Material Safety Data Sheet
Material Name: Rokide® Nickel Chrome 80/20
MSDS ID: Nichrome 80/20
* * * Section 1 - Chemical Product and Company Identification * * *
Part Number: 7733193C
Chemical Name: Resistance Heating Alloy
Manufacturer Information
Saint-Gobain
1 New Bond Street
Worcester, MA 01606
Phone: 508-795-2351
Emergency # 508-795-5000
* * * Section 2 - Hazards Identification * * *
Emergency Overview
This is a non-combustible, non-reactive solid material. Use methods suitable to fight surrounding fire. Under
normal conditions of use for ceramic products, the likelihood of dust generation sufficient for health effects to
occur is very small. If dusts are created, they may cause cuts or abrasions on the surface of the eyes and skin.
May cause mechanical irritation to the skin, eyes, and respiratory tract from dust.
Potential Health Effects: Eyes
May cause eye irritation. Exposure to excessive quantities of dust or powder may mechanically irritate eye tissue.
Potential Health Effects: Skin
May cause abrasions or skin irritation from dust.
Potential Health Effects: Ingestion
No significant adverse effects are expected upon ingestion of the product.
Potential Health Effects: Inhalation
Inhalation may cause mechanical irritation the respiratory tract.
HMIS Ratings: Health: 1* Fire: 0 Reactivity: 0
Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe * = Chronic hazard
* * * Section 3 - Composition / Information on Ingredients * * *
CAS #
7440-02-0
7440-47-3
Substance
Nickel
Chromium
Percent
80
20
Component Information/Information on Non-Hazardous Components
This product is considered hazardous under 29 CFR 1910.1200 (Hazard Communication).
____________________________________________________________ Page 1 of 8
Issue Date: 01/05/2010
Revision: 1.0000
Print Date: 1/8/2010
Material Safety Data Sheet
Material Name: Rokide® Nickel Chrome 80/20
MSDS ID: Nichrome 80/20
* * * Section 4 - First Aid Measures * * *
First Aid: Eyes
Immediately flush eyes with water for at least 15 minutes, while holding eyelids open. Do not rub eyes. Get
medical attention if irritation persists.
First Aid: Skin
Remove contaminated clothing. Wash area of contact thoroughly with soap and water. Do not rub or scratch
exposed skin. If irritation persists, get medical attention. Wash contaminated clothing before reuse.
First Aid: Ingestion
Do not induce vomiting. If ingestion of a large amount does occur, seek medical attention.
First Aid: Inhalation
Move person to non-contaminated air. If symptoms persist, get medical attention.
First Aid: Notes to Physician
Treat symptomatically and supportively.
For eye exposure, insure that eyes have been washed thoroughly.
X-ray follow-up may be indicated for high inhalation exposures, especially in chronically exposed individuals with
review for nodular opacities. A small population segment has been shown to be significantly more vulnerable to
lung injury than the mean.
* * * Section 5 - Fire Fighting Measures * * *
General Fire Hazards
See Section 9 for Flammability Properties.
This material is not expected to be a fire hazard. Dust hazard exists under favoring conditions of small particle
size. Dust accumulation from this product may present an explosion hazard in the presence of an ignition source.
Hazardous Combustion Products
Decomposition of this product may yield metallic oxides.
Extinguishing Media
Dry chemical - use dry powder for metal fires, gently spoon media onto fire. Do not disturb particles.
Fire Fighting Equipment/Instructions
Fire fighters should wear full-face, self contained breathing apparatus and impervious protective clothing. Fire
fighters should avoid inhaling any combustion products.
NFPA Ratings: Health: 1 Fire: 0 Reactivity: 0
Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe
* * * Section 6 - Accidental Release Measures * * *
Containment Procedures
Ventilate area as necessary to reduce any airborne dusts to a safe level before entry unless personal protective
equipment is adequate for protection.
Clean-Up Procedures
Avoid the generation of dusts during clean-up. If sweeping of a contaminated area is necessary, use a dust
suppressant agent. If available, use an industrial vacuum cleaner with HEPA exhaust filtration to clean up
remaining particulate spilled material. Dispose of in accordance with all federal, state, and local disposal
regulations.
____________________________________________________________ Page 2 of 8
Issue Date: 01/05/2010
Revision: 1.0000
Print Date: 1/8/2010
Material Safety Data Sheet
Material Name: Rokide® Nickel Chrome 80/20
MSDS ID: Nichrome 80/20
Evacuation Procedures
None necessary.
Special Procedures
Use personal safety, handling, and exposure recommendations described in Section 8 of this Material Safety
Data Sheet.
* * * Section 7 - Handling and Storage * * *
Handling Procedures
Take every reasonable measure to limit dust/fume concentrations and minimize exposure to dust/fumes.
Storage Procedures
Store in a cool, dry, well-ventilated area. Guard against dust/fume accumulation of this material. Keep the
container tightly closed.
* * * Section 8 - Exposure Controls / Personal Protection * * *
A: Component Exposure Limits
Nickel (7440-02-0)
ACGIH:
OSHA:
NIOSH:
1.5 mg/m3 TWA (inhalable fraction)
1 mg/m3 TWA
0.015 mg/m3 TWA
Chromium (7440-47-3)
ACGIH:
OSHA:
NIOSH:
0.5 mg/m3 TWA
1 mg/m3 TWA
0.5 mg/m3 TWA
B: Component Exposure Limits
Consult local authorities for acceptable exposure limits.
Nickel (7440-02-0)
ACGIH:
OSHA:
NIOSH:
Alberta:
British Columbia:
Manitoba:
New Brunswick:
NW Territories:
Nova Scotia:
Nunavut:
Ontario:
Quebec:
Saskatchewan:
Yukon:
1.5 mg/m3 TWA (inhalable fraction)
1 mg/m3 TWA
0.015 mg/m3 TWA
1.5 mg/m3 TWA
0.05 mg/m3 TWA
1.5 mg/m3 TWA (inhalable fraction)
1 mg/m3 TWA
1 mg/m3 TWA
2 mg/m3 STEL
1.5 mg/m3 TWA (inhalable fraction)
1 mg/m3 TWA
2 mg/m3 STEL
1 mg/m3 TWAEV (inhalable)
1 mg/m3 TWAEV
1.5 mg/m3 TWA (inhalable fraction)
3 mg/m3 STEL (inhalable fraction)
1 mg/m3 TWA
3 mg/m3 STEL
____________________________________________________________ Page 3 of 8
Issue Date: 01/05/2010
Revision: 1.0000
Print Date: 1/8/2010
Material Safety Data Sheet
Material Name: Rokide® Nickel Chrome 80/20
MSDS ID: Nichrome 80/20
Chromium (7440-47-3)
ACGIH:
OSHA:
NIOSH:
Alberta:
British Columbia:
Manitoba:
New Brunswick:
NW Territories:
Nova Scotia:
Nunavut:
Ontario:
Quebec:
Saskatchewan:
Yukon:
0.5 mg/m3 TWA
1 mg/m3 TWA
0.5 mg/m3 TWA
0.5 mg/m3 TWA
0.5 mg/m3 TWA
0.5 mg/m3 TWA
0.5 mg/m3 TWA
0.5 mg/m3 TWA
1.5 mg/m3 STEL
0.5 mg/m3 TWA
0.5 mg/m3 TWA
1.5 mg/m3 STEL
0.5 mg/m3 TWAEV
0.5 mg/m3 TWAEV
0.5 mg/m3 TWA
1.5 mg/m3 STEL
0.1 mg/m3 TWA
3.0 mg/m3 STEL
Engineering Controls
Ventilation should effectively remove and prevent buildup of any dust generated from the handling of this product.
Local exhaust ventilation is recommended when generating excessive levels of airborne dust or vapors from
handling or thermal processing. Use a dust suppressant agent as needed.
PERSONAL PROTECTIVE EQUIPMENT
Personal Protective Equipment: Eyes/Face
Wear safety glasses or chemical goggles to reduce eye contact with dust.
Personal Protective Equipment: Skin
Wear gloves and protective clothing to prevent skin contact. Use good personal hygiene. Showering and
changing into clean clothing after work is strongly recommended.
Personal Protective Equipment: Respiratory
If ventilation is not sufficient to effectively prevent buildup of dust, appropriate NIOSH respiratory protection must
be provided.
Personal Protective Equipment: General
Eye wash fountain is recommended.
* * * Section 9 - Physical & Chemical Properties * * *
Appearance:
Physical State:
Vapor Pressure:
Boiling Point:
Solubility in Water:
Flash Point:
Lower Flammability Limit:
Auto Ignition Temp:
Odor:
pH:
Vapor Density:
Melting Point:
Specific Gravity:
Flash Point Method:
Upper Flammability Limit:
Solid metal rod
Solid
Not applicable
Not applicable
None
Not applicable
Not applicable
Not applicable
Not available
Not applicable
Not applicable
1850°C
4.0
Not applicable
Not applicable
____________________________________________________________ Page 4 of 8
Issue Date: 01/05/2010
Revision: 1.0000
Print Date: 1/8/2010
Material Safety Data Sheet
Material Name: Rokide® Nickel Chrome 80/20
MSDS ID: Nichrome 80/20
* * * Section 10 - Chemical Stability & Reactivity Information * * *
Chemical Stability
This is a stable material.
Chemical Stability: Conditions to Avoid
Avoid dispersion of dust in air. Avoid incompatible materials.
Incompatibility
Inert materials.
Hazardous Decomposition
Decomposition of this product may yield metallic oxides.
Possibility of Hazardous Reactions
Will not occur.
* * * Section 11 - Toxicological Information * * *
Acute Dose Effects
A: General Product Information
This product may cause mechanical eye, skin, and respiratory irritation. May cause abrasion to the eyes and
skin. This product may cause metal fume fever with resulting flu-like symptoms.
B: Component Analysis - LD50/LC50
Nickel (7440-02-0)
Oral LD50 Rat >9000 mg/kg
Repeated Dose Effects
Adverse effects may result from long term exposure to welding fume, gases, or dusts. These include skin
sensitization, neurological damage, and respiratory disease. Nickel overexposure can cause allergic skin
reactions and allergic lung sensitization reactions producing an asthma-like condition. Inhalation can cause
effects on the lungs such as bronchitis, emphysema and impaired function, as well as kidney damage. Ingestion
can result in nausea, vomiting, diarrhea and abdominal cramps. Chronic overexposure during nickel production
has been shown to cause lung and nasal cavity cancers in workers; these effects are directly related to the
degree of exposure. The compounds associated with the production environment included metallic nickel, nickel
oxides and nickel sulfides. Workplaces other than those involved with mining, refining and alloy manufacture
have not been studied. Asthma induced by occupational exposure to nickel has been documented. The asthma
can result from either primary irritation or from an allergic response. Contact dermatitis in workers exposed to
nickel compounds is one of the most prevalent effects of nickel exposure. Chromium III, the naturally occurring
form, has low toxicity while chromium VI is highly toxic due to strong oxidation characteristics and permeability
through biological membranes. Excessive exposure to chromium VI can produce allergic skin sensitization
reactions and severe nasal irritation, scarring and damage to the lungs, liver and kidney damage. Industrial
exposure to chromium may cause dermatitis, skin ulcers, perforation of the nasal septum, as well as cancers of
the lungs, nasal cavity and paranasal sinuses.
____________________________________________________________ Page 5 of 8
Issue Date: 01/05/2010
Revision: 1.0000
Print Date: 1/8/2010
Material Safety Data Sheet
Material Name: Rokide® Nickel Chrome 80/20
MSDS ID: Nichrome 80/20
Carcinogenicity
A: General Product Information
The carcinogenic effect of nickel has been well documented in occupationally exposed nickel refinery workers.
Lung and nasal cancers were the predominant forms of cancer in the exposed workers. In experimental animals
injection of nickel produced injection site tumors although some of these tumors metastasized. Upon inhalation of
nickel, lymphosarcomas were observed in mice and aveolar carcinomas in guinea pigs.
B: Component Carcinogenicity
Nickel (7440-02-0)
ACGIH:
NIOSH:
NTP:
IARC:
A5 - Not Suspected as a Human Carcinogen
potential occupational carcinogen
Reasonably Anticipated To Be A Human Carcinogen (Possible Select Carcinogen)
Monograph 49 [1990]; Supplement 7 [1987] (Group 2B (possibly carcinogenic to humans))
Chromium (7440-47-3)
ACGIH:
IARC:
A4 - Not Classifiable as a Human Carcinogen
Monograph 49 [1990] (listed under Chromium and Chromium compounds); Supplement 7 [1987]
(Group 3 (not classifiable))
* * * Section 12 - Ecological Information * * *
Ecotoxicity
A: General Product Information
No information available for the product.
B: Component Analysis - Ecotoxicity - Aquatic Toxicity
Nickel (7440-02-0)
Test & Species
Conditions
96 Hr LC50 Brachydanio rerio
96 Hr LC50 Cyprinus carpio
96 Hr LC50 Cyprinus carpio
72 Hr EC50 Pseudokirchneriella subcapitata
96 Hr EC50 Pseudokirchneriella subcapitata
48 Hr EC50 Daphnia magna
48 Hr EC50 Daphnia magna
>100 mg/L
1.3 mg/L
10.4 mg/L
0.18 mg/L
0.174 - 0.311 mg/L
>100 mg/L
1 mg/L
Semi-static
Static
Static
Static
* * * Section 13 - Disposal Considerations * * *
US EPA Waste Number & Descriptions
A: General Product Information
Dispose of waste material according to Local, State, Federal, and Provincial Environmental Regulations.
B: Component Waste Numbers
Chromium (7440-47-3)
RCRA:
5.0 mg/L regulatory level
Disposal Instructions
Clean up and dispose of waste in accordance with all federal, state, and local environmental regulations.
See Section 7 for Handling Procedures. See Section 8 for Personal Protective Equipment recommendations.
____________________________________________________________ Page 6 of 8
Issue Date: 01/05/2010
Revision: 1.0000
Print Date: 1/8/2010
Material Safety Data Sheet
Material Name: Rokide® Nickel Chrome 80/20
MSDS ID: Nichrome 80/20
* * * Section 14 - Transportation Information * * *
DOT Information:
Shipping Name: Not regulated as a hazardous material.
TDG Information:
Shipping Name: Not regulated as a dangerous good.
* * * Section 15 - Regulatory Information * * *
US Federal Regulations
A: General Product Information
Components of this product have been checked against the non-confidential TSCA inventory by CAS Registry
Number. Components not identified on this non-confidential inventory are exempt from listing (i.e. as polymers)
or are listed on the confidential inventory as declared by the supplier.
B: Component Analysis
This material contains one or more of the following chemicals required to be identified under SARA Section 302
(40 CFR 355 Appendix A), SARA Section 313 (40 CFR 372.65) and/or CERCLA (40 CFR 302.4).
Nickel (7440-02-0)
SARA 313:
CERCLA:
0.1 % de minimis concentration
100 lb final RQ (no reporting of releases of this hazardous substance is required if the diameter
of the pieces of the solid metal released is larger than 100 micrometers); 45.4 kg final RQ (no
reporting of releases of this hazardous substance is required if the diameter of the pieces of the
solid metal released is larger than 100 micrometers)
Chromium (7440-47-3)
SARA 313:
CERCLA:
1.0 % de minimis concentration
5000 lb final RQ (no reporting of releases of this hazardous substance is required if the diameter
of the pieces of the solid metal released is larger than 100 micrometers); 2270 kg final RQ (no
reporting of releases of this hazardous substance is required if the diameter of the pieces of the
solid metal released is larger than 100 micrometers)
Acute Health: Yes Chronic Health: Yes Fire: No Pressure: No Reactive: No
State Regulations
A: General Product Information
Other state regulations may apply. Check individual state requirements.
B: Component Analysis - State
The following components appear on one or more of the following state hazardous substances lists:
Component
Nickel
Chromium
CAS
7440-02-0
7440-47-3
CA
Yes
Yes
MA
Yes
Yes
MN
Yes
Yes
NJ
Yes
Yes
PA
Yes
Yes
RI
Yes
Yes
The following statement(s) are provided under the California Safe Drinking Water and Toxic Enforcement Act of
1986 (Proposition 65):
WARNING! This product contains a chemical known to the state of California to cause cancer.
____________________________________________________________ Page 7 of 8
Issue Date: 01/05/2010
Revision: 1.0000
Print Date: 1/8/2010
Material Safety Data Sheet
Material Name: Rokide® Nickel Chrome 80/20
MSDS ID: Nichrome 80/20
Component Analysis - WHMIS IDL
The following components are identified under the Canadian Hazardous Products Act Ingredient Disclosure List:
CAS #
Minimum Concentration
Substance
Nickel
Chromium
7440-02-0
7440-47-3
0.1 %
0.1 %
Additional Regulatory Information
A: General Product Information
No additional information available.
B: Component Analysis - Inventory
Substance
Nickel
Chromium
CAS #
7440-02-0
7440-47-3
TSCA
Yes
Yes
CAN
DSL
DSL
EEC
EINECS
EINECS
* * * Section 16 - Other Information * * *
Other Information
The information and recommendations set forth herein are taken from sources believed to be accurate as to the
data hereof; however, Saint-Gobain Coatings Solution makes no warranty with respect to the accuracy of the
information or the suitability of the recommendations and assures no liability to any user thereof.
Key/Legend
ACGIH = American Conference of Governmental Industrial Hygienists; CAS = Chemical Abstracts Service;
CERCLA = Comprehensive Environmental Response, Compensation, and Liability Act; CFR = Code of Federal
Regulations; CPR = Controlled Products Regulations; DOT = Department of Transportation; DSL = Domestic
Substances List; EINECS = European Inventory of Existing Commercial Chemical Substances; EPA =
Environmental Protection Agency; IARC = International Agency for Research on Cancer; IATA = International Air
Transport Association; mg/Kg = milligrams per Kilogram; mg/L = milligrams per Liter; mg/m3 = milligrams per
Cubic Meter; MSHA = Mine Safety and Health Administration; NA = Not Applicable or Not Available; NIOSH =
National Institute for Occupational Safety and Health; NJTSR = New Jersey Trade Secret Registry; NTP =
National Toxicology Program; OSHA = Occupational Safety and Health Administration; SARA = Superfund
Amendments and Reauthorization Act; STEL = Short Term Exposure Limit; TDG = Transport Dangerous Goods;
TSCA = Toxic Substances Control Act; WHMIS = Workplace Hazardous Materials Information System.
End of Sheet NICHROME 80/20
____________________________________________________________ Page 8 of 8
Issue Date: 01/05/2010
Revision: 1.0000
Print Date: 1/8/2010