MSE 445 Corrosion of Metals - Syllabus Carl Altstetter , <caltstet@illinois.edu> 302 MSEB, 217-333-4985 Topic I. Introduction a) costs of corrosion b) types of corrosion c) corrosion rates Page Numbers 1 - 39 II. Electrochemical Thermodynamics 40-50 a) electrochemical reactions b) electrochemical cells c) cell potential d) reference electrodes e) Faraday Law f) electrical work, Gibbs free energy g) mass action, Nernst law h) effects of temperature and concentration i) heat and entropy changes f) effects of pressure, sensors III. Electrochemical Kinetics a) reaction rates b) charge transfer c) polarization, Tafel plot d) diffusion and drift, e) reaction overvoltage 75 - 86 IV. Electrochemical Devices a) batteries b) fuel cells V. Electrochemical Corrosion a) mixed potential 86-108 b) Evans diagram c) effect of corrosion variables d) measurements 65-74, 143-162 Topic Page Numbers e) spectroscopy 109-113, 162-166 f) electrochemical noise g) galvanic series 168-198 h) cathodic protection i) Pourbaix diagram 50 - 64 j) passivity 116 - 142 k) stainless steels l) localized corrosion 199-232 m) microbial-induced corrosion 372-381 VI. Corrosion Control 291-334 a) change of environment b) selection of alloy c) cathodic protection 439-476 d) inhibitors 503-512 e) coatings 477-503 VII. Effects of Environment on Mechanical Behavior 235-290 a) stress corrosion cracking b) hydrogen embrittlement c) corrosion fatigue d) liquid metal embrittlement VIII. High Temperature Corrosion a) description b) mechanisms c) variables 408-438 IX. Case Studies a) stainless steel hot water tank b) ductile iron pipe corrosion c) disposal of radioactive waste d) rebar corrosion e) hip joint prosthesis failure f) lithium ion batteries _____________________________________________________________________________________ Text: Denny Jones Principles and Prevention of Corrosion Prentice-Hall Inc. Upper Saddle River, NJ, 1996 Grading: The grade in this course will be based on two one-hour exams and a term paper, which will count the same as an hour exam. The first hour exam will be at 12 PM on March 19, 2015. Graduate students registered for 4 hours of credit will be required to compile a comprehensive bibliography on the topic of their term paper. The bibliography should include all references on the topic after the year 2004.