"Low NOx Flameless Combustion for Jet Engines and Gas turbines" Yeshayahou Levy Technion - ISRAEL http://jet-engine-lab.technion.ac.il MY THANKS TO ALL CONTRIBUTORS: •Dr. Valery Sherbaum, Technion •Dr. Vitali Ovcherenko, Technion •Dr. Vladimir Erenburg, Technion •Dr. Igor Geisinski, Technion 9th Israeli Symposium on Jet Engines and Gas Turbines, October 7 2010, Technion, Istarel 9th •Mr. Josef Shemenson , Technion •Dr. Arvind Rao, Delft, The Netherlands •Prof. Mario Costa, IST, Portugal •Prof. Farid C. Christo, The University of South, Australia Israeli Symposium on Jet Engines and Gas Turbines October 7 2010, Technion, Istarel 1 Turbo and Jet Engine Laboratory Technion – Israel www. jet-engine-lab.technion.ac.il 100 90 80 70 2025 60 2015 50 present 40 30 20 present 10 2015 0 Noise (dB) 9th Israeli Symposium on Jet Engines and Gas Turbines, October 7 2010, Technion, Istarel 2025 Nox, CO, UHC (%) Fuel Consumption (%) Maintanance Cost (%) NOx, CO & UHC emissions are to be reduced by 70% by year 2015 and 80% by year 2025 Fuel Consumption & CO2 emission to be cut by 15% by year 2015 and 25% by year 2025 Anticipated Future Projections of Engine performance Turbo and Jet Engine Laboratory Technion – Israel 2 www. jet-engine-lab.technion.ac.il NOx Formation in Combustor • Conventional combustion process – Primary zone (2500K) – Dilution zone (TET=1600K) • Formation (simplified) pathways: – Thermal (>1800K) O2 <=> 2O N2 + O <=-> NO + N N + O2 <=> NO + O – Prompt (CH, HCN,..) – Fuel-nitrogen (bound N) NOx FORMATION REGION 9th Israeli Symposium on Jet Engines and Gas Turbines, October 7 2010, Technion, Istarel Turbo and Jet Engine Laboratory CONVENTIONAL COMBUSTOR Technion – Israel 3 www. jet-engine-lab.technion.ac.il 2200° C T conventional 1500° C flameless 1300° C 400° C No NOx production X 9th Israeli Symposium on Jet Engines and Gas Turbines, October 7 2010, Technion, Istarel THE CONCEPT OF FLAMELESS GAS TURBINE COMBUSTOR 4 Turbo and Jet Engine Laboratory Technion – Israel www. jet-engine-lab.technion.ac.il FLAMELESS OXIDATION METHOD FOR NOx REDUCTION CHARACTERISTICS Recirculation of combustion products at high temperature (> 1000°C) Reduced oxygen concentration at the reactance Highly transparent flame with low acoustic oscillation Distributed combustion zone Uniform temperature distribution Reduced temperature peaks Low adiabatic flame temperature High concentration of CO2 & H2O Lower Damköhler number Low NOx and CO emission LARGE VOLUME % O2 % (N2+CO2+H2O) Different Combustion Regimes (Milani & Saponaro, “Diluted Combustion Technologies”, IFRF Combustion Journal, 2001) Observed Experimental Temperature Distribution Plessing et al., 1998 REGULAR 9th Israeli Symposium on Jet Engines and Gas Turbines, October 7 2010, Technion, Istarel FLAMELESS Turbo and Jet Engine Laboratory Flameless Combustion Technion – Israel 5 www. jet-engine-lab.technion.ac.il Conventional Combustor Texit Gas High Peak Temperature Thin reaction zone High Temperature Gradients High NOx production Air Low NOx Combustor Low temperature peak Distributed flame Temperature Uniformity Low NOx production 9th Israeli Symposium on Jet Engines and Gas Turbines, October 7 2010, Technion, Istarel Gas Texit Air Turbo and Jet Engine Laboratory FLAMELESS COMBUSTION PRINCIPLE Technion – Israel 6 www. jet-engine-lab.technion.ac.il FLAMELESS OXIDATION IN FURNACES Industrial Furnace Inlet Main combustion (flameless oxidation) Exhaust Heat extraction 0-5% O2 Gas Turbine Inlet Main combustion Exhaust ? 14-18% O2 9th Israeli Symposium on Jet Engines and Gas Turbines, October 7 2010, Technion, Istarel FLAMELESS OXIDATION IN FURNACES AND GAS TURBINE. Turbo and Jet Engine Laboratory Technion – Israel 7 www. jet-engine-lab.technion.ac.il CONVENTIONAL GAS TURBINE GAS TURBINE WITH THE FLOXCOM COMBUSTOR ●4 ●1 ●2 ●3’ ●3 ●5 9th Israeli Symposium on Jet Engines and Gas Turbines, October 7 2010, Technion, Istarel IMPLEMENTATION OF FLOXCOM METHOD IN GAS TURBINES 8 ●6 Turbo and Jet Engine Laboratory Technion – Israel www. jet-engine-lab.technion.ac.il INDICATIONS OF INCOMPLETE COMBUSTION 9th Israeli Symposium on Jet Engines and Gas Turbines, October 7 2010, Technion, Istarel CFD SIMULATIONS (Farid C. Christo, The University of South Australia) Turbo and Jet Engine Laboratory Technion – Israel 9 www. jet-engine-lab.technion.ac.il OPTIONAL AIR INLETS MODIFICATIONS Diluting air 9th Israeli Symposium on Jet Engines and Gas Turbines, October 7 2010, Technion, Istarel A 600 MODEL OF THE COMBUSTOR SHOWING STIRRING AND DILUTING AIR INLET HOLES 10 Stirring air Turbo and Jet Engine Laboratory Technion – Israel www. jet-engine-lab.technion.ac.il 9th Israeli Symposium on Jet Engines and Gas Turbines, October 7 2010, Technion, Istarel SECTOR COMBUSTOR - FULLY ASSSEMBELED Turbo and Jet Engine Laboratory Technion – Israel 11 www. jet-engine-lab.technion.ac.il 9th Israeli Symposium on Jet Engines and Gas Turbines, October 7 2010, Technion, Istarel OPERATING TEST RIG AT IST, PORTUGAL PHASE I 12 Turbo and Jet Engine Laboratory Technion – Israel www. jet-engine-lab.technion.ac.il 9th Israeli Symposium on Jet Engines and Gas Turbines, October 7 2010, Technion, Istarel Turbo and Jet Engine Laboratory COMBUSTION TESTS Technion – Israel 13 www. jet-engine-lab.technion.ac.il A22SHI 2 -2 k (m s ) 72 66 60 54 A23SHI 48 Ø4 42 Ø4 36 A21SHI 30 24 18 A24SHI 12 6 0 PRIMARY ZONE 10 m/s MEASUREMENTS AT SYMMETRY PLANE INSIDE THE COMBUSTION CHAMBER 9th Israeli Symposium on Jet Engines and Gas Turbines, October 7 2010, Technion, Istarel MEAN VELOCITY VECTORS AND TURBULENT KINETIC ENERGY FIELDS AT THE 14 Turbo and Jet Engine Laboratory Technion – Israel www. jet-engine-lab.technion.ac.il MEASUREMENTS PERFORMED AT THE SYMMETRY PLANE (IST PORTUGAL) 9th Israeli Symposium on Jet Engines and Gas Turbines, October 7 2010, Technion, Istarel CONTOURS OF TEMPERATURE AND O2, CO, NOX, HC, AND CO2 CONCENTRATIONS Turbo and Jet Engine Laboratory Technion – Israel 15 www. jet-engine-lab.technion.ac.il 9th Israeli Symposium on Jet Engines and Gas Turbines, October 7 2010, Technion, Istarel HIGH PRESSURE FLOXCOM TEST RIG AT ANSALDO BARI Turbo and Jet Engine Laboratory Technion – Israel 16 www. jet-engine-lab.technion.ac.il ppm 2000 ppm 20 18 1800 NOx 16 1600 NO 14 1400 12 1200 10 1000 CO 8 800 6 600 4 400 2 200 0 2.5 9th Israeli Symposium on Jet Engines and Gas Turbines, October 7 2010, Technion, Istarel 2.7 2.9 3.1 3.3 3.5 3.7 3.9 EMISSION TEST DIAGRAM AT 2.5 BARS (abs.), NO AND NO2 Vs. THE EXCESS AIR PARAMETER 17 0 4.1 Turbo and Jet Engine Laboratory Technion – Israel www. jet-engine-lab.technion.ac.il 20.0 100 17.5 99 15.0 12.5 10.0 Config. A: Config. B: Config. C: Config. D: ; ; ; ; NOx NOx NOx NOx COMBUSTION EFFICIENCY 98 97 96 7.5 95 NOx 5.0 94 2.5 93 0.0 0.2 0.25 0.3 0.35 0.4 0.45 0.5 0.55 0.6 Combustion efficiency (% ) NOx (dry volume ppm @ 15% O 2) PRELIMINARY DESIGN MODIFICATIONS 92 0.65 g Air inlet (total = 14 holes × 2 sections) Config. Left inlet Right inlet A oooooooooooooo oooooooooooooo B o●o●o●o●o●o●o● o●o●o●o●o●o●o● C oooooooooooooo ●●●●●●●●●●●●●● D o●o●o●o●o●o●o● ●●●●●●●●●●●●●● 9th Israeli Symposium on Jet Engines and Gas Turbines, October 7 2010, Technion, Istarel EFFECT OF GEOMETRICAL VARIATIONS P=1 bar (abs) Q= 4KW (24 KW complete section) Turbo and Jet Engine Laboratory Technion – Israel 18 www. jet-engine-lab.technion.ac.il P=1 bar (abs) Q= 8KW (48 KW complete section) Fuel mixture 1 2 3 4 9 CH4 100 91 81.9 76 39.2 H2 0 9 18.1 24 43.3 CO2 0 0 0 0 17.5 LHV (MJ/Nm3) 35.80 33.55 31.27 29.79 18.70 Tad (ºC) 1952 1956 1961 1965 1923 9th Israeli Symposium on Jet Engines and Gas Turbines, October 7 2010, Technion, Istarel EFFECT OF FUEL COMPOSITION (COMBUSTION OF SYNGAS) Turbo and Jet Engine Laboratory Technion – Israel 19 www. jet-engine-lab.technion.ac.il • • • • FLOXCOM COMBUSTOR HAS LARGE STABLE OPERATIONAL RANGE. NOx EMISSION IS LOW AS EXPECTED. CO AND UHC ARE MODERATE, DESIGN MODIFICATION IS ARE REQUIRED BASIC STUDY IS NEEDED TO FILL GAPS 2nd PHASE OF THE STUDY: 9th Israeli Symposium on Jet Engines and Gas Turbines, October 7 2010, Technion, Istarel INTERMEDIATE CONCLUSION Turbo and Jet Engine Laboratory Technion – Israel 20 www. jet-engine-lab.technion.ac.il Conventional Flameless for Gas Turbine Inlet Main combustion Exhaust 14-18% O2 New design for Aero-engine Heat extraction Inlet 21 % O2 Exhaust Main combustion ADVANTEGEOUS: •COOLER FLAME •NEED FOR LOWER RECIRCULATION RATIO 5-8 % O2 9th Israeli Symposium on Jet Engines and Gas Turbines, October 7 2010, Technion, Istarel MODIFIED FLAMELESS COMBUSTOR WITH INTERNAL HEAT EXCHANGER. 21 Turbo and Jet Engine Laboratory Technion – Israel www. jet-engine-lab.technion.ac.il x Junction Primary Air 2 Main Combustion 3 Recirculation Zone 1 Pre-combustion Inlet Exit 5 Fuel 4 Heat exchanger Secondary Air 9th Israeli Symposium on Jet Engines and Gas Turbines, October 7 2010, Technion, Istarel HEAT AND FLOW DIAGRAM MODIFIED FLAMELESS COMBUSTOR. Turbo and Jet Engine Laboratory Technion – Israel 22 www. jet-engine-lab.technion.ac.il פתח הזרמת אוויר אזור האוויר העוקף פתחי הזרמת דלק צלעות מחליף החום באזור הבעירה (דופן תא )אזור הבעירה USING OPTIMAL CONFIGURATION, COMBUSTION TEMPERATURE MAY BE REDUCED BY AS MUCH AS 170 °C ! 9th Israeli Symposium on Jet Engines and Gas Turbines, October 7 2010, Technion, Istarel Turbo and Jet Engine Laboratory THE HEAT TARNSFER MECHANISM Technion – Israel 23 www. jet-engine-lab.technion.ac.il SINGLE JET FLAMELESS COMBUSTOR 9th Israeli Symposium on Jet Engines and Gas Turbines, October 7 2010, Technion, Istarel SINGLE JET STUDY Turbo and Jet Engine Laboratory Technion – Israel 24 www. jet-engine-lab.technion.ac.il DIFFUSION FLAMELESS 9th Israeli Symposium on Jet Engines and Gas Turbines, October 7 2010, Technion, Istarel Turbo and Jet Engine Laboratory Technion – Israel 25 www. jet-engine-lab.technion.ac.il GASEOUSE FUEL INLETS AIR INLET Cy cl e rfac u ic S CH4 MESH FOR 1/16 SECTOR Air 9th Israeli Symposium on Jet Engines and Gas Turbines, October 7 2010, Technion, Istarel CFD SIMULATIONS - TECHNION COMBUSTION CHAMBER WITH 16 FUEL INLET26 Turbo and Jet Engine Laboratory Technion – Israel www. jet-engine-lab.technion.ac.il TEMPERATURE DISTRIBUTION ~1800K 9th Israeli Symposium on Jet Engines and Gas Turbines, October 7 2010, Technion, Istarel Turbo and Jet Engine Laboratory TEMPERATURE DISTRIBUTION Technion – Israel 27 www. jet-engine-lab.technion.ac.il To outlet CH4 inlet Air inlet | 0 mm 9th Israeli Symposium on Jet Engines and Gas Turbines, October 7 2010, Technion, Istarel | | | 25 | | 50 | | 75 VELOCITY FIELD AT THE CENTER LINE CROSS-SECTION Turbo and Jet Engine Laboratory Technion – Israel 28 www. jet-engine-lab.technion.ac.il RECIRCULATION REGION To outlet 9th Israeli Symposium on Jet Engines and Gas Turbines, October 7 2010, Technion, Istarel Vz - VELOCITY COMPONENT'S DISTRIBUTION 29 Turbo and Jet Engine Laboratory Technion – Israel www. jet-engine-lab.technion.ac.il DIFFUSION REGION FUEL ENTRAINMENT Preliminary NO predictions | | | | | | 3 6 9 12 | 0 mm Temperature distribution NO level 5 ppm 0 NO mass-fraction distribution 9th Israeli Symposium on Jet Engines and Gas Turbines, October 7 2010, Technion, Istarel TEMPERATURE DISTRIBUTION – (NEAR NOZZLE REGION) Turbo and Jet Engine Laboratory Technion – Israel 30 www. jet-engine-lab.technion.ac.il TK experiment 9th Israeli Symposium on Jet Engines and Gas Turbines, October 7 2010, Technion, Istarel THERE IS STILL ROOM FOR IMPROVEMENTS IN THE MODELING … simulation COMPARISON – CFD SIMULATIONS EXPERIMENT Turbo and Jet Engine Laboratory Technion – Israel 31 www. jet-engine-lab.technion.ac.il Regime Tmax , K Texit , K COexit NOexit Krecirc. Adiabatic 2460 1900 8.6x10-12 ≃ 0 46x10-6 1.6 Flux = -15kW/m2 2290 1760 3.3x10-12 ≃ 0 4.4x10-6 1.6 Flux = -25kW/m2 2190 1680 2.5x10-12 ≃ 0 0.76x10-6 1.6 Exp. data - 1630 0 10x10-6 - INCORPORATION OF HEAT LOSS IN THE MODELING IMPROVED RESULTS 9th Israeli Symposium on Jet Engines and Gas Turbines, October 7 2010, Technion, Istarel COMPARISON OF SIMULATION AND TEST RESULTS 32 Turbo and Jet Engine Laboratory Technion – Israel www. jet-engine-lab.technion.ac.il summary • Basic modeling of the FLOXCOM combustion method was complete. • Detailed investigation into internal mixing and enhanced wall heat transfer is currently being performed. • CFD modeling of Jet Flame configuration coupled with experimental result seems to present an efficient tool to gain practical knowledge. • Final integration stage is still needed for an engineering flameless combustion design 9th Israeli Symposium on Jet Engines and Gas Turbines, October 7 2010, Technion, Istarel Turbo and Jet Engine Laboratory Technion – Israel 33 www. jet-engine-lab.technion.ac.il GE-90 c 1 c P U 9' 2 n 'Cpc T07 ' 1 9' P07 ' 9th Israeli Symposium on Jet Engines and Gas Turbines, October 7 2010, Technion, Istarel INCORPORATION OF MODIFIED COMBUSTOR IN A TURBO-FAN ENGINE. 34 Turbo and Jet Engine Laboratory Technion – Israel www. jet-engine-lab.technion.ac.il 35 Pollutant Reduction Problem • Compromises involved with conventional combustors: – Emitted species – Flame stability – Cycle efficiency • Need for alternative combustion concepts 9th Israeli Symposium on Jet Engines and Gas Turbines, October 7 2010, Technion, Istarel LOWER STABILITY LIMIT LOW-EMISSION WINDOW Turbo and Jet Engine Laboratory Wulff and Hourmouziadis, 1997 Technion – Israel 35 www. jet-engine-lab.technion.ac.il Observed Experimental Temperature Distribution Plessing et al., 1998 • Stable and safe Flame combustion • Uniformly distributed temperature • Low-NOx emission Stability limits -SchematicAfter Wunning and Wunning, 1997 9th Israeli Symposium on Jet Engines and Gas Turbines, October 7 2010, Technion, Istarel Turbo and Jet Engine Laboratory COMBUSTION IN HOT VITIATED AIR Technion – Israel 36 www. jet-engine-lab.technion.ac.il 16 14 12 10 8 6 4 2 0 Gas turbines II I IF GASES WITH LARGE OXYGEN CONCENTRATION ARE RECIRCULATED, HIGH ADIABATIC TEMPERATURES ( AND NOx) ARE OBTAINED CO2 , H2O. Industrial furnaces 0 5 10 15 20 Oxygen mole fraction, % 25 I – BEFORE COMBUSTION (STIRRING AIR), II – AFTER COMBUSTION, 9th Israeli Symposium on Jet Engines and Gas Turbines, October 7 2010, Technion, Istarel Turbo and Jet Engine Laboratory O2, CO2, H2O MOLE FRACTION AT THE RECIRCULATION ZONE Technion – Israel 37 www. jet-engine-lab.technion.ac.il ry da n co Se Inlet ai r Recirculation Zone Se co nd ar y Exit Mixing Zone Primary air Recirculation Zone Fuel Inlet ai Mixing holes r Secondary Air Exi t Composite Metallic Fins 9th Israeli Symposium on Jet Engines and Gas Turbines, October 7 2010, Technion, Istarel Fuel Inlet SCHEMATIC REPRESENTATION OF THE FLUID FLOW WITHIN THE “MODIFIED” COMBUSTORS 38 Turbo and Jet Engine Laboratory Technion – Israel www. jet-engine-lab.technion.ac.il GLOBAL EVALUATION OF THE FLOXCOM COMBUSTOR Known parameters and assumptions: •Inlet air temperature Ta •Inlet mass flow rate ma , •exit temperatures Te •100% combustion and mixing efficiency calculated Values: •Air flow distribution: stirring air, mas, dilution air, mad stirring gas, mas+mr •Temperature : stirring gas, Ts combustion, Tc •Recirculation rate: k •oxygen percentage in every stage of the cycle. 9th Israeli Symposium on Jet Engines and Gas Turbines, October 7 2010, Technion, Istarel Turbo and Jet Engine Laboratory Technion – Israel 39 www. jet-engine-lab.technion.ac.il 9th Israeli Symposium on Jet Engines and Gas Turbines, October 7 2010, Technion, Istarel HIGH PRESSURE FLOXCOM TEST RIG AT ANSALDO BARI Turbo and Jet Engine Laboratory Technion – Israel 40 www. jet-engine-lab.technion.ac.il T2 [ x3] T3 [ x3] T1 [ x3] Air In Exhaust gases P1 [ x3] T1...T3 - Temperature Sensores P1 - Pressure sensores 9th Israeli Symposium on Jet Engines and Gas Turbines, October 7 2010, Technion, Istarel CROSS SECTION OF THE 360 DEGREES MODEL OF THE FLOXCOM COMBUSTOR. Turbo and Jet Engine Laboratory Technion – Israel 41 www. jet-engine-lab.technion.ac.il ppm NOx 200 ..........… 100.............. 0 ................ 9th Israeli Symposium on Jet Engines and Gas Turbines, October 7 2010, Technion, Istarel FLOXCOM RELATIVE PERFORMANCE Turbo and Jet Engine Laboratory Technion – Israel 42 www. jet-engine-lab.technion.ac.il