Note on Born approximation: conditions of validity The Born approximation for the scattering amplitude f (n; n0 ) is based on general equation: Z 0 m e ikn x V (x) + (x) d3 x ((1)) f (n; n0 ) = 2 2 ~ and substitution of the exact solution + (x) by the incident wave eiki x . Let us analyze when this approximation is valid. The exact wave function obeys an integral equation: + iki x (x) = e m 2 ~2 Z 0 eikjx x j V (x0 ) jx x0 j + (x0 ) d3 x0 ((2)) The question is: at what condition the integral term is small in comparison to the incident wave? Let consider …rst the case when ka . 1, where a is a characteristic radius of the potential. The integration in (1) and (2) is limited 0 by the potential in a volume with the linear size a, the exponent eikjx x j in this + 0 0 region is of the order of 1 as well as (x ), the denominator jx x j is of the order of a. Thus, the order of the value of the integral term in (2) in this case 2 2 1 or is ma~2jV j and the criterion of the Born approximation validity is ma~2jV j ~2 ~2 jV j ma2 . The value ma2 has meaning of kinetic energy for a particle con…ned in a volume with the linear size a. Let consider now the short-wave limit ka 1. Then the exponent in equation (2) changes rapidly in the volume with the linear size a and the previous 0 estimate becomes invalid. To improve it let substitute eiki x instead of + (x0 ) and multiply and divide the integral by the factor eiki x . The result reads: Z 0 eikjx x j V (x0 ) jx x0 j + (x0 ) d3 x0 eiki x Z eikjx x0 j iki (x x0 ) jx x0 j V (x0 ) d3 x0 ((3)) 0 The exponent in the integral in eq. (3) can be rewritten as eikjx x j(1 cos ) , where is the angle between ki and x x0 . Since ka is very large and jx x0 j has the order of magnitude a, the oscillating exponent cancel the integrand 0 everywhere beyond a region in which p the argument of the exponent k jx x j (1 cos ) is less or equal to , i.e. at . 1= ka. The integration over gives the factor 1= (ka), the rest of the integral contributes a factor jV j a2 . Thus, the Born ja jV ja approximation works if mjV 1, where v = ~k ~2 k = ~v m is the velocity. 1