JOURNAL OF APPLIED PHYSICS 105, 123516 共2009兲 Mechanics of noncoplanar mesh design for stretchable electronic circuits J. Song,1,a兲 Y. Huang,2,3 J. Xiao,3 S. Wang,3 K. C. Hwang,4 H. C. Ko,5 D.-H. Kim,5 M. P. Stoykovich,6 and J. A. Rogers5,7,b兲 1 Department of Mechanical and Aerospace Engineering, University of Miami, Coral Gables, Florida 33146, USA 2 Department of Civil and Environmental Engineering, Northwestern University, Evanston, Illinois 60208, USA 3 Department of Mechanical Engineering, Northwestern University, Evanston, Illinois 60208, USA 4 Department of Engineering Mechanics, Tsinghua University, Beijing 100084, China 5 Department of Materials Science and Engineering, University of Illinois, Urbana, Illinois 61801, USA 6 Department of Chemical and Biological Engineering, University of Colorado, Boulder, Colorado 80309, USA 7 Department of Mechanical Science and Engineering, Department of Electrical and Computer Engineering, Department of Chemistry, and Frederick Seitz Materials Research Laboratory, University of Illinois, Urbana, Illinois 61801, USA 共Received 17 February 2009; accepted 7 May 2009; published online 22 June 2009兲 A noncoplanar mesh design that enables electronic systems to achieve large, reversible levels stretchability 共⬎100%兲 is studied theoretically and experimentally. The design uses semiconductor device islands and buckled thin interconnects on elastometric substrates. A mechanics model is established to understand the underlying physics and to guide the design of such systems. The predicted buckle amplitude agrees well with experiments within 5.5% error without any parameter fitting. The results also give the maximum strains in the interconnects and the islands, as well as the overall system stretchability and compressibility. © 2009 American Institute of Physics. 关DOI: 10.1063/1.3148245兴 I. INTRODUCTION Stretchable electronics is emerging as a technology that could be valuable for various applications such as flexible displays,1 electronic eye camera,2 conformable skin sensors,3 smart surgical gloves,4 and structural health monitoring devices.5 There exist two approaches to achieve stretchability: 共i兲 coplanar stretchable interconnects 共bonded to a substrate兲 between rigid device islands,6 and 共ii兲 wavy layout 共i.e., small wave兲 throughout the whole circuit system.7 Both are fabricated on elastometric substrates, and provide some degree of stretchability 共e.g., 10%兲. None offers strainindependent electronic performance at large strains, which is of interest in practical applications.2,4 Here, we present a noncoplanar mesh design, which is based on the interconnect-island6 concept to accomplish much higher stretchability 共i.e., up to 100%兲. Figure 1 schematically illustrates the fabrication of circuits with noncoplanar mesh design on compliant substrates.2,8 The silicon 共or other semiconductor material兲 islands, on which the active devices or circuits are fabricated, are chemically bonded to a prestrained 共e.g., 50%兲 elastometric substrate of a material such as poly共dimethylsiloxane兲 共PDMS兲, while interconnects are loosely bonded.8 Releasing the prestrain leads to compression, which causes the interconnects to buckle and move out of the plane of the substrate to form arc-shaped structures. The poor adhesion of interconnects 共to PDMS兲 and their narrow geometries and low stiffness 共compared to device is- lands兲 cause the out-of-plane deformation to localize only to interconnects, and therefore the strain in islands is very small. Figure 2 shows a scanning electron micrograph of silicon structure 共island: 20⫻ 20 m2, 50 nm thick; interconnect: 20⫻ 4 m2, 50 nm thick兲 on a 1 mm thick PDMS substrate. The inset clearly shows that the islands remain flat while interconnects buckle. Kim et al.8 developed a full-scale finite element model for the noncoplanar mesh design. But, it is rather complex and does not lead to simple, analytical solutions to be used in the design and optimization of these systems. This paper a兲 Author to whom correspondence should be addressed. Electronic mail: jsong8@miami.edu. b兲 Electronic mail: jrogers@uiuc.edu. 0021-8979/2009/105共12兲/123516/6/$25.00 FIG. 1. 共Color online兲 Schematic illustration of the process for fabricating electronics with noncoplanar mesh designs on a complaint substrate. 105, 123516-1 © 2009 American Institute of Physics Downloaded 22 Jun 2009 to 129.171.233.73. Redistribution subject to AIP license or copyright; see http://jap.aip.org/jap/copyright.jsp 123516-2 J. Appl. Phys. 105, 123516 共2009兲 Song et al. above equation also agrees well with the full-scale finite element analysis.8 tot The total energy Ubridge of the interconnect consists the bending membrane . bending energy Ubridge and the membrane energy Ubridge bending The bending energy Ubridge can be obtained from Eq. 共1兲 3 / 12 as and the bending rigidity Ebridgehbridge bending = Ubridge = FIG. 2. A scanning electron micrograph of a noncoplanar silicon mesh structure 共island: 20⫻ 20 m2, 50 nm thick; interconnect: 20⫻ 4 m2, 50 nm thick兲 on a PDMS substrate. aims at establishing a mechanics theory for the mechanical response of noncoplanar mesh design and predicting the maximum strains in the interconnects as well as in the islands, which are both important to determine the stretchability of the system. For simplicity, silicon is used for both islands and interconnects, though the mechanics theory can be applied to other systems that involve multiple materials. The paper is outlined as follows. The mechanics models of the interconnects and the islands are described in Secs. II and III, respectively. Stretchability/compressibility of various nonplanar mesh designs are discussed in Sec. IV. II. MECHANICS MODEL OF INTERCONNECTS The width of interconnects is much smaller than the width of island such that the rotation at the ends of interconnects is very small. This is verified by the finite element analysis 共see Sec. III and also Kim et al.8兲 as well as by the analytical solution given in the Appendix. Therefore, the “bridge”-like interconnect is modeled as a beam with clamped ends 共as shown in Fig. 3兲 since its thickness 共hbridge ⬃ 50 nm兲 is much smaller than any other characteristic length 共width: wbridge ⬃ 4 m; length: Lbridge ⬃ 20 m兲. The beam, however, undergoes large rotation once the interconnect buckles. Let X denote the initial, strain-free configuration of the beam 共top figure in Fig. 1兲, and x the buckled configuration 共bottom figure in Fig. 1兲. The distance between 0 to Lbridge in these two configuraislands changes from Lbridge tions, as shown in Fig. 3, and the buckle amplitude A is to be determined. The out-of-plane displacement w of the interconnect takes the form w= 冉 冊 冉 冊 2x 2X A A 1 + cos = 1 + cos 0 , 2 Lbridge 2 Lbridge 冕 0 Lbridge /2 0 −Lbridge /2 dX 共2兲 where Ebridge is the Young’s modulus of the interconnect. membrane The membrane strain bridge , which determines the membrane energy, is related to the out-of-plane displacement w in Eq. 共1兲 and in-plane displacement u by9 membrane bridge = 冉 冊 du 1 dw + dX 2 dX 2 共3兲 . membrane via the The membrane force N is then related to bridge membrane . The tension rigidity Ebridgehbridge as N = Ebridgehbridgebridge force equilibrium dN = 0, dX 共4兲 requires a constant membrane force, which gives the in-plane displacement u= 冉 冊 冉 冊 0 − Lbridge Lbridge 4 A2 sin X − X. 0 0 0 16Lbridge Lbridge Lbridge L 0 共5兲 /2 0 du = Lbridge − Lbridge Here the conditions u共0兲 = 0 and 兰−Lbridge 0 /2 bridge have been imposed. Equation 共3兲 then gives a constant membrane strain membrane = bridge 0 − Lbridge Lbridge 2A 2 − . 0 0 2 4共Lbridge兲 Lbridge 共6兲 The membrane energy in the interconnect is given by membrane = Ubridge 冕 0 Lbridge /2 0 −Lbridge /2 1 membrane 2 兲 dX Ebridgehbridge共bridge 2 冋 1 2A 2 0 = EbridgehbridgeLbridge 0 2 4共Lbridge 兲2 0 Lbridge − Lbridge 共1兲 0 Lbridge 册 2 0 2Lbridge 冑 0 Lbridge − Lbridge 0 Lbridge 共7兲 . Minimization of total energy tot Ubridge / A = 0 gives the amplitude A= FIG. 3. 共Color online兲 Schematic diagram of mechanics model for the interconnect region of a noncoplanar mesh structure. 2 3 Ebridgehbridge 4A 2 , 0 12 兲3 共Lbridge + which satisfies vanishing displacement and slope at the two 0 / 2. The sinusoidal buckle profile in the ends X = ⫾ Lbridge 冉 冊 3 1 Ebridgehbridge d 2w 2 12 dX2 in − c , the interconnect 共8兲 2 0 / 关3共Lbridge 兲2兴 is the critical buckling strain where c = 2hbridge 0 for Euler buckling of a doubly clamped beam. For 共Lbridge 0 − Lbridge兲 / Lbridge ⬍ c, the interconnect does not buckle, and membrane therefore has no bending. The membrane strain is bridge 0 0 0 0 = −共Lbridge − Lbridge兲 / Lbridge. Once 共Lbridge − Lbridge兲 / Lbridge exceeds c, the interconnect buckles such that the membrane Downloaded 22 Jun 2009 to 129.171.233.73. Redistribution subject to AIP license or copyright; see http://jap.aip.org/jap/copyright.jsp 123516-3 J. Appl. Phys. 105, 123516 共2009兲 Song et al. FIG. 4. 共Color online兲 The maximum strain in the interconnects vs the prestrain for different interconnect lengths. strain remains a constant −c 关see from Eqs. 共6兲 and 共8兲兴, and the bending strain 共curvature ⴱ hbridge / 2兲 increases bending 0 = 2共hbridge / Lbridge 兲 with the deformation, bridge 0 0 ⫻冑关共Lbridge − Lbridge兲 / Lbridge兴 − c. The maximum 共compressive兲 strain in the interconnect is the sum of membrane and bending strains, and is given by max = bridge hbridge 2 0 Lbridge ⬇ 2 冑 冑 0 Lbridge − Lbridge hbridge 0 Lbridge 0 Lbridge 0 Lbridge − Lbridge 0 Lbridge 0 Lbridge = pre . 1 + pre − c + c , 共9兲 共10兲 The maximum strain in the interconnect in Eq. 共9兲 is then related to the prestrain in the substrate by max = 2 bridge hbridge 0 Lbridge 冑 pre . 1 + pre 10 m and thickness hbridge = 50 nm 关or equivalently hbridge 0 = 25, 50, and 100 nm and length Lbridge = 20 m兴. Therefore thin and long interconnects give small strain, and thus increase the stretchability. III. MECHANICS MODEL OF ISLANDS 0 0 − Lbridge兲 / Lbridge where the approximation holds for 共Lbridge 2 0 2 Ⰷ hbridge / 共Lbridge兲 . Once the prestrain pre in the substrate is relaxed, the bridge length is reduced to Lbridge. Therefore the prestrain is 0 − Lbridge兲 / Lbridge, which can be rewritten given by pre = 共Lbridge as 0 − Lbridge Lbridge FIG. 5. 共Color online兲 Distribution of the strain xx in islands 共20 ⫻ 20 m2兲 when the interconnect relaxes from 20 to 17.5 m. 共11兲 The initial length of the interconnect in experiments is 0 = 20 m and the thickness hbridge = 50 nm, which give Lbridge a critical buckling strain c = 0.0021%. The measured bridge length is Lbridge = 17.5 m after relaxation, which corresponds to prestrain pre = 14.3% in the substrate. Equation 共8兲 then predicts the amplitude A = 4.50 m, which agrees well with the experimentally measured amplitude 4.76 m. The maximum strain in the interconnect is 0.56%. This value is smaller than the fracture strain of silicon 共⬃1%兲, and is much smaller than the prestrain pre. For 1% interconnect strain, the prestrain can reach 68.1%. max given in The maximum strain in the interconnect bridge Eq. 共9兲 or Eq. 共11兲 is proportional to the interconnect thick0 max . Figure 4 shows bridge ness and to length ratio, hbridge / Lbridge 0 versus the prestrain pre for the length Lbridge = 40, 20, and The finite element method is used to study the silicon island on PDMS substrate. The island is modeled as a plate since its thickness hisland is much smaller than the length 0 . The buckled interconnects give the axial force N Lisland 3 = Ebridgehbridgec and bending moment M = 共Ebridgehbridge / 12兲 0 3 0 2 2 冑 ⫻关2 A / 共Lbridge兲 兴 ⬇ Ebridgehbridge / 共3Lbridge兲 pre / 共1 + pre兲 over the width wbridge on each edge of the island. The PDMS substrate is modeled by a unit cell that is a 0 + Lbridge in the 共X-Y兲 plane but square with edge length Lisland very thick in the island thickness direction 共Z兲. The displacements are continuous across the island/substrate interface, and the rest of the top surface is traction free. Periodic boundary conditions are imposed on the lateral surfaces 共X-Z and Y-Z planes兲 of the substrate. Figure 5 shows the strain distribution xx in a Si island 0 = 20 m, and 共Eisland = 130 GPa, island = 0.27, length Lisland 10 thickness hisland = 50 nm兲 on an PDMS substrate 共Esubstrate = 2 MPa and substrate = 0.48兲.11 The axial force and bending moment result from the buckled interconnect 共Ebridge 0 = 130 GPa, Lbridge = 20 m, hbridge = 50 nm, wbridge = 4 m, and Lbridge = 17.5 m after relaxation兲. The maximum strain occurs at the interconnect/island boundary. The strain due to the axial force is negligible as compared to that due to the bending moment. Dimensional analymax sis gives the maximum strain in the silicon island as island 2 2 = ␣6共1 − island兲M / 共Eislandhisland兲, where ␣ is a nondimensional function of dimensionless elastic properties Esubstrate / Eisland, substrate, and island, and nondimensional 0 / Lisland. Finite element analylengths wbridge / Lisland and Lbridge ses show that ␣ is essentially a constant of unity. For large variations in island and substrate elastic properties and inter0 , ␣ only deviates from connect width wbridge and length Lbridge one by a few percent. The maximum strain in the silicon island is then given by Downloaded 22 Jun 2009 to 129.171.233.73. Redistribution subject to AIP license or copyright; see http://jap.aip.org/jap/copyright.jsp 123516-4 J. Appl. Phys. 105, 123516 共2009兲 Song et al. 2 兲M 6共1 − island max island ⬇ 2 Eislandhisland = 2 2 3 共1 − island 兲Ebridgehbridge 2 0 Eislandhisland Lbridge 冑 pre , 1 + pre 共12兲 which can also be related to the maximum strain in interconnect by max = island 2 2 兲Ebridgehbridge 共1 − island 2 Eislandhisland max bridge . 共13兲 Therefore, a stiff and thick island reduces its strain. max that the noncoplanar mesh The maximum prestrain pre design can accommodate is obtained by equating the strains failure and in Eqs. 共11兲 and 共12兲 to the failure strains 共⬃1%兲 bridge failure island of interconnect and island materials, respectively, max ⬍ pre a2 1 − a2 where a= if a ⬍ 1, 共14兲 冋 册 0 2 Eislandhisland Lbridge failure failure min bridge , island . 2 2 2hbridge 共1 − island 兲Ebridgehbridge 共15兲 For a ⱖ 1 共e.g., long interconnects兲, the maximum prestrain is then governed by the failure of PDMS substrate. IV. STRETCHABILITY/COMPRESSIBILITY OF NONCOPLANAR MESH DESIGN 0 0 The length of a unit cell changes from Lbridge + Lisland to 0 Lbridge + Lisland after the prestrain pre is relaxed, where 0 / 共1 + pre兲 is obtained from Eq. 共10兲, and the Lbridge = Lbridge change in island length is negligible because the interconnect buckles to accommodate the release of prestrain. The length 0 once the system is of the unit cell becomes Lbridge ⬘ + Lisland subject to an applied strain applied, where the length of interconnect Lbridge is related to applied by ⬘ applied = ⬘ − Lbridge Lbridge 0 Lbridge + Lisland 共16兲 . The stretchability/compressibility characterizes how much the noncoplanar mesh design can accommodate further deformation. It is defined as the critical applied strain that leads to failure of interconnect or island, which occurs when the maximum strains in interconnect or island reach the corfailure failure and island of the associated responding failure strains bridge materials, respectively. The stretchability is determined by the condition at which the buckled interconnect returns to a flat state, at which point it cannot accommodate any additional stretching. This condition is obtained from Lbridge ⬘ 0 = Lbridge as stretchability = 0 − Lbridge Lbridge Lbridge + 0 Lisland = pre 1 + 共1 + pre兲 0 Lisland . 共17兲 0 Lbridge The result clearly shows that long interconnects, short islands, and large prestrains increase the stretchability. For the FIG. 6. Stretchability and compressibility vs the prestrain for the noncoplanar mesh design 共island: 20⫻ 20 m2, 50 nm thick; interconnect: 20 ⫻ 4 m2, 50 nm thick兲 when the failure strains of interconnect and island are 1%. 0 0 limit of long interconnect Lbridge Ⰷ Lisland , the stretchability is the prestrain pre. For the other limit of short interconnect 0 0 0 0 Lbridge Ⰶ Lisland , the stretchability is 共Lbridge / Lisland 兲关pre / 共1 + pre兲兴. The maximum strain in Eq. 共9兲 for the interconnect now max 0 0 0 = 2共hbridge / Lbridge 兲冑共Lbridge − Lbridge , becomes bridge ⬘ 兲 / Lbridge while Eq. 共12兲 still holds for the maximum strain in island. The compressibility is reached when they reach the correfailure failure and island , or when then sponding failure strains bridge neighbor islands start to contact. This gives the compressibility compressibility = min 冤 共1 + pre兲a2 − pre 1 + 共1 + pre兲 0 Lisland 0 Lbridge , 1 1 + 共1 + pre兲 0 Lisland 0 Lbridge 冥 , 共18兲 where a is given in Eq. 共15兲. For long interconnects 共large a兲, the compressibility is compressibility = 1 / 关1 + 共1 + pre兲 0 0 / Lbridge 兲兴, corresponding to the contact of neighbor ⫻共Lisland islands. For short interconnects 共small a兲, the compressibility is compressibility = 关共1 + pre兲a2 − pre兴 / 关1 + 共1 + pre兲 0 0 ⫻共Lisland / Lbridge兲兴, corresponding to the failure of interconnect or island. Figure 6 shows the stretchability and compressibility 0 = 20 m, hisland = 50 nm, versus the prestrain for Lisland 0 Lbridge = 20 m, hbridge = 50 nm, and wbridge = 4 m. The failure strains of the interconnect and the island are assumed, for failure failure = island = 1%. The stretchability insimplicity, to be bridge creases with the prestrain, but the compressibility decreases. Therefore, prestrain cannot be adjusted to give both maximum stretchability and maximum compressibility. One way to achieve large stretchability and compress0 of interconnect. As ibility is to increase the length Lbridge shown in Fig. 7 for the same set of properties as Fig. 6 and the prestrain pre = 50%, both stretchability and compressibility increase with the length of interconnect, though the compressibility increases much faster than the stretchability. The dot on the curve for compressibility separates the failure of interconnect or island 共left of the dot兲 from the contact of neighbor islands 共right of the dot兲. Downloaded 22 Jun 2009 to 129.171.233.73. Redistribution subject to AIP license or copyright; see http://jap.aip.org/jap/copyright.jsp 123516-5 J. Appl. Phys. 105, 123516 共2009兲 Song et al. bending rigidity of the interconnect, w is the out-of-plane 0 0 displacement that satisfies w共−Lbridge / 2兲 = w共Lbridge / 2兲 = 0, N is the compressive force at the ends, and M = kw⬘共 0 0 / 2兲 = −kw⬘共Lbridge / 2兲 is the moment at the ends. The −Lbridge buckle profile is given by 冉 冊 2X − cos 0 Lbridge , 1 − cos cos w=A FIG. 7. Stretchability and compressibility vs the length of interconnect for the noncoplanar mesh design when the prestrain is 50%. The dot on the curve for compressibility separates the failure of interconnect or island 共left of the dot兲 from the contact of neighbor islands 共right of the dot兲. V. CONCLUDING REMARKS A mechanics model has been established for stretchable electronics with noncoplanar mesh designs. The results predict analytically the buckling amplitude, which agrees well with experiments 共5.5% error兲 without any parameter fitting. The maximum strains in the interconnect and island are also obtained analytically, and are used to predict the stretchability and compressibility. The above model can be extended multilayer interconnects and islands by replacing the corresponding tension and bending rigidities. where the amplitude A is to be determined, is determined 0 from tan = −2EI/ kLbridge , and / 2 ⱕ ⱕ . The limit k → ⬁ gives → , and the buckle profile degenerates to Eq. 共1兲 for a doubly clamped beam. The other limit k → 0 gives → / 2, and the buckle profile becomes w 0 兲, which satisfies w = w⬙ = 0 at two ends X = A cos共X / Lbridge 0 = ⫾ Lbridge / 2 of a simply supported beam. The bending and membrane energies in interconnects are obtained from Eqs. 共2兲 and 共7兲, respectively. Minimization of total energy gives the amplitude 冑 0 A = Lbridge APPENDIX: ROTATION AT THE ENDS OF INTERCONNECTS Section II assumes that interconnects are clamped, which gives vanishing rotation at the ends. The effect of nonvanishing rotation can be accounted for by the rotational springs with the spring constant k such that the bending moment M and the rotation at the ends of interconnects are related by M = k. For each given M, the finite element analysis of islands and substrate in Sec. III gives the rotation , and the ratio M / gives the spring constant k. For example, k = 1.58N for the elastic properties and thicknesses of islands and substrate in Fig. 5. 0 with rotational For an interconnect of length Lbridge 0 springs at its ends 共X = ⫾ Lbridge / 2兲, the equilibrium gives 3 / 12 is the EI共d2w / dX2兲 = −Nw + M, where EI = Ebridgehbridge 2共1 − cos 兲2 22 − sin共2兲 冑 0 Lbridge − Lbridge 0 Lbridge − cr , 共A2兲 2 0 cr = hbridge / 关3共Lbridge 兲2兴关2 + sin共2兲兴2 / 关2 − sin共2兲兴 where is the critical buckling strain. The maximum compressive strain in the interconnect is the sum of membrane and bending strains, and it is given by 2hbridge max = bridge ACKNOWLEDGMENTS We thank for various helps of T. Banks in processing by use of facilities at Frederick Seitz Materials Research Laboratory. This materials is based on work supported by the National Science Foundation under Grant No. ECCS0824129, NSFC, and the US Department of Energy, Division of Materials Sciences under Award No. DE-FG0207ER46471, through the Materials Research Laboratory and Center for Microanalysis of Materials 共Grant No. DE-FG0207ER46453兲 at the University of Illinois at UrbanaChampaign. J.S. acknowledges the financial support from the College of Engineering at the University of Miami. 共A1兲 0 Lbridge 冑 + cr ⬇ 2hbridge 0 Lbridge 2 2 − sin共2兲 冑 冑 2 2 − sin共2兲 0 Lbridge − Lbridge 冑 0 Lbridge 0 Lbridge − Lbridge 0 Lbridge − cr , 共A3兲 0 0 where the approximation holds for 共Lbridge − Lbridge兲 / Lbridge 0 2 Ⰷ hbridge / 共Lbridge兲 . 0 = 20 m, hbridge = 50 nm, For Ebridge = 130 GPa, Lbridge and Lbridge = 17.5 m after relaxation, Eq. 共A2兲 gives the amplitude A = 4.61 m, which agrees well with 4.50 m given by Eq. 共8兲. The maximum strain in the interconnect is 0.49% from Eq. 共A3兲, which is smaller than 0.56% given by Eq. 共11兲. Therefore, the rotation at the ends of interconnect can be neglected. G. P. Crawford, Flexible Flat Panel Display Technology 共Wiley, New York, 2005兲. 2 H. C. Ko, M. P. Stoykovich, J. Song, V. Malyarchuk, W. M. Choi, C.-J. Yu, J. B. Geddes, J. Xiao, S. Wang, Y. Huang, and J. A. Rogers, Nature 共London兲 454, 748 共2008兲. 3 V. Lumelsky, M. S. Shur, and S. Wagner, IEEE Sens. J. 1, 41 共2001兲. 4 T. Someya, T. Sekitani, S. Iba, Y. Kato, H. Kawaguchi, and T. Sakurai, Proc. Natl. Acad. Sci. U.S.A. 101, 9966 共2004兲. 5 A. Nathan, B. Park, A. Sazonov, S. Tao, I. Chan, P. Servati, K. Karim, T. Charania, D. Striakhilev, Q. Ma, and R. V. R. Mruthy, Microelectron. J. 31, 883 共2000兲. 6 S. P. Lacour, J. Jones, S. Wagner, T. Li, and Z. Suo, Proc. IEEE 93, 1459 共2005兲. 7 D. H. Kim, J. H. Ann, W. M. Choi, H. S. Kim, T. H. Kim, J. Song, Y. Huang, and J. A. 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