2nd Qtr. 2013 The 4th IFCE International was organized by Pakistan Foundry Association with the help of local and international participants. It was suitably arranged and was attended by participants who were able to review the tectological developments and scope of work since the 3rd IFCE. PFA was encouraged with the support extended by international organizations like PUM, CBI, GIZ etc. One of the major problems faced by the foundry industries of Pakistan is energy crisis which has affected the production and their supplies resulting in major financial loss. For the solution of energy problem, PFA with the support of GIZ (a team of German experts) and SMEDA have introduced Energy Management System (EnMS) in foundry industries. It is encouraging that GIZ has selected five members of PFA to be provided EnMS free of cost, while additional members will be required to pay Rs 7 Lakh each. CBI an Agency of Netherland has selected Pakistan Foundry Association as Business Support organization (BSO) for a four year Export Coaching Program (ECP). The objective is to guide and motivate the foundry industry through BSO for export purpose to European countries. CBI will provide the sustainable strength for competitive capacity of SME exporters and manufacturers by removing obstacles. PFA members should take a lead in acquiring their guidance for export development of their products. The PUM experts are also helping to improve knowledge and skills development in Pakistan foundries. I welcome the efforts of PFA and PUM in organizing a joint seminar in Faisalabad. The participation of Mr. Robert Dresen, First Secretarty, Embassy of Netherland is gratefully acknowledged. His offer to support PFA for export development to European market specially Netherlands will help our industry. It is my sincere desire that our foundrymen would benefit from the above organizations support and improve their technology to export products from Pakistan Sikandar Mustafa Khan President PFA Contents Chief Editor Mr. Fahad Iqbal Colour Changing Refractory Coatings As Quality Control Tool For Various Foundry Sand Systems & Its Economics 01 Export Coaching Program (ECP) by CBI 11 Energy Efficient Foundries 13 Facility of Energy Management System by GIZ (Germany) with SMEDA for PFA 23 Instrumentation for Energy Conservation 25 Energy saving and controlling cost of Ownership to reduce the production cost FA News Dephosphorization and Desulfurization of molten Ductile Iron and its effect on Ductility 28 Joint Secretary - PFA Editor Mr. Abdul Waheed 30 31 G.M. Foundry M/s, Ravi Spherocast 2.5 km, Defense Road of Bhobatain Chowk, Raiwind Road Lahore. Ph: +92-42-37970474 Mob#: 0321-4989797 Email: abdul.waheed56@hotmail.com Coordinator Mr. Abdul Rashid Secretary - PFA 93-B, Hali Road, Gulberg-II, Lahore Pakistan. Ph: +92 42 35023525, 35753619 Fax: +92 42 35755743 Cell: +92 322 8487873 Email: info@pfa.org.pk pakistanfoundryassociation@gmail.com URL: www.pfa.org.pk 01 Colour Changing Refractory Coatings As Quality Control Tool For Various Foundry Sand Systems & Its Economics Sushil Sharma B.Tech (Chemical Engg.) MD, Shamlax Metachem P. Ltd. Abstract This paper deals with the latest development in India, to ensure complete dehydration of water based coatings. The new concept of Colour Changing Refractory Coatings technology acts as a Quality control tool for the today's modern foundries, which are switching over to the latest resin sand systems. The change over from traditional solvent based coatings to latest water based coatings in most of the foundries, these Colour changing coatings not only enables visual confirmation of complete dehydration of coatings, but also optimize on energy consumption in drying these coatings and increases productivity of the foundry. At the same time it eliminates all moisture related defects such as metal penetration, scabbing and blow holes. The present paper explains in detail these Colour changing refractory coatings for various Foundry Sand systems. Introduction It is a well known fact that the Foundry Coatings are widely used to improve the surface casting finish and to achieve the best cosmetic look of the castings. But at the same time we all know that the best of the Foundry coating can never achieve this on a bad core or moulds. A conventional foundry using Sodium silicate – CO2 gassed binder system uses mostly solvent based refractory coatings. In view of improving productivity, castings quality, to reduce rejection %, to have cleaner environment in the foundry, all modern foundries are shifting to modern resin systems such as phenolic acid cured, cold box resins, shell sand (Hot-Box), Furan Resin, Alpha set etc. Most of these sand resin systems whether for moulds or cores utilizes water based coatings to avoid casting defects such as metal penetration, sand erosion, veining etc. Two Types of Coatings are used by Foundry 1. Solvent Based Coatings 2. Water Based Coatings Now-a-days Modern Foundry is switching over to New Resin Binder Sand Systems, where water based coatings are getting more popular due to following factors - - Cost Environment Friendly Safety Storage Regulations Better Shelf Life Hassle free Transportation While using these Water based coatings the Challenges before a Foundryman are - Complete de-hydration of coating - Are Drying Oven parameters working efficiently ? Above process of complete dehydration is critical as wet coatings results into serious casting defects such as - Scabbing Metal penetration Blow holes Surface Porosity Solutions to these Casting Defects are latest Technological based Colour Changing Refractory Coatings, which changes Colour on drying or ignition. Different types of Colour changing water and solvent based coatings can be solutions for these castings defects. 02 For Water Based Coatings the Colour change of coating can be on drying from Pink to Yellow , or Purple to Yellow, or Yellow to Red. - To avoid over dilution of coating as Colour of the coating will fade & the coating will take more time to change Colour due to higher moisture content. - To make convenient to apply multiple coats as Pink Colour coating will be applied on dried yellow coating, as the applicator knows areas where multiple coats are applied. - To reduces production cycle time. For Solvent Based Coatings the Colour change of coating can be on ignition from Yellow to Orange, or Yellow to Red The basic fact is that the Foundryman needs visual confirmation of drying of coating for the following reasons – - To visually confirm Complete drying of coating - To eliminate all moisture related defects. - To identify poor sand compaction in a core or mould. [as these areas will absorb more moisture from coating and will take longer time to dry]. - To optimize on cost of drying and to avoid over heating by oven / torch. But we are very well aware of the fact that normally Foundries use various types of sand systems such as Three Part Alkyd Resin, Two Part Alpha set (Alkaline Cure), Shell core (Hot Box) & (Cold Box), Furan Resin, Phenolic Two Part (Acid Cured), Cement Molasses, Cement Dextrose, where water based coatings finds application. Similarly, for Sodium-Silicate, Alpha Set & Olvine Sand (Manganese Steel) solvent based coatings are popular. The need is to have Colour changing coatings for various Foundry sand systems. Hence, different water based Refractory coatings (nongraphite) based were developed for various sand systems and the results obtained are as per Table No.1 and solvent based Refractory coatings as per Table no.2. Table No.1 : Colour changing Water Based Foundry Coatings developed for various Sand Systems S.No. 1. 2. 3. 4. Type of Sand System Three Part Alkyd Resin System Two Part Alp Set (Alkaline Cure) System Shell Core [Hot Box] Shell Core [Cold Box] Colour of Wet Coating Colour of Dried Coating Air Dried / Oven Dried Pink Yellow Air Dried / Oven Dried Pink Yellow Air Dried / Oven Dried Pink Yellow Air Dried / Oven Dried Pink/ Purple Yellow Air Dried / Oven Dried 5. Furan Resin Pink Yellow Air Dried / Oven Dried 6. Two Part [Acid Cure] System Yellow Pink Air Dried / Oven Dried 7. Cement Molasses System Pink Yellow Air Dried / Oven Dried 8. Cement Dextrose System Pink Yellow Air Dried / Oven Dried 03 Table No.2 : Colour Changing Solvent Based Foundry Coatings for various Sand Systems S.No. Type of Sand System Colour of Wet Coating Colour of Dried Coating Air Dried / Oven Dried 1. Sodium Silicate – CO2 Yellow Orange On Ignition 2. Alpha Set Resin Sand Yellow Orange On Ignition 3. Olivine Sand System [Manganese Steel] Yellow Red On Ignition It was necessary to ascertain whether the coating has really dried or not on change of Colour. Hence, the lab trials were conducted for various sand systems and the experimental results are tabulated for Two Part Alpha Set sand system as per (Table. 3) & Three Part Alkyd Sand Cores as per (Table 4) & Cold Box Sand Cores as per (Table 5). The weight of the naked core was noted as (W) and the cores were dipped in the coatings suitable for dipping application and weight of the core was noted as (W0). The cores were dried at 150 deg. cent. And the readings were noted at different time intervals of 3, 6, 9, 12, 15 & 18 minutes. It was found that the weight of the core decreases due to moisture evaporation which was indicated by the change of Colour of the coating. (Fig.1). It was found that the weight of the core remained constant as soon as complete dehydration of the coating was over after 15 mins. and the Colour of the coating also changed as the case may be for the sand system, completely from pink to yellow. This visual confirmation of change of Colour of coating indicates complete drying and no further drying of cores is required, was confirmed from the various reading noted for the weight of the core at different time intervals. Calculations : W – Weight of naked (uncoated) core Wc - Constant weight of the core after 100% drying Wt - Weight of core at time 't’ W0 – Weight of core at time 'Zero' % of Moisture at Wt = (Wt-Wc)/(W0-Wc)*100 Laboratory Experimental Results: Table 3 : Cores were prepared of Two Part Alpha set Core @ 150° C Time [Min] Weight of Dipped Core Weight of Coating Moisture % 0 227.50 gm 14.00 gm 100.00% 3 225.50 gm 12.00 gm 82.60% 6 223.00 gm 9.50 gm 60.87% 9 220.50 gm 7.00 gm 39.13% 12 218.50 gm 5.00 gm 21.74% 15 216.00 gm 2.50 gm 0.00% 18 216.00 gm 2.50 gm 0.00% Weight of Dried Core 213.50 gm (W) 04 Table No.4 : Three Part No Bake Core @ 150° C Time [Min] Weight of Coating Weight of Dipped Core Weight of Dried Core Moisture % 100.00 gm 0 109.00 gm 9.00 gm 100.00% 3 108.50 gm 8.50 gm 83.33% 6 108.00 gm 8.00 gm 66.67% 9 107.50 gm 7.50 gm 50.00% 12 107.00 gm 7.00 gm 33.33% 15 106.00 gm 6.00 gm 0.00% 18 106.00 gm 6.00 gm 0.00% Table No.5 : Cold Box Core @ 150° C Time [Min] Weight of Dipped Core Weight of Coating Moisture % 0 246.00 gm 10.00 gm 100.00% 3 244.50 gm 8.50 gm 80.00% 6 243.50 gm 7.50 gm 66.67% 9 241.50 gm 5.00 gm 33.33% 12 240.00 gm 4.00 gm 20.00% 15 238.50 gm 2.50 gm 0.00% 18 238.50 gm 2.50 gm 0.00% Weight of Dried Core 236.00 gm Moisture% Variation @150 deg.cent. 120.00 Moisture% 100.00 80.00 Cold Box Cores 60.00 Two Part Phenolic Alpha Set 40.00 Three Part No Bake 20.00 0.00 0 3 6 9 12 15 18 Time (min) Graph – Moisture % variation @ 150 deg. Cent. 05 Fig. 1 Naked Core Dipped Core [100% Wet] Partially dried core 100% Dried Core Moisture on Core Re-Dried Core Shop Floor Experimental Results : The Colour changing coating was also tested at a renowned Foundry manufacturing Automotive castings, for hub cores. The Cold box cores were dipped in the purple Coloured coating and left for air drying. The air-drying phenomenon was visible as the coating was changing Colour during the drying process. Fig.2 06 Fig. 2 We need to analyze the various advantages of colour changing refractory coatings in detail. Advantages of Colour Changing Refractory Based Coatings 1. To eliminate all moisture related defects – As it is clear from the data collected for various types of resin sand systems, the Colour of coating changes completely as soon as the total moisture is removed. This ensures that no moisture is present in the coating. In conventional WHITE coating there is no visual confirmation to the applicator whether total moisture has been removed or not, particularly from grooves or any area has been left out during the drying process. This visual confirmation eliminates all moisture related defects. 2. To identify poor sand compaction in a core or mould coatings is Energy Saving. l Visual confirmation of drying avoids over heating by oven / torch. l In case of drying ovens it acts as an Energy saver as cores can be taken out on Colour change of coating. l In case of drying by torch overheating of cores / molds is avoided. l Saves Time for drying. l Cores are ready for assembling. l Improves Production cycle. 4. Visual confirmation of Over Dilution Over dilution of coating can be controlled as Colour of coating will fade & Coating will take more time to change Colour due to higher moisture content Visual confirmation is more important particularly in case of Flood & Dip coating applications. 5. Easy to apply multiple coats as Pink Coloured coating will be applied on dried yellow coating . l Applicator knows areas where multiple coats are applied. l In Conventional White coating few areas can be left out with single coating. l Thickness of coating is visible due to distinct Colours. 3. To optimize on cost of drying – l Most important advantage of Colour change 6 . Reduces production cycle time l Visual identification makes operator During core / mold making process, particularly in case of hand molding, if sand compaction is not proper, these areas will absorb more moisture from coating, resulting in more moisture penetration inside the sand surface and the coating will take longer time to dry. 07 understands cores / molds can be sent for final pouring. l In case of air drying, no further waiting is required as visual confirmation of coating getting dried is possible. l Production cycle time is reduced. 7. Coatings are reversible in nature in few cases l Cores / Moulds on storage if absorb moisture, particularly in monsoon season change Colour from Yellow to Pink OR Yellow to Purple. l Visual confirmation in case of water spillage on core / moulds due to reversal Colour change is possible. l Operator knows moisture is absorbed and moisture can be removed before closing the boxes and pouring. l This feature eliminates Moisture related defects completely. Un-burnt coating portion is visible due to distinct l Colour change. l Easy to apply multiple coats. Colour changing Solvent Based Coatings : Colour changing coating acts as a Quality control tool for almost all the Foundry sand systems. Except for Graphite based coatings, Colour changing coating has an edge over conventional white or Coloured (non-Colour changing) coating. Colour changing technology not only eliminates moisture related defects but helps in increasing the productivity, helps during application of multiple coats, helps in saving the energy consumed for drying and in application process. These Colour changing coatings proved to be a technoeconomical solution over conventional refractory coatings. It has cost saving on drying operations and by way of increase in production cycle and reduction in % rejection. In case of solvent based coatings the coating changes its Colour from yellow to orange on ignition, in case of silicate-CO2 cores and AlphaSet alkaline cure sand systems. In case of Manganese steel castings, Magnesite coatings changes Colour from yellow to deep red on ignition. Orange Colour (On ignition) Conclusions : Acknowledgements : Solvent based Colour changing Coating [ Yellow Colour before ignition] The author acknowledges the support fro m the ACC-Nihon Castings Ltd., Jayaswal's Neco Industries Limited, Beekay Engineering Corporation Ltd., L&T Kansbahal for the shop floor trials in evaluating the performance of the Colour changing refractory coatings. Advantages of Colour changing Solvent based coatings – l Wet patches can be identified as these patches do not change Colour. 08 TCT TESIC Foundry Marketing & Services 1993 - 2013 20 Jahre / 20th Anniversary 20 Export Coaching Program (ECP) by CBI By Mr. Abdul Rashid – Secretary PFA CBI (Centre for the Promotion of Imports from developing countries) is an Agency of the Netherlands Ministry of Foreign Affairs. It was established in 1971 in order to support producers / exporters to get a foothold in the Netherlands market, support to Business Support Organizations in improving their capabilities. CBI is supporting 48 developing countries in 27 sectors, providing them sustainable strengthening of the competitive capacity of SME exporters and producers, focusing primarily on European markets. CBI's project for Pakistan is one of the four projects of the program for the Metalworking Sector Asia. On January12, 2013, 1st Coordination Meeting for CBI Pakistan Engineering Sector Export Development was held at Expo Centre, Karachi in which all the stakeholders actively participated and the project plan for Pakistan was disclosed by CBI. 2nd meeting of CBI stakeholders for Export Coaching Program (ECP) was held on March 14, 2013 at DART office Islamabad in which CBI local expert Mr. Imtiaz Rastgar and Mr. Zaheeruddin Dar once again elaborated the whole idea and expressed the hope that outcomes of this program will have far reaching constructive impacts specially on the SME of Pakistan, participants acknowledged their efforts and responded in a very positive way by enrolling themselves into the program. CBI trainer Mr. Wouter Put joined the executive meeting of PFA along CBI local Expert Mr. Zaheeruddin Dar. They explained the house in detail about the role of CBI and they briefly discussed the four year long Export Coaching Program (ECP) in which PFA will participate as their Business Support Organization (BSO). The objective of selecting PFA as BSO is to guide and motivate the foundry industry for export purpose to European countries etc. In this regard five associations from Pakistan have been selected by CBI as BSO's which are l Trade Development Authority of Pakistan (TDAP) l Pakistan Foundry Association (PFA) l Engineering Development Board (EDB) l Small and Medium Enterprises Development Authority (SMEDA) l Pakistan Association of Automotive Parts and Accessories Manufacturers (PAAPAM) In Pakistan, CBI's project duration is 4 years (from Nov. 2012 till the end of 2016). This project aims to achieve l Increased export turnover of participant selected 20 companies up to € 10 million through the Export Coaching Program (ECP), directly supported by CBI l Increased export turnover of another 15 companies up to € 7.5 million through parallel ECP, supported by selected Business Support Organizations (BSO) This whole Export Coaching Program is divided in 14 activities out of which 1st activity “Workshop on Process Control for manufacturing companies” has been done on 25-27 June, 2013 at PAAPAM. Mr. Robert Dresen, First Secretary Economic Department, Embassy of the Netherlands inaugurated that workshop in which CBI consultants Mr. Staf Henderieckx and Mr. Wouter Put delivered the subject matter in detail with industry visits of MECAS Engineering, METLINE Industries and presentations by BSOs. 11 Plot #: CIB-11,12,13, Sector-16, Korangi Industrial Area. Karachi.74900 Pakistan. Phone: 0092-21-35056849 Fax: 0092-21-35075025, Cell: 0092-3212660867 Email: info@g-group.org, businessdevelopment@g-group.org ENERGY EFFICIENT FOUNDRIES Dr. Khalid Mahmood Ghauri Department of Metallurgical and Materials Engineering, University of Engineering & Technology, Lahore, Pakistan Abstract This article mainly focuses upon energy efficient foundries. We are fully aware of this factthat energy is the single most important factor in Countries race to economic superpower status. If there is a short fall of energy in a country then this shortage badly affects the industry, commerce and daily life of people. So the main theme of the article is to discuss the deficiencies and the improved methodologies of energy saving especially in a foundry industry. Sincethe foundry industry is energy intensive and has an important role to play from an environmental point of view while seeking to develop and play an important role in the nation's continued economic growth and development.The same has been received and shared in the light of information available in the published literature. Keywords:Energy efficient foundries, improved methodologies, continued economic growth and development. 1) Introduction: Energy is the single most important factor in Pakistan's race to economically developed status. Pakistan is presently facing a serious energy crisis. Despite strong economic growth during the past decade and consequent rising demand for energy, no worthwhile steps have been taken to install new capacity for generation of the required energy sources. Now, the demand exceeds supply and hence “load-shedding” is a common phenomenon through frequent power shutdowns. Pakistan needs about 14000-15000MW electricity per day, and the demand is likely to rise to approximately 25,000 MW per day by 2015. Presently, it can produce about 11, 500 MW per day and thus there is a shortfall of about 3500-4000MW per day. This shortage is badly affecting industry, commerce and daily life of people. The foundry industry is energy intensive and has an important role to play from an environmental point of view while seeking to develop and play an important role in the nation's continued economic growth and development. There are a number of barriers to energy efficiency: l Lack of awareness, education and customized training l Economic and market distortions l Lack of standardization and labeling on equipment and devices l Lack of financing l Lack of effective coordination l Complacency – a feeling that everything possible has been done l A mistaken feeling that energy monitoring and energy reduction equipment is expensive. 13 Energy stats: India vs Pakistan Coal consumption Indian Energy statistics 339,000,000 Pakistani Energy statistics 4,600,000 Ranked 3rd. 73 times more than Pakistan Ranked 28th. Coal > Production 407,013,000 ton 4,871,000 ton Ranked 3rd in 2005. 83 times more than Pakistan Ranked 21st in 2005. Commercial energy use 494.03 463.14 Ranked 100th. 7% more than Pakistan Ranked 105th. Electricity > Production by source > Fossil fuel Electricity > Production by source > Nuclear 81.7% 68.8% Ranked 105th in 2003. 19% more than Pakistan Ranked 120th in 2003 3.4% 3% Ranked 29th in 2003. 13% more than Pakistan Ranked 30th in 2003. Gasoline prices 0.98 0.87 Ranked 78th. 13% more than Pakistan Ranked 89th. Natural gas reserves 542,400,000,000 cubic feet 695,600,000,000 cubic feet Ranked 23rd. Ranked 22nd. 28% more than India Nuclear Electricity Generation Nuclear Energy Consumption 17.8 terawatt-hours 1.8 terawatt-hours Ranked 18th. 9 times more than Pakistan Ranked 29th. 19.4 terawatt-hours 1.7 terawatt-hours Ranked 18th. 10 times more than Pakistan Ranked 29th. Energy Comparison Chart[1] Pakistan is facing major energy crisis as compared to its neighboring country. Power distribution in foundries is shown below: Power Distribution Tree Transmission losses 3.47 % Input Power 100% Available Power after loss 96.53 % Melting 83.25 % Environmental control 5.33 % Furnace 78.76 % Auxiliary 4.49 % Melting 69.52 % Holding 9.24 % Utilities 2.97 % Sand plant 1.0 % Cooling Pumps 3.86 % Moulding 2.80 % Finishing 2.18 % Mixer 1.80 % Crane & Hoist 0.63 % Power Distribution Chart[2] “Foundries need to understand not only how they use energy, but also how energy consumption patterns affect costs.” – L.V.WHITING 14 Basic Energy Saving Measurement:There are many factors affecting energy consumption in industrial production, and many countries take factors such as tax or special policy to reduce yields, so as to reduce energy consumption would transfer to developing countries where labor cost is low. The reduced yield, however does not solve the problem of energy saving globally. In addition to measures above, the proactive approach of energy ef? ciency improvement can be achieved via improving the energy efficiency of equipment, or deleting directly thehigh-energy part. It is the direct energy-saving measurements; at the same time, indirect measurements such as by means of technological advancements which can lead to higher energy ef? ciency. (1) Direct Energy-Saving Measurement:- Melting is a key procedure in casting production, and improving the energy efficiency of melting equipment is the most direct way to reduce the energy consumption in melting part[3, 4]. Energy consumption in heat treatment of casting production in China is great, and efficiency of heat treatment equipment is low. Let us take ductile iron as an example. Traditionally there is a requirement of graphitization annealing or normalizing where high temperature is needed. If qualified as per specs as cast ductile iron can be produced. Heat treatment part could be eliminated or just low-temperature stress-relief annealing is needed. Hence the contribution to energy saving would be considerable [5,6] (2) Indirect Energy-Saving Measurement:- Nowadays, the forming technology of castings is developing in the direction of high-precision, short process, clean and high quality. Advanced casting technology is not only an important measurement in improving casting quality, but it can also be used in optimizing the entire process[7-8] so as to improve the near- net-shape level of casting, which could results in the decrease of rejection rate and increase of process yield and ? nished rate[9,10] Herein, it leads to the improvement of energy ef? ciency in casting production, namely, indirect energy-saving measurements. Chen et al. [11] carried out a case study on the comparison between direct and indirect energy-saving measurements in an iron casting plant, where the earlier production situation is: large cupola for melting, general sand casting, graphitization annealing for ductile iron, with reject rate of 10%, process yield of 70% and ? nished rate after machining was 60%. Its average unit ? nished energy consumption was 583 kilogram Coal Equivalent per ton (kgce/t). After modernization, the cupola was replaced by induction furnace, and the sand casting was replaced by lost-foam casting, it succeeded in producing the cast ductile iron and therefore eliminated the heat treatment process. The plant utilized computer technology to optimize products design and simulate the production process also. Thus, its current average unit finished energy consumption has been dropped to 212 kgce/t already. Chen et al. assessed the contribution of equipment, forming technology, computer technology and as-cast ductile iron to energy saving. Results indicate that the production rate of as-cast ductile iron is the largest, 37% of energy consumption was cut due to the elimination of heat treatment process; equipment contribution is not as large as expected, just 26%; it is worth mentioning that technology measurements which has no direct effect on energy consumption play an important role in energy conservation, where the contribution rates of lost-foam casting and computer technology are 20% and 17%, respectively 2) Energy Saving Opportunities:2.1.Scrap selection and preparation:l Safety l Correct Size l Density 15 Cleanliness: Ø Sheared versus shredded scrap Ø Rusted scrap Ø Briquetted scrap. l Preheating of scrap l Induction melting Limits the range of scrap used 2.2 Charging of scrap:l Prepare the Charge Sequence l Vibrating Systems l Continuous Charging During the Melt l Pre Heat the Charge in the Furnace l Focus on Reducing the Duration of Charging to Maximize the Melting Process 2.3. Melting:l Mains versus medium Frequency / cupola l Theoretical Power Versus “Best Practice” l Benefits of Batch Melting l Efficiency (No Holding) 97 Percent l Max Power l Power Density l Melting Rate l Furnace Size l Production Planning l Less Emission l Improved Control Estimated Iron Induction Melting Energy Usage Per Ton Melt Tacit 10 Btu Tacit Tacit h/Ton Kwh 10 Btu 10 Btu / Ton / Ton / Ton** /Ton Gross Kwh/ Ton Melt Loss Heel Melting Calculated 800 1.5% 812 2550 2.77 8.71 14.52 Heel Melting and Holding Estimated 954 1.5% 969 3041 3.31 10.39 17.31 Modern Batch Melter Caclulated 500 1.5% 508 1594 1.73 5.44 9.07 Item 1.5% 538% 1690 1.84 5.77 9.62 Batch Melter and Holding Estimated 530 Includes Hold Power for 8 Hours per day and preheat gas at 74 kWh/ton melt for heel melter Estimated Iron Induction Melting Energy UsageChart [12] 2.4. Alloying/Refining/Treatment/Sampling:- 2.7. Transporting Metal:- l Ferro – Alloy Additions l Speed and Accuracy of the Operation l Sampling – Floor Controls l Temperature Control l Sampling – Spectrometer Analysis l Skimming l Slag Removal – Tools, Efficiency 2.8. Pouring:l High Power Thermal Plasma Heating Ø Efficient Heating Ø Fast Ø Offers Metallurgical Benefits l Existing Systems = Ladles & Auto Pouring Units l Both have Disadvantages l Improved Temperature Control to +- 5 degree Celius. l Energy Efficiency Improvement of 20% l Slag Wall, Slag Build – Up – Use of Fluxes l Treatment of Metal 2.5. Holding:l Avoid Holding Metal in Batch Furnaces l Melt Cold – Pour Hot 2.6. Tapping / Ladles:l Refractories l Pre Heating Using Oxy–Fuel to Improve Efficiency l Management “No industrial society has been successful without a vibrant foundry industry base.” – MICHAEL PROMOLI 16 3) Some practical steps for improving energy efficiency in foundries:Here are some initial questions for consideration by all foundries: 1. Have we undertaken an assessment of energy efficiency? 2. Can we benefit from implementing an energy monitoring program to manage energy use? 3. Can we optimize the efficiency of our metal melting and holding processes? 4. Can we optimize the efficiency of the ancillary services in the operation? 5. Can we benefit from investing in energy control systems to shut down equipment when not in use? 6. Can we develop greater staff awareness of energy efficiency and run an effective 'switchoff' program? 7. Can we improve the ladles and refractory materials used in the furnaces? 8. Can we recover energy from any sources for reuse elsewhere in the foundry? 9. Can we benefit from investing in energy efficient equipment and up-grading old equipment (e.g. lighting, ladle preheating, sand reclamation, furnaces etc)? The main areas for energy usage are listed below and then considered in turn. a) Compressed air usage b) Operational controls for energy saving and economy c) Better recovery in terms of input (reduce waste) d) Waste heat recovery e) Energy monitoring and audit a) Compressed air:Air is free but compressed air is not! Compressed air can be considered colorless gold in the industry. Leakage is a major cause of energy wastage. A 3 mm hole will result in a 26 cfm leak and a financial loss of Rs1,93,000 (£2,624.56). Steps recommended to arrest leakage: l Listen for leaks during idle periods l Conduct leak test at least once a fortnight and record quantum of leaks area visible. l Optimize nozzle size (Where different types of machines are used requiring nozzles for blowing l air, it is prudent to use different nozzle sizes depending on the machine size and air required).[13] b) Operational controls for energy saving and economy:Keep tapping temperatures as low as possible. Conduction and radiation losses of a one tonne high-frequency furnace 500 Hz and 900kW at a tapping temperature of 1500°C are 50 kW and 35 kW respectively. These losses can be reduced by approximately 10 kW by having a tapping temperature of 1400°C. To keep the tapping temperature lower, optimize inoculation, reduce ladle travelling distance, preheat the ladle and cover it during metal transfer. It is good practice to display the tapping temperature. Keep the furnace cover closed as far as possible. Radiation loss from the molten metal surface is proportional to the fourth power of temperature. Thus the heat loss at a temperature of around 1500°C comes to 60-70 kW/m2. Hold the molten metal at as low a temperature as possible and for the shortest time. Molten metal should be held, when required, at a low temperature, or turn off the power supply. The rated power should be turned on to heat up again, any chemical analysis of molten metal, preliminary furnace tests and temperature measurements should be performed quickly, and preparatory operations should be performed so that there are no delays from mis-matching with mould assembly or waiting for the crane. Covering the ladle always reduces heat losses. One small foundry was able to save 3 units per melt which equated to 60 units/day and 1500 units/month. At Rs5/-unit (£0.07p), the annual saving was Rs1,25,000 (£1,701.33).[13] c) Better recovery in terms of input (reduce waste):How many tonnes of metal do we melt for each tonne of usable castings? In the worst case, for every tonne of casting produced for sale, up to two tonnes of metal are melted. Consider the major areas of loss (e.g. melt losses, spilt metal, pigged metal, runners and risers, reject castings, or grinding losses). Can metal losses be reduced by minimizing metal spills, or reducing over or under pours through precision pouring techniques? There are often opportunities to 17 redesign, optimize or change the casting process used to increase the metal yield and to work with customers to redesign the casting to reduce its weight or improve its casting characteristics? Can the gating system be redesigned - gating systems (i.e. runners, risers and sprues) are often larger than necessary and wall thicknesses are sometimes over-specified to compensate for porosity and other metal quality problems. Redesign can reduce machining allowances to reduce grinding losses or even eliminate some fettling operations from the foundry? Excess metal melted means more energy used in melting and holding the metal, increased capital costs for unnecessary metal handling capacity, increased fettling costs, unnecessary metal collection and sorting time, increased maintenance of equipment, lost time that could be used for value adding activities and customer relations issues. These all affect the bottom line. Raw material selection and control is also significant since sand or rust in scrap reacts with the furnace refractory to form slags. If slags are formed to about 1% during melting of 3 tonnes of iron, the power loss at 1500°C is about 10kWh/t. In addition the raw material charged should be as dense as possible to improve melting efficiency.[13] d) Waste heat recovery:This relates to the recovery of the maximum energy that is otherwise being wasted in thermal operations. Waste heat recuperators installed to tap the sensible heat from the flue gas coming out of the furnaces, evaporating cooling systems in reheating furnaces and other high temperature installations of a plant are all examples of the drive to recover and reuse a part of the energy that would have gone waste. A hot blast cupola which uses the sensible heat of the exhaust gases to heat the incoming air blast is a good example to cite.[13] e) Energy monitoring and audit:The following are the recommendations for all foundries: l Installation of proper metering and data collection of all major power consuming equipment and operating parameters. l Formation of energy conservation committee to study specific energy consumption and sustain the same. l Energy audit by an independent authority. l Facts and figures collected on energy and production to be displayed to create an awareness. l Learn from others who have implemented energy saving measures.[13] Environmental considerations: Improved energy efficiency reduces greenhouse gas emissions in two ways: Ø Energy efficiency measures for on-site combustion systems (e.g., furnaces, boilers, cupolas, heat-treating ovens) reduce emissions in direct proportion to the amount of fuel not consumed. Ø Reductions in consumption of electricity lead to reductions in demand for electricity and, consequently, reductions in emissions from thermal electric power generating stations. “Taking care of the environment makes good business sense.” – JACK WELCH, former CEO, GE “We want to save energy because we know it helps achieve a higher order objective – the environment in which we live. We do it because it is the right thing to do!” [14] Auditing energy use in a foundry: We will focus on the initial energy audit. An energy audit is a key step that establishes the baseline from which you will measure future energy efficiency improvements. (Other energy audits may be performed later to, for example, verify achievements or uncover other incremental energysaving opportunities.) Following is a list of practice-proven steps in energy auditing.[14] Energy audit purpose: Why have an audit? Can't an excellent energy conservation project yielding good financial return be undertaken without an audit? Yes, it can. It is likely, however, that without the systematic approach of the audit, this ad hoc application of energy management may cause many opportunities – some of which could be better than expected – to be missed; thus the benefits of projects' synergies would remain hidden. 18 An audit has four main stages: 1. Initiating the audit; 2. Preparing the audit; 3. Auditing; and 4. Reporting the audit results[14] Auditor's Toolbox:The following sections include details of the instruments commonly found in the energy auditor's toolbox: [15] Ø Electric power meter Plan Do Ø Combustion analyser Ø Digital thermometer Ø Infrared thermometer Ø Airflow measurement devices Ø Tachometer Ø Ultrasonic leak detect Before arriving at conclusion there has been shared an energy management plan (fig 1) which need customization at the user and in order to maximize profit and growth. Check Act Obtain insight (energy audit) Create awareness Review results Correct deficiencies Get management commitment Train key resources verify effectiveness Review original energy policy Nominate energy champion implement projects Review objectives and targets Policy. objectives, structure Monitor progress Examine opportunities for continual improvement Assign responsibilities Lock in the gains Set new targets Update action plans Develop program(s) Communicate results Start the cycle anew Set targets and measures Celebrate success Review energy program Set priorities Develop action plans © Lorn & associates inc. 2000 19 4) Conclusion:In conclusion many of the methods that have been identified here are indicative and it should be noted that practices will vary from foundry to foundry depending on the alloy system, the process, the weight of the castings, volume, application, mechanization, type of equipment's and a most of other factors. However, it should be noted that all foundries can identify areas where energy efficiencies can be achieved and these will help from an environmental point of view which is of course of significant importance. Acknowledgements:In the name of “Allah”, the most beneficent and merciful who gave us strength and knowledge to complete this Case study report “Energy Efficient Foundries”. This report has been made under the supervision of Prof. Dr. Khalid Mahmood Ghauri by Mubbusher Zia khan & Zeeshan Khalid. References:[1] [2] [3] [4] [5] [6] [7] [8] [9] [10] [11] [12] [13] [14] [15] [16] http://www.nationmaster.com/compare/India/Pakistan/Energy Latest trends in Energy Efficiency-Foundry Industry By Brakes India Limited Foundry Division. Prosanto P, Girish S, Abhishek N and Sanjeev S W. Towards cleaner technologies in small and micro enterprises: a process- based case study of foundry industry in India. Journal of Cleaner Production, 2008, (16): 1264-1274. Wijayatunga P D C, Siriwardena K, Fernando W J L S, Shreshtha R M and Attalage R A. Strategies to overcome barriers for cleaner generation technologies in small developing power systems: Sri Lanka case study. Energy Conversion and Management, 2006, 47: 1179-1191 Xue H Q, Bayraktar E and Bathias C. Damage mechanism of a nodular cast iron under the very high cycle fatigue regime. Journal of Materials Processing Technology, 2008, 202(20): 216-223. Gonzaga R A and Carrasquilla J F. In? uence of an appropriate balance of the alloying elements on microstructure and on mechanical properties of nodular cast iron. Journal of Materials Processing Technology, 2005, 162-163: 293-297. Shehata F and Abd-Elhamid M. Computer aided foundry die- design. Materials & Design, 2003, 24(8): 577-583. [31] Liu B C. Modeling and simulation's role in equipment manufacturing and prospects. Aeronautical Manufacturing Shehata F A. Computer-aided foundry cupola and mold analysis. Journal of Materials Processing Technology, 1997, 63(1-3): 655-660 Askeland D R. Lost Foam Casting (Disposable Mold). Encyclopedia of Materials: Science and Technology, 2008: 4641-4644. Ye Shengping and Sun Zhicheng. Application of aluminum lost foam castings in America and suggestions for promoting LFC of aluminum alloys in China. Foundry, 2008, 57(3): 203-207. (in Chinese Chen Weiping, Huang Dan, Jiang Fan, Luo Hongfeng. Strategy analysis on energy conservation and emission reduction in foundry industry. In: 2008 Guangdong Foundry Conference, Guangdong, China, 2008: 65-75 Practical Application of Improving Energy Efficiency in Foundry By: John T Davis CEO-South Africa Institute of Foundry Men. foundrygate.com/en/noticias/ver/556/india-energy-efficiency , Source: Foundry Trade Journal Guide to Energy Efficiency Opportunities in Canadian Foundries In Partnership with the Canadian Foundry Association. Energy SavingS Toolbox – an Energy audit Manual and Tool((CIPEC) Guide to Energy Efficiency Opportunities in Canadian Foundries In Partnership with the Canadian Foundry Association (Canadian Industry Program for Energy Conservation) 20 Facility of Energy Management System by GIZ (Germany) with SMEDA for PFA By Mr. Abdul Rashid – Secretary PFA Pakistan Foundry Association is always engaged for the development of its member foundries. One of the major problems faced by the foundry industries of Pakistan is energy crisis which has affected the production and their supplies to the OEM resulting in financial crisis. For the solution of energy problem, Pakistan Foundry Association with the support of SMEDA and GIZ (a team of German experts) has planned to bring out its member foundries from the crisis of energy. In this regard GIZ team has conducted several meetings with PFA team and updated about the salient features of their program. Energy Management System (EnMS) is the sole interest of SMEDA and GIZ. After proving EnMS cost benefits in 25 textile industries, GIZ/SMEDA aimed to introduce this system in foundry industry of Pakistan. In this regard a meeting was held on April 25, 2013 at Foundry Service Center (FSC), UET Lahore between the team (Germany trained) of SMEDA and PFA members. A thorough presentation was given by Mr. Azeem-Project Manager and highlighted the salient features of this project. After several meetings PFA informed its members about the possible potential benefits of EnMS and provided them registration and declaration forms to apply for EnMS registration. PFA team also advised GIZ and SMEDA to organize a seminar for the PFA member foundries to update them about EnMS by your experts. Finally a dissemination seminar was conducted on June 7, 2013 at hotel Avari for the introduction of Energy Management System for our members. Mr. Bernhard Meyhoefer, a representative of GIZ informed the house about the potential benefits of EnMS for foundry industry which was followed by question answer session. Mr. Bernhard Meyhoefer also added that for the proper implementation of EnMS, a foundry must fulfill the basic criteria as per described in registration and declaration forms and this offer is only for the members of Pakistan Foundry Association. Mr. Azeem-Project Manager introduced the guide lines to fill the registration and declaration form and submit to GIZ/SMEDA team. The major industry representatives in this seminar were from Millat Tractors Ltd, Millat Equipment Ltd, Ravi Autos Pvt. Ltd unit 1 & 2, Qadri Group of Engineering Pvt. Ltd, KSB Pumps Company Ltd, Paras Engineering Works, Chenab Engineering Works and Foundries Pvt. Ltd, Golden Pumps Pvt. Ltd, Excel Engineering Pvt. Ltd etc. It was interesting that participants showed their great interest in the submission of registration forms. These forms have been analyzed by GIZ team and as a pilot project 5 foundries will be picked up on merit basis to get the services of EnMS free of cost. I would like to add EnMS implication in a foundry will cost Rs. 700,000. In case of PFA members 5 foundries will be selected in pilot project, will not pay any expenses incurred during this process. PFA members have shown keen interest in EnMS and their filled registration and declaration forms have been submitted to GIZ/SMEDA by PFA. After analyzing the forms and short listing foundries, GIZ/SMEDA has selected 11 foundries in which their team is going for initial survey begining from July 11, 2013. 23 Instrumentation for Energy Conservation Vishwas Kale Managing Director, Vijayesh Instruments Pvt Ltd, E mail vijayesh@vsnl.net / vishwask@vsnl.com Instrumentation and process control play a vital role in all processes. For energy conservation, resourceful use of instrumentation is possible. Resource means source or possibility of help. Resources are means of raising money, or means of support. Instrumentation is a big resource. It has possibility of help: to measure, control and log data. It is also a means of raising money/support: make better product with lowest possible rejections and with ease of production. Saving energy is important for environment as well as for cost control. To manage saving of energy, we should have answers for this. What is to be measured, controlled and recorded / logged ? And why for every item. Let us measure correctly. Accuracy is comparison between a reading and the truth. Precision is comparison of different readings of the same thing. So let us be precise and accurate. If not at least measure repeatedly with limited accuracy but with reliability. Why ? Temperature It is possible to take temperature of molten metal at lesser number of times if taken correctly. This will reduce cost of temperature measurements, furnace operations etc. and in effect energy will be saved. Any measurement done correctly and quickly in the first instance saves shutdown or ON/OFF time of furnace or any device, which has to be put OFF electrically or otherwise for measurement. First correct measurement avoids second measurement for verification. In the case of melting of metals, correct tapping temperature is a good clue for the next temperatures in ladle, and while pouring into moulds. In continuous casting machines, a good tapping temperature and only one temperature measurement in ladle is enough to control entire process of casting. To achieve this reliability of temperature measurements, follow the technique correctly. Ladle Preheating Ladle Preheating is to be controlled to get the least temperature drop when hot liquid metal is poured into it. During preheating by burners, a suitable simple thermocouple is inserted and the temperature is checked. This will avoid under heating and unnecessary cooling of hot molten metal when poured into the ladle. Pouring molten metal at right temperature in ladle and avoiding the unnecessary temperature drop means saving in energy. Furnaces-Heat Treatment, Forging etc Does the furnace consume lowest possible energy? Do we actually know job temperature? Do we get uniformity of temperature? Is the furnace fully loaded to use full heat capacity of job? Are the best possible temperature and atmosphere controls achieved? Are we prepared to show customer the true data of heat cycle? Does the furnace consume lowest possible energy? So, can we use better furnace controls? Perhaps yes. Burners could be of self-proportioning type and maintain air to fuel ratio to save fuel. It is also possible to control by motorized valves to again save fuel In case of electric heaters control by thyristor – pulses may be done To achieve uniformity of temperature, try using a circulating fan or a blower. 25 Do mapping of furnace to understand the temperature profile. Replace aged thermocouples from time to time. Use PID controlled action of temperature controllers for tight tolerance of temperature set points. Make sure that the oil is preheated to correct temperature as specified. All this will save energy. Temperature Mapping Of Furnace The thermocouples, datalogger/scanner has valid calibration certificate with NABL accreditation. The data is compared with the actual reading obtained from the thermocouples and instruments used with the furnace for measurement of temperatures. The furnace mapping, apart from satisfying the customer, helps the user to understand the behaviour of furnace and helps to use it better by saving energy. Procedure 1 For furnace temperature mapping, flexible thermocouples are inserted into the furnace and their sensing tips are located at the points or at the jobs where temperature is to be measured. The number of thermocouples is depending on the points to be checked. They are connected to a datalogger/scanner. At predetermined temperatures the readings are recorded at regular short intervals. API has specified a standard for this. Procedure 2 These days more stringent tests are performed- SYSTEM ACCURACY TEST (SAT) and TEMPERATURE UNIFORMITY SURVEY REPORT ( TUS ) ref CQI 9 and AMS 2750 D. The procedure is based on the furnace dimensions, working temperature, application of furnace, furnace class, instrumentation class, number of sensors to be used etc. For any procedure the following information is necessary: Furnace identification: Temperature range : Working temperature: ( at which to be checked ?) Temperature tolerance: Work zone dimensions: Heating method : electric / fuel Process : annealing/tempering/hardening/quenching Belt/conveyor speed: min and max Furnace atmosphere: Controlling instruments: Temperature Controller type On/OFF/ type PID ? Temperature Datalogger ? Recording instruments: Chart Recorder? Datalogger? Instruments and thermocouples: Do you have valid calibration certificates? check ? Thermal Analysis For thermal analysis with no rejection of samples, requirements are: 1. Sample should solidify white 2. Pouring of metal must be at a high enough temperature to obtain liquidus arrest point. 3. Iron must not be heavily nucleated by inoculation or by melting technique 4. Metal must not be treated with Magnesium or Cerium 5. Metal should not be heavily alloyed. This may affect the eutectic arrest points. 6. Verify the calibration of instruments regularly 26 7. Connect holder and cable correctly 8. Check chemical analysis against this method periodically to ensure that the results are not affected by any changes in alloying elements 9. Carbon readings by thermal analysis should generally lie within +/- 0.05 percent of results obtained by analytical method and Silicon readings should generally lie within +/- 0.15 percent 10. The cups must be free from moisture (if hot, then warm them before use by keeping near the furnace). They should be always kept upside down so that foundry dust does not fall in it to give rejected readings. Correct analysis of metal means less operations of furnace or delay in melting and saves energy. Spectrometers Typical difficulties in getting correct analysis from spectrometer analysis are traced to some causes. The ambient temperature, relative humidity around the spectrometer is important to be as specified. The vacuum pump and the O-rings need periodic maintenance and replacement of vacuum pump oil and rings as needed. The optics or lenses have to be cleaned. The sample is taken from an immersion sampler in case of molten metals to avoid contamination. The sample preparation needs polishing by flat cloth and any lines engraving on the sample surface have to be avoided. A straight paper machine is preferred. The sample is burnt into an inert atmosphere of Argon and the gas plays big role. The gas has to be of high purity or needs purification by an argon gas purifier. An Argon gas cylinder is never made empty fully and if any cylinder is found to be containing impurities as shown by the bad burn of sample, it should not be used again, even if refilled. The cylinder may retain the impurities. For burning of sample, the electrodetungsten or silver need correct conical shape of 60 degrees or as recommended. The software with the spectrometer shows all possible causes of incorrect analysis. A good sample saves spectrometer usage, furnace hold up for want of analysis and saves energy. Calibrations Most industries use the calibration services of their in-house facilities or of an external agency. All those who are involved in the process maintain the quality. Everyone contributes some view how best to achieve it. But it must be remembered that such points are not necessarily the requirement. For example, the shop floor engineer demands a tolerance of + / - 5 degrees centigrade temperature while tapping the furnace, and the R & D engineer may demand a temperature within lesser tolerance. Someone has to decide the actual need, which is going to affect the process. If a consensus is not reached then, many a times unnecessarily expensive equipment and methods are used. It is worth to note that the user decides the process, tolerances etc. and this has nothing to do, in some cases, with the internationally accepted norms. Whatever affects the process must be standardized and checked, even a clock for that matter. Some points to ponder could be: measurement parameters, accuracy required, possible utility, special features or requirements, storage conditions, expertise available in the organization. It is better to buy from a reputed source at a higher price with a contract for at least two-three year service. Consider MTBF [mean time between failures or simply how many times failure is possible] as well as MTBR [mean time between repairs or how much time is required for repairs], this will make the equipment useless for use. What is the ease of operations and controls? Is it user friendly? If it is giving quick results? Is it necessary to have them if they cannot be used for any rational use? In some, the range could be large but the span could be made smaller for very accurate and best performance. All these considerations would be useful even for general procurements. A good calibration will give most accurate possible results and in effect saves energy. 27 PRESS RELEASE ENERGY SAVING AND CONTROLLING COST OF OWNERSHIP TO REDUCE THE PRODUCTION COST BY Mr. Imtiaz A. Rastgar ”To compete in international export market Pakistani manufacturers should consider for latest and more efficient technology that helps in lowering the production cost. CompAir air compressors are one of the best compressors in energy consumption and efficient in air production”, as stated by Mr. Aslam Riaz, Chairman S.I.T.E. Superhighway Association of Industry, while addressing a large gathering of industrialist and KARACHI, 18 June, 2013: In current scenario of energy crises and businessmen on “Energy saving and Controlling Cost of price hiking of raw material and increase in GST, it is necessary to focus on air efficiency to reduce production cost Ownership” seminar organized by Rastgar & Co. in collaboration with CompAir and S.I.T.E. Superhighway Association of Industry. Speaking on the occasion, Mr. Chris Goldsworthy, CompAir air compressor expert, stressed on the selection and use of air compressors and detailed the factors which control life time ownership costs of air compressor installations. Chris shed light upon the selection criteria for air compressors, service and spares considerations, efficient piping systems, pressure, filtration and humidity requirements peculiar to each installation. New, energy efficient technologies, like variable speed compressors, oil free water lubricated compressors and Quantima Oil Free Turbo compressors from CompAir were introduced to the audience, who took keen interest in the presentation. Chris said that it is possible to achieve up to a 30% reduction in compressed air energy costs by judicious selection of compressed air equipment like air compressors, dryers, filters, piping layout and piping materials. He further elaborated that it is important to monitor the compressed system on a regular basis, so as to identify and control those areas of the installation where air losses occur. He highlighted that running the compressors at higher than needed pressures will increase energy consumption un-necessarily. When machines which run on air, like airjet weaving and air motors, start leaking air, their efficiency goes down. Chris Goldsworthy appreciated Rastgar & Co's AirAudit initiative in identifying inefficiencies in compressed air system and assistance with entire system performance optimization, leak reduction and practical air management processes, as it helps industries in reducing power consumption and reduction in compressed air system load and wear and tear. This prolongs life of entire compressed air system. The Seminar was organized by Rastgar & Co., Pakistan's leading air compressor distributor and the Best Distributor of the Year 2012, recognized by Gardner Denver. Rastgar & Co. has been distributing CompAir, Quantima, Hydrovane and Reavell compressors in Pakistan for the last 32 years. Speaking on the occasion, CEO Rastgar & Co., Maqsood Zulfqar gave an outline of the training facilities provided for customers' engineers and technical staff in Pakistan and abroad. He also informed the audience about the sales, spares and air audit services provided by Rastgar & Co. Mr. Maqsood Zulfqar CEO of Rastgar & Co. introduced new product “Parker specializes in Low pressure and High pressure piping and fitting”. Mr. Aslam Riaz, Chairman S.I.T.E. Superhighway Association of Industry, appreciated the organizer's efforts for the excellent presentation for bringing in the sharp focus of important aspect of cost control and said he looked forward to more specialized training of technical staff of industrial units in BQA on topics pertaining to compressed air. 28 PFA News PUM and PFA Seminar in Faisalabad Pakistan Foundry Association and Foundry - Engineering Owners Association Faisalabad organized a seminar on 30thMay, 2013 at Chamber of Commerce and Industries Faisalabad for the introduction of PUM activities. Mr. Robert Dresen, First Secretary at Embassy of Netherlands, and Mr. Omer Ali, Economic Affairs specially traveled to Faisalabad to introduce the house about various economic activities and development programs offered by Netherland's Government. He told the participants our government is interested to promote export of various products from Pakistan to their homeland to boost economy. PUM therefore promotes entrepreneurship, self-sufficiency and the sustainable development of small and medium-sized enterprise locally.PUM deploys experienced Dutch senior managers and experts to provide assistance to entrepreneurs in developing countries and emerging markets in a highly effective & efficient manner. Mr. Asim Qadri (PUM Coordinator) Introduced PUM program and briefly discussed PUM success stories in Pakistan. To get the facilities of PUM experts Mr. Abdul Rashid-Secretary PFA introduced the application procedure and offered assistance in filing. At the close of seminar Mr. Muneer Ahmad-Foundry consultant replied many questions from participants about their problems facing in castings and foundry products. Pakistan Foundry Association is highly obliged and grateful to the cabinet Chamber of Commerce and Industries Faisalabad for their hospitality, reception and high tea served to our guests. Iftar cum Dinner by Mr. Sikandar Mustafa Khan President PFA Mr. Sikandar Mustafa Khan President Pakistan Foundry Association continued its traditions and hosted a sumptuous Iftar cum Dinner in the honor of Pakistan Foundry Association members at Pearl Continental Hotel Lahore on Wednesday July 24, 2013. He provided an opportunity to all participants to develop business relations and understanding with each other. There were 32 guests who spared their time and participated in this dinner. Those present were Mr. Laeeq Uddin Ansari, Mr. Asim Qadri, Mr Irfan Ahmad, Mr. Adil J Mansoor, Mr. Umer Farooq, Dr. Faiz Ul Hassan ex-vice chansllor, Dr. Iqbal Qurashi ex Pro-rector, Mr. M.Alamgir Chaoudhry, GM outreach SMEDA and many worthy members. 30 DEPHOSPHORIZATION AND DESULFURIZATION OF MOLTEN DUCTILE IRON AND ITS EFFECT ON DUCTILITY Rub Nawaz Ansari (Deputy Manager, Bolan Castings Ltd. Pakistan) PROBLEM: The importance of phosphorus in the chemistry of the Ductile is vital. It is kept at a level of 0.045 % maximum. The only way to keep it at this level is to use the raw material which should be low in the phosphorus. The consistency in the raw material of the foundry is not much appreciable in Pakistan. The chemistry fluctuates from supplier to supplier and source to source. Therefore it becomes sometimes very hard to keep the phosphorus below the desired level. The surprises result in sub standard production of the ductile iron which has not the up to the mark mechanical properties and premature failure is observed at the end. If there is some fluctuation in sulfur level that has been treated with the soda ash. The sulfur issue is obvious as higher values of sulfur in the melt simply do effect the Mg treatment and consequently nodules are not produced. In other words if the sulfur level is high it do not let the ductile iron to be produced and the problem is highlighted at the earlier stages and addressed accordingly. But it is not in the case of phosphorus. Phosphorus let the ductile iron to be produced but with some low ductility. After mechanical testing or even in service of the part foundry man comes to know that the mechanical properties were not up to the mark. Ductile Iron foundries do not have any method to reduce the phosphorus level in the melt if is introduced through the raw material. In this research it is tried to keep the phosphorus level at minimum level through dephosphorization of the liquid metal. The principles used in dephosphorization in Pig Iron and steel with additives that promote P2O5 in the slag. The most suitable way found is ladle treatment as we could not take risk to add additives in the furnace which may harm its lining. Previous Workings: We found from the literature that oxygen lancing with basic slag forming additives has very good results for the removal of the phosphorus from the steel. We also learned from the literature that Na2CO3 has been used as desulfurizing and dephosphorizing agent for the liquid pig iron. According to Takaharu Mori Ya and Masanobu Fujii, “It has been known for some time that dephosphorization, simultaneously with desulfurization, can be attained by oxidation refining using a Na2C03 or Na20 system slag, but it can hardly be said that the basic investigations are satisfactory.” (“Dephosphorization and Desulfurization Pig Iron by Na2CO3” by Takaharu Mori Ya and Masanobu Fujii) Na2CO3 has also been used in the ductile iron desulfurization. But the practice tells it does not have any considerable impact on the dephosphorization in the case of ductile iron. According to Hitoshi Ono, Tamenori Mas Ui and Hisashi Mori, “The slagging rate of CaO has a great effect on the slag-metal reaction in the steel making process. For this reason, many fundamental and practical studies have so far been made on the mechanism of CaO dissolution into slag and the dissolution rate. In hot metal dephosphorization by lime injection, however, it is not always clear how the injected lime forms slag in hot metal and reacts with phosphorus. It might be thought that the lime injected with oxygen into hot metal forms slag rapidly and participate in the dephosphorization reaction.” (“ Dephosphorization Kinetics and Reaction Region in during Lime Injection with Oxygen” By Hitoshi Ono, Tamenori Mas Ui and Hisashi Mori) 31 Experiments Basis: It is not advisable to lance oxygen for this purpose as it will oxidize the necessary elements like C and Si as well and the cost of re-addition of these will be in creased. The author tried to combine the additives of pig iron and steel together for the simultaneous desulfurization and dephosphorization of the ductile iron without any oxygen lancing which was successful to certain limit. Objectives The project focused on: i. The study of process for reduction of phosphorus percentage. ii. The investigation of the elongation and strength of ductile iron. iii. Fused Lime with Soda Ash ware used as dephosphorising agent. iv. Standard UTS wedge was cast to study the mechanical properties. Materials: The compositions of the available pig iron in the market are as below: CHEMICAL COMPOSITION OF PIG IRON C Si Mn S P 0.015 0.015 0.011 0.043 Imported 1 4.30 0.77 0.035 Imported 2 4.12 0.31 0.015 SCOPES i. The Ladle treatment was used to remove phosphorus from the melt. ii. The process was designed for simultaneous removal of sulfur and phosphorus. Imported 3 4.15 0.45 0.046 0.018 0.046 4.17 0.53 0.049 0.016 0.05 Table 1: Chemical composition of available pig iron Typical Compositions of the Ductile Iron GGG450 Produced without Dephosphorization The following composition is taken for a ferritic S.G. Iron. The cast part is supposed to bear shock loads as well as the nominal stress. Carbon Silicon Mn S P UTS Kg/mm2 Elongation % 3.79 2.52 0.17 0.02 0.044 460 13 3.81 2.44 0.17 0.019 0.043 450 14 3.8 2.59 0.19 0.023 0.045 455 12.3 3.78 2.63 0.15 0.021 0.043 440 13 3.81 2.47 0.15 0.02 0.044 452 11.5 3.79 2.42 0.12 0.019 0.041 460 12 3.8 2.63 0.17 0.019 0.043 470 11 3.81 2.55 0.14 0.021 0.044 445 13 3.78 2.39 0.16 0.02 0.042 457 12 Table 2: Current compositions of ductile iron without dephosphorization 32 Methodology: Additives: The additives chosen for this purpose were: 1. Soda Ash (Na2CO3) 2. Fused Lime Powder. (CaO) Both of the additives were sourced from the local sources in powder form. Furnace: Induction coreless medium frequency furnace was used to melt. Treatment Ladle: Simple open mouth ladle with one ton capacity was used as treatment ladle. Size of the batch: 500 kg liquid metal Temperature: 1430 °C Stirring Time: 10 min Nodule Micrograph 100 X Experimental Work: In a series of experiments the concentration of the additives and the method of addition were altered one by one. We started from using lime powder 1% of the liquid bath size and end up to 3%. However the Soda Ash was kept 2% of the bath size in all the experiments. The best results we obtained when Soda Ash (10kg i.e., 2% of the bath size) and Lime Powder (5 kg i.e., 1% of the bath size) were premixed in the mixer to make a homogeneous mixture before putting them into the ladle bottom. The hot metal was tapped over it. Rest of 5 kg (i.e., 1% of the bath size) of the pure lime was added with the stream of the tapped liquid metal. Results: The results of the experiments were as follows: We do not see any significant effect on C, Si and Mn by the treatment. We also observe no significant change in nodule size and count of the ductile iron. However the amount of S and P has been decreased as shown the following table. Experiment No Carbon Silicon Mn S P UTS Kg/mm2 Elongation % 1 3.8 2.5 0.18 0.02 0.041 460 12.5 2 3.81 2.52 0.16 0.015 0.034 456 13.3 3 3.78 2.5 0.18 0.014 0.028 450 13.6 4 3.81 2.55 0.19 0.013 0.025 453 14 5 3.79 2.52 0.19 0.013 0.022 452 14.6 6 3.8 2.53 0.18 0.013 0.023 446 14.5 Table 3: Ductile Iron compositions after dephosphorization Discussion: The phosphorus is reduced from 0.043% to 0.022% with this process that means 48.86% reduction in Phosphorus level is observed with this process as shown in the table below. Experiment No. Lime addition %age Initial Average Phosphorus %age Final P level (%) Reduction in P Phosphorus Reduction %ge 1 2 3 4 5 6 1 1 2 2 2 3 0.043 0.043 0.043 0.043 0.043 0.043 0.041 0.034 0.028 0.025 0.022 0.023 0.002 0.009 0.015 0.018 0.021 0.02 4.65% 20.93% 34.88% 41.86% 48.84% 46.51% Table 4: Phosphorus reduction values 33 Process Efficiency 0.045 0.04 0.035 0.03 Ph os ph or us % 0.025 Final P level 0.02 0.015 0.01 0.005 0 1 2 3 4 5 6 Experiment No. Similarly we see the increase in elongation with reduced phosphorus level. We observe a maximum of 34% increase in the elongation as shown in the table. Experiment No. Lime addition %age 1 1 12.4 12.5 0.1 0.81% 2 1 12.4 13.3 0.9 7.26% 3 2 12.4 13.6 1.2 9.68% 4 2 12.4 14 1.6 12.90% 5 2 12.4 14.6 2.2 17.74% 6 3 12.4 14.5 2.1 16.94% Previous Ave Current Increase in Elongation Elongation % Elongation % % Increase %age Elongation Table 7.3: Elongation values If we compare the data of phosphorus level and elongation, we find that there is increase in elongation with decrease in phosphorus level keeping all other factors effecting elongation constant as shown in the table. After treatment Experiment Final P level Elongation % No. 1 2 3 4 5 6 0.041 0.034 0.028 0.025 0.022 0.023 12.5 13.3 13.6 14 14.6 14.5 Table 7.4: Phosphorus contents and Elongation values 34 After treatment Elongation % 15 14.5 14 Ph os ph or us % 13.5 After Treatment Elongation % 13 12.5 12 11.5 11 0.041 0.034 0.028 0.025 0.022 0.023 Conclusions We concluded from the results of the experiments as following: 1. The results of the experiments that the process is efficient up to a certain limit. 2. The phosphorus and sulfur can be eliminated simultaneously from the ductile iron melt by use of this process. 3. By keeping all other factors affecting constant the ductility of the ductile iron increases with the reduction of the phosphorus level. 4. The fluidity of the metal did not create any problem so we did not need to increase the carbon equivalent value through carbon or silicon increase. 5. The process has a low cost as both additives are readily available in the local market at lower prices. Based upon the data regarding the ductility and quality assurance together with its relatively low cost, the potential use of low phosphorus s-g iron castings would be expected for diverse machine parts with high quality and reliability. REFERENCES: 1. {Takaharu Mori Ya and Masanobu Fujii} “Dephosphorization and Desulfurization Pig Iron by Na2CO3” http://student.sut.ac.th/sakhob/DeP/Dephosphorization%20and%20Desulfurization%20of%20Molten% 20Pig%20Iron%20by%20Na2CO3.pdf (SUT student web portal, Thailand) 2. {Hitoshi Ono, Tamenori Mas Ui and Hisashi Mori} “ Dephosphorization Kinetics and Reaction Region in during Lime Injection with Oxygen” https://www.jstage.jst.go.jp/article/isijinternational1966/25/2/25_2_133/_pdf (J-STAGE , Japan Sceince and Technology Information Aggregator, Electronic,) 3. {Haruyoshi Tanabe and Masayuki Nakada} “Steelmaking Technologies Contributing to Steel Industries”, http://www.jfe-steel.co.jp/archives/en/nkk_giho/88/pdf/88_04.pdf, (JFE Steel Corporation) 35 We Pour Quality Into Castings PRODUCT RANGE C O M M I T T E D TO F O U N D R I E S Tel: +971(0)6 5262370 | Mob: +923333687664 | Fax: +971(0)6 5262379 Web: www.foseco.com | Email: asif.majeed@foseco.com Address: Foseco Middle East Warehouse No. 1J-09/3, Hamriyah Free Zone, P.O.Box 49261 Sharjah