Last updated: April 2004 LIQUID SCINTILLATION COUNTING OF ENVIRONMENTAL RADIONUCLIDES Literature of measurements carried out with 1220 Quantulus and 1400 LS Counters H-3 1. Schönhofer, F. and Henrich, E., Trace analysis of radionuclides by liquid scintillation counting, Int. Conf. on Analytical Chemistry in Nuclear Technology, Karlsruhe, June 1985 (Report UBA-STS-8502) 2. Schönhofer F. and Henrich, E., Recent progress and application of low level liquid scintillation counting. J. Radioanal. Nucl. Chem., 115 (2), 317 (1987) 3. Schönhofer F. and Weisz, J., Measurement by ultra low level liquid scintillation counting following the Chernobyl accident. J. Radioanal. Nucl. Chem., 115 (1), 125 (1987) 4. Levina, L.A., Vlumbekov, R.F., Fedotov, A.A. and Heruvimov, A.N., Application of LKB 1220 Quantulus for detection of tritium content in hydrosphere. Report Series IAE-4987/2, Institute of Nuclear Energy "Kurchatov Institute", Moscow 1989, 9 pp (in Russian) 5. Wallner, Gabriele, Determination of Environmental Tritium in Tree Rings. In Liquid Scintillation Spectrometry 1992, Proc. of the Int. Conf. on Advances in LSC, LSC 92, Vienna, Austria, Sept 14-18, 1992. Eds. J.E. Noakes, F. Schönhofer and H.A. Polach. Radiocarbon, Tucson 1993, pp. 349-353. 6. Kim, C.K., Cho, Y.W., Han, M.-J. and Pak, C.-K., Tritium Distribution in some Environmental Samples - Rices, Chinese Cabbages and Pine Needles in Korea. J. Korean Assoc. for Radiation Protection, 17 (2), 25-35 (1992) (In Korean with English summary). 7. Morgenstern, U., Hebert, D. and Stolz, W., Electrolytic Tritium Enrichment of Natural Water Samples for Tritium Analysis, in Liquid Scintillation Spectrometry 1992, Proc. of the Int. Conf. on Advances in LSC, LSC92, Vienna, Austria, Sept 14-18, 1992. Eds. J.E. Noakes, F. Schönhofer and H.A. Polach. Radiocarbon, Tucson 1993, pp. 355-360. 8. Schönhofer, F. and Pock, K., Diffusion und Inkorporation von Tritium aus Uhren. Ernährung/Nutrition, 18, nr. 2, 78, 1994 (in German). 9. Schönhofer, F. and Pock, K., Incorporation of Tritium from Wrist Watches. Fifth International Conference on Low Level Measurements of Actinides and Long-Lived Radionuclides in Biological and Environmental Samples, Aomori, Japan, July 10-15, 1994, in J. Radioanal. and Nucl. Chem.: Articles, 197(1), 195-202 (1995). 10.Taylor, C.B., The Relationship between Electrolytic Deuterium and Tritium Separation Factors, and Attainment of Improved Accuracy in Radiometric Low-level Tritium Measurement. Appl. Radiat. Isot. 45(6), 683-692 (1994). 11.Schönhofer, F. and Pock, K., Determination of H-3 in urine by LSC. In ref. Liquid Scintillation Spectrometry 1994, ed. G.T. Cook, D.D. Harkness, A.B. MacKenzie, B.F. Miller and E.M. Scott, Radiocarbon 1996. 12.Povinec, P., Baxter, M.S., Gastaud, J., Wee Kwong, L. Lliong. and Oregioni, B., Low-Level Liquid Scintillation Spectrometry of Soft Beta Emitters. In Liquid Scintillation Spectrometry 1994, ed. G.T. Cook, D.D. Harkness, A.B. MacKenzie, B.F. Miller and E.M. Scott, Radiocarbon 1996, p. 149-155. 13.Filip, J. and Svetlik, I., Tritium and cesium measurements in the Vltava River, South Bohemia. In Liquid Scintillation Spectrometry 1994, ed. G.T. Cook, D.D. Harkness, A.B. MacKenzie, B.F. Miller and E.M. Scott, Radiocarbon 1996. 14.Buchtela, K., Pock, K., Steger, F. and Schönhofer, F., Simplified radioactivity control of waste water for compliance with regulations. In Liquid Scintillation Spectrometry 1994, ed. G.T. Cook, D.D. Harkness, A.B. MacKenzie, B.F. Miller and E.M. Scott, Radiocarbon 1996. 15.Krause, W.J. and Mundschenk, H., Vergleichanalyse Tritium in Wasser 1994. Bundesanstalt für Gewässerkunde Koblenz, August 1995. 79 pp (in German) (Intercomparison of H-3 in water). 16.Belloni, Ingrao, G., Ianni, A. Lucci, F., Sandri, S., Santaroni and Vasselli, R., Confronto di tre sistemi di conteggio a scintillazzione liquida per la determinazione del trizio in acqua, aria, urina e smear test. 5 Convegno Sulle Metodoligie Radiometiche e Radiochimiche in Radioprotezione, Urbino 20-22 Ciugno 1995 (in Italian). 17.Wood, M.J., Outdoor Field Evaluation of Passive Tritiated Water Vapor Samples at Canadian Power Reaction Sites. Health Physics, 70(2), 258-267 (1996). 18.Buzinny M.G., Los' I.P., Skudnova L.V. Tritium in precipitations in Ukraine of 1990-1995. In "Methods of liquid scintillation counting in radioecology", 1995. V.1. Research center for radiation medicine AMS Ukraine.- Kiev, 1996. - PP.39-43. - In Russian. 19.Schönhofer, F. and Kralik, C., Optimization of Liquid Scintillation Measurements of Environmental Tritium. In Int. Conf. on Methods and Applications of Radioanalytical Chemistry MARC-IV, Kona, Hawaii, April 6-11, 1997. 20.Kopka, B., Schikowski, J. and Porstendörfer, J., Low-Level Liquid Scintillation Counting for Quantification of Annual H-3 and C-14 Concentrations in Tree Disks. In Methods and Applications of Low-Level Radioactivity Measurements, Proc. of a Workshop at Research Center Rossendorf Inc. (FZR), Dresden, Nov 7-8, 1996. Chaired by H. Nitsche and S. Niese, Ed. J. Fietz. FZR-170, March 1997 pp. 102-105. 21.Nitzsche, O. and Hebert, D., Practical Aspects of Tritium Measurement in Ground and Surface Waters. In Methods and Applications of Low-Level Radioactivity Measurements, Proc. of a Workshop at Research Center Rossendorf Inc. (FZR), Dresden, Nov 7-8, 1996. Chaired by H. Nitsche and S. Niese, Ed. J. Fietz. FZR-170, March 1997, pp. 106-109. 22.Kim, C.K., Kim, C.-S., Yun, J.-Y. and Kim, K.-H., Distribution of H-3, Cs-137 and Pu-239,240 in the surface seawater around Korea. J. Radioanal. Nucl. Chem. 218 (1), 33-40 (1997). 23.Kim, C.K., Han, M.J. and Kim, K.H., Tritium Concentrations of Tritiated Water Vapor and Tritiated Hydrogen in the Atmosphere in Taejon. J. Korean Assoc. for Radiation Protection, 22 (2), 97-101 (1997). 24.Neary, M.P., Spaulding, J.D., Noakes, J.E. and Culp, R.A., Tritium Analysis of Burn-Derived Water from Natural and Petroleum-Derived Products. J. Agricultural and Food Chemistry. 45(6), 21532157 (1997). 25.Neary, M.P, Tritium Enrichment - To Enrich or Not to Enrich. Radioactivity & Radiochemistry, 8(4), 23-35 (1997). 2 26.Kim, C.-K., Rho, B.-H. and Lee, K.J., Environmental Tritium in the Areas Adjacent to Wolsong Nuclear Power Plant. J. Environ. Radioactivity. 41 (2), 217-231 (1998). 27.Yang, I.C., 1992, Flow and Transport through Unsaturated Rock - Data from Two Test Holes, Yucca Mountain, Nevada: Proceedings of the 3rd International Conference on High-Level Radioactive Waste Management, Las Vegas, Nevada, April 12-16, 1992, p. 732-737. 28.Yang, I.C., Rattray, G.W., and Yu, Pei, 1996, Interpretation of Chemical and Isotopic Data from Boreholes in the Unsaturated-Zone at Yucca Mountain, Nevada: U.S. Geological Survey, Water Resources Investigations Report 96-4058, 58 p. 29.Yang, I.C., Yu, P., Rattray G. W., Ferarese, J. S., and Ryan, J. N., 1998, Hydrochemical investigations in characterizing the unsaturated-zone at Yucca Mountain, Nevada: U.S. Geological Survey WaterResources Investigation Report 98-4132, 57p. 30.Yang, I.C., Rattray, G.W., and Scofield, K.M., 1998, Carbon and hydrogen isotopic compositions for pore water extracted from cores at, Yucca Mountain, Nevada: Proceedings of the 8th International Conference on High-Level Radioactive Waste Management, Las Vegas, Nevada, May 11-14, 1998, p. 27-32. 31.Yang, I.C., 1998, Gaseous- and aqueous- phases chemistry: in Hydrogeology of the unsaturated zone, north ramp area of the Exploratory Studies Facility, Yucca Mountain, Nevada: U.S. Geological Survey Water-Resources Investigation Report 98-4050, edited by J.P. Rousseau, E.M. Kwicklis, and D.C. Gillies, p.115-120 and p.161-169. 32.Schönhofer, F. and Kralik, C., Optimization of Liquid Scintillation Measurements of Environmental Tritium. Radioactivity & Radiochemistry, 10(4), 14-17 (1999). 33.Schäfer, I., Hebert, D. and Zeiske, U., On low-level Tritium measurements with LSC Quantulus. Conference on Low Level Radioactivity Measurement Techniques, Mol, Belgium, 18-22 Oct 1999. 34.Kim, Chang-Kyu, Han Man-Jung, Dose assessment and behavior of tritium in environmental samples around Wolsong nuclear power plant. Appl. Radiat. Isot. 50, 783-791 (1999). 35.Negojur, T.Gh., Kuznetsov, V.L., Varlam, C., 2000. Tritium Determination in the Eastern Antarctic Waters. Antarctic and Arctic Research, The Publishing House of the Romanian Academy. Vol. I, pp. 77-85. The paper also was presented at The Scientific Communications Symposium „100 years of Geography”at the Bucharest University, November, 1999. 36.M.P. Neary and J.E. Noakes, Tritium in Natural Products. In LSC 2001, Advances in Liquid Scintillation Spectrometry, ed. S. Möbius, J.E. Noakes and F. Schönhofer, Radiocarbon 2002, 173179. 37.C. Varlam, I. Stefanescu, D. Steflea and A. Feru. Natural Sparkling Water Sources Analysis Based on Tritium Measurements. In LSC 2001, Advances in Liquid Scintillation Spectrometry, ed. S. Möbius, J.E. Noakes and F. Schönhofer, Radiocarbon 2002, 189-195. 38.U.D. Hoeppener-Kramar, C. Rittmayer and S. Kuhnmuench, Determination of Tritium in Various Matrices by Liquid Scintillation Counting. In LSC 2001, Advances in Liquid Scintillation Spectrometry, ed. S. Möbius, J.E. Noakes and F. Schönhofer, Radiocarbon 2002, 197-201. 39.D.O. Eriksen, V. Martini and S.K. Hartvik, Assessment of Tritium Detection Limits at Institute for Energy Technology (IFE) with Quantulus Low-Level Liquid Scintillation Spectrometer. In LSC 2001, Advances in Liquid Scintillation Spectrometry, ed. S. Möbius, J.E. Noakes and F. Schönhofer, Radiocarbon 2002, 203-211. 3 40.M.P. Neary, Low-Level Tritium Analysis Employing Micro-Tritium Enrichment. In LSC 2001, Advances in Liquid Scintillation Spectrometry, ed. S. Möbius, J.E. Noakes and F. Schönhofer, Radiocarbon 2002, 213-219. C-14 1. Otlet, R.L. and Polach, H.A., Improvements in the precision of radiocarbon dating through the recent developments in liquid scintillation counters. In Proceedings of the 2nd Int. Symp. on Radiocarbon Dating and Archaelogy, Groningen, The Netherlands, Sept. 1987, PACT 29, 1990, editors W.G. Mook and H.T. Waterbolk, pp. 225 - 238. 2. Polach, H.A., Perspectives in radiocarbon dating by radiometry. In Accelerator Mass Spectrometry. Eds. H.E. Gove, A.E. Litherland and D. Elmore, Proc. 4th Int. Symp. on AMS, Niagara-on-the-Lake, Ontario, Canada. Nucl. Instr. Meth. Phys. Res. B29, 415-423 (1987). 3. Polach, H., Evaluation and Status of Liquid Scintillation Counting for Radiocarbon Dating. Radiocarbon 29, 1-11, (1987). 4. Polach, H. and Kaihola, L., Determination of Radon by Liquid Scintillation ß Particle Spectrometry: Towards the Resolution of a C-14 Dating Problem. Radiocarbon, 30(1), 19-24 (1988). 5. Henry Polach, Lauri Kaihola, Steve Robertson and Herbert Haas, Small Sample C-14 Dating by Liquid Scintillation Spectrometry, Radiocarbon, 30 (2), 153-155, 1988. 6. Polach, H., Liquid Scintillation C-14 Spectrometry: Errors and Assurances. Radiocarbon 31 (3), 327331 (1989). 7. Schönhofer F.: Determination of C-14 in alcoholic beverages, Radiocarbon 31 (3), 777-784 (1989) 8. Hood, D. Hatfield, R., Patrick, C., Stipp, J., Tamers, M., Leidl, R., Lyons, B., Polach, H., Robertson, S. and Zhou, Weijian, Radon elimination during benzene preparation for radiocarbon dating by liquid scintillation spectrometry. Radiocarbon 31 (3), 254-259 (1989). 9. Kalin, R.M. and Long, A., Radiocarbon Dating with the Quantulus in an Underground Counting Laboratory: Performance and Background Sources. Radiocarbon 31 (3), 359-367 (1989). 10. Harkness, D.D. and Harrison, A.F., The influence of afforestation on upland and soils: The use of 'bomb C-14' enrichment as a quantitative tracer for changes in organic status. Radiocarbon 31 (3), 637-643 (1989). 11. Head, M.J., Zhou, W. and Zhou, M., Evaluation of C-14 ages of organic fractions of paleosols from loess-paleosol sequences near Xian, China. Radiocarbon 31 (3), 680-696 (1989). 12.Marcenko, Elena, Srdoc, D. Golubic, S. Pezdic, J. and Head, J., Carbon uptake in aquatic plants deduced from their natural C-13 and C-14 content. Radiocarbon 31 (3), 785-794 (1989). 13. Wassenaar, L., Aravena, R. and Fritz, P., The geochemistry and evalution of natural organic solutes in groundwater, Radiocarbon 31 (3), 865-876 (1989). 14. Aravena, R., Drimmie, R.R., Qureshi, R.M., McNeely, R. and Fabris, S., New Possibilities for C-14 Measurements by Liquid Scintillation Counting, Radiocarbon 31 (3), 387-392 (1989). 15. Qureshi, R.R., Aravena, R., Fritz, P. and Drimmie, R.R., The CO2 absorption method as an 4 alternative to benzene synthesis method for C14 dating. Appl. Geochem. 4, 625-633 (1989). 16.Jao Wen-qiang and Xiang Hong-fa, Application of Quantulus-1220 LSC for Geological Dating. Seismology and Geology, 11(1), 99-100 (1989) (in Chinese). 17.Hogg, A., Polach, H., Robertson, S. and Noakes, J., Application of high purity synthetic quartz vials to liquid scintillation low-level C-14 counting of benzene, in Liquid Scintillation Counting and Organic Scintillators, Proc. of the Int. Conf. on New Trends in Liquid Scintillation Counting and Organic Scintillators, Gatlinburg, Tennessee, Oct 2-5 1989. Eds. Ross, H., Noakes, J.E. and Spaulding, J.D., Lewis Publishers, 1991, pp. 123-131. 18. Haas, H. and Trigg, Veronica, Low level scintillation counting with a LKB Quantulus counter: Establishing optimal parameter settings, in Liquid Scintillation Counting and Organic Scintillators, Proc. of the Int. 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Ross, H., Noakes, J.E. and Spaulding, J.D., Lewis Publishers, 1991, pp. 471-479. 21.Kalin, R.M., Wright, L., Devine, J.M. and Long, A., Statistical Considerations of Very Low Background Count Rates in Liquid Scintillation Spectrometry with Applications to Radiocarbon Dating, in ref. Liquid Scintillation Counting and Organic Scintillators, Proc. of the Int. Conf. on New Trends in Liquid Scintillation Counting and Organic Scintillators, Gatlinburg, Tennessee, Oct 2-5 1989. Eds. Ross, H., Noakes, J.E. and Spaulding, J.D., Lewis Publishers, 1991, pp. 489-494. 22.Kaihola, L., Kojola, H. and Heinonen, A., A Minivial for Small Sample C-14 Dating. Radiocarbon 34(3), 402-405 (1992). 23. Hogg, A., Assessment of 0.3 ml Minivials for Radiocarbon Dating by Liquid Scintillation Counting of Benzene. Radiocarbon 34(3), 389-393 (1992). 24.Long, A. and Kalin, R.M., Radiocarbon Dating in the 50000- to 60000-Year Range Without Isotopic Enrichment. Radiocarbon 34(3), 351-359 (1992). 25.Long, A. and Kalin, R.M., Radiocarbon Dating in the 50000 to 60000 Year Range Without Isotopic Enrichment, in Rare Nuclear Processes, Proc. 14th Europhysics Conf. on Nuclear Physics, Bratislava, 22-26 Oct. 1990, ed. P. Povinec. World Scientific, Singapore 1992, p. 256-263. 26. Leavitt, S.W. and Kalin, R.M., A New Tree-Ring Width, deltaC13 and C-14 Investigation of the Two Creeks Site. Radiocarbon 34(3), 792-797 (1992). 27.Schönhofer F., C-14 in Austrian Wine and Vinegar. Radiocarbon 34(3), 768-771 (1992). 29. Hogg, A. and Noakes, J.E., Evaluation of High-Purity Synthetic Silica Vials in Active and Passive Vial Holders for Liquid Scintillation Counting of Benzene. Radiocarbon 34(3), 394-401 (1992). 30. Mas-Pla, J., Trilla, J. and Valls, M.L., Radiocarbon Dating of Travertines Precipitated from Freshwater. Radiocarbon 34(3), 677-685 (1992). 5 31. Barbetti, M., Bird, T., Dolezal, G., Taylor, G., Francey, R., Cook, E. and Peterson, M., Radiocarbon Variations from Tasmanian Conifers: First Results from Late Pleistocene and Holocene Logs. Radiocarbon 34(3), 806-817 (1992). 32. Zhou, W., An, Z., Lin, B., Xiao, J., Zhang, J., Xie, J. and Zhou, M., Chronology of the Baxie Loess Profile and the History of Monsoon Climates in China between 17000 and 6000 Years BP. Radiocarbon 34(3), 818-825 (1992). 33. McCormac, F.G., Kalin, R.M. and Long A., Radiocarbon Dating beyond 50,000 Years by Liquid Scintillation Counting. In Liquid Scintillation Spectrometry 1992, Proc. of the Int. Conf. on Advances in LSC, LSC 92, Vienna, Austria, Sept 14-18, 1992. Eds. J.E. Noakes, F. Schönhofer and H.A. Polach. Radiocarbon, Tucson 1993, pp. 125-133. 34. Hogg, A.G., Performance and Design of 0.3-ml to 10-ml Synthetic Silica Liquid Scintillation Vials for Low-Level C-14 Determination. In ref. Liquid Scintillation Spectrometry 1992, Proc. of the Int. Conf. on Advances in LSC, LSC 92, Vienna, Austria, Sept 14-18, 1992. Eds. J.E. Noakes, F. Schönhofer and H.A. Polach. Radiocarbon, Tucson 1993, pp. 135-142. 35.McCormac, F.G., Liquid Scintillation Counter Characterization, Optimization and Benzene Purity. Radiocarbon 34(1), 37-45 (1992). 36. Stuiver, M. and Pearson, G.W., High-Precision Bidecadal Calibration of the Radiocarbon Time Scale, AD 1950-500 BC and 2500 - 500 BC. Radiocarbon 35(1), 1-23 (1993). 37.Pearson, G.W. and Stuiver, M., High-Precision Bidecadal Calibration of the Radiocarbon Time Scale, AD 500 - 2500 BC. Radiocarbon 35(1), 25-33 (1993). 38. Pearson, G.W., Becker, B. and Qua, Florence, High-Precision C-14 Measurement of German and Irish Oaks to Show the Natural C-14 Variations from 7890 to 5000 BC. Radiocarbon 35(1), 93 - 104 (1993). 39. Pearson, G.W. and Qua, Florence, High-Precision C-14 Measurement of Irish Oaks to Show the Natural C-14 Variations from 1840 - 5000 BC: A Correction. Radiocarbon 35(1), 105 - 123 (1993). 40. Witkin, D., Kalin, R.M., Long, A., Rigali, M.J. and Nagy, B. Production of Impurities in Benzene Synthesis for Liquid Scintillation Counting and its Effect on High-Precision Radiocarbon Measurements. In ref. Liquid Scintillation Spectrometry 1992, Proc. of the Int. Conf. on Advances in LSC, LSC 92, Vienna, Austria, Sept 14-18, 1992. Eds. J.E. Noakes, F. Schönhofer and H.A. Polach. Radiocarbon, Tucson 1993, pp. 115-124. 41.Nair, A.R. and Sinha, U.K, Joseph, T.B. and Rao, S.M., Radiocarbon Dating up to 37,000 Years Using CO2 Absorption Technique. Nucl. Geophys. 9(3), 263-268 (1995). 42.Buzinny, M.G., Zelensky, A.V., Kovaliukh, N.N., Skripkin, V.V. and Sanin, E.V., Retrospective reconstruction of C-14 level in atmosphere due to the Chernobyl accident. Conference on Actual questions of retrospective, live and predictive radiation dosimetry of the Chernobyl accident. October 27-29, 1992, Kiev. Ukraine Scientific Center of Radiation Medicine Enterprise "ROSA" Minchernobyl, Ukraine, Kiev 1993, p. 118-124 (in Russian) 43.Buzinny, M.G., Zelensky, A.V., Kovaliukh, N.N. and Skripkin, V.V., The Possibility of Correlation of C-14 Levels in Vegetation with I-131 in Thyroid Function after Chernobyl Accident, in proceedings of the conference 'Chernobyl and Health', 20-22 April, 1993, Kiev (in Russian). 44.Leaney, E.W., Dighton, J.C. and Herczeg, A.L., Development in the Direct Absorption of Carbon Dioxide Method for Radiocarbon Analysis. 1st ANZ Meeting on Quaternary Dating, 8th-10th 6 February, 1993, Australian National University, Canberra, A.C.T. 45.Robertson S. and Grün, R., Towards Portable Radiocarbon Dating, 1st ANZ Meeting on Quaternary Dating, 8th-10th February, 1993, Australian National University, Canberra, A.C.T. 46.Lambropoulos, N. and Robertson, S., Radiocarbon Dating by Direct CO2 Absorption - A Practical Design., in Archaeometry, Current Australasian Research, eds. B.L. Frankhauser and J. R. Bird, The Australian National University, Canberra, 1993, p. 98-101. 47. Zhou, Weijian, Head, J. and Kaihola, L., Small Sample Dating Facility. Radiocarbon 36(1), 47-49 (1994). 48.Wilson, J.E., McCormac, F.G. and Hogg, A.G Small Sample High-Precision C-14 Dating: Characterization of Vials and Counter Optimization. In ref. L3, p. 59-65. 49. Wilson, J. and McCormac, F.G., High precision dating of small samples. In 15th Radiocarbon Conference, Glasgow, Scotland, Aug 15-19, 1994. Radiocarbon, 37 (2) 1995, abstract only. 50.Kitagawa, H., Liquid scintillation C-14 dating by the method of methanol synthesis. In Liquid Scintillation Spectrometry 1994, ed. G.T. Cook, D.D. Harkness, A.B. MacKenzie, B.F. Miller and E.M. Scott, Radiocarbon 1996. 51.Calf, G. and Barbetti, M., Spectral shifts observed when using teflon vials in a Wallac 1220 Quantulus liquid scintillation spectrometer. In Liquid Scintillation Spectrometry 1994, ed. G.T. Cook, D.D. Harkness, A.B. 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