Asphalt and Asphalt Concrete Dr. Kimberly Kurtis School of Civil Engineering Georgia Institute of Technology Atlanta, Georgia Some Ancient Asphalt History Asphalt materials have been used since 3500BC Waterproofing: boats, vessels for carrying liquids Adhesive and mortar Roads (1st evidence of Asphalt paving, Bablyon ~600BC) Trinidad Lake Asphalt Basket boats http://www.ancientroute.com/resource/Asphalt.htm Asphaltic mortar in walls at Babylon Native Asphalt Sources 144 acre -Trinidad Lake Lake Maricaibo in Venezuela (formerly) La Brea tar pits in California Underground Athabascan tar sands in Canada La Brea Asphalt History 1852 - French place 1st modern natural asphalt pavement 1816 - Scottish engineer John MacAdam introduces paving method using large stones bound with tar or asphalt 1868 - 1st hot mix pavement (with tar binder) placed in US designed by NB Abbott 1876 - Pennsylvania Avenue is paved using TLA 1885 - Automobile is invented http://www.asphaltinstitute.org/faq/lakeasph.htm Asphalt Stats US produces 30-35M tons asphalt/year 500-550M tons asphalt pavement placed per year 70% used for paving 22% used for roofing Other uses include coatings, tiles Sustainability Of the 100M tons of AC pavement removed annually in the US, 80% is recycled. Terminology Bitumen (ASTM D8) - a class of black or dark colored cementitious substances, natural or manufactured, composed primarily of high molecular weight hydrocarbons; completely insoluble in carbon disulfide (CS2). Includes both tar and asphalt Asphalt - A viscous cementitious material composed principally of high molecular weight hydrocarbons (typically 300-2000 g/mol) Asphalt Concrete - A complex (composite) material consisting of a mixture of asphalt cement and mineral aggregates Terminology Terminology Tar Product of destructive distillation of coal, petroleum, wood, sugar Odor Does not dissolve in petroleum products Asphalt Product of fractional distillation of petroleum No odor Will dissolve in petroleum products Fractional Distillation Lower MW, Lower viscosity Higher MW, Higher viscosity Properties of Asphalt Cement Composition is variable, depending on source C 80-87% H 9-11% O 2-8% N 0-1% S 0.5-7% Trace metals 0-0.5% CnH2n+bXd where n ranges from 25-150 X may be S,N,O, trace metals d is usually small b may be negative C84H97S3.2O2.5 for n=84, b=-71, d=5.7 One asphalt cement may contain many different kinds of molecules of varying size, chemistry, and geometry Properties of Asphalt Cement Composition of the asphalt influences binder behavior and performance of the asphalt concrete Asphaltenes - larger, discrete solid (black) inclusions; high viscosity component Resins - solid or semisolid at room temp; fluid when heated, brittle when cold Oils - colorless liquid; low viscosity component Aging Substantial changes occur in the structure,composition, and mechanical behavior of asphalt due to: Volatilization of light HC fractions Oxidation Physical hardening These processes can increase the asphalt viscosity and decrease ductility of asphalt and asphalt concrete. “VISCOSITY”, in simplest sense, is the resistance to flow Aging Aging can occur during mixing, placing, and service. Volatilization - prevalent during hot mixing Oxidation - slow process generally; occurs over time occurs more readily in warmer environments and in poorly compacted pavements Physical Hardening - most pronounced at T<0C Temperature/Viscosity Relationships Viscosity - “resistance to flow” - a fundamental material property relating the rate of shear strain (γ or dγ/dt) in a fluid to the applied shear stress (τ) τ = η(dγ/dt) for an ideally viscous material (Newtonian fluid) η given in units of Poise (P) 1P = 1x10-1 Pascal sec (Pa s) = 1 (g/cm) s Chapter 7 Young book Viscosity Water Motor oil Asphalt Lava η= 1x10-3 Pa s, at room temp = 1 = 105 to 107, at service temps = 1, when heated = 1011-1012 LOW HIGH Viscosity: Newtonian Fluids Newtonian fluid - linear relationship between shear stress and shear strain rate at a given T. (e.g., air, ethanol, water is close) τ η The slope is the viscosity dγ/dt Viscosity: Non-Newtonian Fluids τ Shear-thinning or “pseudoplastic” fluid - Viscosity decreases with increasing dγ/dt (e.g., polymer melts, paints) Apparent viscosity dγ/dt dγ/dt Viscosity: Non-Newtonian Fluids τ Shear-thickening fluid - Viscosity increases with increasing dγ/dt (e.g., clay slurries, cornstarch in water) dγ/dt Apparent viscosity Shear-thinning fluids are more common than shear-thickening fluids. dγ/dt Viscosity: Non-Newtonian Fluids Viscoplastic or “yield stress” fluid Does not flow until a critical or yield stress is applied; below the critical stress, it behaves like a solid (e.g., toothpaste, fresh concrete) τ Bingham fluid το dγ/dt Viscosity Asphalt cements exhibit Newtonian and Non-Newtonian behavior Asphalt Viscosity HMA Asphalt Viscosity 330-340oF 275-310oF Asphalt Viscoelasticity At low temp or low loading duration, elastic behavior At higher temp or long loading duration, viscous behavior dominates At most service temps, viscoelastic behavior is observed True fluid - flows when it is subjected to a shear field and stress, and ceases as soon as the stress is removed. viscous Ideal solid - when subjected to a stress recovers its original state as soon as the stress is removed. elastic Viscoelastic materials - have some characteristics of both a solid and a liquid. Temperature/Viscosity Relationships More viscous/more stiff @ lower T Less viscous/more flowable @ higher T Rutting Rutting - channelized deformation under traffic loading Shoving - pushing of mixture under loading, stopping Cracking - brittle failure due to fatigure, aging, or temperature Shoving Fatigue Cracking Low Temperature Cracking Extended transverse cracking, initiating at the pavement surface, is typical of low temperature cracking. This type of cracking is due to: • Contraction of asphalt concrete at lower temperatures • Restraint to this shrinkage • Tensile stress generated greater than pavement tensile strength CTE of asphalt is greater than that of aggregate => binder selection important in resisting this form of cracking Measuring Physical Properties • • • • Asphalt cements have traditionally been graded according to: Penetration (PEN) on AC and AR Viscosity on asphalt cement (AC) Viscosity on aged residue (AR) Performance Grading Penetration Test Penetration of 100g weight in 5s at 25C (77F) is measured in units of 0.1mm (e.g., 70 PEN=7mm penetration) 100 g After 5 seconds Initial + Fast, simple, low cost test - Empirical; not related to property; similar PEN values can yield wide range of behavior; effect of T not considered Penetration Grades Specifications for Asphalt Cement by Penetration Graded Test 40-50 60-70 85-100 120-150 200-300 Penetration, 25 oC, 100 g, 5 sec. Ductility, 25 oC, 5 cm/min, cm Flash point, COC, oC Soluibility in trichloroethylene, % 40-50 100 min 232 99.0 60-70 100 min 232 99.0 85-100 100 min 232 99.0 120-150 100 min 219 99.0 200-300 -----177 99.0 0.5 50 50 1.0 50 75 1.5 46 100 1.5 40 100 Test on residue from Thin-Film Oven Test: Loss on heating, % maximum 0.5 Penetration, % of original, min 50 Ductility, 25 oC, 5 cm/min, min Viscosity Grades AC grades are based on measurements of absolute viscosity of asphalt tested at 140 oF AR grades are based on the absolute viscosity tested at 140oF of asphalt after being aged in a rolling thin-film oven The RTFO test (ASTM D2872) is made by placing a 50cm3 asphalt cement sample in a cylindrical flat-bottomed pan 5.5” of inside diameter and 3/8” depth. The asphalt layer is about 1/8” deep. The sample and container are placed on a shelf, which rotates approximately 5 to 6 revolutions per minute, in a ventilated oven maintained at 325oF for 5 hr. The asphalt cement is then poured into a standard container used for the penetration test or the viscosity test. Viscosity Tests • • • • The viscosity test utilizes a gravity-flow capillary viscometer. This viscometer is mounted in a thermostatically controlled, constant-temperature bath; for kinematic viscosity: 135C or 275F for absolute viscosity: at 60C or 140F With the viscometer mounted in the bath, asphalt is poured into the large opening of the viscometer until it reaches the filling line. The filled tube remains in the bath at test temperature for a specified period of time to make sure that the tube and asphalt are at the same temperature. A slight pressure is applied to the large opening of the tube, or a slight vacuum to the small opening, thus causing the asphalt to start flowing over the siphon section just above the filling line. Gravity causes the asphalt to flow downward in the vertical section of capillary tubing. A timer is started when the asphalt reaches the first timing mark and is stopped when it reaches the second mark. The time interval, multiplied by a calibration factor for the tube, determines viscosity of the asphalt cement in units of centistokes (Kinematic) or poises (Pa s) (Absolute) AC Grades Specifications for Asphalt Cement by Viscosity Grade Test Viscosity, 60 oC (140 oF), poises AC-2.5 AC-5 AC-10 AC-20 AC-30 AC-40 250 ±50 500±100 1000±200 2000±400 3000±600 4000±800 Viscosity, 135 oC, Cs minimum Penetration, 25 oC, 100 g, 5 sec. Flash point, COC, oC minimum Soluibility in trichloroethylene, % 125 220 162 99.0 Test on residue from Thin-Film Oven Test: Loss on heating, % maximum Viscosity, 60 oC, poises 1000 100 Ductility, 25 oC, 5 cm/min, min 175 140 177 99.0 250 80 219 99.0 300 60 232 99.0 350 50 232 99.0 1.0 2000 100 0.5 4000 75 0.5 8000 50 0.5 12000 40 400 40 232 99.0 0.5 16000 25 1 Poise = 1 Pa s = 0.672 lb./(ft.s) = 1g/(cm s) 1 Centistoke (Cs) = 1 mm2/s AC Grading + Established test method + Measures a fundamental material property + Can be performed at maximum pavement service temperature + No effects of aging - More expensive equipment than for PEN - More technician skill required - Not applicable for non-Newtonian fluids - Wide range in behavior for same AC grade AR Grades Specifications for Asphalt Cement by AR Grades Test Viscosity, 60 oC (140 oF), poises AR-1000 AR-2000 AR-4000 AR-8000 AR-16000 1000±250 2000±500 4000±1000 8000±2000 16000±4000 Viscosity, 135 oC, Cs minimum Penetration, 25 oC, 100 g, 5 sec. % of original penetration Ductility, 25 oC, 5 cm/min, min Flash point, COC, oC minimum Soluibility in trichloroethylene, % 140 65 100 205 99.0 200 40 40 100 219 99.0 275 25 45 75 227 99.0 AR Grades + Established test method + Measures a fundamental material property + Represents asphalt properties after hot mixing + Limited, controlled aging - More expensive equipment than for PEN, AC - More technician skill required than for PEN - Not applicable for non-Newtonian fluids - Wide range in behavior for same AR grade 400 20 50 75 232 99.0 550 20 52 75 238 99.0 Comparison of Grading Schemes Performance Grade Research under the Strategic Highway Research Program (SHRP)’s Superpave program lead to the introduction of Performance Grades in 1993. Addresses concerns with earlier grading schemes: • PEN value does not correlate to a material property • AC, AR grades rely on tests performed at T higher than service T; do not reliably predict performance • PEN and viscosity are measured at 2 different temperatures Summary of PG Tests Procedure/Equipment Purpose Dynamic shear rheometer (DSR) Measure properties at high and intermediate service temperatures Rotational viscometer (RV) Measure properties at high construction temperature Bending beam rheometer (BBR) Direct tension tester (DTT) Measure properties at low service temperature Rolling thin film oven (RTFO) Simulate hardening at construction Pressure aging vessel (PAV) Simulate aging under long-term service Performance Grade PG XX YY XX = 7-day maximum pavement temperature, C 52-70C in 6C increments YY = minimum expected pavement temperature, C in 6C increments Example: PG 64-16 Average 7-day maximum pavement temperature in summer near 64C, and minimum pavement temperature in winter near -16C. Considers rutting at high T and cracking at low T Modifications to Asphalt Cement • Cutbacks - allow easy placement without high T • Emulsions - allow easy placement without high T, lower toxicity/fire hazard • Air-blown asphalt - less susceptible to T Cutbacks Volatile components are mixed with asphalt cement to make a liquid product. After volatilization, asphalt binder remains. Slow Curing (SC): Asphalt cement mixed with a low volatile oil/fuel. SC-70, SC-250, SC-800, SC-3000 Medium Curing (MC): Asphalt cement mixed with a solvent of intermediate volatility, such as kerosene. Uses a softer asphalt base than RC cutbacks. MC-30, MC-70, MC-250, MC-800, MC-3000 Rapid Curing (RC): Asphalt cement mixed with a volatile solvent, such as gasoline or naphtha. Uses a harder asphalt base than MC cutbacks. RC-70, RC-250, RC-800, RC-3000 Gradation based kinematic viscosity measured at 140F. Ex. Viscosity of MC-250 is 250+20% centistokes Cutbacks RC cutback asphalt is used primarily for surface treatments and tack coat. MC cutbacks asphalt is typically used for prime coat, surface treatments, and stockpile patching mixes. SC cutbacks may be used as surface spray for dust control (least common). Cutbacks Asphalt Emulsions Asphalt emulsions = water + asphalt + emulsifying agent = suspension of asphalt in water or water in asphalt; may be cationic, anionic, nonionic Asphalt Emulsions Some advantages: • Like cutbacks, asphalt emulsions can be use with hot or cold aggregate • Unlike asphalt cements, an be used on dry, damp, or wet aggregate • Avoids fire and toxicity issues associated with cutbacks Applications include: cold in-place recycling, cold mixing, tack coats, surface treatment, patching Air Blown Asphalt Air is blown through asphalt at 400-500F; Oxygen in air reacts with HC chains to form water (steam); chains repolymerize forming heavier,harder, more temperature-resistant materials. H …-C-C-H H …-C-C-H H O H …-C-C-C=C + H2O H longer chains Grading of air blown asphalt is based on the softening point of the material. ASTM D-2398 defines 4 grades, Type I (57-66 C), Type II (70-80C), Type III (85-96) and Type (99-107 C). Asphalt Concrete Asphalt Concrete VMA VMA = voids in the mineral aggregate = Vsample-Vagg VMA(%) = (Vsample-Vagg)/Vsample x 100% VMA filled with asphalt = (Va/VMA)x100% Where Va is the volume of absorbed asphalt VMA Calcs (Example) Calculate the percent voids and VMA in a compacted mixture with a 144 lb/ft3 unit weight with: Ingredients % total aggregate Effective SG Coarse agg 70% 2.70 Fine agg 25% 2.65 Filler 5% 2.60 Percent asphalt =5% with SGasphalt=1 VMA Calcs (Example) MASS 0 0.05x144lb/ft3=7.2lb/ft3 0.05(0.95)x144=6.8lb/ft3 0.25(0.95)x144=34.2lb/ft3 0.70(0.95)x144=95.8lb/ft3 Σ 144lb/ft3 VOLUME Air 1-(0.12+0.04+0.21+0.57) = .06 Asphalt 7.2lb/ft3/(1x62.4lb/ft3)=0.12 Filler 6.8/(2.60x62.4) =0.04 Fine Agg 34.2/(2.65x62.4) =0.21 Coarse Agg 95.8/(2.70x62.4) =0.57 Σ 1 ANS. 6% Air VMA = 1-(.04+.21+.57)=0.18 or 18% Another Example EXAMPLE Certain distresses are appeared on a newly constructed asphalt pavement and an engineering evaluation is commissioned to assess the problem. The following data are obtained based on the laboratory testing of the asphalt concrete cores removed from the pavement. a. The bulk specific gravity of the cores is determined (2.584) by measuring the weight of the core in air and in water. b. The core is then heated to soften the asphalt mix and the core is broken into small pieces. The voidless specific gravity of the asphalt mix is determined (2.677) c. After that, the asphalt mix is burned in a high temperature oven and the asphalt content (4.5% of the total mass) is determined based on the weight loss from the testing d. The bulk specific gravity of aggregate (2.885) is determined from the aggregate after the asphalt is burned out. e. The gravity of the asphalt cement (1.022) used in the mix is provided. Determine the air void content, VMA and percent asphalt absorbed of the asphalt mix. Example Vma = Volume of voids in mineral aggregate Vmb = Bulk volume of compacted mix Vmm = Voidless volume of mix Va = Volume of air Vb = Volume of asphalt Vba = Volume of absorbed asphalt Vsb = Volume of mineral aggregate Vse = Volume of mineral aggregate (by effective specific gravity) Solution: Air Content Assume 1000 gram asphalt mix (total mass) Asphalt content by wt. of mix = 4.5% = 45 g Aggregate by weight of mix = 1000 – 45 = 955g Determine air voids Va/Vmb. Vmb =Bulk volume of compacted mix =1000/2.584 = 387.00cm3 Vmm=Voidless volume of mix =1000/2.677 = 373.55cm3 13.45 cm3 AIR VOID CONTENT = (Vmb- Vmm)/ Vmb = 13.45/387 = 3.5% Solution: Asphalt Absorption Asphalt Absorption: ( Wt. of Asphalt Absorbed)/ (Wt. of Agg.) Volume of absorbed asphalt=Volume of mineral aggregate Volume of mineral aggregate (by effective specific gravity) Vba = Vsb - Vse Vsb = Volume of mineral aggregate = 955/2.885 = 331.02cm3 Vse = Vmm - Vb = Voidless volume of mix - Volume of asphalt = 373.55 - 45/1.022 = 373.55 - 44.02 = 329.52cm3 Vba = 331.02 - 329.52 = 1.5cm3 (1.5cm3 x 1.022 g/cm3)/955g x 100% = 0.16% = Asphalt Absorption Solution: VMA VMA = (Vmb – Vsb) / Vmb x 100% = (Bulk volume of compacted mix- Vol Agg)/Bulk Vol x100% = (387.00 – 331.02) / 387.00 x 100 = 14.46% or VMA can be determined by VMA = (Va + Vb - Vba)/Vmb x 100% = (Vol of air + Vol of asphalt - Vol asphalt absorbed)/Bulk Vol x100% = (13.45 + 44.02 - 1.5)/387 = 14.46% Aggregate Properties affecting Stability Gradation - want to maximize point-to-point contact for stability -> dense gradation -> some applications for one-size or gap-graded aggregate Aggregate Properties affecting Stability Surface Texture - much of the strength of the asphalt concrete is derived from mechanical interlock between aggregate particles; crushed rock with much angularity is preferred for strength and stability Aggregate Properties affecting Wetting Wetting - adsorption of asphalt molecules on the aggregate surface • Surface Texture- rougher surface more difficult to wet initially, but once wetted, asphalt adheres more strongly • Moisture Content- polar water molecules can replace longer asphalt chains at aggregate surface • Porosity - want 0.5% minimum porosity for good adhesion • Surface Chemistry - hydrophobic aggregate (ex. Dolomites) are more easily wetted by asphalt than water; converse is true for hydrophilic aggregate (ex. Siliceous aggregate) Proportioning Asphalt Concrete Mixtures OBJECTIVE: to proportion an economical mixture which is stable, flexible, durable, impermeable, fatigue resistant, skid resistant, and workable. However, it is not always possible to optimize all of these properties. Thus, compromises must be made. Proportioning Asphalt Concrete Mixtures However, it is not always possible to optimize all of these properties. Thus, compromises must be made. Proportioning Asphalt Concrete Mixtures Definitions of Desirable Properties Stability: ability of pavement to resist deformation under applied loads • Affected ability of aggregate to distribute loads through point to point contact • Stability improved with an angular, rough textured, strong aggregate with a dense grading • Want just enough asphalt to coat aggregate to provide adhesion. If asphalt content is too high, it will act as a lubricant and reduce particle-to-particle contact between the aggregate. Definitions of Desirable Properties Flexibilty: ability of pavement to withstand deflections and bending (caused by long-term settlement of the base or subgrade layers) without cracking. • Flexibility is maximized with an open-graded aggregate • Flexibility increasing with a higher asphalt content Conflict, then, between requirements for stability and flexibility! Definitions of Desirable Properties Durability: ability to resist disintegration due to weathering (oxidation and stripping) and the abrasive action of traffic. • Durability is maximized when aggregate particles are completely covered with asphalt and no air voids exist which would facilitate the entry of water, air, or light. Because of durability considerations, air content is limited to 5% maximum, and typically ranges from 3-5%. Definitions of Desirable Properties Impermeability: resistance to passage of air and water into the pavement or through it is dependent on the content and interconnectivity of the voids in the mixture. • Impermeability is maximized at a higher asphalt content, with dense aggregate gradations, and good compaction Definitions of Desirable Properties Fatigue Resistance: ability of the mixture to resist failure or fracture under repeated traffic loading. • Mixtures with higher asphalt content and densely graded aggregate generally have greater fatigue resistance than those with lower cement contents and open graded aggregate. Definitions of Desirable Properties Skid Resistance: • Skid Resistance is maximized at lower asphalt contents • Vehicles are more likely to skid when excess asphalt is present on the pavement surface • ‘flushing’ - migration of asphalt to wearing surface; can occur when air content is too low, such that when additional compaction of the pavement occurs during loading, asphalt cement has no voids left to fill and flows to surface. Definitions of Desirable Properties Workability: the ease with which a paving mixture can be placed and compacted • Workability is maximized with a higher binder content and rounder aggregate Those features that improve workability may decrease stability and skid resistance. Mixture Design Three commonly accepted methods: • Marshall method (ASTM D1559) • Hveem method (ASTM D1560) • Superpave method In addition, some states have their own methods. Marshall Method Select Agg Select Asphalt Select Asphalt Content Test End 1. Select aggregate blend to meet gradation and other requirements (ASTM D3515). 2. Select and evaluate asphalt cement. 3. Estimate desired asphalt content to meet requirements for: stability durability flexibility skid resistance workability 4. Prepare 3 samples each at estimated asphalt content and at +0.5% and +1%. • Calculate unit weight (density), % air voids, and VMA • Measure Marshall stability and flow Marshall Stability and Flow The "stability" value represents the maximum load in lbs. the sample can bear under this loading condition, while the "flow" value represents the deformation, in 0.01 in., of the sample at the maximum load. • High stability => high shear strength • Small flow => more brittle • Large flow => more ductile Marshall Method 4. (Cont.) • Analyze results by plotting % asphalt vs. density, stability, flow, air void content, and VMA • Determine % asphalt by weight by taking average % asphalt for these values: - Highest Marshall stability - Highest unit weight - Air content at middle of allowable range (~4%) Marshall Method (4.75+5.25+4.25)/3=4.75 Marshall Method 5. Determine the stability, flow, air voids content, VMA of the mix at the optimum asphalt content from the graphs and compare with the Marshall mix acceptance criteria specified established by highway and government agencies according to the local service conditions. Iterate, if necessary. Superpave Mix Design • One outcome of SHRP’s Superpave (Superior Performing Pavement) research • Developed to connect mix design parameters to predicted performance of the asphalt concrete mixture • Mixtures designed to resist or control 3 primary forms of distress in asphalt pavements: permanent deformation or “rutting” (PD) fatigue cracking low temperature or themal cracking • Hence, this is a more mechanistic approach to mix design Superpave Mix Design Advantages: • Mixture properties and performance are connected (Steps 2&3) • Basic material properties are measured, rather than relying on empirical measures (Steps 2&3) • Seasonal variations are considered (Step 3) • Achieve improved understanding of which mixture parameters influence which mixture properties and which performance measures (Steps 2&3)