HASE Thickener HISOL

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of
HASE Thickener HISOL
ÿLess syneresis
ÿLess color floating
ÿLess pigment settling
ÿCost savings
ÿAPEO free
ÿMicrobe Resistant
Alkali Swellable
Associative Thickeners
HISOL
New thickeners HISOL 301, 303, 305, 307, 308 and 700 are HASE(hydrophobically
modified alkali swellable emulsion) thickeners for water based paints, inks and
putties. Compared with previous HISOL D HASE thickeners, New HISOL thickeners
have excellent pigment wetting properties and show less syneresis of paints based
on new HISOL thickeners during long term storage.
The Main advantages of New HISOL thickener emulsions are the following.
ÂPaints thickened with HISOL 301, 303, 305, 307
ÂPaints thickened with new HISOL thickeners
and 308 thickeners show excellent syneresis
and settling resistance in long term storage,
exhibit no remarkable viscosity change in long
term storage. They are stable under tropical
and less color floating problem during drying.
and freeze-thaw conditions.
ÂPaints thickened with new HISOL thickeners are
ÂBecause low dosages of new HISOL thickeners
highly resistant to attack by microbes and their
are enough to achieve the required paint
enzymes, thereby eliminating viscosity loss. You
viscosity, it is possible to improve water
can design more biologically stable paints.
sensitivity of the paints.
ÂPaints thickened with new HISOL thickeners
are less costly to achieve the same viscosity
than paints thickened with HEC and other
ÂN ew HISOL thickeners do not contain any
APEO surfactants or additives.
HASE thickeners.
PHYSICAL PROPERTIES
Appearance : milky white liquid emulsion
Solid content : 29-31%
Viscosity : 50 cPs max at 25oC
Sp/Gr : 1.052 at 25oC
pH : 2.5-4.5
Ionic charge : Anionic
Surfactant : APEO Free
01 / 02
RHEOLOGICAL
PROPERTIES
700
D201
D180
305
High
D160
Stomer
Viscosity
(KU)
D303
303
307
D108
D206
301
D105
D85
308
D65
Low
D50
Low
High
High Shear Viscosity(P)
Flow & Levelling
Less roll spatter
High film build
Thixotropic flow
Lower sagging
High in can viscosity
Comparison of
HISOL HASE thickeners
Selection Guide
Grade
HISOL D
New HISOL
Main Application
Low Shear
HISOL D160
HISOL D180
HISOL D201
HISOL 700
HISOL 305
Putties & Texture paints
High in can viscosity paints
Medium Shear
HISOL D203
HISOL D108
HISOL D105
HISOL 303
HISOL 307
HISOL 301
Medium flow paints
High Shear
HISOL D206
HISOL 308
Good flow paints
Among the low shear grades, the main application
of HISOL 700 is for putties and texture paints,
based on Styrene-Acrylic copolymer emulsion
and Polyvinylacetate-Acrylate emulsion
and HISOL 305 is for high in can viscosity paints.
HISOL 301, 303 and HISOL 307 are for medium
thickened with combination of HEC and new
HISOL thickeners, they have good viscosity
shear paints, and HISOL 308 is for good flow
paints. In case of high PVC paints, the paints
stability and less syneresis in long term storage.
High in-can Reduce
color
Viscosity
floating
APEO
free
HISOL 700
Ā
Ā
Ā
HISOL 305
Ā
Ā
Ā
HISOL D201
Ā
Ā
Ā
HISOL D180
Ā
Ā
Ā
HISOL D160
Ā
Ā
Ā
HISOL D105
Ā
н
Ā
HISOL 301
Ā
н
Ā
HISOL D203
HISOL 303
Ā
Ā
HISOL 307
Ā
HISOL D85
Ā
Ā
HISOL D206
HISOL 308
Ā
HISOL D65
Ā
Ā
Reduce
spatter
Ā
Ā
н
HISOL D108
HISOL D50
Reduce
Syneresis Paint flow
Tropical
Water
stability
resistance
(St*)
Product
Name
Ā
Ā
н
н
Ā
н
н
Ā
н
н
Ā
Ā
н
н
н
н
Ā
Ā
н
Ā
Ā
Ā
н
Ā
Ā
н
н
н
Ā
Ā
н
н
Ā
Ā
Ā
Ā
н
н
Ā
Ā
Ā
н
Ā
Ā
Ā
●Highly recommended
◯ Recommended
St*Styrene-Acrylic paint
MANUFACTURING
OF THE PAINTS
When new HISOL thickener emulsions meet
HISOL thickener emulsions can be added not
any base, they creat a gel. To save dispersing
time, it is preferable to pre-dilute the HISOL
only to the grinding stage in order to raise the
viscosity during the grinding, but also to the let-
thickeners with water before adding to the
down stage, in order to get the desired final
paint and to agitat slowly in the tank.
viscosity. But when adding in the grinding
After adding the HISOL thickeners, appropriate
stage, it is preferable to add the AMP 95 rather
than ammonia to maintain the viscosity,
(amount CA 10% based on thickener weight) of
because of high temperature of grinding media.
(base ammonia or AMP95) should be added to
get the (pH Up to 8).
If pH is low, paints show abnormal rheology
and worse viscosity stability.
SAFETY AND
HANDLING
New HISOL thickener emulsions are slightly
available. Handling should be available in well
irritating to the skin and eyes and contact with
these areas should be avoided. When handling,
wear impervious rubber gloves and goggles/
ventilated place.
Use stainless steel or plastic vessel when
handling. Store in a closed container between
facemask. For handling/operation where
possible contact may occur, a safety shower
5í-40í Further detailed information can be
found in MSDS.
and eye wash station/facility should be
Components
High PVC interior paints
based on HISOL 301-308
(Vinylacetate-Acrylic
copolymer emulsion
binder)
Deionized water
Control3000
HV3001
HV3002
HV3003
HV3004
HV3005
205.5
205.5
205.5
205.5
205.5
205.5
HIDIS40
2
2
2
2
2
2
Triton CF10
1
1
1
1
1
1
Nopco NXZ
2
2
2
2
2
2
Mergal K14
1.5
1.5
1.5
1.5
1.5
1.5
Tipure R900
50
50
50
50
50
50
Talc #400
60
60
60
60
60
60
OMYA CARB 10
320
320
320
320
320
320
Propylene glycol
10
10
10
10
10
10
Nopco NXZ
2
2
2
2
2
2
HISOL VC200
130
130
130
130
130
130
Deionized water
50
120
115
119
119
115
Natrosol 250HBR(3%)
80
-
-
-
-
-
HISOL 305
-
10
-
-
-
-
Let down HISOL 301
-
-
15
-
-
HISOL 303
-
-
-
11
HISOL 307
-
-
-
-
11
-
HISOL 308
-
-
-
-
-
15
Grind
Ammonia
4
4
4
4
4
4
Texanol
12
12
12
12
12
12
HIQUE 388
Total
-
70
70
70
70
70
70
Total
1000
1000
1000
1000
1000
1000
PVC, %
78.1
78.1
78.1
78.1
78.1
78.1
Stormer, equilibrated, KU
102.5
100.5
102.5
100.4
100.7
102.8
Tropical stability
(60í 5days), KU
ICI, poise(P)
100.3
97.2
105.2
104.3
104.6
104.2
1.7
1.3
1.4
1.4
1.6
1.6
03 / 04
Components
High PVC interior paints
Deionized water
based oh HISOL 301-308
(Styrene-Acrylic
copolymer emulsion
binder)
Grind
Let down
HA4005
205.5
205.5
205.5
205.5
205.5
2
2
2
2
2
Triton CF10
1
1
1
1
1
1
Nopco NXZ
2
2
2
2
2
2
Mergal K14
1.5
1.5
1.5
1.5
1.5
1.5
Tipure R900
50
50
50
50
50
50
Talc #400
60
60
60
60
60
60
OMYA CARB 10
320
320
320
320
320
320
Propylene glycol
10
10
10
10
10
10
Nopco NXZ
2
2
2
2
2
2
HISOL AC53
130
130
130
130
130
130
Deionized water
Natrosol
250HBR(3%)
HISOL 305
10
125
123
125
124
124
120
-
-
-
-
-
-
-
5
-
HISOL 301
-
-
7
HISOL 303
-
-
-
HISOL 307
-
-
-
HISOL 308
-
-
-
-
-
-
-
5
-
-
-
6
-
-
-
6
Ammonia
4
4
4
4
4
4
Texanol
12
12
12
12
12
12
70
70
70
70
70
70
1000
1000
1000
1000
1000
1000
PVC, %
78.1
78.1
78.1
78.1
78.1
78.1
Stormer, equilibrated, KU
Tropical stability
(60í5days), KU
ICI, poise(P)
100.5
90.3
107.2
107.1
107.2
112.1
107.6
111.2
105.5
110.8
106.5
112.3
0.7
0.6
0.7
0.7
0.8
0.9
Deionized water
Control700
MP701
MP702
MP703
MP704
MP705
106
106
106
106
106
106
HIDIS 40
8
8
8
8
8
8
Triton CF10
2
2
2
2
2
2
Nopco NXZ
2
2
2
2
2
2
Natrosol 250HBR(3%)
20
20
20
20
20
20
Propylene glycol
10
10
10
10
10
10
Megal K14
2
2
2
2
2
2
170
170
170
170
170
170
TRONOX CR828
Let down
HA4004
2
Components
Grind
HA4003
205.5
Total
(Styrene-Acrylic
copolymer emulsion
binder)
HA4002
HIDIS40
HIQUE 388
Medium PVC exterior
paints based oh HISOL
301-308
Control4000 HA4001
TALC #400
50
50
50
50
50
50
OMYA CARB 10
150
150
150
150
150
150
Deionized water
58
58
58
58
58
58
HISOL AC53
320
320
320
320
320
320
HIQUE 388
70
70
70
70
70
70
Texanol
10
10
10
10
10
10
Nopco 8034L
2
2
2
2
2
2
Ammonia
2
2
2
2
2
2
100
-
-
-
-
-
HISOL 305
-
5
-
-
-
-
HISOL 301
-
-
6
-
-
-
HISOL 303
-
-
-
4
-
-
HISOL 307
-
-
-
-
4
HISOL 308
-
-
-
-
-
6
1000
1000
1000
1000
1000
1000
Natrosol 250HBR(3%)
Total
PVC, %
50.4
50.4
50.4
50.4
50.4
50.4
Stormer, equilibrated, KU
Tropical stability
(60í5days), KU
ICI, poise(P)
96.5
88.9
96.5
103.1
97.5
106.5
93.7
101.2
95.4
103.4
98.2
104.8
0.6
0.4
0.5
0.5
0.6
0.7
Putties & Texture
paints based
on HISOL 700
Water base putty
Components
Texture paint based
PU101
Grind :
Deionized Water
Grind :
195.3
Deionized Water
205.3
HIDIS 40
5
HIDIS 40
5
Triton CF10
3
Triton CF10
3
Nopco NXZ
4
Nopco NXZ
4
Mergal K14
1.5
Mergal K14
1.5
Talc#400
120
TRONOX CR828
20
Omya Carb 10
580
Omya Carb 10
580
Let down :
Let down :
Propylene Glycol
10
Propylene Glycol
10
Nopco NXZ
3
Nopco NXZ
3
HISOL AC115
60
HISOL AC115
Deionized Water
5
Deionized Water
5
HISOL 700
10
HISOL 700
10
Texanol
2
Texanol
Ammonia
Total :
1.2
1,000,0
Solid contents(%)
Viscosity(cps)
73.8
212,000
PH
Suppliers of Raw
Materials
TE 201
Components
9.2
150
2
Ammonia
1.2
1,000,0
Total :
Solid contents(%)
Viscosity(cps)
67.6
80,000
PH
9.2
Name
Function
Supplier
HIDIS 40
Dispersant
HLC
Triton CF10
Wetting Agent
Dow Chemicals
Nopco NXZ
Defoamer
San Nopco Korea Ltd.
Mergal K14
Biocide
Troy chemical
TRONOX CR828
TiO2
TRONOX INCORPORATION
Talc #400
Extender
DongYang Materials Industrial Co. Ltd.
Omya Carb 10
Extender
Omya Korea
HISOL AC115
Acrylic emulsion
HLC
HISOL VC200
Vinylacetate- Acrylic emulsion
HLC
HISOL AC53
Styrene-Acrylic emulsion
HLC
Texanol
Coalescing agent
Eastman
Natrosol 250HBR
Thickener
Aqualon
HIQUE 388
Opaque Polymer
HLC
05 / 06
www.hankuck.co.kr
SITE OF MANUFACTORY :
1ST INDUSTRIAL ESTATE, 321-21, GONGDAN-DONG, GUMI-SI GYEONGBUK KOREA
TEL 82-54-465-2805, 2804
FAX 82-54-465-2802
HLC R&D CENTER :
1ST INDUSTRIAL ESTATE, 267-131, GONGDAN-DONG, GUMI-SI GYEONGBUK KOREA
TEL 82-54-465-2806 FAX 82-54-465-5056
2015. HLC. Ltd.
Note: The statements made herein are based on our research and the research of others, and believed to be accurate. No guarantee of their accuracy is made.
However, and the products discussed are sold without warranty, express or implied, including warranty of merchantability and fitness for use of this material,
and upon condition that purchasers shall make own tests to determine the suitability of such products for their particular purposes. The user assumes all risk of
use or handling, whether or not in accordance with any action arising of the material being supplied shall be limited to replacement of material.
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