MECHANICAL HYSTERESIS IN MATERIALS USED IN SUPERCONDUCTING ELECTRICAL MACHINES R. Adams, V. Coveney To cite this version: R. Adams, V. Coveney. MECHANICAL HYSTERESIS IN MATERIALS USED IN SUPERCONDUCTING ELECTRICAL MACHINES. Journal de Physique Colloques, 1983, 44 (C9), pp.C9-291-C9-296. <10.1051/jphyscol:1983940>. <jpa-00223387> HAL Id: jpa-00223387 https://hal.archives-ouvertes.fr/jpa-00223387 Submitted on 1 Jan 1983 HAL is a multi-disciplinary open access archive for the deposit and dissemination of scientific research documents, whether they are published or not. The documents may come from teaching and research institutions in France or abroad, or from public or private research centers. L’archive ouverte pluridisciplinaire HAL, est destinée au dépôt et à la diffusion de documents scientifiques de niveau recherche, publiés ou non, émanant des établissements d’enseignement et de recherche français ou étrangers, des laboratoires publics ou privés. JOURNAL DE PHYSIQUE Colloque C9, supplement au n°12, Tome 44, decembre 1983 page C9-291 MECHANICAL HYSTERESIS IN MATERIALS USED IN SUPERCONDUCTING ELECTRICAL MACHINES R.D. Adams and V.A. Coveney University of Bristol, Bristol BS8 1TR, U.K. Dept. of Mechanical Engineering, Queen's Building, Resunfe -- Nous presentons Resunfe présentons iici o i lles e s rrésultats e s u l t a t s pour pour quelques quelques materiaux matériaux qui qui seront seront u t i l i s e s dans utilisas dans lles e s machines 'électriques e^lectriques supraconductrices supraconductrices (cryogênerateurs). (cryogenerateurs). Abstract -- W Abstract Wee present present damping rresults e s u l t s for for aa v variety a r i e t y of of m materials a t e r i a l s which will will be used in in superconducting eelectrical l e c t r i c a l machines (cryoalternators). (cryoalternators). I - INTRODUCTION There are several practical applications for which knowledge of the dynamic behaviour of materials at temperatures near and below 20 K is important. These applications include liquid hydrogen technology and superconductor applications. At present, most of the liquid hydrogen applications are in the area of rocket propulsion although there are tentative plans for hydrogen powered aircraft. Superconductor applications include NMR, particle accelerators, plasma confinement and nuclear fusion, and superconducting AC generators. The purpose of this work was to study the materials used in superconducting AC generators so that losses due to mechanical hysteresis can be established reliably. The problem is the inverse of that which is usually encountered in engineering. Here, the interest is in low energy dissipation since the problem is not that of resonance, but rather of heat generation within the AC generator which can result in the conductors losing their superconducting properties. While much is known of the damping properties of constructional materials at room temperature, less is known of these properties at very low temperatures, and even less when cyclic stresses of engineering significance are considered. The objective of this work is to obtain results for several structural materials, such as copper, superconducting alloys, stainless steel and glass fibre reinforced plastics. The unit of damping used here is the specific damping capacity, IJJ, defined as ty = bJJ/U where U is the maximum energy stored per cycle, and At/ is the energy dissipated. Some predictions will be made for the power dissipation per unit volume of material assuming a cyclic strain amplitude of 10 4 and a frequency of 50 Hz. II - EXPERIMENTAL PROGRAMME The specimen was in the form of a free-free beam and was driven in its first flexural mode of vibration by a coil/magnet pair. The damping and natural frequency were recorded automatically as the temperature changed over the range from M-K to 293 K. A programmed microcomputer was used to control the frequency and amplitude of the excitation via a digital frequency synthesiser and a digital voltmeter. The microcompter controlled up to twenty information channels, so that readings were also taken of temperature as well as calculating the damping values. In this way, a print-out was given of damping and natural frequency at different cyclic stress amplitudes over a range of temperatures. The specimen consists of a beam in bending and it is known that there is a linear variation of stress across the section in addition to the lengthwise variation in Article published online by EDP Sciences and available at http://dx.doi.org/10.1051/jphyscol:1983940 C9-292 JOURNAL DE PHYSIQUE bending moment. However, t h i s can be accounted f o r by measuring t h e v a r i a t i o n of damping with displacement amplitude and then using a f u n c t i o n of t h e form t o g e t h e r with t h e v a r i a t i o n of s t r e s s , o, with p o s i t i o n i n t h e specimen. technique is f u l l y described i n r e f e r e n c e s 1 and 2 . This -4 could be a t t a i n e d i n t h e apparatus Cyclic s t r a i n s of t h e order of 10 % used and t h i s was necessary i n o r d e r t o cover t h e range of amplitudes l i k e l y t o be achieved i n c r y o a l t e r n a t o r s . I11 RESULTS AND DISCUSSION Annealed cryogenic grade copper We were r a t h e r s u r p r i s e d a t first a t f i n d i n g a Bordoni peak i n annealed copper ( s e e Fig. l ) , a s t h i s r e s u l t appeared t o c o n t r a d i c t work published by N i b l e t t & Wilks ( 3 ) who found a ~ d r d o n peak i only f o r cold-worked copper. In o r d e r t o check t h a t t h e v i b r a t i o n t e s t i n g had not cold-worked t h e copper, t h e Vickers hardness (KV10 = 5052) of a specimen t h a t had been t e s t e d a t l o w temperature was compared with a s i m i l a r , u n t e s t e d annealed specimen, Temperature Fig. 1 V a r i a t i o n of s p e c i f i c damping c a p a c i t y , 6, with temperature f o r copper, two Nb T i superconductors, a composite c a b l e and GlOCR g l a s s c l o t h i n eP oxy and with another s i m i l a r u n t e s t e d annealed specimen which had subsequently been extended c o l d by 1.4% (HV10 = 56+2). These hardness t e s t s i n d i c a t e d t h a t t h e e x t e n s i o n , whereas amount of cold-work introduced by t e s t i n g was e q u i v a l e n t <1% t h e curve of damping a g a i n s t temperature c l o s e l y ressembled N i b l e t t and Wilks' curves f o r >2%. I t i s now b e l i e v e d t h a t t h e Bordoni peak occurs f o r annealed when t h e a p p l i e d c y c l i c s t r e s s i s s u f f i specimens i n very pure f . c . c . metals c i e n t l y high ( 4 , 5 ) . Superconducting a l l o y s S e v e r a l superconducting a l l o y s were t e s t e d , both i n t h e pure form and f a b r i c a t e d a s f i l a m e n t s i n a copper m a t r i x . There was a s t r o n g maximum i n damping (I) 2 1.9%) i n t h e as-received NbTi and a s s o c i a t e d with t h i s damping peak was a minumum i n If changes i n l e n g t h can resonant frequency and, t h e r e f o r e , i n Youns modulus. be n e g l e c t e d , a t t h e minimum t h e modulus i s 3% below t h e room temperature v a l u e . I n a d d i t i o n , t h e r e is a secondary damping peak (I) 2 0.95%) a t 25K. A f t e r 300% cold work, t h e major damping peak has diminished t o approximately t h e same l e v e l a s t h e secondary peak, which h a s been much l e s s e f f e c t e d . Not s u r p r i s i n g l y , t h e behaviour of t h e Cu/NbTi composite ( t y p e A61) r e f l e c t s t h a t of both t h e copper and t h e NbTi. A s f o r copper, t h e Bordoni peak is t h e dominant f e a t u r e a t 70K (I) = 2.6%). But it should be noted t h a t t h i s peak i s s t r o n g e r t h a n t h e ("law of mixtures") combination of r e s u l t s f o r copper and NbTi. I t appears t h a t t h e r e i s a r e s i d u a l e f f e c t of cold-work on t h e copper i n s p i t e of t h e anneali n g a t 350 C t o one hour a f t e r each draw. Glass f i b r e r e i n f o r c e d p l a s t i c s R e s u l t s a r e given here f o r t y p e GlOCR GRP composite which i s a cryogenic grade m a t e r i a l made from g l a s s c l o t h i n a n epoxy matrix. It can be seen from Fig. 1 t h a t t h e r e is a l a r g e damping peak (6 = 6.6%) a t 240K. There was a l s o a l a r g e i n c r e a s e i n Young's modulus (about 20%) a s t h e temperature was decreased from 30GK t o 4K. It i s believed t h a t t h e main damping peaks i n t h e epoxies a r e due t o (main chain) segmental motion and it is t h i s behaviour t h a t g i v e s epoxies t h e i r r e l a t i v e l y high damping c h a r a c t e r i s t i c s near room temperature; a t low temperatures t h e y t a k e on a different (glassy) character. Since GlOCR u s e s a solid-type epoxy r e s i n t h e manufacturers were unable t o manuf a c t u r e a s u i t a b l e p i e c e o f r e a c t e d r e s i n f o r our t e s t s . However, a specimen made from a s i m i l a r epoxy (Ciba MY750) gave a damping peak of I) = 20% a t 210K, confirming t h a t t h e peak i n t h e GlOCR m a t e r i a l was matrix dominated. Stainless s t e e l s Three s t a i n l e s s s t e e l s o f t h e AISI 316 family were t e s t e d . These a r e candidate m a t e r i a l s f o r t h e r o t o r of a c r y o a l t e r n a t o r and comprise t h e bulk of m a t e r i a l . A l l of t h e s e m a t e r i a l s gave very much lower damping v a l u e s ( s e e Fig. 2) than t h e copper, superconductors and GRP, t h e lowest being 316 LN. The anomalies i n t h e r e s u l t s f o r 316 LN were r e p e a t a b l e , b u t not e x p l a i n a b l e . A l l t h e s t a i n l e s s s t e e l s t e s t e d showed a p p a r e n t l y anomalous behaviour i n Young's modulus below a c e r t a i n temperature (40-70K). This t y p e of anomalous behaviour ( 6 ) and has been r e p o r t e d ( a t very much h i g h e r f r e q u e n c i e s ) by Ledbetter Ledbetter ( 7 ) , who have suggested t h a t it was due t o magnetic t r a n s i t i o n s ( 6 ) and probably s p i n - g l a s s t r a n s i t i o n s ( 8 ) . However, it h a s a l s o been suggested t h a t t h e anomalies might be due t o p a r t i a l A u s t e n i t i c - M a r t e n s i t i c t r a n s i t i o n s , which could have important i m p l i c a t i o n s f o r t h e use of t h e s e s t e e l s . A simple experiment has been c a r r i e d out by u s which involved comparing t h e inductance of a c o r e l e s s c o i l and a s i m i l a r c o i l with EN58B (304) s t e e l specimen a s t h e c o r e . The two c o i l s which formed two limbs of an out of balance, 2kHz a . c . bridge were taken through st JOURNAL DE PHYSIQUE Temperature K Fig. 2 Variation of s p e c i f i c damping c a p a c i t y , $, w i t h temperature f o r t h r e e stainless steels t h e temperature range 4K - 300K. There was some p o s s i b l e i n d i c a t i o n of "anomalous" magnetic behaviour ( i e : r e v e r s a l i n dL/dT) a t and below l o O K , whereas t h e anomaly i n e l a s t i c modulus occurred a t and below 70K. The magnitude of t h e anomaly i n inductance was not c o n s i s t e n t with an A u s t e n i t i c t o M a r t e n s i t i c t r a n s i t i o n of more than I%,and was t h e r e f o r e u n l i k e l y t o have caused t h e l a r g e modulus anomaly observed. It should be pointed out t h a t both we and Ledbetter measure E from t h e v e l o c i t y of sound ( ~ / p ) +and t h e dimensions of t h e specimen. I f t h e dimensions show some anomalous v a r i a t i o n w i t h temperature, then it is d i f f i c u l t by dynamic t e s t s t o s e p a r a t e t h e two parameters. Additional work on t h e expansion of m a t e r i a l s ( e s p e c i a l l y s t a i n l e s s s t e e l s ) i n t h e range 4 - 300K is t h e r e f o r e being c a r r i e d out using a very s e n s i t i v e d i l a t o m e t e r . The purpose of t h i s work is t o s e e i f t h e r e a r e any anomalies i n expansion which can be r e l a t e d t o t h e anomalies i n r e s o n a n t frequency. Energy d i s s i p a t i o n To convert t h e values of damping i n t o energy d i s s i p a t i o n , we use t h e equation: AU where and = $j'EE2lJ, f = frequency of v i b r a t i o n , E = Young's modulus E = s t r a i n amplitude. -4 Using v a l u e s of f = 50hz and E = 10 f o r a temperature of 4K. , we a r r i v e a t t h e values given i n Table 1 Table 1 Energy d i s s i p a t i o n i n c r y o a l t e r n a t o r m a t e r i a l s 3 (Watts/m ) Material All Cryogenic grade copper >350 NbTi a s received 103 NbTi cold worked 300% A61 superconductor 88 -200 GlOCR GRP 20 316 annealed 33 316 LN annealed 17 316 High C 17 It is c l e a r from t h e s e r e s u l t s t h a t t h e superconductor is a s i g n i f i c a n t source of energy d i s s i p a t i o n , owing t o t h e high damping of both t h e NbTi and t h e copper. Under c y c l i c c o n d i t i o n s of l o a d i n g , it i s t h e r e f o r e e s s e n t i a l t h a t t h e h e a t gene r a t e d be conducted away e f f i c i e n t l y . IV CONCLUSIONS Damping r e s u l t s have been given f o r a v a r i e t y of c r y o a l t e r n a t o r m a t e r i a l s . Under t h e c y c l i c loading c o n d i t i o n s which may be experienced i n p r a c t i c e , t h e h i g h e s t energy d i s s i p a t i o n w i l l occur i n t h e superconductors and t h e s e must t h e r e f o r e be adequately cooled. V REFERENCES 1. Adams R.D.& J. Phys. D: Appl. Phys, Bacon D.G.C., 2. Guild F.J.& Adams R.D., 3. N i b l e t t D.H. 4. N i b l e t t D .H., 5. Stadelmann P. & Benoit W . , 6. Ledbetter H.M., J . Phys. E: S c i . I n s t r . , & Wilks J . , P h i l . Mag., 2, 6, (1973), 27. 14,(1981), 355. (1957), 1427. P r i v a t e communication. Weston W.F. S c r i p t a Metallurgica, & Naimon E.R., 11,(1977), J . Appl. Phys., 645. 5, (1975), 3855. C9-296 7. L e d b e t t e r H.M., 8. C o l l i n g s E.W. JOURNAL DE PHYSIQUE J . Appl. Phys., & L e d b e t t e r H.M., 52, (19811, 1587. Physics L e t t e r s , c, (1979), 53.