Iraqi Journal of Applied Physics Haitham S. Dawood School of Applied Sciences, University of Technology, Baghdad, Iraq Analytical Equivalent Circuit of High-Irradiated Conventional Silicon Solar Cell Performance In this study the current–voltage characteristics of a conventional silicon solar cell were studied. The experimental examination is carried out under a high concentration of light. The variations of the two reverse saturation currents are consistent with the physical significance of both the diffusion and the space-charge generation-recombination terms through their exponential variations. The simulation results clearly demonstrated that the solar cell is described with reasonable accuracy by a two-diode equivalent model that simulates the effects of the double-exponential dark current–voltage characteristics on the open-circuit voltage, fill factor, and conversion efficiency of the solar cell at a high concentration. The theoretical results are in good agreement with the experimental observations. Keywords: Solar cells, Silicon-based devices, Equivalent circuit, High irradiation Received: 20 July 2009, Revised: 22 September 2009, Accepted: 27 September 2009 1. Introduction The presence of a p-n junction in a semiconductor makes solar power possible. The space charge region is formed as a result of the diffusion of majority carriers across the metallurgical junction, and its width is fixed when the diffusion is counter balanced by the drift of carriers in the opposite direction, thus setting up a compact but strong electric field as the collecting junction in the depletion region [1]. In thermal equilibrium, drift and diffusion currents through the depletion region oppose each other, resulting in zero net current flow. Using light as an external stimulus allows the p-n junction to behave as follows. Part of the solar spectrum is absorbed in a semiconductor through the transfer of optical energy to electrons that are excited into the conduction band creating holes in the valence band. The electric field in the depletion region helps in separating these electron-hole pairs, resulting in a voltage or the photovoltaic effect [2]. The efficiency of photovoltaic solar cells decreases with an increase in temperature [3]. When silicon solar cells are used under concentrated sunlight they tend to heat up [4], as a result of which the current and voltage generated by the solar cell are modified. An excessive rise in the solar cell temperature has degrades effects on the solar cell characteristics. In general, the open-circuit voltage (VOC) decreases rapidly and the short circuit current (ISC) increases slowly, as the temperature rises. In this paper, we present a modeling analysis implemented to introduce the I–V characteristics of silicon-based solar cells at high light All rights reserved concentration. The correlations between experimental I–V plots and theoretical counterparts under different illumination intensities are studied. The model must take into account the various recombination and generation processes in the solar cell under illumination. Thus, the device can be modeled with either the conventional single-diode model or the two-diode model. Under illumination, the cell may be represented by an equivalent circuit based on a single-diode model, as shown in Fig. (1). The cell is described as a current source in parallel with the junction as V + IRS q (1) I=I I exp (V + IR ) 1 ph Rsh 0 nKT S where Iph represents the photocurrent, I0 is the saturation current under reverse bias; RS and Rsh are respectively series resistance and shunt resistance, n is the ideality factor, q is the elementary electron charge, k is the Boltzmann constant and T is the temperature. Fig. (1) Single-diode model of a solar cell under high irradiation condition ISSN 1813-2065 Printed in IRAQ 11 IJAP Vol. (5), No. (4), October 2009 The simplified two-diode model of a solar cell may be described by the new lumped parameter simplified equivalent circuit shown in Fig. (2) [5,6]. For a given incident light intensity, at a given temperature, the implicit I–V relationship is given by V + IR S R sh I = I ph I 01 {exp[B1 (V + IR S )] 1} I 02 {exp[B 2 (V + IR S )] 1} (2) where B1=q/kT, B2=B1/n and I01 represents the saturation current originating from the quasi neutral region of the junction which is affected by, as diffusion, recombination and the drift effect [5]; I02 corresponds to the carrier recombination via deep levels in the spacecharge region of the junction [6]. The reverse saturation current I02 is generally 3 to 7 orders of magnitude larger than I01; the diode quality factor n=2 for the approximation corresponding to the Shockley–Read–Hall recombination current in the space-charge region [5,7]; n is also a fitting parameter that is greater than 2. illumination. It should be noted that the illumination does not cause a simple translation of the I–V characteristics along the current axis [9,10], the series resistance effect is non-linear and the injection level changes from low to high level. Several methods have been proposed for the determination of the free parameters in this model from the I–V measurements [11,12]. In order to present general approach for calculating all the cell parameters, we use Eq. (2), for the two following special cases. (i) For V=VOC and I=0 VOC 0 = I ph I 01 {exp[B1 (VOC + IRS )] 1} Rsh (3) I 02 {exp[B2 (VOC + IRS )] 1} (ii) For I=ISC and V=0 I sh RS I SC = I ph I 01 {exp[B1 ( I SC RS )] 1} Rsh (4) I 02 {exp[B2 ( I SC RS )] 1} Differentiating Eq. (2) with respect to I on both sides for the two special cases considered above we have (i) For I=0, V=VOC, one can write 1= dV dI + RS V =VOC I 02 B2 exp[B2 (VOC )]) where Fig. (2) Double-diode model of a solar cell under high irradiation condition RS 0 = dV dI 1 Rsh I 01 B1 exp[B1 (VOC ) ] (5a) V =VOC Thus, RS is given as 1 dV The experimental study of the temperature + RS + I 01 B1 exp[B1 (VOC )] 1= dependence of I01 and I02 should help to verify dI V =VOC Rsh their different origins. Such studies have been (5b) + I 02 B2 exp[B2 (VOC )]) previously published under dark conditions [8]. It is interesting to determine the temperature dependencies of electrical parameters while the cell is operating as a generator under _____________________________________________________________________________________ Re-arranging dV dI RS = V =VOC 1 1 1 + I 01B1 exp[B1 (VOC )] + I 02 B2 exp[B2 (VOC )] Rsh (ii) For V=0, I=ISC, we obtain RS = RS 0 1= dV dI + RS I = I SC 1 Rsh I 01 B1 exp[B1 ( I SC RS )] I 02 B2 exp[B2 ( I SC RS )] where Rsh 0 = 12 dV dI (5c) 1 + I 01 B1 exp[B1 (VOC )] + I 02 B2 exp[B2 (VOC )] Rsh I = I SC © 2009 Iraqi Society for Alternative and Renewable Energy Sources and Techniques (I.S.A.R.E.S.T.) (6) (7) Iraqi Journal of Applied Physics Thus 1 RS = 1 Rsh 0 RS (8) I 01 B1 exp[B1 ( I SC RS )] I 02 B2 exp[B2 ( I SC RS )] For V=VOC and I=ISC, we have I ph = VOC + I 01{exp[B1VOC ] 1} I 02 {exp[B2VOC ] 1} Rsh (9) Equations (3), (4), (6), (8), and (9) form a system of simultaneous equations where the unknown parameters are RS, Rsh, I01, I02, and Iph respectively. To be very general, let u=RS, v=Rsh, x=Iph, y=I01, z=I02 (10) The system can be written as f1 (u , v, x, y, z ) = 0 f 2 (u , v, x, y, z ) = 0 f 3 (u , v, x, y, z ) = 0 f 4 (u, v, x, y, z ) = 0 f5 (u, v, x, y, z ) = 0 (11) The system in Eq. (11) is resolved numerically using the Newton–Raphson algorithm of the form vk vk 1 wk 1 wk xk = xk 1 yk 1 yk zk zk 1 f1 u f2 u f3 u f4 u f5 u f1 v f2 v f3 v f4 v f5 v f1 x f2 x f3 x f4 x f5 x f1 y f2 y f3 y f4 y f5 y f1 z f2 z f3 z f4 z f5 z 1 . f1 (u k 1 , vk 1 , xk 1 , yk 1 , z k 1 ) f 2 (u k 1 , vk 1 , xk 1 , yk 1 , z k 1 ) f 3 (u k 1 , vk 1 , xk 1 , y k 1 , z k 1 ) . (12) f 4 (u k 1 , vk 1 , xk 1 , yk 1 , z k 1 ) f 5 (u k 1 , vk 1 , xk 1 , yk 1 , z k 1 ) ( u k 1 ,vk 1 , xk 1 , yk 1 , z k 1 ) _____________________________________________________________________________________ where the initial conditions are thus given by u (1) v(1) 0 0 x(1) = 0 0 y (1) z (1) 0 (13) The five different parameters of the singlediode model, can be determined directly from the latter equations using I01=0 and I02=I0. 2. Experiment In this work, we have used standard solar panel fabricated by Hebe Solar Co., Ltd. (China) in order to test the model at optimum solar parameters. The panel is 15x15cm in area and partitioned into many multicrystalline silicon p-n junction solar cells. Each cell is 25x25mm in dimensions, 300Um in thickness and delivers 40% more power than customary cells. The front grid was made of 2 silver bus bars, 1mm wide, with about 80 fingers of 5Um length between All rights reserved them and SiNx AR coating. The back side contains of 5mm wide soldering pads (Ag/Al) and back surface field (Al). The contact thickness was 2.5Um and the sheet resistance was 900 /V. The cells were mounted on thermal-clad substrates, which are commonly used for hybrid electronic circuits. The n-type side was 200nm thick with a doping density of 2x1018cm-3 and the p-type side was 800nm thick with a doping density of 2x1017cm-3. The maximum efficiency of this cell as illustrated by the manufacturer is ranging within 13.8-15.6% at 3.5W maximum output power. The conversion measurements were conducted under solar radiation. The concentrator system used is advantageous for giving good illumination uniformity at the focus. The focus was 3X3cm2 in area and was slightly larger than the dimensions of the tested cells. The measured parasitic resistance induced by this set-up was in the order of 20m which is a minimal contribution for the tested cells. Under the same experimental conditions, a solar cell ISSN 1813-2065 Printed in IRAQ 13 IJAP Vol. (5), No. (4), October 2009 operating at a high concentration of light shows only slight degradation as a result of the parasitic effect. 8 7 Current (mA) Current (A) 0.6 0.4 2 diode 1 diode exp. 0.2 0 0 0.4 0.8 1.2 1.6 Voltage (V) Fig. (5) Simulated curves and experimental measurements of I–V characteristics of the solar cell under concentration level of X=139:27 (X is the light concentration level) 1.8 1.6 1.4 1.2 1 0.8 2 diode 1 diode exp. 0.4 5 0.2 4 0 0 3 0.4 0.8 1.2 1.6 Voltage (V) 2 2 diode 1 diode exp. 1 0 0 0.4 0.8 1.2 1.6 Voltage (V) Fig. (3) Simulated curves and experimental measurements of I–V characteristics of the solar cell under concentration level of X=1 (X is the light concentration level) 500 450 400 350 Current (mA) 0.8 0.6 6 300 250 200 150 2 diode 1 diode exp. 100 50 0 0 0.4 0.8 1.2 1.6 Voltage (V) Fig. (4) Simulated curves and experimental measurements of I–V characteristics of the solar cell under concentration level of X=73:36 (X is the light concentration level) 14 1 Current (A) 3. Results and Discussion The equivalent-circuit parameter values were determined and the simulated I–V plots together with the experimental counterparts are represented in Figs. (3–6) for four different concentrations. The simulated parameters were calculated using the single-diode model and the two-diode model presented above. A Comparison between the cell parameters obtained using each model with the corresponding experimental values was conducted to find the best model. The results clearly show that the proposed two-diode model is compatible with the solar cell at high concentrations (X=73:36, 139.27, and 201.19). On the other hand, the single-diode model seems better for the low concentration of X=1 where the two-diode model is less precise than the single-diode model. 1.2 Fig. (6) Simulated curves and experimental measurements of I–V characteristics of the solar cell under concentration level of X=201:19 (X is the light concentration level) At high levels of solar concentration, the good agreement of experimental results with the two-diode model can be explained by the fact that under such conditions the traps, which are susceptible to intervening in the recombination, are saturated and the amount of diffusion becomes significant. The two-diode model can be applied under conditions of weak injection, while taking in account three essential mechanisms [7]. First, the diffusion takes into account the recombination mechanisms in the quasi-neutral regions (notably the contacts). Second, the recombination in the space-charge region of the junction, by the recombinant centers associated with the levels situated in the strip forbidden for a homojunction represented by one exponential term. Finally, Joule effect is translated into losses due to the series resistance and shunt resistance. Therefore the two-diode model is the more suitable for the precise simulation of a solar cell in a real situation [1,5,10]. This is presumably due to the minority carrier diffusion process, © 2009 Iraqi Society for Alternative and Renewable Energy Sources and Techniques (I.S.A.R.E.S.T.) Iraqi Journal of Applied Physics [2] T.K.P. Wong, Electron. Lett., 32(3) (1996) 252 – 253. [3] D. Meneses-RodrXguez, P.P. Horley, J. Gonzalez-Hernandez, Y.V. Vorobiev and P.N. Gorley, Solar Energy, 78 (2005) 243. 4. Conclusions [4] R.V. Singh and C.M. Singal, Solar Cells, 10 The effects of double-exponential dark (1983) 155. current–voltage characteristics on the different [5] T.K.P. Wong and P.C.H. Chan, An parameters of a silicon-based solar cell operating equivalent circuit approach to solar cell at high concentration of light were studied. The modeling, IEEE Region 10 Inter. Conf. on two-diode model was compared to the singleMicroelectronics and VLSI, 1995, TENCON diode one in terms of the agreement between the 95, 6-10 (November 1995) 222-225. simulated cell parameters and experimental [6] G.L. Araujo, E. Sanchez and M. Marti, values. We conclude that the conventional Solar Cells, 5 (1982) 199. single-diode model is inadequate for describing [7] J.-P. Charles, A. Haddi, A. Maouad, H. the behavior of the studied device under high Bakhtiar, A. Zerga, A. Hoffmann and P. light concentration and that the two-diode model Mialhe, Rev. Energy Ren., 3 (2000) 1. is more appropriate. [8] F. Lindholm, J. Fossum and E. Burgess, IEEE Trans. Electron. Devices, 26 (1979) Acknowledgment 165. Author would like to thank Dr. R.M. Ibrahim [9] R.N. Hall, Solid State Electron., 24 (1981) for his valuable comments and notes. He also 595. would like to thank Prof. M.A. Habeeb for his [10] J.-P. Charles, I. Mekkaoui-Alaoui and G. assistance in numerical analysis. Finally, he Bordure, Solid State Electron., 28 (1985) thanks Mr. S.I. Al-Hadithi at Thin Films 807. Laboratory, University of Baghdad for [11] R.A. Kumar, M.S. Suresh and J. Nagaraju, experimental assistance and measurements. IEEE Trans. on Electron. Devices, 48(9) (2001) 2177-2179. References [12] A. Cheknane, H.S. Hilal, F. Djeffal, B. [1] M. Masaki and M. Tatsuo, Jpn. J. Appl. Benyoucef and J.-P. Charles, Microelectron. Phys. Part 1, 45(1B) (2006) 542-545. J., 39(10) (2008) 1173-1180. _____________________________________________________________________________________ which becomes dominant in the conduction mechanisms at a high concentration of light [1,2]. All rights reserved ISSN 1813-2065 Printed in IRAQ 15