Solutions for Progress...Elements for Life... BSI Cosmetic Ingredients Hair Care Kits CASCC Suppliers Day 2015 Brenntag Specialties, Inc. (BSI) makes no warranty, express or implied, including any warranty of merchantability, non-infringement or fitness for a particular purpose, concerning the composition or use of these formulas. User assumes all risks and responsibility resulting from such use and the handling, use, storage, transportation, sale or resale of any product made therefrom. BSI assumes no obligation or liability for any technical advice given by it relating to the formulas or the results obtained therefrom, all such advice being given and accepted at user’s sole risk. User waives all claims against BSI for damages, including consequential and punitive damages, even if BSI has been advised or has notice of the possibility of such damages, and user agrees to defend and indemnify BSI against any loss, damages, liability, cost and expense, relating to the use of the formulas and the handling, use, storage, transportation, sale or resale of any product made therefrom. For additional information, please contact Technical Services at 1-800-732-0562. • Brenntag Specialties, Inc. • 1000 Coolidge St. • South Plainfield, NJ 07080 • Issued: 5/15 BSI Cosmetic Ingredients Sulfate Free Shampoo - 03-068 Ingredients: Phase A Deionized Water ………………………………………………………………..……..… Acrylamidopropyl Trimonium Chloride/Acrylamide Copolymer (N-Hance™ SP-100) …………………………………………………...……... Phase B Cocamidopropyl Hydroxysultaine (Mirataine® CBS) …………………………..…….. Water (and) Sodium Lauroyl Methyl Isethionate (and) Cocamidopropyl Betaine (and) Sodium Cocoyl Isethionate (and) Sodium Methyl Oleoyl Taurate (and) Trisodium Ethylenediamine Disuccinate (Iselux® SFS) …………...… Phase C Polyquaternium-7 (Conditioneze™ 7MP) …..…………………………..………...…… Amodimethicone/Morpholinomethyl Silsesquioxane (and) Trideceth-5 (and) Glycerin (BELSIL® ADM 8301 E)……………..…... Hydrolyzed Wheat Protein (Wheat PL) ………………………………………………… Sodium Chloride (20% Salt Solution) ………………………………………………..… Methylchloroisothiazolinone (and) Methylisothiazolinone (LiquaGard™ S-1) …….. Citric Acid (20% Citric Acid Solution) ………………………………………………...… % W/W Supplier q.s. 0.40 BSI - Ashland 6.00 Solvay 27.50 Innospec 0.40 BSI - Ashland 4.00 1.00 0.20 0.07 q.s. BSI - Wacker BSI BSI - Ashland Procedure: • Phase A - Add water to main container and begin moderate to high propeller agitation. Sprinkle in N-Hance™ SP-100 and mix well until fully hydrated. • Phase B - Add Phase B surfactants individually, mixing well after each addition. • Phase C - Add Phase C ingredients individually, mixing well after each addition. Lower pH to 5.5 - 6.0 with citric acid solution. About the Ingredients: N-Hance™ SP-100: New, substantive conditioning polymer designed for rinse-off surfactant systems to reduce tangling and to improve wet and dry comb properties of hair after shampooing. N-Hance™ SP-100 is especially useful for delivering a highly conditioned feel to wet and dry hair. This polymer also helps deposit silicones and natural oils to the hair resulting in a softer, silkier feel. BELSIL® ADM 8301 E: An excellent conditioning agent in hair care applications. It provides a soft, silky touch and strongly reduces dry and wet combing forces. BELSIL® ADM 8301 E also helps reduce color fade of colored hair. Conditioneze™ 7MP: Cationic aqueous solution of diallyl dimethyl ammonium chloride (DADMAC) and acrylamide copolymer. Conditioneze™ 7MP imparts slip and lubricity and provides lather stability to shampoos. This polymer is also an effective conditioning agent and is substantive to skin and hair. Brenntag Specialties, Inc. (BSI) makes no warranty, express or implied, including any warranty of merchantability, non-infringement or fitness for a particular purpose, concerning the composition or use of these formulas. User assumes all risks and responsibility resulting from such use and the handling, use, storage, transportation, sale or resale of any product made therefrom. BSI assumes no obligation or liability for any technical advice given by it relating to the formulas or the results obtained therefrom, all such advice being given and accepted at user’s sole risk. User waives all claims against BSI for damages, including consequential and punitive damages, even if BSI has been advised or has notice of the possibility of such damages, and user agrees to defend and indemnify BSI against any loss, damages, liability, cost and expense, relating to the use of the formulas and the handling, use, storage, transportation, sale or resale of any product made therefrom. For additional information, please contact Technical Services at 1-800-732-0562. • Brenntag Specialties, Inc. • 1000 Coolidge St. • South Plainfield, NJ 07080 • Issued: 5/15 03-068 BSI Cosmetic Ingredients Revitalizing Hair Mask - 03-062 Ingredients: % W/W Phase A Deionized Water ……………………………………………………………………….…. 57.25 Hydroxyethylcellulose (Natrosol™ 250 HHR CS)……………………………………... 1.00 Polyacrylamidopropyltrimonium Chloride (N-DurHance™ A-1000)…….………...… 3.50 Glycerin ……………………………………………………………………………….…… 5.00 Supplier BSI - Ashland BSI - Ashland Phase B Cetearyl Alcohol (and) Behentrimonium Chloride (and) Bis-PEG-18 Methyl Ether Dimethyl Silane (Kostol STMC)……………………………….…………......… Argania Spinosa Kernal Oil (Virgin Argan Oil TX: 8121) ..…………………………… Persea Americana (Avocado) Oil (Virgin Avocado Oil TX: 8221) .…..………....…… Stearyl Alcohol (and) Cetrimonium Bromide (Miracare CT-100) ……………….…… 5.00 5.00 5.00 3.50 BSI - Koster Keunen BSI - Textron BSI - Textron Solvay Phase C Amodimethicone/Morpholinomethyl Silsesquioxane (and) Trideceth-5 (and) Glycerin (BELSIL® ADM 8301E)…..…...……...…. Dimethicone (and) Dimethiconol (BELSIL® GB 1020) ……………………………..… Hydrolyzed Keratin (Keramois L)……………….……………………….…………...… Hydroxypropyltrimonium Hydrolyzed Wheat Protein (Wheat Q) …………………… Phenoxyethanol (and) Caprylyl Glycol (and) Sorbic Acid (Optiphen Plus)…........... Fragrance …………………………………………………………………….…………… 8.00 3.00 1.00 1.00 1.25 0.50 BSI - Wacker BSI - Wacker-Belsil BSI BSI BSI - Ashland Procedure: • Phase A - Disperse the Natrosol 250 HHR CS in cold water first and heat up to 75 - 80°C while adding the rest of the ingredients. • Phase B - In a separate container premix Phase B and heat to 75 - 80°C. When both main tank and Phase B are 75 - 80°C, add Phase B to the main tank and mix well until uniform. Begin cooling batch to room temperature. • Phase C - Add Phase C ingredients to the main container, mixing well after each addition. Homogenize if necessary to obtain a smooth consistency. Brenntag Specialties, Inc. (BSI) makes no warranty, express or implied, including any warranty of merchantability, non-infringement or fitness for a particular purpose, concerning the composition or use of these formulas. User assumes all risks and responsibility resulting from such use and the handling, use, storage, transportation, sale or resale of any product made therefrom. BSI assumes no obligation or liability for any technical advice given by it relating to the formulas or the results obtained therefrom, all such advice being given and accepted at user’s sole risk. User waives all claims against BSI for damages, including consequential and punitive damages, even if BSI has been advised or has notice of the possibility of such damages, and user agrees to defend and indemnify BSI against any loss, damages, liability, cost and expense, relating to the use of the formulas and the handling, use, storage, transportation, sale or resale of any product made therefrom. For additional information, please contact Technical Services at 1-800-732-0562. • Brenntag Specialties, Inc. • 1000 Coolidge St. • South Plainfield, NJ 07080 • Issued: 5/15 03-062 BSI Cosmetic Ingredients Revitalizing Hair Mask - 03-062 Continued About the Ingredients: Kostol STMC: High performing cosmetic emulsifier and sulfate-free conditioner. Kostol STMC has been designed to produce emulsions with a more radiant white appearance, a more luxurious feeling and texture. It produces an improvement in wet and dry combability, softer feel, ease of style, and frizz control, especially when combined with another cationic conditioning polymer. N-DurHance A-1000: An aqueous conditioning polymer of a highly charged cationic homopolymer of trimethylammonium chloride. It has been developed especially for use as a substantive and durable conditioning polymer for hair. N-DurHance A-1000 works to restore damaged hair surfaces to a hydrophobic state and provides a more semipermanent conditioning effect with significantly improved combability. Keramois L: A 25% active, 1000 average molecular weight Keratin Protein that protects and restores hair from damage. Wheat Q: A wheat polypeptide obtained by hydrolysis of edible wheat. Due to the high content of glutamic acid (39%), it imparts a good moisture effect. WHEAT Q shows good substantivity to hair and helps restoration of damaged hair. Virgin Argan Oil: From the Argan nut native to Morocco, Argan Oil is rich in natural antioxidants such as Vitamin E and essential fatty acids. Its primary benefit seems to come from its ability to naturally hydrate and to help lock in moisture improving shine and luster and to stop frizziness, fly-away and hard to control, unmanageable hair. It has been shown to penetrate the hair shaft to increase elasticity and revive hair damaged by heat, wind, over styling and processing. BELSIL® GB 1020: Dimethiconol gum blend that has a high reduction of wet and dry combining force, improves feel and humidity resistance. BELSIL® GB 1020 also coats and smoothes the hair cuticle, giving it a repairing effect. Virgin Avocado Oil: A highly therapeutic oil rich in vitamins A, B1, B2, D and E, lecithin, pantothenic acid, and essential fatty acids. It applies easily, offers deep penetration and significant moisture retention together with high nourishing properties. BELSIL® ADM 8301 E: An excellent conditioning agent in hair care applications. It provides a soft, silky touch and strongly reduces dry and wet combing forces. BELSIL® ADM 8301 E reduces color fade of dyed hair and protects hair during heat treatments. Brenntag Specialties, Inc. (BSI) makes no warranty, express or implied, including any warranty of merchantability, non-infringement or fitness for a particular purpose, concerning the composition or use of these formulas. User assumes all risks and responsibility resulting from such use and the handling, use, storage, transportation, sale or resale of any product made therefrom. BSI assumes no obligation or liability for any technical advice given by it relating to the formulas or the results obtained therefrom, all such advice being given and accepted at user’s sole risk. User waives all claims against BSI for damages, including consequential and punitive damages, even if BSI has been advised or has notice of the possibility of such damages, and user agrees to defend and indemnify BSI against any loss, damages, liability, cost and expense, relating to the use of the formulas and the handling, use, storage, transportation, sale or resale of any product made therefrom. For additional information, please contact Technical Services at 1-800-732-0562. • Brenntag Specialties, Inc. • 1000 Coolidge St. • South Plainfield, NJ 07080 • Issued: 5/15 03-062 BSI Cosmetic Ingredients Conditioning Shine & Style Spray - 03-074 Ingredients: % W/W Supplier Phase A SD Alcohol 40B 200 proof………………………………………….……………….…… Aminomethyl Propanol (AMP 95)……………………………….………………....…… 3.50 0.12 Dow Phase B Crotonic Acid/Vinyl C8-12 Isoalkyl Esters/VA/ Bis-Vinyldimethicone Crosspolymer (BELSIL® P1101)..………………………..……………….…… 5.00 BSI - Wacker Phase C Deionized Water…………………………………………………………………….…….. 75.43 Amodimethicone/Morpholinomethyl Silsesquioxane (and) Trideceth-5 (and) Glycerin (BELSIL® ADM 8301E)………………...... 5.00 PEG/PPG-20/20 Phenylisopropyl Caprylyl Dimethicone (BELSIL® PF 200) …..…………………………………………………..….….. 5.00 Pentylene Glycol (Hydrolite® 5 616751)………………………………………...……. 3.00 Hydrolyzed Keratin (Keramois L)……………….……………………………….…….... 1.00 Hydroxypropyltrimonium Hydrolyzed Silk (Silk Q)…………………………….….…… 1.00 Propylene Glycol (and) Diazolidinyl Urea (and) Iodopropynyl Butylcarbamate (Liquid Germall Plus) ………….….…. 0.50 Phase D PEG-40 Hydrogenated Castor Oil (Jeechem CA-40)............................................... Fragrance…………………………………………………………………………….….… 0.40 0.05 BSI - Wacker BSI - Wacker Symrise BSI BSI BSI - Ashland Jeen Procedure: • Phase A - Add alcohol to main container and begin moderate propeller agitation. Add AMP to adjust pH as advised in P1101 calculator. • Phase B - Add Phase B BELSIL® P1101, mix well until uniform. • Phase C - Add Phase C Ingredients individually to the main container, mixing well after each addition. • Phase D - Premix fragrance and Jeechem CA-40. Add premix to the main container, mix well. Brenntag Specialties, Inc. (BSI) makes no warranty, express or implied, including any warranty of merchantability, non-infringement or fitness for a particular purpose, concerning the composition or use of these formulas. User assumes all risks and responsibility resulting from such use and the handling, use, storage, transportation, sale or resale of any product made therefrom. BSI assumes no obligation or liability for any technical advice given by it relating to the formulas or the results obtained therefrom, all such advice being given and accepted at user’s sole risk. User waives all claims against BSI for damages, including consequential and punitive damages, even if BSI has been advised or has notice of the possibility of such damages, and user agrees to defend and indemnify BSI against any loss, damages, liability, cost and expense, relating to the use of the formulas and the handling, use, storage, transportation, sale or resale of any product made therefrom. For additional information, please contact Technical Services at 1-800-732-0562. • Brenntag Specialties, Inc. • 1000 Coolidge St. • South Plainfield, NJ 07080 • Issued: 5/15 03-074 BSI Cosmetic Ingredients Conditioning Shine & Style Spray - 03-074 Continued About the Ingredients: BELSIL® PF 200: New amphiphilic phenyl silicone. BELSIL ® PF 200 offers a new approach to gloss boosting technologies in color cosmetics and hair care formulations featuring a high refractive index, increased water compatibility and an improvement of dry combing and suppleness. BELSIL® P 1101: This easy to use, unique silicone - organic polymer hybrid offers both hold and softness in a hair styling resin. Benefits include curl retention and humidity resistance. BELSIL ® P1101 has increased thermal protection when combined with BELSIL® ADM 8301 E. It can be used in both pump and aerosol formulations. BELSIL® ADM 8301 E: An excellent conditioning agent in hair care applications. It provides a soft, silky touch and strongly reduces dry and wet combing forces. BELSIL® ADM 8301 E reduces color fade of colored hair and protects hair during heat treatments. Keramois L: A 25% active, 1000 average molecular weight Keratin Protein that protects and restores hair from damage. Silk Q: A trimethyl quaternary ammonium derivative of Silk Protein. Activated by cationization, it gives excellent adsorption, glossiness and a fine, soft touch to hair. Brenntag Specialties, Inc. (BSI) makes no warranty, express or implied, including any warranty of merchantability, non-infringement or fitness for a particular purpose, concerning the composition or use of these formulas. User assumes all risks and responsibility resulting from such use and the handling, use, storage, transportation, sale or resale of any product made therefrom. BSI assumes no obligation or liability for any technical advice given by it relating to the formulas or the results obtained therefrom, all such advice being given and accepted at user’s sole risk. User waives all claims against BSI for damages, including consequential and punitive damages, even if BSI has been advised or has notice of the possibility of such damages, and user agrees to defend and indemnify BSI against any loss, damages, liability, cost and expense, relating to the use of the formulas and the handling, use, storage, transportation, sale or resale of any product made therefrom. For additional information, please contact Technical Services at 1-800-732-0562. • Brenntag Specialties, Inc. • 1000 Coolidge St. • South Plainfield, NJ 07080 • Issued: 5/15 03-074 BSI Cosmetic Ingredients Healthy Hair & Scalp Treatment Serum - 03-064 Ingredients: % W/W Phase A Deionized Water ………………………………………………….……………………..… 90.50 Glycerin (and) Glyceryl Acrylate/ Acrylic Acid Colpolymer (Lubrajel® DV Free)……. 4.00 Glycerin (and) Glyceryl Polyacrylate (Lubrajel® II XD)……………………………...… 2.00 Amodimethicone/Morpholinomethyl Silsesquioxane Copolymer (and) Trideceth-10 (BELSIL™ ADM 8301 E)…………………………...…..… 2.00 Water (and) Glycerin (and) Hydrolyzed Yeast Protein (Dynagen™)……………….… 1.00 Propylene Glycol (and) Diazolidinyl Urea (and) Iodopropynyl Butylcarbamate (Liquid Germall Plus) ………………………………………………………...... 0.50 Supplier BSI - Ashland BSI - Ashland BSI - Wacker BSI - Ashland BSI - Ashland Procedure: • Phase A - Add Phase A Deionized Water to main container and begin moderate propeller agitation. Add remaining Phase A ingredients individually, mixing well after each addition. About the Ingredients: Dynagen™: Patent-pending yeast extract designed to nurture essential markers to help minimize hair fall and to help strengthen the hair follicle while nourishing the hair root. In vitro studies show that Dynagen™ boosts the expression of key protein markers and collagen I and IV. In vivo clinical study results demonstrate consumer-perceivable anti-hair fall and hair that feels stronger, thicker and healthier. Lubrajel® DV Free: An easy-to-formulate with, water-soluble, Glycol and Paraben Free hydrogel used primarily as a rheology modifier. Lubrajel DV significantly increases the viscosity of almost any product. Lubrajel® II XD: A high efficiency clathrate gel that delivers thickening, moisturization, emolliency and suspension to clear gel products and emulsions including oil-in water, water-in-oil, multiple emulsions and macro emulsions. Lubrajel II XD is ideal for applications requiring superior moisturization. BELSIL ADM 8301 E: An excellent conditioning agent in hair care applications. It provides a soft, silky touch and strongly reduces dry and wet combing forces. BELSIL® ADM 8301 E reduces color fade of colored hair and protects hair during heat treatments. Brenntag Specialties, Inc. (BSI) makes no warranty, express or implied, including any warranty of merchantability, non-infringement or fitness for a particular purpose, concerning the composition or use of these formulas. User assumes all risks and responsibility resulting from such use and the handling, use, storage, transportation, sale or resale of any product made therefrom. BSI assumes no obligation or liability for any technical advice given by it relating to the formulas or the results obtained therefrom, all such advice being given and accepted at user’s sole risk. User waives all claims against BSI for damages, including consequential and punitive damages, even if BSI has been advised or has notice of the possibility of such damages, and user agrees to defend and indemnify BSI against any loss, damages, liability, cost and expense, relating to the use of the formulas and the handling, use, storage, transportation, sale or resale of any product made therefrom. For additional information, please contact Technical Services at 1-800-732-0562. • Brenntag Specialties, Inc. • 1000 Coolidge St. • South Plainfield, NJ 07080 • Issued: 8/15 03-064 BSI Cosmetic Ingredients Sprayable Hair Yogurt - 03-044 Ingredients: % W/W Phase A Deionized Water ………………………………………………………………..……...….. Carbomer (Ashland Carbomer 980) ………….……….………………………….….….. Acrylates Copolymer (and) Water (AquaStyle™ SH-100) ……...…………….………. q.s. 0.05 1.65 Supplier BSI - Ashland BSI - Ashland Phase B Deionized Water …………………………………………………………………….…..… 1.00 Triethanolamine …………………………………………………………….……… q.s. to pH 7 Phase C Amodimethicone/Morpholinomethyl silsesquioxane copolymer (and) Trideceth-10 (BELSIL® ADM 6300 E) …………………………..…...…. Beeswax (and) Sesame Oil (and) Lecithin (and) Methyl Paraben (and) Water (Bee’s Milk #138) ………………….……………………………………….……. Glycerin (and) Glyceryl Acrylate/Acrylic Acid Copolymer (and) Propylene Glycol (and) PVM/MA Copolymer (Lubrajel® Oil) …..…………………………..…..… Synthetic Fluorphlogopite (and) Titanium Dioxide (Sumicos Polar Mist SM132) …... Propylene Glycol (and) Diazolidinyl Urea (and) Iodopropynyl Butylcarbamate (Liquid Germall® Plus)…………………………………..……………….……… 3.00 BSI - Wacker 5.00 BSI - Koster Keunen 0.25 0.20 BSI - Ashland BSI - Sudarshan 0.50 BSI - Ashland Procedure: • Phase A - Add water to main container and begin moderate to high propeller agitation. Sprinkle in Carbomer and mix well until fully hydrated. Add AquaStyle SH-100 and mix well. • Phase B - Premix water and TEA and neutralize Phase A to pH ~7. • Phase C - Add Phase C ingredients individually, mixing well after each addition. Adjust pH to 6.5-7 as necessary. Pour into spray containers. About the Ingredients: AquaStyle™ SH-100: An advanced, acylate-based polymer that provides stiff, long-lasting hold with no flaking and the ability to create crystal clear formulations. AquaStyle™ SH-100 also offers excellent high humidity resistance and a tack - free feel. BELSIL® ADM 6300 E: An excellent conditioning agent in hair care applications. It provides a soft, silky touch and strongly reduces dry and wet combing forces. BELSIL® ADM 6300 E reduces color fade of colored hair and protects hair during heat treatments. Sumicos Polar Mist SM132: Pearlescent pigment based on synthetic mica that provides a bright white luster and shimmer to formulations. Bee’s Milk: An innovative, highly stable dispersion of Beeswax wax in water. Bee’s Milk allows a formulator to utilize the desirable properties of Beeswax without emulsifying or having to apply heat to the formulation. Brenntag Specialties, Inc. (BSI) makes no warranty, express or implied, including any warranty of merchantability, non-infringement or fitness for a particular purpose, concerning the composition or use of these formulas. User assumes all risks and responsibility resulting from such use and the handling, use, storage, transportation, sale or resale of any product made therefrom. BSI assumes no obligation or liability for any technical advice given by it relating to the formulas or the results obtained therefrom, all such advice being given and accepted at user’s sole risk. User waives all claims against BSI for damages, including consequential and punitive damages, even if BSI has been advised or has notice of the possibility of such damages, and user agrees to defend and indemnify BSI against any loss, damages, liability, cost and expense, relating to the use of the formulas and the handling, use, storage, transportation, sale or resale of any product made therefrom. For additional information, please contact Technical Services at 1-800-732-0562. • Brenntag Specialties, Inc. • 1000 Coolidge St. • South Plainfield, NJ 07080 • Issued: 5/15 03-044