Environmental Fluid Mechanics Ι 1 Institute for Hydromechanics MASS TRANSPORT PROCESSES When a tracer cloud is introduced into a fluid flow (e.g. river) two processes are visible: • The cloud is carried away from the point of discharge by the mean current. • The cloud spreads in all directions due to irregular motions and grows in size. Advection - mass transport by mean velocity field Diffusion - mass transport by irregular fluctuations ("random movements") mean flow t1 t2 PASSIVE MIXING PROCESSES - advection + diffusion as they exist in environment (passive source) ACTIVE MIXING PROCESSES - generation of mean and random velocity field by source - momentum or buoyancy passive mixing (weak source) Active mixing (strong source e.g. high velocity) Environmental Fluid Mechanics Ι 2 Institute for Hydromechanics MOLECULAR DIFFUSION − molecular diffusion of dissolved or suspended matter is caused by random movement through molecular motions of individual molecules ∂c <0 ∂x window of unit area J x = diffusive mass flux = ⎡ M ⎤ mass =⎢ 2 ⎥ area , time ⎣ L , T ⎦ Fick's Law of Diffusion: − rate of transport is proportional to the spatial concentration gradient Jx = − D AB ∂c ∂x ∂c ∂x Fick´s law (1-D) ⎡ L2 ⎤ D AB = coefficient of molecular diffusivity = ⎢ ⎥ = f (solvent, solute, temperature...) ⎣T⎦ Typical values for molecular diffusion: D ∼ 2 × 10-5 cm2/s D ∼ 2 × 10-1 cm2/s Dissolved matter in water: Gases in air: Generalization: r J = J x , J y , Jz ( ⎛ ∂ ∂ ∂⎞ ∇=⎜ , , ⎟ divergence vector ⎝ ∂ x ∂ y ∂z ⎠ ) r J = −D∇C Example: Fick´s law (3-D) Salt diffusion in a vessel Water Water initial sharp interface two hours later diffuse interface ~ 1,0 cm Water + NaCl+ Dye Water + NaCl+ Dye Environmental Fluid Mechanics Ι 3 Institute for Hydromechanics ADVECTIVE MASS FLUX − transport of matter due to mean motion (current) r q = (u, v, w ) = hydrodynamic velocity r ⎡ M L⎤ ⎡ M ⎤ c q = ⎢ 3 ⎥ = ⎢ 2 ⎥ = advective mass flux ⎣ L T ⎦ ⎣L , T ⎦ window of unit area Example: Pure advection in x-direction (no diffusion no reaction) t1 t2 no change of shape “plug flow” TOTAL MASS FLUX: Advection + diffusion r r r r N = N x , N y , Nz = c q + J = c q − D∇C ( ) Environmental Fluid Mechanics Ι 4 Institute for Hydromechanics MASS CONSERVATION PRINCIPLE R = rate of production or decay per unit ⎡ M ⎤ volume = ⎢ 3 ⎥ ⎣L , T ⎦ ⎡net flux of mass⎤ ⎢ (In − Out ) ⎥ ⎣ ⎦ − + ⎡Rate of production / ⎤ ⎢decay of mass ⎥ ⎢ ⎥ ⎢(chemical, physical, ⎥ ⎢ ⎥ ⎣bio log ical ... ) ⎦ = ⎡Rate of mass ⎤ ⎢accumulation ⎥ ⎢ ⎥ ⎢⎣ within element ⎥⎦ ∂ Ny ∂ Nx ∂ Nz ∂c ∆ x∆ y ∆ z − ∆ x∆ y ∆ z − ∆ x∆ y ∆ z + R ∆ x∆ y ∆ z = ∆ x∆ y ∆ z ∂x ∂y ∂z ∂t r r ∂ c ∂ N x ∂ N y ∂ Nz ∂ c ∂c + + + = + ∇⋅N = + ∇ ⋅ c q − ∇ ⋅ (D ∇ c) = R ∂t ∂x ∂y ∂z ∂t ∂t ∂c r + q ⋅ ∇ c = D ∇2 c + R ∂t ∂c ∂t + ∂c u ∂x + ∂c v ∂y + ∂c w ∂z ↑ 1444442444443 Temporal Advective transport change Convective Diffusion Equation = ⎛ ∂2 c ∂2 c ∂2 c ⎞ D⎜ 2 + + ⎟ ∂ y2 ∂ z2 ⎠ ⎝∂x 14444244443 Diffusive transport + R ↑ Reaction Environmental Fluid Mechanics Ι 5 Institute for Hydromechanics Solution of the convective diffusion equation: 1. Basic solution: Instantaneous point source (IPtS) in uniform current and infinite space z U r q = (U, 0,0) , (uniform velocity field) R = − k c (first order decay) y t=0 t 1 t 2 x ⎛ ∂2 c ∂2 c ∂2 c ⎞ ∂c ∂c +U =D⎜ 2 + + ⎟ − kc ∂t ∂x ∂ y2 ∂ z2 ⎠ ⎝∂x Initial Conditions (I.C.) t < 0, c = 0 t=0 Sudden mass input M on (x1, y1, z1) Boundary Conditions (B.C.) c → 0 as (x, y, z) → ∞ Solution: [( x − x ) − Ut] − 1 c = M (4 π D t) 3/ 2 123 cmax e 2 + ( y − y1) + ( z − z1) 2 4D t 2 e− k t 14444424444443 123 spatial distribution non-conservative (reaction) effect 1. Position of cloud center: ( x1 + U t, y1, z1) t1 2. Cloud size: 4 D t = 2 σ2 , σ = variance σ = 2D t = standard deviation ∼ t t2 0,5 cmax Distance relative to center 3. Maximum concentration cmax ∼ t-3/2 Environmental Fluid Mechanics Ι 6 Institute for Hydromechanics 2. Other solutions Boundary conditions (finite space): on ⎡: c = specified Ex: c = 0 Absorption condition (Dirichlet B.C.) ∂c = specified ∂n Ex: ∂c =0 ∂n Diffusion barrier (Reflection condition) (Neumann B.C.) Multiple sources → → superposition, due to linearity of governing equation image sources z k c = ∑ ci i=1 i =1 x i=2 Time dependence Initial condition: − Instantaneous sources − Continuous sources Environmental Fluid Mechanics Ι TURBULENCE 7 Institute for Hydromechanics - an instability of a base flow (shear flow) Possibility 1: - damping of disturbance (viscosity) - stable flow damping LAMINAR FLOW Possibility 2: - insufficient damping - large eddies - secondary eddies TURBULENT FLOW disturbance grows SPECTRUM OF EDDIES Large eddies: Integral length scale => lΙ Integral time scale Integral velocity scale uΙ tΙ = lΙ uΙ ⎡ L2 ⎤ =⎢ 3 ⎥ ⎣T ⎦ Energy cascade (transfer of energy from larger to smaller scales) 2 Extraction of energy from mean flow: ε~ 3 K.E. uΙ u ~ = Ι time l Ι / uΙ l Ι Smallest eddies: at some scale (Kolmogorov length scale) the eddy size will be small enough so that viscous damping will prevent further breakdown ⎡ L2 ⎤ Dimensionality: viscosity ν = ⎢ ⎥ , ⎣T⎦ Kolmogorov length scale Turbulence spectrum: Overall criterion: ⎡ L2 ⎤ energy dissipation rate ε = ⎢ 3 ⎥ ⎣T ⎦ ν3 / 4 η = 1/ 4 ε ε lΙ η " equilibrium subrange" Reynolds number U ∼ base velocity, UL > 100 to 1000 ν L ∼ base flow length Re = Environmental Fluid Mechanics Ι 8 Institute for Hydromechanics TURBULENT DIFFUSION Random motion due to turbulent velocity fluctuations cause additional transport ("small scale advection"). u ′ ( t) = fluctuating velocity u (t) = 1 t −T ∫ u ( t ′) d t ′ = mean velocity T t u = u + u′ w = w + w′ v = v + v′ c = c + c′ u′ = 1 t −T ∫ u′ ( t ′ ) d t ′ = 0 T t Averaging process: Reynolds decomposition uc = u c + uc ′ + u′ c + u′ c ′ ⎤ ⎛ ∂2 c ∂2 c ∂2 c ⎞ 1 t + T ⎡ ∂c ∂uc ∂ vc ∂ wc + + + = D ⎜ 2 + 2 + 2 ⎟ + R⎥ d t ∫ ⎢ ∂x ∂y ∂z T t ⎢⎣ ∂ t ∂y ∂z ⎠ ⎝ ∂x ⎥⎦ ⎛ ∂2 c ∂2 c ∂2 c ⎞ ∂c ∂c ∂c ∂c ∂ ∂ ∂ +u +v +w =− u′ c′ − v ′c ′ − w ′ c′ + D ⎜ 2 + 2 + 2 ⎟ + R ∂t ∂x ∂y ∂z ∂x ∂y ∂z ∂y ∂c ⎠ ⎝ ∂x 144424443 time advective transport change by of mean mean velocity conc. 14444244443 "small scale advection" ⇓ turbulent mass transport 14442443 molecular diffusion ≈0 r ⎡ M ⎤ Jt = u′c ′, v ′c ′, w ′c ′ = turbulent diffusive mass flux = ⎢ 2 ⎥ ⎣L , T ⎦ ( ) r Jt needs parameterization : analogy to molecular diffusion (Fick's law) ? ↓ ↓ reaction Environmental Fluid Mechanics Ι 9 Institute for Hydromechanics Example: Tank with Grid Stirring net transport w ′c′ > 0 DIFFUSION IN TURBULENT FLOW → fluctuating velocity field ⇒ multiple scale eddies (spectrum)! Ex: Release from POINT SOURCE σ ∼ t σ ~t a) 0,5 Short time after release t<t Ι , σ < l Ι First small eddies, then eddies of increasing size will cause spreading σ x = u′ 2 t ~ t1 Rapid growth (Taylor theorem, 1921) u′2 =rmsvelocity~uΙ b) Long time after release t>t Ι : Large eddies control spreading ( ) σ x = 2 uΙ t Ι t ~t1 / 2 2 ∴ eddies are independent of each other => random process "Fickian" behavior: corresponds to spreading with gradient-type diffusion and a constant coefficient ⎡ L2 ⎤ Analogy: uΙ t Ι =uΙ l Ι =E x = turbulentdiffusivity = ⎢ ⎥ ⎣T⎦ ∂c ∂c ∂c , , J tx = u′ c ′ = − E x Jty = v ′ c ′ = − E y J tz = w ′ c ′ = − E z ∂y ∂z ∂x 2 Environmental Fluid Mechanics Ι 10 Institute for Hydromechanics PRACTICAL TURBULENT DIFFUSION EQ.: c → c ∂c ∂c ∂c ∂c ∂ ⎛ ∂ c⎞ ∂ ⎛ ∂ c⎞ ∂ ⎛ ∂ c⎞ +u +v +w = ⎟ + R + D ∇2 c ⎜E ⎟+ ⎜ Ey ⎟+ ⎜ Ex ∂t ∂x ∂y ∂ z ∂ x ⎝ ∂ x⎠ ∂ y ⎝ ∂ y ⎠ ∂ z ⎝ z ∂ z⎠ 14444444244444443 turbulent diffusive transport Valid for t > tΙ σ > lΙ ; Diffusivities can have dependence on spatial position and direction: - E x , E y , E z = f ( x , y , z) non-homogeneous if E x , E y , E z = const. homogeneous - Ex ≠ Ey ≠ Ez anisotropic if Ex = Ey = Ez = E isotropic ∂2c ∂2c ∂2c + E + E y x ∂ x2 ∂y 2 ∂z2 → Ex → ⎛ ∂2c ∂2c ∂2c ⎞ ⎟ E⎜ 2 + + ∂y 2 ∂z2 ⎠ ⎝ ∂x Estimation of turbulent diffusivities: E = f (base flow characteristics) Order of magnitude: E ~uΙ l Ι single scale only! TURBULENT CHANNEL FLOW Uh > 500 for turbulence ν τ 0 = ρ gh S = shear stress Re = τ0 = u∗ = friction (shear ) velocity ρ u* = g hS Dominating scales: uΙ ~u∗,l Ι ~h Also: f τ 0 =ρ U 2 8 Or: 1 U = h 2 / 3 S1/ 2 n f = Darcy-Weisbach coefficient, 0.02 .. 0.1 n = Mannings's n, 0.02 ... 0.05 Rule of thumb: u ∗ ≈ ( 0.05 to 0.1) U u∗ = f U² 8 u∗ = gn 2 U² h 1/ 3 Environmental Fluid Mechanics Ι 11 Institute for Hydromechanics MIXING IN RIVERS Eddy diffusivity Ez We expect: E z ~ u ∗ h Velocity profile du = f (u ∗ , z) dz Dimensional analysis: du u ∗ du u ∗ ~ = or dz z dz κ z Upon integration: u 1 = lnz + C 1 u∗ κ log-law κ = von Karman constant = 0.4 C1 = f (Re, roughness) du ⎛ z⎞ τ = τ 0 ⎜ 1− ⎟ = ρ ε z ⎝ h⎠ dz model for momentum exchange (Boussinesq) ⎛ z⎞ τ0 ⎜ 1− ⎟ ⎝ h⎠ z⎞ ⎛ = κ u∗ ⎜ 1 − ⎟ εz = du ⎝ h⎠ ρ dz εz Ez z⎛ z ⎞ = κ ⎜ 1− ⎟ ≡ u∗ h h ⎝ h ⎠ u∗ h ⎡ L2 ⎤ εz = eddy viscosity = ⎢ ⎥ ⎣T⎦ Reynolds analogy for turbulent flows Mass exchange ≈ momentum exchange Depth averaged: Ez κ = = 0.067 ≈ 0.1 u∗ h 6 Rules of thumb: River U, h u ∗ ≈ 0.1U E 2 ≈ 0.1u ∗ h ≈ 0.01Uh Ex: U = 2 m/s, h = 2m Ez = 0.04 m²/s = 400 cm2/s >> D = 2 × 10-5 cm/s !! Environmental Fluid Mechanics Ι 12 Institute for Hydromechanics VERTICAL MIXING e.g. source at surface σ z = 2E z t = 2E z Complete vertical mixing: 2,15 σz = h x U 10% criterion with Gaussian profile 2 ⎛ h ⎞ U xm = ⎜ ⎟ ⎝ 2.15 ⎠ 2E z h = 2.15 xm 2 Ez U Ex: 2 ⎛ 2 ⎞ xm = ⎜ = 25 m ⎟ ⎝ 2.15 ⎠ 2 × 0.04 ⇒ 2 Very fast Typically: Distance to complete vertical mixing 10 to 20 water depth! LATERAL MIXING Wide Channel, Depth h Conditions: x > xm σy > h Assume isotropy: E y ≅ Ez = 0.067 u ∗ h Ey ≅ 0.15 to 0.20 u∗ h Evaluation of field / laboratory tests: Data: 2 2 2 1 d σy 1 σ y ( t 2 ) − σ y ( t1 ) = Ey ≅ 2 dt 2 t 2 − t1 or 2 2 1 σ y ( x 2 ) − σ y ( x1 ) 2 ( x 2 − x1 ) / U Outlines of tracer cloud Data from Mississippi River study on longitudinal mixing (after McQuivey and Keefer 1976b) straight, uniform channels Environmental Fluid Mechanics Ι 13 Institute for Hydromechanics NATURAL CHANNELS; IRREGULARITIES Data: Ey u∗h = 0.5 to 10 . =α α = 0.6 ± 50% ⎛ UB ⎞ ⎟ α = 0.4 ⎜ ⎝ u∗ Rc ⎠ Cumulative Discharge Method (Fischer (1972) 2 Yotsukura and Sayre (1976) Yotsukura and Cobb (1976) dq = hudy = local discharge → from measurement or numerical model y q ( y) = ∫ hudy = cumulative discharge 0 B Q = ∫ hud y = total discharge 0 Approximate local balance: ∂c ∂c⎞ ∂ ⎛ = u ( y) h ( y) ⎜ E y ( y) h ( y) ⎟ ∂x ∂y ⎝ ∂y⎠ ↓ ↓ depth integrated advection uh depth integrated lateral diffusion ∂c ∂ ⎛ ∂c ⎞ = uh ⎜ h 2 E y u ⎟ ∂x ∂q ⎝ ∂q ⎠ ⇒ ∂c ∂c⎞ ∂ ⎛ 2 = ⎜ h Ey u ⎟ ∂x ∂q ⎝ ∂ q⎠ 14243 ⎡ L5 ⎤ "Diffusitivity" = ⎢ 2 ⎥ ≈ constant ⎣T ⎦ Understanding of advective velocity field is key to many environmental diffusion problems! Environmental Fluid Mechanics Ι y/B 14 Institute for Hydromechanics q/Q Transverse distributions of dye observed in the Missouri River near Blair, Nebraska, by Yotsukura et al. /1970), plotted (a) versus actual distance across the stream and (b) versus relative cumulative discharge [Yotsukura and Sayre (1976)]. Environmental Fluid Mechanics Ι 15 LONGITUDINAL DISPERSION (SHEAR FLOW DISPERSION) Institute for Hydromechanics The stretching of a tracer cloud due to vertical and horizontal velocity shear is called longitudinal dispersion. In this case, the velocity differences interact with the transverse diffusion effect and produce an additional transport mechanism Observations: t > t mixing or σ z > h For long time: 1. Gaussian distribution 2. σ L − t Therefore: behavior is analogous to Fickian diffusion Analysis: ∂c ∂c ∂ ⎛ ∂c ⎞ ∂ ⎛ ∂c ⎞ + u ( z, t) = ⎜E x ⎟ + ⎜Ez ⎟ ∂t ∂x ∂x ⎝ ∂z⎠ ∂z ⎝ ∂z⎠ 2-D Spatial decomposition: u = U + u ′′ , u ′′ , c ′′ = spatial deviations Substitute and average c = C + c ′′ , 1h ( ) dz h ∫0 U, C = spatial averages ∂C ∂C ∂u ′′ c ′′ ∂ ⎛ ∂C ⎞ 1 ⎛ ∂ c ⎞ +U + = ⎜E ⎟ + ⎜E ⎟ ∂t ∂x ∂x ∂ x ⎝ x ∂ x ⎠ h ⎝ z ∂z ⎠ h u ′′ c ′′ = 1 u ′′ c ′′ dz h ∫0 h 0 14243 = 0 no flux ⎡ M ⎤ JL = u ′′ c ′′ = dispersive mass flux = ⎢ 2 ⎥ ⎣L , T ⎦ Environmental Fluid Mechanics Ι 16 Institute for Hydromechanics ⎡ M ⎤ JL = u ′′ c ′′ = dispersive mass flux = ⎢ 2 ⎥ ⎣L , T ⎦ JL = − EL − neglect: long. diffusion, ∂C ∂t ↓ + U change of mean conc. ∂C ∂x ↓ = advection mean velocity ⎡L2 ⎤ EL = coeff. of longitudinal dispersion = ⎢ ⎥ ⎣T⎦ Ex << EL ∂C ∂x Analogy: EL ∂2 C ∂ x2 ↓ 1-D spreading by velocity deviations + transverse diffusion Local balance as seen by moving observer (U): u ′′ ∂C ∂x = ∂ ⎛ ∂ c ′′ ⎞ ⎜E z ⎟ ∂z ⎝ ∂z ⎠ ↓ Taylor (1953, 1954) ↓ transport in x direction by differential velocities ⇔ diffusion in vertical direction by turbulence "Stretching" ⇔ With given properties: u ′′ ( z), E z ( z) and evaluate one can compute u ′′ c ′′ This leads to: h z z 1 1 EL = − ∫ u ′′ ∫ u ′′ dz dz dz h 0 0 E z ∫o c ′′ ~ "Homogenization" ∂C , ∂x Environmental Fluid Mechanics Ι Applications: 17 Institute for Hydromechanics 2-D Flows 1. Channel flows: u ′′ ~ log− profile EL = 5.9 u∗ h Elder (1959) EZ ∼ parabolic Compare: E y ≈ E x = 0.2 u∗ h EL >> Ex Plan view of a drop of dye diffusing in the turbulent flow in an open channel. Distribution of concentration C, normalized to have a maximum of 10. The flow is to the left; h = 1.43 cm, x/h = 90 ( Elder, 1959) 2. Turbulent pipe flow: EL = 10.1 u∗ ro ro = pipe radius Taylor (1954) 3. Laminar pipe flow: EL mol r 2 o U2 = 48 D General rule for applicability: Taylor (1953) t > tM = transverse mixing time (vertical) = 0.4 h2 Et Et = transverse diffusivity Environmental Fluid Mechanics Ι 18 Data: Natural Rivers Institute for Hydromechanics EL = 100 to 1000 3-D non-uniformities u∗ h Lateral velocity deviations dominate → Stretching + Lateral (transverse) diffusion Typical cross section of a natural stream (Fischer 1968) Fischer (1965) u ( y), E y ( y) , y B 1 1 EL = − ∫ ( u − U) h ∫ A0 Ey h 0 ↓ A = cross-section y ∫ ( u − U) h dydydy u(y): measurements 0 ↓ or numerical model velocity deviation in lateral direction y - approximate formula (typical conditions): U2 B 2 EL = 0.011 u∗ h good within factor 4 Applicability: t > tm = = (σL ∼ within 2) transverse (lateral mixing time (B / 2) 2 0.4 Ey Other physical non-uniformities: Overall effects: - stretching of "cloud" - increased longitudinal dispersion EL ↑ Environmental Fluid Mechanics Ι 19 Institute for Hydromechanics Practical longitudinal dispersion equation ∂C ∂C ∂2 C +U = EL − kC ∂t ∂x ∂x2 t > tM (often neglected; but careful!) Instantaneous Area Source: C= Continuous Area source: C= In continuous problems Æ long. Dispersion usually negligible ⎡ ( x − Ut) 2 ⎤ ⎥ exp [ − kt] exp − ⎢ 4 π EL t ⎢⎣ 4 EL t ⎥⎦ m ′′ ⎡ xU exp ⎢ 4kEL ⎢⎣ 2 EL u 1+ 2 u q′′ Plug flow: C= ⎛ 4 kEL ⎜1 m 1 + U2 ⎝ 4kEL →0 U2 q′′ ⎛ kx ⎞ exp ⎜ − ⎟ ⎝ U⎠ U ⎞⎤ ⎟⎥ ⎠ ⎥⎦ Environmental Fluid Mechanics Ι 20 Institute for Hydromechanics OCEANIC DIFFUSION (coastal zone, estuaries, large lakes) - eddy structure RELATIVE DIFFUSION" diffusion relative to center of mass, independent of actual location in fixed space (x, y) - mass will follow larger eddies, but will be diffused by action of smaller eddies (of increasing size) → accelerating growth rate Er = C ε1/3 σr4/3 ↑ cloud size „Richardson´s (1921) 4/3 Law“ d σ 2r = 4 Er dt cylindrical coordinate r, ⇒ σ 2r ~ ε t 3 rapid growth Er ~ ε t 2 standard deviation σr ≠ const.!, diffusivity increases with time Environmental Fluid Mechanics Ι Data: 21 Institute for Hydromechanics σ 2 r ~ t 2.3 Er ~ σ 11. r Okubo (1971) → Oceanic Diffusion Diagrams ocean, coastal zone large lake, coastal zone mid-size small lake A. Okubo, "Oceanic Diffusion Diagrams", Deep Sea Research, Vol. 18, 1971 Typical growth rates: 1 hr 1 day 1 week 1 month ∼ ∼ ∼ ∼ σr = 50 m 1 km 10 km 100 km Applications: Instantaneous Point Source (Accident): cmax ~ 1 σ 2r 2-D growth (vertically mixed) c= M e h 2 π σr 2 ⎛ r2 ⎞ ⎟ − ⎜⎜ 2⎟ ⎝ 2σ r ⎠ t2 t1 σr σr c max c max Environmental Fluid Mechanics Ι 22 Institute for Hydromechanics Continuous release (Routine problems): U ∂c ∂ ⎛ ∂ c⎞ = ⎜E ⎟ − kc ∂x ∂y ⎝ y ∂y ⎠ ⎛L⎞ E y = E y0 ⎜ ⎟ ⎝ b0 ⎠ Brooks (1960) 4/3 4/3 Law L = 2 3 σy 22% width 8 E y0 x ⎤ L ⎡ = ⎢1 + ⎥ b ⎣ Ub 2 0 ⎦ c max = erf c0 3/2 ∼ x3/2 ! 3/2 3 8 E y0 x ⎞ ⎛ ⎜1 + ⎟ −1 Ub 2 0 ⎠ ⎝ Environmental Fluid Mechanics Ι References: 23 Institute for Hydromechanics Diffusion and Dispersion Processes Bird, R.B., Stewart, W.E., and Lightfoot, E.N., 1960, "Transport Phenomena", John Wiley & Sons, New York Carslaw, H.S. and Jaeger, J.C., 1959, "Conduction of Heat in Solids", Oxford Press, 2nd ed. Elder, J.W., 1959, "The Dispersion of Marked Fluid in Turbulent Shear Flow", Fluid Mechanics, Vol. 5, Part 4, pp 544-560 Fischer, H.B., 1973, "Longitudinal Dispersion and Turbulent Mixing in Open-Channel Flow", Annual Review of Fluid Mechanics, Vol. 5, pp 59-78, Annual Review, Inc., Paolo Alto, Calif. Fischer, H.B., et al., 1979, "Mixing in Inland and Coastal Waters", Academic Press, New York Holly, E.R. and Jirka, G.H., 1986, "Mixing and Solute Transport in Rivers", Field Manual, U.S. Army Corps of Engineers, Waterways Experiment Station, Tech. Report E-86-11 (NTIS No. 1229110, AD-A174931/6/XAB) Jirka, G.H. and Lee, J.H.-W., 1994, "Waste Disposal in the Ocean", in "Water Quality and its Control", Vol. 5 of Hydraulic Structures Design Manual, M. Hino (Ed.), Balkema, Rotterdam Rutherford, J.C., 1994, "River Mixing", John Wiley & Sons, Chichester Taylor, G.I., 1921, "Diffusion by Continuous Movements", Proc., London Math. Soc., Ser. A, Vol. 20, pp 196-211 Taylor, G.I., 1953, "Dispersion of Soluble Matter in Solvent Flowing Slowly Through a Tube", Proc. Royal Soc. of London, Ser. A, No. 219, pp 186-203 Taylor, G.I., 1954, "The Dispersion of Matter in Turbulent Flow Through a Pipe", Proc. Royal Soc. of London, Ser. A, Vol. 223, pp 446-468 Yotsukura, N. and Sayre, W.W., 1976, "Transverse Mixing in Natural Channels", Water Resources Research, Vol. 12, No. 4, pp 695-704