of HASE Thickener HISOL ÿLess syneresis ÿLess color floating ÿLess pigment settling ÿCost savings ÿAPEO free ÿMicrobe Resistant Alkali Swellable Associative Thickeners HISOL New thickeners HISOL 301, 303, 305, 307, 308 and 700 are HASE(hydrophobically modified alkali swellable emulsion) thickeners for water based paints, inks and putties. Compared with previous HISOL D HASE thickeners, New HISOL thickeners have excellent pigment wetting properties and show less syneresis of paints based on new HISOL thickeners during long term storage. The Main advantages of New HISOL thickener emulsions are the following. ÂPaints thickened with HISOL 301, 303, 305, 307 ÂPaints thickened with new HISOL thickeners and 308 thickeners show excellent syneresis and settling resistance in long term storage, exhibit no remarkable viscosity change in long term storage. They are stable under tropical and less color floating problem during drying. and freeze-thaw conditions. ÂPaints thickened with new HISOL thickeners are ÂBecause low dosages of new HISOL thickeners highly resistant to attack by microbes and their are enough to achieve the required paint enzymes, thereby eliminating viscosity loss. You viscosity, it is possible to improve water can design more biologically stable paints. sensitivity of the paints. ÂPaints thickened with new HISOL thickeners are less costly to achieve the same viscosity than paints thickened with HEC and other ÂN ew HISOL thickeners do not contain any APEO surfactants or additives. HASE thickeners. PHYSICAL PROPERTIES Appearance : milky white liquid emulsion Solid content : 29-31% Viscosity : 50 cPs max at 25oC Sp/Gr : 1.052 at 25oC pH : 2.5-4.5 Ionic charge : Anionic Surfactant : APEO Free 01 / 02 RHEOLOGICAL PROPERTIES 700 D201 D180 305 High D160 Stomer Viscosity (KU) D303 303 307 D108 D206 301 D105 D85 308 D65 Low D50 Low High High Shear Viscosity(P) Flow & Levelling Less roll spatter High film build Thixotropic flow Lower sagging High in can viscosity Comparison of HISOL HASE thickeners Selection Guide Grade HISOL D New HISOL Main Application Low Shear HISOL D160 HISOL D180 HISOL D201 HISOL 700 HISOL 305 Putties & Texture paints High in can viscosity paints Medium Shear HISOL D203 HISOL D108 HISOL D105 HISOL 303 HISOL 307 HISOL 301 Medium flow paints High Shear HISOL D206 HISOL 308 Good flow paints Among the low shear grades, the main application of HISOL 700 is for putties and texture paints, based on Styrene-Acrylic copolymer emulsion and Polyvinylacetate-Acrylate emulsion and HISOL 305 is for high in can viscosity paints. HISOL 301, 303 and HISOL 307 are for medium thickened with combination of HEC and new HISOL thickeners, they have good viscosity shear paints, and HISOL 308 is for good flow paints. In case of high PVC paints, the paints stability and less syneresis in long term storage. High in-can Reduce color Viscosity floating APEO free HISOL 700 Ā Ā Ā HISOL 305 Ā Ā Ā HISOL D201 Ā Ā Ā HISOL D180 Ā Ā Ā HISOL D160 Ā Ā Ā HISOL D105 Ā н Ā HISOL 301 Ā н Ā HISOL D203 HISOL 303 Ā Ā HISOL 307 Ā HISOL D85 Ā Ā HISOL D206 HISOL 308 Ā HISOL D65 Ā Ā Reduce spatter Ā Ā н HISOL D108 HISOL D50 Reduce Syneresis Paint flow Tropical Water stability resistance (St*) Product Name Ā Ā н н Ā н н Ā н н Ā Ā н н н н Ā Ā н Ā Ā Ā н Ā Ā н н н Ā Ā н н Ā Ā Ā Ā н н Ā Ā Ā н Ā Ā Ā ●Highly recommended ◯ Recommended St*Styrene-Acrylic paint MANUFACTURING OF THE PAINTS When new HISOL thickener emulsions meet HISOL thickener emulsions can be added not any base, they creat a gel. To save dispersing time, it is preferable to pre-dilute the HISOL only to the grinding stage in order to raise the viscosity during the grinding, but also to the let- thickeners with water before adding to the down stage, in order to get the desired final paint and to agitat slowly in the tank. viscosity. But when adding in the grinding After adding the HISOL thickeners, appropriate stage, it is preferable to add the AMP 95 rather than ammonia to maintain the viscosity, (amount CA 10% based on thickener weight) of because of high temperature of grinding media. (base ammonia or AMP95) should be added to get the (pH Up to 8). If pH is low, paints show abnormal rheology and worse viscosity stability. SAFETY AND HANDLING New HISOL thickener emulsions are slightly available. Handling should be available in well irritating to the skin and eyes and contact with these areas should be avoided. When handling, wear impervious rubber gloves and goggles/ ventilated place. Use stainless steel or plastic vessel when handling. Store in a closed container between facemask. For handling/operation where possible contact may occur, a safety shower 5í-40í Further detailed information can be found in MSDS. and eye wash station/facility should be Components High PVC interior paints based on HISOL 301-308 (Vinylacetate-Acrylic copolymer emulsion binder) Deionized water Control3000 HV3001 HV3002 HV3003 HV3004 HV3005 205.5 205.5 205.5 205.5 205.5 205.5 HIDIS40 2 2 2 2 2 2 Triton CF10 1 1 1 1 1 1 Nopco NXZ 2 2 2 2 2 2 Mergal K14 1.5 1.5 1.5 1.5 1.5 1.5 Tipure R900 50 50 50 50 50 50 Talc #400 60 60 60 60 60 60 OMYA CARB 10 320 320 320 320 320 320 Propylene glycol 10 10 10 10 10 10 Nopco NXZ 2 2 2 2 2 2 HISOL VC200 130 130 130 130 130 130 Deionized water 50 120 115 119 119 115 Natrosol 250HBR(3%) 80 - - - - - HISOL 305 - 10 - - - - Let down HISOL 301 - - 15 - - HISOL 303 - - - 11 HISOL 307 - - - - 11 - HISOL 308 - - - - - 15 Grind Ammonia 4 4 4 4 4 4 Texanol 12 12 12 12 12 12 HIQUE 388 Total - 70 70 70 70 70 70 Total 1000 1000 1000 1000 1000 1000 PVC, % 78.1 78.1 78.1 78.1 78.1 78.1 Stormer, equilibrated, KU 102.5 100.5 102.5 100.4 100.7 102.8 Tropical stability (60í 5days), KU ICI, poise(P) 100.3 97.2 105.2 104.3 104.6 104.2 1.7 1.3 1.4 1.4 1.6 1.6 03 / 04 Components High PVC interior paints Deionized water based oh HISOL 301-308 (Styrene-Acrylic copolymer emulsion binder) Grind Let down HA4005 205.5 205.5 205.5 205.5 205.5 2 2 2 2 2 Triton CF10 1 1 1 1 1 1 Nopco NXZ 2 2 2 2 2 2 Mergal K14 1.5 1.5 1.5 1.5 1.5 1.5 Tipure R900 50 50 50 50 50 50 Talc #400 60 60 60 60 60 60 OMYA CARB 10 320 320 320 320 320 320 Propylene glycol 10 10 10 10 10 10 Nopco NXZ 2 2 2 2 2 2 HISOL AC53 130 130 130 130 130 130 Deionized water Natrosol 250HBR(3%) HISOL 305 10 125 123 125 124 124 120 - - - - - - - 5 - HISOL 301 - - 7 HISOL 303 - - - HISOL 307 - - - HISOL 308 - - - - - - - 5 - - - 6 - - - 6 Ammonia 4 4 4 4 4 4 Texanol 12 12 12 12 12 12 70 70 70 70 70 70 1000 1000 1000 1000 1000 1000 PVC, % 78.1 78.1 78.1 78.1 78.1 78.1 Stormer, equilibrated, KU Tropical stability (60í5days), KU ICI, poise(P) 100.5 90.3 107.2 107.1 107.2 112.1 107.6 111.2 105.5 110.8 106.5 112.3 0.7 0.6 0.7 0.7 0.8 0.9 Deionized water Control700 MP701 MP702 MP703 MP704 MP705 106 106 106 106 106 106 HIDIS 40 8 8 8 8 8 8 Triton CF10 2 2 2 2 2 2 Nopco NXZ 2 2 2 2 2 2 Natrosol 250HBR(3%) 20 20 20 20 20 20 Propylene glycol 10 10 10 10 10 10 Megal K14 2 2 2 2 2 2 170 170 170 170 170 170 TRONOX CR828 Let down HA4004 2 Components Grind HA4003 205.5 Total (Styrene-Acrylic copolymer emulsion binder) HA4002 HIDIS40 HIQUE 388 Medium PVC exterior paints based oh HISOL 301-308 Control4000 HA4001 TALC #400 50 50 50 50 50 50 OMYA CARB 10 150 150 150 150 150 150 Deionized water 58 58 58 58 58 58 HISOL AC53 320 320 320 320 320 320 HIQUE 388 70 70 70 70 70 70 Texanol 10 10 10 10 10 10 Nopco 8034L 2 2 2 2 2 2 Ammonia 2 2 2 2 2 2 100 - - - - - HISOL 305 - 5 - - - - HISOL 301 - - 6 - - - HISOL 303 - - - 4 - - HISOL 307 - - - - 4 HISOL 308 - - - - - 6 1000 1000 1000 1000 1000 1000 Natrosol 250HBR(3%) Total PVC, % 50.4 50.4 50.4 50.4 50.4 50.4 Stormer, equilibrated, KU Tropical stability (60í5days), KU ICI, poise(P) 96.5 88.9 96.5 103.1 97.5 106.5 93.7 101.2 95.4 103.4 98.2 104.8 0.6 0.4 0.5 0.5 0.6 0.7 Putties & Texture paints based on HISOL 700 Water base putty Components Texture paint based PU101 Grind : Deionized Water Grind : 195.3 Deionized Water 205.3 HIDIS 40 5 HIDIS 40 5 Triton CF10 3 Triton CF10 3 Nopco NXZ 4 Nopco NXZ 4 Mergal K14 1.5 Mergal K14 1.5 Talc#400 120 TRONOX CR828 20 Omya Carb 10 580 Omya Carb 10 580 Let down : Let down : Propylene Glycol 10 Propylene Glycol 10 Nopco NXZ 3 Nopco NXZ 3 HISOL AC115 60 HISOL AC115 Deionized Water 5 Deionized Water 5 HISOL 700 10 HISOL 700 10 Texanol 2 Texanol Ammonia Total : 1.2 1,000,0 Solid contents(%) Viscosity(cps) 73.8 212,000 PH Suppliers of Raw Materials TE 201 Components 9.2 150 2 Ammonia 1.2 1,000,0 Total : Solid contents(%) Viscosity(cps) 67.6 80,000 PH 9.2 Name Function Supplier HIDIS 40 Dispersant HLC Triton CF10 Wetting Agent Dow Chemicals Nopco NXZ Defoamer San Nopco Korea Ltd. Mergal K14 Biocide Troy chemical TRONOX CR828 TiO2 TRONOX INCORPORATION Talc #400 Extender DongYang Materials Industrial Co. Ltd. Omya Carb 10 Extender Omya Korea HISOL AC115 Acrylic emulsion HLC HISOL VC200 Vinylacetate- Acrylic emulsion HLC HISOL AC53 Styrene-Acrylic emulsion HLC Texanol Coalescing agent Eastman Natrosol 250HBR Thickener Aqualon HIQUE 388 Opaque Polymer HLC 05 / 06 www.hankuck.co.kr SITE OF MANUFACTORY : 1ST INDUSTRIAL ESTATE, 321-21, GONGDAN-DONG, GUMI-SI GYEONGBUK KOREA TEL 82-54-465-2805, 2804 FAX 82-54-465-2802 HLC R&D CENTER : 1ST INDUSTRIAL ESTATE, 267-131, GONGDAN-DONG, GUMI-SI GYEONGBUK KOREA TEL 82-54-465-2806 FAX 82-54-465-5056 2015. HLC. Ltd. Note: The statements made herein are based on our research and the research of others, and believed to be accurate. No guarantee of their accuracy is made. However, and the products discussed are sold without warranty, express or implied, including warranty of merchantability and fitness for use of this material, and upon condition that purchasers shall make own tests to determine the suitability of such products for their particular purposes. The user assumes all risk of use or handling, whether or not in accordance with any action arising of the material being supplied shall be limited to replacement of material.