Contents Foreword ……………………………2 Features ……………………………3 Production Processes ……………4 Examples of Uses …………………5 Specifications ………………………9 Properties …………………………13 Steel Pipe …………………………23 Standard Specification for Steel Sheet, Cold-Rolled, Aluminum-Coated Type 1 ………25 1 Nisshin Steel Quality Products Foreword Nisshin Steel Co., Ltd. is Japan's sixth largest producer of iron and steel, with an annual crude steel production capacity in excess of three million tons. The Company, a member of the International Iron and Steel Institute, has extensive experience in the production and marketing of ordinary, specialty, and stainless steel. Nisshin is particularly strong in coated and stainless steel and has also established a firm position in the ordinary and specialty steel markets. The Company has maintained the highest technological standards, developing innovative technology and marketing superior quality steel products for industry and the home. Nisshin Steel Co., Ltd., well-known for Moonstar brand galvanized sheet, galvannealed sheet, and spangle-free galvanized sheet, proudly introduces Alstar, a new type of aluminized steel sheet and coil that has more versatility than conventional aluminized steel sheet. Aluminized steel sheet had been produced by the roll-wiping method in Japan since 1962, but the gas-wiping method developed by Nisshin Steel in 1968 has improved the uniformity and appearance of aluminum-coated steel sheet. This new process has also widened the scope of aluminized steel sheet applications. Alstar metallurgically combines the strength of steel with the advantages of aluminum, and is extensively used where heat resistance is involved. Specific uses are in heat-resistant parts and products for automobiles, burners, and home appliances. Alstar now enjoys the largest share of the domestic aluminized steel sheet market. Aerial view of the Sakai Works Nisshin Steel Quality Products 2 Features Alstar features heat resistance, corrosion resistance at high temperature, heat reflectivity, attractive appearance, nonpolluting properties, and other characteristics that are unique to aluminized steel sheet. The gas-wiping method developed by Nisshin Steel has been applied to Alstar production to offer the following additional features. 1 Uniform aluminum coating and free control of aluminum thickness. 2 Thin aluminum coating(40g/m2 on both sides) . This means better weld-ability and formability and hence better productivity. 3 Even surface finish and silvery white appearance make Alstar useful in applications where a fine finish is important. 4 Nisshin's aluminizing line is in constant operation so Alstar is available where and when it is needed. 3 Nisshin Steel Quality Products Production Processes Figure 1 : Production Processes 8 5 2 4 Coil 1 3 9 10 12 7 14 1 Cut-length Coil 6 13 2 3 11 4 1. 2. 3. 4. 5. 6. 7. Uncoiler Shear Welder Looper Oxidizing, reducing, and annealing furnace Aluminum coating bath Gas-wiping Cold Rolled Steel Coils Oxidizing, Reducing, and Annealing Furnace 8. 9. 10. 11. 12. 13. 14. Cut-length Cooling tower Skin pass mill Tension leveller Posttreatment tank Shear Recoiler Skin pass mill Aluminizing Cooling Posttreatment Aluminum Coated Steel 1.Annealing process Nonannealed cold-rolled steel strip is annealed and the oxide film formed on the surface is reduced in the furnace. 2.Coating process After the strip is reduced to a clean surface, it is passed through the aluminum coating bath. The weight of aluminum coating on the strip is regulated by the gas-wiping method. 3.Posttreatment process The aluminum-coated strip is then treated by chromate solution to make it further corrosion resistant. After thorough drying, the sheet is wound back into a coil. 4.Skin passing process The aluminum-coated strip is skin passed to make it suitable for specific uses, where such factors as surface conditions and age hardening are involved. Nisshin Steel Quality Products 4 Examples of Uses Kerosene heater Kerosene heater Kerosene heater Large-sized kerosene heater Large-sized kerosene heater Large-sized kerosene heater Kerosene heater Water heater 5 Nisshin Steel Quality Products ■ Examples of Uses ■ Kitchen utensils Kitchen utensils Kitchen utensils Oven, toaster Gas oven Two-burner gas stove Gas range Smokestack Nisshin Steel Quality Products 6 ■ Examples of Uses ■ Muffler Muffler Muffler Muffler Heat insulator Reactor part Muffler and converter 7 Nisshin Steel Quality Products ■ Examples of Uses ■ Manifold cover Manifold cover Manifold cover Charcoal stove Charcoal stove Chimney Barbecue grill Kerosene stove Fireplace Nisshin Steel Quality Products 8 Specifications 1.Types of Alstar (1) Alstar is available in the following types which vary with the uses and the means of processing. Table 1 Symbol ASTM(A463) Surface Finish Commercial Quality Type C CQ Dull Drawing Quality D DQ Dull Deep Drawing Quality E DQSK Dull (2) Indication of product's standard is as follows: MSA C(D,E) Quality Product symbol D △△ ××× Posttreatment Surface finish (Dull) Mass of aluminum coating (3) There are several kinds of posttreatment for various uses. These include ordinary chromate and oiling and oiling nonchromate. Table 2 Posttreatment Symbol Chromate and oiling N0 Oiling nonchromate M0 2.Masses of Aluminum Coating Alstar is available in various masses of aluminum coating as shown in the following table. Table 3 Item Symbol Minimum mass on both sides(triple-spot test) ASTM(A463) Nisshin Standard T1-25 T1-40 MSA-40 MSA-60 MSA-80 MSA-100 g/m2 (80) (120) 40 60 80 100 120 ox/ft2 0.25 0.40 (0.13) (0.20) (0.25) (0.33) (0.40) Note : Minimum masses on both sides by the triple-spot test are based on the ASTM standards. 9 Nisshin Steel Quality Products MSA-120 ■ Specifications ■ 3.Mechanical Properties Tension and bend tests of Alstar produce the following values. (1) Tensile strength and elongation Table 4 Elongation(%) , Thickness(mm) Tensile Strength (N/mm2) 0.4 to 0.6 excl. 0.6 to 0.8 excl. 0.8 to 1.0 excl. 1.0 to 1.6 excl. 1.6 to 2.3 incl. Commercial Quality (270) (23) (26) (28) (30) (31) Drawing Quality (270) 30 32 33 34 35 Deep Drawing Quality (270) 34 36 37 38 39 Type Notes : 1. The No.5 test specimen in JIS Z2201 is used for the tension test which is conducted in conformity with JIS Z2241. 2. Values in parentheses for commercial quality sheet are for reference only. (2) Bend test A specimen taken from the aluminized steel sheet in the direction parallel to its rolling is bent through 180°over a radius of 0.5t at right angles to the rolling direction. The outside of the bend shall be free from flaking of the coating, and cracking and breaking in the base metal. This does not apply to those par ts of the specimen which are within 7mm of both ends. Note : The bend test specified in the ASTM standards may be conducted on the product if requested. 4.Available Dimensions Alstar is available in the dimensions shown in the chart below. Figure 2 1,200 1,219 or under 1,150 or under 1,100 1,070 or under Width(mm) 1,000 1,000 914 900 800 700 600 700 or over 600 or over 0.3 0.4 0.5 0.6 0.7 under 1.3 1.4 1.5 1.6 1.7 1.8 1.9 2.0 2.1 2.2 2.3 Thickness(mm) Nisshin Steel Quality Products 10 ■ Specifications ■ 5.Dimensional Tolerances Dimensional tolerances are as shown below. Alstar can also be manufactured to the dimensional tolerances of the ASTM A463 standards. (1) Thickness tolerances Table 5 (mm) Width Thickness Under 1,000 1,000 or Over 0.27 to 0.40 excl. ±0.06 ±0.06 0.40 to 0.60 excl. ±0.07 ±0.07 0.60 to 0.80 excl. ±0.09 ±0.09 0.80 to 1.00 excl. ±0.10 ±0.11 1.00 to 1.25 excl. ±0.11 ±0.12 1.25 to 1.60 excl. ±0.13 ±0.14 1.60 to 2.00 excl. ±0.14 ±0.15 2.00 to 2.30 ±0.16 ±0.17 Notes : 1.The thicknesses shown in the above table indicate sheet thicknesses plus the thicknesses corresponding to aluminum coating masses. 2.Thickness is measured at any point across the width not less than 50mm from a side edge. (2) Length and width tolerances Table 6 Table 7 (mm) (mm) Item Tolerance Edge Tolerance Length +12, −0 Mill edge +10, −0 ─ Slit edge ±0.5 Applies to widths less than 600mm Note : The length tolerances shown in Table 6 do not apply to coil products. Remarks (3) Flatness tolerances The flatness tolerance shall be less than the figures shown in Table 8. Table 8 (mm) Thickness Type Long Edge (maximum deviation from a horizontal flat surface) Center Buckle (maximum deviation from a horizontal flat surface) Under 0.5 0.5 or over Under 0.5 0.5 or over Panel Quality 5 5 3 3 Commercial Quality 8 8 5 5 Press Forming Quality 11 8 8 5 Notes : 1. Flatness tolerances apply to cut length sheets. 2. Consult us about tolerances for panel quality and commercial quality sheet when ordering. 11 Nisshin Steel Quality Products ■ Specifications ■ (4) Camber tolerances Camber is the greatest deviation of a side edge from a straight line. Camber measurement is taken as shown in Figure 3 for cutlengths and Figure 4 for coils. The camber tolerance for sheet with a width of 50mm or over and less than 200mm, and with a length of 2,000mm or over and less than 3,048mm, is measured as shown in Figure 4. Figure 3 Figure 4 Length Width Width Camber 2,000mm Camber The camber tolerance values apply to normal parts of coils and cut-lengths. Their camber tolerances must be less than the values shown below. Table 9 (mm) Width Cut-length Length under 2,000 Length over 2,000 to 3,658 excl. Coil 50 to 60 excl. ─ ─ 8 per 2,000 60 to 200 excl. ─ ─ 4 per 2,000 200 to 600 excl. ─ ─ 4 per 2,000 600 or more 2 4 2 per 2,000 Nisshin Steel Quality Products 12 Properties 1.Heat Resistance Alstar has far greater heat resistance than galvanized and cold-rolled steel sheet and thus keeps its original fine surface luster even when used for long periods at temperatures below 450℃*. If it is exposed to temperatures above 450℃, however, the iron and aluminum become alloyed through mutual diffusion and the surface gradually turns from gray to a darker color. Since this alloy layer has a high fusing point, it will not melt even if exposed to a temperature above the fusing point of aluminum. In addition, an oxide layer is produced on the coated surface by high temperature, which suppresses scale formation so that the sheet will not quickly become oxidized and worn until the diffusion progresses to the point where the aluminum coating becomes unable to control scale formation (approximately 600℃). The heat-resistant characteristics of Alstar are shown below. *We have high grade Alstar which can be used at approximately 500℃. (1) Heating behavior of aluminized steel sheet Figure 5 Heating ……………………………… ……………………………… Al ……………………………… ……………………………… ……………………………… ……………………………… ……………………………… ……………………………… ……………………………… ……………………………… ……………………………… ……………………………… ……………………………… ……………………………… Al ……………………………… ……………………………… ……………………………… Alloy layer Alloy layer Fe (before heating) 13 Nisshin Steel Quality Products Oxidized layer caused by high temperature Heating Fe (after heating) × × × × × × × × × × × × × × × × × × × × Alloy layer Fe (after more heating) × × ■ Properties ■ (2) Microscopic photographs of cross sections of MSA-40 kept at 500℃ for 100 hours and 1,000 hours, respectively Cross sectional structures of Alstar before and after heating to 500℃(Drawing Quality) Before heating After 100 hours of heating at 500℃ After 1,000 hours of heating at 500℃ (3) Heat resistance comparison of aluminized steel, stainless steel, and cold-rolled steel sheet Figure 6 shows a mass increase comparison of Alstar with 18-8 stainless steel and cold-rolled steel sheet after high-temperature oxidation. Alstar shows good heat resistance(at 500℃ to 600℃)similar to stainless steel sheet, and is over 20 times more heatresistant than cold-rolled steel sheet. (40 she led ste el teel sh ldCo Cold-r 40 rol olled s 50 Oxygen Pickup (mg/dm2) et eet (50 60 0℃ ) 0℃) Figure 6 30 ) 00℃ r (6 a t s Al 0℃) t (60 hee s l e ste less stain 18-8 00℃) Alstar (5 20 10 el sheet (500℃) 18-8 stainless ste 0 4 8 12 16 20 24 28 32 36 40 44 48 52 Oxidation Time (hours) Heat resistance comparision of Alstar, stainless steel, and cold-rolled steel sheet Nisshin Steel Quality Products 14 ■ Properties ■ (4) Mass increase/decrease by oxidation through heating and cooling cycles Figures 7 and 8 show a mass increase and decrease comparison of Alstar's different aluminum coating masses with other materials after oxidation, and after being exposed to 10 cycles of heating to 600℃ and 750℃ and then cooled. It is clear from the diagrams that Alstar possesses greater oxidation resistance than cold-rolled and galvanized sheet even at temperatures of 600℃ and 750℃, and can be satisfactorily used below 600℃ without any increase in oxidation. Figure 7 : Heating and Cooling Cycle 750℃ Temperature (℃) 800 600℃ 600 400 200 0 4 8 12 Hours 16 20 24 Figure 8 : Oxidation Increase/Decrease by 600℃ and 750℃ Heating/Cooling Cycles 600℃ 750℃ 100 Oxidation Increase/Decrease (g/m2) 50 TI-25CQ (MSA-80) SUS430 SPC (Cold-rolled steel sheet) Galvanized sheet Galvannealed sheet TI-25CQ 30 10 -10 -20 SUS430 2 5 10 Number of Cycles -30 -50 -70 -100 -200 Galvannealed sheet -300 -500 15 Nisshin Steel Quality Products Galvanized sheet SPC ■ Properties ■ 2.Heat Reflectivity Alstar possesses not only a finely finished surface, but also excellent heat reflectivity. Because Alstar has a very high thermal efficiency, it is useful for making highly effective heat reflecting plates for toasters, ovens, driers, and other consumer durables. For reference, here is a surface luster comparison of Alstar with other steel sheets. Table 10 Surface Finish Surface Luster(%) Surface Roughness(μ) Alstar Type Dull 15 Hmax 8 to 9 Stainless steel sheet 2B 15 Hmax 1.2 Stainless steel sheet BA 60 Hmax 0 Cold-rolled steel sheet coated with silver paint Dull 6 Hmax 8 Notes : 1. Surface luster measured(with gloss meter Model GM-3)in conformity with JIS 8741. 2. 1/10 light filter Gs(60)is used. 3.Corrosion Resistance Aluminum has a more active ionization trend than Mn, Mo, Cr, W, Cd, Fe, and Zn and is more easily corroded. Because aluminum has the characteristic of easily forming a fine oxide film when exposed to air, or a hydroxide film when exposed to water, a corrosion resistance effect by galvanic action, such as is exhibited in galvanized sheet, cannot be expected. Because aluminum's oxide film is stable, the aluminum coated surface of Alstar is considerably more corrosion-resistant than that of galvanized sheet except in certain environments. The corrosion resistance of Alstar under various conditions is shown in the following pages. (1) Corrosion resistance in various pH solutions Unlike zinc, aluminum is relatively resistant to weak acids but not to alkalis. The corrosion resistance of aluminum in pH solutions is as shown in Figure 9. Figure 9 120 110 100 90 80 Alstar (room temperature) Corrosion (g/m2/day) 130 Corrosion resistance in pH Solutions Alstar (60℃) Galvanized sheet (room temperature) Galvanized sheet (60℃) Source : Metal Surface Technology Vol.7, No.7. 70 60 50 40 30 20 10 1 2 3 4 Acidity 5 6 7 pH 8 9 10 11 12 13 14 Alkalinity Nisshin Steel Quality Products 16 ■ Properties ■ (2) Saltwater spray test Aluminum shows a lower potential than iron in saltwater and, in an Fe-Al electrolyte cell with an aluminum anode and steel cathode, the aluminum, as a sacrificial anode, protects the steel from corrosion. Table 11 shows the results of a continuous saltwater spray test on Alstar. Table 11 Pretest Treatment TI-25DQ Alstar (MSA-80 Drawing Quality) Other manufacturers' electro-galvanized sheet 24 Hours 72 Hours 240 Hours 360 Hours Red rust in 384 hours Room temperature 250℃×24 hours Room temperature 250℃×24 hours Red rust 10% Red rust 60% Red rust 60% Red rust 90% Red rust 100% (3) Atmospheric exposure test Aluminized steel sheet develops oxides on the aluminum surfaces when exposed to air, but the stable oxides protect the aluminum layer and prevent discoloring of the surfaces. Exposed steel parts, such as cut sections and pinholes, however, develop red rust. If Cl− is present in a wet state, as in seawater, for example, the oxidized aluminum film is destroyed and starts a sacrificial corrosion protection action. Because aluminum has a lower electrolytic solubility than zinc, aluminized steel sheet has greater corrosion resistance in, for example, coastal areas.[If the coating mass is the same, the ratio is said to be five or six(aluminum)to approximately one(zinc) ] . (4) Resistance to chemicals Alstar has less resistance to alkaline industrial chemicals, but greater resistance to acid industrial chemicals than galvanized sheet. Table 12 Chemicals Light oil Alstar Galvanized Sheet E G Palm oil E E Machine oil E G Boiled oil E E Spindle oil E E Glycerine E E Formalin F G Alcohol G G Acetone E E Carbon tetrachloride E E Coal tar E E Printing ink E E Phthalide E G Aqueous ammonia P F 5% caustic soda P F 5% nitric acid F P 5% sulfuric acid P P 5% acetic acid F P 17 Nisshin Steel Quality Products Note : Evaluation scale : E = Excellent G= Good F = Fair P = Poor ■ Properties ■ (5) Resistance to automobile exhaust gas Alstar demonstrates good corrosion resistance in auto exhaust part uses. The results of an exhaust gas test by the Chrysler Corporation of the U.S. are shown in Table 13. Table 13 Decrease in Mass(g) Decrease in Thickness (converted from the mass decrease) R in. mm TI-25DQ Alstar(MSA-80 Drawing Quality) − x 0.260 0.011 0.0007 0.018 TI-25CQ Alstar(MSA-80 Commercial Quality) 0.191 0.035 0.0005 0.013 Notes : 1. Test method: Chrysler's spec. 461H-83. 2. Test outline: (a)A mixed solution of 180° F(82℃)0.01N hydrobromic acid and 0.05N sulfuric acid was used for the test. (b)Cold muffler conditions. After immersing the test pieces in the test solution for five seconds, they were kept over the solution surface for one hour. This was repeated 20 times(20 hours) . (c)Hot muffler conditions. Then the test pieces were heated in a furnace at 1,000° F(538℃)for two hours. (d)Steps(b)and(c)were repeated for 240 hours. 3. Test results judgment: (a)Amounts of decrease before and after the test were measured. (b)Decreased amounts were converted into decrease in sheet thickness. (c)Converted sheet thickness decrease must be less than 0.002 in.(0.051mm) . 4. Test results: The test simulated a running Chrysler car. Sheet thickness decreased in inverse proportion to aluminum coating mass Alstar passed this test. Nisshin Steel Quality Products 18 ■ Properties ■ 4.Weldability Alstar differs slightly from cold-rolled steel sheet under welding conditions. Since aluminum is soft, flexible and has good electric conductivity, aluminized steel sheet generates less heat at welds than cold-rolled steel sheet. Alstar does not require as high a current as galvanized sheet due to the aluminum coating which has a higher melting point, less fluidity, and less spread of molten area. Conditions for spot, seam, and other kinds of welding are given below. (1) Spot welding Table 14 shows an example of spot welding conditions for Alstar. Table 14 : MSA-40 Commercial Quality Electrode Face Time ( ) Thickness (mm) D R Electrode Force (N) 0.6 16 25 1,800 9 8,700 1,900 0.8 16 25 2,000 10 9,500 2,500 1.0 16 50 2,500 11 10,500 4,100 1.2 16 50 3,100 12 12,000 5,900 1.4 16 50 3,900 14 13,000 7,800 2.0 16 50 5,400 18 14,000 12,700 Current (A) Shear Strength (N) Note : With a low welding current, sufficient strength cannot be expected. With an overcurrent, the aluminum coating deteriorates more than necessary and dark gray stripes appear around welds. Suitable welding conditions between these extremes must be selected. The scope of correct welding conditions narrows in inverse proportion to sheet thickness. Chromium copper alloy electrode tips may be used and, as with galvanized sheet, aluminum pickup poses a problem. Good water-cooling to minimize pickup and periodic dressing are necessary. As in the case of welding mild steel, radius-face tips or truncated cone face(120°to 140° )tips are recommended. Figure 10 shows the results of a spot welding test on MSA-40 and MSA-80, which differ in aluminum coating mass. While MSA-40 shows a sharp drop in shear strength after approximately 900 spot welds, MSA-80 develops the same phenomenon after approximately 600 spot welds. proximately 600 spot welds. Figure 10 : Electrode Life in Spot Welding Alstar MSA-80 1.0mm MSA-40 1.0mm (Commercial Quality) 9,800 8 6 Shear Strength (N) Diameter of Electrode Force Mark (mmφ) 8,800 7,800 6,900 9,800 8,800 7,800 6,900 Shear strength 5,900 5,900 4,900 4,900 3,900 3,900 8 2,900 2,900 6 2,000 4 1,000 2 0 0 4 2,000 2 1,000 0 0 Diameter of electrode force mark 0 100 200 300 400 500 600 Number of Welds Notes : Welding conditions: Welding current: 11,200A to 14,500A. 19 Nisshin Steel Quality Products Electrode force: 2,000N Welding time: 7 . 700 800 900 1,000 ■ Properties ■ (2) Seam welding Table 15 shows an example of seam welding conditions for Alstar. Table 15 Time Thickness (mm) Electrode Width (mm) Electrode Force (N) On Off Welding Speed (cm/min.) Current (A) 0.8 7 3,900 3 2 150 17,000 to 19,000 0.95 7 4,200 3 3 150 16,000 to 18,000 0.95 7 4,200 3 2 230 18,000 to 21,000 1.2 7 4,400 3 2 150 18,000 to 20,000 1.2 7 4,900 4 2 230 18,000 to 21,000 (3) Gas welding and arc welding Gas welding is difficult and requires a certain amount of skill. It is recommended that a two-stage regulator be used for assuring the correct gas flow. Use killed steel wire for satisfactory results. Flux for stainless steel is suitable for the purpose. Shielded arc electrodes may be used for arc welding, but care must be taken in selecting the right kind of electrode. Ilmenite or high titanium type electrodes produce blow holes. For the best results, select a low hydrogen type electrode. If a corrosionresistant characteristic is required, use stainless steel. When oxidation of welds must be reduced to a minimum, argon arc welding(TIG)produces good results. Tables 16 and 17 show examples of arc welding and TIG welding. Table 16 : Example of Arc Welding Weldability JIS Rating of X-ray Results Tensile Strength (N/mm2) Elongation (%) D4313 Poor 6 387 24.2 Weld D4316 Good 1 368 28.9 Base metal 1.2 D30816 Stainless steel Excellent 1 379 28.0 Base metal 1.2 D4316 Good 1 327 28.4 Base metal Thickness (mm) Welding Rod T1-25CQ MSA-80 Commercial Quality 1.2 1.2 SPCC Sheet Welded Rupture Point Table 17:Example of TIG Welding Sheet Welded Thickness (mm) T1-25CQ MSA-80 Commercial Quality 1.6 Welding Rod Welding Current Weldability JIS Rating of X-ray Results Tensile Strength (N/mm2) Elongation (%) Rupture Point GA(gas-welding rod for mild steel) AC Poor 2 380 24 Base metal DM-2(gas-welding rod for Si-Mn alloy) AC Good 1 389 28 Base metal D308(18-8 stainless steel rod) AC Good 1 393 24 Base metal GA DC Poor 4 400 24 Base metal DM-2 DC Good 1 380 28 Base metal D308 DC Excellent 1 398 26 Base metal Notes : 1. Argon gas flow rate: 6 l/min 2. AC power source: Pure tungsten electrode 3.2φ 3. DC power source: Thorium-containing tungsten electrode 3.2φ (4) Weld repairs Welds and damaged aluminum coating can be repaired with silver paint or with molten aluminum spray. Nisshin Steel Quality Products 20 ■ Properties ■ 5.Formability Aluminized steel sheet is generally said to have poor formability as compared with cold-rolled and galvanized sheet because it has a hard alloy layer of steel and aluminum between the base metal and the aluminum coating. However, Alstar offers good formability comparable to other steel sheets if proper consideration is taken of its characteristics. (1) Deep drawing (a)Die and punch radii and clearances must be used where appropriate to prevent aluminum exfoliation on the parts pressed by deep drawing. (b)Die radii 6t to 10t and punch radii similar to those used in cold-rolled steel sheet drawing may be used, although the figures vary with forms to be drawn. A clearance of about 1.2t is appropriate. (c)If redrawing is necessary, a drawing ratio of more than 60 percent is recommended per drawing. A sample(0.55mm)formed by a 6 ton cushion pressure (2) Burring (a)The hole enlarging ratio of Alstar ranges from 0.3 to approximately 0.8, depending on the forming process (This compares with 0.5 to 0.9 for cold-rolled steel sheet) . (b)The hole enlarging operation can be improved by observing the following instructions: ・Direct burrs inward. ・Use an enlarging punch that has a greater taper. ・Add embossing during the enlarging process. An example of hole enlarging and drawing is shown below. Drawn sample(1.2mm)auto muffler end plate 21 Nisshin Steel Quality Products ■ Properties ■ 6.Paintability Alstar requires chemical treatment before painting to assure good adhesion of paint. (1) Pretreatment Degreasing alone is insufficient to assure good adhesion. For the best results, the following process is recommended. Degreasing ・Take note of pH. ・Use trichloroethylene or other neutral chemicals. Chemical Treatment Painting ・Chromate treatment or phosphate treatment is recommended. (2) Paint The same paint as used in painting other steel sheets may be used for Alstar if it is pretreated. To obtain satisfactory corrosion resistance, adhesion and other qualities, the right paint for the intended use should be selected. The following are examples of paint that may be used for Alstar: ・Vinyl resin paint. ・Silicon resin paint. ・Polyurethane resin paint. ・Phenol resin paint. ・Alkyd resin paint. ・Lacquer. 7.Food Sanitation The aluminum coating consists of aluminum, silicon and iron. Tests conducted by prefectural governments in Japan, under the Food Sanitation Law, have proved that even if these elements enter the human body, they are harmless and will be completely discharged. An example of analysis of the aluminum coating of a utensil made from Alstar is shown below. Aluminum(77.2%) Silicon(7.4%) Iron(15.4%) Caution : Chromate treatment for preventing white rust on the aluminum surface is harmful, and therefore only oiling without chromate is recommended. Nisshin Steel Quality Products 22 Steel Pipe Alstar steel pipe is made from Alstar steel sheet by high-frequency welding. It has all the features of Alstar steel sheet. Being highly heat resistant, Alstar steel pipe is used in large quantities in the automobile industry as exhaust pipe. 1.Features 1)Evenly coated with aluminum 2)Thin aluminized Alstar steel pipe is available. 3)Highly heat resistant 4)High workability 5)Excellent weldability 6)Smooth, aesthetically pleasing surface 2.Quality (1) Appearance Alstar steel pipe has an aesthetically pleasing surface peculiar to aluminum. Bare metal is exposed on the outer surface of welded joints in an area 3mm to 5mm wide after bead cutting but can be aluminized to order. Slight beads are built on the inner surface of welded joints but can be cut away as necessary. (2) Workability Alstar steel pipe has the same workability as the JIS G3445 machine-structure carbon steel pipe STKM-11A. (3) Effect of pipe production on aluminum coats Pipe production has little if any detrimental effect on the aluminum coating of Alstar steel sheet. (4) Corrosion resistance of welds Since bare metal is exposed at the welds after bead cutting, rust forms at an early stage of the salt spray test. Alstar steel pipe is generally used unfinished after bead cutting as heat-resistant parts but has not posed any problem in such applications. 3.Mechanical properties Typical mechanical properties of Alstar steel pipe made of MS-40(drawn material)are shown in Table 18. 23 Nisshin Steel Quality Products ■ Steel Pipe ■ Table 18 Test Piece Size 35.0 φ×1.2mm 38.1 φ×1.2mm 42.7 φ×1.2mm Number of Test Cycles Tensile Test Flattening Test (2/3D) Flaring Test Bending Test (3D) 45 Good 1.39 ─ ─ Good 1.38 ─ 46 Good 1.39 Creases occurred Tensile Strength (N/mm2) Elongation (%) 1 366 2 ─ 1 361 2 ─ ─ Good 1.30 ─ 1 362 45 Good 1.37 ─ 2 ─ ─ Good 1.40 ─ Notes : 1. Tensile test: JIS No.11 test piece 2. Flattening test: 2/3D, the welded portion is placed at right angles to the direction of compression. 3. Flaring test: Using a 60°cone punch, pipe end openings are widened until cracks occur. 4. Flaring ratio: Diameter after flaring/initial diameter Table 19: Available Dimensions of Alstar Steel Pipe Outside Diameter or Side Length (mm) Length (mm) 0.6∼2.3 12.7∼63.5 3,500∼6,100 0.8∼2.0 16×16∼25×25 Thickness (mm) Round Pipe Sharp Edge Square Pipe Rounded Edge Square Rectangle 0.8∼2.3 22×10∼60×30 Square 0.8∼2.3 25×25∼50×50 Rectangle 0.8∼2.3 25×12∼60×30 3,500∼6,000 Note : Dimensions other than those listed above can be negotiated. Nisshin Steel Quality Products 24 Extracts from ASTM A 463-83 Standard Specification for Steel Sheet, Cold-Rolled, Aluminum-Coated Type 1 1. Scope 1.1 This specification covers aluminum-coated steel sheet Type 1 in coils and cut lengths coated with an aluminumsilicon alloy by the hot-dip process. The aluminum-silicon alloy for coating has 5% to 11% silicon added to promote better adherence. It is intended principally for heat-resisting applications and also for uses where corrosion resistance and heat are involved. The weight of coating expressed as the total coating on both sides may be specified in accordance with Table 1. Aluminum-coated steel sheet is available in the following quality designations: Commercial Quality, Drawing Quality, Drawing Quality Special Killed, and Structural(Physical)Quality. Notes : 1. values stated in U.S. customary units are to be regarded as the standard. 3. Description of Terms 3.1 Quality Designations: 3.1.1 Commercial Quality -This material is intended for parts where bending, moderate forming, or moderate drawing may be involved. 3.1.2 Drawing Quality -This material is intended for fabricating identified parts where drawing or severe forming may be involved. Care should be taken to ensure that the coating designation is compatible with the end use. 3.1.3 Drawing Quality Special Killed -This material is intended for fabricating identified parts where particularly severe drawing or forming may be involved or essential freedom from aging is required. Care should be taken to ensure that the coating designation is compatible with the end use. 3.1.4 Structural(Physical)Quality-This material is produced when mechanical properties are specified or required. Such properties or values include those indicated by tension, hardness, or other commonly accepted mechanical tests. Care should be taken to ensure that the coating designation is compatible with the end use. 4. General Requirements for Delivery 4.2 Aluminum-coated steel sheet shall be ordered to a decimal thickness for both coils and cut lengths. The thickness is the total of the base metal and the coating. 25 Nisshin Steel Quality Products 8. Mechanical Requirements 8.1 Base Metal Bend Test-Commercial quality(CQ) , drawing quality(DQ) , or drawing quality special killed (DQSK) shall be capable of being bent at room temperature in any direction through 180 deg. flat on itself without fracturing of the base metal. Bend test requirements for structural(physical) quality are subject to negotiation. 9. Coating Tests 9.1 Weight of Coating: 9.1.1 The weight of coating shall conform to the requirements for triple- and single-spot minimum checks prescribed in Table 1 for the specific coating designation. The weight of coating is the total amount on both sides of a sheet, expressed in ounces per square foot(or grams per square meter)of sheet. 9.2 Coating Bend Test: 9.2.1 For all qualities other than structural(physical) quality, the bend test specimens of coated metal shall be capable of being bent through 180 deg. over a diameter equal to twice the thickness in any direction without flaking of the coating on the outside of the bend only. A handoperated vise with smooth jaws should be used for making the tests, unless excessive thickness makes this impractical. Any other method used to make the bend test should not involve impact. Flaking of coating within 1/4 in.(6.4mm)of the edge of the bend specimen shall not be cause for rejection. Bend tests are not required of coils or cut lengths ordered extra-smooth or stretcher-leveled. This Standard is issued under the fixed designation A 463; the number immediately following the designation indicates the year of original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. TABLE 1 Coating Designation and Minimum Coating Test Limits for Aluminum-Coated Steel Sheet Type1 Note : The weight of coating in ounces per square foot and coating thickness in inches refer to the total coating on both surfaces. The coating designation is the term by which this product is specified. Triple-Spot Test Total Both Sides Coating Designation a Single-Spot Test Total Both Sides TI 40(regular) oz/ft2 0.40 g/m2 120 oz/ft2 0.30 g/m2 90 TI 25(light) 0.25 75 0.20 60 Calculated Coating Thickness Based on Minimum Single Spot Test,a in. 0.0013 0.0008 Calculation based on aluminum density of 0.0975 lb/in. 11. Dimensions, Weights, and Tolerances 11.1 Aluminum-coated steel sheet is produced to decimal thickness only. The density of aluminum is 0.0975 lb/in. as compared to that of zinc which is 0.258 lb/in.; hence, the weight equivalents are different. Table 3 gives the thickness and weight equivalents of aluminum-coated steel sheet Type1. 11.2 Thickness tolerances and all other dimensional tolerances are given in Tables 4 through 16. TABLE 4 Thickness Tolerances of Aluminum-Coated Steel Sheet Type1 Notes : 1. Thickness is measured at any point across the width not less than 3/8 in. (9.5mm)from a side edge. 2. Regardless of whether total thickness tolerance is specified equally or unequally, over and under, the total tolerance should be equal to twice the tabular tolerance. Thickness Tolerances for Widths and Thicknesses, Over and Under, in. Specified Width, in. Specified Thickness, in. Over 0.101 to 0.187, incl Over 0.075 to 0.101, incl Over 0.061 to 0.075, incl Over 0.043 to 0.061, incl Over 0.023 to 0.043, incl 0.023 and thinner To 32 incl 0.008 0.007 0.006 0.005 0.004 0.003 Over 32 to 40, incl 0.008 0.008 0.006 0.005 0.004 0.003 Over 40 to 60, incl 0.009 0.008 0.006 0.005 0.004 0.003 TABLE 5 Width Tolerances of Aluminum-Coated Steel Sheet Type1(Coils and Cut Lengths Not Resquared) Specified Width, in. (mm) Over 12(300)to 30(760) , incl Tolerance Over Specified Width, No Tolerance Under Appendix A1. Metric Equivalents A1.1 The metric equivalents for the tolerances given in the tables are shown in Table A1. TABLE A1 Metric Equivalents a in. mm 1/8 3.2 in. mm in. 0.0254 3/16 4.762 6.350 mm Over 30 to 48(760 to 1,220) , incl 3/16 4.8 0.001 Over 48 to 60(1,220 to 1,520) , incl 1/4 6.4 0.005 0.127 1/4 0.010 0.254 5/16 7.938 0.050 1.270 3/8 9.525 0.100 2.540 1/2 12.700 0.200 5.080 3/4 19.050 1/16 1.588 7/8 22.225 1/8 3.175 1 25.400 a Conversion factor : 1 in.×25.4=mm. Nisshin Steel Quality Products 26 www.nisshin-steel.co.jp JAPAN Registered Head Office Shinkokusai Building, 4-1, Marunouchi 3-chome, Chiyoda-ku, Tokyo 100-8366, Japan Telephone:(81-3)3216-5530 Facsimile:(81-3)3216-5747 OVERSEAS Singapore Representative Office 16 Raffles Quay #20-01, Hong Leong Bldg., Singapore 048581 Telephone:(65)6221-1277/8 Facsimile:(65)6224-2357 Bangkok Representative Office Unit 6, 35th Floor, CRC Tower All Seasons Place, 87/2 Wireless Road, Phatumwan, Bangkok 10330, Thailand Telephone:(66)2-654-0783 Facsimile:(66)2-654-0981 Guangzhou Representative Office Room 1505, Office Tower, CITIC Plaza, 233 Tian He North Road, Guangzhou 510613, P.R.China Telephone:(86)20-3877-1054 Facsimile:(86)20-3877-1094 Subsidiary Nisshin Steel USA, LLC 1701 Golf Road, Continental Tower3, Suite1004, Rolling Meadows, IL 60008 U.S.A. Telephone:(1-847)290-5100 Facsimile:(1-847)290-0826 Tsukiboshi (Shanghai) Steel Treading Co.,Ltd. Shanghai Maxdo Centre 3208-3210, 8 Xing Yi Road, Hongqiao Development Zone, Shanghai 200336, P.R.China Telephone:(86-21)5208-0736 Facsimile:(86-21)5208-0639 Notice Technical information in this booklet, while every reasonable effort was made to ensure the accuracy at the time of this publication, is general information relating to our products only and is not meant as any warranty, expressed or implied. Such technical information does not guarantee that any of our products are suitable for your particular application or purpose. Use of any information contained in this booklet shall be at user's risk. Any information in this booklet is subject to change without prior notice. Please contact Nisshin Steel office for updated information. Printed in Japan on recycled paper R-03 '07.01