4.4 Linear Dielectrics r F stable θ stable magnetic dipole superconductor F image dipole 4.4.1 Susceptibility, Permitivility, Dielectric Constant r If E is not too strong, the polarization is proportional to the field. r r r r r r P = χ eε 0 E (since D = ε 0 E + P , D is electric displacement from ρ free ) r r Æ ∇× D = ∇× P = 0 χ e is called the electric susceptibility. χe = M P , χm = ε0E H r r r r r D = ε 0 E + P = ε 0 (1 + χ e )E = εE , ε is called the permittivity. εr = ε = 1 + χ e is called the relative permittivity, or dielectric constant. ε0 Material Dielectric Constant Material Dielectric Constant Vacuum 1 Benzene 2.28 Helium 1.000065 Diamond 5.7 Air 1.00054 Water 80.1 Nitrogen 1.00055 KTaNbO3 34,000 What is high K material? +++++++++ +++++++++ +++++++++ εr = 2 E E Vacuum ------------------------It may discharge for an electric field higher than E. Example: A metal sphere of radius a carries a charge Q. It is surrounded, out to radius b, by linear dielectric material of permittivity ε . Find the potential at the center. r r r Q Q Q rˆ and b > r > a , E = D= rˆ Æ r > b , E = rˆ 2 2 4πε 0 r 4πr 4πεr 2 a b V= Q 4π a b Q 1 1 1 1 1 ∫− + − 2 dr = − + dr ∫ ε r2 εr b ∞ 0 4π ε 0b εb εa r r χεQ b > r > a , P = χ eε 0 E = e 0 2 rˆ 4πεr r ρb = −∇ ⋅ P = 0 r r χεQ χεQ r = a , σ b = P ⋅ (− rˆ ) = − e 0 2 and r = b , σ b = P ⋅ (rˆ ) = e 0 2 4πεa 4πεb If the space is entirely filled with a homogeneous linear dielectric, then r r E ∇ ⋅ D = ρ f and ∇ × D = 0 vacuum P When crossing the boundary: r r ∇× D = ∇× P ≠ 0 Example: A parallel-plate capacitor is filled with insulating material of dielectric constant ε r . What effect does this ---------- have on its capacitance? ++++++++++ 2 AD = Aσ + Æ D+ = 2 AD = Aσ − Æ D− = Ein = σ+ 2 σ− 2 , E+ ,up = =− σ+ 2 σ+ σ σ , E+ ,up , out = + , E+ , down = − + 2ε 2ε 0 2ε 0 , E− ,up = − σ+ σ σ , E− , down = + , E− , doun , out = + 2ε 0 2ε 2ε 0 Q Q Aε σ σ Æ ∆V = d = d, C= = = ε r Cvacuum Aε ∆V d ε ε 4.4.2 Boundary Value Problem with Linear Dielectrics If we place free charge inside a linear dielectric, r r r ε0D χ = − e ρf ρ b = −∇ ⋅ P = −∇ ⋅ χ eε 0 E = −∇ ⋅ χ e ε 1 + χe ( ) If we place the free charge on the boundary: D⊥ , above − D⊥ ,below = σ f Æ ε above E⊥ , above − ε below E⊥ ,below = σ f ∂Vabove ∂V − ε below − below = σ f , continuity: Vabove = Vbelow ∂n ∂n ε above − + Example: A sphere of homogeneous linear dielectric material is r placed in an otherwise uniform electric field E0 . Find the E0 electric field inside the sphere. Method 1: ∂V ∂V The free charge is on the boundary Æ ε out − out − ε in − in = σ f = 0 ∂r ∂r Only bound charge exists, no free charge. r >> R , Vout → − E0 r cosθ r = R, ε ∂Vin ∂V = ε 0 out and Vin = Vout ∂r ∂r Vout = − E0 r cosθ + A cosθ , Vin = Br cosθ r2 A 3 2A ε − ε0 = BR , εB = ε 0 − E0 − 3 Æ B = − E0 , A = R 3 2 R R 2 + ε / ε0 2ε 0 + ε r 3 3 3 ∂V Vin = − E0 r cosθ = − E0 z Æ E = − zˆ = E0 zˆ 2 + εr 2 + εr 2 + εr ∂z − E0 R + Method 2: r Uniformly polarized sphere with polarization P = Pzˆ may produce electric field r P E=− zˆ inside. 3ε 0 r P zˆ inducing the polarization: Total field inside: E = E0 − 3ε 0 r r 3 3 3χ e P zˆ Æ P = Pzˆ = χ eε 0 E = χ eε 0 E0 − ε 0 E0 Æ E = E0 zˆ = E0 zˆ 3 2 3 ε 3 + + χ + ε χ 0 e e r Example: Suppose the entire region below the plane z = 0 is filled with uniform linear dielectric material of susceptibility χ e . Calculate the force on a point charge q situated a distance d above the origin. Considering q without dielectric material: q d 1 E z ,below = − 2 2 2 4πε 0 r + d r + d2 r σ Considering dielectric material without q: σ b = P ⋅ zˆ Æ E z , above = b and 2ε 0 ( ) E z ,below = − σb 2ε 0 r σ b qd − Total effect: P ⋅ zˆ = σ b = χ eε 0 Ez ,below,total = χ eε 0 − 3 2 2 2ε 0 4πε 0 r + d σb = − 1 χe qd 2 2π χ e + 2 r + d 2 ( ) 3/ 2 Total bound charge: χe q Qb = ∫ σ b da = − χe + 2 χe q at z = -d to solve the problem. Use image charge Qb = − χ + 2 e V= 1 q + 4πε 0 x 2 + y 2 + ( z − d )2 Qb x 2 + y 2 + (z + d ) 2 z>0 q + Qb 1 2 2 2 4πε 0 x + y + (z − d ) r 1 qQb zˆ attractive force on q: F = 4πε 0 (2d )2 V= z<0 4.4.3 Energy in Dielectric Systems To charge up a capactor, it takes energy of Q Q2 1 dQ = = CV 2 C 2C 2 Change of capacitance in dielectric materials: Cdielectric = ε r Cvacuum Æ increase the energy because of an increase of charge dW = VdQ Æ W = ∫ ( ) ( ) r r r ∆W = ∫ ∆ρ f Vdτ , ρ f = ∇ ⋅ D Æ ∆W = ∫ ∆ ∇ ⋅ D Vdτ = ∫ ∇ ⋅ ∆D Vdτ ( ) ( ) ( ) ( ) r r r r r r r ∇ ⋅ ∆DV = ∇ ⋅ ∆D V + ∆D ⋅ ∇V Æ ∇ ⋅ ∆D V = ∇ ⋅ ∆DV + ∆D ⋅ E Choose V=0 at r → ∞ . r r 1 r r r r ∆W = ∫ ∆D ⋅ Edτ for a linear dielectric ∆D ⋅ E = ∆ D ⋅ E 2 ( ) ( ) W= 1 r r D ⋅ Edτ 2∫ l 4.4.4 Forces on Dielectrics x fringing field Cvacuum = Q wlσ ε 0 wl = = V σ d d ε0 Cdielectric = ε r Cvacuum Æ C = ε 0w d x + εr ε 0w d (l − x ) = ε 0 w (ε r l − χ e x ) d Assume that the total charge on the plate is constant ( Q = CV ), W = F =− 1 Q2 2 C dW Q 2 dC 1 2 dC ε χw = = V = − 0 e V 2 attractive force 2 2d dx 2C dx 2 dx If you start from constant voltage, the work supplied by a battery must be included. F =− d 1 dQ 2 CV + V dx 2 dx If the voltage is constant and the charge is varying, you must include the force due to the battery for maintaining a constant voltage. ++++++++ + + + + ++++ Exercise: 4.18, 4.23, 4.28 1. Dielectric material Æ increase the capacitance of a capacitor Æ store much more charges 2. P E+ P 3ε 0 E P E E + P / ε0 E P − P ε0 − P 3ε 0 3. Ferroelectricity: BaTiO3 ferroelectric Transition temperature? Curie-Weiss law? antiferroelectric