J1me 7, 1966 F. A. SCHWERTZ 3,254,998 INDUCTION IMAGE FORMATION Filed April 2, 1962 INVENTOR. FREDERICK A. SCHWERTZ ,3 QQQ ATTORNEY United States Patent 0 " 3,254,998 Patented June 7, 1966 l 2 3,254,998 radiation exposure of an original copy thus according more ef?cient, expeditious image formation than known Frederick A. Schwertz, Pittsford, N.Y., assignm- to Xerox plate structures as an inducing member, the invention INDUCTION IMAGE FORMATION gorporation, Rochester, N.Y., a corporation of New or r ‘ by the prior art. In addition by employing multiplying accords increased speed sensitivity in the inducing of electrostatic latent images onto an insulating rectifying layer. The image thus induced may thereafter be utilized in any of the conventional forms of xerography. Accordingly, the instant invention has for an objective 10 the formation of electrostatic latent images on insulating In the process of xerography, for example, as ?rst dis rectifying layers simultaneous with an exposure of area closed in Carlson patent 2,297,691, issued October 6, of a photo-responsive member adjacent and across said 1942, a zerographic plate comprising a layer of photo layer. In accordance with this objective, images formed Filed Apr. 2, 1962, Ser. No. 184,326 8 Claims. _(CI. 96-11) This invention relates to xerography and in particular‘ to improved method and apparatus for charge deposition. conductive insulating material on a conductive backing employing high speed multiplying xerographic plates are is given a uniform electric charge over its surface and is 15 induced into an adjacent insulating rectifying layer and then exposed to the subject matter to be reproduced, usual there preserved for further processing. ly by conventional projection techniques. This exposure It is a further object of the invention to provide im discharges the plate areas in accordance with the radia proved method and apparatus for induction formation tion intensity that reaches them, and thereby creates an of image patterns on insulating rectifying layers. electrostatic latent image on or in the photoconductive 20 It is a further object of the invention to provide im layer. The latent image thus formed may thereafter be proved novel method and apparatus for induction for utilized, as for example, by being developed with an elec troscopic powder which may be af?xed to the xerographic mation of image patterns on insulating rectifying layers during exposure. plate, or optionally transferred to a secondary support It is a further object of the invention to form induced surface on which it is affixed, or the latent image may be 25 charge patterns on insulating rectifying layers from pat utilized without development as though sensing or for terns of activating radiation having a lower radiation in transfer to other surfaces by techniques known in the tensity than was required for image formation by method and apparatus known heretofore. art. Various means of charge deposition are known in the It is still a further object of the invention to device art of xerography including corona charging and a form 30 novel apparatus and method to induce charges on insulat of induction charging as disclosed, for example, in the above-cited Carlson patent for depositing charge onto a xerographic plate. After depositing a charge uniformly onto a xerographic‘plate, it is usual to discharge the plate selectively on exposure to radiation of predetermined intensity as to form an electrostatic latent image. Recently there has been discovered a novel method of inp rectifying layers in predetermined pattern con?gura tionr formed substantially simultaneously with exposure of a high speed xerographic plate. Embodiments of the invention are illustrated in the following drawings in ‘which: FIG. 1 is a sectional view of an embodiment of ap paratus in accordance with the invention; and, FIG. 2 is a sectional view of an embodiment of a depositing electrostatic ‘charge onto insulating surfaces continuous automatic apparatus in accordance with the by principles of induction wherein the chargeable mem ber comprises an insulating layer of current insulating 40 invention. Referring to FIG. 1, there is illustrated apparatus in rectifying material that preferentially conducts one polar cluding support means 10 to support original copy 11 to ity of charge carrier and like a diode, conducts in one be reproduced. Copy 11 is exposed through a conven direction only. This prior method ?rst charges or al tional objective lens 12 supported in a suitable light-tight ternatively charges and exposes a xerographic plate con ventionally, which charge is then employed to correspond 45 housing 13 enclosing the radiation and light sensitive mem bers utilized for image formation. Supported in the focal ingly charge the insulating rectifying layer. plane of the lens is a photoconductive member, gen In the art of xerography, most plate members when erally designated 14, that may comprise, for example, a charged respond to radiation in a manner such that each xerozgraphic plate having a p‘hotoconductive layer 15 of the plate surface produces less than one charge carrier 50 vitreous selenium overlying a conductive member which unit of radiation energy, such as a photon, exposed to _to dissipate the charge. There are also known plate mem bers which result in multiplication effects. These effects are attributed to solid state qualities that cause a multi in this embodiment is transparent and may comprise a transparent coating 16 such as tin oxide on an insulating glass transparent base 17. ' The induced image ‘is to be formed on an insulating plication of charge carriers so that the plate exhibits in creased speed sensitivity when exposed to the same unit 55 rectifying plate, designated 22, that may, for example, comprise ‘a vitreous selenium layer 23 supported on an interfacial layer 24 such as copper oxide, in turn overly ing a conductive backing member 25. intensity of radiation as compared to conventional plates, A potential from a source 30 is applied across the or contra, effects more rapid dissipation on exposure at the same level of radiation intensity. These multiplying 60 sandwich as shown for a predetermined programmed period controlled by a suitable timing device 31 to form plates, however, although exhibiting greater sensitivity an induced electrostatic latent image on the surface of ‘than conventional plates, are also characterized by high of radiation energy. This then results in an equivalent charge dissipation of the plate on exposure to a lower or rapid dark decay properties. That is, these multi plying plates are unable to retain an applied charge in the layer 23. On energizing of the timer, there is applied a potential between the conductive layers while simultane absence of radiation, such that images of charge formed 65 ously, through relay 32, lamps 33 are energized from a during exposure decay too rapidly to be developed. Now in accordance with the instant invention, there is 110 volt source to illuminate the pattern of copy 11. As the copy pattern is illuminated, the light image-of the copy renders layer 15 selectively conductive in pattern con?guration corresponding to the light areas of the copy provided novel improved method and apparatus for in ducing charge into insulating rectifying layers. By means 70 to form an electrostatic latent image on the interface sur of the invention, electrostatic latent images are induced face of layer 15. The pattern thus formed at the interface onto the insulating rectifying layer simultaneous with a 3,254,998 3 4 . is effective to induce on the surface of layer 23, an op 67 at an erase station 74. posite polarity charge in position in adjacent areas across mechanism, plate power supply, and erasure mechanism may be placed in inoperative condition and the apparatus the areas of charge on surface 15 and conforming also to the configuration of the pattern of copy 11. After run as a copy duplicator. Alternatively, the exposure That is, following movement separating the plate 22 from plate 14, the electrostatic of drum 35 past the image forming station 50, there latent image induced on the surface of layer 23 can be utilized for development, as in the process of xerography, can be used to subsequently induce image patterns onto exists on the drum surface an induced image pattern of secondary insulating rectifying layers to be described, or insulating rectifying layer is supplied from a supply spool can be used for such other utilization purposes known to those in the art. Thus, following the application of a selective ?eld pattern of an original image, there is in duced a charge pattern on the insulating rectifying layer conforming in con?guration to the pattern of copy 11. charge. This pattern is advanced to induction image stations 51 and 52 whereat a web member 53 having an 70 and moves around a roller 71 which, as illustrated in this embodiment, is maintained at ground potential. Speed of movement of members 53 is synchronized with the speed of rotation of drum 35 and as the drum surface contacts the surface of web 53, charge patterns The image formed on layer 15 will remain on its surface 15 previously induced on the‘ drum surface cause re-induc for a period depending on the decay rate property of tion onto the surface of plate members 53. The insulat the photoconductor used. If layer 15 has a low decay ing rectifying layer of web 53 may in this embodiment rate, the image can be reused for subsequent induction comprise a layer of zinc oxide in an insulating binder charging without the necessity of reg-exposing under an applied ?eld. On the other hand, even with a low decay rate characteristic, if it is not desired to reuse this image, overlying a conductive backing such as foil or paper in a conductive condition or the like. With a positive charge pattern on the surface of drum 35, negative charge pat it can be erased by \a uniform illumination of light from terns conforming in con?guration to the image pattern lamps 34 under control of a suitable On-Off switch. projected will be formed on the surface of members 53 Reference is not had to FIG. 2 in which is illustrated at the charge induction stations 51 and 52. an embodiment of an automatic apparatus employing the 25 Following image induction at stations 51 and 52, instant invention. An insulating rectifying layer in the members 53 are advanced out of contact with the surface form of a cylindrical drum, generally designated 35, in of drum 35 and are advanced through processing sta accordance with the invention may comprise, for example, tions 72. At the process stations, the charge patterns on a vitreous selenium layer 40 overlying a copper oxide the surface of 53 may be developed and fused to form interlayer 41 on a conductive aluminum base 42 and 30 duplicate hard copy or may be otherwise utilized as, for which drum is mounted for rotation about a shaft 43 example, through scanning or the like to create electrical that is driven continuously by a motor M—l. Drum 35 ' signals for utilization as for display on cathode-ray tubes is driven in the direction indicated by the arrow and or the like. Following passage through the process sta moves ?rst through an image forming station 50, to be tions, members 53 are advanced onto takeup spools 73. described, and next to image induction stations 51 and 35 As is well known in the art, these webs may be cut into 52 whereat the induced image formed at station 50 is appropriate lengths and stacked rather than fed to take utilized for forming secondary induction images on plate members 53 having an insulating rectifying layer of op posite polarity characteristics to that of drum 35 as will be understood. ' Original copy that is to be reproduced may, for ex ample, be contained on a continuous micro?lm web,59 although any conventional copy source and projection technique known in the art of xerography or photography can be employed in the alternative. The ?lm web is continuously advanced by means of a motor M—2 from a supply reel 60 to a takeup reel 61 inbetween which it passes an illumination source comprising, for example, a lamp 62 and a condenser lens 63. The image pattern up spools as shown. Alhough two charge induction stations are shown, it should be realized that in the concept of the instant in 40 vention the image on drum 35 is in no way affected while the charge is induced into an adjacent member such as web 53. Accordingly, any number of stations may be positioned around the charge inducing member, which in this instance is drum ,35, to induce charge into adjacent members substantially any number of times. After pass ing the induction stations, drum 35 is advanced through an erase station 74 whereas the insulating rectifying layer, which is also photoconductive, may be illuminated with light to erase the charge pattern from its surface and is optically projected by an objective lens 64 which may, 50 thus prepare'the drum for recycling. if desired, have a focal length adapted to effect projection In each of the described embodiments, it has been at a desired magni?cation ratio. The light image is pro considered that the insulating rectifying material is jected downward in this embodiment through a projection chosen on exposure to generate .a range of charge carries slit 65 onto an advancing p‘hotoconductive member 66, sufficient to‘operate as described. Where the circum that may be constructed similarly as member 14 of FIG; 55 stances require, the range may be enhanced by applying I, and continuously energized from a power source selective levels of heat or radiation as by employing 69. Drum 35 moves at a synchronous rate with the rate a transparent substrate 25 through which light can be of the projected image and member 66 is driven through applied in conjunction with the exposure step. Thus a suitable gear-Wheel 68 from motor M—l at a linear rate identical with the peripheral rate of drum 35. For il lustrative purposes, member 66 is shown of ?nite length which will necessitate its being returned to a leftmost starting position between exposures out of physical con it was found thatwhen using a 11/2 mil zinc oxide plate formed of a zinc oxide photoconductor in a silicone 'binder on an aluminum substrate, spaced opposite a NESA (tin oxide) backed vitreous selenium plate on a transparent glass substrate, a satisfactory image was in tact with drum 35 if the latter continues to rotate. Al duced on the zinc oxide surface. The air gap between ternatively, member 66 can be constructed of ?exible ma 65 the two surfaces was believed to be less than about ?ve terial or connected rigid segments and made endless for microns in thickness and as uniform as possible. The continuous recycling. In the latter instance there will image was formed of a photographic negative placed on the glass substrate of the selenium and rear illumination illumination (not shown) to eliminate unwanted patterns from a high intensity light source of about 4500 ang remaining on surface 15 after utilized for induction, and 70 stroms effectively placed a shadow image on the selenium means to offset the endless member after image formation surface. Simultaneously, a potential on the order of ap around‘the projection path as to avoid interfering with proximately 600 volts was connected to the substrates be required an image erasure means, such as a source of the image being projected. Operation of the unit can be continuous with drum 35 with the negative pole being connected to the aluminum substrate and the positive pole connected to the NESA. being constantly recycled after erasure by an erase unit 75 The voltage was applied for a period of approximately 3,254,998 5 6 30 seconds after which the two electrodes were shorted since a ?ow of positive charge through the zinc oxide binder layer would be required. In this latter instance, a out and the plates separated. After separation, a nega tive voltage of greater than 200 volts was found to have been induced onto the zinc oxide surface. This charge, which constituted a latent electrostatic pattern of the p-type semiconducting storage or insulating rectifying layer would be necessary to achieve a similar result. In general, the induction of a positive electrostatic im negative image, was developed by well-known techniques age from the photoconductor requires a semiconducting of xerography and resulted in a sharp, dense image as is storage layer or insulating rectifying layer in which the commonly associated with a large negative charge. An available current carrier is the electron. Conversely, for opposite positive charge was formed on the selenium the induction of negative electrostatic images from the surface. 10 photoconductor, the available current carrier must be the Brie?y ‘as understood, there are basically two forms positive hole. Therefore, with a proper selection of appro of insulating rectifying materials, those which are pref priate materials, a latent image having a polarity of choice erentially conductive with a majority of charge {carriers opposite the photoconductor may be induced and subse for positive charge carriers (holes), are termed “p” type, quently utilized as is conventional in the xerographic proc and those conductive for negative charge carriers (elec 15 ess. trons) are termed “11” type. While zinc oxide had been prominently mentioned as the rectifying layer with which the process of the invention Some materials may re spond in varying degrees to either form of charge carrier but being substantially insulators as all insulating rectify ing layers contain virtually no intrinsic charge carriers but rather possesses only those charge carriers injected 20 therein from an external source or generated therein by may be carried out, other semiconductors which will form highly rectifying contacts to a conducting support, and which need not be inherently photoconductive, would also form suitable storage or insulating rectifying layers. In other Words, it is essential that current flow into the semi the activity of activating radiation. The zinc oxide bind~ er layer has the apparent property of being “it” type. In conductive layer or insulating rectifying layer only when any event negative charges attracted to the selenium biased in the forward direction by the electrostatic image charge are injected from the binder layer substrate, pass 25 being formed on the photoconductive surface that is ef through the binder layer, and 1are trapped at the ‘binder fective to induce the image on the surface of the insulat layer top surface. These immobilized charges on the ing rectifying layer. binder layer become ?xed when the binder plate and the The insulating rectifying layers may contain the de selenium plate are separated in the dark. The binder sired properties for use in the instant invention or they layer, therefore, being an insulating rectifying layer, has 30 may be so rendered. Thus Where the insulating layer is it self insufficiently rectifying, i.e., conducts both polarities equally or is only slightly p-type or n-type, recti?cation come trapped near or at the top surface. The potential may be supplied by forming a highly rectifying barrier thus induced on the insulating recti?er layer can be com layer between the insulating layer and the conductive parable to normal xerographic potentials since it is known 35 backing which injects charge carriers into the insulator that the series capacitance of the insulating recti?er layer or alternatively, the layer may be doped. As stated above, during the photoconductor exposure, while biased in the zinc oxide is strongly n-type so that modi?cation of the conductive direction, is effectively in?nite. The actual material either by doping or by the interposition of a bar capacitance of the insulating recti?er layer, which be rier layer between the zinc oxide and the conductive the property that application of a small electrostatic ?eld causes charges to be injected from the substrate to be comes etfective on dis-assembly, can be made comparable 40 electrode are unnecessary for utility herein. with the capacitance of normal xerographic plates. Therefore in accordance with the invention, semi-con ductive ?lms orrinsulating rectifying layers have been found for which the conductivity differs substantially de pending upon the direction of the impressed electric ?eld. As shown by the above example, plates comprising a ?lm Vitreous selenium is p-type and commercial xerographic plates on an aluminum backing may be used as describedéherein. However, as a properly prepared selenium layer is only slightly p~type, the use of such unmodi?ed layers results in moderately long charging times. By the addition of a rectifying barrier layer such as cuprous oxide between the vitreous selenium and the conductive backing, the found to sustain a negative surface charge and are known charging time ‘may be reduced to the order of 1 or 2 to sustain negative surface charge many times longer than seconds. Alternatively, the selenium may be doped to 'they will support a positive surface charge. In other 50 either render it highly p-type or even to reverse the polar words, this ?lm can be made to serve as a resistor-diode ity of the major charge carriers to render the material n conducting electrons from the base to the surface at a ty-pe. Thus, as disclosed in U.S. 2,863,768, when alloyed much greater, rate than in the opposite direction under with arsenic trisul?de, selenium becomes highly n-type ‘an equal but. opposite ?eld. Further, such conduction while still being an elfective photoconductive insulator. . of zinc oxide in ‘a binder coated on aluminum have been will take place Without light exposure but only because 55 Tellurium is also a suitable additive to selenium to render of the applied ?eld. The distribution of negative charges , induced on the zinc oxide surface is a mirror image of a vitreous selenium layer n-type. The selenium may also be rendered more highly p-type by the inclusion of very the positive electrostatic image formed on the selenium minor amounts of halogen. In the case of doping with a surface. These negative charges remain on the zinc oxide halogen, care must be taken to prevent the inclusion of surface and form a negatively charged electrostatic latent 60 too much impurity which would render the material too image. When the separation is carried out in air, some conductive for use as a photoconductive insulator. air breakdown has been found to occur causing the nega As should be apparent, substantially all known photo tively induced image to be of a reduced magnitude than conductive insulating layers can be employed in connection that formed on the selenium plate. Where separation is with this invention, either intrinsically or as modi?ed ac carried out in a vacuum or with a controlled potential, 65 cording to the teaching herein, and included Within this this presents no problem. That is, a control potential may group, for example, are semiconductive materials cooled ‘be provided between the rbases during separation as, for below the temperature necessary for thermal generation example, disclosed in copending application Serial vNo. of charge carriers therein which thus act as insulators. 747,542, ?led July 9, 1958, now U.S. Patent No. 3,057, Therefore in the instant invention, it is essential that 719, in the names of Walkup and Byrne. 70 the charge inducing member induce a developable charge density on the insulating rectifying layer. To accomplish Thus in the zinc oxide binder layer, electric current is carried by electrons and holes make no appreciable contri this, there must be a su?icient magnitude of potential avail bution to the current. If the latent image on the selenium able from a potential source and the intensity level of the > activating radiation must be sufficiently high to render surface were composed of negative charges, the process described above ‘would not work as well with Zinc oxide, 75 the charge inducing member sufficiently and selectively 3,254,998 7 8 conductive in an allotted charging time. Most photocon ductors employed in xerography, such as vitreous seleni um, have a quantum e?iciency of somewhat less than unity. This means that, at best, for each photon of light which Pressure exerted on the backs of the respective plates has found to reduce the air ?lm thickness to accord in duced potentials of higher order. Also the use of insulat ing liquids of high speci?c conductive capacitance in place strikes a xerographic plate, one “electron” or “hole” is of the air ?lm has also been found to increase the gap removed. capacitance. By obtaining charge-carrier multiplication . . whereby each absorbed photon will produce- many charge carriers within the plate, there results quantum e?iciency greater than unity. In other words, by carrier multiplica The advantages of the invention should be instantly apparent in that it accords expeditious induction of elec trostatic latent images on insulating rectifying layers si tion is meant causing ?ow of more than one electronic 10 multaneous with exposure while according increased sensi charge (in excess of dark current) by the action of each tivity of response to radiation by the use of multiplying photon of light energy incident on a light sensitive medium. plates as the charge inducing member. At the same time This phenomenon of multiplying plates and their struc by means of the invention, “wear and tear” on the delicate tures are disclosed in copending application, Serial No. surface of the inducing photoconductive insulator is large— 714,929, ?led February 12, 1958 in the name of J. Bardeen 15 ly eliminated. That is, since the necessity for developing and now Patent US. 3,041,166. the image on the inducing photoconductor, transferring The instant invention when used with multiplying plates of the type described in the above referred to Bardeen the developed image and cleaning off the residual powder is eliminated, physical damage to a fragile surface such patent captures the image while preserving speed. It is knownthat the time necessary to induce a charge onto the 20 surface of an insulating recti?er layer to a potential within as vitreous selenium is at an absolute minimum. In the above description, there is disclosed a novel method and apparatus for induction-charging of an in l/e of its ?nal value, is the product of the resistivity of sulating rectifying layer. From the discussion of the in the material, measured in the conductive direction, times vention in connection with the drawings, there will be the dielectric constant of the material expressed in MKS units. Because of this factor, it is necessary to either main 25 suggested obvious modi?cations and variations to those skilled in the art and such variations and modi?cations tain contact for an adequate time to effect desired charge are intended to be included in the scope of this invention density or to provide a greater charge density in the and, it is intended to cover the invention broadly within charge inducing member and allow charge to be induced for less time as required for equilibrium, to result in a the claims. For example, in FIG. 2, a ?at plate could charge deposit on the insulating rectifying layer equal to 30 be substituted for drum 35. Also, for a full frame ex what is desired. Now however, in accordance with the instant invention, the induction time may be decreased posure, a ?at plate could be stopped momentarily during exposure instead of a continuous slit exposure as illus by utilizing multiplier photoconductors as charge induc ing members having a quantum e?iciency greater than trated. What is claimed is: unity. ' 35 1. A method of forming an electrostatic latent image The multiplying e?ect is produced when using photo of original copy by induction on a ?rst plate comprising conductors such as cadmium sul?de and cadmium selen an insulating rectifying layer supported on a conductive ide. Therefore, in the instant invention, the photocon substrate and capable of allowing ?ow of current in a tive layer designated 15 can be constituted of a pho ?rst direction and substantially insulating in the reverse toconductive material such as cadmium sul?de to achieve 40 a desired quantum multiplication. With such an arrange ment, less light is required to achieve the desired charge direction including: (a) placing a second plate comprising a photoconduc tive insulator overlying a conductive radiation trans density on the surface of plate'23. By this means the mitting substrate with the surface of the insulator rate of induced image formation, especially in automatic in closely spaced substantially contiguous relation machines, can be increased dependent on the multiplica ship to the surface of a ?rst plate on which an image tion effect available with the photoconductor employed. Thus, the handicap of high dark decay characteristics associated with these multiplying plate structures is im is to be formed; (b) connecting a charging potential between the sub strates of said plates; and, (c) while said potential is connected exposing said sec ond plate to an activating radiation image of original material in the instant invention in which it is not neces sa'ry that the charge formed on the surface of the induc ing member be developable. Rather, in accordance with the invention, retention of charge by the inducing mem ber may totally be unnecessary beyond being utilized to copy for a time period su?icient to inducev a charge pattern of the copy on the surface of the ?rst plate. 2. The method according to claim 1 in which said sec induce an image pattern onto an insulating rectifying ond plate comprises a material having a quantum e?icien layer. Therefore in ‘accordance with the instant inven 55 cy greater than unity. tion, utilizing simultaneous application of ?eld and ex _ 3. A method of forming an electrostatic latent image posure, a photoconductor having a quantum ef?ciency of of original copy by induction on a ?rst plate comprising greater than unity may be utilized to advantage to in an insulating rectifying layer supported on a conductive duce charge patterns on insulating rectifying layers in substrate and capable of allowing ?ow of current in a place of other photoconductors usually used in commer 60 ?rst direction and substantially insulating in the reverse cial xerography. Since the highest possible image potential or charge on the insulating rectifying layer is the desired goal, the direction including: (a) placing a second plate comprising a photoconduc space between surfaces ‘during the induction formation should be as small as possible. Since the induction image 65 should faithfully represent the original image, all capaci In the case of an air ?lm, this means (b) connecting a charge potential between the sub that the presence of dust particles could constitute a criti~ cal factor, and should therefore consciously be excluded. 70 Also ‘preferably, although not necessarily, the insulating rectifying layer, the photoconduc-tor layer or both should be su?iciently ?exible to conform to the irregularities of strates of said plates; ‘ v (c) while said potential is connected exposing said second plate through the transparent substrate to an activating radiation image of original copy for a time period su?icient to induce a charge pattern of the copy on the surface of the insulating rectifying the other surface as to minimize the extent of interference caused by occasional dust particles or the like. spaced substantially contiguous relationship to the insulating rectifying layer surface of a ?rst plate on which an image is to be formed; tance should preferably be uniform throughout the entire area of interest. tive insulator overlying a conductive transparent sub strate with the surface of the insulator in closely 75 layer; and, ' 3,254,998 9 10 (d) separating said plates in a manner to produce an induced charge pattern of original copy on the sur face of said ?rst plate developable with eiectroscopic powder deposition. copy on the surface of the insulating rectifying layer of said ?rst plate; and, (d) placing said induced image bearing surface into 4. The method according to claim 3 in which said second plate comprises a material having a quantum. effi ciency greater than unity. period su?icient to induce. a charge pat-tern of the 1 5. A method of forming an electrostatic latent image of original copy by induction on a ?rst plate comprising an insulating rectifying layer supported on a conductive 10 closely spaced relationship with the surface of an insulating rectifying layer of a third plate whereby a charge pattern of original copy is induced on the surface of the insulating rectifying layer of said third plate. 7. The method according to claim 6 in which the in substrate and capable of allowing ?ow of current in a ?rst sulating rectifying layers of said ?rst and third plates direction and substantially insulating in the reverse direc are predominantly conductive in the direction of current tion more predominantly with one polarity of current than ?ow to current of opposite polarities. the other including: 8. In the method of Xerography in which developable (a) placing a second plate comprising a photoconduc 15 electrostatic latent images are formed on a support sur tive insulator overlying a conductive transparent sub face, the improvement comprising a method of forming an strate with the surface of the insulator in closely electrostatic latent image of original copy by induction spaced substantially contiguous induction charging on the surface of a ?rst plate comprising an insulating relation to the surface of an insulating rectifying rectifying layer supported on a conductive substrate and layer of a ?rst plate on which an image is to be 20 capable of allowing ?ow of current in a ?rst direction and formed; _ (b) connecting opposite poles of a DC. charging po tential between the substrates of said plate with the pole connected to the substrate of the ?rst plate being of the same polarity as the corresponding pre 25 dominance of its conductivity; (c) while said potential is connected exposing an ac tivating radiation image of original copy through the transparent substrate of the second plate for a time period sufficient to induce a charge pattern of the 30 copy on the surface of the insulating rectifying layer of the ?rst plate; and, (d) separating said plates whereby said induced charge pattern of original copy is retained on said insulating rectifying layer and is developable with electroscopic powder deposition. 6. A method of forming an electrostatic latent image of original copy by induction on a ?rst plate comprising an insulating rectifying layer capable of allowing ?ow of substantially insulating in the reverse direction including: (a) placing a second plate comprising a photoconduc tive insulator overlying a conductive transparent sub strate with the surface of the insulator in closely spaced substantially contiguous relationship to the surface of an insulating rectifying layer on a ?rst plate on which an image is to be formed; (b) connecting a charging potential between the sub strates of said plates; (0) 'while said potential is connected simultaneously exposing said second plate through the transparent substrate to an activating radiation image of original copy for a time period su?icient to induce a charge pattern of the copy on the surface of the insulating rectifying layer; and, (d) separating said plates whereby the insulating rec tifying layer retains an induced charge pattern of original copy developable with electroscopic powder deposition. current in a ?rst direction and substantially insulating in References Cited by the Examiner the reverse direction and supported on a conductive sub strate including: (a) placing a second plate comprising a photoconduc tive insulator overlying a conductive transparent sub strate ‘with the surface of the insulator in closely 2,817,277 2;833,648 5/1958 spaced substantially contiguous relationship to the 2,853,383 9/1958 Keck ___________ __ 95——1.7 X insulating rectifying layer surface of a ?rst plate on which an image is to be formed; 2,937,943 2,962,374 5/1960 11/1960 Walkup _________ __ 95—-——1.7 X Dessauer ________ __ 95--—1.7 X UNITED STATES PATENTS 12/1957 ‘BOgdOHOff _________ __ 95—-1.7 Walkup _________ __ 95-17 X (b) connecting a D.‘C. charging potential between the substrates of said plates; 50 NORMAN G. TORCHIN, Primary Examiner. (c) concomitant with connection of said potential, ex EVON C. BLUNK, Examiner. posing the substrate of said second plate to an ac tivating radiation image of original copy for a time D. D. PRICE, Assistant Examiner.