Food Ingredient Solutions Creating value through applications knowledge, market insight, and a powerful product portfolio Ashland Specialty Ingredients is a world leader in cellulosic food ingredients. Our premium additives and stabilizers enable healthier, tastier, and more convenient foods. Ashland’s stabilizers and gums are recognized throughout the world for quality, consistency and performance. These ingredients are derived from renewable, natural raw materials, and are produced in current Good Manufacturing Practices (cGMP) facilities in the U.S., Europe, and Asia. We do more than just manufacture -- our products are also supported by a global network of research and application scientists and technically trained salespeople. Since the 1950s, our solutions and expertise have enabled formulators to break new ground in food and beverage performance. The results are all around you: • Reduced oil uptake in fried foods • Gluten-free formulations for new-direction carbohydrates • Enhanced mouthfeel in reduced sugar beverages • Economical protein stabilization in acidified dairy products • Reduced saturated fat in your diet with meat substitutes • Enhanced moisture and shelf-life in bakery products • Reduced milk fat with creamy mouthfeel in whipped toppings • Mouthfeel and thickening with excellent clarity in beverages and syrups AeroWhip™ and Klucel™ hydroxypropylcellulose a a a a Aqualon™, Bondwell™ and Blanose™ cellulose gum a a a a a a a a Aquasorb™ cellulose gum a a Supercol™ guar gum a Water Binding Thickener Thermal Gelation a a a a a a a a a a a a a a a a a Structure Enhancer a a a a a a a Stabilizer a a a a a a a a a a a Rheology Control Mouthfeel a Benecel™ methylcellulose and hydroxypropylmethylcellulose Aquacel™ cellulose gum Foam Promoter Sauces and Savory Products Prepared Foods Pet Food Function Meat Alternatives Meat Desserts and Toppings Dairy Beverage Bakery Alcoholic Beverages Application a a a a a a AeroWhip™ and Klucel™ HPC Klucel hydroxypropylcellulose (HPC) is a unique hydrocolloid for food applications. It is extremely surface-active and its low surface and interfacial tensions in solution make it a premier whipping aid. This property, combined with its “protective colloid” action, gives it outstanding dual functionality in oil-in-water emulsions (stabilizer and emulsifier) and in whipped products (stabilizer and whipping aid). Several different viscosity grades are available. Key Benefits Alcoholic Beverages Klucel products are both water- and alcohol-soluble and can be used to thicken ready-to-drink cocktails for the desired mouthfeel. Dairy AeroWhip HPC is a specialty grade optimized for stabilizing dairy and nondairy whipped toppings. For dairy whipping creams, the amount of milk fat can be reduced significantly, leading to a healthier and more cost-effective product with a creamy mouthfeel. • Exceptional stiffness and stability Desserts and Toppings • Crisp, clean edges for decorators In nondairy whipped toppings, AeroWhip HPC creates stiff foams, increases overrun, and controls syneresis. • Fast air incorporation Klucel HPC makes strong, flexible films and is thermoplastic. The film forming property of Klucel HPC makes excellent protective coatings for candies and nuts. • Resistant to melt and deformation • Increased overrun • Improved body and mouthfeel • Prevents cracking and shrinking • Reduced fat content and cost Recommended Dosage Level by Application (wt%) Klucel™ HPC AeroWhip™ HPC Whipped topping powder Whipped topping Candy and Nut Coating Desserts and Toppings Whipping cream Low fat cream Dairy Ice cream HPC Grade EF LF JF GF 620 630 Ready-To-Drink Cocktails Alcoholic Beverages 1.0-3.02 1.0-3.02 1.0-3.02 0.2-1.0 0.2-1.0 Most recommended in bold. 1 As percentage of dry mix. 2 Klucel HPC is used in either water or alcohol based spray coating. 0.2-0.3 0.1-0.4 0.1-0.4 0.05-0.2 0.5-1.01 Benecel™ MC and HPMC Benecel methylcellulose (MC) and hydroxypropylmethylcellulose (HPMC) are versatile, multifunctional food gums. The polymeric structure of these products, which is different from other cellulosics, improves cohesion, texture and mouthfeel. They are unique hydrocolloids because they reversibly gel at elevated temperatures. Benecel MC and HPMC perform many functions in foods, depending on type, grade, use level, and conditions. Among these functions are thermal gelation, film formation, thickening, binding, and water retention. Several different viscosity grades are available. Key Benefits Bakery In fillings, thermal gelation of Benecel MC and HPMC inhibits moisture migration into pie crusts and prevents boil-out while heating fruit bars and pocket dough products. Benecel MC and HPMC stabilize dough and batter aeration to improve volume in cakes and gluten free applications. Dairy Benecel MC and HPMC improves and stabilizes aeration in dairy desserts and sherbets along with creating a firm yet creamy structure to cream cheese. Desserts and Toppings • Exceptional binding Small amounts of Benecel MC and HPMC significantly enhance foam stability. This is particularly useful in stabilizing whipped toppings and desserts. • Reduces oil pick up • Stabilizes filling during baking • Texturizes warm sauces Recommended Dosage Level by Application (wt%) Meat Balls and Patties Meat Extruded Fried Meats and Seafood Whipped Toppings Mousses Desserts and Toppings Icings and Frostings Frozen Dairy Products Cream Cheese Reduced Egg in Bakery Products Pie and Pastry Filling Dairy Pancake and Waffle Batter Gluten-Free Products Donut and Fried Pastry Cakes and Reduced Fat Cakes Bakery Cream Bakery Benecel™ MC / HPMC Grade 0.1-0.3 0.2-0.3 0.2-0.8 0.2-0.4 A4M A40M 0.2-0.6 0.2-0.6 0.1-0.4 0.3-0.6 0.5-1.0 0.3-0.6 A4C 0.2-0.6 A15 0.5-2.0 0.1-0.4 F4M 0.2-0.8 F450 0.2-0.6 0.2-0.5 0.1-0.4 0.2-0.8 0.2-0.5 F50 0.3-0.5 0.5-1.0 E15 E4M 0.2-0.4 0.2-0.5 0.2-0.5 0.1-0.4 0.2-0.8 0.2-0.5 K100LV 0.2-0.4 0.5-2.0 0.1-0.3 K4M 0.1-0.3 0.1-0.3 K35M 0.05-0.2 K200M Most recommended in bold. 1 As percentage of dry mix. Meat Alternatives Sauces and Savory Benecel MC and HPMC effectively bind food ingredients in meat alternatives, allowing them to hold their shape and maintain a meat-like texture in terms of appearance, integrity, firmness and mouthfeel. Benecel MC and HPMC add texture and viscosity to sauces through a wide range of temperatures and reduces skin formation caused by water evaporation. Prepared Foods HPMC and MC aid in shape retention of prepared foods through various freeze, thaw and cooking processes. For restructured fried foods, Benecel MC and HPMC reduce oil pick up, bind ingredients, and retain product integrity. For restructured fried foods, Benecel MC and HPMC not only reduce oil pick up but become part of the product matrix binding all the ingredients together during the frying process and reducing batter blow out. 0.4-0.6 Tomato Pizza Sauce Soups Meat Glaze Dry Mix Soup 0.2-1.0 Dry Mix Sauce 0.1-0.5 Cheese Sauce Barbecue Sauce 0.3-0.8 0.1-0.5 0.2-2.0 Sauces and Savory Products Potato Croquettes French Fries Extruded Onion Rings 0.5-1.0 Cheese Croquettes 0.8-1.0 Prepared Foods Batter for Deep-Fat Frying Vegetable Burgers 0.2-0.8 0.2-0.4 Meat Analogues Sausages Meat Nuggets/ Snacks Meat Alternatives 0.2-1.0 0.6-0.8 0.8-1.5 0.2-1.0 0.5-1.0 0.3-0.6 0.4-0.6 0.2-0.4 0.1-0.5 0.1-0.5 0.2-1.0 0.5-1.51 0.2-1.0 0.2-1.0 0.2-0.5 0.3-0.5 0.3-0.8 0.2-1.0 0.3-0.8 0.3-0.8 0.5-1.51 0.5-1.51 0.5 - 0.8 0.3-1.0 0.1-0.5 0.5-1.51 0.5-1.51 0.2-0.8 0.1-0.5 0.2-2.0 0.2-0.5 0.1-0.5 0.1-0.5 0.1-0.5 Aqualon™, Bondwell™ and Blanose™ CMC Cellulose gum from Ashland Specialty Ingredients is widely used as an cost-effective thickener and stabilizer in foods and beverages. Besides modifying the behavior of water, cellulose gum is useful in modifying flow, adding texture, and enhancing mouthfeel. A wide range of cellulose gum grades with different viscosities, molecular weights, degrees of substitution and particle sizes are available and products can be customized to meet specific applications. Our global manufacturing base is designed for your regional needs: Aqualon (US), Blanose (EU) and Bondwell (China). Key Benefits • Improved texture and mouthfeel • Clear in solution • Protein stabilization • Water absorption and retention • Pectin replacement Alcoholic Beverages Aquacel™ WS CMC is a specialty grade designed for stabilization of tartrates (KHT) preventing wine crystals in white wine. Ready-to-drink cocktails benefit from CMC’s ability to control rheology in alcohol-based beverages and achieve the desired mouthfeel. Bakery CMC has the capability for high water absorption and retention in baked and un-baked dough creating bakery products with improved texture, volume, and nut and fruit distribution. The improved water retention means delayed staling, longer shelf-life and crumb stabilization. CMC is also used in various bakery fillings to achieve a desired level of thickening ranging from fluid to creamy. CMC prevents phase separation and controls syneresis within the filling itself and reduces moisture migration into the dough. Aquasorb CMC is a specialty grade designed for maximum water holding in bakery and other applications Beverages CMC adds crystal-clear, pleasant, clean mouthfeel as it thickens any beverages to the desired viscosity. Recommended Dosage Level by Application (wt%) 7HOF 0.03-0.1 0.5-1.0 Instant Powder Drinks Juice Beverages Fruit Flavored Drinks Concentrates/Squashes Coffees and Teas Chocolate Drinks Soft Tortillas/Dry Masa Flour Pita Bread, Pizza Beverage Pie Fillings Muffins Cakes Cake Mixes Bakery Breads White Wine CMC Grade 9H7F2 9H4F 7H4F 7H3SF 7HF Ready-To-Drink Cocktails Alcoholic Beverages 0.1-0.3 0.05-0.2 0.05-0.2 0.4-0.6 0.1-0.5 0.5-1.0 0.5-1.0 0.5-1.0 0.3-0.8 0.4-0.6 0.1-0.5 7LF 7MF 7M8SF 0.1-0.4 0.3-0.8 9M31F 0.1-0.4 12M31F Aquasorb™ 0.5-1.0 0.5-1.0 0.5-1.0 0.3-0.8 0.5-1.0 A-500 Aquacel™ 40mg/L WS Most recommended in bold. 1 As percentage of dry mix. 2 Aqualon brand available only. Fine and coarse particle size products are also available in most product types. Particle size selections should be made based upon manufacturing process and final product requirements. 0.050.15 0.050.15 0.2-0.4 0.05-0.4 0.05-0.4 0.4-0.61 0.3-0.5 0.1-0.4 0.1-0.3 0.1-0.4 0.1-0.3 0.3-0.5 0.1-0.8 0.1-0.8 0.1-0.6 0.5-0.71 0.5-0.71 Aqualon™, Bondwell™ and Blanose™ CMC Dairy Desserts and Toppings Not only does CMC provide the desired mouthfeel, it also stabilizes low pH dairy beverages such as acidified milk drinks, milk, or juice blends. The stabilizing nature of CMC allows it to prevent curling separation of the dairy protein. Frozen desserts like ice cream, benefit from the water binding properties of CMC improving mouthfeel and controlling ice-crystal formation. Toppings, like sauces and savory, benefit from economic thickening and stabilization. CMC is used in ice cream to control rheology of the continuous phase. This helps with melt down, adds texture and protects against heat shock and ice-crystal formation. Recommended Dosage Level by Application (wt%) CMC Grade 0.1-0.25 0.1-0.25 0.1-0.5 0.1-0.3 0.1-0.4 9H7F2 0.1-0.5 9H4F 7H4F 0.1-0.3 0.1-0.3 0.1-0.2 0.2-0.4 *0.1-0.3 0.05-0.1 0.1-0.5 7H3SF 0.1-0.25 0.1-0.25 0.1-0.5 7HF 0.2-0.4 0.1-0.2 0.2-0.4 0.1-0.5 7HOF 0.5-0.8 0.3-0.6 0.3 -0.5 7LF 0.1 -0.5 7MF 0.2-0.5 7M8SF 0.3-0.6 0.3-0.6 0.1-0.3 0.3-0.6 9M31F 12M31F 0.1-0.3 Aquasorb™ A-500 Aquacel™ WS Most recommended in bold. 1 As percentage of dry mix. 2 Aqualon brand available only. Fine and coarse particle size products are also available in most product types. Particle size selections should be made based upon manufacturing process and final product requirements. Water Ice/Ice Pops Sherbet Meringues Marzipan Marshmallow Topping Icings Chocolate Topping Yogurt and Butter Milk Drinks Spreadable Cheese Desserts and Toppings Soft Serve Puddings Ice Milk Ice Cream Cottage Cheese Acidified Milk Drink Dairy 0.1-0.5 0.1-0.5 Meat Prepared Foods Emulsified and frozen meats have improved yield, less phase separation and less cracking as CMC binds the water in the product. The water binding also acts as a releasing agent when peeling off meat casings. CMC hydrates quickly making it an ideal stabilizer for thickening in dry mix preparations. For extruded snacks, it aids with extrusion and improves breaking strength. Pet Food CMC is a cost-effective thickener and stabilizer in a wide variety of sauces and savories that controls and reduces syneresis. Sauces and Savory CMC thickens the gravy, retards the softening of pellets in dry pet food, improves extrusion and appearance of semi-moist pet food and stabilizes the fat in canned pet food. 0.3-0.5 0.1-0.3 0.1-0.3 0.1-0.4 0.4-0.6 0.2-0.5 0.2-0.6 0.05-0.3 0.1-0.5 Table/Pancake Syrup Salad Dressings Pickle Relish Mayonnaise Ketchup Fruit Preps and Jams Barbecue Sauce 0.1-0.5 Cheese Sauce Sauces and Savory Products Instant Spice Mixes/Dips Instant Hot Cereal Instant Fried Noodles Extruded Snacks Prepared Foods Soft, Semi-Moist Pet Food Dry Pet Food Canned Pet Food Pet Food Meat Casings Frozen Fish Emulsified Meat and Fish Meat 0.05-0.3 0.5-1.01 0.1-0.51 0.5-1.01 0.5-1.0 0.3-0.6 0.3-0.6 0.1-0.51 0.2-0.6 0.3-0.8 0.1-0.4 1.0-2.0 0.2-0.6 0.5-1.0 0.1-0.5 0.5-0.8 0.1-0.5 0.4-0.8 0.3-0.5 1.0-2.0 0.3-0.5 0.5-1.0 0.8-1.5 1 0.5-1.0 0.2-0.5 0.4-0.8 0.5-1.0 0.5-1.0 0.3-0.5 0.5-1.0 0.5-1.0 0.4-0.8 Supercol™ guar gum Bakery When it comes to guar, Ashland manufactures the highest quality guar available for viscosity build. Our Supercol guar gum is processed in the U.S. for high purity, low odor, and low flavor. Broadly used in bakery, dairy, and pet food applications, Supercol guar gum is the choice for companies that want to control costs while increasing quality. For pie fillings guar is adaptable to any method of processing allowing full flavor to come through with good body and eye appeal. For tortilla manufacturing retardation of a product’s cracking tendency and reduction of dough stiffness is important. Guar solves the problems and enables improved machining quality. Several different viscosity grades are available. Beverages Key Benefits • Very low odor Guar improves mouthfeel and prolongs suspension time of fruit particles all with minimal flavor contribution. • Very low flavor Dairy • Economical In ice cream, guar enables rapid dispersion, along with good uniformity and body. In cheese products guar prevents syneresis, improves shelf life, and enables better distribution of particles. • Quick viscosity build Recommended Dosage Level by Application (wt%) Most recommended in bold. 1 As percentage of dry mix. Cold-Pack Cheese 0.2-0.6 0.3-0.5 0.1-0.3 0.01-0.1 0.1-0.4 0.4-0.6 0.01-0.1 0.1-0.3 0.2-0.6 0.2-0.4 0.1-0.3 Ice Cream Cheese Spread 0.4-0.61 Cream Cheese Cheese Sauce 0.01-0.1 Cottage Cheese Instant Powder Drinks 0.1-0.4 Dairy Beverages Beverages Soft Tortillas/Dry Masa Flour Supercol™ guar gum Grade U US GF G2-S K-1 Pie Fillings Bakery 0.3-0.4 0.1-0.4 0.1-0.3 0.2-0.4 0.1-0.25 Desserts and Toppings Prepared Foods Guar enables rapid cold-water hydration and easy of incorporation of overrun for icings and frosting. Guar eliminates the need for boiling in instant mixes, adds viscosity, increases moisture retention and improves shelf-life. For noodles it enables more elastic properties and aids in dough handling. In soups it improves mouthfeel and suspension of meat and vegetable pieces. Meat For canned meat guar immobilizes the free water. It also helps with improvement of flow rate during stuffing casing and product firmness and increased viscosity in encased products. For sauces and savory, guar helps with maintaining a uniform body, water retention and heat-cold resistance. 0.2-0.5 0.3-0.6 0.1-0.3 0.2-0.4 0.5-0.81 0.2-0.4 0.5-0.8 Soups 0.5-1.01 Mustard 0.3-0.6 Barbecue Sauce 0.1-0.3 Instant Soup Mixes Canned Meat 0.1-0.3 Sauces and Savory Products Instant Noodles Icings 0.3-0.6 Prepared Foods Instant Dressings and Dips Frostings Pet Food Doughnut Manufacturing Meat Canned Pet Food Guar stabilizes meat and vegetable chunks in pet food. Gravies Pet Food Desserts and Toppings Sauces and Savory 0.1-0.2 0.4-0.9 1 0.1-0.3 0.3-0.6 0.3-0.6 0.5-1.0 0.2-0.5 0.2-0.4 0.2-0.4 0.2-0.4 0.3-0.6 0.3-0.6 0.2-0.5 0.2-0.4 0.1-0.2 Regulatory Information HPC Regulatory Klucel and AeroWhip HPC comply with the requirements of the U.S. Food and Drug Administration for direct additives to food for human consumption, as specified in the Code of Federal regulations, Title 21, Part 172.870 and the monograph requirements for hydroxypropylcellulose in the Food Chemicals Codex and JECFA, current editions. Klucel and AeroWhip HPC also conforms to the purity criteria of E463 as mentioned in the Annex of EC directive 98/86/EC and amendments, and conforms to Japan’s MHLW Ordinance No. 131 and Ordinance amendment No. 23 adding HPC [No. 255]. HPC Labeling Common label declarations include hydroxypropylcellulose and E463. MC and HPMC Regulatory Status Benecel MC complies with the requirements of the U.S. Food and Drug Administration for use in foods as specified in the U.S. Code of Federal Regulations, Title 21, Part 182.1480, “Substances Generally Recognized as Safe” (GRAS). Benecel HPMC complies with the requirements of the U.S. Food and Drug Administration for direct addition to foods as specified in the U.S. Code of Federal Regulations, Title 21, Part 172.874. Benecel MC and HPMC comply with the monograph requirements set forth in the Food Chemicals Codex and JECFA, current editions. Benecel MC and HPMC also comply with the purity criteria of E461 and E464, respectively, as mentioned in the Annex of EC directive 98/86/EC and amendments. MC and HPMC Labeling Common label declarations include methylcellulose, E461, and hydroxypropylmethylcellulose, E464. CMC Regulatory Status Aqualon, and Blanose and Bondwell CMC F-suffix A types cellulose gum comply with the requirements of the U.S. Code of Federal Regulations, Title 21 section 182.1745, “Substances Generally Recognized as Safe” (GRAS) for use in foods and meets the monograph requirements set forth in the Food Chemicals Codex and JECFA, current editions. Cellulose gum also conforms to the purity criteria of E466 as mentioned in the Annex of EC directive 98/86/EC and amendments. An ADI (acceptable daily intake) of “not specified” has been allocated by the Scientific Committee of the EU and the Joint FAO/WHO Expert Committee on Food Additives. Specific Bondwell grades from Jiangmen also comply with local Chinese and other AP standards. Both 95% and 99.5% purity grades are available. Please contact your local sales representative for more information. CMC Labeling “Cellulose Gum”, accepted as a common or usual name for purified sodium carboxymethylcellulose, may be used in food label ingredient statements. Common label declarations include cellulose gum, CMC and E466. Guar Gum Regulatory Status SUPERCOL guar gum complies with the monograph requirements for guar gum in the Food Chemicals Codex and JECFA, current editions. Supercol guar gum also conforms to the purity criteria of E412 as mentioned in the Annex of EC directive 98/86/EC and amendments. It is affirmed as Generally Recognized as Safe (GRAS) for direct addition to human food and is in compliance with the requirements of the U.S. Food and Drug Administration as specified in the Code of Federal Regulations, Title 21, Section 184.1339, subject to the limitations and requirements therein. Guar Gum Labeling Common label declarations include guar gum. Global Headquarters Ashland Inc. 50 East RiverCenter Blvd. P.O. Box 391 Covington, KY 41012-0391 U.S.A. Tel: +1 859 815 3333 Ashland Specialty Ingredients 8145 Blazer Drive Wilmington, DE 19808 U.S.A. Tel: +1 877 546 2782 Regional Centers Europe — Switzerland Tel: +41 52 560 55 00 Fax: +41 52 560 55 99 Asia Pacific — Singapore Tel.: +65 6775 5366 Fax: +65 6776 9690 Nanjing Technical Center Tel.: +86 025 83520888 food@ashland.com ashland.com/food+beverage ® Registered trademark, Ashland or its subsidiaries, registered in various countries ™ Trademark, Ashland or its subsidiaries, registered in various countries ©2010, 2011, 2013, Ashland PC-10238.5 All statements, information and data presented herein are believed to be accurate and reliable, but are not to be taken as a guarantee, an express warranty, or an implied warranty of merchantability or fitness for a particular purpose, or representation, express or implied, for which Ashland Inc. and its subsidiaries assume legal responsibility.