Marc-Georg Willinger Fritz Haber Institute of the Max-Planck-Society Department of Inorganic Chemistry Faradayweg 4-6 14195 Berlin, Germany Office: +49- (0)30-8413-4464 E-Mail: willinger@fhi-berlin.mpg.de PERSONAL INFORMATION Date of Birth: Place of Birth: Nationality: Marital Status: 03.05.1973 Dornbirn Austrian Married SHORT CV Since Jan. 2011 Group leader of the “Electron Microscopy” group at the Department of Inorganic Chemistry of the Fritz Haber Institute of the Max Planck Society in Berlin, Germany Dec. 2006-Jan. 2011 Independent researcher at the “Department of Chemistry and CICECO”, University of Aveiro, Portugal Nov. 2006 Awarded with the Schering-Price for the best PhD in chemistry in 2005 (http://www.scheringstiftung.de/de/foerderung/wissensc haft/nachwuchspreise/schering-preis/2225-scheringpreis-2005.html) Jul. 2005- Dez 2006 Postdoctoral fellow at the Fritz-Haber-Institute of the Max Planck Society, Department of Inorganic Chemistry (Prof. R. Schlögl), Berlin, Germany Mar. 2002- Jun. 2005 PhD student at the Fritz-Haber-Institute of the Max Planck Society, Department of Inorganic Chemistry, Berlin, Germany. Supervisor: Prof. R. Schlögl Jun. 2005 Dissertation (PhD, summa cum laude) at the Technical University, Berlin, Germany. Title of the thesis: “Electronic structure of Vanadium Phosphorus Oxides” Feb. 2002 Diploma (M.Sc. in physics, honours degree) at the Technical University, Vienna, Austria. Title of the diploma thesis: “Investigation of the Oxygen K-Edge Fine Structure in Vanadium Oxides.” Supervisor: Prof. P. Schattschneider Sept. 1998-Jun 1999 Bachelor of Science (first class honours degree), Erasmus grant at the Napier University, Edinburgh, UK SCIENTIFIC INTERESTS As a material scientist, I am interested in the relation between the geometric arrangement of structural units and the resulting electronic structure and physical/chemical properties of materials. I am specialized in the field of analytical electron microscopy (scanning electron microscopy, high resolution transmission electron microscopy, electron diffraction, energy dispersive X-ray spectroscopy, electron energy loss spectrometry, image simulation). The combination of these techniques with abinitio band structure calculations of the electronic structure and the simulation of electron energy loss spectra allows a detailed interpretation of spectral data obtained at ultimate spatial resolution in the electron microscope. Atomically resolved imaging and the combined theoretical/experimental approach provides a unique tool for the study of advanced nanostructured materials. At the FritzHaber-Institute we have developed in-situ scanning electron microscopy for the study of catalytic reactions on surfaces under catalytically relevant conditions. My group is further working on the development of a micro-reactor for the coupling of catalytic reactions with electron microscopy via identical location TEM and the application of MEMS based holders for in-situ TEM. PUBLICATIONS (JOURNAL PAPERS) The oxidation of copper catalysts during ethylene epoxidation M. T. Greiner, T. E. Jones, B. E. Johnson, T. C. R. Rocha, Z. J. Wang, M. Armbrüster, M. Willinger, A. Knop-Gericke and R. Schlögl Phys. Chem. Chem. Phys., 2015, Advance Article, DOI: 10.1039/C5CP03722K Electrochemical Degradation of Multiwall Carbon Nanotubes at High Anodic Potential for Oxygen Evolution in Acidic Media Youngmi Yi, Julian Tornow, Elena Willinger, Marc G. Willinger, Chinmoy Ranjan and Robert Schlögl ChemElectroChem, 2015, Advance Article, DOI: 10.1002/celc.201500268 Eutectic Syntheses of Graphitic Carbon with High Pyrazinic Nitrogen Content Nina Fechler, Niels P. Zussblatt, Regina Rothe, Robert Schlögl, Marc-Georg Willinger, Bradley F. Chmelka, and Markus Antonietti Adv. Mater. 2015, DOI: 10.1002/adma.201501503 An Experimental and Theoretical Approach to Understanding the Surface Properties of One-Dimensional TiO2 Nanomaterials Atiđa Selmani, Mario Špadina, Milivoj Plodinec, Ida Delač Marion, Marc Georg Willinger, Johannes Lützenkirchen, Harry D. Gafney, and Engelbert Redel J. Phys. Chem. C, 2015, 119 (34), pp 19729–19742. DOI: 10.1021/acs.jpcc.5b02027 Direct Observation of Graphene Growth and Associated Copper Substrate Dynamics by in Situ Scanning Electron Microscopy Zhu-Jun Wang, Gisela Weinberg, Qiang Zhang, Thomas Lunkenbein, Achim KleinHoffmann, Michalina Kurnatowska, Milivoj Plodinec, Qing Li, Lifeng Chi, Robert Schlögl and Marc-Georg Willinger ACS Nano, 2015, 9, 2, 1506-1519. DOI: 10.1021/nn5059826 Direct Imaging of Octahedral Distortion in a Complex Molybdenum Vanadium Mixed Oxide Thomas Lunkenbein, Frank Girgsdies, Anna Wernbacher, Johannes Noack, Gudrun Auffermann, Akira Yasuhara, Achim Klein-Hoffmann, Wataru Ueda, Maik Eichelbaum, Annette Trunschke, Robert Schlögl, and Marc G. Willinger Angew. Chem. Int. Ed. 2015, 54, 6828-6831. DOI: 10.1002/anie.201502236 Formation of a ZnO Overlayer in Industrial Cu/ZnO/Al2O3 Catalysts Induced by Strong Metal–Support Interactions Thomas Lunkenbein, Julia Schumann, Malte Behrens, Robert Schlögl, and Marc G. Willinger Angew. Chem. Int. Ed. 2015, 54, 4544-4548. DOI: 10.1002/anie.201411581 Oxide-supported IrNiO(x) core-shell particles as efficient, cost-effective, and stable catalysts for electrochemical water splitting Nong HN, Oh HS, Reier T, Willinger E, Willinger MG, Petkov V, Teschner D, Strasser P. Angew. Chem. Int. Ed. 2015, 54, 2975-2979. DOI: 10.1002/anie.201411072 Improving textural properties of -alumina by using second generation biomass in conventional hydrothermal method Cristiane S. Cardoso, Yordy E. Licea, Xing Huang, Marc Willinger, Benoit Louis, Marcelo M. Pereira Micropor. Mesopor. Mat. 2015, 207, 134-141. DOI: 10.1016/j.micromeso.2015.01.015 Structural evolution of aragonite superstructures obtained in the presence of the siderophore deferoxamine Marc-Georg Willinger, Julien Polleux, Markus Antonietti, Helmut Cölfen, Nicola Pinna and Nadine Nassif Cryst. Eng. Comm. 2015, 17, 21, 3927-2935. DOI: 10.1039/C5CE00186B Gas sensing properties and p-type response of ALD TiO2 coated carbon nanotubes Catherine Marichy, Nicola Donato, Mariangela Latino, Marc Georg Willinger, JeanPhilippe Tessonnier, Giovanni Neri, and Nicola Pinna Nanotechnology, 2015, 26, 024004. DOI: 10.1088/0957-4484/26/2/024004 Ultraviolet photodetectors with high photosensitivity based on type-II ZnS/SnO2 core/shell heterostructured ribbons Xing Huang, Yong-Qiang Yu, Jing Xia, Hua Fan, Lei Wang, Marc-Georg Willinger, Xiao-Ping Yang, Yang Jiang, Tie-Rui Zhanga and Xiang-Min Meng Nanoscale, 2015, 7, 5311-5319. DOI: 10.1039/C5NR00150A A Case of Strong Metal–Support Interactions: Combining Advanced Microscopy and Model Systems to Elucidate the Atomic Structure of Interfaces Marc G. Willinger, Wei Zhang, Oleksandr Bondarchuk, Shamil Shaikhutdinov, HansJoachim Freund, and Robert Schlögl Angew.Chem.Int.Ed. 2014, 53, 5998-6001. DOI: 10.1002/anie.201400290 In-situ redox cycling behaviour of Ni–BaZr0.85Y0.15O3−δ cermet anodes for Protonic Ceramic Fuel Cells Narendar Nasani, Zhu-Jun Wang, Marc G. Willinger, Aleksey A. Yaremchenko, Duncan P. Fagg Int. J. Hydrogen Energy, 2014, 39, 34, 19780-19788. DOI: 10.1016/j.ijhydene.2014.09.136 The influence of intercalated oxygen on the properties of graphene on polycrystalline Cu under various environmental conditions Raoul Blume, Piran R. Kidambi, Bernhard C. Bayer, Robert S. Weatherup, Zhu-Jun Wang, Gisela Weinberg, Marc-Georg Willinger, Mark Greiner, Stephan Hofmann, Axel Knop-Gericke, and Robert Schlögl Phys. Chem. Chem. Phys., 2014, 16, 25989, DOI: 10.1039/C4CP04025B Decomposition synthesis of tuneable, macroporous carbon foams from crystalline precursors via in situ templating D. Ressnig, T. Corbiere, T. Lunkenbein, U. Braun, M. G. Willinger, and M. Antonietti J.Mater.Chem.A ,2014, 2,18076–18081. DOI: 10.1039/C4TA03646H Single Crystalline Wurtzite ZnO/Zinc Blende ZnS Coaxial Heterojunctions and Hollow Zinc Blende ZnS Nanotubes: Synthesis, Structural Characterization and Optical Properties Xing Huang, Marc Georg Willinger, Hua Fan, Zailai Xie, Achim Klein Hoffmann, Frank Girgsdies, Chun-sing Lee, and Xiangmin Meng Nanoscale, 2014, 6, 8787, DOI: 10.1039/C4NR01575D A Case of Strong Metal–Support Interactions: Combining Advanced Microscopy and Model Systems to Elucidate the Atomic Structure of Interfaces Marc G. Willinger, Wei Zhang, Oleksandr Bondarchuk, Shamil Shaikhutdinov, HansJoachim Freund, and Robert Schlögl Angew.Chem.Int.Ed. 2014, 53, 5998 –6001, DOI 10.1002/anie.201400290 Photodeposition of Copper and Chromia on Gallium Oxide: The Role of CoCatalysts in Photocatalytic Water Splitting G. Wilma Busser, Bastian Mei, Anna Pougin, Jennifer Strunk, Ramona Gutkowski, Wolfgang Schuhmann, Marc-Georg Willinger, Robert Schlögl, and Martin Muhler ChemSusChem, 2014, 7 (4), 1030–1034, DOI: 10.1002/cssc.201301065 Colloidal Polymers from Dipolar Assembly of Cobalt-Tipped CdSe@CdS Nanorods. Lawrence J. Hill, Nathaniel E. Richey, Younghun Sung, Philip T. Dirlam, Jared J. Griebel, Eli Lavoie-Higgins, In-Bo Shim, Nicola Pinna, Marc-Georg Willinger, Walter Vogel, Jason J. Benkoski, Kookheon Char, and Jeffrey Pyun ACS Nano, 2014, 8 (4), pp 3272–3284, DOI: 10.1021/nn406104d Spinel Mn–Co Oxide in N-Doped Carbon Nanotubes as a Bifunctional Electrocatalyst Synthesized by Oxidative Cutting Anqi Zhao, Justus Masa, Wei Xia, Artjom Maljusch, Marc-Georg Willinger, Guylhaine Clavel, Kunpeng Xie, Robert Schlögl, Wolfgang Schuhmann, and Martin Muhler J. Am. Chem. Soc., 2014, 136 (21), pp 7551–7554, DOI: 10.1021/ja502532y Site-specific ionisation edge fine-structure of Rutile in the electron microscope Hetaba W, Löffler S, Willinger MG, Schuster ME, Schlögl R, and Schattschneider P Micron, 2014, 63, 15-19, DOI 10.1016/j.micron.2014.02.008 Nanosized Heterostructures of Au@Prussian Blue Analogues: Towards Multifunctionality at the Nanoscale Guillaume Maurin-Pasturel, J_r_me Long, Yannick Guari, Franck Godiard, Marc-Georg Willinger, Christian Guerin, and Joulia Larionova Angew. Chem. 2014, 126, 3953 –3957, DOI 10.1002/ange.201310443 Charging and Discharging Behavior of Solvothermal LiFePO4 Cathode Material Investigated by Combined EELS/NEXAFS Study Manfred E. Schuster, Detre Teschner, Jelena Popovic, Nils Ohmer, Frank Girgsdies, Julian Tornow, Marc G. Willinger, Dominik Samuelis, Maria-Magdalena Titirici, Joachim Maier, and Robert Schlögl Chem. Mater., 2014, 26 (2), pp 1040–1047, DOI: 10.1021/cm403115t Methane Decomposition and Carbon Growth on Y2O3, Yttria-Stabilized Zirconia, and ZrO2 Michaela Kogler, Eva-Maria Köck, Lukas Perfler, Thomas Bielz, Michael StögerPollach, Walid Hetaba, Marc Willinger, Xing Huang, Manfred Schuster, Bernhard Klötzer, and Simon Penner Chem. Mater., 2014, 26 (4), pp 1690–1701, DOI: 10.1021/cm404062r One-step synthesis of a highly homogeneous SBA-NHC hybrid material: en route to single-site NHC-metal heterogeneous catalysts with high loadings. Mansuy Rocquin, Mickaël Henrion, Marc-Georg Willinger, Philippe Bertani, Michael J. Chetcuti, Benoit Louis, and Vincent Ritleng Dalton Trans., 2014, 43, 3722-3729, DOI: 10.1039/C3DT52982G Study of thermal stability of (3-aminopropyl) trimethoxy silane-grafted titanate nanotubes for application as nanofillers in polymers Milivoj Plodinec, Andreja Gajović, Damir Iveković, Nenad Tomašić, Boris Zimmermann, Jelena Macan, Tatjana Haramina, D S Su, and Marc Willinger Nanotechnology 2014, 25, 435601. DOI: 10.1088/0957-4484/25/43/435601 Methane Coupling over Magnesium Oxide: How Doping Can Work Pierre Schwach, Marc Georg Willinger, Annette Trunschke and Robert Schlögl Angew.Chem.Int.Ed., 2013, 52, 11381 –11384, DOI: 10.1002/anie.201305470 Tin Dioxide–Carbon Heterostructures Applied to Gas Sensing: StructureDependent Properties and General Sensing Mechanism Catherine Marichy, Patricia A. Russo, Mariangela Latino, Jean-Philippe Tessonnier, Marc-Georg Willinger, Nicola Donato, Giovanni Neri and Nicola Pinna J. Phys. Chem. C, 2013, 117 (38), pp 19729–19739, DOI: 10.1021/jp406191x Catalyst-graphene interactions during scaleable graphene growth on polycrystalline copper Piran R. Kidambi, Bernhard C. Bayer, Raoul Blume, Zhu-Jun Wang, Carsten Baehtz, Robert S. Weatherup, Marc Willinger, Robert Schloegl and Stephan Hofmann Nano Lett., 2013, 13 (10), pp 4769–4778, DOI: 10.1021/nl4023572 Galvanic Replacement Reactions in Metal Oxide Nanocrystals Myoung Hwan Oh, Taekyung Yu, Seung-Ho Yu, Byungkwon Lim, Kyung-Tae Ko MarcGeorg Willinger, Dong-Hwa Seo, Byung Hyo Kim, Min Gee Cho, Jae-Hoon Park, Kisuk Kang, Yung-Eun Sung, Nicola Pinna, Taeghwan Hyeon Science, 2013, 340 no. 6135 pp. 964-968, DOI: 10.1126/science.1234751 Polarity-Free Epitaxial Growth of Heterostructured ZnO/ZnS Core/Shell Nanobelts Xing Huang, Meng Wang, Lidong Shao, Marc-Georg Willinger, Chun-Sing Lee, and Xiang-Min Meng J. Phys. Chem. Lett., 2013, 4 (5), pp 740–744 DOI: 10.1021/jz4001533 Particle shape optimization by changing from an isotropic to an anisotropic nanostructure: preparation of highly active and stable supported Pt catalysts in microemulsions Riny Y. Parapat, Muliany Wijaya, Michael Schwarze, Sören Selve, Marc Willinger and Reinhard Schomäcker Nanoscale, 2013, 5, 796-805, DOI: 10.1039/C2NR32122J Microwave-assisted coating of carbon nanostructures with titanium dioxide for the catalytic dehydration of D-xylose into furfural Patricia A. Russo,Sergio Lima, Valentina Rebuttini, Martyn Pillinger, Marc-Georg Willinger, Nicola Pinna and Anabela A. Valente RSC Adv., 2013, 3, 2595–2603 Assembly of Three-Dimensional Hetero-Epitaxial ZnO/ZnS Core/Shell Nanorod and Single Crystalline Hollow ZnS Nanotube Arrays Xing Huang, MengWang, Marc-Georg Willinger, Lidong Shao, Dang Sheng Su, and Xiang-MinMeng ACSNano 2012, 6, 8, 7333–7339 One-Step Synthesis and Self-Assembly of Metal Oxide Nanoparticles into 3D Superlattices Andrea Pucci, Marc-Georg Willinger, Feng Liu, Xiangbing Zeng, V Alentina Rebuttini, Guylhaine Clavel, Xue Bai, Goran Ungar, and Nicola Pinna ACSNano, 2012, 5, 4382-4391 MOx/CNTs hetero-structures for gas sensing applications: role of CNTs defects G. Neri, S. G. Leonardi, N. Donato, C. Marichy, J.-P. Tessonnier, M.-G. Willinger, Kyeong-Hwan Lee, N. Pinna Procedia Engineering 47 2012 1259 – 1262 Structure−Activity Studies on Highly Active Palladium Hydrogenation Catalysts by X‑ray Absorption Spectroscopy Matthias Bauer, Roland Schoch, Lidong Shao, Bingsen Zhang, Axel Knop-Gericke, Marc Willinger, Robert Schlögl, and Detre Teschner J. Phys. Chem. C 2012, 116, 22375−22385, DOI: dx.doi.org/10.1021/jp306962v Directing the Deposition of Ferromagnetic Cobalt onto Pt-Tipped CdSe@CdS Nanorods: Synthetic and Mechanistic Insights Lawrence J. Hill, Mathew M. Bull, Younghun Sung, Adam G. Simmonds, Philip T. Dirlam, Nathaniel E. Richey, Sean E. DeRosa, In-Bo Shim, Debanjan Guin, Philip J. Costanzo, Nicola Pinna, Marc-Georg Willinger, Walter Vogel, Kookheon Char, and Jeffrey Pyun, ACSNano, 2012, 6, 10, 8632-8645 A one-pot hydrothermal synthesis of sulfur and nitrogen doped carbon aerogels with enhanced electrocatalytic activity in the oxygen reduction reaction Stephanie-Angelika Wohlgemuth, Robin Jeremy White, Marc-Georg Willinger, MariaMagdalena Titirici and Markus Antonietti Green Chem., 2012, 14, 1515–1523, DOI: 10.1039/C2GC35309A Nanoporous Piezo- and Ferroelectric Thin Films Paula Ferreira, Ru Z. Hou, Aiying Wu, Marc-Georg Willinger, Paula M. Vilarinho, Jadra Mosa, Christel Laberty-Robert, Cédric Boissière, David Grosso, and Clément Sanchez Langmuir, 2012, 28, 2944-2949 Crystallographic relationships in the crossed-lamellar microstructure of the shell of the gastropod Conus marmoreus Alejandro Rodriguez Navarro, Antonio Checa, Marc-Georg Willinger, Raul Bolmaro, and Jan Bonarski Acta Biomater., 2012, 8, 2, 830-835 Aragonitic dendritic prismatic microstructure of the anomalodesmatan bivalve Thracia Antonio Checa, Elizabeth M. Harper, and Marc Willinger, Invertebr. Biol., 2012, 131(1), 19-29 Mineral bridges in nacre Checa AG, Cartwright JH, Willinger MG., J Struct Biol., 2011, 176, 330–339 Solution-processed networks of silicon nanocrystals: The role of internanocrystal medium on semiconducting behavior R. N. Pereira, S. Niesar, W. B. You, A. F. Cunha, N. Erhard, A. R. Stegner, H. Wiggers, M.G. Willinger, M. Stutzmann, and M. S. Brandt J. Phys. Chem. C, 2011, 115, 20120-20127 Photoluminescence, cytotoxicity and in vitro imaging of hexagonal terbium phosphate nanoparticles doped with europium Weihua Di, Jie Li, Naoto Shirahata, Yoshio Sakka, Marc-Georg Willinger and Nicola Pinna Nanoscale, 2011, 3, 1263–1269, DOI: 10.1039/C0NR00673D Tin dioxide sensing layer grown on tubular nanostructures by a non-aqueous atomic layer deposition process Catherine Marichy, Nicola Donato, Marc-Georg Willinger, Mariangela Latino, Dmitry Karpinsky, Seung-Ho Yu, Giovanni Neri, and Nicola Pinna Adv. Funct. Mater., 2011, 21, 658-666 Surfactant-free nonaqueous synthesis of lithium titanium oxide (LTO) nanostructures for lithium ion battery applications Seung-Ho Yu, Andrea Pucci, Tobias Herntrich, Marc-Georg Willinger, Seung-Hwan Baek, Yung-Eun Sungac, and Nicola Pinna J. Mater. Chem., 2011, 21, 806-810, DOI: 10.1039/C0JM03064C CoFe2O4-TiO2 and CoFe2O4-ZnO thin film nanostructures elaborated from colloidal chemistry and atomic layer deposition Guylhaine Clavel, Catherine Marichy, Marc-Georg Willinger, Serge Ravaine, David Zitoun, and Nicola Pinna Langmuir, 2010, 26 (23), 18400-18407 Synthesis and Field Emission Properties of Ultra-Nanocrystalline Diamond Fibers and Helices Singh, M.K.; Titus, E.; Willinger, M.G.; Grácio, J. J. Nanosci. Nanotechno., 2010, 10, 2422-2433 Nonaqueous sol–gel chemistry applied to atomic layer deposition: tuning of photonic band gap properties of silica opals Catherine Marichy, Jean-Francois Dechézelles, Marc-Georg Willinger, Nicola Pinna, Serge Ravaine and Renaud Vallée Nanoscale, 2010, 2, 786-792, DOI: 10.1039/B9NR00220K Mesoporous silica nanoparticles combining two-photon excited fluorescence and magnetic properties Elena Chelebaeva, Laurence Raehm, Jean-Olivier Durand, Yannick Guari, Joulia Larionova, Christian Guérin, Alexandre Trifonov, Marc Willinger, Kalaivani Thangavel, Alessandro Lascialfari, Olivier Mongin, Youssef Mir and Mireille Blanchard-Desce J. Mater. Chem. 2010, 20, 1877-1884, DOI: 10.1039/B922052F Enhanced photoluminescence features of rare earth phenylphosphonate hybrid nanostructures synthesized under nonaqueous conditions Weihua Di, Rute A. S. Ferreira, Marc-Georg Willinger, Xinguang Ren, and Nicola Pinna J. Phys. Chem. C 2010, 114, 6290–6297, DOI: 10.1021/jp911762h In vivo inspired conditions to synthesize biomimetic hydroxyapatite N. Nassif, F. Martineau, O. Syzgantseva, F. Gobeaux, M. Willinger, T. Coradin, S. Cassaignon, T. Azais, and M. M. Giraud-Guille Chem. Mater. 2010, 22, 3653–3663, DOI: 10.1021/cm903596q Micro-Raman investigation of vanadium-oxide coated tubular carbon nanofibers for gas-sensing applications S. Santangelo; G. Messina; G. Faggio; M.-G. Willinger; N. Pinna; A. Donato; A. Arena; N. Donato; G. Neri Diamond and Relat. Mater., 2010, 19, 590-594, DOI: 10.1016/j.diamond.2009.11.014 The “benzyl alcohol route”: An elegant approach towards doped and multimetal oxide nanocrystals Nicola Pinna, Mohamed Karmaoui, Marc-Georg Willinger Journal of Sol-Gel Science and Technology, 2010, DOI: 10.1007/s10971-009-2111-2 A general nonaqueous route to crystalline alkaline nanostructures M. Karmaoui, M.-G. Willinger, L. Mafra, T. Herntrich, N. Pinna Nanoscale, 2009, 1, 360 - 365, DOI: 10.1039/b9nr00164f earth aluminate Microstraining in titania-, alumina- and silica-supported V2O5-catalysts D. Habel, O. Görke, M. Tovarb, M. Willinger, M. Ziemann, O. Schwarz, R. Schomäcker, H. Schubert J. Eur. Ceram. Soc., 2009, 29, 1093–1099 Transition metal-doped ZrO2 and HfO2 nanocrystals Andrea Pucci, Guylhaine Clavel, Marc-Georg Willinger, David Zitoun and Nicola Pinna J. Phys. Chem. C, 2009, 113, 28, 12048-12058 The controlled deposition of metal oxides onto carbon nanotubes by atomic layer deposition: examples and a case study on the application of V2O4 coated nanotubes in gas sensing Marc-Georg Willinger, Giovanni Neri, Anna Bonavita, Giuseppe Micali, Erwan Rauwel, Tobias Herntrich, Nicola Pinna Phys. Chem. Chem. Phys., 2009, 11, 3615 - 3622 A general soft-chemistry route to metal phosphate nanocrystals Marc-Georg Willinger, Guylhaine Clavel, Weihua Di, Nicola J. Ind. Eng. Chem., 2009, 15, 883-887, DOI:10.1016/j.jiec.2009.09.017 Pinna Microstructure and electron field emission study of diamond nanorod decorated a-SiO2 nanowires by microwave Ar–CH4/H2 plasma chemical vapor deposition with addition of N2 M.K. Singh, E. Titus, M.G. Willinger, J.C. Madaleno, J. Grácioa Diamond & Related Materials 2009 18, 865–869 Effect of annealing and electric properties of high-k thin films grown by ALD using carboxylic acids as oxygen source Erwan Rauwel, Frédérique Ducroquet, Protima Rauwel, Marc-Georg Willinger, Igor Matko, Nicola Pinna J. Vac. Sci. Technol. B 2009, 27, 230 Non-aqueous sol.gel routes applied to atomic layer deposition of oxides Guylhaine Clavel, Erwan Rauwel, Marc-Georg Willinger, Nicola Pinna J. Mater. Chem. 2009, 19, 454 The key role of the surface membrane in why gastropod nacre grows in towers Antonio G. Checa, Julyan H. E. Cartwright, Marc-Georg Willinger PNAS 2009 106:38-43 Vanadium oxide sensing layer grown on carbon nanotubes by a new atomic layer deposition process Marc-Georg Willinger, Giovanni Neri, Erwan Rauwel, Anna Bonavita, Giuseppe Micali, Nicola Pinna Nano Lett. 2008, 8, 4201 Carboxylic Acids as Oxygen Supplying Agents for Atomic Layer Deposition of High-k Thin Films Erwan Rauwel, Frédérique Ducroquet, Protima Rauwel, Marc-Georg Willinger, Igor Matko, Dimitri Kiselev, Nicola Pinna ECS Transactions 2008, 16, 279 IL-assisted synthesis of V2O5 nanocomposites and VO2 nanosheets Helena Kaper, Marc-Georg Willinger, Igor Djerdj, Silvia Gross, Markus Antonietti, Bernd M. Smarsly J. Mater. Chem., 2008, 18, 5761–5769 Citric acid-assisted hydrothermal synthesis of luminescent TbPO4:Eu nanocrystals: controlled morphology and tunable emission Weihua Di, Marc-Georg Willinger, Rute A. S. Ferreira, Xinguang Ren, Shaozhe Lu, Nicola Pinna J. Phys. Chem. C 2008, 112, 18815 Carboxylic acids as oxygen sources for the atomic layer deposition of high-k metal oxides Erwan Rauwel, Marc-Georg Willinger, Frédérique Ducroquet, Protima Rauwel, Igor Matko, Dmitry Kiselev, Nicola Pinna J. Phys. Chem. C 2008, 112, 12754 Non-Aqueous Routes to Metal Oxide Thin Films by Atomic Layer Deposition E. Rauwel, G. Clavel, M.-G. Willinger, P. Rauwel, N. Pinna; Angew. Chem. Int. Ed. 2008, 47, 3592 Manganese Doped Zirconia Nanocrystals G. Clavel, M.-G. Willinger, D. Zitoun, N. Pinna Eur. J. Inorg. Chem. 2008, 863 Solvent dependent shape and magnetic properties of doped ZnO Nanostructures G. Clavel, M.-G. Willinger, D. Zitoun, N. Pinna Adv. Funct. Mater. 2007, 17, 3159 Facile autoreduction of iron oxide/carbon nanotube encapsulates Wei Chen, Xiulian Pan, Marc-Georg Willinger, Dang Sheng Su, and Xinhe Bao. JACS, 2006, 128 (10), 3136-3137 Electron beam induced reversible solid-liquid-solid phase transitions of Bi nano particles J. B. Wagner, M.-G. Willinger, J.-O. Müller, D. S. Su, R. Schlögl Small, 2006, 2, 230-234 Electronic structure of -VOPO4 M.-G. Willinger, D. S. Su, R. Schlögl Physical Review B 2005, 71, 155118 Geometric and electronic structure of gamma-V2O5 : Comparison between alphaV2O5 and gamma- V2O5 M. Willinger, N. Pinna, D. Su, and R. Schlögl Phys. Rev. B 2004, 69, 155114 Local Structure of Nanoscopic Materials: V2O5 Nanorods and Nanowires N. Pinna, M. Willinger, K. Weiss, J. Urban, and R. Schlögl Nano Lett. 2003, 3, 1131 Tribochemical modification of Bi promoted vanadyl phosphate systems 1: An improved catalyst and insight into structure-function relationship I. Ayub, D. S. Su, M. Willinger, A. Kharlamov, L. Ushkalov, V. A. Zazhigalov, N. Kirilova, R. Schlögl Phys. Chem. Chem. Phys. 2003, 5, 970-978 Anisotropy and collection angle dependence of the oxygen K ELNES in V2O5: A band-structure calculation study D. S. Su, C. Hébert, M. Willinger, R. Schlögl Micron, 2003, 34, 227-233 Oxygen K-edge in vanadium oxides: Simulations and experiments C. Hébert, M. Willinger, D. S. Su, P. Pongratz, P. Schattschneider, R. Schlögl European Physical Journal B 2002, 28, 407-414 Tribochemical modification of the microstructure of V2O5 D.S. Su, V. Roddatis, M. Willinger, G. Weinberg, E. Kitzelmann, R. Schlögl and H. Knözinger Catalysis Letters 2001, 74, 169-175 INVITED TALKS Willinger M.: “Structural and chemical characterization at the nanometer scale” Seminar given at the Seoul National University, South Korea, Department of Chemical Convergence for Energy & Environment, Nov. 25, 2009, Seoul National University, Gwanak-gu, Seoul 151-742, Korea Willinger M.: “Investigation of nanostructured catalysts by a combined DFT/TEM approach”, Seminar at the institute for Chemical Physics of Materials (Catalysis Tribology), May 18, 2006, Université Libre de Bruxelles Campus Plaine, CP 243 B1050 Bruxelles Willinger M.: “Characterization of nanostructured catalysts by a combined DFT/TEM approach”, Seminar at the Laboratorio Associado CICECO, Universidade de Aveiro, May 8, 2006, Campus Universitario de Santiago 3810-193 Aveiro Portugal Willinger M.: “Energy loss spectra of inelastically scattered electrons as a tool for structure investigation”. Conference on high resolution diffraction applied for structure characterization of modern materials. June 13-17, 2004, Zakopane, Poland. Willinger M.: “EELS Near Edge Structures: A Tool for Probing the Electronic Structure and Related Properties of Solids”. International Workshop on microstructural characterisation of oxide films and multilayers by TEM and HREM. Polish Academy of Sciences; 26-27 Sep. 2002, Warsaw, Poland. COMMUNICATIONS AT INTERNATIONAL CONFERENCES M.G. Willinger, M. Niederberger, J.P. Tessonier, C. Hess, R. Schlögl, and D.S. Su; “Getting insight into the active dynamic species of VPO catalysts from the investigation of nanostructured VOx model catalysts“. Talk at the 6th international symposium on group five elements, Adam Mickiewicz University, 60-780 Poznan, Poland. M.G. Willinger; “Electron energy loss sepctrometry in the TEM: Chemical information at the nanometer scale”. Talk at the Nanospain 2008, Nanoiberian Conference, April 2008, Braga, Portugal. G. Clavel, M.-G. Willinger, D. Zitoun, N. Pinna; “Doped ZnO: a case study for the influence of solvent and structure”. Poster at the E-MRS 2007 Fall Meeting, September 17 – 21, 2007, Warsaw, Poland. M. Willinger, M. Niederberger, C. Hess, R. Schlögl; “Towards an understanding of the active site of VPO catalysts using nanostructured VxOy model catalysts” Oral contribution at the North American Catalysis Society (NACS) - 20th North American Meeting (NAM) June 17-22, 2007, Houston, Texas, U.S.A. J.P. Tessonnier, D. Wang, M.G. Willinger, R. Schlögl, D.S. Su; “Tuning the catalytic properties of VxOy supported on multiwalled carbon nanotubes”. Oral contribution at the E-MRS 2007 Spring Meeting, May 28 to June 1, 2007, Strasbourg, France. M.G. Willinger, M. Hävecker, N. Pinna, D. S. Su, R. Schlögl; “Investigation of nanostructured catalysts by a combined DFT/TEM approach”. Abstract and poster for the 11th International Conference on Theoretical Aspects of Catalysis, June 11–14, 2006, Schmöckwitz near Berlin, Germany. M.G. Willinger, D. S. Su, R. Schlögl; “Investigation of nanostructured catalysts by a combined DFT/TEM approach”. Abstract and poster for the International Conference on Density Functional Theory and Transmission Electron Microscopy DFTEM 2006, April 21–23, 2006, Vienna, Austria M. Willinger, D.S. Su., R. Schlögl; “Geometric- vs electronic structure of VOPO4 - DFT and ELNES study”. International EELS Workshop EDGE 2005, May 1–5, 2005, Grundlsee, Austria. P. Schattschneider, J. Bernardi, D. Eyidi, C. Hébert, F. Hofer, B. Jouffrey, M. Nelhiebel, St. Rubino, M. Stöger-Pollach, M. Willinger; “Fundamentals of EELS”. Presentation during a seminar at the ETH Zürich, Sep 09, 2005, Zürich, Switzerland. M. Willinger, D. S. Su, R. Schlögl; “Micro and electronic structure of vanadium phosphorus oxides”. Abstract and poster for the 13th European Microscopy Congress EMC 2004, Aug. 21-27, 2004, Antwerp, Belgium. M. Willinger, A. Liskowski, D. S. Su, R. Schlögl, J. A. Lopez-Sanchez, J. K. Bartley, G. J. Hutchings; “Micro- and electronic structure of the catalyst and the V5+ phases of vanadium phosphorus oxides”. Abstract and poster for the 13. International Conference on Catalysis, Jul. 11-16, 2004, Paris, France. I. Ayub, D. S. Su, M. Willinger, A. Kharlamov, L. Ushkalov, V. A. Zazhigalov, R. Schlögl; “Enhanced catalytic activity by tribomechanical activation treatment of Bipromoted vanadyl phosphate systems”. Abstract and poster for the XXXVI Jahrestreffen Deutscher Katalytiker, Mar. 19-21, 2003, Weimar, Germany. N. Pinna, K. Weiss, H. Sack-Kongehl, U. Wild, M. Willinger, J. Urban and R. Schlögl; “Divanadium pentoxide nanorods” Abstract and poster for the XXXVI Jahrestreffen Deutscher Katalytiker, Mar. 19-21, 2003, Weimar, Germany. M. Willinger, N. Pinna, D. S. Su, R. Schlögl; “Ab-Initio Band-structure calculations of a new polymorph of V2O5: A comparison between V2O5 and - V2O5”. Abstract and poster for the XXXVI Jahrestreffen Deutscher Katalytiker, Mar. 19-21, 2003, Weimar, Germany. M. Willinger, D. S. Su, N. Pinna, R. Schlögl; “Electronic structure studies of - V2O5: Ab-initio calculations and EELS measurements”. Abstract and poster for the 9th Wien Workshop, Apr. 23-26, 2003, Vienna, Austria. N. Pinna, K. Weiss, H. Sack-Kongehl, U. Wild, M. Willinger, J. Urban and R. Schlögl: “Synthesis, characterization and size control of vanadium oxide nanorods”. Poster for the Autumn School on Materials Science and Electron Microscopy Sep. 28 - Oct. 03, 2002, Berlin, Germany. C. Hébert, D. S. Su, M. Willinger, P. Schattschneider; “Simulation of the O-K ELNES in vanadium oxides with Wien97”. Poster, 7. WIEN Workshop, Sep. 27-29, 2001, Vienna, Austria. C. Hébert, M. Willinger, D. S. Su, R. Schlögl; “ELNES of some vanadium oxides: Simulations and experiments”. Poster, Dreiländertagung für Elektronenmikroskopie, Sep. 09-14, 2001, Innsbruck, Austria. D. S. Su, V. Roddatis, M. Willinger, G. Weinberg, E. Kitzelmann, H. Knözinger, R. Schlögl; “Characterisation of tribochemically activated vanadium oxide V2O5”. Poster, Europe Cat V, Sep. 02-07, 2001, Limerick, Ireland. M. Willinger, D. S. Su, R. Schlögl, C. Hébert, P. Schattschneider; “Ab-Initio simulation of the oxygen 1s ionisation near edge structure in vanadium pentoxide”. Abstract and poster for the XXXIV. Jahrestreffen Deutscher Katalytiker, Mar. 21-23, 2001, Weimar, Germany. M. Willinger, D. S. Su, C. Hébert, P. Schattschneider, R. Schlögl; “Site specific ab-initio calculations of the oxygen 1s ionisation edge in vanadium pentoxide”. Poster, Autumn School 2000 on Materials Science and Electron Microscopy, Oct. 10-15, 2000, Berlin, Germany.