Powder Coating using Metallic Powders Architect Information Surface Finishes Status 11/2014 Powder Coating in Metallic Colours Architect Information Contents 1. 2. 3. 4. 5. 6. 7. 8. 9. 10. 11. 12. Portfolio Metallic Composition of powder-based Metallic Surface Finishes Principle of Powder Production Components of Metallic Powders Pigment Types as distinguishing Features of Metallic Powders Incorporation of Pigments Coating using Metallic Powders Surfaces based on Metallic Powders Typical problems with Metallic Powders Cleaning of Metallic Surface Finishes Schüco System Finish Information Contact details Page 2 1. Schüco Overview System Finish Schüco Options Metallics in coating (Status 11.2014) – Metallics in Red Basis Performance Decor Premium MetallicEffekte Fluorpolymer-Pulver Cost PowColor Facade Quality Powder Base Coat with Topcoat AnoLine Pre-Anodisation with Powder Top Coat MetallicLine DuraClean (Powder) Anti-Graffiti High Durability Quality Fine Texture Powder AnoLine FS Wood & Stone Optics: DECORAL NATURALL WetLine Trend/-colours Metallic AnColor Anodisation (E6/EV1, C0) MetallicLine Plus INOX Optic Powder Anodisation for Structural Glassing (SG Anodisation) Coloured Anodisation with / without mechanical Pretreatment (E1 to E6, C0, C31 to C35) (Anodisation) INOX Optic Classic INOX Optic Plus Silbver & Gold (EV2 to EV 4) Gloss anodisation S315 WetColor (Liquid Paint) Polyurethan (PUR) Duraflon PUR Trend SANDALOR Duraflon Duraflon Trend AnoLine DF PVDF PVDF Decor Page 3 2. Composition of powder-based Metallic Surface Finishes Example: Powder layer layer Powder Protective & & bonding Protective bondinglayer layer Metallicaluminium aluminium Metallic Page 4 Quality-assured powder coating with GSB/Qualicoat approval Corrosion protection and bonding base for powder coating as per GSB/Qualicoat Schüco profiles, accessories and customer material 3. Principle of Powder Production Process of powder production (Source: TIGER) Steps: 1) Supply 2) Initial weight & logging 3) Pre-mixing 4) Extrusion 5) Rolling out 6) Breaking over rollers 7) Optimisation of particle size in the grinder 8) Packaging 9) Bonding (if necessary) Page 5 4. Components of Metallic Powders Overview Colour-independent components: Colour-dependent components: Polyester-based polymers Curing components These two components determine the basic properties and are tailored to the architecture. Pigment preparation The effect is set up in a reproducible way by means of the following properties: - Material (chemical composition, finish) - Particle size (effect & characteristic) Additives - Distributing agent (controls the position of the Additives optimise the surface finish process particles in the coating and thereby their and the formation of effects and ageing effect). behaviour (where applicable). They also prevent undesired effects such as rotting. The entire product is tested and Filling agent Serves to support the process when covering the colour layer. Page 6 approved by quality assurance bodies such as GSB and/or Qualicoat for use in architecture. 5. Metallic powders: Pigment Types Overview of Raw Materials available for Metallic Effects Uncoated aluminium pigments and coated polymers or SiO2 - Very good decorative effects - Can be attacked by oxidation, acids and bases Copper and brass alloys - Very good decorative effects - Can be attacked by oxidation, acids, bases and ammonia Stainless steel - Attractive appearance, but high specific density makes it difficult to incorporate in powder coating - Extremely durable (even in industrial and coastal areas) - Problems owing to nitrogen content, labelling required above approx. 8% (sensitising, possibly carcinogenic) Coated mica pigments - Attractive look paired with good incorporation and mechanical resistance - Weather-resistant owing to the coating of TiO2 - Variable colour effect owing to coating with different metal oxides Page 7 5. Metallic Powders: Pigment Types Non-leafing Aluminium Pigments (Images: Inver) Non-leafing (sparkle/silver dollar) - Fine to mid-size particles, D 50 approx. 10 - 60µm Grip and moisture-resistant - Sparkling effects - Natural anodised effects - Weather-resistant thanks to coating with special polymer or SiO2 Silver Dollar, Dv50 = 35 Sorgente di Luce Light source Metallic powder Substrato Pre-treated Aluminium Page 8 5. Metallic Powders: Pigment Types Leafing Aluminium Pigments (images: Inver) Leafing (brilliant, chrome effect) - Coated with silica acid to achieve leafing - effect (position on surface finish) Very small particles, Dv50 approx. 5 - 15µ Low grip and scratch resistance No weather resistance Flakes Dv50 = 18 Sorgente di Luce Light source Metallic powder Pre-treated Aluminium Substrato Page 9 5. Metallic Powders: Pigment Types Raw Materials for Metallic Effects: Pearl Effect Pigments Naturally or artificially produced mica flakes are the main component of all pearl effect pigments. Density of 2.7 to 3.1 g/cm3 Based on the naturally or artificially produced mineral mica, the flakes are treated with transparent metal oxides (TiO2, Fe2O3, Cr2O3) having a high reflection value. Weather-resistant owing to the coating of TiO2. Mica Metal oxide Page 10 (Scheme Inver / image: Tiger) 5. Metallic Powders: Pigment Types Colour Effects of Pearl Effect Pigments Blue Colour effects through interference Green Red Yellow Silver TiO2 Mica TiO2 TiO2 Mica Mica TiO2 TiO2 Mica Mica Colour effects through interference and absorption. Red Bronze Copper Fe2O3 Fe2O3 Fe2O3 Mica Mica Mica Page 11 Brown Green Gold Fe2O3 Fe2O3 TiO2 TiO2 Mica Mica Cr2O3 TiO2 Mica 5. Metallic Powders: Pigment Types Difference in Effect of Effect Pigments (Inver) Principle: The light is refracted, reflected and distributed diffusely over the different pigment lamina. Colour effects are generated by the superimposition of reflected light rays. Metal pigments Pearl effect pigments Light reflection Reflected and refracted light Light Sorgente di luce source Light source Sorgente di luce Powder layer Powder layer Page 12 6. Metallic Powder: Incorporation of the Pigments Dry blend Powder coating Bonding Pigment The bonding procedure does not improve the chemical resilience of the pigments. Scheme: TIGER Page 13 6. Metallic Powders: Incorporation of Pigment Differences in Effect dependent on Method of Incorporation Dry Blend (dry mixture) - Powder coating and pigment are mixed in the drum-tumbling machine - Pigment and powder lie next to one another as loose material - Cost-effective process - Risk of separation with application (no cloudy formations, delay in effect) Illustrations: - Left: microscopic view of metallic dry blend (Image: Inver) - Right: microscopic view of a metallic dry-blend with assignment of components (Image: TIGER) Pigment particles Page 14 Coating particles 6. Metallic Powders: Incorporation of Pigment Differences in Effect dependent on Method of Incorporation Bonding (sintering) - The pigment particles are bound to polymer particles - Recirculation of the finest particles - Distribution of particle sizes changes - More expensive (extra charge), but recovery possible Illustrations: - Left: microscopic view of bonded metallic powder coating (Image: Inver) - Right: microscopic view of a bonded metallic powder coating with assignment of components (Image: TIGER) Pigment Powder corn Page 15 7. Basics of processing Metallic Powders General Principles for coating Metallic Colours To avoid optical anomalies, a building project is handled by a single anodiser. Profiles and customer material (accessories, metal sheets, fittings) must be processed by one anodiser to ensure the finish is as uniform as possible. The surface finishes shown on colour charts and with samples are not binding for projects; they serve merely as a guide. When project orders are processed, Schüco sends finished samples with the metallic colour provided by the surface finisher for approval by the architects/investor as a binding basis for the surface finish order. Additional orders must be specified as such by the architects, stating the sample or name of the order wherever possible, to guarantee uniformity of colour (without ageing). Page 16 7. Coating of Metallic Powders Principles of electrostatic Powder Coating Vertical coating facility at a Schüco partner in Points to note with metallic powders: Germany (Schüco image) • Extraction only through the fluidisation unit and not from the box. • Use of same application technology (Corona or tribo technology) for all parts to be coated. • The hanging is critical (same alignment, precoating if necessary for difficult geometry, adjustment of belt speed). • Adherence to the curing conditions (powder manufacturer and Schüco SN 47): thick and thin-walled parts must not be hung haphazardly as this may result in uneven surface finishes. • The main visible surface should always be coated last; where there are several main visible surfaces, the best possible method of hanging and alignment needs to be found. Page 17 7. Surface Finishes using Metallic Powders Definition of Surface Finish Requirements Schüco delivers its surface finishes based on proven GSB and/or Qualicoat-approved metallic powders, supplemented by monitoring of the surface finish partner by Schüco (system finish). Additional security of surface finish by Schüco as part of the system finish warranty: - Application tests of new surface finishes on Schüco standard profiles (application) Links: Quality standards institutions - GSB: www.gsb-international.de - Qualicaot: www.qualicoat.net - AAMA: www.aamanet.org Schüco www.schüco.com - Access for architects - Download area Page 18 - Application test on function and negative effects with Schüco aids (cleaner, protective foiling) - Sample sheets for approval 8. Surfaces based on Metallic Powders Object Process Schüco suggests for larger building projects Additional protective steps for the optical (objects) the pre-agreed joint organisation of Results for Metallic Coatings of Objects: the coating powder: The metal builder provides the required total volume of the object to order the required Depending on the pigmentation of a metallic powder in the smallest number of productions. powder due to the general exiting tolerances in the finish process, it can not always be avoided to One object sshould be coated if possible just have visible differences in colour / effect (compare by one coater (Schüco material & customerSupplementary terms and conditions of sale and owned material) due to the used application delivery for surface finishing and associated technology. services of Schüco International KG § 6.9). In preparation of an order Schüco can check with the potential powder supplier upon request and will inform the customer accordingly. Written clearance of sample sheets by the metal builder to Schüco. Agreement for limiting samples out of production or preparation of a sample facade. Page 19 8. Surfaces based on Metallic Powders Current Metallic Finishes based on Powder Coating – all in High Durable Quality (photos: Schüco) MetallicLine Plus Cupper as Fine Texture (top) and smooth (bottom) Selection MetallicLine Plus as Fine Texture Page 20 MetallicLine Gold (top) and Buliding Bronce (below) with smooth texture WetLine Overview (Iron oxide) 8. Surfaces based on Metallic Powders Current Metallic Finishes based on Powder & Liquid Paint Coating (AnoLine DF) AnoLine Page 21 AnoLine FS (photo: Schüco) AnoLine DF 8. Surfaces based on Metallic Powders Current Schüco Metallic Surfaces developed in co-operation with powder suppliers AnoLine SanLine – Sandalor® Optik Trend colours Metallics – White Metallics AnoLine Anolok – UK Anodisation Optics Trend colours Metallics – iridescent Metallics Seite 22 9. Metallic Surface Finishes Typical problems with Metallic Surface Finishes (images: Inver/FEM) Different Application Technology Page 23 Different Layer Thickness 9. Metallic Surface Finishes Typical Problems (Images: Inver) Incorrect Cleaning Agent (corrosion) Page 24 Insufficient Mortar Resistance 10. Cleaning and Maintenance of Metallic Surface Finishes Notes Metallic surface finishes fulfil the following coating requirements: Protection of metallic base layer and decorative function Maintenance and cleaning is required in order to retain these protective qualities and to maintain value for as long as possible. Owing to the chemical nature of the pigments used to generate the metallic effect, metallic coatings must be maintained and cleaned carefully in accordance with the cleaning instructions. For more information, see the relevant trade associations: Gütegemeinschaft für die Reinigung von Metallfassaden e.V (GRM) (Quality Control Association for Cleaning of Metal Façades) Internet: www.grm-online.de Window & Façade Association Internet: http://window.de Page 25 11. Viewing and Acceptance of Metallic Surfaces Information Metallic Surfaces offer interesting decorative properties. Due to factors such as kind of effect, effect intensity, angle dependency (of effect), application geometry and part geometry, the resulting decorative impression may be different from a master sample. The viewing and acceptance of objects with coated surfaces including metallic surfaces is performed under diffuse day light at a 90° angle towards the building side in a distance of 5 m (outside surface) or 3 m (inside surface). The result is based on the primate of the eye, e.g. a uniform optic of the surface for each side is intended. Additional information is provided by: Verband der Fenster- & Fassadenhersteller e.V. (VFF) Informationen at: http://www.window.de/vff.html Page 26 12. Schüco System Finish Information Overview of available information from Schüco – Status 11/2014 Downloads via www.schueco.com: Architect info Pre-treatment Architect info Powder Coating Architect info Metallics Architect info Dirt repellent Coatings Architect info Liquid Paints Architect info Anodisation Videos Finish Methods Digitale Info via SCV: A wide series of information for current finish products is also available as PDF. Function and Service Information Schüco All Information are available as PDF in German or English. Page 27 Printed Information: Colour finishes for Aluminium (Colour Booklets) Edition Basic 07/2012 (Art. No. 63116) for often requested finishes used in end customer business such as RAL, Standard Metallics and Anodisation according to EURAS. Edition Advance 12/2014 (Art. No. 63118) contains also object surface options and special finish methods used mainly for objects. 13. Contact Details For additional information and support for the presented products, please contact the Service Centre Finish (SCV) Schüco International KG Karolinenstraße 1-15 33615 Bielefeld Tel.: Fax: 0521 / 783 - 0 0521 / 783 - 451 www.schueco.com info@schueco.com Page 28