Annals of Warsaw University of Life Sciences - SGGW )RUHVWU\DQG:RRG7HFKQRORJ\ʋ60- (Ann. WULS - 6**:)RUDQG:RRG7HFKQRO The influence of artificial weathering on abrasion resistance of selected wood species from South America AGNIESZKA -$1.2:6.$3$:(à ĩ85$:6.,$1'5=(- 0$=85(. 'HSDUWPHQWRI:RRG6FLHQFHDQG:RRG3URWHFWLRQ Warsaw University of Life Sciences Abstract The influence of artificial weathering on abrasion resistance of selected wood species from South America 7KH DUWLILFLDO ZHDWKHULQJ PHWKRG FRQVLVWLQJ RI DOWHUQDWLQJ VRDNLQJ ZRRG LQ ZDWHU GU\LQJ DW D temperature of 70 °C and UV radiation exposure was used to determine the influence of weathering on resistance to abrasion of garapa (Apuleia leiocarpa 9RJ 0DFEULGH FXPDUX Dipteryx odorata $XEO :LOG DQG tatajuba (Bagassa guianensis $XEO6HOHFWHGZRRGVSHFLHVZHUHRIVLPLODUVWUXFWXUHGHQVLW\DQGKDUGQHVV The results of artificial weathering are changes in the abrasion resistance. With the progressive artificial weathering abrasion resistance of wood changed gradually. In case of tatajuba and garapa wood resistance to abrasion was VLPLODUO\ ,Q FDVH RI JDUDSD ZRRG WKH ZLGHVW UDQJH RI FKDQJHV DIWHU ZHDWKHULQJ SURFHVV ZDV REVHUYHG ,W ZDV fouQGWKDWQRWRQO\ZRRGGHQVLW\GHWHUPLQHVZRRGDEUDVLYHUHVLVWDQFHEXWan LPSRUWDQWIDFWRULVZRRGVWUXFWXUH mainly arrangement of wood fibers. Keywords: DUWLILFLDOZHDWKHULQJgarapa (Apuleia leiocarpa 9RJ0DFEULGHFXPDUXDipteryx odorata $XEO :LOGDQGWDWDMXEDBagassa guianensis $XEODEUDVLRQUHVLVWDQFH. ,1752'8&7,21 The important factors determining use of wood terrace boards and flooring surface are not only aesthetic attractiveness in terms of cRORU JUDLQ DQG ILJXUH EXW LQ its good wearing properties such as abrasion resistance ['HVFKDQG'LQZRRGLH]. Aesthetics is formed by the visual impression oIWKHSDWWHUQVRIZRRGHQHOHPHQWVOD\RXWRI structure of applied wood speFLHVWKHLUFRORUDQGVXUIDFHfinishing quality. During outside exposition wood surfaces is subjected to changes in texture and color. Factors responsible for these changes are alternating DFWLRQV RI KXPLGLW\ DQG WHPSHUDWXUH SKRWR-chemical and biological processes as well as mechanical erosion caused by wind and rDLQIDOO >0DWHMDN @. Variability of weather conditions and prolonged exposure to them causes the process called wood weathering also referred to as an ageing. Wood weathering is a process of irreversible changes in appearance and properties caused by long-term acting of the weather conditionsVRODUUDGLDWLRQFRQWHQW of oxygen in DLUFKDQJHVLQWHPSHUDWXUHDQGKXPLGLW\DVVXPLQJQRGLUHFWLQIOXHQFHRIELRWLF factors [)HLVW&RORPHWDO:LOOLDPV]. During exposure in natural environmentLQLWLDOO\VPRRWKZRRGVXUIDFHEHFRPHVURXJK as wood fibers rise and wood cracks. This is accompanied by changes in chemical components [:LOOLDPV-DQNRZVND@$OORIWKHVHFKDQJHVRFFXUPDLQO\LQVXUIDFH OD\HURIZRRG5HVHDUFKRIFKHmical changes in wood represents explanation of degradation RI WKH RXWHU OD\HUV WDNLQJ SODFH LQ ZRRG GXULQJ H[SRVXUH WR QDWXUDO FRQGLWLRQV >)HLVW 'RQHJDQHWDO:LOOLDPV@/LJQLQFRQVWLWXWHV- % of wood tissue and due to phenolic naturH OLJQLQ DEVRUEV PRVW RI WKH 89 UDGLDWLRQ ZKLFK FRQVHTXHQWO\ FDXVHV LWV degradation. Lignin deprived of cellulose chain adhesives and coatings is also degraded as a UHVXOWRIRWKHUZHDWKHULQJIDFWRUVYDULDEOHDPELHQWFRQGLWLRQV Because of changes in wRRGVXUIDFHVGXULQJH[WHUQDOH[SRVLWLRQZHKDYHXQGHUWDNHQ to investigate the mechanical properties having a significant influence on the terrace boards XVDJH WKDW LV KDUGQHVV DQG DEUDVLRQ ZHDU UHVLVWDQFH RI WKH ZRRG VSHFLHV IURP 6RXWK America that arH RIWHQ IRXQG LQ 3ROLVK PDUNHW )XUWKHUPRUH Rbjective of this study was 61 determination and comparison the influence of artificial weathering (assuming the absence of ELRWLF LQWHUDFWLRQV DEUDVLRQ UHVLVWDQFH 7KH UHVHDUFK LQFOXGHV VHOHFWHG ZRRG VSHFLHV IURP 6RXWK$PHULFDJDUDSDFXPDUXWDWDMXED- wood often used in Europe for products dedicated WRRXWVLGHXVDJHVXFKDVWHUUDFHV 0$7(5,$/$1'0(7+2'6 Wood species selected for the research are deciduous hardwood species from South America WDE. This wood is of diffuse-porous structure. All of species are wood with irregular fibres DUUDQJHPHQW VWULSHG RU LQWHUORFNHG DUUDQJHPHQW RI ILEHUV Wood species selected for the research are a group of materials used for the production of elements used in external FRQGLWLRQVHOHYDWLRQWHUUDFHERDUGVJDUGHQIXUQLWXUHHWF Table 1. The research material Trade names and names according to EN 13556 (2005) Apuleia leiocarpa 9RJ0DFEULGH garapa* Bagassa guianensis Aubl. tatajuba Dipteryx odorata $XEO:LOG cumaru * Apuleia leiocarpa 9RJ0DFEULGHDUHQRWLQFOXGHGLQ(1 Latin names Origin South America Samples of each wood genus were taken from one board to obtain "identical sample". That method let to keep wood structure so the appearing changes in the artificial weathering SURFHVVZHUHWKHPDLQIDFWRUIRUWKHH[DPLQHGSURSHUWLHVJURXSVRIVDPSOHVZHUHWDNHQ from each species of wood. Tangential and radial wood surface was tested separately. Only longitudinal sections were tested because of the fact that in final product these sections GRPLQDWH 'LPHQVLRQV RI VDPSOHV ZHUH [[ PP (DFK JURXS ZDV LQWHQGHG IRU WKH research of different stages of weathering. Surfaces of wood had been sanded before the experiment began. The design of the artificial weathering cycle was based on literature [Matejak et al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thickness and loss RIPDVVRIWKHWHVWHGVDPSOHVDIWHUKXQGUHGUHYROXWLRQVRIWKHZKHHO7KHORDGDPRXQWHGWR JWHVWWHPSHUDWXUHZDVFORVHGWR&DQGDLUKXPLGLW\- 7KHDEUDVLRQWHVWZDV made before artificial weathering SURFHVVDIWHU0 and 40 cycles of artificial weathering. 3ULRU to the determination of DEUDVLYH ZHDU UHVLVWDQFH HDFK JURXS ZDV FRQGLWLRQHG LQ DLU DW D WHPSHUDWXUHFORVHWR &DQG5+7RFRPSDUHUHVLVWDQFHWRDEUDVLRQSHUFHQWDJH loss of mass was determinate. We decided to determine wood density according to ,62 )XUWKHUPRUH ZRRG KDUGQHVV ZHUH GHWHUPLQHG DFFRUGLQJ WR (1 7KHVHWHVWVZHUHFDUULHGRXW E\WKH%ULQHOOPHWKRGZLWKDKDUGQHVVWHVWHURIWKHFRPSDQ\&9,QVWUXPHQWV/'%7KH WHVWFRQVLVWHGRILQGHQWLQJDPPEDOOPDGHRIVWLOOLQWRWKHwooden element being subject WR WKH WHVW ZLWK WKH IRUFH RI N1 DQG GXULQJ WKH WLPH VSHFLILHG LQ WKH VWDQGDUG )RU HDFK LQGHQWDWLRQWKHKDUGQHVVZDVFDOFXODWHGLQDFFRUGDQFHWRWKHIRUPXOD 62 ZKHUH +%–%ULQHOOKDUGQHVV>03D@ F – loading forFH>1@ D – GLDPHWHURIVWHHOEDOO>PP@ d – diameter of the indentation [mm]. The number of indentations for each wood VSHFLHVZDVRQUDGLDOFURVVVHFWLRQDQG RQWDQJHQWLDOFURVVVHFWLRQ 5(68/76 Carrying out 40 cycles of the process of artificial weathering resulted in changes of the appearance of wood samples. AIWHUWKHILUVWF\FOHVZRRGVDPSOHVVXUIDFHEHFDPHURXJKDQG cracks occurred. Soaking wood in water resulted in raising wood fibers during drying and partial chipping of material (gentle rubbing the surfaces with a finger resulted in chipping of wood substance showing degradation of ligno-FHOOXORVLF EDFNERQH RI FHOO ZDOOV The roughest surface was observed in case of cumaru wood. 3UREDEO\ WKLV SKHQRPHnon was accompanied by an irregular fibres arrangement. The artificial weathering process caused the cracking of the wood samples. Dealing with the issue of weatheringDPRQJRWKHUV0DWHMDNHW DO >@ )HLVW >] :LOOLDPV [] WKH PDLQ UHDVRQ WKDW causes wood damage is sorption stress which occurs during rapid wetting and fast drying (running at high frequency RIFKDQJHVLQKXPLGLW\FDXVHZRRGFUDFNLQJ Artificial weathering process caused a color changes,QLWLDOO\WKHVXUIDFHRIWHVWZRRG samples became darker. The first cycles of artificial weathering caused no obvious change in FRORUEXWDIWHUHDFKVWDJHRIWKHSURFHVVGLIIHUHQFHVZHUHREVHUYHG- VDPSOHVEHFDPHGDUNHU which was probably the result of dissolved dye substances in deeper layerV DQG WKHQ depositing them on the surface of wood during drying. This phenomenon was confirmed by Donegan et al. [@ Williams [@DQG-DQNRZVND>@. Table 2. 5HVXOWVRIGHWHUPLQDWLRQGHQVLW\RIWHVWHGZRRGVSHFLHVLQEUDFNHWVWDQGDUGGHYLDWLRQZDVJLYHQ Name of wood Wood density kg·m- Cumaru Garapa Tatajuba * moisture content after conditioning LQDLUDWDWHPSHUDWXUHFORVHWR °C and r+ Table 3. 5HVXOWVRIGHWHUPLQDWLRQKDUGQHVVRIWHVWHGZRRGVSHFLHVLQEUDFNHWVWDQGDUGGHYLDWLRQZDVJLYHQ Name of wood Radial cross section Tangential cross section 03D Cumaru Garapa Tatajuba * moisture content after conditioning LQDLUDWDWHPSHUDWXUHFORVHWR °C and r+ 7HVWHGZRRGVSHFLHVVKRZVLPLODUOHYHORIGHQVLW\WDE$FFRUGLQJWR.U]\VLN>@DOO of tested wood species can be classed as very heavy wood. Effects of hardness tests showed 63 that in case of cumaru and garapa there is no significant difference between radial and WDQJHQWLDOFURVVVHFWLRQ WDE 2QO\LQFDVHRIWDWDMXEDZRRGGLIIHUHQFH EHWZHHQKDUGQHVV on tangential and radial cross section was found and confirmed with t-Student test. Comparison the effects of abrasive resistance test of untreated wood (percentage ORVVHVRIPDVVZHUHFRPSDUHG– WDELWFDQEHVDLGWKDWJDUDSDZRRGVKRZHGWKHKLJKHVW UHVLVWDQFH WR DEUDVLRQ WKH VPDOOHVW ORVV RI PDVV 7KLV SKHQRPHQRQ LV D OLWWOH VXUSULVLQJ taking account that garapa is not the heaviest wood in group of tested wood species. As it is NQRZQIURPOLWHUDWXUH>.U]\VLN@DEUDVLYHUHVLVWDQFHRIZRRGLVGHSHQGLQJRQGHQVLW\RI a material. )XUWKHUPRUH WKH KHDYLHVW WHVWHG ZRRG VSHFLHV - cumaru showed the smallest resistance to abrasion. It lets to make conclusion that not only wood density determines wood DEUDVLYH UHVLVWDQFH EXW WKH YHU\ LPSRUWDQW IDFWRU LV ZRRG VWUXFWXUH PDLQO\ DUUDQJHPHQW RI wood fibers (cumaru and tatajuba have striped fibres but garapa rather interlocked fibres. In case of cumDUXZRRGWKHURXJKHVWVXUIDFHZDVREVHUYHGEXWDIWHUDUWLILFLDOZHDWKHULQJZRRG surface became smoother in touch. The loose wood fibers crumbled out during the first cycles of artificial weathering and after that losses of mass were smaller. Table 4 5HVXOWVRIDEUDVLYHZHDUUHVLVWDQFHWHVWV– percentage loss of mass (in bracket standard deviation was JLYHQ Before artifical weathering After 20 cycles of artificial weathering After 40 cycles of artificial weathering radial cross section radial cross section Name of wood radial cross section tangential cross section tangential cross section tangential cross section Garapa Tatajuba * moisture content after conditioning LQDLUDWDWHPSHUDWXUHFORVHWR °C and r+ Cumaru In case of tatajuba and garapa wood resistance to abrasion was similarly. In case of JDUDSD ZRRG WKH ZLGHVW UDQJH RI FKDQJHV DIWHU ZHDWKHULQJ SURFHVV ZDV REVHUYHG ,W confirmed that artificial weathering caused gradually degradation of surfaces layer degradation of ligno-cellulosic backbone of cell walls and in case of garapa degradation was the most dynamic. After analysis of average value of percentage loss of mass it can be said that radial section is more resistant to wearing than tangential cross section. Only tatajuba wood did not confirm this relation. 1HYHUWKHOHVV RI WHVWHG ZRRG VSHFLHV ZLWK WKH DUWLILFLDO ZHDWKHULQJ SURFHVV DEUDVLYH UHVLVWDQFHZHUHZRUVW0RUHRYHULWZDVREVHUYHGWKDWDFFHOHUDWHGZHDWKHULQJKDVLQIOXHQFHRQ variability of resuOWVKLJKHUYDOXHRIFRHIILFLHQWYDULDWLRQIt can be caused by variability of grade degradation of wood surface. 64 CONCLUSIONS 7KHDUWLILFLDOZHDWKHULQJPHWKRGFRQVLVWLQJRIDOWHUQDWLQJVRDNLQJZRRGLQZDWHUGU\LQJDWD temperature of 70 °C and UV radiation exposure was used to determine the influence of weathering on resistance to abrasion of garapa (Apuleia leiocarpa 9RJ0DFEULGHFXPDUX (Dipteryx odorata $XEO :LOG DQG WDWDMXED Bagassa guianensis $XEO 6HOHFWHG ZRRG VSHFLHVZHUHRIVLPLODUVWUXFWXUHGHQVLW\DQGKDUGQHVV The results of artificial weathering are changes in the abrasion resistance. With the progressive artificial weathering abrasion resistance of wood changed gradually. In case of WDWDMXED DQG JDUDSD ZRRG UHVLVWDQFH WR DEUDVLRQ ZDV VLPLODUO\ ,Q FDVH RI JDUDSD ZRRG WKH widest range of changes after weathering process was observed. It was found that not only ZRRG GHQVLW\ GHWHUPLQHV ZRRG DEUDVLYH UHVLVWDQFH EXW very important factor is wood VWUXFWXUHPDLQO\DUUDQJHPHQWRIZRRGILEHUV 5()(5(1&(6 &2/20;&$55,//2)12*8(6)*$55,*A 3Structural analysis of photodegraded wood by meanV RI )7,5 VSHFWURVFRS\ 3RO\PHU 'HJUDGDWLRQ DQG 6WDELOLW\– '(6&+ +( ',1:22',( -0 7LPEHU 6WUXFWXUH 3URSHUWLHV &RQYHUVLRQ DQG8VH7KH0DF0LOODQ3UHVV/WG/RQGRQ '21(*$1 9 )$172==, - -285'$,1 & .(56(// . 0,*'$/ $ 635,1*$7( 5 722/(< - 8QGHUVWDQGLQJ H[WUDFWLYH EOHHGLQJ -RLQW &RDWLQJV)RUHVW3URGXFWV&RPPLWWHH 4. (1Wood and parquet flooring. Determination of resistance to indentation %ULQHOO7HVWPHWKRG (1,62-5XEEHU- or plastics-coated fabrics. Determination of abrasion resistance. Taber abrader. 6. )(,67:&2XWGRRU:RRG:HDWKHULQJDQG3URWHFWLRQ,Q 52:(//50 %$5%2855- HGV$UFKDHRORJLFDOZRRGSURSHUWLHVFKHPLVWU\DQGSUHVHUYDWLRQ Advances in Chemistry Series 3URFHHGLQJV RI WK PHHWLQJ RI WKH $PHULFDQ &KHPLFDO6RFLHW\ 6HSWHPEHU- /RV $QJHOHV:DVKLQJWRQ'&$PHULFDQ &KHPLFDO6RFLHW\&KDSWHU- 7. ),/621 3 '$:621-$1'2+ % ( 0$78$1$ / &RORULPHWULF DQG YLEUDWLRQDO VSHFWURVFRSLF FKDUDFWHUL]DWLRQ RI ZHDWKHUHG VXUIDFHV RI ZRRG DQG ULJLG polyvinyl chloride-wood flour composite lumber. Wood Science and Technology No - +2/= $ =XP $OWHUXQJVYHUKDOWHQ GHV :HUNVWRIIHV +RO] - HLQLJH $QVLFKWHQ 8QWHUVXFKXQJHQ(UJHEQLVVH+RO]WHFKQRORJLH- ,62 :RRG – Determination of density for physical and mechanical tests. ,QWHUQDWLRQDO2UJDQL]DWLRQRI6WDQGDUGL]DWLRQ JANKOWS.$ $ 7KH VWXG\ RI FKDQJHV LQ FRORU RI ZRRG DQJHOLP SHGUD (Hymenolobium VSDQGSLTXLDCaryocar VSGXULQJDUWLILFLDOZHDWKHULQJ$QQDOVRI Warsaw University of Live Science – 6**:)RUHVWU\DQG:RRG7HFKQRORJ\9RO - 0$7(-$.0 6WDU]HQLHGUHZQDLNRQVWUXNFMLGUHZQLDQ\FK3U]HP\Vá'U]HZQ\ - 0$7(-$.03232:6.$(6=(-.$ ( 9HUJOHLFKHQGH 8QWHUVXFKXQJHQ EHU 0HWKRGHQ GHV EHVFKOHXQLJWHQ $OWHUQV YRQ +RO] +RO]IRUVFKXQJ XQG +RO]YHUPHUWXQJ+HIW- 31-EN 'UHZQR RNUąJáH L WDUFLFD 7HUPLQRORJLD VWRVRZDQD Z KDQGOX drewnem w Europie 65 :,//,$06 5 6 )LQLVKLQJ RI :RRG ,Q :RRG KDQGERRN - Wood as HQJLQHHULQJPDWHULDO*HQ7HFK5HS)3/-*75-0DGLVRQ:,86'HSDUWPHQW RI$JULFXOWXUH)RUHVW6HUYLFH)RUHVW3URGXFW/DERUDWRU\ :,//,$06 5 6 :HDWKHULQJ RI ZRRG +DQGERRN RI ZRRG FKHPLVWU\ DQG wood composites. %RFD5DWRQ&5&3UHVV- Streszczenie: :Sá\ZSU]\VSLHV]RQHJRVWDU]HQLDQDĞFLHUDQLHGUHZQD wybranych gatunków ] APHU\NL 3RáXGQLRZHM 3UDFD GRW\F]\ ]PLDQ\ ZáDĞFLZRĞFL SRZLHU]FKQL GUHZQD garapa (Apuleia leiocarpa 9RJ0DFEULGHtonkowca wonnego (Dipteryx odorata $XEO:LOGi tataĪXE\ (Bagassa guianensis $XEO VSRZRGRZDQHM G]LDáDQLHP V]WXF]QHJR VWDU]HQLD Z\EUDQH GR EDGDĔ JDWXQNL GUHZQD FKDUDNWHU\]RZDá\ VLĊ ]EOLĪRQą VWUXNWXUą JĊVWRĞFL L WZDUGRĞFLą 0DMąFD V\PXORZDü G]LDáDQLH QDWXUDOQ\FK F]\QQLNyZ DWPRVIHU\F]Q\FK ]DVWRVRZDQD PHWRGD VWDU]HQLRZD SROHJDáD QD SU]HPLHQQ\P PRF]HQLX GUHZQD Z ZRG]LH VXV]HQLX Z WHPSHUDWXU]H & L QDĞZLHWODQLX SURPLHQLDPL ultrafioletowymi. 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