Solar Cell Technology LIU ZHI1 Department of Mechanical Engineering, National University of Singapore 21 Lower Kent Ridge Road, Singapore 119077 ABSTRACT This UROP project is mainly discussed about the general principles and applications of solar cell technology. It starts from the photon emission by the diffusion reaction in the sun to the generation of electricity by solar panel, and finally application of solar cell into common device for daily use. 1 The outcome of this UROP project is to let me get a deep understanding of the general principles of how solar cell generates electricity from sunlight. Meanwhile, third generation of solar cell which is thin film, its working principle, efficiency and future development, will also be investigated. 1. Introduction This UROP project is mainly discussed about the genral principles and applications of solar cell technology. It starts from the photon emission by the diffusion reaction in the sun to the generation of electricity by solar panel, and finally application of solar cell into common device for daily use. After completing this UROP project, I get a deep understanding of the general principles of how solar cell generates electricity from sunlight. Meanwhile, I also touched a little bit on the third generation of solar cell which is thin film, its working principle, efficiency and future development. 1.1 Proposal Before I started the project, I set a plan to do this research. And the general information is as follows: Four areas I intend to research in my UROP project. 1) Get to know the basic knowledge of the sun and the sunlight generation. (photons generation and its energy level of different wavelength) 2) Understand solar cell technology and the principle of electricity generation. 1 Student 3) Get to know the latest technology on solar cell manufacturing process, and do a research on its production cost and how to minimize this cost. 4) Do a research on the areas of applications of solar cell technology(which industry or civil equipments are suitable for using solar energy ) Six processes I intend to follow during the UROP project: 1) Research on sunlight generation. Know the principles that how solar technology convert into electricity or thermal energy. 2) Research on various usage of solar energy worldwide and each technology’s efficiency of converting solar energy. 3) Get to know different kinds of solar cell (monocrystalline, multicrystalline, solar cell concentrator technology, electrochemical PV cells, and thin film solar cells) and advantage and disadvantage of each cell. And cost and percentage of usage of each solar cell. 4) Research on the solar cell manufacturing processes and its techniques on various cells mentioned above. Try to find one or two ways to lower the cost of these cells. 5) Research on various equipments which are suitable to use solar cell. 6) If possible, I want to make a solar cell module myself and implement it into the equipment. 1.2 Methodology Most of the information is from the internet because it is the easiest way. There is also a shortcoming because it is not academically reliable. I also searched some academic papers in NUS database, and some of them are very profound for me. I think as my study goes deeper and deeper in this area, I will be capable to read academic journals on this topic. This report is just a conclusion of what I have learned and experienced so far, and also some of my thoughts during the learning processes. 2. Results and Discussion 2.1 Photons generation Study solar cell technology, I think the first step is to study the sun, where the photon source comes from. So I searched a lot of information on the internet, such as the composition of the sun, structure of the sun, general condition of the sun and fusion reaction in the sun, which is the most important step for photon generation. Energy crisis let us shift our focus from oil to sunlight, which is a renewable, stable and environmental friendly energy resource. Firstly, the sun will spend around 10 billion years as a main sequence star before it stops its fusion reaction. Secondly, the generation of electromagnetic wave is stable and continuously emitted to the space. Thirdly, through the solar cell technology, all we need to do is to put the solar cell under the sun and it will generate electricity automatically. Compared with other energy generation, it does not have any emission or consume any natural resources on the earth, so we call it environmental friendly energy. Below are some statistics about photon generation and energy received on the earth. Fusion reaction inside the sun: 4H+2He 2He + E (E is released in the form of electromagnetic wave, photon) The life of the sun: 10 billion years Solar energy power measured by satellite around the earth: 1366 w/m w 2 Cross section of the earth 127400000km2 Total power earth received from the sun: 1.74*1017W, plus or minus 3.5% In 2005, total worldwide energy consumption was 500 EJ (= 5 x 1020J) .This is equivalent to an average energy consumption rate of 15 TW (= 1.5 x 1013 W). 0.01% energy from the sun can fulfill the whole world energy consumption. 2.2 Photovoltaic voltaic technology (solar cell) This is the core technology I need to research in my project. Nowadays, a lot of energy research companies or institutions study on this topic and new technologies in this area developed very fast. The only problem to prevent this solar cell from largely implemented into daily d use is the cost. Researchers use various methods to make cheaper solar cell. Such as thin film solar cell, organic/ polymer solar cell, but the energy conversion efficiency will decreased decreased as the cost decreasing. Basically, the principles of all kinds of solar cells are the same, it is photovoltaic effect. To explain the photovoltaic solar panel more simply, photons from sunlight knock electrons into a higher state of energy level, create electricity. Photons heat the solar cell, and make the electrons move in the connected line and generate electricity. We can also use the conventional silicon as an example; use the p-type type silicon and n-type n silicon make a p-nn junction (actually it is a doping process, dope n-type into the p-type type wafer). When the photons photo hit on the n-type type silicon and make the electrons into activated state, these electrons break the bonding of the atoms and travel to the pp-type side, meanwhile, holes left on the n--type type side. There are two modes of charge carrier separation. One is drift,, which is driven by an electrostatic field. And another is diffusion, charge carrier diffuse from high concentration to low concentration. Then the current will be formed if using the circuit to connect two sides of the panel. The resulting circuit of solar sol cell is show below: Fig 2.1 All photovoltaic devices are some type of photodiode. Fig 2.2 Depletion region: the depletion region, also called depletion layer, depletion zone, junction region or the space charge region, is an insulating region within a conductive, dope doped semiconductor material where the charge carriers have diffused away, or have been forced away by an electric static field. The uncompensated ions are positive on the N side and negative on the P side. This cr creates an electric field that provides a force opposing the continued diffusion of charge carriers. When the electric field is sufficient to arrest further transfer of holes and electrons, the depletion region has reached its equilibrium dimensions. Integrating the electric field across the depletion region determines what is called the built-in voltage (also called the junction voltage or barrier voltage or contact potential Much of the solar radiation reaching the earth is composed of photons with energies greater than the band gap of the silicon. So the electrons in the silicon just absorb enough activate energy to break the atomic bonding and form current. The difference of the energy emitted and absorbed is converted into heat via lattice vibration. Solar cell is usually connected in series to create an addictive voltage. Connecting in parallel will yield a high current. These are very basic stuff I have learned in year 1. However, during my research, some common rule of thumb comes into my picture which I cannot learn from the textbook. For example, the average power is equal to 20% of peak power, so that each peak kilowatt of solar array output power corresponds to energy production of 4.8kWh per day. 2.3 Various usages of solar energy and each technology’s converting efficiency Besides solar cell converting electricity, there are various ways of converting solar power for our daily use. I just use a short paragraph to conclude solar energy use in human history. The oldest way of solar energy use should be evaporation ponds, which is used to obtain salt from sea water. As time passed, more and more new technology come out, people use plastic bottle and sunlight to disinfection drink water in Indonesia. 70GW solar water heating system implemented in China in 2006. Solar chemical process also was studied since 1970. Solar energy can also be used to desalinate saline or brackish water. Then it comes to the solar panel, most interested part of solar energy use for scientists nowadays. From the usage on satellites in 1960s, the cost of solar panel was decreased from 286USD/watt to 2USD/watt today or even less. The efficiency increased from 4.5% to around 30% today. Meanwhile, the application of solar power is shifting from satellites to domestic electricity generation, solar powered vehicles, railroad crossings and so on. As the shortage of fossil energy today, people pay more and more attention on solar energy study and more and more solar cells are implemented in the equipment for our daily use. 2.4 A close look at different kinds of solar cells, advantages and disadvantages of each kind solar cell. So far, there are basically three generations of solar cells exist. They all based on the photovoltaic effect to generate electricity. The first generation is crystalline silicon, which can approach 33% converting efficiency. Second generation is the thin film generation. This kind of solar cells are all consists of thin film made from certain chemical composite. Typical examples are CdTe, CIS, CIGS. Compared with the first generation, it has the lower producing cost, but lower efficiency. The third generation is also based on thin film technology; current research is aiming to increase converting efficiency to 30%-60% while maintaining the costs. So let me start from the basic silicon p-n junction solar cell. This kind of solar cell divided into monocrytalline silicon, polycrystalline silicon and ribbon silicon, usually the monocrystalline has the highest efficiency but also highest production cost. Ribbon has lower efficiency than polycrystalline, but it is the cheapest among the 3 types. Those p-n junction silicon solar cells accounts for 89.6% market ratio in 2007. Thin film solar cell is the newly emerged technology. Due to its relatively low cost compared with silicon, it got a market share of 5.2% in 2007 and will be increased in the following years. The conventional thin film has the lower efficiency than p-n junction silicon; new technologies create multi-layer thin films which can better absorb the coming sunlight. Thus, it has even high converting efficiency than bulk silicon. Some typical thin film solar cells are as follows: Thin film solar cell mainly consists of CdTe, CIS, CIGS and GaAs. Compared with other thin film, CdTe is easier to deposit and more suitable for mass production. The only shortcoming is the toxicity of cadmium, a heavy metal that is a cumulative poison. It has already proved that cadmium released to the atmosphere is relatively lower than other thin film solar cells. • CIS and CIGS are two similar thin film, the only difference is that CIGS use Ga substitute for In in the CIS. This method can reduce the cost because of limited availability of In, meanwhile, it also increase the optical band gap of the cell. The efficiency will also be increased. The best conversion deficiency for flexible CIGS cells is 14.1% in 2006, and it was increased to 19.9% on March 2008. The only disadvantage of this technology is the manufacturing cost. • GaAs is the lowest cost alternative in terms of $/kWh and $/W. This kind of semiconductor are carefully chosen to absorb nearly the entire solar spectrum, thus, it has the higher efficiency. It has reached a record high of 40.7% under solar concentration and laboratory conditions. Same disadvantage as other thin film, high production cost. Other kind of technology such as light-absorbing dyes has a very low producing cost. However, the dyes in these cells suffer from degradation under heat and UV light. The cell casing is difficult to seal due to the solvents used in assembly. • • • Organic/polymer solar cell is a whole new concept of solar cell. It does not like the bulk silicon, the charge carrier is by drifting, and it absorbs light and activates electrons into activated state. Due to the concentration gradient created, the electrons will diffuse into the holes and generate electricity. The highest efficiency so far is 6.5%. But it is very fit for the applications where mechanical flexibility and disposability are important. Silicon thin film is made of amorphous silicon, photocrytalline silicon or nanocrystalline silicon. It tends to be less efficient than bulk silicon but also less expensive to produce. With some new methods, the conversion efficiency can be largely increased. For example, Amorphous silicon has a higher band gap (1.7 eV) than crystalline silicon (c-Si) (1.1 eV), which means it absorbs the visible part of the solar spectrum more strongly than the infrared portion of the spectrum. As nc-Si has about the same band gap as c-Si, the two materials can be combined in thin layers, creating a layered cell called a tandem cell. The top cell in a-Si absorbs the visible light and leaves the infrared part of the spectrum for the bottom cell in nanocrystalline Si. There are also some other kind of solar cell, like nanocrystalline solar cell, concentrating photovoltaics (it is a method to increase the efficiency of solar cell while keep the low usage of solar panel use). 2.5 Manufacturing Processes This part is mainly discussed about various manufacturing method of solar cell. There are generally two kinds of solar cell. One is based on the traditional silicon bulk, p-n junction solar cell; it is divided into monocrystalline and multicrystalline. And another is thin film solar cell, the main production of this generation solar cell includes CIGS, CdTe, and GaAs as discussed in the previous part. Monocrystalline and Multicrystalline Solar Cell Because this kind of solar cells are semiconductor devices, they share many of the same processing and manufacturing techniques as other semiconductor devices such as computer and memory chips. However, the stringent requirements for cleanliness and quality control are more relaxed for solar cells. Most large-scale commercial solar cell factories today make screen printed poly-crystalline silicon solar cells. Single crystalline wafers which are used in the semiconductor industry can be made into excellent high efficiency solar cells, but they are generally considered to be too expensive for large-scale mass production. Poly-crystalline silicon wafers are made by wire-sawing block-cast silicon ingots into very thin (180 to 350 micrometer) slices or wafers. The wafers are usually lightly p-type doped. To make a solar cell from the wafer, a surface diffusion of n-type dopants is performed on the front side of the wafer. This forms a p-n junction a few hundred nanometers below the surface. Antireflection coatings, which increase the amount of light coupled into the solar cell, are typically next applied. Over the past decade, silicon nitride has gradually replaced titanium dioxide as the antireflection coating of choice because of its excellent surface passivation qualities. It is typically applied in a layer several hundred nanometers thick using plasma-enhanced chemical vapor deposition. Some solar cells have textured front surfaces that, like antireflection coatings, serve to increase the amount of light coupled into the cell. Such surfaces can usually only be formed on single-crystal silicon, though in recent years methods of forming them on multicrystalline silicon have been developed. Czochralski Process After some research online, I have found the manufacturing method to produce monocrystalline silicon is Czochralski Process. Czochralski process is a method of crystal growth used to obtain single crystals of semiconductors, metals, salts, and synthetic gemstones. It is named after Polish scientist Jan Czochralski, who discovered the method in 1916 while investigating the crystallization rates of metals. The process is generally like this: A seed crystal, mounted on a rod, is dipped into the molten silicon. The seed crystal's rod is pulled upwards and rotated at the same time. By precisely controlling the temperature gradients, rate of pulling and speed of rotation, and then it can extract a large, single-crystal, cylindrical ingot from the melt. By investigating and visualizing the temperature and velocity fields during the crystal growth process, occurrence of unwanted instabilities in the melt can be avoided. This process is normally performed in an inert atmosphere, such as argon, and in an inert chamber, such as quartz. After the growth of large cylindrical ingots, A commercial HCT saw with high-speed wires and SiC slurry makes precision cuts to slice them to the specified cross section. Prepare for the monocrystalline silicon solar cell production. Multicrystalline silicon solar cell production procedure • A series of controls ensure that silicon feedstock meets the strict purity requirements necessary to produce solar grade silicon ingots. • The silicon is melted down in a GT Solar Directional Solidification System (DSS) furnace. • A PLC program controls the entire process of melting, directional solidification, and cooling to optimize the process based on the type of silicon feedstock and the production requirements. • The electric furnace combined with the PLC controls ensures efficient production and minimizes environmental impact. • A commercial HCT saw with high-speed wires and SiC slurry makes precision cuts to slice them into 16 bricks according to the specified cross section. • 8 bricks at a time are sliced into extremely thin wafers that are ready for solar cell production. 8 bricks can yield approximately 3,000 wafers. • The wafers then move on to the automated production line. Etching and texturing of wafers removes any saw damage and creates a surface that reduces solar reflection in order to capture as much light as possible. • A high temperature phosphorus diffusion process creates the p/n junction necessary to produce photovoltaic electricity. • The solar cells are then coated with an anti-reflective coating to enhance their light capturing capability. • Finally, a state-of-the-art automated printing line applies the silver bus strips and coats the backside with aluminum. Manufacturing process of thin film There are basically two methods to manufacturing thin film solar cells like CIGS. The first one is sequential deposition of Cu, Ga and In and a post treatment in Se and S atmosphere. The second method is the co-evaporation method, which makes a one step in-line process possible. For CdTe thin film production. In the fabrication process, all the layers are grown by vacuum evaporation. Commercially available soda-lime glass coated with fluorine doped tin oxide was used as substrates. CdS layers were grown in a high vacuum evaporation chamber at a substrate temperature of 150℃ and subsequently annealed at 450℃ for recrystallizaiton. Without breaking the vacuum CdTe was then deposited at a substrate temperature of 300℃. Vacuum evaporation was used for the deposition of 600 nm CdCl2 layers on CdTe and the stacks were annealed at 430℃ for 30 min in air. 2.6 Various Application of Solar Cell Recent years have seen rapid growth in the number of installations of PV on to buildings that are connected to the electricity grid. This area of demand has been stimulated in part by government subsidy programmes (especially Japan and Germany) and by green pricing policies of utilities or electricity service providers (e.g. in Switzerland and the USA). The central driving force though comes from the desire of individuals or companies to obtain their electricity from a clean, non-polluting, renewable source for which they are prepared to pay a small premium. In these grid-connected systems, PV System supplies electricity to the building and any day-time excess may be exported to the grid. Batteries are not required because the grid supplies any extra demand. However, if you want to be independent of the grid supply you will need battery storage to provide power outside daylight hours. Solar PV modules can be retrofitted on to a pitched roof above the existing roof-tiles, or the tiles replaced by specially designed PV roof-tiles or roof-tiling systems. If you are planning to put a PV system on to a building and have it connected to the grid supply there are likely to be local regulations that need to be met, and permission required from your utility or electricity service provider. The level of credit for any exported electricity will vary depending on local schemes in place. Industrial usage Solar Energy has been the power supply of choice for industrial applications, where power is required at remote locations. This means in these applications that solar power is economic, without subsidy. Most systems in individual uses require a few kilowatts of power. The examples are powering repeater stations for microwave, TV and radio, telemetry and radio telephones. Solar energy is also frequently used on transportation signal. E.g. offshore navigation buoys, lighthouses, aircraft warning lights on pylons or structures, and increasingly in road traffic warning signals. Solar is used to power environmental and situation monitoring equipment and corrosion protection systems for pipelines, well-heads, and bridges or other structures. As before, for larger electrical loads it can be cost effective to configure a hybrid power system that links the PV with a small diesel generator. Solar cell’s great benefit here is that it is highly reliable and requires little maintenance In remote area Apart from off-grid homes, other remote buildings such as schools, community halls, and clinics can all benefit from electrification with Solar Energy. This can power TV, video, telephony and a range of refrigeration equipment. Rather than base solar power generation on individual dwellings, it is also possible to configure central village power plants that can either power homes via a local wired network, or act as a battery charging station where members of the community can bring batteries to be recharged. PV Systems can be used to pump water in remote areas e.g. as part of a portable water supply system. Specialized solar water pumps are designed for submersible use or to float on open water. Usually, the ability to store water in a tank means that battery power storage is unnecessary. Large-scale desalination plants can also be PV powered. Larger off-grid systems can be constructed to power larger and more sophisticated electrical loads by using an array of PV modules and having more battery storage capacity. Commercial buildings On an office building, atria can be covered with glass/glass PV modules, which can be semi-transparent to provide shaded light. On a factory, large roof areas have been the best location for solar modules. If they are flat, then arrays can be mounted using techniques that do not breach the weatherproof roof membrane. Also, skylights can be covered partially with PV. The vertical walls of office buildings provide several opportunities for PV incorporation. The first is as a "curtain wall system" that constitutes the weather barrier of the building. The second is an underlying weather barrier that provides the insulation and sealing of the building. The third option is to create sunshades or balconies incorporating a PV System. Sunshades may have the PV System mounted externally to the building or have PV cells specially mounted between glass sheets comprising the window. Solar vehicles Solar powered cars are cars which are powered by an array of photovoltaic cells. The electricity created by the solar cells either directly powers the vehicle through a motor, or goes into a storage battery. Even if a vehicle is completely covered in solar cells, it will only receive a smaller amount of solar energy and will be able to convert only a small amount of that to useful energy. Because of this, most solar powered vehicles are only used in research, educational tools or to compete in the various races for solar powered vehicles. Helios UAV in solar powered flight In 1974, the unmanned Sunrise II plane inaugurated the era of solar flight. In 1980, the Gossamer Penguin made the first piloted flights powered solely by photovoltaics. This was quickly followed by the Solar Challenger which demonstrated a more airworthy design with its crossing of the English Channel in July 1981. Developments then turned back to unmanned aerial vehicles (UAV) with the Pathfinder (1997) and subsequent designs, culminating in the Helios which set the altitude record for a non-rocket-propelled aircraft at 29,524 metres (96,860 ft) in 2001. The Zephyr, developed by BAE Systems, is the latest in a line of record-breaking solar aircraft, making a 54-hour flight in 2007, and month-long flights are envisioned by 2010. Some small appliance for our daily use Solar Powered Calculators Solar Powered Watch Electrical Power Charger 2.7 Asian Youth Energy Summit On 30 and 31 Oct. 2008. I attended Asian Youth Energy Summit Conference. It was held in NUS international Conference Center by Energy Carta, which is a non-profit organization that seeks to educate and engage students and young professionals with industry and other stakeholders about issues related to Sustainable Development and Energy. It is a quite meaningful conference for me. That’s because I have learned a lot of things during this two-day conference, and also get interactions with some green energy enthusiasts, great person in this industry. An undergraduate student from Rice University gave us an impressive presentation on solar cells. It encourages me to keep on studying in this area. I think I can also achieve what he has done because we are all undergraduates. Mr. Dipal Barua, who is the managing director of Grameen Shakti, gave us an amazing talk on what he has done in his home country, Bengal. Because most of the areas in Bengal are still uncovered by the electrical grid, so he develops a new product, simple solar module powering system. He recruited women in the rural area, and assembly this solar modules. Each set of modules can power TV for 2 or 3 hours and light for 5 to 6 hours after sunset. Of course, in the daytime, it can fully power all these devices. It brought a lot of convenience for the local people and meanwhile, it also creates hundreds of jobs for women in the rural area. Actually, Professor Muhamad Yunus and Grameen Bank received the Nobel Prize in 2006 for its contribution to poverty reduction and peace. I joined Professor Luther’s discussion panel, who is the CEO of Solar Energy Research Institute of Singapore (SERIS), which is a National Lab based in NUS. Christophe Inglin, who is the Managing Director of Phoenix Solar in Singapore. They gave us a brief view for the solar technology development in the next decade. They mainly focused on the amorphous silicon and thin film solar cell development. The transforming efficiency has researched to 14% for CIGS now, and can be achieved for higher efficiency. Another discussion panel was held by NUS Prof Chou Siaw Kiang, who is executive director of Energy Studies Institute. Benjamin K. Sovacool, research fellow of Lee Kuan Yew School of public Policy. They gave us a whole new perspective on solar cell development. They start from the economic side and political side. As I have discussed previously, during the 1970s and 1980s oil shortage crisis, large amount of research fund and incentive policy were going to solar cell industry. However, after the crisis, people shifted their focus back on the fossil fuel area. Solar cell keeps on growing 14% each year till 2000. The main point here is that whether this technology can be developed largely depends on the government policy. That’s because its high costs compared with the grid electricity. Singapore government aims to grow the Clean Energy industry to generate a total of S$1.7 billion in value-added and 7000 jobs by 2015. Good news is that Norway’s Renewable Energy Corp decided to build the world’s largest solar plant at a cost of $6.3 billion in Singapore. So I can see I have a bright future if I put myself into this industry. 3. Conclusion This is the first time I make extensive study on a specific area. I get most of the information from internet, conference handout, and research papers. Some of the information may be not reliable. However, I get to know the basic concept of the solar cell technology, various kinds of solar cell and their applications. Also I find out each kind solar cell’s working principle. The market share of each kind of solar cell has also been investigated. In the second half of the project, I focused my study on the manufacturing process of the solar panels, get a deep understanding that how the silicon or thin film solar cells were made. Due to the knowledge constrains, I cannot provide any suggestions for the manufacturing methods discussed above. After discussing about the manufacturing methods, I did an intensive study on the application of solar cell. There are really a lot. Almost all the electrical device can be powered by solar cell. We just need to consider the efficiency and the economic optimization of each kind of solar cell application. In my proposal, I intend to buy a solar cell and implement it into a device for daily use. However, due to the school lab condition and time constrains, I cannot put all my thoughts into practice. Asian Youth Energy Summit really helps me a lot on this project. I get to know the latest technology and research direction in this area. And also some other consideration, such as economy and public policy also come into my mind. So I can see a clearer picture of solar cell technology. On the conference, I also make some friends who are enthusiasm in the renewable energy area. We exchanged our thoughts and ideas on it, and it is really fantastic conference. I also got interactions with professional people in this area, like Christophe Inglin, who is managing director of Phoenix Solar Pte. I joined Professor Hawlader’s FYP students meeting weekly. Get to know more about what my seniors is doing now. Each of them has their presentation every week. They shared their thoughts and results on their study field, and Porf Hawlader gave them many valuable suggestions. I also shared with them what I have done in the past week, and ask them for some suggestions. It is really happy to work with them, and I like that style. Meanwhile, I have learned a lot from this kind of meeting. Above all, from UROP study, I have learned the basic principle of solar cell and their future development. It is really an enriching experience for me. I also make some friends and get to know some big person in this area. Besides technology, there are also some factors, such as economy and public policies, come into my mind. It lets me to view the full picture that how a technology is promoted into the society. I like to thank my mentor, Professor M.N.A Hawlader, who gives me tremendous help and valuable suggestions in this UROP project. Let me join their FYP meeting, and take their time to listen to my presentation. It is a quite happy journey in my university life. REFERENCES Wikipedia (2008). Solar Cell Technology. Retrieved 12 November, 2008 from the World Wide Web: http://en.wikipedia.org/wiki/Solar_cell Solarbuzz (2008). Solar Cell manufacturing process. Retrieved 12 November, 2008 from the World Wide Web: http://www.solarbuzz.com/plants.htm Romeo, K. K.(2005) High-efficiency flexible CdTe solar cells on polymer substrates Solar Energy Materials and Solar Cells, Volume 90, Issues 18-19, 23 November 2006, Pages 3407-3415 M. Powalla, B.(2002) Development of large-area CIGS modules Solar Energy Materials and Solar Cells, Volume 75, Issues 1-2, January 2003, Pages 27-34