SiC @ Infineon An insight in the analysis for SiC André Kabakow Infineon Technologies AG andre.kabakow@infineon.com Copyright © Infineon Technologies 2011. All rights reserved. Content General information Examples of analysis Summary and Outlook 6/19/2013 Copyright © Infineon Technologies 2011. All rights reserved. Page 2 Content General information Examples of analysis Summary and Outlook 6/19/2013 Copyright © Infineon Technologies 2011. All rights reserved. Page 3 Purpose Infineon is one of the key player in SiC power technology. Understanding the material is essential to keep this role. SiC is about 30 years behind Si (taking wafer size as a basis ). fundamental research is still ongoing 6/19/2013 Page 4 Material properties very hard high temperature stability high thermal conductivity excellent chemical and radiation resistance more than 250 known polytypes 4H structure - ABCB most common structures: 6H, 4H and 3C only 4H SiC used for IFX power devices 100 mm (4-inch) wafers available today 150 mm wafers available since August 2012 6/19/2013 Page 5 Physical and electrical properties wide energy bandgap (eV) 4H-SiC: 3.26 Si: 1.12 high breakdown electric field [V/cm] 4H-SiC: 2.2 x 106 Si: 2.5 x 105 high thermal conductivity (W/cm · K @ RT) 4H-SiC: 3.0-3.8 Si: 1.5 high saturated electron drift velocity [cm/sec (@ E ≥ 2 x 105 V/cm)] 4H-SiC: 2.0 x 107 Si: 1.0 x 107 SiC is very suitable for power devices 6/19/2013 Page 6 SiC market and potential SiC power technology has the potential to start to play a major role next to conventional Si in the current decade estimated worldwide annual sales 100-150 Mio. € estimated growth rate 30-40% p.a. key applications hybrid and electric vehicles renewable energies (wind energy plants and solar converter) switching power supplies uninterruptable power supplies drives key drivers efficiency low system costs power density 6/19/2013 Copyright © Infineon Technologies 2011. All rights reserved. Page 7 SiC related issues defect density (104-105 cm-2) affects the performance and reliability of SiC devices influence of crystal defects on functionality and reliability of SiC devices is barely understood characterization and analysis necessary to develop failure mechanisms formation of a MOS structure not as easy as for Si new challenges for FA 6/19/2013 Page 8 Content General information Examples of analysis Summary and Outlook 6/19/2013 Copyright © Infineon Technologies 2011. All rights reserved. Page 9 Electrical characterization in principle as for Si power devices high current measurements High Power Curve Tracer (pulsed measurement) ¬ avoids overheating of the device partial backside opening of the device for further characterization ¬ BS contact with probe needle not necessary ¬ ensures a good BS contact die solder leadframe package 6/19/2013 Copyright © Infineon Technologies 2011. All rights reserved. Page 10 Emission Microscopy - EMMI SiC is transparent not only to IR, but also to the visible light spectrum SiC merged pn-Schottky-Diode Schottky diode for normal current pn diode for surge current 6/19/2013 Copyright © Infineon Technologies 2011. All rights reserved. Page 11 Emission Microscopy - EMMI higher Vf after extreme stress at high current densities beyond specification EMMI shows a reduced effective area EMMI signature points to extensive crystal defects reference 6/19/2013 fail Copyright © Infineon Technologies 2011. All rights reserved. Page 12 Bipolar Degradation current density [A/cm2] Stacking faults can grow at high current densities triggered by electron hole recombination. forward 400 characteristics before and after stress 300 p+ BPD n- drift layer n+ substrate 200 cathode growth of stacking faults triggered by electron-hole-recombination 100 0 0 6/19/2013 1 2 3 voltage[V] 4 J.P. Bergmann et al., Mat. Sci. For. Vols. 353-356 (2001), pp 299-302 Copyright © Infineon Technologies 2011. All rights reserved. Page 13 Crystal defect etching etching in molten KOH at 500°C under a fume hood Ni wire Ni foil tube furnace at IFX bigger Ni cup smaller Ni cup with molten KOH Ni cage with the sample 6/19/2013 Copyright © Infineon Technologies 2011. All rights reserved. Page 14 crystall defect etching size and shape of the etch pits depend on the defect type no easier procedure is known to decorate crystal defects till now threading edge dislocation basal plane dislocation threading screw dislocation Yukari Ishikawa et al., Mat. Sci. For. Vols. 645-648 (2010), pp 351-354 6/19/2013 Copyright © Infineon Technologies 2011. All rights reserved. Page 15 SEM to visualize p doped areas mechanical cross section is required saves further investigation with e.g. SCM (Scanning Capacitance Microscopy) misaligned p doping of a JFET 6/19/2013 Copyright © Infineon Technologies 2011. All rights reserved. Page 16 Content General information Examples of analysis Summary and Outlook 6/19/2013 Copyright © Infineon Technologies 2011. All rights reserved. Page 17 Summary and outlook FA methods, well-known for Si, still applicable for SiC some work better: “p doped areas under SEM” some work worse: “crystal defect etching” Analysis, with all of its methods, can contribute to a better understanding of the material and its failure mechanisms. What is the correlation between the EMMI signature of “bipolar degraded” devices and the triggered crystal defects? Find an easier method for defect etching 6/19/2013 Copyright © Infineon Technologies 2011. All rights reserved. Page 18 Picture credits page 4: http://www.nature.com/nature/journal/v430/n7003/images/430974 a-f1.2.jpg http://atecom.en.alibaba.com/viewimg/picture.html?picture=http:// i00.i.aliimg.com/photo/v2/525568278/EPI_Ready_Polish_Wafer_4H _6H_Silicon.jpg page 5: https://apecconf.org/2012/images/PDF/2012/Industry_Sessions/is1.5.5.pdf http://upload.wikimedia.org/wikipedia/commons/1/15/Toyota_Prius _Plug-In_Hybrid_IAA_2009.jpg http://www.quantrimang.com.vn/photos/image/032011/29/Usnasa-columbia.jpg http://www.greenology.co.za/images/windturbine.jpg 6/19/2013 Copyright © Infineon Technologies 2009. All rights reserved. Page 19