Impact of Environmental and Radiation Exposure on Flammability of Fiber Optic Cable Materials for Nuclear Power Applications Brian G. Risch, Ray Lovie, and Erin Bowman Prysmian Group P.O. Box 39 Claremont, NC 28610-0039 1-828-459-8435 · brian.risch@draka.com Abstract This study examines the impact of end of life thermal aging simulations on materials flammability and cable burn test results conducted according to IEEE 1202. Additionally, the impact of radiation exposure simulations equivalent to cable radiation exposure outside of the containment vessel during a severe Loss Of Cooling Accident (LOCA) are examined with respect to both cable operation as well as cable mechanical properties and flammability. Several classes of cable materials are examined including a PVDF compound, LSZH compounds with varying formulation, a CPE jacketing compound, and an elastomeric tight buffer material. It is demonstrated that cable safety, from a flammability standpoint and rated burn test performance, is not compromised after 50 years or more under normal service conditions or after radiation exposure equivalent to that which could be experienced even in a very severe nuclear accident. The lifetime prediction techniques which incorporate known failure mechanisms for these materials predict practical service lifetimes for many combinations of materials that exceed 50 years under normal service conditions. Keywords: fiber optic cable, reliability, lifetime, Arrhenius, nuclear power plant, cable burn testing. 1. Introduction Currently there are over 400 operational nuclear power plants which produce 14% of global electricity.1 In Europe the percentage of electricity produced from nuclear power plants is about 30% and increasing. Currently there are dozens of new nuclear reactors under construction with 150 or more being planned for the coming years. With the demand for nuclear power increasing due to concerns about greenhouse gas emissions, limitations of fossil fuel resources, and increasing global energy demands, continued growth in the nuclear power industry is expected. Especially with the recent nuclear accident at the Fukushima Daiichi nuclear power plant in March of 2011, there has been increasing concerns about safety of nuclear power plants. A critical concern for fiber optic cables in nuclear power plants is not only that they continue to function during their lifetime and in the event of an accident, but also that the cables do not propagate a fire in the event of an emergency. A critical part of testing for any cable designed for a nuclear power application includes testing of functional parameters for sensitivity to service environment. Critical parameters investigated for the fiber optic nuclear power plant cables in this study are sensitivity of cable and cable material flammability to both thermal aging and radiation. . 2. The Arrhenius Approach to Thermal Lifetime Simulation Almost universally the simulation of long-term service for lifetime estimation of cables used in nuclear power applications is achieved by the use of isothermal aging at elevated temperature and using Arrhenius extrapolation.2,3,4,5,6 Typically, for qualification of a cable, the activation energy for degradation of the cable materials must first be determined in order to establish the time and temperature required to simulate an in-service lifetime. Then the cable must be aged according to this criteria followed by some functional and performance testing. Cable burn testing after simulated in-service lifetime is important to examine if there are any mechanisms present which could lead to degradation of cable flame retardancy. It is important to assure that cable flame retardancy does not degrade during the life of the cable as compromised cable flame retardancy could lead to fire propagation in the event of an accident. The Arrhenius equation describes a specific rate constant (K) as a function of an activation energy (Ea), the gas constant (R), and temperature (T). K=Ae -[Ea/RT] . (1) To determine the time to equivalent aging at different temperatures, equation (1) can be expressed as: t1 = t2 e [(Ea/R)*(1/T1-1/T2 )] , (2) where t1 is the time of accelerated aging at temperature T1, and t2 is the time of simulated lifetime at temperature T2. Similarly, equation 2 can be rewritten to determine a simulated lifetime, t2, at temperature T2 that corresponds to environmental exposure testing at temperature T1, and time, t2: t2 = t1 e [(Ea/R)*(1/T2-1/T1 )] , (3) The Arrhenius activation energies of all materials investigated in this study were determined earlier and have been published along with experimental details in the 2010 IWCS proceedings. 7 3. Considerations for Radiation Testing of Fiber Optic Cables Optical fiber cables within nuclear power plants must be able to maintain their mechanical integrity and fire retardancy throughout their lifetime, even with thermal and radiation exposure. Testing must be conducted to ensure that potential material changes caused by radiation exposure do not hinder the fire retardancy of the cable and introduce a possible mode of fire propagation in the event of an accident. A very important consideration for introduction of fiber optic cables into nuclear power generation environments is the impact of radiation on optical fiber cable performance. Ionizing radiation can have the most profound and variable impact on optical fiber performance. The impact of radiation on optical fiber performance is a function of variables such as fiber type, doping of core/cladding, perform process, operation wavelength and light power, total radiation dose, dose rate, annealing (time after dose), as well as operation temperature. It is therefore of critical importance to match the fiber type for a given cable design to the application environment within the nuclear power plant environment. The impact of total radiation dose as well as dose rate may a strong function for optical fibers, cable materials, and biological matter. Especially for optical fibers a high radiation dose over a short time can be more damaging than a similar dose experienced over a lifetime.8 When designing fiber optic cables for nuclear power plants, both total accumulated dose and a single, high dose event must be considered. In the event of a nuclear accident the optical fiber cable must continue to function even during very high peak dose rates which may occur for short periods of time. The cable materials and optical fiber also must be robust enough to withstand a large total integrated radiation dose. Some examples of possible ranges of peak radiation doses and total doses are given in Table 1 below (1 Gy = 1J absorbed/ Kg). Table 1: Examples of Typical Gamma-Radiation Doses for Specific Environments and Events. Radiation Dose (Gy) Environment or Event 0.06mGy Chest x-Ray 400mGy/hr Highest measured on campus dose outside of containment structures during Fukushima Daiichi I nuclear accident.9 1 Gy/hr Approximate peak dose during Fukushima Daiichi I nuclear accident in immediate vicinity of reactor within containment structures. 5 Gy Short-term 1 time full body gamma dose fatal to ~50% of humans within one month.10 >200 Gy/hr Peak dose during 1986 Chernobyl nuclear accident in reactor building.11 10 Gy <5 Gy Dose experienced by some emergency workers at the April 26th, 1986 Chernobyl nuclear accident.12 60 year integrated radiation exposure for general areas outside of containment in a nuclear power plant application.13,14 <5 Gy Design Basis Accident (DBE) radiation dose for general areas outside of containment in a nuclear power plant application.13,14 <100 000Gy Typical 60 year integrated radiation exposure for areas inside of secondary containment but outside of primary containment.14 <10 000 Gy 60 year integrated radiation exposure for radioactive waste storage area in a typical nuclear power plant.* <100 000 Gy 60 year integrated radiation exposure for radioactive waste tank cubicles inside a typical nuclear power plant.* 400 000 – Possible design basis accident total radiation dose inside primary containment for a typical modern nuclear reactor.* 3 000 000 Gy *Normally, fiber optic cables are not installed in these locations within a nuclear power plant. When considering the specific route design within a nuclear power generation campus, each link must be considered for specific environmental and radiation exposure conditions. To optimize cable performance for these specific conditions, both cable design and fiber type must be selected appropriately. Often standard fibers will not be suitable, and radiation resistant fibers such as germanium doped PCVD phosphorous-free optical fibers will be required for specific areas where radiation levels will be elevated.15,16,17 For applications where even higher levels of radiation resistance are required, fibers such as PCVD full fluorine-doped optical fibers may be required.18 4. Experimental 4.1 Thermal Lifetime Simulation Based on Arrhenius Testing of Materials. After determination of the Arrhenius activation energy for materials degradation, the required heat aging conditions corresponding to simulated lifetimes at service temperatures can be determined using equation 3. The simulated lifetimes corresponding to the aging conditions for aged flammability testing are included in Table 2. Table 2: Simulated Lifetime for Materials Flammability Testing Determined from Materials Arrhenius Testing. Aging Temp. (°C) Simulated Use Temp. (°C) T1 T2 Ea (KJ/mo l) t2 320 80 50 110 28 60 100 50 110 40 320 100 50 110 213 320 110 50 110 537 110 146 70 110 299 Test Time Simulated Lifetime (Years) 4.2 Co-60 Gamma Irradiation Radiation exposure of cables was performed using a Co-60 gamma source. Principal gamma ray energies for this source are 1.173 and 1.333MeV. Radiation dose rates were in the range of 0.5 – 2 KGy/hr for the cable radiation exposure. Initial target dose rates were set at 10, 20, 50, and 100KGy at the test lab and actual minimum and maximum radiation doses for each sample were monitored through the use of dosimeters placed on the inside and outside of the specimens. Tesnile tests on dogbone and tube samples were measured using an Instron model 4468 mechanical tester. A crosshead speed of 50mm/min was used for mechanical testing. 62.5micron multimode Germanium doped PCVD phosphorousfree optical fibers were used in the measurement test cables. Cable function was verified through optical attenuation measurements at 1310nm before and after irradiation on cabled fiber and against an equivalent reference fiber irradiated at an equivalent radiation dose and dose rate to ensure that no fiber to cable interaction was present. Cabled fiber attenuation measurements corresponded well with bare fiber attenuation measurements performed on identical fiber types with equivalent histories. For cables irradiated at 20KGy radiation induced attenuation was within 5% of the expected value for fibers with an equivalent radiation history. Target and actual sample radiation doses are listed in Table 3. The dosimetry data indicates that in all cases the minimum sample dose exceeded the target dose and, in most cases, was quite close to the target dose. The dose range selected was well over typical worst case total integrated radiation dose for 60 years of service life followed by a Design Basis Accident (DBE) and an additional year of post accident service required for the harshest applications where class 1E fiber optic cables are currently deployed.13,14 Table 3: Target and Actual Radiation Doses for Radiation Exposure Testing. Target Dose (KGy) Actual Min. Dose (KGy) Actual Max. Dose (KGy) 10KGy 15.1 18.6 20KGy 21.1 28 50KGy 51.9 60.8 100KGy 102.2 125.6 Figure 1: Tensile testing being performed on a cable jacket material sample. 4.4 Cable Material LOI Testing 4.3 Cable Material Mechanical Testing The mechanical testing of cable jacket materials was performed according to FOTP-89. In the case of tight buffers where tensile testing could not be completed due to the fact that practical samples for testing could not be removed from the optical fibers, static bend testing, mandrel wrap testing and tight buffer strip force testing was completed according to the procedure specified in ICEA 596. Mandrel diameters for mandrel wrap testing and coil formation were selected using 20 times the buffer diameter for tight buffers and loose tubes, the larger of 20 times diameter or 50mm for interconnect cables, or 150mm for general purpose, riser and plenum cables as explained in ICEA 596 Section 7.16 Low and High Temperature Bend Test. Limiting Oxygen Index (LOI) testing was performed in accordance to ASTM D2863 at a flow rate of 4.0cm/s. Oxygen content was monitored with an oxygen analyzer. After the oxygen analyzer calibration was confirmed before each experiment, it was used to verify the % oxygen for each burn. Normally the LOI test is performed on compression molded plaques of with a thickness 3.19mm. Testing of cable jacket samples was performed on strips of material cut from a cable jacket with a thickness of 1.4mm. The reduced thickness of these cable jacket samples relative to the 3.19mm plaques results in a systematic shift of both the control and experimental numbers to slightly lower values. Any change in measured LOI of cable materials after environmental conditioning could indicate a potential change in cable burn test performance for cables containing these materials. 5. Results and Discussion LOI test results on thermally aged jacket samples from cable lifetime simulation testing are summarized in Tables 4A-C. For all materials examined no significant impact of thermal aging was observed on measured LOI, even for aging simulation conditions that well exceeded cable lifetime requirements. No impact of aging temperature was observed between temperatures with low acceleration factors and temperatures with high acceleration factors. Table 4A: LOI Test Results for LSZH Jacketing Compound Thermal Lifetime Simulation. Aging Time (days) Aging Temp. (°C) Simulated Use Temp. (°C) - - - 35.6 320 80 50 28 35.6 320 100 50 213 35.6 320 110 50 537 36.0 Control Figure 2: LOI testing of cable jacket material sample. Simulated Lifetime (Years) LOI (%) 4.5 Cable Burn Testing Cable burn testing according to IEEE Standard 1202-2006 was completed before and after environmental exposure conditioning of 1f simplex cables at 100°C for 90 days and radiation exposure testing of cables to different radiation doses. The cables tested included two control cable burns, two cable burns of environmental exposure lifetime simulation cables, and cables subjected to 21.1KGy as well as 102.2KGy of gamma irradiation. The criteria for passing the IEEE 1202 burn test is that sample damage does not exceed 1.5 m (59 in) when measured from the center of the ribbon burner. Table 4B: LOI Test Results for CPE Jacketing Compound Thermal Lifetime Simulation. Aging Time (days) Control 320 Aging Temp. (°C) Simulated Use Temp. (°C) Simulated Lifetime (Years) - - - 34.6 110 50 537 34.3 LOI (%) Table 4C: LOI Test Results for PVDF Jacketing Compound Thermal Lifetime Simulation. Aging Time (days) Aging Temp. (°C) Simulated Use Temp. (°C) - - - 67.2 320 80 50 28 67.0 320 100 50 213 67.2 110 146 70 299 67.5 Control Figure 3. Schematic Diagram of IEEE 1202 Cable Burn Test. Simulated Lifetime (Years) LOI (%) LOI test results as well as other mechanical properties of irradiated 3.19mm thick plaques of LSZH compound are summarized in Table 5A. No impact of irradiation at radiation dose up to 100KGy was observed for LOI test results. Type IV tensile bars cut from the compression molded plaques showed a slight increase in both tensile strength and ultimate elongation as a function of increasing radiation dose up to 100KGy. A slight increase in modulus was observed for the samples which may indicate that a low level of radiation induced crosslinking may be occurring during cable irradiation. The increase in modulus was also evident though a slight increase in Shore hardness from about a 60D instantaneous value for the unaged specimens to about a 65D instantaneous value for the sample irradiated to a dose of 50KGy, as shown in Table 5B. Table 5A: LOI and Mechanical Test Results for LSZH Compound Radiation Exposure Testing. Radiation Dose (KGy) Tensile Strength Retention Elongation Retention LOI (%) Modulus (MPa) 0 (Control) 100% 100% 42.6 248 ± 20 15.1 105% 72% 42.1 270 ± 20 21.1 138% 78% 42.1 320 ± 20 51.9 119% 111% 41.9 339 ± 20 102.2 134% 143% 42.9 310 ± 20 Table 5A: Modulus and Shore Hardness for LSZH Compound Radiation Exposure Testing. Radiation Dose (KGy) Shore D Hardness Modulus (MPa) (Instantaneous) Tables 7A and 7B summarize mechanical test results on tight buffer samples from irradiated cables at various radiation doses. The tight buffer material did not exhibit any signs of degradation due to irradiation in the dose range studied. Table 7A: 18mm Dynamic Mandrel Wrap Test Results for Tight Buffered Fibers After Radiation Exposure Testing. Radiation Dose Observation: Result: Control nonIrradiated No splitting, cracking, or other damage. Pass 20 KGy No splitting, cracking, or other damage. Pass 100 KGy No splitting, cracking, or other damage. Pass Table 7B: Tight Buffer Strip Force Testing After Radiation Exposure Testing. Radiation Dose Requirement: Result: Control nonIrradiated >1.3N & <13.3N (>0.3lb & <3.0lb) 7.7 ± 0.5 N (Pass) >1.3N & <13.3N 60 ± 1 248 ± 20 20 KGy 21.1 63 ± 1 320 ± 20 100 KGy 51.9 65 ± 1 339 ± 20 0 (Control) (>0.3lb & <3.0lb) Tables 6A and 6B summarize mechanical test results on cable jacket samples from irradiated cables at various radiation doses. The cable jacket samples exhibited either no substantial impact of radiation on the mechanical properties of the LSZH compound or a slight increase in tensile strength. Table 6A: Mechanical Test Results of Type IV Tensile Bars Cut From 24f Breakout Cable Jacket. Radiation Dose (KGy) Elongation Retention % Tensile Strength (Psi) 1637 Tensile Strength Retention % 0 100% 15.1 140% 1784 109% 21.1 148% 1775 108% 102.2 132% 2024 124% 100% Elongation Retention % 0 Stress at Max Load (Psi) Tensile Strength Retention % 1628 21.1 99% 1649 101% 102.2 96% 1697 104% >1.3N & <13.3N 7.5 ± 0.5 N (Pass) (>0.3lb & <3.0lb) Table 8 summarizes the IEEE 1202 cable burn testing results on thermally aged cable samples. No significant impact of simulated thermal aging to end of life was observed on cable burn test performance. The cable burn test results are consistent with LOI test results on samples from aged cables in that no impact of thermal lifetime simulations well in excess of required service lifetimes was observed on these materials. The safety margin is the margin by which the test requirement was exceeded for burn length. Table 8: IEEE 1202 Cable Burn Test Summary on Heat Aged and Unaged Cables. Cable Identification : Unaged Cable 1 Unaged Cable 2 Aged Cable 1 Aged Cable 1 Time to Ignition (s) 0:07 0:06 0:06 0:07 Afterflame (min:s) 1:01 0:23 0 0 Cable Damage: Melt: 91.4cm Melt: 88.9cm Melt: 81.3cm Melt: 91.4cm Char: 63.5cm Char: 60.1cm Char: 55.9cm Char: 58.4cm Ash: 17.8cm Ash: 20.3cm Ash: 17.8cm Ash: 27.9cm Pass Pass Pass Pass Table 6B: Mechanical Test Results of Tubular Jacket Samples From LSZH Simplex Cable Jacket. Radiation Dose (KGy) 8.2 ± 0.5 N (Pass) Pass/Fail Safety Margin 39% 41% 46% 39% Peak Smoke (m2/s) 0.0015 0.0025 0.0031 0.0014 Total Smoke (m2) 0.577 0.680 1.522 0.692 Table 9 summarizes the cable burn testing results on cables irradiated to dose levels of up to 100KGy. No impact of cable irradiation was seen on burn performance within this range of radiation doses. The cable burn test results are consistent with LOI test results in that no impact of radiation was seen on the flammability of these materials within the dose range studied. Table 9: IEEE 1202 Cable Burn Test Summary on Irradiated Cables Cable Identification : Unaged Cable 1 Unaged Cable 2 20KGy Exposure 100KGy Exposure Time to Ignition (s) 0:11 0:12 0:14 0:07 Afterflame (min:s) 4:45 3:21 2:45 0 Cable Damage: Melt: 106.7cm Melt: 91.4cm Melt: 91.4cm Melt: 91.4cm Char: 58.4cm Char: 45.7cm Char: 50.8 Char: 55.9cm Ash: 15.2cm Ash: 12.7cm Ash: 10.2cm Ash: 20.3cm Pass Pass Pass Pass Safety Margin 29% 39% 39% 39% Peak Smoke (m2/s) 0.0014 0.0016 0.0006 0.0009 Total Smoke (m2) 0.949 1.396 0.614 0.657 Pass/Fail technologies were observed to be insensitive to thermal aging and radiation and each has have an application depending on flame retardancy and use environment requirements for the cable. Functional testing of cables for attenuation also verified that with properly selected fibers, cables would maintain their ability to function without radiation induced attenuation becoming too high to compromise network integrity. No cable material changes were observed which could induce unexpected changes in cabled fiber attenuation performance. Finally, it should be noted that lifetime prediction based on Arrhenius lifetime extrapolation combined with cable environmental exposure testing is only one part of a comprehensive cable and system reliability approach. The reliability of the system is dependent on each fiber, cable, and component. Optical fibers, cable designs, and materials must be properly selected to meet the reliability requirements for normal service conditions as well as extreme situations that may be encountered during an accident or natural disaster even at the end of the rated lifetime. 7. Acknowledgments I would like to acknowledge Boyce Lookadoo for his help in materials testing and monitoring samples during testing. I would also like to thank Jan Pirrong for editorial input. 8. References 1 International Atomic Energy Agency Nuclear Technology Review; International Atomic Energy Agency, Vienna (2009). 2 6. Conclusions Arrhenius activation energies determined in an earlier study were used to determine thermal aging conditions required to simulate service lifetimes of fiber optic cables for nuclear cable applications. After a thermally simulated lifetime and radiation exposure, mechanical and burn testing was conducted on cables and cable materials. Mechanical properties of the materials selected for the cable designs studied were found to be insensitive to thermal aging equivalent to a lifetime under service conditions. Additionally both LOI testing on materials and cable burn tests were found to be unaffected by thermal aging equivalent to a lifetime under service conditions. In addition to thermal lifetime service simulations, cables and materials designed for use in nuclear power applications must also be tested for sensitivity to radiation. Radiation exposure testing on cables and cable materials was conducted to the highest extrapolated dose levels for outside of containment in nuclear power plant environments. Mechanical properties of the materials tested showed almost no impact of this high level of radiation exposure other than a slight increase in modulus which would be attributed to an expected low level of radiation induced crosslinking. LOI testing on the cable materials as well as IEEE 1202 burn tests on cables also showed no degradation even after high radiation exposure levels. In this study three materials systems were investigated which contained a common mineral based flame retardant system as well as an inherently flame retardant polymer. The flame retardant S.K. Aggarwal, et. al., Assessment and management of ageing of major nuclear power plant components important to safety: Incontainment instrumentation and control cables (Volumes 1 &2), IAEA-TECDOC-1188; International Atomic Energy Agency, Vienna (2000). 3 P. Holzmann and G. Slitter, Eds., Nuclear Power Plant Equipment Qualification Reference Manual, EPRI, TR 100516 (1992). 4 IEE std. 323-2003: IEEE Standard for Qualifying Class 1E Equipment for Nuclear Power Generating Stations. 5 IEC 60216 : Guide for the Determination of Thermal Endurance Properties of Electrical Insulating Materials. Ageing Procedures and Evaluation of Test Results. 6 IEEE P1682 : Standard for Qualifying Fiber Optic Cables, Connections, and Optical Fiber Splices for Use in Safety Systems of Nuclear Power Generating Stations. 7 Brian G. Risch, Shawn Fox, and Richard A. van Delden, “Lifetime Prediction of Fiber Optic Cable Materials for Nuclear Power Applications: Evaluation of Failure Mechanism, End of Life Criteria, and Test Methodology”, 59ht International Wire and Cable Symposium Proceedings, (2010) 183-191. 8 T. Wijnands, L.K. De Jonge, J. Kuhnhenn, S.K. Hoeffgen, U. Weinand, “Optical Absorption in Commercial Single Mode Optical Fibers in a High Energy Physics Radiation Field”, IEEE Transactions on Nuclear Science, (2008) 55, 2216 – 2222. 9 John Matson, “Fast Facts about Radiation from the Fukushima Daiichi Nuclear Reactors”, Scientific American, March 16, 2011. 10 "Fact Sheet on Biological Effects of Radiation", Publication date December 2004. The U.S. Nuclear Regulatory Commission (NRC). 11 G. Medvedev , Chernobyl Notebook, JPRS-UEA-034-89, Published in Novy Mir. (June 1989). 12 A.K. Guskova, et. al., Acute radiation effects in victims of the Chernobyl accident, UNSCEAR 1988 Report Appendix to Annex G. 13 United States Nuclear Regulatory Commission: Issued Design Certification - Advanced Passive 1000 (AP1000), Rev. 15; AP1000 Design Control Document,Chapter 3: Design of Structures, Components, Equipment and Systems. 14 United States Nuclear Regulatory Commission: Issued Design Certification - Issued Design Certification - Advanced BoilingWater Reactor (ABWR); ABWR Design Control Document, Tier 2, Chapter 3: Design of Structures, Components, Equipment and Systems. 15 H. Lydtin, “A Technique Suitable for Large-Scale Fabrication of Optical Fibers”, Journal of Lightwave Technology, LT-4 (1986) 8, 1034-1038. 16 S. Girard, J. Keurinck , Y. Ouerdane, J-P. Meunier, A.Boukenter, “Gamma-rays and pulsed X-ray radiation responses of germanosilicate single-mode optical fibers : influence of cladding codopants”, Journal of Lightwave Technology (2004) , 22 (8), 1915-1922. Erin Bowman Prysmian Group Fiber Optic Cable Development 2512 Penny Rd. P.O. Box 39 Claremont, NC 28610 Erin Bowman is the Senior Materials Engineer at the fiber-optic cable plant in Claremont, NC. She holds a B.S. in Chemistry and a B.S. in Applied Mathematics from North Carolina State University. She has more than 10 years experience in the areas of analytical chemistry and polymer characterization in the fiberoptic, aerospace, and specialty textiles industries. Before working for the Prysmian Group Erin worked on Lockheed Martin Space Shuttle Materials for NASA. Ray Lovie Prysmian Group Fiber Optic Cable Development 2512 Penny Rd. P.O. Box 39 Claremont, NC 28610 17 H. Henschel, “Radiation hardness of present optical fibers”, SPIE Vol. 2425 Optical Fiber Sensing and Systems in Nuclear Environments, 21-31 (1994). 18 B.T. Huffman, C. Issever, N.C. Ryder1 and A.R. Weidberg, “The radiation hardness of specific multi-mode and single-mode optical fibres at -25◦C beyond a full SLHC dose to a dose of 500 kGy(Si)”, Journal of Instrumentation (2010) 5, C11023. Brian G. Risch Prysmian Group Fiber Optic Cable Development 2512 Penny Rd. P.O. Box 39 Claremont, NC 28610 Brian G. Risch is the Materials Technology Manager at the Prysmian fiber optic cable plant in Claremont, NC. He holds a B.A. degree in physics from Carleton College and a Ph.D. in Materials Science and Engineering from Virginia Polytechnic Institute and State University. Brian has studied structure property relationships in polymeric materials and materials reliability for the last 20 years. Prior to working for Draka, Brian worked for Alcatel for 7 years at Alcatel’s Optical Fiber Cable R&D center specializing in cable materials and fundamental material reliability and then for 6 years at Hewlett Packard as a failure analysis engineer. Ray Lovie is Product Development Manager at the Prysmian fiber optic cable plant located in Claremont, N. Carolina, USA. He holds a B.Sc (Mechanical Engineering) degree from the University of Manitoba and has over 20 years’ experience in the design, development, and manufacture of Outside Plant and Premises optical fiber cables.