MATERIAL SAFETY DATA SHEET PRODUCT NAME: VALVE-REGULATED LEAD-ACID BATTERY Battery, wet, non-spillable, UN2800 Saft America Inc. d/b/a Alcad Standby Batteries 3 Powdered Metals Drive North Haven, CT 06473 Information: Phone 203-985-2500 Fax 203-985-2539 HMIS RATINGS NFPA RATINGS For Chemical Emergency Spill, Leak, Fire, Exposure or Accident Call CHEMTREC - Day or Night 800-424-9300 Date 06/11/08 3 Health 3 Health 0 Flammability 0 Flammability 2 Reactivity 2 Reactivity 1. HEALTH HAZARDS ROUTE(S) OF ENTRY: Inhalation, skin and Ingestion INHALATION: LC50: 347 PPM in rats (1 hour) INGESTION: LD50: 214MG/KG in rats May cause burns to human (and animal) tissue contacted, including eye corrosion and corneal ulceration. If ingested, may cause severe burns to the mucous membranes of the mouth and esophagus. Toxic effects described in animals from single exposure by inhalation include respiratory irritation. CARCINOGENICITY: NTP: No IARC: No OSHA regulated: No Overexposure by inhalation may include irritation of the upper respiratory passages or erosion of dental surfaces. Higher exposures may lead to temporary lung irritation. Individuals with pre-existing disease of the lungs may have increased susceptibility to the toxicity of excessive exposures. 2. EMERGENCY FIRST AID If sulfuric acid is spilled, immediately flush skin or eyes with clean water for at least 15 minutes and remove contaminated clothing and shoes. If medical treatment is delayed, immerse the affected area in iced water. AVOID FREEZING TISSUE. If swallowed, do NOT induce vomiting; drink large quantities if water of fruit juice. In all cases, contact a physician immediately. 3. SPECIAL PRECAUTIONS PRECAUTIONS TO BE TAKEN DURING HANDLING AND STORAGE: Avoid rough handling. Do not store above 140°F. Always have water safety showers and eyewash fountains available. OTHER PRECAUTIONS: Wear full protective clothing when handling this material. No smoking regulations must be enforced as hydrogen is evolved during charging of battery. 4. REACTIVITY HAZARDS Stable under normal conditions. INCOMPATIBILITIES (MATERIALS TO AVOID): Sulfuric acid reacts vigorously with alkaline solutions, metal powders, strong oxidizers, reducers and combustibles. HAZARDOUS DECOMPOSITION OR BY-PRODUCTS: Toxic fumes may be released if incinerated. Flammable hydrogen gas produced during charging. HAZARDOUS POLYMERIZATION: Will not occur. MS-L30, VRLA battery 5. FIRE AND EXPLOSION HAZARDS FLASH POINT: N/A FLAMMABLE LIMITS: LEL: N/A UEL: N/A EXTINGUISHING MEDIA: Water, dry chemical. Do not use carbon dioxide (CO2) extinguishers directly on plastic containers due to possibility of thermal shock causing cracking and electrolyte leakage. SPECIAL FIRE FIGHTING PROCEDURES: Wear full protective clothing. Use NIOSH/MSHA approved positive pressure self-contained breathing apparatus. Neutralize runoff with lime, soda ash, etc., to prevent corrosion of metals and formation of hydrogen gas. UNUSUAL FIRE AND EXPLOSION HAZARDS: Sulfuric Acid can react with oxidizing or reducing materials and when heated it emits highly toxic fumes. Lead can react with oxidizing materials and when heated emits highly toxic fumes. 6. HAZARDOUS INGREDIENTS SPECIFIC CHEMICAL IDENTITY; COMMON NAME(S) OSHA PEL Sulfuric Acid; H2S04; Battery fluid, acid, electrolyte Lead, lead oxide, lead alloy ACGIH TLV 3 1.00 MG/M 3 0.15 mg/m OTHER LIMITS % 10% 71% 7. PHYSICAL PROPERTIES BOILING POINT: VAPOR DENSITY (AIR=1): SOLUBILITY IN WATER: EVAPORATION REATE (BUTYL CETATE=1): APPEARANCE AND COLOR: N/A N/A N/A N/A VAPOR PRESSURE (MM HG): SPECIFIC GRAVITY (WATER=1): MELTING POINT: N/A N/A N/A Each battery cell has a blue, white or gray rectangular plastic container enclosing lead electrodes and sulfuric acid electrolyte. 8. ENVIRONMENTAL PROCEDURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Comply with federal, state and local regulations on reporting releases, containing spills and reparation. Contain spill to smallest possible area and absorb as appropriate. Avoid splashing and misting redemption. WASTE DISPOSAL METHOD: Comply with federal, state and local regulations. If approved, neutralize with soda ash or lime and transfer to waste treatment system. 9. INDUSTRIAL HYGIENE CONTROL MEASURES VENTILATION: Adequate to meet TLV requirements. RESPIRATORY PROTECTION: Proper acid canister-type full face piece (See MCA data sheet SD-201). EYE PROTECTION: Chemical splash goggles; full-length face shield. HAND PROTECTION: Rubber or plastic acid-proof gauntlet gloves. OTHER PROTECTIVE EQUIPMENT: Rubber or plastic apron and boots; long sleeve wool, acrylic or polyester clothing; acid-proof suit and hood. WORK/HYGIENIC PRACTICES: Always use extreme care; wash thoroughly after handling. 2 MS-L30, VRLA battery 10. ENVIRONMENTAL REPORTING REQUIREMENTS EMERGENCY PLANNING AND COMMUNITY RIGHT-TO-KNOW ACT PF 1986 (EPCRA): Lead-acid batteries are manufactured using chemicals subject to the reporting requirements of EPCRA, sections 302, 311, 312 and 313 (40 CFR 355 and 372): CAS# 7664-93-9 7439-92-1 CHEMICAL NAME Sulfuric acid Lead REPORTABLE QUANTITY 500 pounds* 10,000 pounds *Battery electrolyte is a mixture of sulfuric acid and water. Only the amount of 100% sulfuric acid must be counted in the reportable quantity. A copy of the MSDS may be required to be filed with the local emergency planning commission, state emergency response commission and local fire department in accordance with sections of EPCRA. Last Date Revised 06/11/08 Disclaimer: This information has been complied for sources considered to be dependable and is to the best of our knowledge and belief, accurate and reliable as of the dated compiled. However, no representation, warranty (either expressed or implied) or guarantee is made to the accuracy reliability or completeness of the information contained herein. This information relates to the specific material designated and may not be valid for such material used in combination with any other materials or in any process. It is the user’s responsibility to satisfy himself as to the suitability and completeness of this information for his own particular use. We do not accept liability for any loss or damage that may occur, whether direct, indirect, incidental or consequential, for the use of this information nor do we offer warranty against patent infringement. Additional information is available by calling the telephone number above designated for this purpose. 3 MS-L30, VRLA battery