THE FATE OF ICE CAVES IN NORTH-WESTERN CANADA AS CLIMATE WARMS: WHAT WILL WE LOSE? Charles J Yonge PhD Alberta Speleological Society Yonge Cave & Karst Consulting Inc., 1009 Larch Place, Canmore, T1W 1S7 AB, Canada chas-karst@telus.net Abstract A number of ice cave sites in the northwestern Canada region are exhibiting a loss of perennial ice apparently resulting from the current climate warming trend. Three of the six sites in this study show such ice loss; with one further cave unproven as it is a new site. In addition, the fate of ice from some of the caves in earlier studies remains unknown as they have not been revisited - generally because of their remote locations. In an effort to understand the systematics of perennial ice in caves, three types of ice cave have been suggested: cold trap, cold zone and permafrost (Yonge and MacDonald, 2014). Why should we be worried about the condition of these ice caves? Ice caves in their own right are very beautiful as shown in a number of the accompanying photographs. But beyond the esthetics, cave ice may also be an important proxy climate record, monitoring the very climate that appears to be changing quite rapidly. Study of cave ice is very important if we are to fully understand the implications of what the ice is telling us. Thus, in this study we continued the attempt to unravel climate using the stable isotopes of oxygen and hydrogen (δ18O and δ2H), now comparing this data to that collected in earlier work (Yonge & MacDonald, 1999, Yonge & MacDonald, 2006). Where possible, we have tried to understand the chronology of ice, collecting trapped organic material for 14C dating. Plate1 The Booming Ice Chasm – a large newly discovered cold trap cave in the Crowsnest Pass, Alberta, Canada RCGS – Ice Caves Introduction A number of studies of perennial ice in caves have been undertaken (see e.g. Ford and Williams, 2007, Yonge 2004); but there are relatively few studies employing stable isotopes and these are confined to Europe (Kern et al., 2011; Persoiu1 and A. Pazdur, 2011; Holmlund et al., 2005; Racovita & Onac, 2000; Lauritzen 1996) and North America (Lacelle et al., 2009; Yonge & MacDonald, 1999, Yonge & MacDonald, 2006; Martin & Quinn, 1991; Marshall & Brown, 1974). With the current interest in climate change, a wealth of studies has accumulated on polar (e.g. Jouzel & Masson-Delmotte, 2010; Johnsen et al., 2001) and cordilleran (e.g. Thompson & Davis, 2005) ice cores. While ice cores deal with the direct precipitation of snow and the subsequent modification of the resulting layers by various physical processes, the mechanisms of ice formation in caves, being confined, can be quite different and may require an alternative interpretation (e.g. Yonge & MacDonald, 2014; Lacelle et al., 2009 and Yonge & MacDonald, 1999). Here we apply the model of Yonge & MacDonald (2014) identifying three possible ice cave types (and combinations of these where cave systems are complex). We have examined caves which are dominated by a cold zone close to the entrance (Cold Zone type); those in Permafrost (Permafrost type) and pit caves where cold air and snow is trapped (Cold Trap type). While we have examined fourteen caves from the region in previous studies, in this study five new sites and one repeat site have been added. In the latter case, it was possible to compare records from 1989-1992 to our collection in 2014. All sites exemplify classic perennial ice features: massive ice, hoar frost, ice stalagmites & stalactites and extrusion ice (see e.g. Yonge, 2004). Stable isotopes measured on the ice (δ18O and δ2H) assist in understanding the origin of the freezing moisture, whether from direct snow (cold trap), moist summer air (permafrost) or humid air within the cave (cold zone). Delineating the complex systematics of cave ice formation is vitally important if it is to be used (or rejected) as a proxy climate record. Methodology Field Sites While stable isotope data of perennial ice was acquired from 6 cave sites, which from south to north comprise: Bisaro Anima, AB (49o 36’ N, 115o 09’ W; elevation 2400m), Booming Ice Chasm, AB (49o 37’ N, 114o 38’ W; elevation 2200m), Plateau Mountain Ice Cave, AB (50o 20’ N, 114o 31’ W; elevation 2250m), Canyon Creek Ice Cave, AB (50o 54’ N, 114o 47’ W; elevation 1775m), Ice Trap, AB (53o 03’ N, 114o 39’ W; elevation 2390m) and Grotte Valerie, Nahanni, NWT (61o 19’ N, 124o 10’ W; elevation 700m). The cave types investigated appear to be: • Bisaro Anima: Cold Trap • Booming Ice Chasm: Cold Trap • Plateau Mtn. Ice Cave: Permafrost • Canyon Creek Ice Cave: Cold Zone • Ice Trap: Permafrost/cold zone • Grotte Valerie, NWT: Permafrost/cold zone All are from the east side of the Great Divide (see Results and Discussion below for details). Sample Collection We drilled out massive ice (floor and stratified) using an ice climbing screw. Where the ice was stratified, we sampled visually obvious ice layers sequentially, then transferring the samples to 30ml glass bottles with the ice screw carefully dried after each extraction. We collected all other ice by crumbling the ice into the bottles with seepage water collected by direct dripping into the sample vials. RCGS – Ice Caves Analysis We had the samples analyzed at the Calgary University Stable Isotope Laboratory: δ18O and δ2H are expressed in per mille (‰) against the V-SMOW standard as: δ = (Rsample/Rstandard - 1) 103 (‰) (1) Rsample and Rstandard are the ratios of 18O/16O and 2H/1H in the sample and standard respectively. Precision is +/-0.1%o on δ18O and 0.7%o on δ2H %o. Because concentrations of the heavy isotopes (18O and 2H) are small compared to the common 16O and 1H, use of the δ-value allows terrestrial samples to be compared to (homogeneous) ocean water yielding sensible numbers. The Vienna Standard Mean Ocean Water (V-SMOW) has a δ-value of 0 ‰ and all terrestrial sample tend to have negative values (i.e. during the distillation process in the hydrological cycle, the lighter isotopes with a lower vapour pressure are picked up in clouds preferentially). Results Global precipitation world-wide, while negative compared to ocean water, falls on or close to the Global Meteoric Water Line – GMWL (see blue line on figure 1 – Craig, 1961; Dansgaard, 1964), which yields: δ2H = 8δ18O +10 (‰) (2) Some minor modifications of this line have been introduced later (Rozanski et al., 1993) but do not affect our arguments presented here. Positions on the line generally relate to site temperature, where the lowest temperature is associated with the lowest δ-values (figures 1 and 2). Figure 1: Hydrogen & oxygen stable Isotope data for the 6 caves in this study compared to the GMWL. RCGS – Ice Caves Isotopic data for 19 caves - comprising those of Yonge and MacDonald (2006) and the 6 ice caves in this study - is presented in Figure 2. Data from ice caves on each side of the Great American Divide fall on two distinct Regional Meteoric Water Lines (RMWL - figure 2 and Table 1): δ2H = 8.0 δ18O + 4.1 (‰) East (3) δ2H = 8.0 δ18O + 12.8 (‰) West (4) Figure 2 The δ18O - δ2H of ice from 19 North American ice caves from East (<250km from coast) and West (>750km from coast) of the Divide (data from Yonge and MacDonald, 2006 and this study). And in addition, despite the universality of the GMWL and the RMWL here in Western Canda, it has long been recognized that Local Meteoric Water Lines (LMWL) exist at each site. With lower slopes, these lines cross the GMWL with their means, representing mean annual temperature, plotting close to the GMWL. LMWL’s are presented in table 1 and figure 3 for the caves in this study; all are east of the Great Divide and all exhibit slopes less than 8, especially Plateau Mountain Ice Cave (at 4.2) discussed in a later section. Figure 4 presents the average deuterium excess d-excess (‰) for each of the 19 caves of Figure 1. This is acquired by forcing the LMWLs to a slope of 8 yielding the d-excess at intercept. The figure is another, effective way of expressing differences in the two regions where the d-excess unambiguously splits into two fields, each representing the east and west of the Great Divide. The dexcess is also a way of expressing δ18O in terms of δ2H. Ice Cave LMWL Regression δ2H = N/A R2 = 0.04 2 18 δ H = 6.7δ O -19.0 R2 = 0.97 2 18 δ H = 6.9δ O -14.4 R2 = 0.97 2 18 δ H = 4.2δ O -62.7 R2 = 0.98 2 18 δ H = 6.9δ O –11.0 R2 = 0.94 2 18 δ H = 6.9δ O –11.0 R2 = 0.99 ___________________________________________ _ Regional RMWL (slopes forced to 8) East of Divide δ2H = 8.0δ18O +4.1 R2 = 0.96 2 18 West of Divide δ H = 8.0δ O +12.8 R2 = 0.90 Combined data of Yonge and MacDonald (2006) & this study. Grotte Valerie Ice Trap Canyon Creek Plateau Mountain Boom. Ice Chasm Bisaro SGIP Table 1 Local & Regional Meteoric Water Lines RCGS – Ice Caves Figure 3 Regional Meteoric Water Lines (RMWL) for the caves in this study d-excess = 8.0 δ18O + δ2H Figure 4 The d-excess versus distance from the Pacific coast for 19 North American ice caves (Circled are fields for caves <250km and >750km). Discussion Meteoric Water Lines and Ice Caves Figures 2 and 4 show delineated fields relating to two RMWLs clearly defined by the d-deficiency. The ice caves east of the Great Divide on average yield a lower d-excess (4.1%o), which appears to be a combination of a drier, more evaporative climate there and a greater tendency to precipitate snow and hoar frost in the caves. An evaporative climate tends to yield precipitation which falls along a model slope of 4 below the GMWL, but also the direct sublimation of cloud vapour to snow and cave hoar yields values below the GMWL (Plateau Mountain Ice Cave – figure 3 – being a good example). The caves close to the coast are in high humidity regimes where rain is more dominant and the resulting ice (mainly of snow in cold traps) tends to plot close to the GMWL (intercept of +12.8%o). The LMWLs in this study (table 1) yield slopes around 8 or less, which supports the argument above of a drier, colder climate on the east side of the Divide leading to lower humidity and a greater proportion of solid precipitation. Note that in figure 2 the easterly caves tend to plot with more negative δ-values on the Water Lines indicative of the cooler climate on that side of the Divide. We now examine the ice caves in more detail, starting with the cold trap caves (Bisaro and Booming Ice Chasm), followed by the permafrost caves (Plateau Mountain, Grotte Valerie and Ice Trap, ending with the cold zone cave (Canyon Creek). Cold Trap Caves: Bisaro (Superman’s Glittering Ice Palace) and Booming Ice Chasm Cold traps occur where there is little through movement of air within a pit-like cave. Cold winter air sinks into the cave, generally through a bottleneck, and displaces warmer air within. Snow falling through or blowing into the entrance aids the cold trap conditions providing an environment for perennial ice. During the summer, buoyant warm air cannot get into the cave other than by eddy currents and the cave maintains a temperature lower than the mean annual temperature. Thus, the formation of ice in cold trap caves appears likely to resemble glacier ice by direct accumulation of snow; in some cases where ice flow has been demonstrated within the cave it is referred to as a Glacier Cave (Holmlund et al., 2005; MacDonald, 1994; Yonge and MacDonald, 2014). RCGS – Ice Caves Figure 5 Figure 6 δ2H Variation within stratified ice Bisaro SGIP Bisaro’s Superman’s Glittering Ice Palace (SGIP) received only a preliminary investigation in the summer of 2014 (figures 5 and 6). The Bisaro area is in a remote location, currently accessible by helicopter. SGIP is however a Winter air exchange classic cold trap cave with winter air and occasional blowing snow flowing down and being trapped in the lower chamber, which forms a stratified ice capped by residual snow. Little can be said about the cave ice data except that it conforms to that which is expected for a cave to the east of the Great Divide (figure 3). The stratified ice profile shows a general warming trend ending with the residual snow on top of the mound, δ2H ranging from -142 to -113 ‰. However, we do not know the age of the ice although from experience of such small ice caves, it is likely to be young – measured in decades. Figure 7 The Bisaro Plateau near Fernie BC showing the location of Bisaro SGIP RCGS – Ice Caves Plate 2 Booming Ice Chasm – a view in a side passage located on the map below Figure 8 Booming Ice Chasm The Booming Ice Chasm is essentially a massive shaft 140m deep (Plates 1, 2 and Figure 8). Ice Sampling: Stratified Icefall Hoar Frost Figure 9 shows the results for a small stratified ice mass (figure 8 shows the sample location). While there is a trend toward increasingly depleted 2H towards the present day (lower δ-values), they are nonetheless well within those expected for the area (Figure 1), having similar Figure 9 Booming Ice Chasm Hoar Frost RCGS – Ice Caves Ice Falls characteristics to the other cold trap cave, Bisaro SGIP (Figure 3). Included on Figure 9 are the average values for the massive ice falls (Plates 1, 2 and map) and hoar frost taken from the walls at the entrance and bottom of the Main Shaft. One interpretation for the stratified ice would be a varying mixture of incoming, refrozen snow melt and the hoar frost. The latter is likely moist summer air enriched in the heavy isotopes which freezes on the walls and eventually falling to the floor (see section on Permafrost ice cave types). If this mixing is real, then a climatic interpretation could be that a greater proportion of hoar ice in the ice mass implies a warmer climatic regime. The stratigraphy shows a cooling toward the present day but the rate is not known with undated ice. Permafrost Caves: Plateau Mountain Ice Cave, Grotte Valerie and the Ice Trap Permafrost caves have been discussed by Yonge and MacDonald (1999), where an isotopic model was developed to explain the surprisingly high δ−values and low d-excess of cave ice when compared to snow or average precipitation. The premise of the model is that warm, moist air enters the cave in summer where it is forced to freeze on the permafrost walls at ~0oC. This vapour-solid sublimation process leads to a large fractionation of the isotopes, with higher δ−values in the ice (hoar frost). In addition the warm summer vapour source will have relatively high δ−values associated with the higher temperatures outside. Thus the combined outcome is a high δ−value in the hoar relative to average precipitation. Figure 10 - from Yonge and MacDonald, 2013 - shows the results from Ice Chest, which is only a few hundred metres 2 west of the Booming Ice Chasm, but is nevertheless within Figure 10 δ H versus distance from the the mountain permafrost zone. The hoar ice here has entrance of Ice Chest, Alberta (Permafrost similar δ−values to the massive ice in the cave (derived Type). After Yonge & MacDonald, 1999. from falling hoar), but the latter declines somewhat as the entrance is approached, increasingly affected by an added lower δ−value of seepage water derived from snowmelt. Plate3 Sheep residing in patterned ground on Plateau Mountain Plate 4 Looking out of the entrance of Plateau Mountain Ice Cave RCGS – Ice Caves Plateau Mountain Ice Cave is in the unique ecological reserve of Plateau Mountain, an example of relict alpine permafrost from the Late Wisconsin glaciation. The flat mountain top was not glaciated during the Late Pleistocene and its summit permafrost is not yet in equilibrium with current climate. The surface exhibits patterned ground and thermokarst resulting from melting of ice wedges formed beneath stony borders during a colder climate (plate 3). The slopes of Plateau Mountain show very well developed block slopes (view in plate 4), in contrast to the rocky mountain sides seen elsewhere in the adjacent Rockies. At the northern end of the mountain, the > 400m Plateau Mountain Ice Cave penetrates into the surface of the relict permafrost with temperature decreasing with depth. Plateau Mountain Ice Cave was mapped during this study as no good survey had previously existed (Figure 11). While the map was almost completed, a couple of high-level fissure leads remain to be explored just before entering the large main chamber. Figure Plate 5 Hoar ice in the NW gallery of Plateau Mountain Ice Cave with detail below. The few data of samples collected from the two western galleries in Plateau Mountain Ice Cave (PMIC) show an interesting local meteoric water line (LMWL) with slope much lower than all of the caves studied here (Table 1 & Figure 3) and those previously encountered (Yonge and MacDonald, 2013): δ2H = 4.2δ18O -62.7 R2 = 0.98 (5) The most depleted sample – approximately lying on the GMWL - came from a pool in the ice “streamway” in the SW gallery. It appears to represent an end member and may be derived from drip water, i.e. an average of precipitation at the site. All of the other samples are hoar frost (Plate 5) and they trend away from the GMWL along an apparent mixing line of slope 4.2 with increasing d-excess. Figure 13 shows what happens if we freeze vapour derived from a water body of GMWL composition. At say 10oC, water with a d-excess of +10 ‰ (i.e. on the GMWL) forms a vapour at +14 ‰, but condenses back at 0oC with a d-excess of +3.0 ‰ (or if derived from 0oC vapour -+1.2 ‰). The middle 3 Plateau Mountain samples have an average dexcess of +5.0 ‰ and the furthest right -5.9 ‰ (figure 12). While the latter seems too depleted for the model, we would expect a variety of air masses entering the cave whose Figure 12 Isotope data for Plateau Mountain Ice Cave and Grotte Valerie Figure 13 The depletion of d-Excess when external vapour is forced to freeze within an ice cave at 0oC RCGS – Ice Caves composition could vary considerably, so the model is only a guide. Another consideration is that evaporated water bodies evolve along model slopes of 4 (Dansgaard, 1964), close to what we have here. However, there is no liquid water evident so this shouldn’t act as a mechanism. However the ice in the cave is retreating and there is much evidence of melting and refreezing of the hoar – perhaps there is an evaporative component, but likely to be very small. Regarding the fate of the ice, the managers of the site (Alberta Environment and Sustainable Development) have very restrictive access policy for its protection. Therefore a good understanding of the ice formations and what the future holds is very important if the site is to be protected. It seems that while restricting visitors will help, it may be a losing battle against current climate warming and the ice will eventually disappear along with the mountain permafrost. Core samples from the massive floor ice may assist in our understanding, perhaps showing an increased evaporative component? Figure 14 Grotte Valerie, Nahanni, NWT with sample locations Plate 6 Grotte Valerie – Great Ice Passage. Photo: Sylvain Foster Grotte Valerie in the Nahanni, NWT is also a permafrost cave in a rather remote location. A very few ice samples (4), hoar frost ice core were collected by a colleague who was guiding some visitors there in the summer of 2014 (Figures 12, 14 and plates 6 and 7). The samples clearly lie off the GMWL with d-excesses of +0.8 ‰ (ice cores) and -4.4 ‰ (hoar). In agreement of the model in figure 13, we see a much depleted hoar but the ice cores staying within the model boundaries. However, these are the first samples collected from such an easterly (and northern) ice cave, and it’s likely that the LMWL here lies somewhere to the right of the GMWL giving these rather low values (i.e. starting at the LMWL, with the d-excess < 10‰ will yield cave hoar ice lower values than modelled). It also suggests that a detailed sampling of the ice cores might give climate information, especially as they are in the vicinity of a number of Dall Sheep that had fallen down an ice slope in the last 2,000 years – some are trapped under the ice, allowing dating, with the two cores being taken from the lowest depth of the banded ice (Figures 14 & 15). Figure 15 shows the dynamics of air movement through the cave in summer. Warm air can be drawn in through the west entrance despite being higher (albeit only RCGS – Ice Caves 40m) because cold air is draining from the lower, permafrozen entrance. This moist summer air then is forced to condense as hoar at descending temperatures 0 to -3oC. The descending temperature is also a function of the cold zone effect (see next section). Clearly, this cave is worthy of further study, both to further understand the systematics of the ice formation and then to interpret climate from the ice cores based on the ice systematics. Dating of the sheep remains would be important for timelines. Figure 15 A schematic of Grotte Valerie, Nahanni, NWT. After Ford & Williams 2007 Plate 7 Grotte Valerie - clockwise: collecting hoar ice/descending ice above the sheep remains/sampling the ice from previous/ice stalagmite formed on Dall sheep skull. Photos: Sylvain Foster RCGS – Ice Caves Plate 8 Large Passage in the Ice Trap. Note fault slickensides on ceiling Photo: Greg Horne Plate 9 The Ice Trap showing “kitty litter” cryosediments – inset for detail. Photos: Greg Horne The Ice Trap is another remarkable ice cave in Plate 10 a remote location up “Kitty Litter” the Snaring River in containing Jasper National Park. A extrusion high proportion of the ice. Photo: cave is in large, faulted Lee Hollis passageways (Plate 8). The majority of the >3.5km system appears to vary from -2oC to -7 o C, with relative humidity 27-95% (Figure 16) and is thus within the mountain permafrost. The cave is thus unusually dry with dusty (cryoturbated) sediments (nicknamed “kitty litter”) indicative of its cold and arid environment (Plate 9). Although generally dry, in one area we were able to collect extrusion ice within the kitty litter (Plate 10), which shows cryoturbation in process – the freezing and extrusion process crumbling the sediments. The δ-values are consistent with sublimation of cave vapour discussed earlier in this section. Plate 11 Ancient marmot midden in Ice Trap. Photo: Greg Horne Figure 16 Temperature & Relative Humidity at the Ice Tongue from the 7 May to 7 June, 2005 The cave promises interesting Holocene climatic information. For example, guano taken from a nest of mortified marmots was 14C dated to 9,560 +/- 40 years; a most surprising result considering the freshness of the site (Plate 11). Date RCGS – Ice Caves Figure 17 shows a rough map of the cave superimposed on a Google Earth image of the high alpine environment (entrance at 2,350m). Access to the cave is either by helicopter or a 2-day, high alpine traverse from Jasper. We were fortunate to access the cave for sampling in the summer of 2014 by sharing a helicopter assigned to fire duty. Ice Wave Cave Entrance Ice Tongue Figure 17 Ice Trap Cave on Google Earth. Inset shows the north-facing entrance area (Photo: Greg Horne). The Ice Trap contains two areas of massive ice (Figure 17), the Ice Wave and Ice Tongue (Plates 12 and 13). Single core samples were taken from each of the two sections of the Ice Wave (Upper & Lower). These gave the lowest (most-depleted) δ-values from the cave, the Upper more depleted than the Lower, and almost the most depleted in all of the studies (Figures 2 and 18). In fact, low δ-values from a previous study (Yonge and MacDonald (2013) from Canyon Creek Ice Cave, thought to be due to a cold zone: Canyon Creek in this context is discussed at length in the following section, but some comments are useful here. Cold Zones result as humid air flows out of a cave and, on approaching the entrance, generally meets a less humid environment, condenses and cools as latent heat is taken from the walls of the Plate 12 Upper section of the cave (note that in Figure 16, relative Wave. The white powder is humidity - admittedly measured at the calcite precipitating from the ice Ice Tongue - exhibit values <100% thus as it sublimes. Photo: Greg Horne allowing precipitation by sublimation). In cold region caves, the cold zone can be reduced to <0oC thus forming ice there. As the cave vapour moves towards the entrance and precipitates, it becomes steadily more depleted isotopically by the Rayleigh Distillation mechanism. Interestingly, the Upper Ice Wave (δ2H = -196‰) is more depleted than the Lower Ice Wave (δ2H = -184‰), which is to be expected if an entrance lies above the Upper. At this point there is a boulder choke in the cave, which is likely a collapsed entrance. Of course, another alternative is that the ice is old and dates back to an earlier, cooler climatic time. Unfortunately, we do not see any organic material to date here, so the age of this ice is unknown. RCGS – Ice Caves Plate 13 The Ice Tongue. Plate 13 shows the spectacular Ice Tongue whose faceted morphology suggests ice retreat via sublimation. While on previous visits 9 years earlier, we thought that this represented an ice-filled passage in retreat, our summer visit of 2014 showed a great deal of change. We noted a small, drafting hole to the right of the Tongue, which allowed access to its far side (see left of Plate 14). Once through into this hitherto inaccessible area, it was evident that retreat is occurring on both sides and that far from an ice-filled passage, we were dealing more with an ice plug. Furthermore, on the far side of the Tongue, we entered a wetter area of dripping icicles, likely snowmelt from outside and another blocked entrance. Clearly the ice is rapidly Photo: Greg Horne. Plate 14 Back of the Ice Tongue showing sampling sites. Photos: Packrat guano 14C date locations Greg Horne disappearing and this may be our last visit before the ice is gone. Importantly, we have measured two 14C dates on packrat guano – inset of Plate 14 – shows the base of the ice formation to be 2,170+/-30 and 1,120+/-30 years in an upper layer (Plate 14). Unfortunately we could not find any organic material higher in the ice strata for dating. We further sampled the stratified ice for stable isotopes, focusing on the main layers seen (Plates 14 & 15), with results shown in Figures 18 and 19. Recent breach of the Ice allowing access to the stratified ice wall Plate 15 Ice core sampling from the back of the Ice Tongue. Photo: Greg Horne RCGS – Ice Caves Figure 18 Stable isotope data for Ice Trap Cave Figure 19 d-Excess and δ2H for stratified ice in Ice Trap Cave. The d-Excess expresses the coupling between δ18O & δ2H. Top and bottom dates are extrapolated. 11 years 1,210 years Average dExcess for all cave ice 2,170 Base of Ice 2,472 Data from the ice wall are shown in Figure 19 with the two offset sampling profiles (Figure 18) combined. As reported above, we currently have a base 14C date for the ice at 2,170 and a medial date of 1,210 years. With extrapolation, the whole mass appears to date from 2,472 years to the present day. However to make a climatic interpretation, we need to understand which type of ice emplacement mechanism we have? As discussed above, a cold zone is operating but aided by an added permafrost component. And the cold zones at the Wave and Tongue appear to be recent via post-glacial breaching of the cave system. At the Tongue, the wall of ice appears to reflect this with the cold zone commencing 2,472 years ago and continuing to the present day. Figure 20 illustrates the difficulty of climate interpretation without a much denser data record from Ice Trap. Both the d-excess and δ2H values show opposite transitions at the beginning of the MWP (Medieval Warm Period)mand during the LIA (Little Ice Age). One scenario this that low d-excess and higher δ2H seen mainly at 600AD and 1700AD suggest domination by permafrost hoar, whereas the opposite (200AD and 1190AD) is indicative a cold zone domination in a warmer climate. This also fits with the general cooling of climate over the Holocene (Esper et al, 2012 and Yonge, 2012). An alternative scenario is that the permafrost/cold zone mechanism at the cave has remained essentially the same over the 2.47ka period of ice accumulation and that high d-excess and low δ2H are associated with a colder and less humid outside environment. In fact, there appears to be an overall trend in time towards enriched δ2H (i.e. a greater participation of warmer summer air and thus a warming trend – previous section). The first scenario fits better with the Medieval Warm Period/Little Ice Age model with the current “Hockey Stick” current temperature rise; more stable isotope and 14C data are required to establish it. Figure 20 Stable isotope climate record from Ice Trap Cave compared to reconstructed global temperatures (upper plot) and the normalized temperature record for SW Canada (lower green plot). RCGS – Ice Caves Figure 20 Schematic of a cave environment which generates a cold zone. From Luetscher and Jeannin, 2004 Cold Zone Caves Cold zones in caves result from evaporative cooling at the cave walls. This condition generally occurs close to the cave entrance where the relative humidity drops from 100% deep in the cave to <100% toward the outside. The condition is also seasonal in that summer moisture condensation can transfer energy to the cave surfaces - increasing temperatures –and so it is during the fall and winter when the cold zone is maintained. In some cases the cold zone supports perennial ice, as we discuss here. Wigley and Brown (1976) have modelled cave temperature and humidity yielding a relaxation length (the cold zone is scaled by airflow rate and passage diameter): Figure 21 A schematic of the cold zone mechanism xo = 100D1.2V 0.2 (6) Where D is the passage diameter, V is the flow rate and cold zone xo is in metres. Plate 16 Cold zone in Castleguard cave where xo = 200m. Canada’s longest cave, Castleguard contains a classic cold zone cave with ice extending around 400m, but the ice is not perennial (Plate 16). However here, we examine Canyon Creek Ice Cave, a rather low altitude cave which supports a (retreating) cold zone. We also have data over 20 years apart allowing us to study recent changes to the ice. Plate 17 Stratified Ice in Canyon Creek Ice Cave 152m from the entrance in 2014 – Photo: Nick Vieira While Canyon Creel Ice Cave is a classic cold zone cave, we note that some permafrost caves in this study with significant air movement (Ice Trap and Grotte Valerie) act in some way like cold zone caves (e.g. Figure 15). However, in these cases the cold zone is aided or maintained by the presence of remnant mountain permafrost (see discussion in the previous section). The cold zone currently extends from around 50m to 180m from the entrance (xo=130m); which with D = 1.2m and V = 1.3m/s further into the cave is what would be predicted. However, the ice is currently in retreat if compared to ice collections taken from the summer of 1989 to early 1992 (MacDonald, 1994), although non-perennial ice is still seen along the 130m relaxation zone (xo). RCGS – Ice Caves Figure 22 displays the δ2H of various ice types versus distance from the cave entrance from our previous study. Superimposed on the figure is a vertical bar showing the range of the 2014 data; in essence this data fits well with what was measured over 20 years earlier. Figures 23 and 24 show the stratified ice results for the d-excess and δ2H at 56m (old data when ice extended further towards the entrance) and 152m (the current ice front). Note that when looking at averages for the stratified ice at each of those locations, shifts of both the d-excess (5.7 to 4.3 ‰) and δ2H (-154 to -135 ‰) are seen. The latter averages broadly indicate a Rayleigh distillation mechanism which one would expect occurring across the cold zone (x0). However, we see a great variation in the stratified ice sequences, whereas if the mechanism of ice emplacement was purely Rayleigh distillation from a constant vapour source (cave air), then there should be no Figure 23 A plot of d-excess for stratified ice for Canyon Creek Ice Cave. Old data is from Yonge & MacDonald, 2014. See text for green correlation lines. Figure 24 A plot of stratified of ice versus entrance distance for Canyon Creek Ice Cave. Old data is from Yonge & MacDonald, 2014. See text for green correlation lines. Figure 22 A plot of δ2H of ice types versus entrance distance for Canyon Creek Ice Cave (from Yonge & MacDonald, 2014) Stratified ice data range from this study variation. The variation could be explained by a mixing of a groundwater contribution to the ice produced by sublimation in the cold zone and that the data of Figure 22 represents the degree of mixing, pure mixing giving the upper line and pure Rayleigh giving the lower. In terms of climate interpretation, we do not yet have any dates on this ice. However, there is reason to believe it is only in the order of decades old. First there is fresh wood and occasional human detritus trapped in the ice. There are also anecdotal accounts of the ice almost completely disappearing in the recent past. Indeed, in the early 80’s it was possible to get through the ice and access almost 600m of further passages in the back part of the cave (the total length of the cave is 727m). It is thus possible that we are observing variations of a few years in the layers and that annual variations could be observed if closer sampling was employed (visually obvious layers were sampled – Plate 18). RCGS – Ice Caves Plate 18 Sampling stratified Ice in Canyon Creek Ice Cave 152m from the entrance in 2014 – Photo: Nick Vieira The d-excess and δ2H amplitudes are greater in the earlier sampled ice, but was sampled much closer to the entrance (56m) than in this study (152m) when the ice was more extensive. The obvious implication is that external factors such as summer moisture and seepage modify the Rayleigh generated ice the closer to the entrance where there is more interaction from outside sources. In any event, it would be useful if the two records showed correlated amplitudes with ice layer, and while this is not obvious, we have made some attempt (green lines on figures 23 and 24). Having chosen the negative swings on the δ2H plot, we then see some correspondence in positive peaks of the d-excess. If we apply this to the opposite swings, we again see correlated amplitudes (not shown for clarity), giving us some assurance of being on the right track. Bases on the above discussion, the climatic (or weather) interpretation is of more negative δ-values representing a purer Rayleigh mechanism at work. This would occur when a longer transitional period (figure 21) exists in the spring, securing a stable evaporitic environment along the cold zone, but one that did not melt the ice or not allow ice formation i.e. a colder climate/weather regime. The converse (higher δ-values) implies a weakening of the Rayleigh distillation and an influence of moist summer effects (air mass and seepage). Because of the kinetic nature of the Raleigh + mixing system, only warmer and colder trends can be discerned and not actual temperatures. It seems that the only system of the three ice types (cold trap, permafrost and cold zone) that would allow quantitative temperatures to be assessed is the cold trap type. Conclusions Climatic Information – Cold Trap Caves: While there is much work to be done before stable isotopes of ice in caves can be used as a proxy for recent climate change, this study has moved forward in the understanding of the ice systematics. Prior work, of MacDonald (1994) and Holmlund et al (2005) has shown that cold trap caves with extensive ice can act like underground glaciers allowing stable isotopes to be used as proxies for the precipitation and hence temperature at the site. A word of caution Temperature oC though is that although cold traps can flow as glaciers 5 6.5 8 they are nonetheless constrained by the surrounding rock mass, with the likelihood of seepage water modifying the stratigraphy and muting the climate signal. Also, ice caves are rarely just one type; one type might dominate, but may have components of the other types and may be modified by Rayleigh and/or permafrost effects. Figure 25 Variation of δ2H in stratified ice from Q5 & Projects Cave (Yonge & MacDonald, 2013). Green line is mean precipitation. Temperature from isotopic values is based on Yonge et al (1985). RCGS – Ice Caves Figure 25 from Yonge and MacDonald 2013 shows the δ2H variation for ice stratigraphy from two caves on Vancouver Island, both of which contain substantial (40m+) plugs of stratified ice. A moist coastal regime dominates here with substantial inputs of both rain and snow to the caves. Although the figure shows that ice samples oscillate around mean precipitation δ-values, Q5 yields a range generally higher than those for Projects Cave. Q5 has a stream running into the entrance in the summer where the ice samples are found, so is likely more biased towards the heavier summer water. Projects Cave shows lower values, but these cluster around mean precipitation at -92%o. It has no entrance stream and stratified ice occurs almost 20m into the cave – a result of glacial movement perhaps. In this case we would have more confidence in the record for Projects Cave, but would need to obtain data on its chronology as has been done at Scarisoara Cave (Holmlund et al, 2005); the figure shows possible bi-annual (seasonal) variations in the δ−values. Temperatures are based on a North American curve for average cave temperatures and δ2H values (Yonge et al, 1985). In the current study, few additional data were acquired on cold trap ice stratigraphy, but there is potential for future work in the Booming Ice Chasm. Permafrost and Cold Zone Caves: Because of the kinetic nature of these ice emplacement mechanisms, which depend on the duration and intensity of external conditions - moist summer air in the case of permafrost caves and transitional spring or fall temperatures in the case of cold zone caves, only relative temperature changes can be obtained. However, in the above we note that temperature trends in Cold Zone caves are opposite to Cold Trap caves (and glaciers); i.e. that lower δ−values imply higher temperatures and vice versa. Plate 19 The ice tongue in 2005 (above) & 9 years later (below) A final word on cave ice stratigraphy is that much more needs to be done. One area is in the dating of the ice strata, which unfortunately incurs higher costs than acquiring isotope data. We were able to get some 14C dating done “in kind” through the Royal Provincial Museum which has allowed us to study some of the ice chronology and obtain some real climatic interpretation (i.e. the section on Ice Trap Cave). Now while climatic interpretation is important from ice cave stable isotope data, and which appears to offer another tool for investigating recent climate change, there is also the concern that the ice is disappearing at human scale rates. For example, in plate 14 we can see the condition of the ice in 2014 along with a breech that allowed us access to the other side of the Ice Tongue. Plate 19 shows a thinning of the Ice Tongue Plate 20 Ice formations in The from 2005 to 2014. It is thus evident that Ice Cave, Wood Buffalo National this ice will disappear, perhaps in another Park – Photo Greg Horne decade, especially as the ice plug has been breached. This suggests some urgency in studying ice caves generally. At the 6th International Ice Caves Workshop in Idaho, George Veni, Executive Director of the National Cave and Karst Research Institute in Carlsbad, New Mexico, USA gave a clarion call to this effect: Time, money, and melting ice: Proposal for a cooperative study of the world’s cave ice in a race against climate change.” RCGS – Ice Caves Plate 21 Beautifully banded ice stratigraphy in The Ice Cave, Wood Buffalo National Park – Photo Greg Horne In any event, we plan to continue our quest to document ice caves in the northwestern Canadian region. The Ice Cave in Wood Buffalo National Park, Alberta is beautiful example (plates 20 and 21) that we would like to study. In fact it was on the itinerary for this study, but forest fires last summer prevented access. ACKNOWLEDGEMENTS We are indebted to the Royal Canadian Geographical Society for their financial support of the project under their Independent Research Grant. Without this support this project would not have been undertaken. 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