Design Manual for Thermoelectric Systems Tellurex: discover what’s possible. Tellurex offers a wide variety of products and services for your thermoelectric needs. Tellurex Plug and play convenience means stock thermoelectric cooling engine assemblies that can speed you though the design phase straight to proof of concept. Both cold plate and air to air systems are available as well as temperature control options and power supplies. Tellurex further provides engineering, design, and assembly services to get you from proof of concept to finished goods. Visit our website: www.tellurex.com or call us at 231-9470110 for design assistance. All thermoelectric application designs present unique challenges that affect performance and longevity of the thermoelectric module. Because of this fact, Tellurex does not make performance or reliability proclamations for designs that have not been reviewed and approved by Tellurex. Tellurex Corporation www.tellurex.com SA-10-FRM-01 Thermoelectric Cooling, Heating When DC voltage is applied to the module, the positive and negative charge carriers in the pellet array absorb heat energy from one substrate surface and release it to the substrate at the opposite side. The surface where heat energy is absorbed becomes cold; the opposite surface where heat energy is released, becomes hot. Using this simple approach to "heat pumping", thermoelectric technology is applied to many widely-varied applications– small laser diode coolers, portable refrigerators, scientific thermal conditioning, liquid coolers, and beyond. Each individual thermoelectric system design will have a unique capacity for pumping heat (in Watts or BTU/hour) and this will be influenced by many factors. The most important variables are ambient temperature, physical & electrical characteristics of the thermoelectric modules employed, and efficiency of the heat dissipation system (i.e., sink). Typical thermoelectric applications will pump heat loads ranging from several milliwatts to hundreds of watts. The Thermoelectric "Sweet Spot" The majority of practical applications for thermoelectric technology fall within a very narrow range of operating conditions. • • • Temperature differential (Delta T) between 30°C and 50°C Thermoelectric module current draw (l) between 70% and 80% of IMAX, and Co-efficient of performance (COP) between 0.25 and 0.4. Tellurex Corporation www.tellurex.com SA-10-FRM-01 1. Getting Started; Understand the Thermal loads: Active and Passive To maintain a temperature difference between an object and the ambient environment, a certain amount of energy must be continually moved out of (for cooling) or into (for heating) the object. The rate at which this energy is moved (usually expressed in watts), is the thermal load expressed as Q. In designing a thermoelectric system one of the most important processes is reaching an understanding of your thermal load. You must have this information to select the thermoelectric device and heat exchangers for the job. To start you need to arrive at a good, solid estimate of how much thermal load must be removed from the object to achieve the performance objectives. Examples of active, passive and combination of the two are: Active only: a specific electrical device is producing heat while in operation and needs to be cooled. The cooling system will be in direct contact with the device, the only significant source of heat will be that specific device. Passive only: a cup-holder in the center console of an automobile contains a bottle of water, the only significant source of heat is the atmosphere surrounding the cup-holder. Combination of active and passive load: An enclosure containing electrical equipment needs to be kept at a certain temperature for the equipment to function properly. The electrical equipment inside the box is a source of heat. The atmosphere surrounding the enclosure is warmer than the desired internal temperature and is also a source of heat. The active load portion is easily conceived; the passive load is like a leaky boat. Water is continually leaking into the boat and you have to bail out the water to stay afloat. With a thermoelectric system, you are trying to keep your thermal load colder than the ambient temperature; you have to bail out the heat faster than it is leaking in. In cooling applications Heat is going to leak into the thermal load from the ambient environment through the insulation, doors, seals and pass-through. Worst Case Scenario Design: Determine what the highest ambient temperature and the desired cold temperature. This is generally your worst case. If you design your system so that you'll have enough cooling capacity in that worst case, you'll have more than enough potential for every other situation. The worst-case difference between your ambient and load temperatures, will be your 'Delta T' in the equations which follow. Passive Load Determination If your system is an active load only you may skip this section. If you have a passive load element this section will help you estimate that load. The transfer of heat from a load to the ambient environment, is largely a function of two thermal processes—conduction and convection. Conduction is the transfer of heat through matter (insulation, structural components, seals, fasteners, etc.) and is a function of the temperature difference (i.e., Delta T) across the material, the physical dimensions, and the thermal conductivity Tellurex Corporation www.tellurex.com SA-10-FRM-01 of the material (K). Convection is heat transfer across the boundary layer of air at the surface of a material. It is a function of the Delta T across the boundary layer and the rate of air movement at the surface—the faster the air movement, the greater the convection of heat. With a well-insulated thermal load (e.g., an insulated enclosure), convection is a relatively inconsequential component and you can often focus exclusively on the conductive element. The following equation can be used to estimate a purely conductive load: (Purely conductive passive load equation) Where Q is the amount of heat conducted (it can be expressed in either BTU/hour or watts, although in the thermoelectric industry, most support documentation is based on wattage); ΔT is the temperature difference between the thermal load and the ambient environment (in F° for BTU/hour calculations, in C° for watts); K (Kappa) is the thermal conductivity of the material expressed in either BTU/hour-feet-F° or watts/meter-C°; L is the thickness of the material (in feet for BTU/hour calculations, meters for watts); and A is the exposed surface area of the material (in square feet for BTU/hour calculations, square meters for watts). If you want to include both the conductive and convective components of the load, you can use this equation: (Combination conductive/convective passive load equation) where Q is the amount of heat conducted and convected (expressed in either BTU/hour or watts); K (Kappa) is the thermal conductivity of the material expressed in either BTU/hour-feet-F° or watts/meter-C°; h is the heat transfer coefficient (in still air, this ranges between 4-5 BTU/hour-feet2-F° or 23-28 watts/meter2-C°; in turbulent air, h falls in the range of 14-20 BTU/hour-feet2-F° or 85-113 watts/meter2-C°); L is the thickness of the material (in feet for BTU/hour calculations, meters for watts); A is the exposed surface area of the material (in square feet for BTU/hour calculations, square meters for watts); and ΔT is the temperature difference between the thermal load and the ambient environment (in F° for BTU/hour calculations, in C° for watts). Note that the result that you get for Q with this equation will be lower than that obtained for the formula based only upon conduction. This is because the convection/conduction equation accounts Tellurex Corporation www.tellurex.com SA-10-FRM-01 for two sources of thermal resistance to heat flow. With the calculation reflecting a slightly greater series resistance to heat leakage, it logically follows that fewer watts will be indicated to compensate for passive load. When you are dealing with an un-insulated load, or an un-insulated portion of one (e.g., a cold plate), then it becomes very important to explore the convective part of thermal load. In these situations, convection may offer the primary resistance to the leakage of heat. Remember that in some situations (e.g., an un-insulated enclosure), you will have air movement on both the inside and outside; as a result, your Delta T will be split between the two boundary layers (based on the relative convectivity of each). As you will find in using the equation below to estimate your convective load, without insulation, you will need to pump a lot more wattage with your thermoelectric system. (Purely convective passive load equation) where Q is the amount of heat convected (expressed in either BTU/hour or watts); h is the heat transfer coefficient (in still air, this ranges between 4-5 BTU/hour-feet2-F° or 23-28 watts/meter2-C°; in turbulent air, h falls in the range of 14-20 BTU/hour-feet2-F° or 85-113 watts/meter2-C°); A is the exposed surface area of the material (in square feet for BTU/hour calculations, square meters for watts); and ΔTB is the temperature difference across the boundary layer at any exposed surfaces (in F° for BTU/hour calculations, in C° for watts). When dealing with enclosures, you can also estimate your passive load empirically once a prototype is built. Simply place a known heat load inside (make sure that the enclosure can 'take the heat'), then monitor the temperatures of the ambient and enclosure interior. Once the Delta T between the inside and ambient has stabilized, you can use the following equation to determine the passive load: where Q is the passive load, expressed in watts; TAMB is the ambient temperature after stabilization (in C°); TENC is the enclosure temperature after stabilization (in C°); ΔTDES is the desired temperature difference between the inside of the enclosure and the ambient environment (in C°); and P is the power dissipation within the heater employed for the test (expressed in watts). Tellurex Corporation www.tellurex.com SA-10-FRM-01 2. Thermoelectric System Design Taking an active load example of a specific electrical device that is producing heat while in operation given above. The cooling system will be in direct contact with the device, the only significant source of heat will be that specific device. That device has been found to be a 20 watt device that works best at 20°C. Q = 20 watt heat load arrived at through the exercises above. TA = 35°C maximum ambient air temperature TC = 20°C required temperature of electronic component Prior to using the performance graphs to determine which thermoelectric module is appropriate for our application, we must first identify the hot side temperature (TH) and the resultant temperature differential across the module (ΔT). In this design, we will keep the rise of the heat sink temperature to no more than about 15°C above ambient (this is a good rule of thumb heat sink rise). This would give us a thermoelectric module hot side temperature of about 50°C. TH = TA + heat sink rise above ambient = 25°C + 15°C = 50°C The temperature differential across the module can now be calculated as follows: ΔT = TH - TC= 50°C – 20°C = 30°C Module selection: The performance graphs for each of the modules provide data for hot side temperature of 27°C and 50°C. For this application, use the Thot = 50°C curves. Figure 1 Q v. Voltage under various Delta T Tellurex Corporation www.tellurex.com SA-10-FRM-01 Figure 2 Voltage v. DT under various currents The specification sheets indicate that a C2-40-1504 module is capable of meeting the needs. On Figure 1 follow the 30°C delta t line (teal) until it intersects the 20 watt Y axis lines. The intersection is slightly below the 11 volt level. This indicates some extra capacity if a 12 volt power supply is used. Next, using figure 2, locate the intersection of the 11 volt Y axis level and the 30°C delta T along the X axis. The intersection is very near the 3 amp line. We can now approximate the thermoelectric module power using: Power = I x V = 3 amps x 11 volts = 33 watts Protection against corrosion and short circuit: It is important to consider the atmosphere that your thermoelectric system will operate in: Is the environment caustic? Will there be condensation or water present? Is there an electrically conductive dust that may cause electrical shorting? Of all these scenarios condensation of water is the most common and most detrimental. Condensation is the enemy of thermoelectric devices. If the target temperature is below the dew point temperature water vapor will condense on the thermoelectric device. You must protect the electrical components from exposure to water. Just as you would any not want to put a toaster in a bathtub because of electrical shorting, you would not want to operate a thermoelectric device in a condensing application without protecting the electric conductors. Tellurex offers very effective methods of protecting thermoelectric devices from corrosive environments. Our product “Z-Coat” is a conformal coating that provides excellent corrosion resistance against caustic chemicals or water vapor. Our product “Z-seal” is a perimeter seal that provides excellent vapor barrier protection as well as dielectric protection against electrical shorting in systems. Tellurex does not recommend using a silicone perimeter seal for condensing applications. Silicone, while providing good dielectric protection against electrically conductive dust, does not prevent water vapor from passing through the perimeter seal. Once the vapor passes through the silicone perimeter it condenses to liquid form, and cannot escape. The liquid water inside the silicone perimeter acts as an electrical and thermal short causing premature failure of the thermoelectric device. Other design considerations to prevent corrosion or short circuit conditions are insulation methods that can block Tellurex Corporation www.tellurex.com SA-10-FRM-01 out water vapor and dust. There are many types of insulation available that provide various levels of protection, especially effective are injected insulations that bond to the surfaces of your system. Heat sink selection: The values identified in the preceding first pass analysis are used to assess overall system feasibility. We want to qualify our assumption of 15°C rise across heat sink. The hot side temperature will be equal to the ambient temperature (TA) plus the rise in temperature across the heat sink from dissipating the heat load (Q) and the heat resulting from the thermoelectric module electrical power (V x I). TH = TA + (V x I + Q) RQ where RQ = thermal resistance of heat sink in C° temperature rise per Watt dissipated. The heat pumping capability of the thermoelectric module is significantly influenced by the efficiency of the heat sink. The hot side of the module must interface with an efficient heat removal system to achieve useful temperature differential across the thermoelectric module. Natural convection, forced convection, and liquid cooled are three of the most common types of heat sinks. Thermal resistance varies among the different types and sizes of sinks with natural convection being the least efficient and liquid cooled the most efficient. The majority of thermoelectric cooling applications use forced convection heat sinks with thermal resistance values (RQ) ranging from 0.05°/W to 0.9°/W. Using values now known for TA V, I, and Q we can solve for RQ to determine if it is reasonable: RQ = (TH — TA)/(V x I +Q)=(50°C - 35°C)/(11V x 3 amps +20W) RQ = 0.283°C/W Our proposed system using a C2-40-1504 module and a forced convection sink/fan combination meets or exceeds the criteria for this application. An experienced heat sink supplier can help with the selection of a system that meets the RQ requirements. 3. System Assembly Several methods for installing thermoelectric modules have been developed, including: mechanical clamping, epoxy bonding, and direct solder bonding. The individual requirements of the application will determine which method is most appropriate, mechanical clamping is by far the most common. Thermoelectric modules are relatively strong in compression and weak in shear; whichever method of installation is used, it is important to avoid excessive mechanical loading of the module. Mechanical Clamping: • Recommended flatness of interface surfaces should be within 0.001" and free of drit, burrs etc. • Thermal interface materials must be used to fill in the small thermal gaps Tellurex Corporation www.tellurex.com SA-10-FRM-01 • • • o Choices include silicone-based thermal grease, graphite foil, and thermallyconductive pads. o Refer to your interface material specifications for performance curves in relation to pressure. Bolt the object to be cooled and heat sink together using stainless steel fasteners washers and or split type lock-washers, compression springs or Bellville washers can also be used. The recommended compression loading is 70 to 150 per sq. inch of module surface. Insure an even pressure across the module surface when tightening the screws. Design Manual Summary: 1: Understand the load: You must determine how much work the thermoelectric system must do to achieve the goal. 2: Select your thermoelectric device: Choose a thermoelectric device that can do the work you have determined while operating in the worst case scenario. Choose the module that can do this while operating in the “sweet spot” of 70-80% of Imax. 3: Select the level of corrosion, and dielectric protection: Choose the level of protection needed for your operating conditions. 4: Select your heat sink: Determine what heat sink performance is needed to achieve the goal, and source the proper device. 5: Assemble your system: A properly designed and assembled system will provide even clamping force, good thermal interface, proper sized thermoelectric module, adequate heat sinking, proper corrosion resistance, and insulation as needed. Tellurex Corporation www.tellurex.com SA-10-FRM-01