SAFETY DATA SHEET
Unleaded Gasoline
Last changed: 18/11/2011
Replaces date: 01/11/2011
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
Trade name
Synonyms
Unleaded Gasoline
Gasoline
1.2. Relevant identified uses of the substance or mixture and uses advised against
RECOMMENDED USES:
INADVISABLE USES:
Fuel for spark ignition piston engines.
None.
1.3. Details of the supplier of the safety data sheet
NATIONAL MANUFACTURER/IMPORTER
Enterprise
Statoil ASA (Site: Mongstad)
Address
Forusbeen 50
Postal code
N-4035 Stavanger
Country
Norge
Email
Statoil competence center: chem@statoil.com
Tel
+47 56 34 40 00
1.4. Emergency telephone number
Emergency Phone
+47 22 59 13 00
Type of assistance
Giftinformasjonen
Opening Hours
SECTION 2: Hazards identification
2.1. Classification of the substance or mixture
DPD
F+; R12, Xi; R38, Carc. Cat. 2; R45, Muta. Cat. 2; R46, N; R51/53, Repr. Cat. 3; R62, Xn; R65, R67
Classification:
CLP
Flam. Liq. 1;H224, Asp. Tox. 1;H304, Skin Irrit. 2;H315, STOT SE 3;H336, Muta. 1B;H340, Carc.
Classification: 1B;H350, Repr. 2;H361, Aquatic Chronic 2;H411
Most serious
harmful
effects::
Extremely flammable liquid and vapour.May be fatal if swallowed and enters airways.Causes skin
irritation.May cause drowsiness or dizziness.May cause genetic defects.May cause cancer.Suspected
of damaging fertility or the unborn child.Toxic to aquatic life with long lasting effects.
2.2. Label elements
Signal word:
H-phrases
H224
H304
H315
H336
H340
H350
H361
H411
Danger
Extremely flammable liquid and vapour.
May be fatal if swallowed and enters airways.
Causes skin irritation.
May cause drowsiness or dizziness.
May cause genetic defects.
May cause cancer.
Suspected of damaging fertility or the unborn child.
Toxic to aquatic life with long lasting effects.
1 / 12
SAFETY DATA SHEET
Unleaded Gasoline
Last changed: 18/11/2011
P-phrases
P201
P210
P501
P301/310
P403/233
P280
Replaces date: 01/11/2011
Obtain special instructions before use.
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
Dispose of contents/container in accordance with local regulation.
IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
Store in a well-ventilated place. Keep container tightly closed.
Wear protective gloves/protective clothing/eye protection/face protection.
SUPPLEMENTAL HAZARD INFORMATION (EU)
Restricted to professional users.
2.3. Other hazards
The mixture does not meet the criteria for PBT or vPvB.
SECTION 3: Composition/information on ingredients
3.2. Mixtures
Ingredient name
Gasoline;
tert-butyl methyl ether
Reg. no.
EC No.
CAS No.
Conc.
(wt%)
01-2119471335- 289-220- 86290-81- 85 - 100
39-0011
8
5
%
DPD-Classification
CLPclassification
Xn,Xi,F+,N,Carc. Cat. Flam. Liq. 1 H224
2,Muta. Cat. 2,Repr. Skin Irrit. 2 H315
Cat. 3,R38 - R45 Muta. 1B H340
R46 - R51/53 - R62 - Carc. 1B H350
R65 - R67 - R12
Repr. 2 H361
STOT SE 3 H336
Asp. Tox. 1 H304
Aquatic Chronic 2
H411
01-2119452786- 216-653- 1634-04- 0 - 15 % Xi,F,R38 - R11
27-0059
1
4
Flam. Liq. 2 H225
Skin Irrit. 2 H315
toluene
203-625- 108-88-3 11 %
9
Xn,Xi,F,Repr. Cat.
Flam. Liq. 2 H225
3,R38 - R48/20 - R11 Skin Irrit. 2 H315
- R63 - R65 - R67
Repr. 2 H361d
STOT SE 3 H336
STOT RE 2 H373
Asp. Tox. 1 H304
benzene
200-753- 71-43-2
7
T,Xi,F,Carc. Cat.
1,Muta. Cat. 2,R36/38
- R45 - R46 R48/23/24/25 - R11 R65
Flam. Liq. 2 H225
Skin Irrit. 2 H315
Eye Irrit. 2 H319
Muta. 1B H340
Carc. 1A H350
STOT RE 1 H372
Asp. Tox. 1 H304
n-hexane
203-777- 110-54-3 > 3 %
6
Xn,Xi,F,N,Repr. Cat.
3,R38 - R48/20 R51/53 - R11 - R62 R65 - R67
Flam. Liq. 2 H225
Skin Irrit. 2 H315
Repr. 2 H361f
STOT SE 3 H336
STOT RE 2 H373
Asp. Tox. 1 H304
Aquatic Chronic 2
H411
0-5%
Full text of R-, H- and EUH-phrases: see section 16.
The EUH hazard statements mentioned in CLP-classification are only label elements.
SECTION 4: First aid measures
4.1. Description of first aid measures
INHALATION
Seek fresh air. Seek medical advice in case of persistent discomfort.
2 / 12
SAFETY DATA SHEET
Unleaded Gasoline
Last changed: 18/11/2011
Replaces date: 01/11/2011
INGESTION
Wash out mouth thoroughly and drink 1-2 glasses of water in small sips. Do not induce
vomiting. If vomiting occurs, keep head low so that stomach contents do not enter lungs.
Immediately call a POISON CENTER or doctor/physician.
SKIN
Remove contaminated clothing. Wash skin with soap and water. Seek medical advice in case of persistent discomfort.
EYES
Flush with water (preferably using eye wash equipment) until irritation subsides. Seek medical
advice if symptoms persist.
BURNS
Flush with water until pain ceases. Remove clothing that is not stuck to the skin - seek medical
advice/transport to hospital. If possible, continue flushing until medical attention is obtained.
GENERAL
When obtaining medical advice, show the safety data sheet or label.
4.2. Most important symptoms and effects, both acute and delayed
May cause chemical pneumonia if ingested or vomited. Causes skin irritation. May cause
genetic defects. May cause cancer. Suspected of damaging fertility or the unborn child. The
product releases organic solvent vapours which may cause lethargy and dizziness. At high
concentrations, the vapours may cause headache and intoxication.
4.3. Indication of any immediate medical attention and special treatment needed
In case of shortness of breath, give oxygen. Keep victim warm. Ensure that medical personnel
are aware of the material involved, and take precautions to protect themselves. Epinephrine
and other sympathomimetic drugs may initiate cardias arrhythmias in persons exposed to high
concentration of hydrocarbon solvents (e.g. in enclosed spaces or with deliberate abuse). The
use of other drugs with less arrhythmogenic potential should be considered. If
sympathomimetic drugs are administered, observe for the development of cardiac arrhythmias.
SECTION 5: Firefighting measures
5.1. Extinguishing media
SUITABLE EXTINGUISHING MEDIA:
Extinguish with powder, foam, carbon dioxide or water mist. Use water or water mist to cool
non-ignited stock.
UNSUITABLE EXTINGUISHING MEDIA
Do not use water stream, as it may spread the fire.
5.2. Special hazards arising from the substance or mixture
Explosive mixtures may form with air when heated/exposed to fire. Heating will cause a rise in
pressure in packaging with a risk of bursting. Can generate harmful flue gases containing
carbon monoxide in the event of fire.
5.3. Advice for firefighters
Wear Self-Contained Breathing Apparatus (SCBA) with a chemical protection suit. Move
containers from danger area if it can be done without risk. Avoid inhalation of vapour and flue
gases - seek fresh air.
SECTION 6: Accidental release measures
3 / 12
SAFETY DATA SHEET
Unleaded Gasoline
Last changed: 18/11/2011
Replaces date: 01/11/2011
6.1. Personal precautions, protective equipment and emergency procedures
FOR NON-EMERGENCY PERSONNEL
Smoking and naked flames prohibited. Take precautionary measures against static discharges.
Use spark-free tools and explosion proof equipment. Wear gloves. Stay upwind/keep distance
from source. Keep unnecessary personnel away. Provide good ventilation.
FOR EMERGENCY RESPONDERS
In addition to the above: Chemical protective suit equivalent to EN 943-2 is recommended.
6.2. Environmental precautions
Stop leak if this can be done without risk. Prevent spillage from entering drains and/or surface
water. Notify proper authorities in case of contamination of soil or aquatic environment or
discharge to drains.
6.3. Methods and material for containment and cleaning up
METHODS AND MATERIAL
Contain and absorb spill with sand or other absorbent, non-combustible material and transfer to
suitable waste containers.
6.4. Reference to other sections
See section 13 for instructions on disposal.
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Work under effective process ventilation (e.g. local exhaust ventilation). Running water and eye
wash equipment must be available. Smoking and naked flames prohibited. Take precautionary
measures against static discharges. Use spark-free tools and explosion proof equipment. Do
not store, use and/or consume foods, beverages or tobacco products in the work room. Store
personal protective equipment separately from other clothing. Wash hands before breaks,
before using restroom facilities, and at the end of work.
7.2. Conditions for safe storage, including any incompatibilities
Store safely, out of reach of children and away from food, animal feeding stuffs, medicines, etc.
Keep in tightly closed original packaging. Store in a well-ventilated area.
7.3. Specific end use(s)
None.
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
LEGAL BASIS
EH40/2005 Workplace exposure limits incl. supplement from October 2007.
MONITORING PROCEDURES
Compliance with the stated occupational exposure limits may be checked by occupational
hygiene measurements.
4 / 12
SAFETY DATA SHEET
Unleaded Gasoline
Last changed: 18/11/2011
Replaces date: 01/11/2011
OTHER INFORMATION REGARDING LIMIT VALUES AND MONITORING
Occupational exposure limits:
Ingredient: toluene
Exposure limit: 50 (8h), 100 (15m) ppm, 191 (8h), 384 (15m) mg/m3
Remarks: Sk
Ingredient: n-hexane
Exposure limit: 20 (8h), - (15m) ppm, 72 (8h), - (15m) mg/m3
Ingredient: tert-butyl methyl ether
Exposure limit: 25 (8h), 75 (15m) ppm, 92 (8h), 275 (15m) mg/m3
Ingredient: benzene
Exposure limit: 1 (8h), - (15m) ppm, - (8h), - (15m) mg/m3
Remarks: Sk, Carc
Remarks: Sk: Can be absorbed through skin
Carc: Capable of causing cancer and/or heritable genetic damage.DNEL values: Worker:
86290-81-5:
Inhalation DNEL (acute/short-term exposure - systemic effects), 1300mg/m3/15 m, Assessment
factor 3, Dose descriptor LOAEC, Most sensitive endpoint
Inhalation DNEL (acute/short-term exposure - local effects), 1100mg/m3/15 m, Assessment
factor 3
Dose descriptor LOAEC
Inhalation DNEL (long-term exposure - local effects), 840mg/m3/8h, Assessment factor 6, Dose
descriptor NOAECPopulation in general:
Inhalation DNEL (acute/short-term exposure - systemic effects)
1200 mg/m3/15 m
Assessment factor 5
Dose descriptor LOAEC
Inhalation DNEL (acute/short-term exposure - local effects)
640 mg/m3/15 m
Assessment factor 5
Dose descriptor LOAEC
Inhalation DNEL (long-term exposure - local effects)
180 mg/m3/15 m
Assessment factor 10
Dose descriptor NOAECPNEC values: 86290-81-5:
PNEC aqua (freshwater) 2,6 , Assessment factor: 1
PNEC aqua (marine water) 13,8 mg/l, Assessment factor: 1
8.2. Exposure controls
EXPOSURE SCENARIOS
See enclosed exposure scenarios for further information.
APPROPRIATE ENGINEERING CONTROLS
Wear the personal protective equipment specified below.
EYE PROTECTION
Wear safety goggles if there is a risk of eye splash. Eye protection must conform to EN 166.
HAND PROTECTION
In case of direct skin contact, wear protective gloves of e.g. nitrile rubber. Penetration time: >8
hours. Gloves must conform to EN 374. Wear coveralls.
5 / 12
SAFETY DATA SHEET
Unleaded Gasoline
Last changed: 18/11/2011
Replaces date: 01/11/2011
RESPIRATORY PROTECTION
Light use (small volume, shortterm contact (below 10 min.)):
Not required.Medium use (medium volume, medium contact (1-2 hours)):
In case of insufficient ventilation: Wear respiratory protective equipment. Filter type: A/AX.Heavy use (high volume,
longterm contact (more than 2 hours)):
In case of insufficient ventilation: Wear fresh air respiratory protective equipment.Respiratory protection must conform
to one of the following standards: EN 136/140/145.
OTHER INFORMATION
Ensure compliance with local regulations for emissions.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
STATE
Liquid.
COLOUR
Colourless
ODOUR
Gasoline
SOLUBILITY
N/A
EXPLOSIVE PROPERTIES Non-explosive
OXIDISING PROPERTIES Non-oxidising.
Parameter
pH (concentrate)
pH (solution for use)
Melting point
Freezing point
Initial boiling point and boiling range
Flash point
Evaporation rate
Flammability (solid, gas)
Flammability limits
Explosion limits
Vapour pressure
Vapour density
Relative density
Partition coefficient
Auto-ignition temperature
Decomposition temperature
Viscosity
Odour threshold
Value/unit
No data
No data
­60 °C No data
31,30 ­ 191,60 °C < ­40 °C No data
No data
No data
No data
4 - 240 kPa
No data
0,62 - 0,88
280 ­ 470 °C No data
< 1 mm2/s
N/A
Method/reference
N/A
N/A
Observation
N/A
Extremely flammable
N/A
(37,8 °C ) N/A
(15 °C ) N/A
N/A
(37,8 °C ) 9.2. Other information
Parameter
Upper/lower flammability limits:
Note no.
Value/unit
1,4-7,6%
Method/reference
Observation
Comments
OTHER INFORMATION
None.
SECTION 10: Stability and reactivity
10.1. Reactivity
Not reactive.
6 / 12
SAFETY DATA SHEET
Unleaded Gasoline
Last changed: 18/11/2011
Replaces date: 01/11/2011
10.2. Chemical stability
The product is stable when used in accordance with the supplier´s directions.
10.3. Possibility of hazardous reactions
None known.
10.4. Conditions to avoid
Avoid heating and contact with ignition sources. Prevent vapour accumulation.
10.5. Incompatible materials
Avoid contact with strong oxidising agents. Avoid contact with strong reducing agents.
10.6. Hazardous decomposition products
Product decomposes in fire conditions or when heated to high temperatures, and toxic gases
such as carbonmonoxide may be released.
SECTION 11: Toxicological information
11.1. Information on toxicological effects
Gasoline;
Route of exposure Exposure time
Value/unit
LC50 (Inhalation)
> 5610
Rat, vapour
LD50 (Dermal)
> 2000 mg/kg
Rabbit
LD50 (Oral)
> 5000 mg/kg
Rat
Result
Species
Source Test
method
(OECD
403)
(OECD
402)
(OECD
401)
Acute toxicity - oral
Ingestion may cause discomfort. The product does not have to be classified. Based on existing
data, the classification criteria are deemed not to have been met.
Acute toxicity - dermal
The product does not have to be classified. Based on existing data, the classification criteria
are deemed not to have been met.
Acute toxicity - inhalation
The product does not have to be classified. Based on existing data, the classification criteria
are deemed not to have been met.
Skin corrosion/irritation
Irritating to skin – may cause reddening.
86290-81-5: Rabbit: Irritating (OECD 404)
Serious eye damage/eye irritation
The product does not have to be classified. Based on existing data, the classification criteria
are deemed not to have been met.
86290-81-5: Rabbit, 72h: Iritis: 0 (OECD 405)
7 / 12
SAFETY DATA SHEET
Unleaded Gasoline
Last changed: 18/11/2011
Replaces date: 01/11/2011
Respiratory sensitisation or skin sensitisation
The product does not have to be classified.
86290-81-5: Guinea pig: Non-sensitising (OECD 406)
Germ cell mutagenicity
May cause genetic defects. Test data are not available.
Carcinogenic properties
May cause cancer.
86290-81-5: Neoplastic effects observed.
Reproductive toxicity
Suspected of damaging fertility or the unborn child. Test data are not available.
Single STOT exposure
The product releases organic solvent vapours which may cause lethargy and dizziness. At high
concentrations, the vapours may cause headache and intoxication. Inhalation of vapours may
cause irritation to the upper airways. Test data are not available.
Repeated STOT exposure
The product does not have to be classified. Based on existing data, the classification criteria
are deemed not to have been met.
86290-81-5: Rat, 3750mg/kg bw/day, : NOAEL (dermal) (OECD 410)
Aspiration hazard
May cause chemical pneumonia if ingested or vomited. Test data are not available.
Other toxicological effects
None known.
SECTION 12: Ecological information
12.1. Toxicity
Unleaded Gasoline
Route of exposure Exposure time
Value/unit
Result
Species
EC50 (Acute
48 h
Daphnia)
EC50 (Acute algae) 72 h
4,5 mg/l
Daphnia magna
3,1 mg/l
LC50 (Acute fish)
8,2 mg/l
Selenastrum
capricornutum
Pimephales
promelas
96 h
tert-butyl methyl ether
Route of exposure Exposure time
EC50 (Acute
48 h
Daphnia)
EC50 (Acute algae) 72 h
Value/unit
100 - 1000 mg/l
2300 mg/l
Result
Species
Daphnia sp
Source Test
method
Acute
toxicity
Acute
toxicity
Acute
toxicity
Source Test
method
Acute
toxicity
Acute
toxicity
8 / 12
SAFETY DATA SHEET
Unleaded Gasoline
Last changed: 18/11/2011
Replaces date: 01/11/2011
Toxic to aquatic life with long lasting effects.Chronic toxicity: 86290-81-5:
Fish: Pimephales promelas: 14dNOELR = 2,6 mg/l
Crustacea: Daphnia magna: 21dNOEC = 2,6 mg/l
12.2. Persistence and degradability
Readily biodegradable.
86290-81-5: Readily biodegradable.
1634-04-4: Not readily biodegradable.
12.3. Bioaccumulative potential
Test data are not available.
12.4. Mobility in soil
The product is predicted to have low mobility in soil and sediment.
12.5. Results of PBT and vPvB assessment
The mixture does not meet the criteria for PBT or vPvB.
12.6. Other adverse effects
None.
SECTION 13: Disposal considerations
13.1. Waste treatment methods
GENERAL REGULATIONS
Avoid discharge to drain or surface water. Collect spills and waste in closed, leak-proof
containers for disposal at the local hazardous waste site.
CATEGORY OF WASTE
EWC code: Depends on line of business and use, for instance 13 07 02 petrol
Absorbent/cloth contaminated with the product:
EWC code: 15 02 02 absorbents, filter materials (including oil filters not otherwise specified),
wiping cloths, protective clothing contaminated by dangerous substances
SECTION 14: Transport information
Classified as Dangerous Goods:
Land transport (ADR/RID)
14.1. UN
1203
number
14.2. UN
Gasoline.
proper
shipping
name
14.3.
3
Transport
hazard
class(es)
Hazard
label(s)
Hazard
33
identification
number
Yes
14.4. Packing
group
14.5.
Environmental
hazards
II
Tunnel
restriction
code
D/E
The product must be labelled as an
environmental hazard (symbol: fish and
tree) in packaging sizes of more than 5
kg/l.
9 / 12
SAFETY DATA SHEET
Unleaded Gasoline
Last changed: 18/11/2011
Inland water ways transport (ADN)
14.1. UN
1203
number
14.2. UN
Gasoline.
proper
shipping name
14.3.
3
Transport
hazard
class(es)
Hazard
label(s)
Environmental
N2+F
hazard in tank
vessels
Sea transport (IMDG)
14.1. UN
1203
number
14.2. UN
Gasoline.
proper
shipping
name
14.3.
3
Transport
hazard
class(es)
Hazard
label(s)
Sub Risk:
IMDG Code
segregation
group
Marine
pollutant
Substance
name(s) on
marine
pollutant
EMS:
Air transport (ICAO-TI / IATA-DGR)
14.1. UN
1203
number
14.2. UN
Gasoline.
proper
shipping
name
14.3.
3
Transport
hazard
class(es)
Hazard
Corrosive
label(s)
Replaces date: 01/11/2011
14.4. Packing
group
14.5.
Environmental
hazards
II
yes
14.4. Packing
group
14.5.
Environmental
hazards
II
14.4. Packing
group
II
The product must be labelled as a Marine
Pollutant (MP) in packaging sizes of more
than 5 kg/l.
14.6. SPECIAL PRECAUTIONS FOR USER
None.
14.7. TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL73/78 AND THE IBC CODE
Not included.
SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or
mixture
Declaration number (PRN-no.)
(PRN nr. Norway): 27594
10 / 12
SAFETY DATA SHEET
Unleaded Gasoline
Last changed: 18/11/2011
Replaces date: 01/11/2011
PROVISIONS
Special care should be applied for employees under the age of 18. Young people under the age
of 18 may not carry out any work causing harmful exposure to this product.
15.2. Chemical safety assessment
OTHER INFORMATION
Chemical safety assessments have been performed for the following substances:
86290-81-5 / 289-220-8 Gasoline
SECTION 16: Other information
Indication of changes
ISSUED:
12/08/2004
Indication of changes
Version
1.0.0
2.0.0
3.0.0
4.0.0
Rev. date
12/08/2004
01/07/2005
18/01/2007
20/11/2008
Responsible
Marta Teigland
Anja Birkeland
Anja Birkeland
Tove Michelsen Solli
Changes
Preparation
Reclassification
Revision, reclassification
Revision, UN-no. section 14
ABBREVIATIONS
PBT: Persistent, Bioaccumulative and Toxic
vPvB: Very Persistent and Very Bioaccumulative
DNEL: Derived No Effect Level
PNEC: Predicted No Effect Concentration
STOT: Specific Target Organ Toxicity
CLASSIFICATION METHOD
Test data
LIST OF RELEVANT R-PHRASES
R11
Highly flammable.
R12
Extremely flammable.
R36/38
Irritating to eyes and skin.
R38
Irritating to skin.
R45
May cause cancer.
R46
May cause heritable genetic damage.
R48/20
Harmful: danger of serious damage to health by prolonged exposure through inhalation.
R48/23/24/25 Toxic: danger of serious damage to health by prolonged exposure through inhalation, in contact with skin
and if swallowed.
R51/53
Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R62
Possible risk of impaired fertility.
R63
Possible risk of harm to the unborn child.
R65
Harmful: May cause lung damage if swallowed.
R67
Vapours may cause drowsiness and dizziness.
11 / 12
SAFETY DATA SHEET
Unleaded Gasoline
Last changed: 18/11/2011
Replaces date: 01/11/2011
LIST OF RELEVANT H-STATEMENTS
H224
Extremely flammable liquid and vapour.
H225
Highly flammable liquid and vapour.
H304
May be fatal if swallowed and enters airways.
H315
Causes skin irritation.
H319
Causes serious eye irritation.
H336
May cause drowsiness or dizziness.
H340
May cause genetic defects.
H350
May cause cancer.
H361
Suspected of damaging fertility or the unborn child.
H361f
Suspected of damaging fertility.
H361d
Suspected of damaging the unborn child.
H372
Causes damage to organs through prolonged or repeated exposure.
H373
May cause damage to organs through prolonged or repeated exposure.
H411
Toxic to aquatic life with long lasting effects.
TRAINING ADVICE
A thorough knowledge of this safety data sheet should be a prerequisite condition.
OTHER INFORMATION
Changes have been made in the following sections: 1, 12, 16.Other information: Exposure scenarios are enclosed as
appendicies.Version: 01.05/GBR
SDS IS PREPARED BY
Enterprise
Bureau Veritas Norway AS
Address
Stokkamyrveien 20
Postal code
4313 Sandnes
Country
Norway
Email
post.svg@no.bureauveritas.com
Internet
http://www.bureauveritas.no
Tel
+47 51 57 40 00
Fax
+47 51 57 40 01
12 / 12