STAINLESS Heat-Resistant Austenitic Stainless Steel (ASTM:UNS 31060) (NSSMC-NAR-AH-4) http://www.nssmc.com/ 2-6-1 Marunouchi, Chiyoda-ku,Tokyo 100-8071 Japan Tel: +81-3-6867-4111 Heat-Resistant Austenitic Stainless Steel S004en_01_201212f © 1997 , 2012 NIPPON STEEL & SUMITOMO METAL CORPORATION Alloy Design・Features ❶ Main Use Applications 1 Parts requiring heat resistance in Industrial Furnaces, Heat-treating Furnaces, Power Plants and Alloy design of NSSMC-NAR-AH-4 Oxidation Resistance・ Creep Rupture Erosion Resisitance Strength High Cr≧22.5% Solid solution strengthening: Addition of N Addition of rare earth metals Grain boundary strengthening: Addition of B Chemical Plants. Microstructural Stability・ Cost Saving Addition of N 2 Fuel cell reforming Tube. Weldability Decrease of Si Optimization of Creq / Nieq Grain size control 3 Auto parts(Exhaust Manifold etc.). 4 Substitute for SUS310S. Especially suited for material requiring high-temperature mechanical strength. Specification and Equivalent Specification Physical Properties ●ASTM A240, A213 ●UNS S31060 ●ASME Code Case 2430 (ASME Section Ⅰ & Ⅷ, Div.1 Boiler and Pressure Vessel) ❶ Specification Table 1 : Chemical Composition (wt%) 0.3%Si -0.07%C -23%Cr -11%Ni -0.2%N -La+Ce -B ❷ Superior High Temperature Properties Designation C NSSMC-NAR-AH-4 0.05〜 0.10 0.05〜 0.10 UNS S31060 (for reference) SUS 310S ≦0.08 Si Mn P S ≦1.00 ≦1.00 ≦0.040 ≦0.030 ≦0.50 ≦1.00 ≦0.040 ≦0.030 ≦1.50 ≦2.00 ≦0.045 ≦0.030 Cr Ni N other elements 22.00〜 24.00 22.00〜 24.0 22.00〜 26.00 10.00〜 12.00 10.00〜 12.5 19.00〜 22.00 0.18〜 0.25 0.18〜 0.25 La+Ce 0.03〜0.07 La+Ce 0.025〜0.070 B0.001〜0.010 ─ ─ ●Higher tensile strength and creep strength at high temperature than SUS310S(JIS G4303) . ●Excellent oxidation resistance at 900〜1000℃ superior to SUS310S. ●Superior structure stability after long-term exposure to high temperature(700〜900℃) , without a drastic drop in toughness like SUS310S. ❸ Superior Weldability ●Lower sensitivity of weld hot cracking than SUS310S, especially favorable for thick plates ❷ Physical Properties Table 2 : Density, Specific Heat, Thermal Conductivity and Thermal Diffusivity Designation Density(g/cm3) NSSMC-NAR-AH-4 UNS S31060 7.88 502 13.8 0.036 8.03 502 14.2 ─ (for reference) SUS 310S Specific Heat(J/Kg・K)Thermal Conductivity(W/m・K) Thermal Diffusivity(cm2/sec) welding. Table 3 : Linear Expansion Coefficient ❹ Cost Saving Temperature(℃) 30-100 30-200 30-300 30-400 30-500 30-600 30-700 30-800 Linear Expansion(×10−6/℃) 15.7 16.2 16.8 17.1 17.4 17.7 18.1 18.5 30-900 30-1000 18.7 19.1 ●Reasonably designed chemical composition as compared with SUS310S. Table 4 : Poisson' s ratio Notice: While every effort has been made to ensure the accuracy of the information contained within this publication, the use of the information is at the reader’ s risk and no warranty is implied or expressed by Nippon Steel & Sumitomo Metal Corporation with respect to the use of the information contained herein. The information in this publication is subject to change or modification without notice. Please contact the Nippon Steel & Sumitomo Metal Corporation office for the latest information. Please refrain from unauthorized reproduction or copying of the contents of this publication. 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Other product or service names shown may be trademarks or registered trademarks of their respective owners. 1 Temperature(℃) RT 450 500 600 700 800 900 1000 Modulus of Elasticity(GPa) 188 158 154 146 138 130 128 119 Poisson' s ratio 0.260 0.260 0.260 0.262 0.263 0.263 ─ ─ 2 ❸ Mechanical Properties ❸ High-temperature Properties Table 5 : Mechanical Properties NSSMC-NAR-AH-4 UNS S31060 (for reference) SUS 310S Elongation(%) Hardness(HRB) ≧280 ≧600 ≧40 ≦95 ≧205 ≧520 ≧40 ≦90 Properties of NSSMC-NAR-AH-4 300 0.2% Yield Strength/Tensile Strength 2 (N/mm ) 0.2% Yield Strength(N/mm2) Tensile Strength(N/mm2) 0.2% Yield Strength/Tensile Strength 2 (N/mm ) Designation 900 :AH-4 :SUS 310S 200 Tensile Strength 100 0.2% Yield Strength 0 800 900 Test Temperature(℃) 800 0.2% Y.S. T.S. 700 600 500 400 300 200 0 1000 SUS 310S AH-4 Fig.2 Tensile properties at room temperature Fig.1 Tensile properties at high temperature 150 ❶ Chemical Composition 50 900℃ 1000℃Designation 30 SUS 310S Si Mn P S Cr Ni N La+Ce B NSSMC-NAR-AH-4 0.07 0.31 0.48 0.021 0.001 23.11 10.95 0.197 0.03 0.003 (for reference) SUS 310S 0.05 0.58 1.21 0.023 0.001 24.63 20.25 0.024 ─ ─ Impact Value (J/cm2) C Stress (N/mm2) Designation 10 10 10 Time to rupture(h) 2 3 5 1000 ❹ Resistance to high-temperature oxidation or coarser, as measured by Test Methods E112 0 ( Thickness ≧ 6mm) 100 cycles 200 Weight change by oxidation 2 (g/m ) 900℃ 0 -100 0 -100 300 400 40 SUS 310S AH-4 1000℃ SUS 310S AH-4 (25minutes heating-5minutes air cooling) Fig.5 Cyclic oxidation test result in the air 3 800 Aging temperature(℃) Fig.4 Charpy impact properties after aged at 700~900℃ Weight gain by oxidation 2 (g/m ) ● Grain size:Average grain size of ASTM No.7 SUS 310S 0 600 10 4 Fig.3 Creep rupture properties Microstructure ● Austenitic structure 50 AH-4 5 10 Photo 1. Typical microstructure after solution heat treated Aging time:3000h 100 Table 6 : Typical Chemical Composition (wt%) ❷ Test piece:2mm V-notch, half size Test temperature:room temperature AH-4 30 1000℃ 900℃ in air 20 10 0 AH-4 SUS 310S Fig.6 Continuous oxidation test result(200h) 4 ❺ Resistance to high-temperature erosion 600 Designation AH-4 10 SUS 310S Blasted speed:5m/s Temp.:900℃ Abrasives:silicate sand ε=2% 400 2000 200 1000 0 50 0 100 0.1 0.3 5 600 1000 (Cold rolling) No crack ↓ 0 AH-4 Time(h) Fig.7 Erosion test result(900℃) (n=2) Thickness (mm) Maximum depth of thickness loss Total crack length (mm) Weight loss (mg) 3000 Weight loss Maximum depth of thickness loss (μm) 4000 Available Sizes ❻ Weldability SUS 310S 3.0 1219 1524 2000 6.0 (Hot rolling) 32.0 40.0 Fig.8 Hot cracking test result (Longi Varestraint test) 2,000 1,000 3,000 Width(mm) ❼ Creep Rupture Strength of Welded Joint 900℃ 1000℃ 50 Available maximum length:6,000mm :Range of consultation Consult us for custom-made dimensions. AH-4 Base Metal Stress (N/mm2) 30 Welded Joint 10 5 10 10 10 Time to rupture(h) 2 3 Fig.9 Creep rupture test result of welded joint 4 10 5 Base metal thickness:20mm Welding process:GTAW Welding consumable:WEL Auto TIG AH-4(1.2φ) ❽ Welding Consumables ●Supplier : Nippon Welding Rod Co., Ltd. [URL] http://www.nihonwel.co.jp/ [e-mail] info@nihonwel.co.jp 5 For TIG welding For SMA welding WEL TIG AH-4 1.2, 1.6, 2.0, 2.4, 3.2mmφ WEL Auto TIG AH-4 1.2, 1.6mmφ WEL AH-4 2.6, 3.2, 4.0, 5.0mmφ 6