A Presentation for Power-Gen Asia 1-3 September 2015, Bangkok Thailand Reversing Ash Buildup Problems in SCR Reactors with Ash Sweepers Robin Chen Power Generation Group Martin Engineering China ABSTRACT This presentation will look at how an ash sweeper system can solve many of the problems with ash accumulation currently experienced in many SCR’s. Industry experts estimate that ash buildup issues affect as many as 58% of the Selective Catalytic Reduction (SCR) systems. The trend in the power generation industry has been to combat these SCR ash piling problems by replacing the catalyst with larger openings. The idea is simple: the larger the opening the less likely the ash is to build up. The problem is that by doing this, the SCR loses surface area which is critical for the removal of NOx. In addition the reduced surface area shortens catalyst life and increases ammonia usage. Ash sweepers provide a periodic discharge of compressed air across the top of the catalyst layer, to prevent buildups and return ash to the gas stream. The development of the ash sweeper system has allowed power plants to reverse the trend and even install smaller pitch catalyst, while increasing both NOX removal and catalyst life. In addition this solution offers a lower capital investment requirement. This paper will outline the success results in two different installation with ash sweeper systems. INTRODUCTION: BUILDUPS IN SCRS Many coal fired power plants now have installed a reactor for a Selective Catalytic Reduction— an SCR-- as a pollution control device. The SCR uses ammonia and catalyst to convert the nitrogen oxides –the NOx—in the flue gas into nitrogen and water. 1 But inside the SCR, fly ash from the combustion exhaust drops out of the exhaust and collects on the layers of catalyst. This reduces the SCR’s efficiency, because the NOx must contact the catalyst to cause the reaction. It also leads to ammonia passing through the SCR without reacting, called “ammonia slip.” The unmixed ammonia will form ammonia bisulfate (ABS). ABS can cause a sticky and very corrosive buildup, which leads to blockages and corrosion issues in the air heaters and ESP’s. Typical ash accumulation on the catalyst inside an SCR. The effects of the buildup can be significant. Past papers have been presented which indicated the buildup in the air heater can cost over a million dollars per year in thermal efficiency. Buildup in the SCR also leads to increased gas velocities through the system, which increases erosion and thus shortens catalyst life. And this buildup also leads to an increase in pressure drop, which increases fan power consumption. In addition, the accumulation of this fly ash can shorten the life of the catalyst, closing the passages, and leading to erosion of those passages that remain open. Industry experts estimate that buildup issues affect as many as 58% of the Selective Catalytic Reduction (SCR) systems. This buildup not only occurs in the SCR but also in the duct work leading to the SCR. Buildup in duct work is becoming an increasing important safety issue since in the recent past two years ducts have collapsed in the power industry. Fighting Buildups with Sonic Horns To reduce these penalties in efficiency and in operating costs, plants have used several techniques to reduce and or cleanup (mitigate) the ash accumulations. Sonic horns, which use the energy of high intensity, low frequency sound to keep dust in suspension, have been accepted as the best choice for cleaning by the suppliers of SCR systems. Sonic horns installed on each layer of catalyst in the SCR will reduce fly ash buildup and improve the plant’s pollution control. The horns generate a burst of sound at frequent intervals to prevent the buildup of particulates across the catalyst face. They prevent buildup, and should not be used to try to knock down hardened accumulations. The typical spacing between horns on an SCR is 9 to 12 feet apart—that is, between two-and-ahalf and four meters. The horns are driven with plant compressed air, typically supplied at 80-90 psi at 60 to 70 cfm. But the Problem Persists But the operation of sonic horns does not always eliminate the problems with ash buildup. Often the cause can be poor gas flow distribution, which allows a large amount of ash to drop out in a concentrated area, much like a river where a sand bar will starts on an inside bend where the flow slows. This large concentration overwhelms the sonic horns. 2 To minimize these buildups and the problems they cause, engineers conceived of using blasts of air to remove these concentrations, suspending the particles in the air so they can move through the SCR. To supply this blast of air, we proposed to apply ash sweepers. The ash sweeper systems may be used as a replacement for, or a supplement to, the sonic horns. So What Is An Ash Sweeper? Based on air cannon technology, an ash sweeper is a reservoir of plant compressed air, held behind an actuator valve. When the valve is triggered, the stored air is released out of the tank as an eruption. The air is discharged through outlets nozzles mounted in the walls of vessels. Following discharge, the exhaust valve closes, and the air reservoir typically then automatically refills with air to await the next controlled release. A number of different air cannon systems are available, including "individual tank” air cannons, which each serve a single opening into the vessel, and “multiple port” systems, which feed several outlets alternately from a single air storage tank. Used in industrial applications since the 1970's, air cannons are generally installed to improve the discharge of bulk materials from storage or the flow of material through a process vessel. Air cannons have a long history of success in high temperature applications such as cement kiln preheater towers and clinker coolers. Consequently, engineers were confident the ash sweepers could operate in the high temperature and dusty conditions inside an SCR. Ash sweepers on an SCR Ash sweepers are usually installed on first level of catalyst–the area that captures the most ash— providing overlapping coverage with sonic horns. The ash sweepers are placed four to six feet apart, with the discharge nozzles placed directly below the bell of the sonic horns. “Multiple port” ash sweeper system Ash sweeper nozzles are placed to discharge across the top of the catalyst to sweep ash particle back up into the gas flow. In a combined cleaning system, the ash sweepers should discharge at the start of the horn cycle, to break any adhered material loose. The horn continues to sound after the ash sweeper has fired, to keep material in suspension. 3 This combined system of combining ash sweepers with sonic horns to prevent ash accumulation and improve efficiency has now been tried in several coal-fired power plants in North America. The following are reports on two of these cases. The first discusses installing ash sweepers on an SCR; the second covers ash sweepers installed to clear a ductwork passage. Combined cleaning system composed of sonic horns and ash sweepers. CASE 1: TECO BIG BEND STATION Tampa Electric, a subsidiary of TECO Energy, operates five power plants in Florida. The largest plant is Big Bend Power Station, located across Tampa Bay in Hillsborough County near the community of Apollo Beach. Big Bend Power Station has four coal-fired generating units with a combined output of more than 1,700 megawatts. The first unit began service in 1972; the second and third generating units were added in 1973 and 1976, respectively; with the fourth unit coming online in 1985. An additional natural gasand fuel oil-fired unit was installed in 2009. TECO Big Bend Power Station The units burn a high-sulfur Eastern bituminous coal, which at times is blended with up to 20% pet coke in the plant’s four boilers. Over the years, pet coke has proven to be troublesome in SCR, by causing buildup and poisoning the catalyst. In 2007, TECO began to retrofit SCRs to the four boilers at Big Bend station to ensure compliance with emission permit limits. This installation was described in an article Big Bends Multi-Unit SCR Retrofit, published in March 2010 edition of Power Magazine. As that article pointed out, adding the SCR’s into the existing plant confines provided “particularly complex challenges.” Installed in the ‘high dust’ location before the precipitator, the four SCRs were engineered by Sargent & Lundy and each equipped with roughly one million pounds of 6.9 pitch Cormetech honeycomb catalyst. Due to the limited real estate, and the existing plant configuration, a less-thanideal gas flow path led to problems. Although sonic horns had been incorporated in the overall design, the Big Bend SCRs still had major build-ups of ash on several of the top layers of the catalyst. Buildups on the front wall of the SCR required cleaning four times per year; at times, the buildup would cover 50% of the catalyst surface. Ash accumulation inside the SCR at Big Bend 4 In many of these cleanings, the plant was forced to clean each passage through the “honeycomb catalyst individually by poking out ash with a welding rod. The cost and time during outages to remove the build-up was significant, and the buildups increase the amount of “ammonia slip” through the SCR, and so increased the amount of ammonia consumed and hence the SCR’s cost of operation. After a review of the problem and the options for solution, the plant agreed to try the installation of ash sweepers on the SCR to control these buildup problems. Two eight-port multi-port ash sweeper systems supplied by Martin Engineering were installed in November 2011. These systems serve a total of 16 fan-jet nozzles spaced across the top layer of one SCR. In addition, all the sonic horns installed on the SCR were rebuilt. These horns suffered from a buildup of ABS and some had ceased working. Horn sections suffering from ABS buildup were replaced, and all sound generators were rebuilt. Insuring proper operation of the sonic horns is important to success of the combined cleaning system. Multiport ash sweeper system installed on SCR at Big Bend Station Fan jet nozzles installed inside the SCR Big Results at Big Bend In a shutdown at the end of three months of run time, the plant evaluated the performance of the combined cleaning system. An inspection of the SCR at the end of February 2012 showed the top layer of catalyst had virtually no build-up of ash. This led plant officials to investigate and verify savings derived from the installation of the ash sweepers systems. Their calculations included a significant reduction in SCR cleaning costs, as shown in Table 1. Reduced buildup inside SCR after installation of ash sweeper system 5 Table 1. SCR Cleaning Costs at TECO Big Bend Date of Outage Days in Labor Operation Cost Prior to Cleaning Vacuum Truck Cost BEFORE March 2011 March 2011 September 2011 October 2011 37 9 36 50 $18,701 $17,053 $10,897 $21,849 $14,629 $18,426 $11,146 $27,789 AFTER March 2012 June 2012 47 10 $9931 $5439 $9463 $5560 Table 2 compares outages categorized as similar, based on the length of operating time leading to the outage. This Table 2 comparison indicates that cleaning the SCR following the installation of the ash sweeper systems required less than 50 percent of the labor and truck expense as the experience “before installation.” Table 2. Comparing SCR Cleaning Costs based on Length of Operation Before Installation October 2011 After Installation March 2012 Labor “Run Cost Time” (Days) Comparison A 50 $21,849 47 $9,931 Vacuum Truck Cost Total Savings $27,789 $9,463 $ Saved $11,918 $18,326 $30,244 % Reduction in Cleaning Cost 55% 66% Comparison B Before Installation 9 $17,053 $18,426 March 2011 After Installation 10 $5,439 $5,560 June 2012 $ Saved $11,614 $12,866 $24,470 % Reduction in Cleaning Cost 68% 70% Total Savings (two outages ) $54,714 (Four outages per year) Estimated Annual Savings $120,000 Following the two “after installation” outages, the savings over comparable “before installation” outages” came to $54,714. Estimated annual savings from the plant’s typical four-outage schedule reach $120,000. (Table 2) 6 Reductions in Ammonia Cost In November and December of 2011—before the ash sweeper installation—plant figures show the SCR consumed 2.00 pounds of ammonia for ever MW/hour produced. In January and February 2012, after the installation, the ammonia usage dropped to 1.80 pounds per megawatt hour. When calculated with the plant’s annual consumption of ammonia, this reduction provides an annual savings of 209 tons of ammonia. With the plant’s budget electricity production for 2012 for 2093 gigawatts at the plant’s contracted ammonia cost for the past year of $472 per ton, this provides an annual savings in excess of $98,000. (Table 3.) Table 3. Ammonia Usage at TECO Big Bend Ammonia Used (Pounds per MW/hour) November/December 2011 Before Installation January/February 2012 After Installation Reduction in Ammonia Consumed per MW/hour Yearly Reduction in ammonia consumption (lbs) Converted to tons Ammonia price (delivered)/ton Savings in ammonia consumed 2.00 1.80 0.20 418,600 209.3 $472 $98,789.60 At the plants where the ammonia cost is closer to the industry average of $750 per ton, the annual savings would be more than $150,000. Reductions in Pressure Drop Buildups in the SCR create an increase in pressure drop, which in turn causes the ID fan to work harder, consuming more electricity as it tries to maintain gas flow. The pressure drop caused by poor SCR performance then results in additional ash buildups in the SCR, air preheater, ductwork, and precipitator, magnifying and accelerating the problem. In some cases, this pressure drop (DP) became so severe it required stopping the boiler to allow the SCR to be cleaned. The improved flow through the catalyst resulting from the addition of the ash sweeper system provides other improvements and other savings to the plant. One benefit was a reduction in system pressure drop of 2.5 inches water column. At the unit load of 380 MW, this resulted in a reduction in the power consumption by the plant’s ID fan of 1.93 MW/hour. Assuming an operating factor of 85%, this turns into an annual savings of $356,418.10. This means less electricity used inside the plant, and more electricity to sell. Improved Catalyst Performance and Life In addition to the operating savings, the key benefit of the ash sweeper system is the improved performance of the SCR in helping the plant achieve its regulated emission levels. When ash builds up, it blocks usable catalyst and so increases wear on the catalyst sections that are still exposed. Erosion is a problem but more importantly, the activity of the catalyst—its ability to stimulate the reaction of ammonia and flue gas inside the SCR—is reduced much faster. For one thing, the plant now receives the benefit of all the catalyst it paid for. If catalyst costs a million dollars a layer, and a layer is 40 percent covered with ash (and so NOT interacting with the flue gas), the plant has lost $400,000 of its investment. 7 In addition, the flow rate through the catalyst that remains open is increased, and as a consequence, receives more erosive wear. In essence, it wears out sooner, because it has more flue gas with ash moving through it at an increased speed. And this effect is not only seen on the first layer--the layer with the buildup—but is also seen on the following second and third layers of catalyst, because of the restrictions in the first layer have narrowed the flow path through the lower layers. And one final note: if the buildup deflects the flow of gas at a 30 degree angle—so that the particles in that gas strike the catalyst at an angle--this angled assault increases the erosive wear on the catalyst at three times the previous rate. In short, the catalyst adjacent to the pile wears three times faster than normal because it must cope with the “run off” from the pile of ash. Improvement in Plant Safety Ash accumulations change gas flow, increasing errosive wear on catalyst. A reduction in SCR cleaning improves plant safety, as any personnel trip into the SCR exposes workers to the hazards from hot ash, as well as back, shoulder, wrist and arm injuries from repetitive physical work in these conditions. In summary: Prompt Payback for Big Bend The result of the installation of the ash sweeper systems to remove the buildups from the SCR catalyst provides a significant opportunity for savings and for operational improvements at TECO Big Bend. The plant’s calculations showed an operational savings of more than $574,000 annually. This figure represents nearly four times the cost of the installed ash sweeper system. Table 4. Combined Savings at Big Bend in 1 Year (Rounded) Reduction in Cleaning Costs $120,000 Reduction in Ammonia Costs $ 98,000 Reduction in ID Fan Energy Consumption $356,000 Total Annual Savings $574,000 CASE 2: OPPD NEBRASKA CITY Located about 50 miles south of the city of Omaha along the Missouri River, Omaha Public Power District (OPPD) operates the Nebraska City Power Station. This is a two-unit facility, with the 646-MW Unit 1 opened in 1979 and the 720-MW Unit 2 started-up thirty years later in 2009. Both units are fueled with PRB coal. While Unit 2 features state-of the art emission control systems, the operation of these systems was not without problems. OPPD Nebraska City Station 8 Buildups in the ductwork Nebraska City Station was experiencing ash buildup in the ductwork leading from the plant’s dual SO2 scrubbers to the baghouse. The outlet ductwork from the two scrubbers joined together in a horizontal run and then as a combined flow the duct passage turned up to the baghouse inlet plenum. A number of vertical vanes are located just before the juncture of the two horizontal ducts, followed by a number of horizontal turning vanes located where the duct sloped up to the baghouse. With the combining of gas paths and the upward slope of the duct a substantial amount of fly-ash would drop out of the gas flow, building on the slope plate and burying the horizontal turning vanes. Ash buildup inside the ductwork The ash buildup in this 18-foot tall duct had reached a height as much as six feet. Plant and pollution control OEM engineers were concerned that the weight of this buildup would exceed the structural capacity of the ductwork, creating a safety issue and threatening compliance with environmental permits. The ash sweeper system To remedy the problem with the material buildups in the ductwork, Nebraska City plant agreed to install ash sweeper systems from Martin Engineering. Installation consisted of two independent sets of multi-port ash sweeper systems, one set for each scrubber, with eight ports on each duct outlet generally positioned between or upstream of the vertical turning vanes. The number of vertical turning vanes played a major role in determining the number of ash sweeper discharge nozzles used. Fanjet nozzles were used on the ash sweeper discharge ports in the ductwork, to provide a wider (if somewhat shorter) cleaning action. At the Nebraska City plant, the fan jet nozzles proved effective in moving ash 15 to 20 feet. After installation and operation of the multiport ash sweeper system on the ductwork, the overall ash depth has been reduced and the area where the system was installed has been swept clean. Success at Nebraska City During the Nebraska City plant’s last outage cycle, the PLC controlling the ash sweeper cycle on the “A” set of ash sweepers had failed, and so the ash sweeper system was not functional. Inspection of the “A side” ductwork showed an ash level estimated at 54 inches deep along the horizontal duct with about 48 inches of buildup at the vertical turning After installation of the ash sweeper,, ash buildups at the turning vanes was reduced. 9 vanes where the ash sweeper discharge nozzles are located. The slope plate was covered up to the bottom horizontal turning vane about 30 inches above the duct floor On the “B” side where the ash sweeper system remained in operation showed a significant reduction in ash buildup. The ductwork at the nozzle installation between the vertical turning vanes was cleared to the bare metal and the ash drop out downstream on the upward slope plate was estimated at one half the depth of the “A” side. The horizontal portion of the outlet duct that is located upstream of the ash sweeper had a deposit of ash 28 inches deep. The reduced level of ash in the horizontal duct is believed to be a result of the ash sweeper installation combined with process changes in scrubber operations. Future operation with consistent PLC functionality will be needed to determine upstream impact. As the ash sweeper systems in the Nebraska City Station reduces the depth of the ash accumulations inside the ductwork, the plant anticipates it will reduce the number of hours (and resulting costs) required to clean the ductwork during plant outages. In Conclusion Ash sweeper systems have now been installed in coal-fired power plants in China and eliminates some significant ash buildups. The installation of ash sweepers on selective catalytic reactor systems provides significant improvements for coal-fired power plants. These benefits include extending life of catalyst, reducing ammonia consumption and cost, Reducing cleanup cost and frequency, and improving plant efficiency by extending the length of time available for operation before cleanup requires an outage. Additional installations will provide further opportunities for research and verification of the results discussed above. ## 10