Cement Additives
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Cement Additives Oil and Gas Technologies With good chemistry great things happen.™ Ashland is the world’s leading manufacturer of additives for drilling fluids, stimulation fluids, completion fluids, workover fluids, cementing slurries and production. We provide oil and gas service companies superior and cost-effective fluids performance across a broad range of pH, temperature and salt conditions. Our high-quality products are versatile, widely compatible and environmentally friendly.1 Cementing Additives manufactured by Ashland include hydroxyethylcellulose, carboxymethyl hydroxyethylcellulose, synthetics and surfactants. We provide a broad range of effective solutions for oil-well cement slurries under a wide range of temperature and salt conditions. Natrosol™ hydroxyethylcellulose • Consistent fluid loss and free water control Developmental Product Aqu D-5278 carboxymethyl hydroxyethylcellulose • Superior thickening efficiency • Consistent fluid loss and free water control • Easily breakable; provides efficient suspending capacity • Superior thickening efficiency • Non-ionic water-soluble polymer • Readily crosslinked with polyvalent cations • Excellent salt tolerance • Short-term acid thickening capability • Available in powder and liquid form (environmentally friendly anhydrous solvent-based suspensions and EcoDura™ PLONOR rated aqueous suspensions) • Excellent proppant suspension capacity • Compatible with virtually all other additives for water-based systems • Environmentally friendly EcoDura™ aqueous fluidized polymer suspension • High active content suspension • Readily dispersible and easily dissolves • Compatible with virtually all other additives for water-based systems • PLONOR rated • Extremely low residue after break • Water-soluble, high molecular weight polymer with both anionic and nonionic substitution. • Excellent salt tolerance XxtraDura™ additives for extreme operating conditions • Universal fluid loss control additive • Outstanding gas migration control additive • Effective at low dosages • Compatible with common cement additives • Functions in broad operating conditions of temperature (+350 °F) and salt environments (36% NaCl) • Available in powder and liquid forms 1 Contains no hazardous or toxic compounds. Techwax™ additives Drewplus™ foam control agents • Excellent fluid loss control • Broad range available • Outstanding temperature and shear stability • Alcohol, mineral oil and silicone-based products • Superior performance control of drilling fluid rheology even in the presence of contaminants Surfadone™, Strodex™ & Dextrol™ surfactants • Capable of controlling rheology in the presence of divalent salts • High performance spacer surfactants • High emulsification • Wide range of chemistries • Efficient corrosion control • Liquid products that are easy and safe to handle • Functions across a broad pH range Jaypol™ performance chemistry • Functions at a high calcium level and especially tolerant of highdissolved irons • High-temperature stability • Prevents scale build-up in both formation and production equipment • High-performance water clarifier Ashland Cementing Products Function Product Description XxtraDura™ FLA 3766 Anionic synthetic co-polymer XxtraDura FLA 3767 Anionic synthetic co-polymer XxtraDura GMA 4176 Polymeric solution of anionic synthetic co-polymers XxtraDura GMA 4176P Polymeric blend of anionic synthetic co-polymers XxtraDura GMA 4176 HD Polymeric solution of anionic synthetic co-polymers for high density cement slurries XxtraDura GMA 4176 HDP Polymeric blend of anionic synthetic co-polymers for high density cement slurries EcoDura™ PVA Aqueous FPS of polyvinyl alcohol PVP K-30 Polyvinylpyrrolidone Natrosol™ 250 LR Ultra Low viscosity hydroxyethylcellulose EcoDura FLA 4451 PLONOR aqueous FPS of Natrosol™ 250 LR hydroxyethylcellulose Natrosol 250 EXR Medium-low viscosity hydroxyethylcellulose Natrosol 250 GXR Medium viscosity hydroxyethylcellulose Natrosol 180 GR Medium viscosity hydroxyethylcellulose EcoDura FLA 4641 PLONOR aqueous FPS of Natrosol™ 180 GR hydroxyethylcellulose Natrosol 250 MR Medium-high viscosity hydroxyethylcellulose Natrosol Liquid MR Medium-high viscosity hydroxyethylcellulose Developmental Product Aqu D-5278 Carboxymethyl hydroxyethylcellulose Natrosol 250 HHR-P Ultra high viscosity hydroxyethylcellulose Natrosol 210 HHX Ultra high viscosity and fast hydration hydroxyethylcellulose Natrosol S-HEC Ultra high viscosity and high temperature hydroxyethylcellulose Techwax™ LX100 Xanthan dispersion in butyl diglycol Fluid Loss Synthetics Gas Migration Fluid Loss Enhancer Fluid Loss HEC Free Fluid / Suspension Bio-Polymer Free Fluid / Suspension Form Operating Temperature Salt Tolerant Features and Benefits Liquid 80 – 350°F Yes • Extreemly efficient, even at low dosage and high temperature • Right Angle Set Powder 80 – 350°F Yes • Minimal rheological effect on slurry properties • Composition structure stable at temperatures above 500°F Liquid 80 – 350°F Yes Powder 80 – 350°F Yes Liquid 80 – 350°F Yes Powder 80 – 350°F Yes Liquid 80 - 240°F No • Excellent film forming ability for gas migration control Powder 80 - 240°F Yes • Works synergistically with formaldehyde napthalene sulfonate dispersants to enhance fluid loss control of fluid loss control additives Powder 80 – 220°F Yes Liquid 80 – 220°F Yes Powder 80 – 200°F Yes Powder 80 – 200°F Yes Powder 80 – 200°F Yes Liquid 80 – 200°F Yes Powder 80 – 200°F Yes Powder 80 – 200°F Yes Powder 80 - 250°F Yes Powder 80 – 200°F Yes Powder 80 – 200°F Yes Powder 80 – 230°F Yes Liquid 80 – 270°F Yes • Multipurpose cement additive • Extremely efficient at low dosage • Outstanding gas migration control (fluid migration test and right angle set) • Excellent slurry stability • Wide range of viscosity grades for varying density systems • Readily dispersible • High viscosity multi-purpose film forming HEC for fluid loss • High viscosity HEC for free fluid and suspension control • Efficient at low dosage Ashland Cementing Products Function Product Description Form Lost Circulation Techwax FLA12 Crosslinked SBR latex Powder Foaming Agents Techwax DFA Ether sulfate Liquid DrewPlus S-4386 Aqueous emulsion of silica Liquid DrewPlus L-1311E Mineral oil based Liquid DrewPlus L-419 Polysiloxane/silica emulsion Liquid DrewPlus L-108 Mineral oil emulsion of silica Liquid DrewPlus T-4201 Mineral oil based defoamer containing hydrophobic silica Liquid Techwax AD2E Long chain alcohol Liquid Dextrol OC-60 Tridecyl alcohol ethoxylated phosphate ester Liquid Strodex LFK-70 Tridecyl alcohol ethoxylated phosphate ester Liquid Strodex TH-100 Tridecyl alcohol ethoxylated phosphate ester Liquid Anti-Foaming Agents Spacer Surfactants Ashland Products for Oil and Gas Applications X X X Aqu D-5278 carboxymethyl hydroxyethylcellulose (CMHEC) X X X X X X X X X X X AquaPAC™ and AquaFLO™ carboxymethyl cellulose (CMC) X X X X X X X Aqualon™ carboxymethyl cellulose (CMC) X X X X X X X X X X X X Galactasol™ guar derivatives Polyvinylpyrrolidone (PVP) X X X X XxtraDura™ synthetic additives Techwax™ additives X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X Jaypol™ scale inhibitors X X Inhibex™ kinetic hydrate inhibitors Drewplus™ foam control agents Surfadone™, Strodex™ and Dextrol™ surfactants Propargyl alcohol M-Pyrol™ solvent X X Pour Point Depressant X Kinetic Hydrate Inhibitor X Specialty Solvents X Scale Inhibitor X Corrosion Inhibitors Acid Thickeners X Defoamers Rheology Modifiers X Corrosion Inhibitors Gellants X Foamers Fluid Loss Control X Defoamers Rheology Modifiers X EcoDura™ PLONOR liquid additives Defoamers X X Spacer Surfactants X X Foamers X X Defoamers X X Spotting Fluids X X Wetting Agents X X Detergent X X Emulsifiers X X Lubricant X X Fluid Loss Control X X Foamers X Natrosol™ liquid additives Defoamers Fluid Loss Control Production Free Fluid Control Corrosion Inhibitors Stimulation Extender Gas Migration Control Completion Rheology Modifier Shale Swell Inhibitors Cementing Natrosol™ hydroxyethylcellulose (HEC) Product Lines/Functionality Rheology Modifiers Drilling Fluids X X X X X X X X Global Headquarters Ashland Inc. 50 East RiverCenter Blvd. Covington, KY 41012 USA Tel: +1 859 815 3333 Ashland Specialty Ingredients 8145 Blazer Drive Wilmington, DE 19808 USA Tel: +1 877 546 2782 Regional Sales Offices North America The Woodlands, TX USA Tel: +1 281 465 6800 oilandgastechnologiesNA@ashland.com Latin America São Paulo, Brazil Tel: +55 11 3649 0455 Fax: +55 11 3649 0450 Mexico City, Mexico Tel: +52 55 5276 6110 Fax: +52 55 2614 2939 Buenos Aires, Argentina Tel: +54 11 4314 8971 Fax: +54 11 4314 8976 oilandgastechnologiesSA@ashland.com Asia Pacific Singapore Tel: +65 6775 5366 Fax: +65 6775 5433 Mumbai, India Tel: +91 22 61484646 Fax: +91 22 61484639 oilandgastechnologiesAP@ashland.com Shanghai, P.R. China Tel: +86 21 2402 4888 Fax: +86 21 2402 4850 Europe Schaffhausen, Switzerland Tel: +41 52 560 5500 oilandgastechnologiesEMEA@ashland.com Middle East and Africa Dubai, U.A.E. Tel: +971 4 381 8515 oilandgastechnologiesEMEA@ashland.com ashland.com ™ Registered trademark, Ashland or its subsidiaries, registered in various countries ™ Trademark, Ashland or its subsidiaries, registered in various countries ©2013, 2015, 2016, Ashland PC-11787.4 The information contained in this brochure and the various products described are intended for use only by persons having technical skill and at their own discretion and risk after they have performed necessary technical investigations, tests and evaluations of the products and their uses. Certain end uses of these products may be regulated pursuant to rules or regulations governing medical devices, drug uses, or pesticidal or antimicrobial uses. It is the end user’s responsibility to determine the applicability of such regulations to its products. All statements, information, and data presented herein are believed to be accurate and reliable, but are not to be taken as a guarantee of fitness for a particular purpose, or representation, express or implied, for which seller assumes legal responsibility. No freedom to use any patent owned by Ashland, its subsidiaries, or its suppliers is to be inferred.
