LABELLING OF WORKPLACE
HAZARDOUS CHEMICALS
Code of Practice
DECEMBER 2011
Safe Work Australia is an Australian Government statutory agency established in 2009. Safe Work
Australia consists of representatives of the Commonwealth, state and territory governments, the
Australian Council of Trade Unions, the Australian Chamber of Commerce and Industry and the
Australian Industry Group.
Safe Work Australia works with the Commonwealth, state and territory governments to improve
work health and safety and workers’ compensation arrangements. Safe Work Australia is a national
policy body, not a regulator of work health and safety. The Commonwealth, states and territories
have responsibility for regulating and enforcing work health and safety laws in their jurisdiction.
ISBN 978-0-642-33309-4 [PDF]
ISBN 978-0-642-33310-0 [RTF]
Creative Commons
Except for the logos of Safe Work Australia, SafeWork SA, Workplace Standards Tasmania,
WorkSafe WA, Workplace Health and Safety QLD, NT WorkSafe, WorkCover NSW, Comcare and
WorkSafe ACT, this copyright work is licensed under a Creative Commons
Attribution-Noncommercial 3.0 Australia licence. To view a copy of this licence, visit
http://creativecommons.org/licenses/by-nc/3.0/au/
In essence, you are free to copy, communicate and adapt the work for non commercial purposes,
as long as you attribute the work to Safe Work Australia and abide by the other licence terms.
Contact information
Safe Work Australia
Phone: +61 2 6121 5317
Email: info@safeworkaustralia.gov.au
Website: www.safeworkaustralia.gov.au
WORKSAFE
Western Australia
TABLE OF CONTENTS
FOREWORD2
4.
1.INTRODUCTION
4.1 Grouping information
20
4.2 Orientation and size of label elements
20
1.1
When is a label under the
WHS Regulations not required?
3
3
1.2 The meaning of key terms and abbreviations 4
5
LABELLING DESIGN AND LAYOUT
OTHER DUTIES IN RELATION
TO LABELLING
20
21
1.3 What are the duties in relation
to labelling hazardous chemicals?
4
5.1 Containers found without
correct labelling
21
2. LABELLING HAZARDOUS
CHEMICALS – GENERAL INFORMATION
6
5.2 Reviewing and updating
information on labels
21
2.1 What information must be
included on a label?
6
APPENDIX A – DEFINITIONS
AND ABBREVIATIONS
22
2.2 Product identifier, including
details of ingredients
6
APPENDIX B – CHECKLIST
FOR PREPARATION OF A LABEL
25
2.3 Manufacturer/importer information
8
2.4 Label elements
9
APPENDIX C – GUIDE FOR
SELECTING GENERIC NAMES
26
2.5 Expiry Date
11
APPENDIX D – APPLICATION
OF LABEL ELEMENTS
34
2.6 Pipe work
11
APPENDIX E – PRECEDENCE
RULES OF LABEL ELEMENTS
81
APPENDIX F – HAZARD PICTOGRAMS
86
APPENDIX G – COMPARISON
OF HAZARD PICTOGRAMS
WITH ADG CODE CLASS LABELS
87
APPENDIX H – EXAMPLE LABELS
89
APPENDIX I – OTHER RELEVANT
INFORMATION
97
3.
SPECIAL LABELLING SITUATIONS
3.1 Small containers
12
12
3.2 Research chemicals or samples
for analysis
13
3.3 Decanted or transferred
hazardous chemicals
14
3.4 Hazardous chemicals with known
hazards that are not supplied
to another workplace
15
3.5 Hazardous waste products
16
3.6 Hazardous chemicals classified
in the explosives hazard class
17
3.7 Hazardous chemicals that are
dangerous goods packaged for transport
17
3.8 Consumer products
18
3.9 Agricultural or veterinary
chemical products
18
3.10 Products containing nanomaterials
19
CODE OF PRACTICE | LABELLING OF WORKPLACE HAZARDOUS CHEMICALS
1
FOREWORD
This code of practice for labelling workplace chemicals is an approved code of practice under
section 274 of the Work Health and Safety Act (WHS Act).
An approved code of practice is a practical guide to achieving the standards of health, safety
and welfare required under the WHS Act and the Work Health and Safety Regulations (the
WHS Regulations).
A code of practice applies to anyone who has a duty of care in the circumstances
described in the code. In most cases, following an approved code of practice would achieve
compliance with the health and safety duties in the WHS Act, in relation to the subject
matter of the code. Like regulations, codes of practice deal with particular issues and do
not cover all hazards or risks that may arise. The health and safety duties require duty
holders to consider all risks associated with work, not only those for which regulations and
codes of practice exist.
Codes of practice are admissible in court proceedings under the WHS Act and Regulations.
Courts may regard a code of practice as evidence of what is known about a hazard, risk
or control and may rely on the code in determining what is reasonably practicable in the
circumstances to which the code relates.
An inspector may refer to an approved code of practice when issuing an improvement
or prohibition notice.
This Code of Practice has been developed by Safe Work Australia as a model code of
practice under the Council of Australian Governments’ Inter-Governmental Agreement for
Regulatory and Operational Reform in Occupational Health and Safety for adoption by the
Commonwealth, state and territory governments.
A draft of this Code of Practice was released for public consultation on 7 December 2010
and was endorsed by the Workplace Relations Ministers Council on 10 August 2011.
SCOPE AND APPLICATION
This Code applies to substances, mixtures and articles used, handled or stored at the
workplace and which are defined as hazardous chemicals under the WHS Regulations.
While this Code applies to hazardous chemicals as defined, it is recommended practice to
provide a label for any chemical that is suspected of producing adverse health, safety or
environmental effects but has insufficient information generated to allow it to be correctly
classified. The label should reflect current state of knowledge.
This Code provides practical guidance to persons conducting a business or undertaking
involved in the manufacture, import, supply or use of hazardous chemicals on how to
correctly label hazardous chemicals used in the workplace.
HOW TO USE THIS CODE OF PRACTICE
In providing guidance, the word ‘should’ is used in this Code to indicate a recommended
course of action, while ‘may’ is used to indicate an optional course of action.
This Code also includes various references to provisions of the WHS Act and Regulations
which set out the legal requirements. These references are not exhaustive. The words ‘must’,
‘requires’ or ‘mandatory’ indicate that a legal requirement exists and must be complied with.
2
CODE OF PRACTICE | LABELLING OF WORKPLACE HAZARDOUS CHEMICALS
1. INTRODUCTION
This Code describes the type of information that is needed on labels for various hazardous
chemicals so that users of these chemicals in workplaces can identify any hazards associated
with the correct classification of the chemical and take appropriate steps to eliminate or
minimise the risks.
1.1
When is a label under the WHS Regulations not
required?
In general, a label is required for any substance, mixture or article classified as a hazardous
chemical under the WHS Regulations. However, there are several types of hazardous
chemical that are excluded from the labelling provisions under Regulation 335 or exempted
from coverage from all provisions in Part 7.1 of the WHS Regulations.
DUAL USE PRODUCTS
Some hazardous chemicals may be intended for supply to both the consumer household
markets and workplaces in identical containers and packaging. These products are
sometimes referred to as dual use products. A dual use product label need only comply
with the Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) labelling
requirements. If the manufacturer or importer determines that the use handling and storage
of the product are predominantly related to a work activity, the label must meet WHS
requirements.
FOOD AND BEVERAGES
Food and beverage products that are packaged in a form intended for consumption do
not require labelling under the WHS Regulations. However, large or bulk quantities must be
labelled to meet workplace requirements. For example, a 1000 L container of flammable
alcoholic spirits must be labelled to meet WHS requirements, while a 750 mL bottle of the
same spirits does not.
THERAPEUTIC GOODS
Therapeutic goods are regarded as correctly labelled under the WHS Regulations when
labelled in accordance with Therapeutic Goods Administration (TGA) requirements and in a
form:
„„
intended for intake or administration to or by a patient or consumer, or
„„
intended for use for therapeutic purposes.
When not in a form intended for intake or administration to or by a patient or consumer, or
for therapeutic purposes, workplace labelling must be used.
For example, a pharmacist repacks a 1 kg container of formulated tablets in smaller
containers for dispensing to patients. The 1 kg container must comply with TGA labelling
requirements. However, a 1 kg container of the same material in powdered form used by
a pharmacist in manufacturing or formulating products must be labelled according to
workplace labelling requirements.
CODE OF PRACTICE | LABELLING OF WORKPLACE HAZARDOUS CHEMICALS
3
1. INTRODUCTION
1.2
The meaning of key terms and abbreviations
ADG Code means the Australian Code for the Transport of Dangerous Goods by Road and
Rail, 7th edition, approved by the Australian Transport Council. The ADG Code is accessible
at the National Transport Commission website www.ntc.gov.au.
Container means anything in or by which a hazardous chemical is, or has been, wholly
or partly covered, enclosed or packed, including anything necessary for the container to
perform its function as a container.
Hazardous chemical means any substance, mixture or article that satisfies the criteria for a
hazard class in the Globally Harmonised System of Classification and Labelling of Chemicals
(GHS) including a classification referred to in Schedule 6 of the WHS Regulations, but does
not include a substance, mixture or article that satisfies the criteria solely for one of the
following hazard classes:
„„
acute toxicity - oral - Category 5
„„
acute toxicity - dermal - Category 5
„„
acute toxicity - inhalation - Category 5
„„
skin corrosion/irritation - Category 3
„„
serious eye damage/eye irritation - Category 2B
„„
aspiration hazard - Category 2
„„
flammable gas - Category 2
„„
acute hazard to the aquatic environment – Category 1, 2 or 3
„„
chronic hazard to the aquatic environment - Category 1, 2, 3 or 4, or
„„
hazardous to the ozone layer.
Label means the written, printed or graphical information elements concerning a hazardous
chemical that is affixed to, printed on or attached to the container of a hazardous chemical.
Further definitions and abbreviations used in this Code are listed in Appendix A.
1.3
What are the duties in relation to labelling
hazardous chemicals?
The WHS Regulations apply specific duties to various persons in relation to the correct
labelling of workplace hazardous chemicals. These duties are summarised below.
4
Duty holder
Responsibilities
Manufacturers
and importers
„„
Ensure that the chemical is correctly labelled.
Suppliers
„„
Must not supply a hazardous chemical to a workplace if
the supplier knows, or ought reasonably to know, that the
chemical is not correctly labelled.
CODE OF PRACTICE | LABELLING OF WORKPLACE HAZARDOUS CHEMICALS
1. INTRODUCTION
Duty holder
Responsibilities
Person who
is conducting
a business or
undertaking
„„
Ensure that any hazardous chemical that is used, handled or
stored at the workplace is correctly labelled in accordance
with Schedule 9 of the WHS Regulations, except where:
„„
the hazardous chemical is a consumer product, retaining
its original label and only used in workplaces in
household quantities and in a way that is incidental to
the nature of the work, or
„„
a hazardous chemical is in transit.
„„
Ensure that a hazardous chemical is correctly labelled if the
chemical is manufactured at the workplace; or transferred
or decanted from the chemical’s original container at the
workplace.
„„
Ensure, so far as reasonably practicable, that containers are
correctly labelled while holding a hazardous chemical.
„„
nsure that containers that are labelled for holding a
E
hazardous chemical are used only for the use, handling or
storage of the hazardous chemical.
Note: The three duties directly above do not apply if the
hazardous chemical is used immediately after being put into
the container and the container is thoroughly cleaned after
the chemical has been used, handled or stored so it is in a
condition it would be in if the container had never contained
the chemical.
„„
Ensure, so far as is reasonably practicable, that a hazardous
chemical in pipe work is identified by a label, sign or another
way on or near the pipe work.
Note: a person who packages or re-labels a hazardous chemical with their own product
name is considered to be a manufacturer and therefore will have the same obligations as the
manufacturer or importer under the WHS Regulations to correctly label.
Under the WHS Regulations, manufacturers and importers of a substance, mixture or
article have an obligation to correctly classify that substance, mixture or article. To prepare
a correct and accurate label for a hazardous chemical, you need to know the correct
classification of the hazardous chemical.
CODE OF PRACTICE | LABELLING OF WORKPLACE HAZARDOUS CHEMICALS
5
2. LABELLING HAZARDOUS
CHEMICALS – GENERAL INFORMATION
This chapter deals with the complete set of labelling elements that should be included on
a container. A checklist for the preparation of a label is provided in Appendix B. In some
situations it is not possible or reasonably practicable to legibly include the complete set of
labelling elements on a label. Reduced label requirements are permitted in such situations.
Guidance on the label requirements for these and other special situations is provided in
Chapter 3 of this Code.
2.1
What information must be included on a label?
A hazardous chemical is correctly labelled if the chemical is packed in a container
that includes the following:
Regulation 335
Part 3
Schedule 9
„„
is written in English
„„
the product identifier
„„
t he name, Australian address and business telephone number of either the
manufacturer or importer
„„
the identity and proportion disclosed, in accordance with Schedule 8 of the WHS
Regulations, for each chemical ingredient
„„
any hazard pictogram(s) consistent with the correct classification(s) of the chemical
„„
any hazard statement(s), signal word and precautionary statement(s) that is
consistent with the correct classification(s) of the chemical
„„
any information about the hazards, first aid and emergency procedures relevant
to the chemical, which are not otherwise included in the hazard statement or
precautionary statement, and
„„
the expiry date of the chemical, if applicable.
You may include any information on the label that does not contradict or cast doubt on any
other information that is required on the label.
The following additional information should also be included on the label, where available:
„„
an emergency phone number, for specific poisons or treatment advice
„„
the overseas name, address and telephone number of the manufacturer or supplier
„„
a valid website or internet address
„„
reference to the safety data sheet, for example a statement on the label that says:
“Additional information is listed in the safety data sheet”.
2.2
Product identifier, including details of ingredients
Information on the identity of a product includes a product identifier and the disclosure
of certain ingredients. The product identifier and details of ingredients should be grouped
together and located at the most prominent position on the label, for example at the top or
centre of the label, or on a front panel.
A product identifier is a unique name or number by which the chemical is to be known,
and which allows the product users to identify the hazardous chemical. The product
identifier must be the same as that listed in the safety data sheet, and may be identical
to the trade name.
6
CODE OF PRACTICE | LABELLING OF WORKPLACE HAZARDOUS CHEMICALS
2. LABELLING HAZARDOUS CHEMICALS – GENERAL INFORMATION
A label must identify those ingredients, including their proportions, which contribute to the
overall hazard class and hazard category of the hazardous chemical in accordance with
Schedule 8 of the WHS Regulations. Disclosure of ingredient names is not required for
ingredients that meet only physicochemical and/or environmental hazard classifications.
For pure substances, the identity of an ingredient can be identical to the product identifier.
The identity of a hazardous ingredient must be disclosed on a label using its chemical
identity, unless the use of a generic name is permitted. The chemical identity of the
hazardous ingredient can be disclosed by any of the following:
„„
the IUPAC name
„„
the CAS name
„„
the technical name (if different from the IUPAC or CAS name), which must be generally
used in commerce, regulations and codes to identify a substance or mixture, and
recognised by the scientific community.
Note: Trade names are not acceptable as technical names.
A generic name may be used to describe a hazardous ingredient if:
„„
the identity of the ingredient is commercially confidential, and
„„
an exposure standard has not been established for the ingredient, and
„„
the hazardous ingredient meets the criteria for any of the following GHS hazard classes
and categories, and no other GHS health hazard classes and categories:
„„ acute toxicity – Category 4 (oral, dermal, inhalation)
„„ aspiration hazard – Category 1
„„ serious eye damage/ eye irritation – Category 2A
„„ skin corrosion/irritation – Category 2
„„ specific target organ toxicity (single exposure) – Category 3.
A guide for selecting generic names for ingredients is included in Appendix C of this Code.
FOR COMPLEX MIXTURES
The identity of all hazardous ingredients in a complex mixture must be determined so far
as is reasonably practicable. In some situations it may be difficult to identify individual
ingredients for example in natural products or extracts where the chemical composition of
the mixture may vary according to the source. In these circumstances, technical names may
be used to identify hazardous ingredients.
The ingredient and formulation details for hazardous complex mixtures must include as much
information as possible. Chemical families or sub-families should be distinguished wherever
possible. Chemical sub-families that may be used to represent a mixture of ingredients in
complex mixtures include aliphatic hydrocarbons, aromatic hydrocarbons, aliphatic alcohols,
aliphatic aldehydes and silicates.
DISCLOSING PROPORTIONS OF INGREDIENTS
The proportion of a disclosed ingredient, expressed as a weight or volume percentage
of the hazardous chemicals must be described as an exact proportion, unless the exact
concentration of an ingredient is commercially confidential. For multiple ingredients,
proportions of hazardous ingredients should be listed in descending order by mass
or volume.
CODE OF PRACTICE | LABELLING OF WORKPLACE HAZARDOUS CHEMICALS
7
2. LABELLING HAZARDOUS CHEMICALS – GENERAL INFORMATION
Where the proportions of ingredients in the hazardous chemical are commercially
confidential, the following ranges—or a narrower range as described in the paragraph
immediately below—must be used as an alternative to disclosing exact proportions:
„„
<10%
„„
10- <30%
„„
30 – 60%
„„
>60%
The proportion of an ingredient may be disclosed using a narrower range than the applicable
range listed above. For example, for an ingredient present at 35%, a range of 30 - 40% may
be used instead of 30 - 60%.
For complex mixtures, proportion ranges should be used to cover any variability in the
composition. Where the exact composition of a complex mixture is not known, this should
be clearly indicated on the label.
Where possible, the percentage composition should add up to or indicate a total of 100%,
even if an estimate of non-hazardous ingredients needs to be provided
Example of how ingredients can be represented on the subsection of a label
Flammable Liquid A contains the following ingredients:
Toluene
55 %
Ethyl methyl ketone
40 %
Methanol
3.5 %
2-Butanol
1 %
Xylene
0.5 %
As both xylene and 2-butanol are not hazardous to health at these concentrations, they
do not need to be disclosed in the ingredients subsection of the label.
Note: as they both have exposure standards they should be disclosed on the label as
good practice.
The ingredients and their proportions may be disclosed on the label using the exact
proportions:
Flammable Liquid A, contains:
Toluene
Ethyl methyl ketone
Methanol
Non-hazardous ingredients
55 %
40 %
3.5 %
1.5 %
If the ingredient proportions are commercial-in-confidence, they may be disclosed on
the label using a range:
Flammable Liquid A, contains:
Toluene
Ethyl methyl ketone
Methanol
2.3
30 - 60 %
30 - 60%
<10 %
Manufacturer/importer information
The label must include the Australian contact details of the manufacturer or importer.
8
CODE OF PRACTICE | LABELLING OF WORKPLACE HAZARDOUS CHEMICALS
2. LABELLING HAZARDOUS CHEMICALS – GENERAL INFORMATION
Additional information, including details of an overseas manufacturer or supplier – for
example, a website or internet address – may be included on the label.
The manufacturer or importer identification may be provided in a less-prominent position
on the label, for example the back portion of the label. It should be grouped with the expiry
date, where applicable.
2.4 Label
elements
The combination of label elements required on the label of a hazardous chemical is directly
linked to its hazard classification. Label elements apply to classification endpoints or hazard
categories and must be determined as specified in the GHS.
Appendix D includes tables listing all the elements that apply to each hazard class and
category or division.
The potential exists for duplication or redundancy of certain label elements where a
hazardous chemical meets the criteria for more than one hazard class or category in
the GHS. Duplicate or redundant information should not be included on a label. Rules of
precedence of certain label elements and general guidance that should be used to determine
when elements may be omitted from a label are provided in Appendix E.
Some hazardous chemicals, for example dangerous goods which cannot otherwise be
classified into any hazard class described in the GHS, will not have any corresponding label
elements. For these hazardous chemicals, hazard pictograms, hazard statements, signal
words and precautionary statements cannot be included on the label. The labels for these
products should include information on the hazards and safety precautions. For example, for
dry ice (solid carbon dioxide), information on the asphyxiation hazard and precautions for
handling to avoid cryogenic burns should be included on the label.
The signal word, hazard pictograms and hazard statements should be grouped together in a
prominent position on the label, and located either immediately following or adjacent to the
product identifier and chemical ingredients.
SIGNAL WORDS
Signal words are used to indicate the relative level of severity of a hazard. The GHS uses
‘Danger’ and ‘Warning’ as signal words. ‘Danger’ is used for a more severe or significant
hazard, while ‘Warning’ is used for the less severe hazards.
Only one signal word should be present on any one label. If the signal word ‘Danger’ applies,
then the signal word ‘Warning’ should not appear on the label.
Signal words should be represented in bold and uppercase text.
HAZARD STATEMENTS
Hazard statements describe the nature of a hazard, including the degree of hazard, where
appropriate. A unique hazard statement is assigned to each hazard class and category. The
hazard statements and corresponding hazard class and category are provided in Appendix
D. All relevant hazard statements must appear on the label. Where a hazard classification
results in hazard statements with duplicate information, the information should only appear
once, in line with the rules of precedence outlined in Appendix E.
Additionally Appendix D lists 12 non-GHS hazard statements that should be included on the
label, where relevant.
CODE OF PRACTICE | LABELLING OF WORKPLACE HAZARDOUS CHEMICALS
9
2. LABELLING HAZARDOUS CHEMICALS – GENERAL INFORMATION
A unique hazard statement code is assigned to each hazard statement. The hazard
statement code is intended to be used for reference purposes only. It is not part of the
hazard statement and should not be used to replace it or be included on the label.
Hazard statements should be represented in bold and sentence case text.
PRECAUTIONARY STATEMENTS
Precautionary statements describe the recommended measures that should be taken to
minimise or prevent adverse effects resulting from exposure to, or improper storage or
handling of, a hazardous chemical. Precautionary statements are assigned to each hazard
class and category.
Precautionary statements are separated into five categories:
„„
revention statements refer to precautions to be taken to prevent an accident or
P
exposure.
„„
Response statements refer to instructions in case of an accident.
„„
Storage statements refer to instructions for safe storage of the chemical.
„„
Disposal statements refer to appropriate disposal instructions.
„„
General statements for use as appropriate.
The precautionary statements that correspond to each hazard class and category are
provided in Appendix D. Not all precautionary statements relating to a particular hazard
classification need to be used on the label. As a guide, a maximum of between six and ten
precautionary statements should appear on the label, depending on the nature and severity
of the hazards.
Where a hazard classification results in duplicate precautionary statements, the information
should only appear once in line with the rules of precedence outlined in Appendix E.
A combination of precautionary statements may be used to save label space, improve
readability and to provide flexibility in the application of precautionary phrases.
Related precautionary statements should be grouped together on a label to allow for ease of
location. Precautionary statements should be printed in sentence case text.
A unique precautionary statement code is assigned to each precautionary statement. The
precautionary statement code is intended to be used for reference purposes only. It is not
part of the precautionary statement and should not be used to replace it or be included on
the label.
The general precautionary statements refer to general precautionary measures to be taken,
for example:
„„
If medical advice is needed, have product container or label at hand.
„„
Keep out of reach of children.
„„
Read label before use.
Unlike other precautionary statements, general precautionary statements are not linked to
particular hazard classes or categories and their inclusion on labels of workplace hazardous
chemicals is not mandatory.
Where general precautionary statements are used, they should be located in a prominent
position on the label, for example adjacent to the product identifier. General precautionary
statements should be printed in sentence case text.
10
CODE OF PRACTICE | LABELLING OF WORKPLACE HAZARDOUS CHEMICALS
2. LABELLING HAZARDOUS CHEMICALS – GENERAL INFORMATION
HAZARD PICTOGRAMS
The GHS specifies nine hazard pictograms, having regard to physical, health and
environmental hazards. These are provided in Appendix F of this Code.
Hazard pictograms must be included on the label in most cases. In some circumstances
however, pictograms may be omitted from the label in line with the rules of precedence
outlined in Appendix E. In all other cases, where pictograms are required, all the relevant
hazard pictograms must be included on the label.
Hazard pictograms should be in the shape of a square set at an angle of 45o (i.e. diamondshaped) on its point. The hazard pictograms should have a black symbol on a white
background with a red border or frame of sufficient width to be clearly visible. Pictograms
with a black border may also be used.
Class labels recommended for the transport of dangerous goods as specified in the ADG
Code may be used instead of the relevant hazard pictograms specified in the GHS. Never use
both in the same label. A comparison of the hazard pictograms as specified in the GHS and
the ADG Code class labels are shown in Appendix G1.
2.5
Expiry Date
The expiry date for a chemical must be provided, where, for example degradation or
decomposition of the chemical may occur over time, with the result that the hazard
classification of the chemical changes, or where the chemical is no longer within acceptable
specifications for potency and stability. For example ethers may form explosive peroxides
over time.
An expiry date may be provided in a less prominent position of the label, for example
the back portion of the label. It should be grouped with any manufacturer or importer
identification information. An expiry date should be represented in sentence case text.
2.6 Pipe
work
A person conducting a business or undertaking must ensure, so far as is reasonably
practicable, that a hazardous chemical in pipe work is identified by a label, sign or
another way on or near the pipe work.
Regulation 343
Pipelines and pipe-work used for the conveyance of hazardous chemicals must be identified.
The identification used should communicate information relevant to the identity of the
chemical, its hazards and any necessary precautions to be observed. Methods for identifying
hazardous chemicals in pipe work may include:
„„
signs adjacent to pipe-work
„„
markings on the pipe-work, for example colour coding (refer to AS 1345-1995
Identification of the contents of pipes, conduits and ducts for guidance)
„„
schematic layouts displayed prominently.
1
GHS pictograms can be downloaded from the GHS website at
www.unece.org/trans/danger/publi/ghs/pictograms.html or via the GHS homepage at
www.unece.org/trans/danger/publi/ghs/ghs_welcome_e.html.
Transport of Dangerous Goods class labels can be downloaded from the National Transport Commission website at
http://www.ntc.gov.au/viewpage.aspx?documentid=1313
CODE OF PRACTICE | LABELLING OF WORKPLACE HAZARDOUS CHEMICALS
11
3. SPECIAL LABELLING SITUATIONS
This chapter outlines requirements and guidelines for labelling hazardous chemicals in special
situations where the full requirements do not apply. You should always aim to provide as
much information on the hazards and safe use of the chemical on the label as possible.
Under the WHS Regulations, reduced labelling is permitted for hazardous chemicals that are:
„„
supplied in small containers
„„
research chemicals or samples for analysis
„„
decanted or transferred
„„
not supplied to another workplace, and where the hazards are known to the workers
using the chemical
„„
hazardous wastes
„„
classified into the explosives hazard class and are not explosive articles.
This section also provides guidance on the acceptability of labels prepared in accordance
with other labelling systems and handled in a workplace, specifically:
„„
hazardous chemicals classified in the explosive hazard class and labelled in compliance
with the Australian Explosives Code (AEC)
„„
dangerous goods labelled in compliance with transport requirements2
„„
consumer products
„„
gricultural or veterinary chemical products that are labelled in accordance with the
a
requirements of the Australian Pesticides and Veterinary Medicines Authority.
3.1
Small containers
Where a hazardous chemical is packaged in a container that is too small to attach a label
with information that is required of hazardous chemical labels in general, then the label
must be written in English and include the following:
Regulation 335
Part 3
Schedule 9
2
„„
the product identifier
„„
the name, Australian address and business telephone number of either the
manufacturer or importer.
„„
a hazard pictogram or hazard statement that is consistent with the correct
classification of the chemical, and
„„
any other information required for hazardous chemicals labels in general that is
reasonably practicable to include.
Dangerous goods that are labelled to comply with transport requirements and are stored in a workplace may also
need to comply with requirements as specified in the Australian Code for the Transprot of Dangerous Goods by
Road and Rail (ADG Code).
12
CODE OF PRACTICE | LABELLING OF WORKPLACE HAZARDOUS CHEMICALS
3. SPECIAL LABELLING SITUATIONS
In addition to the mandatory items mentioned above, labels for small containers or packages
must include as much labelling information required for hazardous chemical labels in general
that is reasonably practicable to include. Priority should be given to the inclusion of those
labelling elements relating to the most significant hazards of the hazardous chemical.
The most significant hazard will vary from chemical to chemical, and will be dependent upon,
for example, likely routes of exposure based on its physical state (i.e. whether it is a gas,
liquid or solid), its packaging and its intended use.
EXAMPLES OF THE MOST SIGNIFICANT HAZARD
„„ The information relating to a hazardous chemical’s inhalation hazard properties may be
considered most significant for a paint that is intended for application using a spray gun,
but not where it is intended for application using a brush.
„„ The information relating to dermal toxicity may be considered most significant for a
chemical that is packaged in an ampoule (i.e. where spillage could occur during opening),
but not where the chemical is packaged in a ready-to-use syringe.
For hazardous chemicals with multiple hazard categories, the most stringent set of
precautionary statements should be selected. This is appropriate for situations where rapid
action or response may be crucial following accidental exposure, and therefore, information
relating to these actions should be included in preference to non-critical information.
EXAMPLE OF THE MOST STRINGENT SET OF PRECAUTIONARY STATEMENTS
If a chemical can cause long term systemic effects, and is also acutely toxic, then the first
aid measures for acute toxicity will normally take precedence over those for longer term
effects. However, medical attention for the delayed health effects may be required in
some cases of incidental exposure, even if it is not associated with immediate symptoms
of exposure. Therefore, the information relevant to medical attention that is required due
to delayed health effects may be applicable.
„„
Where certain hazard or other information has been omitted from the label, then it is
recommended that alternative means for communicating the information should be used.
The complete set of hazard and other information may be included on an outer box (for
example for a box containing several very small ampoules), a swing tag or insert, or a leaflet
inside a box.
Examples of acceptable labels for small containers are provided in Appendix H.
3.2
Research chemicals or samples for analysis
A research chemical is a substance or mixture that has been manufactured in a laboratory for
the purposes of genuine research and which is not for use or supply to others for a purpose
other than genuine analysis or research. A chemical that is supplied commercially to another
workplace is not included under the meaning of research chemical or samples for analysis
under any circumstances.
Regulation 335
Part 3
Schedule 9
If a hazardous chemical is used for research purposes only or is a sample for analysis,
the label must, at a minimum, be written in English and include the product identifier
and a hazard pictogram or hazard statement that is consistent with the correct
classification of the chemical.
A research chemical or sample for analysis must be correctly classified and the identity
of the substance or mixture must be determined.
CODE OF PRACTICE | LABELLING OF WORKPLACE HAZARDOUS CHEMICALS
13
3. SPECIAL LABELLING SITUATIONS
The product identifier of a research chemical or sample for analysis may be:
„„
the actual name of the chemical
„„
a recognised abbreviation or acronym
„„
a chemical formula, structure or reaction components.
Where a research chemical or sample for analysis cannot be identified this should be
indicated clearly on the label. Labels for research chemicals or samples for analysis should
include as much hazard information as possible, based on the identity and the known or
suspected hazards.
Where labelling the actual laboratory container is impractical due to its size or the conditions
under which it is used, other methods of providing the information can be used, for example
a secure swing tag, a sign attached to supporting apparatus or labelling an outer container.
For example, for a rack of test tubes, rather than label each individual test tube containing
the same hazardous chemical, you may attach a label to the rack using a swing tag.
3.3
Decanted or transferred hazardous chemicals
If a hazardous chemical has been decanted or transferred from the container in which
it was packed and it will not be used immediately or it is supplied to someone else, the
label must, at a minimum, be written in English and include the following:
Regulation 335
Part 3
Schedule 9
„„
the product identifier, and
„„
a hazard pictogram or hazard statement consistent with the correct classification
of the chemical.
For the purposes of this Code, decant means to transfer a hazardous chemical from a
correctly labelled container to another container within a workplace. Such a container may
range from a small flask in a research laboratory to a large vessel that is used to contain
reaction components prior to use in a mixing or reaction process.
Where the entire amount of a decanted hazardous chemical will be used immediately,
labelling of its container is not required.
A decanted hazardous chemical can only be considered to be used immediately in situations
where:
„„
it is not left unattended by the person who decanted it
„„
t he decanted hazardous chemical is used only by a person present at the decanting
process
„„
the container is subsequently rendered free from any hazardous chemical immediately
after use, so the container is in the condition it would be in if it had never contained the
chemical.
EXAMPLES
„„ A sample of hydrocarbon solvent is dispensed from a bulk container into a 15 L container
by Worker A. All of the decanted hydrocarbon solvent in the 15 L container is then
used immediately by Worker A in the same shift. No hydrocarbon solvent is left in the
15 L container (as though it has never contained the chemical). The container with the
dispensed solvent is not left unattended by Worker A before it is used.
In this example, the decanted hydrocarbon solvent is considered to be used immediately.
14
CODE OF PRACTICE | LABELLING OF WORKPLACE HAZARDOUS CHEMICALS
3. SPECIAL LABELLING SITUATIONS
„„
sample of hydrocarbon solvent is dispensed from a bulk container into a 15 L container
A
by Worker A. The solvent in the 15 L container is not completely used up by Worker A
at the end of his/her work shift. Worker A has not left the container with the dispensed
solvent unattended during the shift. The remainder of the solvent is left for Worker B.
In this example, the decanted hydrocarbon solvent is not considered to be used
immediately.
Where a container is repeatedly used for decanting as part of normal work procedures or
processes, a permanent label with all the general labelling information must be attached
to the container. Permanently labelled containers must not be used to contain any other
substances or mixtures than those specified on the label.
3.4 Hazardous
chemicals with known hazards
that are not supplied to another workplace
If a hazardous chemical is not being supplied to another workplace and the hazards
associated with the chemical are known to the workers involved in using, handling
or storing the chemical, then the label must, at a minimum, be written in English
and include the following:
Regulation 335
Part 3
Schedule 9
„„
the product identifier, and
„„
a hazard pictogram or hazard statement that are consistent with the correct
classification of the chemical.
Where a hazardous chemical will not be supplied to another workplace, and your workers
involved in its handling have sufficient knowledge of the associated hazards, then you may
omit some of the information normally required in a label. The label should communicate
enough information on the hazards as necessary to ensure its safe use.
EXAMPLES OF LABELLING CHEMICALS THAT ARE NOT SUPPLIED TO ANOTHER
WORKPLACE
„„ Hazardous Chemical A is manufactured at Site A. Batch samples of Hazardous Chemical
A are routinely sent to a laboratory at the same manufacturing site for analysis. Samples
of Hazardous Chemical A are handled on a regular basis at the on-site laboratory,
and the hazards are well-known by the workers. Reduced labelling is permitted for
the batch samples.
„„
Active Constituent A is manufactured at Site A and then later formulated into an enduse product, Agricultural Chemical Product A. The end-use product is formulated at
the same facility, Site A, where the active ingredient is manufactured, and the workers
undertaking the formulation step are aware of the hazards. In this case, the reduced
labelling is permitted for Active Constituent A. However, Agricultural Chemical
Product A must be labelled with all requisite labelling information.
„„
From the previous example, if Active Constituent A is transported to a different facility,
Site B, for formulation into the end-use product Agricultural Chemical Product A, even
where both facilities are owned and operated by the same company, Active Constituent
A must be labelled with all requisite labelling information.
CODE OF PRACTICE | LABELLING OF WORKPLACE HAZARDOUS CHEMICALS
15
3. SPECIAL LABELLING SITUATIONS
3.5
Hazardous waste products
Hazardous waste products must be identified and correctly classified, so far as is reasonably
practicable. Where it is not reasonably practicable to undertake a complete hazard
classification of waste material, the hazard classification must be determined or estimated
using a precautionary approach based on the known or likely constituents of the waste.
If it is reasonably likely that a waste product is a hazardous chemical, then the label
on the container of the hazardous waste must be written in English and at a minimum,
include the following:
Regulation 335
Part 3
Schedule 9
„„
the product identifier
„„
t he name, Australian address and business telephone number of either the
manufacturer or the importer, and
„„
a hazard pictogram and hazard statement that are consistent with the correct
classification of the chemical.
The product identifier should reflect the nature of the waste as closely as possible and
may depend on the extent of knowledge about the components of the waste. Examples of
product identifiers may include:
„„
chlorinated solvent waste
„„
flammable waste
„„
chromium VI waste
„„
heavy metal waste.
Labels for hazardous wastes should include as much hazard information as reasonably
practicable based on what is known about the identity and any suspected hazards. The label
of any hazardous wastes should also include, where possible, the following information:
„„
t he identity of any known or likely hazardous constituents or impurities and their
proportions (for example, ‘contains chromium VI, 5%’, or ‘may contain trace levels of
organic peroxides’)
„„
relevant precautionary statements
„„
relevant first aid and safety directions
„„
any other information that may assist identification of the hazardous waste and its
associated hazards.
If you have made every reasonable attempt to identify and classify the chemical waste and
have been unsuccessful, you should clearly indicate this on the label.
16
CODE OF PRACTICE | LABELLING OF WORKPLACE HAZARDOUS CHEMICALS
3. SPECIAL LABELLING SITUATIONS
3.6
Regulation 335
Part 3
Schedule 9
Hazardous chemicals classified
in the explosives hazard class
If a hazardous chemical may be classified in the explosives hazard class and is not an
explosive article, the chemical must be packed in a container that has a label in English
that complies with the Australian Code for the Transport of Explosives by Road and Rail
and includes the following:
„„
the proper shipping name and UN number of the chemical, and
„„
any hazard pictogram, any hazard statement and any precautionary statement
that are consistent with the correct classification of the chemical in relation to
health hazards.
The Australian Code for the Transport of Explosives by Road and Rail (Explosives Code)
outlines requirements for labelling of explosives hazard class. This labelling regime is
designed primarily for the communication of physical hazards of explosives during their
transport.
Hazardous chemicals in the explosives class that meet the criteria for health hazards may
require health and safety information on labels in addition to that required by the Explosives
Code to meet workplace requirements.
Information on health hazards is not required on labels of explosive articles. Explosive
articles should be labelled in accordance with the Explosives Code. However, where exposure
to substances and mixtures within an article could occur during handling, any relevant health
information should be included on labels.
3.7
Hazardous chemicals that are dangerous goods
packaged for transport
Where a hazardous chemical has been packaged and labelled in accordance with dangerous
goods transport requirements and is in-transit, the hazardous chemical is not subject to
workplace labelling requirements. Where workplace hazardous chemicals are not in-transit,
they must be labelled with all of the required labelling information.
Hazardous chemicals that are classified as dangerous goods and transported by road or
rail must comply with the labelling or marking requirements that are specified in the ADG
Code. Transport markings and class labels of the ADG Code are designed primarily to assist
emergency services personnel in case of an accident or emergency.
Note: The ADG Code refers to dangerous goods pictograms as Class or Division labels. Other
information required on a package or container is referred to as markings. The size and
colour of labels and markings required for transport are specified in the ADG Code.
The ADG Code recognises the GHS as an appropriate labelling system for inner packages of
dangerous goods during transport. As this code describes GHS-compliant labelling, labels
prepared in accordance with this code should meet the inner package labelling requirements
prescribed in the ADG Code for dangerous goods during transport.
To meet both workplace and transport labelling requirements, additional health and safety
information may be required on some transport containers. The additional information would
generally relate to chronic health hazards, which are not regulated for transport purposes.
CODE OF PRACTICE | LABELLING OF WORKPLACE HAZARDOUS CHEMICALS
17
3. SPECIAL LABELLING SITUATIONS
For outer packaging used within the workplace, workplace labelling requirements may
be met by attaching to the container a supplementary panel or label that includes the
additional information. The additional information should be clearly distinguishable from
the information required to meet transport laws.
3.8
Regulation 335
Consumer products
A hazardous chemical does not need to meet the labelling requirements under the
WHS Regulations if the chemical is a consumer product with the original label on its
container and if it is reasonably foreseeable that the hazardous chemical will be used
in the workplace only:
„„
in a quantity that is consistent with consumer household use
„„
in a way that is consistent with consumer household use, and
„„
in a way that is incidental to the nature of the work carried out by a worker using
the chemical.
The following example shows how to distinguish between a consumer product and
a workplace hazardous chemical:
Toilet cleaner is sold in 750 ml bottles for domestic use and is sold in 20 L containers to
commercial cleaning businesses. The 750 ml bottle is intended for domestic use and does
not need to be labelled in accordance with the WHS Regulations.
However, it is reasonably foreseeable that, due to the package size of the 20 L product,
it would be used in a workplace rather than in a domestic situation. Therefore, the 20 L
product must be labelled according to workplace labelling requirements.
Consumer products which do not meet the definition of a workplace hazardous chemical
and are covered by the SUSMP must comply with SUSMP labelling requirements.
3.9
Regulation 335
Part 3
Schedule 9
Agricultural or veterinary chemical products
Agricultural and veterinary chemicals must have a label in English that complies with
the requirements of the Australian Pesticides and Veterinary Medicines Authority and
also includes the following:
„„
any hazard statement that is consistent with the correct classification of the
chemical, and
„„
any precautionary statement that is consistent with the correct classification of
the chemical.
Agricultural or veterinary chemical refers to any agricultural chemical product or veterinary
chemical product as defined in the Commonwealth’s Agricultural and Veterinary Chemicals
Code Act 1994.
The Australian Pesticides and Veterinary Medicines Authority (APVMA) labelling codes for
agricultural and veterinary chemical products are the Ag Labelling Code and the Veterinary
Labelling Code, respectively. You may omit the hazard pictogram and signal word from
the labels of these chemicals. However, the label must contain hazard statements and
precautionary statements for all of the intrinsic hazards of the product.
18
CODE OF PRACTICE | LABELLING OF WORKPLACE HAZARDOUS CHEMICALS
3. SPECIAL LABELLING SITUATIONS
Note: Hazard and precautionary statements required for some intrinsic hazards under the
WHS Regulations may not be required on labels by APVMA legislation. As the manufacturer
or importer, you must ensure that any additional hazard and precautionary statements
required by the WHS Regulations are included on the label, provided they are not contrary
to the information required by the APVMA legislation.
3.10Products
containing nanomaterials
For engineered or manufactured nanomaterials3 or chemicals containing engineered or
manufactured nanomaterials, it is recommended that labels be prepared in accordance with
this Code unless there is evidence that the nanomaterials are not hazardous.
The following label statements are recommended for products containing nanomaterials
when the hazards are not fully characterised:
„„
Contains engineered/manufactured nanomaterials. Caution: Hazards unknown.
„„
Contains engineered/manufactured nanomaterials. Caution: Hazards not fully
characterised.
These phrases are for use on an interim basis, as the manufacturer/importer has a duty to
correctly classify the chemical and include information on known hazards on the label in
accordance with the WHS Regulations.
3
•
ISO TS 80004-1:2010 Nanotechnologies- Vocabulary-Part 1: Core Terms provides the following definitions:
Nanomaterial – material with any external dimension in the nanoscale or having internal structure or surface
structure in the nanoscale
•
Engineered nanomaterial – nanomaterial designed for a specific purpose or function
•
Manufactured nanomaterial – nanomaterial intentionally produced for commercial purposes to have specific
properties or specific composition
•
Nanoscale – size range from approximately 1nm to 100 nm.
CODE OF PRACTICE | LABELLING OF WORKPLACE HAZARDOUS CHEMICALS
19
4. LABELLING DESIGN AND LAYOUT
The label must be written English.
The size of a label should be:
„„
large enough to contain all of the relevant hazard and other information in a size and
style that is easily visible and legible in the workplace
„„
appropriate to the size of the container, with larger labels present on larger containers.
The information on a label may be presented using one or more panels, or sections,
dependent on the size and shape of the container. The label should be firmly secured to
the outside of the container and should be visible in the normal storage position. The label
should be sufficiently durable so as to remain legible and firmly attached to the container for
the foreseeable lifetime of the product under normal storage and handling conditions.
The information and hazard pictograms on any label should be printed in a colour or colours
that provide a distinct contrast to the background colour.
4.1
Grouping information
A label should group specific information together so that hazard or precautionary
information can be easily located.
4.2
Orientation and size of label elements
The text, hazard pictograms and other information on a label should be of a size and style
that is easily legible and is appropriate to the size of the label and container.
The following table is provided as a guide for the minimum dimensions for hazard pictograms
and sizes of text on containers of various capacities:
Container capacity
Minimum hazard
pictogram dimensions
Minimum text size
≤ 500 mL
15 x 15 mm
2.5 mm
> 500 mL and ≤ 5 L
20 x 20 mm
3 mm
> 5 L and ≤ 25 L
50 x 50 mm
5 mm
≥ 25 L
100 x 100 mm
7 mm
Note 1: Refer to the ADG Code for marking requirements for dangerous goods being
transported.
Examples of labels that have been produced in accordance with the labelling system
described in this Code are provided in Appendix H.
20
CODE OF PRACTICE | LABELLING OF WORKPLACE HAZARDOUS CHEMICALS
5. OTHER DUTIES IN
RELATION TO LABELLING
A person conducting a business or undertaking who manufactures hazardous chemicals
at the workplace or decants or transfers a hazardous chemical from its original container,
must ensure that the container is correctly labelled.
Regulation 342
The person conducting a business or undertaking at the workplace must also ensure
that a container labelled for a hazardous chemical is used only for the use, handling or
storage of that hazardous chemical.
These requirements do not apply if the hazardous chemical is used immediately after it
is put into the container and the container is thoroughly cleaned immediately after use
to the condition it would be in if it had never contained the material.
5.1
Containers found without correct labelling
If you find that a container of a hazardous chemical is not correctly labelled in accordance
with the WHS Regulations, you should attach the product identifier to the container.
You should not use a hazardous chemical that is not correctly labelled. Store it in isolation
until it is appropriately labelled.
If the product identifier of an unlabelled chemical is not known, this should be clearly marked
on the container, for example by attaching a label to the container with the statement:
Caution - Do Not Use - Unknown Substance.
You should take steps to either identify and correctly label the unknown chemical or dispose
of the contents in accordance with relevant environmental regulations and, where necessary,
in consultation with the relevant waste management authority.
5.2 Reviewing
and updating information on labels
From time to time, the hazard classification of a hazardous chemical may change, for
example where new information becomes available. Where the hazard classification of a
hazardous chemical changes, the label must be reviewed and, if necessary, revised to reflect
any required changes.
Importers, manufacturers and suppliers should review any new or significant information
in relation to any hazardous chemicals they import, manufacture or supply. A review of the
literature and other relevant sources of information should be undertaken on a regular basis.
It is good practice to review the label information of a hazardous chemical at the same time
as the safety data sheet (SDS) is updated. SDSs are updated:
„„
when any new information about the hazardous chemical is known or received to ensure
the SDS contains correct, current information
„„
at least once every five years.
If you have duty to label a workplace hazardous chemical, then you must ensure that the
label contains correct information at the time it is affixed to the container of the hazardous
chemical.
CODE OF PRACTICE | LABELLING OF WORKPLACE HAZARDOUS CHEMICALS
21
APPENDIX A - DEFINITIONS
AND ABBREVIATIONS
Article means a manufactured item, other than a fluid or particle, that:
„„
is formed into a particular shape or design during manufacture, and
„„
has hazard properties and a function that are wholly or partly dependent on the shape
or design.
CAS Name is the chemical name recommended by the Chemical Abstracts Service,
Columbus, Ohio, USA.
Chemical identity means a name, in accordance with the nomenclature systems of the
International Union of Pure and Applied Chemistry or the Chemical Abstracts Service, or
a technical name, that gives a chemical a unique identity.
Class, of dangerous goods, means the number assigned to the goods in the ADG Code
indicating the hazard, or most predominant hazard, exhibited by the goods.
Class label means a pictogram described in the ADG Code for a class, or division of a class,
of dangerous goods.
Combustible liquid means a liquid, other than a flammable liquid, that has a flash point,
and a fire point less than its boiling point.
Combustible substance means a substance that is combustible and includes dust, fibres,
fumes, mists or vapours produced by the substance.
Consumer product means a thing that:
„„
is packed or repacked primarily for use by a household consumer or for use in an office
„„
if the thing is packed or repacked primarily for use by a household consumer—is
packed in the way and quantity in which it is intended to be used by a household
consumer
„„
if the thing is packed or repacked primarily for use in an office—is packed in the way
and quantity in which it is intended to be used for office work.
Division, of dangerous goods, means a number, in a class of dangerous goods, to which
the dangerous goods are assigned in the ADG Code.
Explosives Code means the Australian Code for the Transport of Explosives by Road and
Rail endorsed by the Workplace Relations Ministers’ Council as amended from time to time.
Exposure standard means an exposure standard published by Safe Work Australia in the
Workplace Exposure Standards for Airborne Contaminants.
NoteWorkplace Exposure Standards for Airborne Contaminants will replace the Adopted National Exposure Standards for Atmospheric Contaminants in the Occupational Environment [NOSHC:1003(1995)].
Generic name means a name applied to a group of chemicals having a similar structure
and properties.
Genuine research means systematic investigative or experimental activities that are carried
out for either acquiring new knowledge (whether or not the knowledge will have a specific
practical application) or creating new or improved materials, products, devices, processes
or services.
GHS means the Globally Harmonised System of Classification and Labelling of Chemicals,
Third revised edition, published by the United Nations.
22
CODE OF PRACTICE | LABELLING OF WORKPLACE HAZARDOUS CHEMICALS
APPENDIX A - DEFINITIONS AND ABBREVIATIONS
Hazard means a situation or thing that has the potential to harm people, property or the
environment.
Hazard category means a division of criteria within a hazard class in the GHS.
Hazard class means the nature of a physical, health or environmental hazard and includes
a class of dangerous goods
Hazard pictogram means a graphical composition, including a symbol plus other graphical
elements, that is assigned in the GHS to a hazard class or hazard category.
Hazard statement means a statement assigned to a hazard class or hazard category
describing the nature of the hazards of a hazardous chemical including, if appropriate,
the degree of hazard.
Import means to bring into the jurisdiction from outside Australia.
Ingredient means any component of a mixture.
In transit—a thing is in transit if the thing:
„„
is supplied to, or stored at, a workplace in containers that are not opened at the
workplace
„„
is not used at the workplace
„„
is kept at the workplace for not more than five consecutive days.
ISO name is a chemical name approved by the International Organisation for Standardisation.
IUPAC name is the chemical name recommended by the International Union of Pure and
Applied Chemistry.
Laboratory means a building or room equipped for analysis, genuine research or practical
teaching, and which is not used for production purposes.
Manufacture includes the activities of packing, repacking, formulating, blending, mixing,
making, remaking and synthesising.
Mixture means a combination of, or a solution composed of, two or more substances that
do not react with each other.
Precautionary Statement means a phrase prescribed by the GHS that describes
recommended measures to be taken to prevent or minimise the adverse effects of exposure
to a hazardous chemical or the improper handling of a hazardous chemical.
Product identifier means the name or number used to identify a product on a label or
in a safety data sheet.
Proper Shipping Name means a proper shipping name under the ADG Code.
Research chemical means a substance or mixture that is manufactured in a laboratory for
genuine research and is not for use or supply for a purpose other than analysis or genuine
research.
Safety data sheet (SDS) means a document that describes the identity, properties (that
is to say chemical and physical properties and health hazard and environmental hazard
information), uses, precautions for use, safe handling procedures and safe disposal
procedures of a hazardous chemical.
CODE OF PRACTICE | LABELLING OF WORKPLACE HAZARDOUS CHEMICALS
23
APPENDIX A - DEFINITIONS AND ABBREVIATIONS
Signal word means the word danger or warning used on a label to indicate to a label reader
the relative severity level of a hazard, and to alert the reader to a potential hazard, under the
GHS.
Substance means a chemical element or compound in its natural state or obtained or
generated by a process:
„„
including any additive necessary to preserve the stability of the element or compound
and any impurities deriving from the process, but
„„
xcluding any solvent that may be separated without affecting the stability of the
e
element or compound, or changing its composition.
SUSMP means the Standard for the Uniform Scheduling of Medicines and Poisons, published
by the National Drugs and Poisons Schedule Committee as amended from time to time.
Technical name means a name that is:
„„
ordinarily used in commerce, regulations and codes to identify a substance or mixture,
other than an International Union of Pure and Applied Chemistry or Chemical Abstracts
Service name
„„
recognised by the scientific community.
Transfer includes the pumping, dispensing or decanting from one container into another or
from one place to another.
UN Number means the number assigned to dangerous goods by the United Nations
Subcommittee of Experts on the Transport of Dangerous Goods. UN Numbers are published
in the UN Recommendations on the Transport of Dangerous Goods – Model Regulation, and
in the ADG Code.
24
CODE OF PRACTICE | LABELLING OF WORKPLACE HAZARDOUS CHEMICALS
APPENDIX B - CHECKLIST FOR
PREPARATION OF A LABEL
The following table lists the steps that are recommended for the preparation of a label for a hazardous chemical.
The information is intended for use as a quick reference guide. It may not apply to all situations. The relevant
sections of this Code should be referred to for full details of the labelling requirements.
Step
Comments/Reference information
1
Select the suitable product identifier.
2
Determine which ingredients require disclosure.
Refer to Subsection 2.2 for ingredient disclosure
requirements.
3
Select the label elements which apply to
classification endpoints or hazard categories, in
accordance with correct hazard classification
Label elements applicable to all hazard
categories are tabulated in Appendix D.
4
Combine all applicable elements, and then
determine which elements may be omitted from
the label to avoid duplication or redundancy.
Refer to Appendix E for precedence rules and
hierarchy of elements.
5
Determine which label elements may be omitted
where a special labelling situation may apply.
Refer to Chapter 3.
6
Determine whether other relevant health and
safety information may be required.
Particularly important for hazard endpoints not
covered by the GHS but where there are health
and safety concerns
7
Select the appropriate supplier details to be
included.
Other information, for example web address
or emergency contact phone number, may be
included.
8
Determine whether an expiry date is required.
Expiry date is required if degradation over time
could change the hazard classification. For
example, if a highly toxic impurity is formed.
9
Identify any other relevant information that may
be required.
For example, reference to SDS or product use
information.
10
Design the label layout and grouping of
information.
Refer to Chapter 4.
CODE OF PRACTICE | LABELLING OF WORKPLACE HAZARDOUS CHEMICALS
25
APPENDIX C - GUIDE FOR
SELECTING GENERIC NAMES
This guide describes a procedure for naming hazardous chemicals and the division
of substances into families.
The families are defined in the following manner:
„„
inorganic or organic substances whose properties are identified by having a common
chemical element as their chief characteristic. The family name is derived from the name
of the chemical element. These families are identified as in subsection C1.3 below by the
atomic number of the chemical element (001 to 103)
„„
organic substances whose properties are identified by having a common functional
group as their chief characteristic.
„„ the family name is derived from the functional group name, and
„„ these families are identified by the number convention found in subsection
C1.3 (601 to 650).
„„
sub-families bringing together substances with a common specific character have been
added in certain cases.
Establishing the Generic Name
C.1. General
Principles
In selecting a generic name, the following approach is adopted:
„„
identify the functional groups and chemical elements present in the molecule
„„
determine the most important functional groups and chemical elements, which
contribute to its properties.
The identified functional groups and elements taken into account are the names of the
families and sub-families. These names are set out in subsection C.3 in the form of a
(non-restrictive) list.
C.2. Practical
application
After having conducted a search to see if the substance belongs to one or more families or
sub-families on the list, the generic name can be established in the following way:
a)
If the name of a family or sub-family is sufficient to characterise the chemical elements or important functional groups, this name will be chosen as the generic name.
Examples:
26
Name
Family
Sub-family
Generic Name
1,4-dihydoxybenzene
604: Phenols and derivatives
Phenol derivative
Butanols
603: Alcohols and derivatives
Aliphatic alcohols
Aliphatic alcohol
2-isopropoxyethanol
603: Alcohols and derivatives
Glycolethers
Glycolether
Methacrylate
607: Organic acids and derivatives
Methacrylates
Methacrylate
CODE OF PRACTICE | LABELLING OF WORKPLACE HAZARDOUS CHEMICALS
APPENDIX C - GUIDE FOR SELECTING GENERIC NAMES
b)
If the name of a family or sub-family is not sufficient to characterise the chemical elements of important functional groups, the generic name should be a combination
of the corresponding different family or sub-family names.
Examples:
Name
Family
Sub-family
Generic Name
Lead hexafluorosilicate
009: Fluorine compounds
Inorganic fluorides
082: Lead compounds
Inorganic lead
fluoride
Chlorobenzene
602: Halogenated hydrocarbons
Halogenated aromatic
hydrocarbons
017: Chlorine compounds
Chlorinated
aromatic
hyrdrocarbon
2,3,6-Trichlorophenylacetic
acid
607: Organic acids and derivatives
Halogenated aromatic acids
017: Chlorine compounds
Chlorinated
aromatic acid
1-Chloro-1-nitropropane
610: Chloronitrated compounds
601: Hydrocarbons
Aliphatic hydrocarbons
Chlorinated
aliphatic
hydrocarbon
Tetrapropyl
dithiopyrophosphate
015: Phosphorus compounds
Phosphoric esters
016: Sulphur compounds
Thiophosphoric
ester
c)
In the case of certain elements, notably metals, the name of the family or sub-family may be indicated by the words ‘organic’ or ‘inorganic’.
Examples:
Name
Family
Sub-family
Generic Name
Dimercury dichloride
080: Mercury compounds
Inorganic mercury
compound
Barium acetate
056: Barium compounds
Organic barium compound
Ethyl nitrite
007: Nitrogen compounds
Nitrites
Organic nitrite
Sodium hydrosulphite
016: Sulphur compounds
Inorganic sulphur
compound
C.3.Division
of substances into families and sub-families
Family No.
Families
Sub-Families
001
Hydrogen compounds
Hydrides
003
Lithium compounds
004
Beryllium compounds
CODE OF PRACTICE | LABELLING OF WORKPLACE HAZARDOUS CHEMICALS
27
APPENDIX C - GUIDE FOR SELECTING GENERIC NAMES
28
Family No.
Families
Sub-Families
005
Boron compounds
Boranes
Borates
006
Carbon compounds
Carbamates
Inorganic carbon compounds
Salts of hydrogen cyanide
Urea and derivatives
007
Nitrogen compounds
Quaternary ammonium compounds
Acid nitrogen compounds
Nitrates
Nitrites
008
Oxygen compounds
009
Fluorine compounds
Inorganic fluorides
011
Sodium compounds
012
Magnesium compounds
Organometallic magnesium derivatives
013
Aluminium compounds
Organometallic aluminium derivatives
014
Silicon compounds
Silicones
Silicates
015
Phosphorus compounds
Acid phosphorus compounds
Phosphonium compounds
Phosphoric esters
Phosphates
Phosphites
Phosphoramides and derivatives
016
Sulphur compounds
Acid sulphur compounds
Mercaptans
Sulphates
Sulphites
017
Chlorine compounds
Chlorates
Perchlorates
018
Argon compounds
019
Potassium compounds
020
Calcium compounds
021
Scandium compounds
022
Titanium compounds
023
Vanadium compounds
CODE OF PRACTICE | LABELLING OF WORKPLACE HAZARDOUS CHEMICALS
APPENDIX C - GUIDE FOR SELECTING GENERIC NAMES
Family No.
Families
Sub-Families
024
Chromium compounds
Chromium VI compounds
025
Manganese compounds
026
Iron compounds
027
Cobalt compounds
028
Nickel compounds
029
Copper compounds
030
Zinc compounds
Organometallic zinc derivatives
031
Gallium compounds
032
Germanium compounds
033
Arsenic compounds
034
Selenium compounds
035
Bromine compounds
036
Krypton compounds
037
Rubidium compounds
038
Strontium compounds
039
Yttrium compounds
040
Zirconium compounds
041
Niobium compounds
042
Molybdenum compounds
043
Technetium compounds
044
Ruthenium compounds
045
Rhodium compounds
046
Palladium compounds
047
Silver compounds
048
Cadmium compounds
049
Indium compounds
050
Tin compounds
Organometallic tin derivates
051
Antimony compounds
052
Tellurium compounds
053
Iodine compounds
054
Xenon compounds
055
Caesium compounds
056
Barium compounds
057
Lanthanum
058
Cerium compounds
CODE OF PRACTICE | LABELLING OF WORKPLACE HAZARDOUS CHEMICALS
29
APPENDIX C - GUIDE FOR SELECTING GENERIC NAMES
30
Family No.
Families
Sub-Families
059
Praseodymium compounds
060
Neodymium compounds
061
Promethium compounds
062
Samarium compounds
063
Europium compounds
064
Gandolinium compounds
065
Terbium compounds
066
Dysprosium compounds
067
Holmium compounds
068
Erbium compounds
069
Thulium compounds
070
Ytterbium compounds
071
Lutetium compounds
072
Hafnium compounds
073
Tantalum compounds
074
Tungsten compounds
075
Rhenium compounds
076
Osmium compounds
077
Iridium compounds
078
Platinum compounds
079
Gold compounds
080
Mercury compounds
Organometallic mercury derivatives
081
Thallium compounds
082
Lead compounds
Organometallic lead derivatives
083
Bismuth compounds
084
Polonium compounds
085
Astate compounds
086
Radon compounds
087
Francium compounds
088
Radium compounds
089
Actinium compounds
090
Thorium compounds
091
Protactinium compounds
092
Uranium compounds
093
Neptunium compounds
094
Plutonium compounds
CODE OF PRACTICE | LABELLING OF WORKPLACE HAZARDOUS CHEMICALS
APPENDIX C - GUIDE FOR SELECTING GENERIC NAMES
Family No.
Families
Sub-Families
095
Americium compounds
096
Curium compounds
097
Berkelium compounds
098
Californium compounds
099
Einsteinium compounds
100
Fermium compounds
101
Mendelevium compounds
102
Nobelium compounds
103
Lawrencium compounds
601
Hydrocarbons
Aliphatic hydrocarbons
Aromatic hydrocarbons
Alicyclic hydrocarbons
Polycyclic aromatic hydrocarbons (PAH)
602
Halogenated hydrocarbons*
Halogenated aliphatic hydrocarbons*
Halogenated aromatic hydrocarbons*
Halogenated alicyclic hydrocarbons*
* Specify according to family corresponding to halogen.
603
Alcohols and derivates
Aliphatic alcohols
Aromatic alcohols
Alicyclic alcohols
Alcanolamines
Epoxy derivatives
Ethers
Glycolethers
Glycols and polyols
604
Phenols and derivatives
Halogenated phenol derivatives*
* Specify according to the family corresponding to halogen.
605
Aldehydes and derivates
Aliphatic aldehydes
Aromatic aldehydes
Alicyclic aldehydes
Aliphatic acetals
Aromatic acetals
Alicyclic acetals
CODE OF PRACTICE | LABELLING OF WORKPLACE HAZARDOUS CHEMICALS
31
APPENDIX C - GUIDE FOR SELECTING GENERIC NAMES
32
Family No.
Families
Sub-Families
606
Ketones and derivatives
Aliphatic Ketones
Aromatic Ketones*
Alicyclic Ketones
* Quinones included
607
Organic acids and derivatives
Aliphatic acids
Halogenated aliphatic acids*
Aromatic acids
Halogenated aromatic acids*
Alicyclic acids
Halogenated alicyclic acids*
Aliphatic acid anhydrides
Halogenated aliphatic acid anhydrides*
Aromatic acid anhydrides
Halogenated aromatic acid anhydrides*
Alicyclic acid anhydrides
Halogenated alicyclic acid anhydrides*
Salts of aliphatic acid
Salts of halogenated aliphatic acid*
Salts of aromatic acid
Salts of halogenated aromatic acid*
Salts of alicyclic acid
Salts of halogenated alicyclic acid*
Esters of aliphatic acid
Esters of halogenated alicyclic acid*
Esters of aromatic acid
Esters of halogenated aromatic acid*
Esters of alicyclic acid
Esters of halogenated alicyclic acid*
Esters of glycol ether
Acrylates
Methacrylates
Lactones
Acyl halogenides
* Specify according to the family corresponding to halogen
608
Nitriles and derivatives
609
Nitro compounds
610
Chloronitrated compounds
611
Azoxy and azo compounds
612
Amine compounds
Aliphatic amines and derivatives
Alicyclic amines and derivatives
Aromatic amines and derivatives
Aniline and derivatives
Benzidine and derivatives
CODE OF PRACTICE | LABELLING OF WORKPLACE HAZARDOUS CHEMICALS
APPENDIX C - GUIDE FOR SELECTING GENERIC NAMES
Family No.
Families
Sub-Families
613
Heterocyclic basis and derivatives
Benzimidazole and derivatives
Imidazol and derivatives
Pyrethrinoids
Quinoline and derivatives
Triazine and derivatives
Triazole and derivatives
614
Glycosides and alkaloids
Alkaloid and derivatives
Glycosides and derivatives
615
Cyanates and isocyanates
Cyanates
Isocyanates
616
Amides and derivatives
Acetamide and derivatives
Anilides
617
Organic Peroxides
650
Various substances
Do not use this family. Instead, use the families or sub-families
mentioned above.
CODE OF PRACTICE | LABELLING OF WORKPLACE HAZARDOUS CHEMICALS
33
APPENDIX D – APPLICATION
OF LABEL ELEMENTS
This appendix is intended to provide guidance for the application of an appropriate signal
word, and appropriate hazard pictograms, hazard statements, and precautionary statements.
The tables at the end of this appendix specify the signal word, hazard pictograms, hazard
statements and precautionary statements that apply to each hazard class and category.
STRUCTURE OF HAZARD STATEMENT TEXT
All of the hazard statement text that appears in bold should appear on the label, except as
otherwise specified.
All of the information that appears in italics should appear as part of the hazard statement,
where applicable.
The hazard statement codes shown in the tables are intended to be used for reference
purposes only. They are not part of the hazard statement text and should not be used on
a label.
STRUCTURE OF PRECAUTIONARY STATEMENT TEXT
There are five types of precautionary statements: general, prevention, response (in case of
accidental spillage or exposure, emergency response and first aid), storage and disposal.
All of the precautionary statement text that appears in bold should appear on the label,
except as otherwise specified.
To provide flexibility in the application of precautionary phrases, a combination of statements
may be used to save label space and improve the readability of phrases. A combination of
phrases can also be useful for different types of hazard where the precautionary behaviour
is similar.
When a forward-slash or diagonal mark [/] appears in a precautionary statement text, it
indicates that a choice has to be made between the phrases they separate
When three full stops […] appear in a precautionary statement text, it indicates that all
applicable conditions are not listed.
When text in the precautionary statement text appears in italics, this indicates that specific
conditions apply to the use or allocation of the precautionary statement. This may relate
to conditions attaching to either the general use of a precautionary statement or its use
for a particular hazard class and/or hazard category. The text in italics is not intended to be
present on a label.
The precautionary statements included in the following matrices cover general emergency
response and first-aid information. For some specific chemicals, supplementary first aid,
treatment measures or specific antidotes or cleansing materials may be required. Poisons
Centres and/or medical practitioners or specialist advice should be sought in such situations
and included on labels where appropriate
The precautionary statement codes that are used in the tables are intended to be used for
reference purposes only. They are not part of the precautionary statement text and should
not be used on a label.
PRECAUTIONARY STATEMENT FORMED FROM A COMBINATION OF PHRASES
‘Keep away from heat, sparks and open flame and store in a cool well ventilated place’.
34
CODE OF PRACTICE | LABELLING OF WORKPLACE HAZARDOUS CHEMICALS
APPENDIX D - APPLICATION OF LABEL ELEMENTS
PRECAUTIONARY STATEMENT THAT CONTAINS A FORWARD-SLASH [/]
The precautionary statement:
P280 ‘Wear protective gloves/protective clothing/eye protection/face protection’,
could read:
‘Wear eye protection’, where the hazard classification does not warrant the additional
personal protective equipment.
PRECAUTIONARY STATEMENT THAT CONTAINS THREE FULL STOPS […]
For the precautionary statement:
P241 ‘Use explosion-proof electrical/ventilating/lighting/.../equipment’, the use
of ‘...’ indicates that other equipment may need to be specified.
PRECAUTIONARY STATEMENT THAT CONTAINS TEXT IN ITALICS
The precautionary statement:
P241 ‘Use explosion-proof electrical/ventilating/lighting/.../ equipment’, only applies
for flammable solids ‘if dust clouds can occur’.
GENERAL PRECAUTIONARY STATEMENTS
General precautionary statements are not aligned with any particular hazard category, and
according to the GHS principles, these statements are required for consumer products
only. Manufacturers of hazardous chemicals may choose to include these on workplace
labels, particularly where it is foreseeable that the chemical may be used in a non-workplace
situation.
GENERAL PRECAUTIONARY STATEMENTS
P101 If medical advice is needed, have product container or label at hand
P102 Keep out of reach of children
P103 Read label before use
ALLOCATION OF LABEL ELEMENTS
The matrices below provide the following information for each hazard class and hazard
category of the GHS:
a)
b)
c)
d)
e)
hazard category; and
the assigned symbol; and
the assigned signal word; and
the assigned hazard statement and code; and
the assigned precautionary statements, by precautionary statement type, and code.
CODE OF PRACTICE | LABELLING OF WORKPLACE HAZARDOUS CHEMICALS
35
APPENDIX D - APPLICATION OF LABEL ELEMENTS
Symbol
Exploding bomb
EXPLOSIVES
Hazard category
Signal word
Hazard statement
Unstable Explosive
Danger
H200 Unstable
Explosive
Prevention
Response
Storage
Disposal
P201
Obtain special instructions
before use.
P372
Explosion risk in case
of fire.
P202
Do not handle until all safety
precautions have been read and
understood.
P373
DO NOT fight fire
when fire reaches
explosives.
P401
Store ...
…in accordance with
local/regional/ national/
international Regulations
(to be specified).
P501
Dispose of contents/
container to...
…in accordance
with local/regional/
national/international
Regulations (to be
specified).
P281
Use personal protective
equipment as required.
P380
Evacuate area.
Precautionary statements
36
CODE OF PRACTICE | LABELLING OF WORKPLACE HAZARDOUS CHEMICALS
APPENDIX D - APPLICATION OF LABEL ELEMENTS
EXPLOSIVES
Hazard category
Signal word
Hazard statement
Symbol
Exploding bomb
Division 1.1
Danger
H201 Explosive; mass
explosion hazard
Division 1.2
Danger
H202 Explosive; severe
projection hazard
Division 1.3
Danger
H203 Explosive; fire, blast
or projection hazard
Prevention
Response
Storage
Disposal
P210
Keep away from heat/sparks/open
flames/hot surfaces. - No smoking.
Manufacturer/supplier or the
competent authority to specify
applicable ignition source(s).
P370 +P380
In case of fire:
evacuate area.
P401
Store ...
…in accordance with
local/regional/ national/
international Regulations
(to be specified).
P501
Dispose of contents/
container to...
…in accordance
with local/regional/
national/international
Regulations (to be
specified).
Precautionary statements
P230
Keep wetted with...
…Manufacturer/supplier or the
competent authority to specify
appropriate material.
- if drying out increases explosion
hazard, except as needed for
manufacturing or operating
processes (e.g. nitrocellulose).
P372
Explosion risk
in case of fire.
P373
DO NOT fight
fire when
fire reaches
explosives.
P240
Ground/bond container and
receiving equipment.
- if the explosive is electrostatically
sensitive.
P250
Do not subject to grinding/shock/
…/friction.
…Manufacturer/supplier or the
competent authority to specify
applicable rough handling.
P280
Wear face protection.
Manufacturer/supplier or the
competent authority to specify
type of equipment.
CODE OF PRACTICE | LABELLING OF WORKPLACE HAZARDOUS CHEMICALS
37
APPENDIX D - APPLICATION OF LABEL ELEMENTS
Symbol
Exploding bomb
EXPLOSIVES
Hazard category
Signal word
Hazard statement
Division 1.4
Warning
H204 Fire or projection
hazard
Prevention
Response
Storage
Disposal
P210
Keep away from heat/sparks/
open flames/hot surfaces. - No
smoking.
Manufacturer/supplier or the
competent authority to specify
applicable ignition source(s).
P370 +P380
In case of fire:
Evacuate area.
P401
Store ...
…in accordance with
local/regional/ national/
international Regulations
(to be specified).
P501
Dispose of contents/
container to...
…in accordance
with local/regional/
national/international
Regulations (to be
specified).
Precautionary statements
P240
Ground/bond container and
receiving equipment.
- if the explosive is
electrostatically sensitive.
P250
Do not subject to grinding/
shock/…/friction.
Manufacturer/supplier or the
competent authority to specify
applicable rough handling.
P280
Wear face protection.
Manufacturer/supplier or
competent authority to specify
type of equipment.
38
P372
Explosion risk in case
of fire.
- except if explosives
are 1.4S AMMUNITION
AND COMPONENTS
THEREOF.
P373
DO NOT fight fire
when fire reaches
explosives.
P374
Fight fire with normal
precautions from a
reasonable distance.
-If explosives are
1.4S AMMUNITION
AND COMPONENTS
THEREOF.
CODE OF PRACTICE | LABELLING OF WORKPLACE HAZARDOUS CHEMICALS
APPENDIX D - APPLICATION OF LABEL ELEMENTS
Symbol*
EXPLOSIVES
Hazard category
Signal word
Hazard statement
Division 1.5
Danger
H205 May mass
explode in fire
Prevention
Response
Storage
Disposal
P210
Keep away from heat/sparks/
open flames/hot surfaces.
- No smoking.
Manufacturer/supplier or the
competent authority to specify
applicable ignition source(s).
P370 +P380
In case of fire:
Evacuate area.
P401
Store ...
…in accordance with
local/regional/ national/
international Regulations
(to be specified).
P230
Keep wetted with...
…Manufacturer/supplier or the
competent authority to specify
appropriate material.
- if drying out increases explosion
hazard, except as needed for
manufacturing or operating
processes (e.g. nitrocellulose).
P373
DO NOT fight fire
when fire reaches
explosives.
P501
Dispose of contents/
container to...
…in accordance
with local/regional/
national/international
Regulations (to be
specified).
Precautionary statements
P372
Explosion risk in case
of fire.
P240
Ground/bond container and
receiving equipment
- if the explosive is
electrostatically sensitive.
P250
Do not subject to grinding/
shock/…/friction.
…Manufacturer/supplier or the
competent authority to specify
applicable rough handling.
P280
Wear face protection.
Manufacturer/supplier or
competent authority to specify
type of equipment.
*Note: This symbol is according to the ADG Code for the transport of dangerous goods
CODE OF PRACTICE | LABELLING OF WORKPLACE HAZARDOUS CHEMICALS
39
APPENDIX D - APPLICATION OF LABEL ELEMENTS
Symbol*
EXPLOSIVES
Hazard category
Signal word
Hazard statement
Division 1.6
No signal word
No hazard statement Prevention
Response
Storage
Disposal
No precautionary statements
No precautionary
statements
No precautionary
statements
No precautionary
statements
Precautionary statements
*Note: Symbol for Explosive Division 1.6 is the symbol used for the transport of dangerous goods
Symbol
Flame
FLAMMABLE GASES
Hazard category
Signal word
Hazard statement
1
Danger
H220 Extremely
flammable gas Prevention
Response
Storage
P210
Keep away from heat/sparks/
open flames/hot surfaces. -No
smoking.
Manufacturer/supplier or
competent authority to specify
applicable ignition source(s).
P377
Leaking gas fire:
Do not extinguish,
unless leak can be
stopped safely.
P403
Store in well-ventilated
place.
Precautionary statements
40
P381
Eliminate all ignition
sources if safe to
do so.
CODE OF PRACTICE | LABELLING OF WORKPLACE HAZARDOUS CHEMICALS
Disposal
APPENDIX D - APPLICATION OF LABEL ELEMENTS
Symbol
Flame
FLAMMABLE AEROSOLS
Hazard category
Signal word
Hazard statement
1
Danger
H222 Extremely
flammable aerosol
2
Warning
H223 Flammable aerosol
Response
Storage
Precautionary statements
Prevention
P210
Keep away from heat/sparks/
open flames/hot surfaces. -No
smoking.
Manufacturer/supplier or the
competent authority to specify
applicable ignition sources(s).
Disposal
P410 + P412
Protect from sunlight.
Do not expose to
temperatures exceeding
500C/1220F.
P211
Do not spray on an open flame
or other ignition source.
P251
Pressurized container: Do not
pierce or burn, even after use.
Symbol
Flame over circle
OXIDISING GASES
Hazard category
Signal word
Hazard statement
1
Danger
H270 May cause
or intensify fire;
oxidiser Prevention
Response
Storage
P220
Keep/Store away from
clothing/…/combustible
materials.
…Manufacturer/supplier or the
competent authority to specify
other incompatible materials.
P370 + P376
In case of fire: Stop
leak if safe to do so.
P403
Store in well-ventilated
place.
Precautionary statements
Disposal
P244
Keep reduction valves free from
grease and oil.
CODE OF PRACTICE | LABELLING OF WORKPLACE HAZARDOUS CHEMICALS
41
APPENDIX D - APPLICATION OF LABEL ELEMENTS
GASES UNDER PRESSURE
Symbol
Gas cylinder
Hazard category
Signal word
Hazard statement
Compressed gas
Warning
H280 Contains gas under pressure;
may explode if heated
Liquefied gas
Warning
H280 Contains gas under pressure;
may explode if heated
Dissolved gas
Warning
H280 Contains gas under pressure;
may explode if heated
Response
Storage
Precautionary statements
Prevention
Disposal
P410 + P403
Protect from sunlight. Store in a
well-ventilated place.
Symbol
Gas cylinder
GASES UNDER PRESSURE
Hazard category
Signal word
Hazard statement
Refrigerated liquefied
gas
Warning
H281 Contains refrigerated
gas; may cause cryogenic
burns or injury
Prevention
Response
Storage
P282
Wear cold insulating
gloves/face shield/eye
protection.
P336
Thaw frosted parts with
lukewarm water. Do not
rub affected area.
P403
Store in well-ventilated
place.
Precautionary statements
P315
Get immediate medical
advice/attention
42
CODE OF PRACTICE | LABELLING OF WORKPLACE HAZARDOUS CHEMICALS
Disposal
APPENDIX D - APPLICATION OF LABEL ELEMENTS
FLAMMABLE LIQUIDS
Symbol
Flame
Hazard category
Signal word
Hazard statement
1
Danger
H224 Extremely flammable
liquid and vapour
2
Danger
H225 Highly flammable
liquid and vapour
3
Warning
H226 Flammable liquid
and vapour
Prevention
Response
Storage
Disposal
P210
Keep away from heat/sparks/open
flames/hot surfaces.– No smoking.
Manufacturer/supplier or the
competent authority to specify
applicable ignition source(s).
P303 + P361 +
P353
IF ON SKIN (or
hair): Remove/
Take off
immediately all
contaminated
clothing. Rinse
skin with water/
shower.
P403 + P235
Store in a well-ventilated
place. Keep cool.
P501
Dispose of contents/
container to...
… in accordance
with local/regional/
national/international
Regulations
(to be specified).
Precautionary statements
P233
Keep container tightly closed.
P240
Ground/Bond container and
receiving equipment
- if electrostatically sensitive
material is for reloading.
- if product is volatile so as to
generate hazardous atmosphere.
P241
Use explosion-proof electrical/
ventilating/lighting/.../equipment.
... Manufacturer/supplier or the
competent authority to specify
other equipment.
P370 + P378
In case of fire: Use
... for extinction.
...Manufacturer/
supplier or the
competent
authority to specify
appropriate media.
- if water increases
risk.
P242
Use only non-sparking tools.
P243
Take precautionary measures
against static discharge.
P280
Wear protective gloves/eye
protection/face protection
Manufacturer/supplier or the
competent authority to specify
type of equipment.
CODE OF PRACTICE | LABELLING OF WORKPLACE HAZARDOUS CHEMICALS
43
APPENDIX D - APPLICATION OF LABEL ELEMENTS
Symbol
No symbol
FLAMMABLE LIQUIDS
Hazard category
Signal word
Hazard statement
4
Warning
H227 Combustible
liquid
Prevention
Response
Storage
Disposal
P210
Keep away from flames and
hot surfaces. – No smoking.
P370 + P378
In case of fire: Use ...
for extinction.
... Manufacturer/supplier
or the competent
authority to specify
appropriate media.
- if water increases risk.
P403 + P235
Store in a wellventilated place.
Keep cool.
P501
Dispose of contents/
container to...
in accordance with
local/regional/
national/international
Regulations (to
be specified).
Precautionary statements
P280
Wear protective gloves/eye
protection/face protection
Manufacturer/supplier or the
competent authority to specify
type of equipment.
FLAMMABLE SOLIDS
Symbol
Flame
Hazard category
Signal word
Hazard statement
1
Danger
H228 Flammable solid
2
Warning
H228 Flammable solid
Prevention
Response
Storage
P210
Keep away from heat/sparks/
open flames/hot surfaces. No smoking.
Manufacturer/supplier or the
competent authority to specify
applicable ignition source(s).
P370 + P378
In case of fire: Use ...
for extinction
...Manufacturer/supplier
or the competent
authority to specify
appropriate media.
- if water increases risk.
Precautionary statements
P240
Ground/Bond container and
receiving equipment.
- if electrostatically sensitive
material is for reloading.
44
CODE OF PRACTICE | LABELLING OF WORKPLACE HAZARDOUS CHEMICALS
Disposal
APPENDIX D - APPLICATION OF LABEL ELEMENTS
P241
Use explosion-proof
electrical/ventilating/
lighting/... /equipment.
... Manufacturer/supplier or
the competent authority to
specify other equipment.
- if dust clouds can occur.
P280
Wear protective gloves/eye
protection/face protection
Manufacturer/supplier or
the competent authority to
specify type of equipment.
SELF-REACTIVE SUBSTANCES AND MIXTURES
Symbol
Exploding bomb
Hazard category
Signal word
Hazard statement
Type A
Danger
H240 Heating may
cause an explosion
Prevention
Response
Storage
Disposal
P210
Keep away from heat/sparks/
open flames/hot surfaces. No smoking.
Manufacturer/supplier or
the competent authority to
specify applicable ignition
source(s).
P370 + P378
In case of fire: Use ...
for extinction.
... Manufacturer/
supplier or the
competent authority
to specify appropriate
media.
- if water increases risk.
P403 + P235
Store in a wellventilated place. Keep
cool.
P501
Dispose of contents/
container to...
...in accordance
with local/regional/
national/international
Regulations (to be
specified).
Precautionary statements
P220
Keep/Store away from
clothing/…/combustible
materials.
... Manufacturer/supplier or
the competent authority to
specify other incompatible
materials.
P370 + P380 + P375
In case of fire:
Evacuate area. Fight
fire remotely due to
the risk of explosion.
P411
Store at temperatures
not exceeding
…°C/…°F.
... Manufacturer/
supplier or the
competent authority
to specify temperature.
P420
Store away from other
materials.
P234
Keep only in original
container.
P280
Wear protective gloves/eye
protection/face protection.
Manufacturer/supplier or
the competent authority to
specify type of equipment.
CODE OF PRACTICE | LABELLING OF WORKPLACE HAZARDOUS CHEMICALS
45
APPENDIX D - APPLICATION OF LABEL ELEMENTS
SELF-REACTIVE SUBSTANCES AND MIXTURES
Symbol
Exploding bomb
and flame
Hazard category
Signal word
Hazard statement
Type B
Danger
H241 Heating may cause
a fire or explosion
Prevention
Response
Storage
Disposal
P210
Keep away from heat/sparks/
open flames/hot surfaces. No smoking.
Manufacturer/supplier or
the competent authority to
specify applicable ignition
source(s).
P370 + P378
In case of fire: Use ...
for extinction.
... Manufacturer/
supplier or the
competent authority
to specify appropriate
media.
- if water increases risk.
P403 + P235
Store in a well-ventilated
place. Keep cool.
P501
Dispose of contents/
container to...
...in accordance
with local/regional/
national/international
Regulations (to be
specified).
Precautionary statements
P220
Keep/Store away from
clothing/…/combustible
materials.
... Manufacturer/supplier or
the competent authority to
specify other incompatible
materials.
P370 + P380 + P375
In case of fire:
Evacuate area. Fight
fire remotely due to
the risk of explosion.
P411
Store at temperatures not
exceeding
…°C/…°F.
... Manufacturer/supplier or
the competent authority
to specify temperature.
P420
Store away from other
materials.
P234
Keep only in original
container.
P280
Wear protective gloves/eye
protection/face protection.
Manufacturer/supplier or
the competent authority to
specify type of equipment.
46
CODE OF PRACTICE | LABELLING OF WORKPLACE HAZARDOUS CHEMICALS
APPENDIX D - APPLICATION OF LABEL ELEMENTS
SELF-REACTIVE SUBSTANCES AND MIXTURES
Symbol
Flame
Hazard category
Signal word
Hazard statement
Type C
Danger
H242 Heating may cause a fire
Type D
Danger
H242 Heating may cause a fire
Type E
Warning
H242 Heating may cause a fire
Type F
Warning
H242 Heating may cause a fire
Prevention
Response
Storage
Disposal
P210
Keep away from heat/
sparks/open flames/hot
surfaces. - No smoking.
Manufacturer/supplier or
the competent authority to
specify applicable ignition
source(s).
P370 + P378
In case of fire: Use
...
for extinction.
... Manufacturer/
supplier or the
competent
authority to specify
appropriate media.
- if water increases
risk.
P403 + P235
Store in a well-ventilated place.
Keep cool.
P501
Dispose of contents/
container to...
...in accordance
with local/regional/
national/international
Regulations
(to be specified).
Precautionary statements
P220
Keep/Store away from
clothing/…/combustible
materials.
... Manufacturer/supplier or
the competent authority to
specify other incompatible
materials.
P411
Store at temperatures not
exceeding
…°C/…°F.
... Manufacturer/supplier or the
competent authority to specify
temperature.
P420
Store away from other materials
P234
Keep only in original
container.
P280
Wear protective gloves/eye
protection/face protection.
Manufacturer/supplier or
the competent authority to
specify type of equipment.
Note: Hazard category Type G: There are no label elements allocated to this hazard category
CODE OF PRACTICE | LABELLING OF WORKPLACE HAZARDOUS CHEMICALS
47
APPENDIX D - APPLICATION OF LABEL ELEMENTS
PYROPHORIC LIQUIDS
Symbol
Flame
Hazard category
Signal word
Hazard statement
1
Danger
H250 Catches fire
spontaneously if
exposed to air
Prevention
Response
Storage
P210
Keep away from heat/sparks/
open flames/hot surfaces. No smoking.
Manufacturer/supplier or the
competent authority to specify
applicable ignition source(s).
P302 + P334
IF ON SKIN: Immerse in
cool water/wrap with
wet bandages
P422
Store contents under...
... Manufacturer/supplier
or the competent
authority to specify
appropriate liquid or
inert gas.
Precautionary statements
P222
Do not allow contact with air.
P280
Wear protective gloves/eye
protection/face protection.
Manufacturer/supplier or the
competent authority to specify
type of equipment.
48
P370 + P378
In case of fire: Use ...
for extinction.
... Manufacturer/supplier
or the competent
authority to specify
appropriate media.
- if water increases risk.
CODE OF PRACTICE | LABELLING OF WORKPLACE HAZARDOUS CHEMICALS
Disposal
APPENDIX D - APPLICATION OF LABEL ELEMENTS
PYROPHORIC SOLIDS
Symbol
Flame
Hazard category
Signal word
Hazard statement
1
Danger
H250 Catches fire
spontaneously if
exposed to air
Prevention
Response
Storage
P210
Keep away from heat/sparks/
open flames/hot surfaces. No smoking.
Manufacturer/supplier or the
competent authority to specify
applicable ignition source(s).
P335 + P334
Brush off loose particles
from skin. Immerse in
cool water/wrap in wet
bandages.
P422
Store contents under...
... Manufacturer/supplier
or the competent
authority to specify
appropriate liquid or
inert gas.
Precautionary statements
P222
Do not allow contact with air.
P280
Wear protective gloves/eye
protection/face protection.
Manufacturer/supplier or the
competent authority to specify
type of equipment.
P370 + P378
In case of fire: Use ...
for extinction.
... Manufacturer/supplier or
the competent authority
to specify appropriate
media.
- if water increases risk.
Disposal
CODE OF PRACTICE | LABELLING OF WORKPLACE HAZARDOUS CHEMICALS
49
APPENDIX D - APPLICATION OF LABEL ELEMENTS
SELF-HEATING SUBSTANCES AND MIXTURES
Hazard category
Signal word
Hazard statement
1
Danger
H251 Self-heating; may
catch fire
2
Warning
H252 Self-heating in large
quantities; may catch fire
Response
Storage
Symbol
Flame
Precautionary statements
Prevention
P235 + P410
Keep cool. Protect from
sunlight.
P407
Maintain air gap between
stacks/pallets.
P280
Wear protective gloves/eye
protection/face protection.
Manufacturer/supplier or
the competent authority to
specify type of equipment.
P413
Store bulk masses
greater than … kg/…lbs
at temperatures not
exceeding …°C/…°F.
... Manufacturer/supplier or
the competent authority
to specify mass and
temperature.
P420
Store away from other
materials.
50
CODE OF PRACTICE | LABELLING OF WORKPLACE HAZARDOUS CHEMICALS
Disposal
APPENDIX D - APPLICATION OF LABEL ELEMENTS
SUBSTANCES AND MIXTURES WHICH, IN
CONTACT WITH WATER, EMIT FLAMMABLE GASES
Symbol
Flame
Hazard category
Signal word
Hazard statement
1
Danger
H260 In contact with
water releases flammable
gases, which may ignite
spontaneously 2
Danger
H261 In contact with water
releases flammable gases
Prevention
Response
Storage
Disposal
P223
Keep away from any
possible contact with water,
because of violent reaction
and possible flash fire.
P335 + P334
Brush off loose particles
from skin and immerse
in cool water/wrap in
wet bandages.
P402 + P404
Store in a dry place. Store
in a closed container.
P231 + P232
Handle under inert gas.
Protect from moisture.
P370 + P378
In case of fire: Use ... for
extinction
... Manufacturer/supplier
or the competent
authority to specify
appropriate media.
- if water increases risk.
P501
Dispose of contents/
container to...
…in accordance
with local/regional/
national/ international
Regulations (to be
specified).
Precautionary statements
P280
Wear protective gloves/eye
protection/face protection.
Manufacturer/supplier or
the competent authority to
specify type of equipment.
SUBSTANCES AND MIXTURES WHICH, IN
CONTACT WITH WATER, EMIT FLAMMABLE GASES
Symbol
Flame
Hazard category
Signal word
Hazard statement
3
Warning
H261 In contact with water
releases flammable gases
Prevention
Response
Storage
Disposal
P231 + P232
Handle under inert gas.
Protect from moisture.
P370 + P378
In case of fire: Use ...
for extinction
... Manufacturer/supplier
or the competent
authority to specify
appropriate media.
- if water increases risk.
P402 + P404
Store in a dry place. Store
in a closed container.
P501
Dispose of contents/
container to...
…in accordance
with local/regional/
national/ international
Regulations
(to be specified).
Precautionary statements
P280
Wear protective gloves/eye
protection/face protection.
Manufacturer/supplier or
the competent authority to
specify type of equipment.
CODE OF PRACTICE | LABELLING OF WORKPLACE HAZARDOUS CHEMICALS
51
APPENDIX D - APPLICATION OF LABEL ELEMENTS
OXIDISING LIQUIDS
Symbol
Flame over circle
Hazard category
Signal word
Hazard statement
1
Danger
H271 May cause fire
or explosion; strong
oxidiser
Prevention
Response
Storage
P210
Keep away from heat.
P220
Keep/Store away from
clothing and other
combustible materials.
P306 + P360
IF ON CLOTHING:
Rinse immediately
contaminated clothing
and skin with plenty of
water before removing
clothes.
P221
Take any precaution to avoid
mixing with combustibles/...
... Manufacturer/supplier or the
competent authority to specify
other incompatible materials.
P371 + P380 + P375
In case of major fire
and large quantities:
Evacuate area. Fight fire
remotely due to the risk
of explosion.
P280
Wear protective gloves /eye
protection/face protection.
Manufacturer/supplier or the
competent authority to specify
type of equipment.
P370 + P378
In case of fire: Use ...
for extinction
... Manufacturer/supplier
or the competent
authority to specify
appropriate media.
- if water increases risk.
Precautionary statements
P283
Wear fire/flame resistant/
retardant clothing.
52
CODE OF PRACTICE | LABELLING OF WORKPLACE HAZARDOUS CHEMICALS
Disposal
P501
Dispose of contents/
container to...
…in accordance
with local/regional/
national/international
Regulations
(to be specified).
APPENDIX D - APPLICATION OF LABEL ELEMENTS
OXIDISING LIQUIDS
Symbol
Flame over circle
Hazard category
Signal word
Hazard statement
2
Danger
H272 May intensify fire;
oxidiser
3
Warning
H272 May intensify fire;
oxidiser
Prevention
Response
Storage
P210
Keep away from heat.
P370 + P378
In case of fire: Use ...
for extinction
... Manufacturer/supplier
or the competent
authority to specify
appropriate media.
- if water increases risk.
Precautionary statements
P220
Keep/Store away from
clothing/…/combustible
materials.
…Manufacturer/supplier or
the competent authority to
specify other incompatible
materials.
Disposal
P501
Dispose of contents/
container to...
…in accordance
with local/regional/
national/international
Regulations
(to be specified).
P221
Take any precaution to avoid
mixing with combustibles/...
... Manufacturer/supplier or
the competent authority to
specify other incompatible
materials.
P280
Wear protective gloves/eye
protection/face protection.
Manufacturer/supplier or
the competent authority to
specify type of equipment.
CODE OF PRACTICE | LABELLING OF WORKPLACE HAZARDOUS CHEMICALS
53
APPENDIX D - APPLICATION OF LABEL ELEMENTS
OXIDISING SOLIDS
Symbol
Flame over circle
Hazard category
Signal word
Hazard statement
1
Danger
H271 May cause fire
or explosion; strong
oxidiser
Prevention
Response
Storage
P210
Keep away from heat.
P306 + P360
IF ON CLOTHING:
Rinse immediately
contaminated clothing
and skin with plenty of
water before removing
clothes.
Precautionary statements
P220
Keep away from clothing and
other combustible materials.
P221
Take any precaution to avoid
mixing with combustibles/...
... Manufacturer/supplier or the
competent authority to specify
other incompatible materials.
P280
Wear protective gloves/eye
protection/face protection.
Manufacturer/supplier or the
competent authority to specify
type of equipment.
P283
Wear fire/flame resistant/
retardant clothing.
54
P371 + P380 + P375
In case of major fire
and large quantities:
Evacuate area. Fight
fire remotely due to
the risk of explosion.
P370 + P378
In case of fire: Use ...
for extinction.
... Manufacturer/supplier
or the competent
authority to specify
appropriate media.
- if water increases risk.
CODE OF PRACTICE | LABELLING OF WORKPLACE HAZARDOUS CHEMICALS
Disposal
P501
Dispose of contents/
container to...
…in accordance
with local/regional/
national/international
Regulations
(to be specified).
APPENDIX D - APPLICATION OF LABEL ELEMENTS
OXIDISING SOLIDS
Symbol
Flame over circle
Hazard category
Signal word
Hazard statement
2
Danger
H272 May intensify fire;
oxidiser
3
Warning
H272 May intensify fire;
oxidiser
Prevention
Response
Storage
P210
Keep away from heat.
P370 + P378
In case of fire: Use ...
for extinction
... Manufacturer/supplier
or the competent
authority to specify
appropriate media.
- if water increases risk.
Precautionary statements
P220
Keep/Store away from
clothing/…/combustible
materials.
…Manufacturer/supplier or the
competent authority to specify
incompatible materials.
Disposal
P501
Dispose of contents/
container to...
…in accordance
with local/regional/
national/international
Regulations
(to be specified).
P221
Take any precaution to avoid
mixing with combustibles/... ...
Manufacturer/supplier or the
competent authority to specify
other incompatible materials.
P280
Wear protective gloves/eye
protection/face protection.
Manufacturer/supplier or the
competent authority to specify
type of equipment.
CODE OF PRACTICE | LABELLING OF WORKPLACE HAZARDOUS CHEMICALS
55
APPENDIX D - APPLICATION OF LABEL ELEMENTS
ORGANIC PEROXIDES
Symbol
Exploding bomb
Hazard category
Signal word
Hazard statement
Type A
Danger
H240 Heating may cause
an explosion
Response
Storage
Disposal
P210
Keep away from heat/sparks/
open flames/hot surfaces.No smoking.
Manufacturer/supplier or the
competent authority to specify
applicable ignition source(s).
P411 + P235
Store at temperatures not
exceeding …°C/…°F. Keep
cool.
... Manufacturer/supplier or
the competent authority to
specify temperature.
P220
Keep/Store away from
clothing/…/combustible
materials.
... Manufacturer/supplier or the
competent authority to specify
incompatible materials.
P410
Protect from sunlight.
P501
Dispose of contents/
container to...
…in accordance
with local/regional/
national/international
Regulations
(to be specified).
Precautionary statements
Prevention
P420
Store away from other
materials.
P234
Keep only in original container.
P280
Wear protective gloves/eye
protection/face protection.
Manufacturer/supplier or the
competent authority to specify
type of equipment.
56
CODE OF PRACTICE | LABELLING OF WORKPLACE HAZARDOUS CHEMICALS
APPENDIX D - APPLICATION OF LABEL ELEMENTS
Symbol
Exploding bomb
and flame
ORGANIC PEROXIDES
Hazard category
Signal word
Hazard statement
Type B
Danger
H241 Heating may cause
a fire or explosion
Precautionary statements
Prevention
Response
Storage
Disposal
P210
Keep away from heat/sparks/
open flames/hot surfaces.- No
smoking.
Manufacturer/supplier or the
competent authority to specify
applicable ignition source(s).
P411 + P235
Store at temperatures
not exceeding …°C/…°F.
Keep cool.
... Manufacturer/supplier or
the competent authority to
specify temperature.
P220
Keep/Store away from
clothing/…/combustible
materials.
... Manufacturer/supplier or the
competent authority to specify
incompatible materials.
P410
Protect from sunlight.
P501
Dispose of contents/
container to...
…in accordance
with local/regional/
national/international
Regulations
(to be specified).
P420
Store away from other
materials.
P234
Keep only in original container.
P280
Wear protective gloves/eye
protection/face protection.
Manufacturer/supplier or the
competent authority to specify
type of equipment.
CODE OF PRACTICE | LABELLING OF WORKPLACE HAZARDOUS CHEMICALS
57
APPENDIX D - APPLICATION OF LABEL ELEMENTS
ORGANIC PEROXIDES
Symbol
Flame
Hazard category
Signal word
Hazard statement
Type C
Danger
H242 Heating may cause a fire
Type D
Danger
H242 Heating may cause a fire
Type E
Warning
H242 Heating may cause a fire
Type F
Warning
H242 Heating may cause a fire
Response
Storage
Disposal
P411 + P235
Store at temperatures not
exceeding …°C/…°F. Keep cool.
... Manufacturer/supplier or the
competent authority to specify
temperature.
P501
Dispose of contents/
container to...
...in accordance
with local/regional/
national/international
Regulations
(to be specified).
Precautionary statements
Prevention
P210
Keep away from heat/sparks/
open flames/hot surfaces. - No
smoking.
Manufacturer/supplier or the
competent authority to specify
applicable ignition source(s).
P220
Keep/Store away from clothing/
…/combustible materials.
... Manufacturer/supplier or the
competent authority to specify
incompatible materials.
P410
Protect from sunlight.
P420
Store away from other
materials.
P234
Keep only in original container.
P280
Wear protective gloves/eye
protection/face protection.
Manufacturer/supplier or the
competent authority to specify
type of equipment.
Note: Hazard category Type G: There are no label elements allocated to this hazard category
58
CODE OF PRACTICE | LABELLING OF WORKPLACE HAZARDOUS CHEMICALS
APPENDIX D - APPLICATION OF LABEL ELEMENTS
CORROSIVE TO METALS
Symbol
Corrosion
Hazard category
Signal word
Hazard statement
1
Warning
H290 May be corrosive to
metals
Prevention
Response
Storage
P234
Keep only in original
container
P390
Absorb spillage to
prevent material
damage
P406
Store in corrosive resistant/...
container with a resistant
inner liner.
... Manufacturer/supplier or the
competent authority to specify
other compatible materials.
Precautionary statements
ACUTE TOXICITY - ORAL
Disposal
Symbol
Skull and crossbones
Hazard category
Signal word
Hazard statement
1
Danger
H300 Fatal if swallowed
2
Danger
H300 Fatal if swallowed
Prevention
Response
Storage
Disposal
P264
Wash …thoroughly after
handling.
… Manufacturer/supplier or
the competent authority
to specify parts of the
body to be washed after
handling.
P301 + P310
IF SWALLOWED:
Immediately call
a POISON CENTER
or doctor/physician.
P405
Store locked up.
P501
Dispose of contents/
container to...
... in accordance
with local/regional/
national/international
Regulations
(to be specified).
Precautionary statements
P270
Do not eat, drink or
smoke when using this
product.
P321
Specific treatment
(see ... on this label)
... Reference to
supplemental first aid
instruction.
- if immediate
administration of
antidote is required.
P330
Rinse mouth.
CODE OF PRACTICE | LABELLING OF WORKPLACE HAZARDOUS CHEMICALS
59
APPENDIX D - APPLICATION OF LABEL ELEMENTS
ACUTE TOXICITY - ORAL
Symbol
Skull and crossbones
Hazard category
Signal word
Hazard statement
3
Danger
H301 Toxic if swallowed
Prevention
Response
Storage
Disposal
P264
Wash …thoroughly
after handling.
… Manufacturer/supplier
or the competent
authority to specify
parts of the body to be
washed after handling.
P301 + P310
IF SWALLOWED:
Immediately call a POISON
CENTER or doctor/physician.
P405
Store locked up.
P501
Dispose of contents/
container to...
... in accordance
with local/regional/
national/international
Regulations
(to be specified).
Precautionary statements
P270
Do not eat, drink or
smoke when using this
product.
P321
Specific treatment (see ... on
this label)
... Reference to supplemental
first aid instruction.
- if immediate administration
of antidote is required.
P330
Rinse mouth.
ACUTE TOXICITY - ORAL
Symbol
Exclamation mark
Hazard category
Signal word
Hazard statement
4
Warning
H302 Harmful if
swallowed
Prevention
Response
Storage
P264
Wash …thoroughly after
handling.
… Manufacturer/supplier
or the competent
authority to specify
parts of the body to be
washed after handling.
P301 + P312
IF SWALLOWED: Call a
POISON CENTER or doctor/
physician if you feel unwell.
Precautionary statements
P330
Rinse mouth.
P270
Do not eat, drink or
smoke when using this
product.
60
CODE OF PRACTICE | LABELLING OF WORKPLACE HAZARDOUS CHEMICALS
Disposal
P501
Dispose of contents/
container to...
... in accordance
with local/regional/
national/international
Regulations
(to be specified).
APPENDIX D - APPLICATION OF LABEL ELEMENTS
ACUTE TOXICITY - DERMAL
Symbol
Skull and crossbones
Hazard category
Signal word
Hazard statement
1
Danger
H310 Fatal in contact
with skin 2
Danger
H310 Fatal in contact
with skin
Prevention
Response
Storage
Disposal
P262
Do not get in eyes, on skin,
or on clothing.
P302 + P350
IF ON SKIN: Gently wash with
plenty of soap and water.
P405
Store locked up.
P264
Wash … thoroughly after
handling
… Manufacturer/supplier or
the competent authority to
specify parts of the body to
be washed after handling.
P310
Immediately call a POISON
CENTRE or doctor/physician.
P501
Dispose of contents/
container to...
…in accordance
with local/regional/
national/international
Regulations
(to be specified).
Precautionary statements
P270
Do not eat, drink or smoke
when using this product.
P280
Wear protective gloves/
protective clothing.
Manufacturer/supplier or
the competent authority to
specify type of equipment.
P322
Specific measures (see ... on
this label)
... Reference to supplemental
first aid instruction.
- if immediate measures such
as specific cleansing agent is
advised.
P361
Remove/Take off immediately
all contaminated clothing.
P363
Wash contaminated clothing
before reuse.
CODE OF PRACTICE | LABELLING OF WORKPLACE HAZARDOUS CHEMICALS
61
APPENDIX D - APPLICATION OF LABEL ELEMENTS
ACUTE TOXICITY - DERMAL
Symbol
Skull and crossbones
Hazard category
Signal word
Hazard statement
3
Danger
H311 Toxic in contact
with skin
Prevention
Response
Storage
Disposal
P280
Wear protective gloves/
protective clothing.
Manufacturer/supplier
or the competent
authority to specify type
of equipment.
P302 + P352
IF ON SKIN: Wash with plenty
of soap and water.
P405
Store locked up.
P501
Dispose of contents/
container to...
... in accordance
with local/regional/
national/international
Regulations
(to be specified).
Precautionary statements
P312
Call a POISON CENTRE or
doctor/physician if you feel
unwell.
P322
Specific measures (see ...
on this label)
... Reference to supplemental
first aid instruction.
- if measures such as specific
cleansing agent is advised.
P361
Remove/Take off immediately
all contaminated clothing.
P363
Wash contaminated
clothing before reuse.
62
CODE OF PRACTICE | LABELLING OF WORKPLACE HAZARDOUS CHEMICALS
APPENDIX D - APPLICATION OF LABEL ELEMENTS
ACUTE TOXICITY - DERMAL
Symbol
Exclamation mark
Hazard category
Signal word
Hazard statement
4
Warning
H312 Harmful in contact
with skin
Prevention
Response
Storage
P280
Wear protective gloves/
protective clothing.
Manufacturer/supplier
or the competent authority
to specify type of
equipment.
P302 + P352
IF ON SKIN: Wash with
plenty of soap and water.
Precautionary statements
P312
Call a POISON CENTRE or
doctor/physician if you feel
unwell.
Disposal
P501
Dispose of contents/
container to...
... in accordance
with local/regional/
national/international
Regulations
(to be specified).
P322
Specific measures
(see ... on this label)
... Reference to
supplemental first aid
instruction.
- if measures such as specific
cleansing agent is advised.
P363
Wash contaminated
clothing before reuse.
CODE OF PRACTICE | LABELLING OF WORKPLACE HAZARDOUS CHEMICALS
63
APPENDIX D - APPLICATION OF LABEL ELEMENTS
ACUTE TOXICITY - INHALATION
Symbol
Skull and crossbones
Hazard category
Signal word
Hazard statement
1
Danger
H330 Fatal if inhaled
2
Danger
H330 Fatal if inhaled
Prevention
Response
Storage
Disposal
P260
Do not breathe dust/fume/
gas/mist/ vapours/spray.
Manufacturer/supplier or
the competent authority
to specify applicable
conditions.
P304 + P340
IF INHALED: Remove victim
to fresh air and keep at rest
in a position comfortable for
breathing.
P403 + P233
Store in a wellventilated place.
Keep container
tightly closed.
- if product is
volatile as to
generate hazardous
atmosphere.
P501
Dispose of contents/
container to...
... in accordance
with local/regional/
national/international
Regulations
(to be specified).
Precautionary statements
P271
Use only outdoors or in a
well-ventilated area.
P284
Wear respiratory
protection.
Manufacturer/supplier or
the competent authority to
specify equipment.
P310
Immediately call a POISON
CENTER or doctor/physician.
P320
Specific treatment is urgent
(see ... on this label)
... Reference to supplemental
first aid instruction.
- if immediate administration
of antidote is required.
P405
Store locked up.
64
CODE OF PRACTICE | LABELLING OF WORKPLACE HAZARDOUS CHEMICALS
APPENDIX D - APPLICATION OF LABEL ELEMENTS
ACUTE TOXICITY - INHALATION
Symbol
Skull and crossbones
Hazard category
Signal word
Hazard statement
3
Danger
H331 Toxic if inhaled
Prevention
Response
Storage
Disposal
P261
Avoid breathing dust/
fume/gas/mist/ vapours/
spray.
Manufacturer/supplier or
the competent authority
to specify applicable
conditions.
P304 + P340
IF INHALED: Remove victim
to fresh air and keep at rest
in a position comfortable for
breathing.
P403 + P233
Store in a wellventilated place. Keep
container tightly
closed.
- if product is volatile
so as to generate
hazardous atmosphere.
P501
Dispose of contents/
container to...
... in accordance
with local/regional/
national/international
Regulations
(to be specified).
Precautionary statements
P271
Use only outdoors or in a
well-ventilated area.
P311
Call a POISON CENTER or
doctor/physician.
P321
Specific treatment (see ... on
this label)
... Reference to supplemental
first aid instruction.
- if immediate specific measures
are required.
P405
Store locked up.
ACUTE TOXICITY - INHALATION
Symbol
Exclamation mark
Hazard category
Signal word
Hazard statement
4
Warning
H332 Harmful if
inhaled
Prevention
Response
Storage
P261
Avoid breathing dust/fume/
gas/mist/ vapours/spray.
Manufacturer/supplier or the
competent authority to specify
applicable conditions.
P304 + P340
IF INHALED: Remove victim
to fresh air and keep at rest
in a position comfortable for
breathing.
Precautionary statements
P271
Use only outdoors or in a
well-ventilated area.
Disposal
P312
Call a POISON CENTER or
doctor/physician if you feel
unwell.
CODE OF PRACTICE | LABELLING OF WORKPLACE HAZARDOUS CHEMICALS
65
APPENDIX D - APPLICATION OF LABEL ELEMENTS
SKIN CORROSION/IRRITATION
Symbol
Corrosion
Hazard category
Signal word
Hazard statement
1A to 1C
Danger
H314 Causes severe
skin burns and eye
damage
Prevention
Response
Storage
Disposal
P260
Do not breathe dusts
or mists.
- if inhalable particles of
dusts or mists may occur
during use.
P301 + P330 + P331
IF SWALLOWED: Rinse mouth.
Do NOT induce vomiting.
P405
Store locked up.
P501
Dispose of contents/
container to...
... in accordance
with local/regional/
national/international
Regulations
(to be specified).
Precautionary statements
P264
Wash …thoroughly after
handling.
…Manufacturer/supplier or
the competent authority
to specify parts of the
body to be washed after
handling.
P280
Wear protective gloves/
protective clothing/
eye protection/face
protection.Manufacturer/
supplier or the competent
authority to specify type
of equipment.
P303 + P361 + P353
IF ON SKIN (or hair): Remove/
Take off immediately all
contaminated clothing. Rinse
skin with water/shower.
P363
Wash contaminated clothing
before reuse.
P304 + P340
IF INHALED: Remove victim
to fresh air and keep at rest
in a position comfortable for
breathing.
P310
Immediately call a POISON
CENTER or doctor/physician.
P321
Specific treatment (see ...
on this label)
... Reference to supplemental
first aid instruction.
- Manufacturer/supplier or the
competent authority may
specify a cleansing agent if
appropriate.
P305 + P351 + P338
IF IN EYES: Rinse cautiously
with water for several minutes.
Remove contact lenses, if
present and easy to do.
Continue rinsing.
66
CODE OF PRACTICE | LABELLING OF WORKPLACE HAZARDOUS CHEMICALS
APPENDIX D - APPLICATION OF LABEL ELEMENTS
SKIN CORROSION/IRRITATION
Symbol
Exclamation mark
Hazard category
Signal word
Hazard statement
2
Warning
H315 Causes skin
irritation
Precautionary statements
Prevention
Response
P264
Wash …thoroughly after
handling.
…Manufacturer/supplier or
the competent authority to
specify parts of the body to be
washed after handling.
P302 + P352
IF ON SKIN: Wash with
plenty of soap and water.
P280
Wear protective gloves.
Manufacturer/supplier or the
competent authority to specify
type of equipment.
Storage
Disposal
P321
Specific treatment (see ...
on this label)
... Reference to supplemental
first aid instruction.
- Manufacturer/supplier or the
competent authority may
specify a cleansing agent if
appropriate.
P332 + P313
If skin irritation occurs: Get
medical advice/attention.
P362
Take off contaminated
clothing and wash before
reuse.
CODE OF PRACTICE | LABELLING OF WORKPLACE HAZARDOUS CHEMICALS
67
APPENDIX D - APPLICATION OF LABEL ELEMENTS
SERIOUS EYE DAMAGE/IRRITATION
Symbol
Corrosion
Hazard category
Signal word
Hazard statement
1
Danger
H318 Causes serious
eye damage
Precautionary statements
Prevention
Response
P280
Wear eye protection/
face protection.
Manufacturer/supplier or
the competent authority
to specify type of
equipment.
P305 + P351 + P338
IF IN EYES: Rinse cautiously
with water for several minutes.
Remove contact lenses,
if present and easy to do.
Continue rinsing.
Storage
Disposal
P310
Immediately call a POISON
CENTER or doctor/physician.
SERIOUS EYE DAMAGE/IRRITATION
Symbol
Exclamation mark
Hazard category
Signal word
Hazard statement
2A
Warning
H319 Causes serious
eye irritation
Prevention
Response
Storage
P264
Wash … thoroughly
after handling.
… Manufacturer/supplier
or
the competent authority
to specify parts of the
body to be washed after
handling.
P305 + P351 + P338
IF IN EYES: Rinse cautiously
with water for several minutes.
Remove contact lenses, if
present and easy to do.
Continue rinsing.
Precautionary statements
P337 + P313
If eye irritation persists: Get
medical advice/attention.
P280
Wear eye protection/
face protection.
Manufacturer/supplier or
the competent authority
to specify type of
equipment.
68
CODE OF PRACTICE | LABELLING OF WORKPLACE HAZARDOUS CHEMICALS
Disposal
APPENDIX D - APPLICATION OF LABEL ELEMENTS
SENSITISATION – RESPIRATORY
Symbol
Health hazard
Hazard category
Signal word
Hazard statement
1, 1A, 1B
Danger
H334 May cause allergy
or asthma symptoms
or breathing difficulties
if inhaled
Precautionary statements
Prevention
Response
P261
Avoid breathing dust/fume/
gas/mist/ vapours/spray.
Manufacturer/supplier or
the competent authority to
specify applicable conditions.
P304 + P341
IF INHALED: If breathing
is difficult, remove victim
to fresh air and keep
at rest in a position
comfortable for breathing.
P285
In case of inadequate
ventilation wear respiratory
protection.
Manufacturer/supplier or
the competent authority
to specify equipment.
P342 + P311
If experiencing respiratory
symptoms: Call a POISON
CENTER or doctor/
physician
Storage
CODE OF PRACTICE | LABELLING OF WORKPLACE HAZARDOUS CHEMICALS
Disposal
P501
Dispose of contents/
container to...
... in accordance
with local/regional/
national/international
Regulations
(to be specified).
69
APPENDIX D - APPLICATION OF LABEL ELEMENTS
SENSITISATION – SKIN
Symbol
Exclamation mark
Hazard category
Signal word
Hazard statement
1, 1A, 1B
Warning
H317 May cause an
allergic skin reaction
Prevention
Response
Storage
P261
Avoid breathing dust/fume/
gas/mist/ vapours/spray.
Manufacturer/supplier or
the competent authority to
specify applicable conditions.
P302 + P352
IF ON SKIN: Wash with
plenty of soap and water.
Precautionary statements
P272
Contaminated work clothing
should not be allowed out of
the workplace.
P280
Wear protective gloves.
Manufacturer/supplier or
the competent authority to
specify type of equipment.
P333 + P313
If skin irritation or rash
occurs: Get medical
advice/attention.
P321
Specific treatment
(see ... on this label)
... Reference to
supplemental first aid
instruction.
- Manufacturer/supplier or
the competent authority
may specify a cleansing
agent if appropriate.
P363
Wash contaminated
clothing before reuse.
70
CODE OF PRACTICE | LABELLING OF WORKPLACE HAZARDOUS CHEMICALS
Disposal
P501
Dispose of contents/
container to...
... in accordance
with local/regional/
national/international
Regulations
(to be specified).
APPENDIX D - APPLICATION OF LABEL ELEMENTS
GERM CELL MUTAGENICITY
Symbol
Health hazard
Hazard category
Signal word
Hazard statement
1A, 1B
Danger
H340 May cause genetic defects <...>
2
Warning
H341 Suspected of causing genetic
defects <...> <...> (state route of exposure if it
is conclusively proven that no other
routes of exposure cause the hazard)
Prevention
Response
Storage
Disposal
P201
Obtain special instructions
before use.
P308 + P313
IF exposed
or concerned:
Get medical
advice/
attention.
P405
Store locked up.
P501
Dispose of contents/
container to...
... in accordance
with local/regional/
national/international
Regulations
(to be specified).
Precautionary statements
P202
Do not handle until all
safety precautions have
been read and understood.
P281
Use personal protective
equipment as required.
CARCINOGENICITY
Symbol
Health hazard
Hazard category
Signal word
Hazard statement
1A, 1B
Danger
H350 May cause cancer <...> 2
Warning
H351 Suspected of causing cancer <...>
<...> (state route of exposure if it is
conclusively proven that no other routes
of exposure cause the hazard).
Prevention
Response
Storage
Disposal
P201
Obtain special instructions
before use.
P308 + P313
IF exposed or
concerned: Get
medical advice/
attention.
P405
Store locked up.
P501
Dispose of contents/
container to...
... in accordance
with local/regional/
national/international
Regulations (to be
specified).
Precautionary statements
P202
Do not handle until all
safety precautions have
been read and understood.
P281
Use personal protective
equipment as required.
CODE OF PRACTICE | LABELLING OF WORKPLACE HAZARDOUS CHEMICALS
71
APPENDIX D - APPLICATION OF LABEL ELEMENTS
TOXIC TO REPRODUCTION
Symbol
Health hazard
Hazard category
Signal word
Hazard statement
1A, 1B
Danger
H360 May damage fertility or
the unborn child <...> <<...>>
2
Warning
H361 Suspected of damaging
fertility or the unborn child
<...> <<...>> <...> (state specific effect if
known)
<<...>> (state route of exposure if
it is conclusively proven that no
other routes of exposure cause
the hazard)
Prevention
Response
Storage
Disposal
P201
Obtain special instructions
before use.
P308 + P313
IF exposed or
concerned: Get
medical advice/
attention.
P405
Store locked up.
P501
Dispose of contents/
container to...
... in accordance
with local/regional/
national/international
Regulations
(to be specified).
Precautionary statements
P202
Do not handle until all
safety precautions have
been read and understood.
P281
Use personal protective
equipment as required.
72
CODE OF PRACTICE | LABELLING OF WORKPLACE HAZARDOUS CHEMICALS
APPENDIX D - APPLICATION OF LABEL ELEMENTS
TOXIC TO REPRODUCTION
(effects on or via lactation)
Symbol
No symbol
Hazard category
Signal word
Hazard statement
(additional)
No signal word
H362 May cause harm to
breast-fed children
Precautionary statements
Prevention
Response
P201
Obtain special instructions before
use.
P308 + P313
IF exposed or
concerned: Get
medical advice/
attention.
P260
Do not breathe dusts
or mists.
- if inhalable particles of dusts or
mists may occur during use.
Storage
Disposal
P263
Avoid contact during pregnancy/
while nursing.
P264
Wash … thoroughly after handling.
…Manufacturer/supplier or the
competent authority to specify
parts of the body to be washed
after handling.
P270
Do not eat, drink or smoke when
using this product.
CODE OF PRACTICE | LABELLING OF WORKPLACE HAZARDOUS CHEMICALS
73
APPENDIX D - APPLICATION OF LABEL ELEMENTS
SPECIFIC TARGET ORGAN TOXICITY
(Single Exposure)
Symbol
Health hazard
Hazard category
Signal word
Hazard statement
1
Danger
H370 Causes damage to organs
<...> <<...>> <...> (or state all organs affected
if known)
<<...>> (state route of exposure
if it is conclusively proven that no
other routes of exposure cause
the hazard)
Prevention
Response
Storage
Disposal
P260
Do not breathe dust/
fume/gas/mist/ vapours/
spray.Manufacturer/
supplier or the competent
authority to specify
applicable conditions.
P307 + P311
IF exposed: Call a
POISON CENTER
or doctor/physician.
P405
Store locked up.
P501
Dispose of contents/
container to...
... in accordance
with local/regional/
national/international
Regulations
(to be specified).
Precautionary statements
P264
Wash …thoroughly after
handling.
… Manufacturer/supplier or
the competent authority
to specify parts of the
body to be washed after
handling.
P321
Specific treatment
(see ... on this label)
... Reference to
supplemental first
aid instruction.
- if immediate
measures are
required.
P270
Do not eat, drink or
smoke when using this
product.
74
CODE OF PRACTICE | LABELLING OF WORKPLACE HAZARDOUS CHEMICALS
APPENDIX D - APPLICATION OF LABEL ELEMENTS
SPECIFIC TARGET ORGAN TOXICITY
(Single Exposure)
Symbol
Health hazard
Hazard category
Signal word
Hazard statement
2
Warning
H371 May cause damage to
organs <...> <<...>>
<...> (or state all organs affected,
if known)
<<...>> (state route of exposure
if it is conclusively proven that
no other routes of exposure
cause the hazard)
Prevention
Response
Storage
Disposal
P260
Do not breathe dust/fume/
gas/mist/vapours/spray.
Manufacturer/supplier or
the competent authority
to specify applicable
conditions.
P309 + P311
IF exposed or if
you feel unwell: Call
a POISON CENTER
or doctor/physician.
P405
Store locked up.
P501
Dispose of contents/
container to...
... in accordance
with local/regional/
national/international
Regulations
(to be specified).
Precautionary statements
P264
Wash …thoroughly
after handling.
… Manufacturer/supplier or
the competent authority to
specify parts of the body to
be washed after handling.
P270
Do not eat, drink or smoke
when using this product.
CODE OF PRACTICE | LABELLING OF WORKPLACE HAZARDOUS CHEMICALS
75
APPENDIX D - APPLICATION OF LABEL ELEMENTS
SPECIFIC TARGET ORGAN TOXICITY
(Single Exposure)
Hazard category
Signal word
Hazard statement
3
Warning
H335 May cause respiratory
irritation; or Symbol
Exclamation mark
H336 May cause drowsiness
or dizziness
Precautionary statements
Prevention
Response
Storage
Disposal
P261
Avoid breathing dust/fume/
gas/mist/vapours/spray.
Manufacturer/supplier or
the competent authority to
specify applicable conditions.
P304 + P340
IF INHALED:
Remove victim to
fresh air and keep
at rest in a position
comfortable for
breathing.
P403 + P233
Store in a well-ventilated place.
Keep container tightly closed.
- if product is volatile so as to
generate hazardous atmosphere.
P501
Dispose of contents/
container to...
... in accordance
with local/regional/
national/international
Regulations
(to be specified).
P271
Use only outdoors or in
a well-ventilated area.
76
P405
Store locked up.
P312
Call a POISON
CENTER or doctor/
physician if you
feel unwell.
CODE OF PRACTICE | LABELLING OF WORKPLACE HAZARDOUS CHEMICALS
APPENDIX D - APPLICATION OF LABEL ELEMENTS
SPECIFIC TARGET ORGAN TOXICITY
(Repeated Exposure)
Hazard category
Signal word
Hazard statement
1
Danger
H372 Causes damage to
organs <...> through prolonged
or repeated exposure <<...>> <...> (state all organs affected,
if known)
<<...>> (state route of exposure if
it is conclusively proven that no
other routes of exposure cause
the hazard)
Prevention
Response
Storage
P260
Do not breathe dust/fume/
gas/mist/ vapours/spray.
Manufacturer/supplier or
the competent authority to
specify applicable conditions.
P314
Get medical advice/
attention if you feel
unwell.
Symbol
Health hazard
Precautionary statements
P264
Wash … thoroughly after
handling.
…Manufacturer/supplier or
the competent authority to
specify parts of the body to
be washed after handling.
Disposal
P501
Dispose of contents/
container to...
... in accordance
with local/regional/
national/international
Regulations
(to be specified).
P270
Do not eat, drink or smoke
when using this product.
CODE OF PRACTICE | LABELLING OF WORKPLACE HAZARDOUS CHEMICALS
77
APPENDIX D - APPLICATION OF LABEL ELEMENTS
SPECIFIC TARGET ORGAN TOXICITY
(Repeated Exposure)
Hazard category
Signal word
Hazard statement
2
Warning
H373 May cause damage to
organs <...> through prolonged or
repeated exposure <<...>> <...> (state all organs affected,
if known)
<<...>> (state route of exposure if
it is conclusively proven that no
other routes of exposure cause
the hazard)
Prevention
Response
Storage
P260
Do not breathe dust/fume/
gas/mist/ vapours/spray.
Manufacturer/supplier or
the competent authority to
specify applicable conditions.
P314
Get medical
advice/
attention if you
feel unwell.
Symbol
Health hazard
Precautionary statements
Disposal
P501
Dispose of contents/
container to...
... in accordance
with local/regional/
national/international
Regulations (to be
specified).
ASPIRATION HAZARD
Symbol
Health hazard
Hazard category
Signal word
Hazard statement
1
Danger
H304 May be fatal if swallowed
and enters airways
Precautionary statements
Prevention
Response
Storage
Disposal
P301 + P310
IF SWALLOWED:
Immediately call a
POISON CENTER
or doctor/
physician.
P405
Store locked up.
P501
Dispose of contents/
container to...
... in accordance
with local/regional/
national/international
Regulations (to be
specified).
P331
Do NOT induce
vomiting.
78
CODE OF PRACTICE | LABELLING OF WORKPLACE HAZARDOUS CHEMICALS
ADDITIONAL NON-GHS HAZARD STATEMENTS
Regulation 335
Schedule 9
A label must include any information about the hazards, first aid and emergency
procedures relevant to the chemical, not otherwise included in the hazard statement
and precautionary statements.
The following twelve non-GHS hazard statements should be used on labels of hazardous
chemicals where applicable.
PHYSICAL HAZARD STATEMENTS
AUH001: Explosive when dry
For explosive substances and mixtures placed on the market wetted with water or alcohols
or diluted with other chemicals to suppress their explosives properties.
AUH006: Explosive with or without contact with air
For substances and mixtures that are unstable at ambient temperatures, for example
acetylene.
AUH014: Reacts violently with water
For substances and mixtures that react violently with water, for example acetyl chloride,
alkali metals and titanium tetrachloride.
AUH018: In use, may form flammable/explosive vapour-air mixture
For substances and mixtures not classified as flammable themselves but which may
form flammable/explosive vapour-air mixtures. For substances this might be the case
for halogenated hydrocarbons and for mixtures this might be the case due to a volatile
flammable component or due to the loss of a volatile non-flammable component.
AUH019: May form explosive peroxides
For substances and mixtures that may form explosive peroxides during storage, for example
diethyl ether, 1,4-dioxan.
AUH044: Risk of explosion if heated under confinement
For substances and mixtures not classified as explosive but which may nevertheless
display explosive properties in practice if heated under sufficient confinement. In particular,
substances and mixtures that decompose explosively if heated in a steel drum do not show
this effect if heated in less-strong containers.
HUMAN HEALTH HAZARD STATEMENTS
AUH029: Contact with water liberates toxic gas
For substances and mixtures, when in contact with water or damp air, evolve gases classified
for acute toxicity in Category 1, 2 or 3 in potentially dangerous amounts, for example
aluminium phosphide, phosphorus pentasulphide.
AUH031: Contact with acids liberates toxic gas
For substances and mixtures that react with acids to evolve gases classified for acute
toxicity in Category 3 in dangerous amounts, for example sodium hypochlorite and barium
polysulphide.
CODE OF PRACTICE | LABELLING OF WORKPLACE HAZARDOUS CHEMICALS
79
ADDITIONAL NON-GHS HAZARD STATEMENTS
AUH032: Contact with acids liberates very toxic gas
For substances and mixtures that react with acids to evolve gases classified for acute
toxicity in Category 1 or 2 in dangerous amounts, for example salts of hydrogen cyanide,
sodium azide.
AUH066: Repeated exposure may cause skin dryness or cracking
For substances and mixtures which may cause concern as a result of skin dryness, flaking or
cracking but which do not meet the criteria for skin irritancy.
AUH070: Toxic by eye contact
For substances or mixtures where an eye irritation test has resulted in overt signs of systemic
toxicity or mortality among the animals tested, which is likely to be attributed to absorption
of the substance or mixture through the mucous membranes of the eye. The statement
should also be applied if there is evidence in humans for systemic toxicity after eye contact.
The statement should also be applied where a substance or a mixture contains another
substance labelled for this effect, if the concentration of this substance is equal to, or greater
than 0.1 %.
AUH071: Corrosive to the respiratory tract
For substances and mixtures in addition to classification for inhalation toxicity, if data is
available that indicates the mechanism of toxicity was corrosivity.
In addition to an appropriate acute toxicity symbol, a ‘corrosion’ symbol (similar to the
‘corrosion’ symbol used for skin and eye corrosivity) is added along with the hazard
statement AUH071: Corrosive to the respiratory tract.
For substances and mixtures in addition to classification for skin corrosivity, if no acute
inhalation test data is available and which may be inhaled.
80
CODE OF PRACTICE | LABELLING OF WORKPLACE HAZARDOUS CHEMICALS
APPENDIX E - PRECEDENCE
RULES OF LABEL ELEMENTS
This appendix provides information on the rules of precedence of certain label elements, and
general guidance for when redundant elements may be omitted from a label.
Duplication or redundancy of label elements may occur where a hazardous chemical meets
the criteria for more than one hazard class or category. Duplication of an element may occur
where:
„„
specific precautionary statement applies to several hazard categories into which a
a
particular chemical is classified
„„
n element may become redundant because a more stringent control applies to another
a
hazard category (for example, the type of PPE required).
Duplicate or redundant information should not be included on a label.
Multiple Hazards and Precedence
of Hazard Information
HAZARD PICTOGRAMS
The following rules apply for the use of hazard pictograms on a label:
„„
where a transport of dangerous goods class label (pictogram) is required on the
container to meet transport regulations, the equivalent hazard pictogram, as specified in
the GHS, should not appear
„„
if the skull and crossbones hazard pictogram applies, the exclamation mark hazard
pictogram should not appear
„„
if the corrosive hazard pictogram applies, the exclamation mark hazard pictogram should
not appear if it is used to communicate skin or eye irritation
„„
if the health hazard pictogram appears for respiratory sensitisation, the exclamation
mark hazard pictogram should not appear if it is used to communicate skin sensitisation,
or for skin or eye irritation.
HAZARD STATEMENTS
Where hazard statements are required to be present on a label, then all of the assigned
hazard statements must appear on the label except where:
„„
the statement duplicates or conflicts with another statement or other hazard information
that is required on the label
„„
mission of the statement would not decrease the level of protection or information in
o
relation to the hazards.
SIGNAL WORDS
Where the signal word ‘Danger’ applies, the signal word ‘Warning’ should not appear
concomitantly.
PRECAUTIONARY STATEMENTS
Where precautionary statements are required to be present on a label, then normally not
more than six to ten precautionary statements are required, unless necessary to reflect
the nature and the severity of the hazards. For example, precautionary statements can be
omitted if:
CODE OF PRACTICE | LABELLING OF WORKPLACE HAZARDOUS CHEMICALS
81
APPENDIX E - PRECEDENCE RULES OF LABEL ELEMENTS
„„
the statement duplicates or conflicts with another statement or other hazard information
that is required on the label; and
„„
mission of the statement would not decrease the level of protection or information in
o
relation to the hazards.
Any conflict that arises between precautionary statements that are present on labels may be
resolved by modifying the statements. However, the new statement(s) must give equivalent
levels of information or protection.
Note: It is not mandatory to include information relating to environmental hazard categories
on the label of a workplace hazardous chemical. However, this information should be
included if a fully GHS-compliant label is desired.
EXAMPLE OF WHERE THE OMISSION OF A PRECAUTIONARY STATEMENT IS
ACCEPTABLE
An example where the omission of a precautionary statement on the label may be
acceptable (and recommended) is where the use of personal protective equipment applies
to different hazard categories for the same hazardous chemical.
For example, where the precautionary statements ‘Wear face protection’ and ‘Wear gloves
and face protection’ are specified, then only the latter statement should appear on the label
as it relates to the more stringent protective measures.
EXAMPLE THAT ILLUSTRATES HOW SOME OF THE PRECEDENCE RULES FOR ELEMENTS
SHOULD BE APPLIED ON LABELS
In the following example, the chemical meets the criteria for flammable liquid (Category 2)
and skin sensitisation (Category 1), as specified in the GHS.
The label that contains all of the elements required to meet the criteria for a substance or
mixture that is classified as a flammable liquid (Category 2) and skin sensitiser (Category 1)
is provided below. No precedence rules are applied:
82
CODE OF PRACTICE | LABELLING OF WORKPLACE HAZARDOUS CHEMICALS
APPENDIX E - PRECEDENCE RULES OF LABEL ELEMENTS
Flammable liquid
(Category 2)
Skin sensitisation
(Category 1)
Signal word
Danger
Warning
Hazard statement
Highly flammable liquid and vapour
May cause an allergic skin reaction
- Keep away from heat/sparks/open
flames/hot surfaces.– No smoking.
Manufacturer/supplier or the competent
authority to specify applicable ignition
source(s).
- Avoid breathing dust/fume/gas/mist/
vapours/spray.
Manufacturer/supplier or the
competent authority to specify
applicable conditions.
- Keep container tightly closed.
- Contaminated work clothing should
not be allowed out of the workplace.
Hazard Pictogram
Precautionary
Statements
- Ground/Bond container and receiving
equipment
„„
if electrostatically sensitive material
is for reloading.
„„
if product is volatile so as to generate
hazardous atmosphere.
- Use explosion-proof electrical/
ventilating/lighting/.../equipment.
Manufacturer/supplier or the competent
authority to specify other equipment.
- Use only non-sparking tools.
Take precautionary measures against
static discharge.
- Wear protective gloves/eye protection/
face protection
Manufacturer/supplier or the competent
authority to specify type of equipment
.- IF ON SKIN (or hair): Remove/take off
immediately all contaminated clothing.
- Wear protective gloves.
Manufacturer/supplier or the competent
authority to specify type of equipment.
- IF ON SKIN: Wash with plenty
of soap and water.
- If skin irritation or rash occurs:
Get medical advice/attention.
- Specific treatment
(see ... on this label)
...Reference to supplemental first aid
instruction.
- Manufacturer/supplier or the
competent authority may specify
a cleansing agent if appropriate.
- Wash contaminated clothing
before reuse.
- Dispose of contents/container to...
In accordance with local requirements
(to be specified).
- Rinse skin with water/shower.
- In case of fire: Use ... for extinction
...Manufacturer/supplier or the competent
authority to specify appropriate media
- if water increases risk.
- Store in a well-ventilated place.
CODE OF PRACTICE | LABELLING OF WORKPLACE HAZARDOUS CHEMICALS
83
APPENDIX E - PRECEDENCE RULES OF LABEL ELEMENTS
Precautionary
Statements
- Keep cool.
- Dispose of contents/container to …
in accordance with local requirements (to
be specified).
According to the precedence rules described above, the following elements should be omitted from the label:
„„ The signal word ‘Warning’ because ‘Danger’ applies.
„„ The precautionary statement ‘Wear protective gloves…’ because the statement ‘Wear protective gloves and
eye protection/face protection…’ also applies, and therefore provides for more stringent PPE controls.
„„ The statement ‘Dispose of contents/container to…’ as this is duplicated and should only appear on the label
once.
The following precautionary statements refer to similar controls and may be combined to aid comprehensibility
and to save label space:
„„
IF ON SKIN (or hair): Remove/take off immediately all contaminated clothing
„„
IF ON SKIN: Wash with plenty of soap and water
These statements could be combined to read:
„„
IF ON SKIN (or hair): Remove/take off immediately all contaminated clothing and wash skin (or hair) with
plenty of soap and water.
The label elements that apply to a flammable liquid (Category 2) and skin sensitiser (Category 1) with the
precedence rules applied are:
Signal word
Danger
Hazard statement
Highly flammable liquid and vapour
May cause an allergic skin reaction
Hazard Pictogram
Precautionary
Statements
84
- Keep container tightly closed.
- Keep away from heat/sparks/open flame/hot surfaces – No smoking.
...Manufacturer/supplier or the competent authority to specify applicable
ignition source(s).
CODE OF PRACTICE | LABELLING OF WORKPLACE HAZARDOUS CHEMICALS
APPENDIX E - PRECEDENCE RULES OF LABEL ELEMENTS
Precautionary
Statements
- Ground/Bond container and receiving equipment.
- if electrostatically sensitive material is for reloading.
- if product is as volatile as to generate hazardous atmosphere:
- Use explosion-proof electrical/ventilating/lighting/…/equipment.
Manufacturer/supplier or the competent authority to specify other equipment.
- Use only non-sparking tools.
- Take precautionary measures against static discharge.
- Wear protective gloves and eye protection/face protection
Manufacturer/supplier or the competent authority to specify type of equipment.
- Avoid breathing dust/fume/gas/mist/vapours/spray.
Manufacturer/supplier or the competent authority to specify applicable conditions.
- Contaminated work clothing should not be allowed out of the workplace.
- In case of fire: Use ... for extinction.
...Manufacturer/supplier or the competent authority to specify appropriate media..
- if water increases risk.
- IF ON SKIN (or hair) Remove/take off immediately all contaminated clothing and
wash skin (or hair) with plenty of soap and water.
- Rinse skin with water/shower.
- If skin irritation or rash occurs: Get medical advice/attention.
- Wash contaminated clothing before re-use.
- Specific treatment (see … on this label) …Reference to supplemental first aid
instruction – Manufacturer/supplier or the competent authority may specify a cleansing
agent if appropriate.
- Store in a well-ventilated place.
- Keep cool.
- Dispose of contents/container to …in accordance with local/regional/national/
international Regulations (to be specified).
CODE OF PRACTICE | LABELLING OF WORKPLACE HAZARDOUS CHEMICALS
85
APPENDIX F - HAZARD PICTOGRAMS
The nine hazard pictograms that are representative of the physical,
health and/or environmental hazards are shown below:
Pictogram
Hazard
Exploding bomb
Pictogram
Gas cylinder
- Explosive
Flame
- Gases under pressure
Corrosion
- Flammability
Flame over circle
- Corrosive
Skull and crossbones
- Oxidising
Health hazard
- Acute toxicity
Exclamation mark
- Chronic Health hazards
Environment
- Environmental hazard
Chronic health hazards include carcinogens, reproductive toxins, mutagens,
specific target organ toxicants, and aspiration toxicants.
86
Hazard
CODE OF PRACTICE | LABELLING OF WORKPLACE HAZARDOUS CHEMICALS
- Certain health Hazards
(e.g. sensitisers)
APPENDIX G – COMPARISON OF HAZARD
PICTOGRAMS WITH ADG CODE CLASS LABELS
The table below compares hazard pictograms from the GHS with the corresponding ADG Code class labels.
Hazard
Pictograms
GHS Hazard
Dangerous Goods class labels (pictograms)
Explosives
Self-reactives
Organic
peroxides
Flammables
Self-reactives
Pyrophorics
Self-heating
Emits
flammable
gas in contact
with water
Organic
peroxides
Dangerous
goods classes
Explosive
EXPLOSIVE
FLAMMABLE
LIQUID
FLAMMABLE
GAS
FLAMMABLE
SOLID
EXPLOSIVE
SPONTANEOUSLY
COMBUSTIBLE
EXPLOSIVE
DANGEROUS
WHEN WET
ORGANIC
PEROXIDE
Oxidisers
OXIDIZING
AGENT
„„
Flammability
(Liquid, Solid
or Gas)
„„
Pyrophoric,
„„
Emits
Flammable
Gas
„„
Organic
Peroxide
„„
Oxidiser
„„
Oxidising gas
OXIDIZING
GAS
2
Gases under
pressure
NON-FLAMMABLE
NON-TOXIC
GAS
FLAMMABLE
GAS
OXIDIZING
GAS
2
Non-toxic nonflammable gas,
flammable gas,
oxidising gas,
toxic gas
TOXIC
GAS
Acute toxicity
„„ Acute toxicity
TOXIC
GAS
Acute toxicity
Skin irritants
Eye irritants
Skin
sensitisers
TOXIC
GAS
„„ Acute Toxic
gas
No equivalent
CODE OF PRACTICE | LABELLING OF WORKPLACE HAZARDOUS CHEMICALS
87
APPENDIX G – COMPARISON OF HAZARD PICTOGRAMS WITH ADG CODE CLASS LABELS
Carcinogens
Respiratory
sensitisers
Reproductive
toxicants
Target organ
toxicants
Germ cell
mutagens
Eye corrosion
Skin corrosion
Corrosive
to metal
No equivalent
Corrosive
to metals
CORROSIVE
Aquatic
toxicity.
Not covered
within the
scope of
workplace
hazardous
chemicals
requirements
No equivalent
hazard
pictogram
Environmental
hazard
Miscellaneous
dangerous goods
MISCELLANEOUS
DANGEROUS
GOODS
Not covered within the scope of
workplace hazardous chemicals
requirements
Infectious
Not covered within the scope of
workplace hazardous chemicals
requirements
Radioactive
88
CODE OF PRACTICE | LABELLING OF WORKPLACE HAZARDOUS CHEMICALS
APPENDIX H - EXAMPLE LABELS
This appendix contains example labels that have been produced in accordance with the labelling system described in
this Code (in some cases they have been reduced in size for the purpose of presenting in this document). Examples 1-4
are prepared for a hypothetical hazardous mixture, Flammosol. Flammosol contains 95% aliphatic hydrocarbons and
5% toxicole and is classified as a flammable liquid (Category 2), acute toxicity – oral (Category 3) and skin corrosion/
irritation (Category 2).
Note: it is assumed that toxicole is an acceptable technical name.
Example 1: Flammosol label containing the full set of workplace labelling information
The general precautionary statements ‘Read label before use’ and ‘Keep out of reach of children’ have been included.
Inclusion of these statements is not mandatory. In accordance with precedence rules described in Appendix E, the
exclamation mark hazard pictogram and ‘Warning’ signal word have been omitted and duplicate precautionary
statements have not been included.
Read label before use. Keep out of reach of children
Flammosol
FLAMMABLE LIQUID, TOXIC N.O.S.
(aliphatic hydrocarbons, toxicole)
UN 1992
Contains:
Aliphatic hydrocarbons 95%
Toxicole 5%
4L
DANGER
Highly flammable liquid and vapour
Toxic if swallowed
Causes skin irritation
IF ON SKIN (or hair): Take off contaminated
clothing and wash before re-use.
Rinse skin using plenty of soap and water.
If skin irritation occurs: Get medical
advice/attention.
IF SWALLOWED: Immediately call
a POISON CENTRE or doctor/physician.
Rinse mouth.
Store locked up in a well-ventilated place.
Keep cool.
Dispose of contents/container in accordance
with Jurisdictional regulations.
In case of fire: Use powder for extinction.
Keep away from sparks and open flames. – No smoking.
Keep container tightly closed.
Ground/bond container and receiving equipment.
Use explosion-proof electrical equipment.
Use only non-sparking tools.
Take precautionary measures against static discharge.
Wear protective gloves and eye and face protection.
Wash hands thoroughly after handling.
Do not eat, drink or smoke when using this product.
Refer to the Safety Data Sheet before use.
Madeup Chemical Company, 999 Chemical Street, Chemical Town, My State. Telephone: 1300 000 000
www.madeup-chemical-company.com.au
CODE OF PRACTICE | LABELLING OF WORKPLACE HAZARDOUS CHEMICALS
89
APPENDIX H – EXAMPLE LABELS
Example 2: Flammosol label containing the full set of workplace labelling information using 2 separate panels
Front panel
Read label before use. Keep out of reach of children
Flammosol
FLAMMABLE LIQUID, TOXIC N.O.S.
(aliphatic hydrocarbons, toxicole)
UN 1992
Contains:
Aliphatic hydrocarbons 95%
Toxicole 5%
4L
DANGER
Highly flammable liquid and vapour
Toxic if swallowed
Causes skin irritation
Madeup Chemical Company, 999 Chemical Street, Chemical Town, My State. Telephone: 1300 000 000
www.madeup-chemical-company.com.au
Back panel
IF ON SKIN (or hair): Take off contaminated clothing and wash before re-use.
Rinse skin using plenty of soap and water.
If skin irritation occurs: Get medical advice/attention.
IF SWALLOWED: Immediately call a POISON CENTRE or doctor/physician.
Rinse mouth.
In case of fire: Use powder for extinction.
Keep away from sparks and open flames. – No smoking.
Keep container tightly closed.
Ground/bond container and receiving equipment.
Use explosion-proof electrical equipment.
Use only non-sparking tools.
Take precautionary measures against static discharge.
Wear protective gloves and eye and face protection.
Wash hands thoroughly after handling.
Do not eat, drink or smoke when using this product.
Store locked up in a well-ventilated place. Keep cool.
Dispose of contents/container in accordance with Jurisdictional Regulations.
Refer to the Safety Data Sheet before use.
90
CODE OF PRACTICE | LABELLING OF WORKPLACE HAZARDOUS CHEMICALS
APPENDIX H - EXAMPLE LABELS
Example 3: Flammosol label that meets both transport and workplace labelling requirements (single container)
The equivalent dangerous goods (transport) classification for Flammosol is a class 3 (flammable liquid, packing group
II) and a class 6.1 (oral toxicity, packing group III). The transport markings should be in the most prominent position
on the container and should be clearly distinguishable from the workplace labelling. Hazard pictograms are not
included on the workplace label panel as the equivalent class labels appear on the transport panel.
Transport markings label portion (to comply with transport Regulations)
Flammosol
FLAMMABLE LIQUID, TOXIC N.O.S.
(aliphatic hydrocarbons, toxicole)
UN 1992
FLAMMABLE
LIQUID
TOXIC
Madeup Chemical Company, 999 Chemical Street, Chemical Town, My State.
Workplace information label panel:
Flammosol
Contains:
Aliphatic hydrocarbon 95%
Toxicole 5%
DANGER
4L
Highly flammable liquid and vapour
Toxic if swallowed
Causes skin irritation
IF ON SKIN (or hair): Take off contaminated clothing and wash before re-use.
Rinse skin using plenty of soap and water.
If skin irritation occurs: Get medical advice/attention.
IF SWALLOWED: Immediately call a POISON CENTRE or doctor/physician. Rinse mouth
In case of fire: Use powder for extinction.
Keep away from sparks and open flames. – No smoking.
Keep container tightly closed.
Ground/bond container and receiving equipment.
Use explosion-proof electrical equipment.
Use only non-sparking tools.
Take precautionary measures against static discharge.
Wear protective gloves and eye and face protection.
Wash hands thoroughly after handling.
Do not eat, drink or smoke when using this product.
Store locked up in a well-ventilated place. Keep cool.
Dispose of contents/container in accordance with Jurisdictional Regulations.
Madeup Chemical Company, 999 Chemical Street, Chemical Town, My State.
Telephone: 1300 000 000 www.madeup-chemical-company.com.au
CODE OF PRACTICE | LABELLING OF WORKPLACE HAZARDOUS CHEMICALS
91
APPENDIX H - EXAMPLE LABELS
Example 4: Flammosol labels that are appropriate for small containers
The amount of information included on the label of a small container will vary, and be dependent on the size and
shape of the container; and the number of label elements to be included, particularly where the hazardous chemical
meets the criteria for multiple hazard classes. As a mandatory minimum, small containers must be labelled with the
product identifier, manufacturer or importer information and hazard pictograms or hazard statements. Labels for small
containers or packages must include as much labelling information as reasonably practicable
a)
This example contains the minimum labelling information permitted and a reference to the safety data sheet.
Flammosol
Refer to the Safety Data Sheet before use.
Madeup Chemical Company, 999 Chemical Street,
Chemical Town, My State.
Telephone: 1300 000 000
b) This label has sufficient room to include additional labelling information. Following the guidance
provided in Appendix E, hazard statements, the identity and proportions of the hazardous ingredients,
critical first aid instructions and reference to the safety data sheet have been included.
Flammosol
Contains:
Hydrocarbon solvent 95%
Toxicole 5%
Highly flammable liquid and vapour
Toxic if swallowed
Causes skin irritation
IF SWALLOWED: Immediately call a POISON CENTRE or doctor/physician.
Rinse mouth.
Additional information is listed in the Safety Data Sheet
Madeup Chemical Company, 999 Chemical Street, Chemical Town, My State. Telephone: 1300 000 000
92
CODE OF PRACTICE | LABELLING OF WORKPLACE HAZARDOUS CHEMICALS
APPENDIX H - EXAMPLE LABELS
Example 5: Example labels for hazardous waste
a)
Hazardous Waste label that meets both transport and workplace labelling requirements (single container)
Selected precautionary statements relating to first aid instructions, accident prevention and personal protective
equipment and disposal advice have been included. Hazard pictograms have not been included as the corresponding
transport class labels already appear. The generic type of waste solvent is expected to be known e.g.alcohols, esters,
ketones, aliphatic hydrocarbons, aromatic hydrocarbons or chlorinated hydrocarbons.
Flammable Toxic Waste - Batch 1
FLAMMABLE LIQUID, TOXIC N.O.S.
(hydrocarbons, organotin compound)
UN 1992
Contains
Mixed aromatic and aliphatic hydrocarbons (90%)
Alkyl tin (5%)
FLAMMABLE
LIQUID
TOXIC
Flammable liquid and vapour
Toxic if swallowed
IF SWALLOWED: Immediately call a POISON CENTRE
or doctor/physician.
Keep away from ignitions sources. – No smoking.
In case of fire: Use powder for extinction.
Wear protective gloves, eye and face protection.
Dispose of contents in accordance with Jurisdictional
Regulations
Madeup Chemical Company, 999 Chemical Street, Chemical Town,
My State. Telephone: 1300 000 000
www.madeup-chemical-company.com.au
CODE OF PRACTICE | LABELLING OF WORKPLACE HAZARDOUS CHEMICALS
93
APPENDIX H - EXAMPLE LABELS
b) Hazardous Waste label that meets workplace labelling
requirements and transport inner packaging requirements
The main differences between this and the previous example are that hazard pictograms
are used and the proper shipping name and UN number are not included.
Flammable Toxic
Waste – Batch 1
Contains
Mixed aromatic and aliphatic hydrocarbons (90%)
Alkyl tin (5%)
Flammable liquid and vapour
Toxic if swallowed
IF SWALLOWED: Immediately call a POISON CENTRE
or doctor/physician.
Keep away from ignitions sources. – No smoking.
In case of fire: Use powder for extinction.
Wear protective gloves, eye and face protection.
Dispose of contents in accordance with Jurisdictional Regulations
Madeup Chemical Company, 999 Chemical Street, Chemical Town,
My State. Telephone: 1300 000 000
www.madeup-chemical-company.com.au
c)
Labelling of hydrochloric acid waste that meets workplace labelling
requirements and transport inner packaging requirements
Hydrochloric acid waste
May be corrosive to metals
Causes serious eye damage
Wear eye/face protection
IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do so. Continue rinsing.
Immediately call a POISON CENTRE or doctor/physician.
Madeup Chemical Company, 999 Chemical Street, Chemical Town, My State.
Telephone: 1300 000 000
www.madeup-chemical-company.com.au
94
CODE OF PRACTICE | LABELLING OF WORKPLACE HAZARDOUS CHEMICALS
APPENDIX H - EXAMPLE LABELS
Example 6: Example labels for research chemicals or samples for analysis
a)
In this example, the chemical identity and some of the hazardous properties are known, and are therefore,
included on the label.
A.B. Researcher
Aromatic amide
WARNING
Causes serious eye irritation
Causes skin irritation
b) In this example, the identity of the chemical is known. However, the hazardous properties have not been
determined.
A.B. Researcher
Phenolic aldehyde
CAUTION
Unknown properties
Note: For examples 6(a) and 6(b), a generic name in accordance with Appendix C should be used, as chemical
structures are difficult to communicate in the event of an incident.
c)
In the following example, neither the identity nor the hazardous properties of the substance are known.
ABR14b
(Uncharacterised substance)
CAUTION
Unknown properties
CODE OF PRACTICE | LABELLING OF WORKPLACE HAZARDOUS CHEMICALS
95
APPENDIX H - EXAMPLE LABELS
Example 7: Example labels for a substance not otherwise classifiable under the GHS.
The following two example labels are for carbon dioxide (dry ice). Dry ice does not meet any of the hazard
categories of the GHS, and therefore cannot be assigned any label elements. However there are health
and safety issues associated with the handling, use and storage of dry ice and information on these
hazards should be included on labels.
a)
The following label meets road transport labelling requirements. It also meets workplace labelling requirements
as it includes other health and safety information that are applicable to its workplace storage, handling and use.
CARBON DIOXIDE, SOLID (dry ice)
UN 1845
2.5 kg net
Asphyxiation hazard: Use only in well ventilated area
Wear gloves and eye protection
MISCELLANEOUS
DANGEROUS
GOODS
Madeup Chemical Company, 999 Chemical Street,
Chemical Town, My State. Telephone: 1300 000 000
b) The following label meets workplace labelling requirements and road transport inner packaging requirements.
No hazard pictograms or class labels are present. However, health and safety information relating to storage,
handling and use in the workplace is included.
Dry Ice (solid CO2)
2 kg net
Asphyxiation hazard: Use only in well ventilated area
Wear gloves and eye protection
Madeup Chemical Company, 999 Chemical Street,
Chemical Town, My State. Telephone: 1300 000 000
96
CODE OF PRACTICE | LABELLING OF WORKPLACE HAZARDOUS CHEMICALS
APPENDIX I - OTHER
RELEVANT INFORMATION
„„
ADG Code (7th Edition) for download
http://www.ntc.gov.au/ViewPage.aspx?documentid=01147
„„
ADG Code class labels for download
www.ntc.gov.au/ViewPage.aspx?documentid=01313
„„
ADG Code publication information
www.infrastructure.gov.au/transport/australia/dangerous/index.aspx
„„
Code of Practice: Preparation of Safety Data Sheets
„„
GHS hazard pictograms for download
www.unece.org/trans/danger/publi/ghs/pictograms.html
„„
GHS revision 3 – Official text and corrigenda:
http://www.unece.org/trans/danger/publi/ghs/ghs_welcome_e.html
„„
Labelling of Agricultural and Veterinary chemicals
„„For Veterinary Chemicals/Products:
„„www.apvma.gov.au/MORAG_vet/vol_5/vet_labelling_code.html
„„For Agricultural Chemicals/Products:
„„www.apvma.gov.au/MORAG_ag/vol_5/ag_labelling_code.html
„„
SUSMP publication information
http://www.tga.gov.au/industry/scheduling-poisons-standard.htm
„„
UN Model Regulations for the Transport of Dangerous Goods
http://live.unece.org/index.php?id=3304
CODE OF PRACTICE | LABELLING OF WORKPLACE HAZARDOUS CHEMICALS
97
THIS CODE PROVIDES PRACTICAL
GUIDANCE ON HOW TO MEET
THE REQUIREMENTS UNDER THE
WHS REGULATIONS IN RELATION
TO LABELLING OF WORKPLACE
HAZARDOUS CHEMICALS.