Table 8.1 Magnetic quantities and their units. Magnetic quantity Symbol Definition Magnetic field; magnetic induction Magnetic flux B F = qv ! B "# $" = Bnormal $A Magnetic dipole moment Bohr magneton % m# %m = I A &# & = e!/2me. Magnetization vector Magnetizing field; Magnetic field intensity Magnetic susceptibility Absolute permeability Relative permeability Magnetic permeability Inductance Magnetostatic energy density M Units Comment T = tesla = webers m-2 Wb = weber Produced by moving charges or currents and acts on moving charges or currents. $" is flux through $A and Bnormal is normal to $A. Total flux through any closed surface is zero. Experiences a torque in B and a net force in a nonuniform B. Magnetic moment due to the spin of the electron. & = 9.27!10-24 A m2 Net magnetic moment in a material per unit volume H is due to external conduction currents only and is the cause of B in a material. A m2 H A m2 or J T-1 Magnetic moment A m-1 per unit volume A m-1 H = B/%o – M 'm M = 'm H None %o c = [(o%o]-1/2 %r %r = B / (%oH). H m-1 = Wb m-1 A-1 None %# % = %o %r H m-1 Not to be confused with magnetic moment. L Evol L = ")otal / I dEvol = H dB H (henries) J m-3 Total flux threaded per unit current. dEvol is the energy required per unit volume in changing B by dB. Relates the magnetization of a material to the magnetizing field H. A fundamental constant in magnetism. In free space %o = B/H. From Principles of Electronic Materials and Devices, Second Edition, S.O. Kasap (© McGraw-Hill, 2002) http://Materials.Usask.Ca Table 8.2 Classification of magnetic materials. Type 'm 'm vs. T (typical values) T independent Negative and small Diamagnetic (–10-6) Paramagnetic Negative and large (–1) Positive and small, *10-5 – 10-4) Positive and small (10-5) Ferromagnetic Positive and very large Antiferromagnetic Positive and small Ferrimagnetic Positive and very large Below a critical temperature Independent of T Comment and examples Atoms of the material have closed shells. Organic materials, e.g. many polymers; covalent solids, e.g. Si, Ge, diamond; some ionic solids, e.g. alkalihalides, some metals e.g. Cu, Ag, Au. Superconductors Due to the alignment of spins of conduction electrons. Alkali and transition metals. Curie or Curie-Weiss Materials in which the constituent atoms have a law permanent magnetic moment, e.g. gaseous and liquid oxygen, ferromagnets (Fe), 'm = C / (T–TC) antiferromagnets (Cr) and ferrimagnets (Fe3O4) at high temperatures. Ferromagnetic below May possess a large permanent magnetization and paramagnetic even in the absence of an applied field. above the Curie Some transition and rare earth metals, Fe, Co, Ni, temperature Gd, Dy Antiferromagnetic Mainly salts and oxides of transition metals e.g. below and MnO, NiO, MnF2, and some transition metals, +– paramagnetic above Cr, Mn. the Neel temperature Ferrimagnetic below May possess a large permanent magnetization and paramagnetic even in the absence of an applied field. above the Curie Ferrites. temperature From Principles of Electronic Materials and Devices, Second Edition, S.O. Kasap (© McGraw-Hill, 2002) http://Materials.Usask.Ca Table 8.3 Properties of the ferromagnets Fe, Co, Ni and Gd. Fe Co Ni Gd Crystal structure BCC HCP FCC HCP Bohr magnetons per atom 2.22 1.72 0.60 7.1 Msat(0) (MA m-1) 1.75 1.45 0.50 2.0 Bsat = %o Msat (T) 2.2 1.82 0.64 2.5 TC 770 ,C 1043 K 1127 ,C 1400 K 358 ,C 631 K 16 ,C 289 K From Principles of Electronic Materials and Devices, Second Edition, S.O. Kasap (© McGraw-Hill, 2002) http://Materials.Usask.Ca Table 8.4 Selected soft materials and some typical values and applications (Wh is the hysteresis loss, energy dissipated per unit volume per cycle in hysteresis losses, J m-3 cycle-1, typically at Bm = 1 T). Magnetic Material %oHc (T) Bsat (T) Br (T) %ri %rmax Wh Typical applications IDEAL SOFT 0 Large 0 Large Large 0 2.2 <0.1 150 104 250 2.0 0.5-1 103 104 – 4!105 30-100 2!10-7 0.7-0.8 <0.1 105 106 <0.5 5!10-6 0.86 <0.1 8!103 105 <0.1 Transformer cores, inductors, electrical machines, electromagnet cores, relays, magnetic recording heads etc. Large eddy current losses. Generally not preferred in electrical machinery except in some specific applications (e.g., some electromagnets and relays) Higher resistivity and hence lower eddy current losses. Wide range of electrical machinery (e.g., transformers etc.) High permeability, low loss electrical devices, e.g. specialty transformers, magnetic amplifiers Low-loss electrical devices, audio transformers, HF transformers, recording heads, filters etc. 2!10-6 1.6 <10-6 105 20 Low-loss transformer cores 10-5 0.4 <0.01 5!103 <0.01 HF low-loss applications. Low conductivity ensures negligible eddy current losses. HF transformers, inductors (pot cores, E and U cores etc.), recording heads. Iron <10-4 (commercial grade, 0.2% impurities) Silicon iron <10-4 (Fe: 2-4%Si) Supermalloy (79Ni-15Fe5Mo-0.5Mn) 78 Permalloy (78.5%Ni21.5%Fe) Glassy metals Fe-Si-B Ferrites Mn-Zn ferrite 2!103 From Principles of Electronic Materials and Devices, Second Edition, S.O. Kasap (© McGraw-Hill, 2002) http://Materials.Usask.Ca Table 8.5 Hard magnetic materials and typical values. Magnetic Material %oHc (T) Br (T) (BH)max -3 (kJ m ) Examples and Uses IDEAL HARD Large Large Large Permanent magnets in various applications Alnico (Fe-Al-NiCo-Cu) 0.19 0.9 50 Wide range of permanent magnet applications Alnico (Columnar)) 0.075 1.35 60 Strontium ferrite (anisotropic) 0.3-0.4 0.36-0.43 24-34 dc motors, starter motors, loudspeakers, telephone receivers, various toys Rare earth cobalt e.g. Sm2Co17 (sintered). 0.62-1.1 1.1 150-240 Servo motors, stepper motors, couplings, clutches, quality audio headphones etc. NdFeB magnets 0.9-1.0 1.0-1.2 200-275 Wide range of applications, small motors (e.g. in hand tools), walkman equipment, CD motors, MRI body scanners, computer applications Hard particles --Fe2O3 0.03 0.2 Audio and video tapes, floppy disks From Principles of Electronic Materials and Devices, Second Edition, S.O. Kasap (© McGraw-Hill, 2002) http://Materials.Usask.Ca Table 8.6 Selected examples of Type I and Type II superconductors. Critical fields are close to absolute zero (obtained by extrapolation). Type I for pure and clean elements. Type I Sn Hg Ta V Pb Nb Tc (K) 3.72 4.15 4.47 5.40 7.19 9.2 Bc (T) 0.030 0.041 0.083 0.14 0.08 0.198 Type II Nb3Sn Nb3Ge Ba2–xBrxCuO4 Hg-Ba-Ca-Cu-O Y-Ba-Cu-O Bi-Sr-Ca-Cu-O YBa2Cu3O7 (Bi2Sr2Ca2Cu3O10) Tc (K) 18.05 23.2 30 - 35 93 - 95 Bc2 (Tesla) at 0 K 24.5 38 ~150 ~300 -2 Jc (A cm ) ~ 107 at 0 K 122 130 - 135 104 - 107 From Principles of Electronic Materials and Devices, Second Edition, S.O. Kasap (© McGraw-Hill, 2002) http://Materials.Usask.Ca Table 8.7 Selected examples of flexible magnetic storage media based on coatings of particulate mat Typical values. Particulate matter Typical application %oMr (T) %oHc (T) Comment --Fe2O3 Audio tapes (Type I) 0.16 0.036 Widely used particles --Fe2O3 Floppy disk 0.07 0.03 Co(--Fe2O3) Video tape 0.13 0.07 CrO2 Audio tapes (Type II) 0.16 0.05 CrO2 Video tape 0.14 0.06 Fe Audio tape (Type IV) 0.30 0.11 Cobalt impregnated --Fe2O3 particles More expensive than --Fe2O3 High coercivity and magnetization. To avoid corrosion, the particles have to be treated (expensive) From Principles of Electronic Materials and Devices, Second Edition, S.O. Kasap (© McGraw-Hill, 2002) http://Materials.Usask.Ca Table 8.8 Selected examples of thin films in magnetic storage media; typical values. Thin Film Deposition %oMs (T) %oHc (T) Comment and typical or potential application Co-(Rare earth) Sputtering in vacuum 0.7-0.8 0.05-0.07 Longitudinal magnetic recording media. Hard disks. Co-Cr alloys Sputtering in vacuum 0.4-0.7 0.03 Perpendicular magnetic recording media . Co(--Fe2O3) Sputtering in vacuum 0.3 0.07-0.08 Longitudinal magnetic recording media. Co-Ni-P Electroplating 1 0.1 Longitudinal magnetic recording media. From Principles of Electronic Materials and Devices, Second Edition, S.O. Kasap (© McGraw-Hill, 2002) http://Materials.Usask.Ca