SAFETY DATA SHEET
Dissolvine H-Fe-4.5
Version 1
Revision Date 04/24/2015
Print Date 05/06/2015
US / Z8
1. PRODUCT AND COMPANY IDENTIFICATION
Product name
: Dissolvine H-Fe-4.5
Product Use Description
: Chelating agent
Plant nutrient
Chemical characterization
: Hydroxyethylethylenediaminetriacetic acid, iron sodium
complex, 30-40% aqueous solution
Company
: Akzo Nobel Functional Chemicals LLC
525 West Van Buren
Chicago IL 60607-3823
USA
: +118008287929
: +113125447188
: RegulatoryAffairs@akzonobel.com
: AkzoNobel: +31 57 06 79 211 CHEMTREC - USA: 1-800-4249300 CANUTEC - CANADA: 1-613-996-6666
Telephone
Fax
E-mail address
Emergency telephone
2. HAZARDS IDENTIFICATION
Emergency Overview
Appearance
Color
Odor
Clear liquid
red brown
Slightly ammonia like
GHS Classification
Oxidizing liquids, Category 3
Eye irritation, Category 2A
GHS Label element
Hazard pictograms
:
Signal Word
: Warning
Hazard Statements
: H272 May intensify fire; oxidizer.
H319 Causes serious eye irritation.
Precautionary Statements
: Prevention:
P210 Keep away from heat.
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P220 Keep/Store away from clothing/ combustible materials.
P221 Take any precaution to avoid mixing with combustibles.
P264 Wash skin thoroughly after handling.
P280 Wear protective gloves/ eye protection/ face protection.
Response:
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water
for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing.
P337 + P313 If eye irritation persists: Get medical advice/
attention.
P370 + P378 In case of fire: Use water spray to extinguish.
Disposal:
P501 Dispose of contents/container in accordance with local
regulation.
The following percentage of the mixture consists of ingredient(s) with unknown acute toxicity: 27 %
Potential Health Effects
Inhalation
: Inhalation of aerosols may cause irritation to mucous
membranes.
Thermal decomposition can lead to release of irritating gases
and vapors.
Skin
: May cause skin irritation.
Eyes
: Causes serious eye irritation.
Ingestion
: May cause irritation of the mucous membranes.
Aggravated Medical
Condition
: None known.
Carcinogenicity:
IARC
OSHA
NTP
: Group 2A: Probably carcinogenic to humans
Sodium nitrate
7631-99-4
Group 2B: Possibly carcinogenic to humans
Nitrilotriacetic acid
139-13-9
: No ingredient of this product present at levels greater than or
equal to 0.1% is identified as a carcinogen or potential
carcinogen by OSHA.
: Reasonably anticipated to be a human carcinogen
Nitrilotriacetic acid
139-13-9
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3. COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous ingredients
Chemical Name
Sodium nitrate
CAS-No.
7631-99-4
Classification
Ox. Sol. 3; H272
Concentration [%]
20 - 30
Eye Irrit. 2A; H319
Nitrilotriacetic acid
139-13-9
Eye Irrit. 2A; H319
0.1 - 1
Carc. 2; H351
For the full text of the H-Statements mentioned in this Section, see Section 16.
4. FIRST AID MEASURES
General advice
: Move out of dangerous area.
Consult a physician.
Show this material safety data sheet to the doctor in
attendance.
Inhalation
: If breathed in, move person into fresh air.
Consult a physician after significant exposure.
Skin contact
: Take off contaminated clothing and shoes immediately.
Rinse immediately with plenty of water.
Eye contact
: Rinse with plenty of water.
Remove contact lenses.
Protect unharmed eye.
Keep eye wide open while rinsing.
Obtain medical attention.
Ingestion
: Clean mouth with water and drink afterwards plenty of water.
Never give anything by mouth to an unconscious person.
Obtain medical attention.
5. FIRE-FIGHTING MEASURES
Suitable extinguishing media
: Alcohol-resistant foam
Carbon dioxide (CO2)
Specific hazards during fire
fighting / Specific hazards
arising from the chemical
: Water spray may be ineffective unless used by experienced
firefighters.
Do not allow run-off from fire fighting to enter drains or water
courses.
Combustion products
: No hazardous combustion products are known
Special protective equipment
for fire-fighters
: Wear self-contained breathing apparatus and protective suit.
Further information
: Use water spray to cool unopened containers.
Collect contaminated fire extinguishing water separately. This
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must not be discharged into drains.
Fire residues and contaminated fire extinguishing water must
be disposed of in accordance with local regulations.
See also Section 9. Physical and chemical properties: Safety data
6. ACCIDENTAL RELEASE MEASURES
Personal precautions
: Use personal protective equipment.
Ensure adequate ventilation.
Remove all sources of ignition.
Environmental precautions
: Do not flush into surface water or sanitary sewer system.
If the product contaminates rivers and lakes or drains inform
respective authorities.
Methods for cleaning up /
Methods for containment
: Contain spillage, and then collect with non-combustible
absorbent material, (e.g. sand, earth, diatomaceous earth,
vermiculite) and place in container for disposal according to
local / national regulations (see section 13).
Avoid contact with combustible material (paper, wool, oil).
Additional advice
: For personal protection see section 8.
7. HANDLING AND STORAGE
Handling
Advice on safe handling
Advice on protection against
fire and explosion
Storage
Requirements for storage
areas and containers
Other data
: For personal protection see section 8.
Smoking, eating and drinking should be prohibited in the
application area.
Dispose of rinse water in accordance with local and national
regulations.
Avoid contact with skin, eyes and clothing.
: Keep away from combustible material.
: Prevent unauthorized access.
Keep container tightly closed in a dry and well-ventilated
place.
: No decomposition if stored and applied as directed.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Exposure Guidelines
Contains no substances with occupational exposure limit values.
Hazardous components without workplace control parameters
Engineering measures
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Effective exhaust ventilation system
Ensure that eyewash stations and safety showers are close to the workstation location.
Personal protective equipment
Eye/face protection
: Tightly fitting safety goggles
Hand protection
: Glove material: For prolonged or repeated contact use
protective gloves.
: Glove material: Protective gloves complying with EN 374.
Skin and body protection
: Protective suit
Respiratory protection
: In the case of vapor or aerosol formation use a respirator with
an approved filter.
Hygiene measures
: Handle in accordance with good industrial hygiene and safety
practice.
When using do not eat or drink.
When using do not smoke.
Wash hands before breaks and at the end of workday.
Environmental exposure controls
General advice
: Do not flush into surface water or sanitary sewer system.
If the product contaminates rivers and lakes or drains inform
respective authorities.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance
Form
: Clear liquid
Color
: red brown
Odor
: Slightly ammonia like
Odor Threshold
: not determined
Safety data
pH
: 5 - 7 at 1 % solution
Freezing point
: < -18 °C
Boiling point
: 106 °C
Flash point
: Not applicable
Evaporation rate
: not determined
Flammability (solid, gas)
:
Lower explosion limit
: Not applicable
Upper explosion limit
: Not applicable
Vapor pressure
: similar to water
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Relative vapor density
: not determined
Relative density
: ca. 1.4
Water solubility
: Miscible.
Solubility in other solvents
: not determined
Partition coefficient: noctanol/water
: log Pow: < 0
Autoignition temperature
: Not applicable
Decomposition temperature
: > 107 °C
Viscosity, dynamic
: not determined
Viscosity, kinematic
: not determined
Explosive properties
: Not explosive
Oxidizing properties
: Not classified as oxidizing.
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This material safety datasheet only contains information relating to safety and does not replace any
product information or product specification.
10. STABILITY AND REACTIVITY
Conditions to avoid
: Extremes of temperature and direct sunlight.
Materials to avoid
: None known.
Hazardous decomposition
products
: No hazardous decomposition products are known.
Thermal decomposition
: > 107 °C
Reactivity
: Stable under normal conditions.
Chemical stability
: Stable under recommended storage conditions.
Hazardous reactions
: No dangerous reaction known under conditions of normal use.
11. TOXICOLOGICAL INFORMATION
PRODUCT INFORMATION:
Toxicology Assessment
Further information
: Suspected of causing cancer.
Carcinogenicity:
IARC
OSHA
: Group 2A: Probably carcinogenic to humans
Sodium nitrate
7631-99-4
Group 2B: Possibly carcinogenic to humans
Nitrilotriacetic acid
139-13-9
: No ingredient of this product present at levels greater than or
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NTP
Print Date 05/06/2015
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equal to 0.1% is identified as a carcinogen or potential
carcinogen by OSHA.
: Reasonably anticipated to be a human carcinogen
Nitrilotriacetic acid
139-13-9
TOXICOLOGY DATA FOR THE INGREDIENTS:
Toxicology Assessment
Component: Nitrilotriacetic acid
CMR effects
: Carcinogenicity: Limited evidence of a carcinogenic effect.
Test result
Component: Sodium nitrate
Eye irritation
: Result: Irritation to eyes, reversing after 7 to 21 days.
Literature data.
Component: Nitrilotriacetic acid
Acute inhalation toxicity
: LC0 : > 5 mg/l
Exposure time: 4 h
Test atmosphere: dust/mist
Saturated vapor concentration
Skin irritation
: Result: No skin irritation
Eye irritation
: Result: Irritating to eyes.
Repeated dose toxicity
: Species: Rat
Application Route: Oral
Exposure time: 104 w ()
NOEL: 92 mg/kg
Germ cell mutagenicity
Genotoxicity in vitro
: Ames test
Result: negative
Method: OECD Test Guideline 471
In vitro gene mutation study in mammalian cells
mouse lymphoma cells
Result: negative
Method: OECD Test Guideline 476
Genotoxicity in vivo
: In vivo micronucleus test
Method: OECD Test Guideline 474
Result: negative
Reproductive toxicity/Fertility
: Species: Rat
Fertility: No observed adverse effect level Parent: 450 mg/kg
body weight/day
Method: OECD Test Guideline 416
Result: Animal testing did not show any effects on fertility.
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Target Organ Systemic
Toxicant - Single exposure
: The substance or mixture is not classified as specific target
organ toxicant, single exposure.
Target Organ Systemic
Toxicant - Repeated
exposure
: Routes of exposure: Inhalation, Ingestion
The substance or mixture is not classified as specific target
organ toxicant, repeated exposure.
Aspiration toxicity
: No aspiration toxicity classification
12. ECOLOGICAL INFORMATION
PRODUCT INFORMATION:
Ecotoxicology Assessment
Additional ecological
information
: None known.
Further information on ecology
Hazardous to the ozone layer
Regulation
: 40 CFR Protection of Environment; Part 82 Protection of
Stratospheric Ozone - CAA Section 602 Class I Substances
Remarks
: This product neither contains, nor was manufactured with a
Class I or Class II ODS as defined by the U.S. Clean Air Act
Section 602 (40 CFR 82, Subpt. A, App.A + B).
INGREDIENTS:
Test result
Component: Nitrilotriacetic acid
Ecotoxicity effects
Toxicity to fish (Chronic
toxicity)
: NOEC: > 54 mg/l
Exposure time: 224 d
Species: Pimephales promelas (fathead minnow)
Test Type: flow-through test
Method: Other guidelines
Information given is based on data obtained from similar
substances.
Elimination information (persistence and degradability)
Bioaccumulation
: Not expected considering the low log Pow value.
Biodegradability
: Result: Readily biodegradable.
13. DISPOSAL CONSIDERATIONS
Product
: Do not dispose of waste into sewer.
Do not contaminate ponds, waterways or ditches with
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chemical or used container.
Hazardous waste
Dispose of contents/container in accordance with local
regulation.
Contaminated packaging
: Empty remaining contents.
Dispose of as unused product.
Do not burn, or use a cutting torch on, the empty drum.
14. TRANSPORT INFORMATION
International Regulation
ADR
Not regulated as a dangerous good
UNRTDG
Not regulated as a dangerous good
IATA-DGR
Not regulated as a dangerous good
IMDG-Code
Not regulated as a dangerous good
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable for product as supplied.
Domestic regulation
49 CFR
Not regulated as a dangerous good
TDG
Not regulated as a dangerous good
NOM-002-SCT
Not regulated as a dangerous good
15. REGULATORY INFORMATION
Notification status
CH INV
TSCA
DSL
AICS
NZIoC
ENCS
ISHL
KECI
PICCS
IECSC
: NO. Not in compliance with the inventory
: NO. This product either contains a chemical substance that is not listed
on the public TSCA Inventory or the TSCA Inventory status of the product
has not been evaluated.
: NO. This product contains the following components that are not on the
Canadian DSL nor NDSL.
: NO. Not in compliance with the inventory
: NO. Not in compliance with the inventory
: NO. Not in compliance with the inventory
: NO. Not in compliance with the inventory
: NO. Not in compliance with the inventory
: NO. Not in compliance with the inventory
: NO. Not in compliance with the inventory
For explanation of abbreviations, see section 16.
TSCA list
OSHA Hazards
: Not relevant
: Carcinogen
EPCRA - Emergency Planning and Community Right-to-Know
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CERCLA Reportable Quantity
This material does not contain any components with a CERCLA RQ.
SARA 304 Extremely Hazardous Substances Reportable Quantity
This material does not contain any components with a section 304 EHS RQ.
SARA 311/312 Hazards
: Chronic Health Hazard
SARA 302
: No chemicals in this material are subject to the reporting
requirements of SARA Title III, Section 302.
SARA 313
: The following components are subject to reporting levels
established by SARA Title III, Section 313:
Sodium nitrate
7631-99-4
Nitrilotriacetic acid
139-13-9
Clean Air Act
This product does not contain any hazardous air pollutants (HAP), as defined by the U.S. Clean Air
Act Section 12 (40 CFR 61).
This product does not contain any chemicals subject to disclosure and listed under the U.S. Clean
Air Act Section 112(r) for Accidental Release Prevention (40 CFR 68.130, Subpart F).
This product does not contain any chemicals listed under the U.S. Clean Air Act Section 111 SOCMI
Intermediate or Final VOC's (40 CFR 60.489).
Clean Water Act
This product does not contain any Hazardous Substances listed under the U.S. CleanWater Act,
Section 311, Table 116.4A.
This product does not contain any Hazardous Chemicals listed under the U.S. CleanWater Act,
Section 311, Table 117.3.
This product does not contain any toxic pollutants listed under the U.S. Clean Water Act Section 307
US State Regulations
Massachusetts Right To Know
Sodium nitrate
Nitrilotriacetic acid
7631-99-4
139-13-9
20 - 30 %
0.1 - 1 %
17084-02-5
20 - 30 %
7631-99-4
139-13-9
20 - 30 %
0.1 - 1 %
17084-02-5
20 - 30 %
7631-99-4
139-13-9
20 - 30 %
0.1 - 1 %
Pennsylvania Right To Know
Hydroxyethylethylenediaminetriacetic
acid, ferric complex
Sodium nitrate
Nitrilotriacetic acid
New Jersey Right To Know
Hydroxyethylethylenediaminetriacetic
acid, ferric complex
Sodium nitrate
Nitrilotriacetic acid
California Prop. 65
WARNING! This product contains a chemical known in the State of California to cause cancer.
Nitrilotriacetic acid
139-13-9
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16. OTHER INFORMATION
Full text of H-Statements
H272
H319
H351
: May intensify fire; oxidizer.
: Causes serious eye irritation.
: Suspected of causing cancer.
Further information
HMIS Classification
: Health Hazard: 2
Chronic Health Hazard: *
Flammability: 0
Physical hazards: 1
NFPA Classification
: Health Hazard: 2
Fire Hazard: 0
Reactivity Hazard: 0
Specific hazards: OX
0
2
0
OX
Notification status explanation
REACH
CH INV
TSCA
DSL
AICS
NZIoC
ENCS
ISHL
KECI
PICCS
IECSC
1907/2006 (EU)
Switzerland. New notified substances and declared preparations
United States TSCA Inventory
Canadian Domestic Substances List (DSL)
Australia Inventory of Chemical Substances (AICS)
New Zealand. Inventory of Chemical Substances
Japan. ENCS - Existing and New Chemical Substances Inventory
Japan. ISHL - Inventory of Chemical Substances
Korea. Korean Existing Chemicals Inventory (KECI)
Philippines Inventory of Chemicals and Chemical Substances
(PICCS)
China. Inventory of Existing Chemical Substances in China (IECSC)
Further information
Revision Date
04/24/2015
The information in this material safety data sheet should be provided to all who will use, handle,
store, transport or otherwise be exposed to this product. The user must determine the
appropriate measures that need to be implemented for the use and handling of this product in
the c ontext of the user's operations and use of this product. The information contained herein
supersedes all previously issued bulletins on the subject matter covered. If the date on this
document is more than three years old,call to make certain that this sheet is current. No warranty
is made as to the product’s merchantability or fitness for any particular purpose, or that any
suggested use will not infringe any patent. User must determine for himself, by preliminary tests
or otherwise, the suitability of this product for his purposes, including mixing with other products.
Nothing contained herein shall be construed as granting or extending any license under any
patent.
The information provided in this Material Safety Data Sheet is correct to the best of our
knowledge, information and belief at the date of its publication. The information given is designed
only as a guidance for safe handling, use, processing, storage, transportation, disposal and
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release and is not to be considered a warranty or quality specification. The information relates
only to the specific material designated and may not be valid for such material used in
combination with any other materials or in any process, unless specified in the text.
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