, will be the critical area needed for each inclination j. 122 Energy Technology A. Y. 2006-07 Isolated PV systems (V) • Simplified method: – Procedure: 5. The minimum required surface of the installation would correspond to the optimum inclination that is obtained after choosing the minimum value between the maximum of each row (ie. of each inclination). The ideal inclination and the critical period are determined. 123 Energy Technology A. Y. 2006-07 Isolated PV systems (VI) • Simplified method: – Procedure: 6. After that, the size of the PV generator is determined following these steps: • The number of sun equivalent hours is calculated: Nh = • ] 2 The power to be installed is calculated: Pinstal = Energy Technology [ 1 standard sun [kW/m ] H T , jk ·n.º of days of the month kWh/m 2 Dk ·n.º of days of the month [kWh] N h [h] 124 A. Y. 2006-07 Isolated PV systems (VII) • Simplified method: – Procedure: 6. After that, the size of the PV generator is determined following these steps: • The number of panels in series in one branch of the PV array is calculated dividing the nominal V of the installation by the nominal V Vinstal of one panel: npser = • Vmodule The number of branches of panels in parallel is obtained dividing the required P by the P of one module and the number of panels in series: Pinstal np paral = 125 Pmodule ·npser Energy Technology A. Y. 2006-07 Isolated PV systems (VIII) • Calculation of the storage system: – Procedure to calculate the days of autonomy: 1. The vector of number of days of autonomy is established, [Nau], where each element corresponds to one month. A normal value for the months of less radiation is between 7 and 15 days. 2. The required accumulation (energy) will be the maximum value calculated for the different months: Au = max [Nauk· Dk ] in kWh. 126 Energy Technology A. Y. 2006-07 Isolated PV systems (IX) • Calculation of the storage system: – Procedure to calculate the days of autonomy: 3. The minimum capacity of the battery may be the corresponding to a discharge regime of 100 hours: Au in kWh. CB100 = PD100 PD100 is the depth of maximum discharge, 70% for batteries with deep discharge and 40% for lead-acid batteries. 127 Energy Technology A. Y. 2006-07 Isolated PV systems (X) • Calculation of the storage system: – Procedure to calculate the days of autonomy: 4. To pass from kWh to Ah the nominal tension of the battery is introduced: CB100 [Ah ] = CB100 [Wh ] Vinstal [V ] 128 Energy Technology A. Y. 2006-07 Isolated PV systems (XI) • Calculation of the storage system: – Procedure to calculate the days of autonomy: 5. It is also necessary to calculate the daily cycle of the batteries, due to the gap between the demand hours and the sun hours. The minimum capacity of the battery for a fast discharge regime is: CB10 = Au· DF in kWh, PD10 where DF is the gap consumption in kWh and PD10 the depth of discharge that must be higher than 20%. 129 Energy Technology A. Y. 2006-07 Isolated PV systems (XII) • Calculation of the storage system: – The batteries to be installed must have values of C10 and C100 higher than CB10 and CB100. – Example: on blackboard. 130 Energy Technology A. Y. 2006-07 Isolated PV systems (XIII) • Simulation method: – For prefixed values of batteries’ capacity and panels’ area, this method determines the fraction of the energy to be supplied by an auxiliary source as consequence of the loss of charge of the batteries (LC). – Usable battery capacity: CBu = CB100·PD100. – Daily energy balance on the battery ⇒ charge state at the end of the day d: Balance = Bd = Bd −1 + H d ·η · A Dd − CBu CBu 131 Energy Technology A. Y. 2006-07 Isolated PV systems (XIV) • Simulation method: – The former value is set to 1 if it is higher than 1. – If charge state is not enough to meet the demand of the following day, the battery is charged with the auxiliary system: Bd ·CBu ≥ Dd ⇒ Eauxd = 0 Bd ·CBu < Dd ⇒ Eaux d = CBu ·(1 − Bd ) – With fixed values of A and CBu, the values of Eauxd are calculated for a high enough period of time. 132 Energy Technology A. Y. 2006-07 Isolated PV systems (XV) • Simulation method: – The fraction of the demand to be covered with the auxiliary generator is calculated by: LC = n n d =1 d =1 ∑ Eauxd ∑ Dd – It is possible to get a certain value of LC with different combinations of values of A and CBu. – The usual installations are designed for values of LC between 0.1 and 0.01. 133 Energy Technology A. Y. 2006-07 Bibliography (I) • José Mª de Juana et al., Energías Renovables para el Desarrollo, Paraninfo, Madrid, 2002. • Tomas Markvart, Solar Electricity, John wiley & Sons Ltd., West Sussex, 1994. • Mukund R. Patel, Wind and Solar Power Systems, CRC Press LLC, Boca Raton, 1999. • Ann-Marie Borbely, Jan F. Kreider, Distributed Generation, CRC Press LLC, Boca Raton, 2001. 134 Energy Technology A. Y. 2006-07 Bibliography (II) • Eduardo Lorenzo, Electricidad Solar. Ingeniería de los Sistemas Fotovoltaicos, Progensa, Sevilla, 1994. • Instituto para la Diversificación y Ahorro de la Energía (IDAE), Manuales de Energías Renovables, 6- Energía solar fotovoltaica, Edición especial Cinco Días, Madrid, 1996. 135 Energy Technology A. Y. 2006-07