SAFETY DATA SHEET
1.
PRODUCT NAME:
PRODUCT CODE:
PRODUCT AND COMPANY IDENTIFICATION
CONTACT CEMENT BRUSH GRADE
PRODUCT CODE
VV1700
VV1701
VV1702
PRODUCT PACKAGING
Quarts
Gallon
Pail
CHEMICAL NAME:
CHEMICAL FAMILY:
POLYCHORINATED RUBBER
POLYCHORINATED RUBBER RESIN
FORMULA:
PROPIETARY
Supplier:
MASTER PAINTS & CHEMICAL CORP.
GUAYANILLA PR, 00656-0248
Telf : 787- 835 4000 / 787 835 4001
Fax: 787- 8352223
E-fax: 787-966 7180
www.mastergroup-pr.com
2.
Components
EMERGENCY TELEPHONE: (INFOTRAC) 1-800-535-5053
COMPOSITION INFORMATION ON COMPONENTS
CAS-Number
WT/WT
Units
(%)
Range
Vapor
Pressure)
Polychorinated Rubber
Propietary
Phenolic Resin
Propietary
Aromatic Solvent (Mix)
Propietary
Suplier Trade Secret
Propietary
15 -25
N/A*
N/A
OSHA: 0.75 ppm 8 hour TWA, 2.0
ppm STEL.
ACGIH: 0.3 ppm ceiling
N/A
0- 10
35-45
OSHA PEL: TWA 200 ppm
CL 300 ppm 500ppm (10min. max.
peak)
ACGIH TLV: TWA 20 ppm
5.9 mm
<1
ACGIH (TLV) - TWA: 10 (mg/m3)
OSHA (PEL) TWA: 15 (mg/m3)
N/A
Acetone
67-64-1
15-20
OSHA PEL : TWA 1000ppm
ACGIH TLV: 500 ppm STEL 750
ppm
*Material is not known to contain Toxic Chemicals under Section 313 of Title III of the Superfund Amendments (SARA) and Reauthorization Act of
1986 and 40 CFR part 372.
Legend
ACGIH - American Conference of Governmental Industrial Hygienists
STEL: Short Term Exposure Limit
TLV: - Threshold Limit Value (8 hr. Time weighted Average or TWA)
OSHA - Occupational Safety & Health Administration
3.
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HAZARDS IDENTIFICATION
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GHS Label elements, including precautionary statements
Emergency Overview
Signal word
Danger
Hazard Statements
Causes skin irritation
Causes serious eye irritation
May cause drowsiness or dizziness
Suspected of damaging fertility or the unborn child
May cause damage to organs through prolonged or repeated exposure
Highly flammable liquid and vapor
Appearance Clear, colorless to
Physical State Liquid
yellow/orange
Precautionary Statements - Prevention
Obtain special instructions before use
Do not handle until all safety precautions have been read and understood
Use personal protective equipment as required
Wash face, hands and any exposed skin thoroughly after handling
Use only outdoors or in a well-ventilated area
Do not breathe dust/fume/gas/mist/vapors/spray
Keep away from heat/sparks/open flames/hot surfaces. - No smoking
Keep container tightly closed
Ground/bond container and receiving equipment
Use explosion-proof electrical/ ventilating/ lighting/ equipment
Use only non-sparking tools
Take precautionary measures against static discharge
Keep cool
Wear eye/face protection
Odor Aromatic solvent/toluene
Precautionary Statements - Response
IF exposed or concerned: Get medical advice/attention
Specific treatment (see supplemental first aid instructions on this label)
Eyes
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing
If eye irritation persists: Get medical advice/attention
Skin
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower
If skin irritation occurs: Get medical advice/attention
Wash contaminated clothing before reuse
Inhalation
IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
Fire
In case of fire: Use CO2, dry chemical, or foam for extinction
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4.
FIRST AID MEASURES
Inhalation:
Remove patient to fresh air. If patient is having difficulty breathing, seek immediate medical attention. If not
breathing, clear airway and start mouth-to-mouth artificial respiration (or use bag-mask
respirator). Seek
immediate medical attention.
Skin Contact:
Wash affected areas with soap and water. If irritation develops, seek medical attention. If product is
absorbed into clothing, remove clothing as soon as possible. Launder clothing before reusing.
Eye Contact:
Flush eyes with water for 15 minutes. Remove contact lenses prior to water flush. Seek medical
attention.
Ingestion:
Give patient 3-4 glasses of water. DO NOT induce vomiting. Seek immediate medical attention. DO NOT
give anything by mouth to an unconscious person. Ingestion may cause irritation to the gastro-intestinal
tract.
Additional Information:
Sudden death due to ventricular fibrillation has been reported from acute inhalation in
chronic
solvent
abusers. Life support should be provided due to CNS depression, cardiopulmonary failure,
and
Metabolic acidosis in massive overexposure.
5.
FIRE-FIGHTING MEASURES
Flash Point: -5ºF (23 ºF) / Seta Flash Closed Cup
Burning Rate: Not Available
Flammability Classification: Flammable liquid
Firefighting Equipment: Use self-contained breathing apparatus with full-face piece and pressure demand or other
positive-pressure mode.
Risk of explosion due to mechanical impact: Not Available
Risk of explosion due to static discharge: Static discharge may serve as an ignition source for this product.
Hazardous Products of Combustion: Carbon Oxides (CO and CO2) and various Hydrocarbons.
Special Remarks:
Extremely flammable liquid and vapor. Vapor may cause flash fires. Vapors are heavier than air
and can travel long distances to ignition sources. For small or incipient fire, use dry chemical, CO2,
or alcohol foam. For large fire, use alcohol foam, water spray or fog. Cool containing vessels with
water jet to
prevent pressure build-up, autoignition, or explosion. All electrical equipment in
area must be rated for
flammable liquids. Bond and ground all containers when dispensing.
6.
ACCIDENTAL RELEASE MEASURES
Personal Precautions: Wear appropiate PPE. Extremely flammable. Remove all sources of ignition. Make sure area
is well ventilated. Spilled adhesive may be slippery
Environmental Precautions: Prevent further leakage or spillage if safe to do so. Prevent product from entering
drains. Do not flush into surface water or sanitary sewer system.
Small Spill or Leak: Absorb spilled product with vermiculite, dry sand, or earth. Place in a suitable non-leaking
container and tightly seal for disposal.
Large Spill or Leak:
Dike and contain spill. Absorb spilled product with vermiculite, dry sand, or earth. Place in a
suitable non-leaking container and tightly seal for disposal.
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7.
HANDLING AND STORAGE
Handling Precautions:
Wear appropriate PPE. Keep away from heat, sparks, and flames. If used indoors, make sure to provide
adequate ventilation to prevent vapor build-up. Bond and ground all containers when dispensing. All
electrical equipment in area must be rated for flammable liquids.
Storage Requirements:
Flammable material should be stored away form other materials in a storage cabinet or room. Store in a
cool, dry, well-ventilated area. Ensure product is kept away from all sources of heat and sparks. Keep
container tightly closed when not in use. Prohibit smoking in the storage area. Do not store with acids or
oxidizers.
8.
EXPOSURE CONTROLS / PERSONAL PROTECTION
Engineering Controls: Provide exhaust ventilation or other engineering controls to keep airborne concentrations of
vapors below their respective threshold limit value. Ensure that a working eyewash and safety shower are in
the work area.
Protective Equipment: Wear splash goggles or safety glasses with side shields, synthetic apron, and neoprene or
rubber gloves. In case of insufficient ventilation, wear an approved (NIOSH) respirator with organic vapor
cartridge and dust/mist pre-filter.
Exposure Guidelines/Other:
Product Name
Exposure Limits
n-Hexane
OSHA PEL: TWA 500ppm
ACGIH TLV: TWA 50 ppm
Toluene
OSHA PEL: TWA 200ppm. CEL 300 ppm.
ACGIH TLV: TWA 20 ppm
Acetone:
OSHA PEL: TWA 1000 ppm
ACGIH TLV: TWA 500 ppm STEL 750 ppm
Consult local authorities and local regulations for exposure limits.
9.
PHYSICAL AND CHEMICAL PROPERTIES
Appearance:
Clear Red Liquid
Odor:
Strong Solvent
PH:
Not Applicable
Specific Gravity / Density: 0.89 / 7.4 lbs./ gal
Volatile by weight (max):
80 %
Non Volatile Component by weight (min): 20 %
Vapor Pressure:
Vapor Density:
Evaporation Rate
VOC Content:
602.5g/L
Boiling Point:
(176 -185)ºF / (80-85)ºC Flash
Point: -5ºF (23 ºF ) / Seta Flash Closed Cup
Viscosity:
(700 – 1800) cps
Solubility:
Not Soluble in Water
185 mm Hg @ 20ºC
Highest component value is 3.14 for Toluene (air = 1)
Weighted average is 2.65 (air = 1)
Highest component value is 7.7 for Acetone
Weighted average is 6.1compared to Butyl Acetate
10.
Chemical Stability:
500ppm (10 min. max. peak)
STABILITY AND REACTIVITY
Product is stable as supplied.
Conditions To Avoid: All ignition sources and elevated temperatures.
Incompatible Materials: Cooper and Cooper alloys, strong acids, alkalies, reducing agents, and oxidizers
Hazardous Decomposition Products: Carbon dioxide (CO and CO2) and Hydrocarbons.
Possibility Of Hazardous Polymerization: Will not occur by itself.
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11.
Acute Toxicity to Animals:
Acetone:
n-Hexane:
Toluene:
TOXICOLOGICAL INFORMATION
Inhalation 4 hour LC50=30000ppm (rat)
Inhalation 4 hour LC50=18600ppm (mouse)
Oral LD50=5800 mg/kg (rat)
Dermal LD50>16000 mg/kg (rat)
Inhalation 4 hour LC50=38500 ppm (rat)
Oral LD50: 28700 mg/kg (rat)
Inhalation 4 hour LC50=7585 (rat)
Inhalation 4 hour LC50=7100 ppm (mouse)
Oral LD50=5580 mg/kg (male rat)
Dermal LD50=12125 mg/kg (rabbit)
Chronic Toxicity to Animals: No additional information
Acute Toxicity to Humans: No additional information
Chronic Effects on Humans: Classified PROVEN for human (n-Hexane). n-Hexane has been shown to cause
neuropathy (numbness of arms and legs) in long term exposures .
Carcinogenic Effects: Not classifiable for humans or animals.
Mutagenic Effects: Classified NONE for human.
Teratogenic Effects: Classified PROVEN for human (Toluene).
Developmental Toxicity:
Classified PROVEN for human (Toluene). Causes damage to kidneys, liver, and central nervous system.
Has been reported to cause spontaneous abortion in woman that intentionally concentrated and inhaled
vapors.
12.
ECOLOGICAL INFORMATION
Ecotoxicity:
Product may kill grasses and small plants. Non-toxic to fish. Moderately toxic to amphibians by preventing
dermal respiration. may cause gastrointestinal distress to birds and mammals by ingestion.
BOD5 and COD: Not Available.
Biodegradable/OECD: Not Available
Mobility: Not Available
Toxicity of the Products of Biodegradation: Not Available
Special Remarks on the Products of Biodegradation: Not Available
13.
DISPOSAL CONSIDERATIONS
Spilled, contaminated, or waste material should be put into a suitable container and handled according to Federal,
State, and local regulations. Contact a qualified waste management company for assistance. Do not incinerate, weld,
cut or braze container. Residual vapors may be explosive. Empty containers should be disposed of properly.
Dispose of in accordance with Federal, State and Local regulations.
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14.
TRANSPORT INFORMATION
Multi-modal shipping descriptions are provides for informational purpose and do not consider container sizes. The
presence of a shipping description for a particular mode of transport (ocean, air, etc.), does not indicate that the
product is packaged suitable for that model of transport. All packaging must be reviewed for suitability prior to
shipment, and compliance with the applicable regulations is the sole responsibility of the person offering the product
for transport.
DOT
5 Liter (1.3 Gallons) and Less may be Classed as LTD. QTY.
Larger Containers are Regulated as: UN1133, ADHESIVES, CONTAINING FLAMMABLE LIQUID, 3, PG II,
(ERG#128)
Proper Shipping Name
Hazard Class
Packing Group
Marine Pollutant
ERG Number
ADHESIVES, CONTAINING FLAMMABLE LIQUID
3
II
This product do not contains a chemical which is listed as a marine pollutant according
to DOT
128
TDG
UN-No.
Proper Shipping Name
Hazard Class
Packing Group
Description
UN1133
ADHESIVES
3
II
N1133, ADHESIVES, 3, II
MEX
UN-No.
Proper Shipping Name
Hazard Class
Packing Group
Description
UN1133
ADHESIVES
3
II
UN1133, ADHESIVES, 3, II
ICAO
UN-No.
Proper Shipping Name
Hazard Class
Packing Group
Description
UN1133
ADHESIVES
3
II
UN1133, ADHESIVES, 3, II
IATA
UN-No.
Proper Shipping Name
Hazard Class
Packing Group
Description
UN1133
ADHESIVES
3
II
UN1133, ADHESIVES, 3, II
IMDG/IMO
UN-No.
Proper Shipping Name
Hazard Class
Packing Group
EmS-No.
Description
UN1133
ADHESIVES
3
II
F-E, S-D
UN1133, ADHESIVES, 3, II, (-5°C C.C.)
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15.
REGULATORY INFORMATION
U.S. Federal Regulations
Chemical (& CAS Number)
SARA 302
(EHS)TPQ
SARA 304 (EHS)
Rq
Acetone (67-64-1)
n-Hexane (110-54-3)
Toluene (108-88-3)
All quantities in pounds
SARA 313
de minimis
1
1
CERCLA
Rq
5000
5000
1000
CAA 112(r)
TQ
RCRA
code
U002
U220
TSCA Inventory Status: All components of this material are listed on the US Toxic Substances Control Act (TSCA)
inventory.
International Regulations:
Canadian Inventory Status: All components of this material are listed on the Canadian Domestic Substances List
(DSL).
EINECS: The chemical in this product are listed.
WHIMS: B2 & D2B\
16.
DISCLAIMER
The information contained herein is presented in good faith and believed to be accurate as of the effective
date shown above. This information is furnished without warranty of any kind. Employers should use this
information only as a supplement to other information gathered by them and must make independent
determination of suitability and completeness of information from all sources to assure proper use of these
materials and the safety and health of employees. Any use of this data and Information must be determined
by the user to be in accordance with applicable federal, provincial, and local laws and regulations.
Prepared By
Product Stewardship
23 British American Blvd.
Latham, NY 12110
1-800-572-6501
Revision Date
Revision Note
26-Jan-2015
No information available
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