Polycarbonate: A Preferred Material Choice for LED Lighting Applications By William Marshall, Sr. Account Manager LED Lighting, Styron, Berwyn, Pa. Introduction Light Emitting Diodes (LEDs) have clearly emerged as the premier choice in lighting solutions. Government regulations and consumer preference for more environmentally conscious, energy efficient products have caused manufacturers to develop solutions for the marketplace that offer new levels of energy efficiency, durability and long life. While the technology has evolved, so have the materials that go into the finished product. Plastic – especially polycarbonate – has become the “material of choice” because of its one-of-a-kind properties and the versatility it provides. The needs of manufacturers and fabricators for LED lighting components are extremely complex and typically include a variety of considerations such as: Protecting the costly LED light source Ensuring top notch ignition resistance Providing for long term heat stability Meeting industry regulations and standards Accommodating movement and jarring Balancing clarity and diffusion Meeting thermal requirements Offering great design freedom and light weighting of parts Very few materials can fulfill these needs. Polycarbonate and various polycarbonate blends are now seen in a variety of LED applications because they have the balance of properties to meet these demanding and varied requirements. This white paper discusses the components and modules of LED lighting applications that utilize these materials as well as important considerations when selecting a plastic resin. It focuses on the benefits of polycarbonate and polycarbonate compounds and blends and why manufacturers and molders alike consider the material to be an ideal choice to use in LED lighting. Components, Modules & Key Properties One can find plastics in virtually all areas of LED applications. The three areas where plastic resins are especially well suited include: Coverings, the lenses, optics, light pipes, diffusers, signage, and recessed troffer lighting Housings and Enclosures, which include luminaires LED Reflectors, the parts made of high reflectivity materials that are designed to maximize light output by directing the light emitted from an LED light source These components all have very specific performance requirements ranging from maximizing light output to support high efficacy, providing excellent LED light hiding capabilities and uniform diffusion, offering superior ignition resistance to meet demanding UL requirements, and ensuring premium aesthetics. Polycarbonate is often considered an ideal starting point. It has the basic properties needed in LED applications and successfully can be customized to meet very specific performance requirements. Some of the important properties which polycarbonate offers include: Durability Durability is the starting point for LED light source protection. What is needed is a material that is extremely tough. Since the LED light source itself, a solid-state semiconductor, is more robust than traditional incandescent light sources, the materials used to cover the source should be at least as resilient as the light source itself. Polycarbonate is much more impact resistant and is less prone to breakage than other available materials. It has outstanding toughness, even over a wide temperature range. Polycarbonate, which is often used for items such as riot shields, aircraft canopies, and impact resistant panels, can withstand tremendous impact. Due to this outstanding toughness, polycarbonate is easier to work with and less prone to breakage or chipping when cutting the material into shapes. In many applications, it is possible to down-gauge or decrease the thickness of a fabricated part when using polycarbonate versus another material. This results in part-weight and material-cost reductions, which offer a more environmentally-friendly solution due to the fact that less product is being used and a reduced amount of energy is needed. Optical properties An LED can be a very bright, unidirectional source, and manufacturers need materials that either make it possible for the light to shine directly through a surface for maximum brightness, or provide uniform light distribution with no evidence of the light source, for a more diffused effect. It often is a careful balance to adjust properties, because material additives for light diffusion can impact light transmission, and vice versa. The covering of an LED source regulates the amount of light that is transmitted or diffused. Customers look for a material that offers high clarity and high purity to ensure the optimum light transmission possible. Depending on the application, manufacturers are also concerned with the uniformity of light distribution. Polycarbonate can be tailored to specific needs for an application through the compounding process. Light transmission greater than 90 percent can be achieved for transparent polycarbonate resins. For 2 polycarbonate resins containing a light diffusion additive, excellent light uniformity can be achieved over the entire surface of the part while hiding the bright LED light source, eliminating “hot spots.” UV Stability Exposure to a light source has the potential to compromise the properties of a material. In an LED environment this exposure can come from two directions -- the LED source itself, and also from the natural light of the sun. It should be noted that for LED white light sources, typically a blue LED coated with a yellow phosphor is used which results in the emission of white light. LED sources of this nature have little or no UV emission. Compared to traditional light sources such as fluorescents, incandescent, HID, the LED source causes much less UV degradation of plastics materials used as lenses. The major concern with UV exposure for LED applications is in outdoor use when exposed to sunlight. This constant exposure can result in degradation of properties over time. This makes it especially important to select the right material for LED applications, and when formulating materials, to properly UV stabilize the product to minimize the impact of this phenomenon. Polycarbonate offers a number of methods to do this including additives and layered films in extruded product. Clearly the selection of a material is complex and a number of factors must be considered to ensure the right solution for LED lighting applications. Polycarbonate, understandably, is a leading material choice because it has effectively addressed some of the most difficult challenges of the LED lighting industry. Thermal Stability Lighting applications generate heat, and the proximity of the material to the light source determines the thermal properties needed. While LED lights are considered energy efficient, they still generate heat, particularly for the higher powered LED light sources where operating temperatures can reach 80 – 110 degrees C. For optics and lens applications requiring close contact to the LED source, a material with excellent thermal stability is required. Polycarbonate resins offer superior thermal stability compared to acrylic resins and can be used for continuous use temperatures up to 120 degrees C. Ignition Resistance The requirement for ignition resistance, or flame retardancy, depends on the UL codes governing the materials used for enclosures / lenses for the specific LED lighting application. High powered LED light sources operate at temperatures as high as 80 – 110 degrees C. Polycarbonate resins offer superior ignition resistance for these types of operating conditions. For lower voltage applications using Class 2 power sources requiring UL 94 HB and V-2 flammability requirements, polycarbonate, acrylics and styrenic-based resins such as SAN can be considered as materials for lenses, covers, and optics. For more demanding LED lighting applications where Class 1 power sources are used, the materials requirement for optics and lenses is UL V-0 and, in some cases, UL 5VA. 3 Polycarbonate is among the only transparent plastic resins that offer the light transmission, thermal stability, and ignition resistance required for these demanding applications at a reasonable cost. Design Flexibility One of the advantages of LED lighting is the freedom it offers manufacturers to be creative in their product designs. Unlike traditional incandescent lighting, the lighting industry is no longer restricted in aesthetic configuration. Plastics materials used for housing or covering the LED source can be formed into countless shapes and sizes by shaping resins/materials through injection molding, injection blow molding, profile extrusion and sheet extrusion/thermoforming processes. Polycarbonate offers this processability option with a wide range of products available for specific processing requirements. In addition, because of the relative strength and toughness of polycarbonate, parts can be down-gauged for weight, energy and cost savings. Compounds & Blends Clearly polycarbonate is a good base. It can be combined with other monomers, polymers or additives to achieve the proper balance of properties. A user can maintain the primary properties of the material while customizing the formulation to exacting requirements. As an example, various components of an LED application, particularly housings and luminaire enclosures, require opaque materials, often with demanding UL flammability requirements. Opaque plastics block all light from passing through them and provide an aesthetically-pleasing outer covering for the LED light source. While polycarbonate is transparent in its natural state, it can take on an opaque appearance when combined with various additives or another material, such as ABS. Ignition resistant PC and PC/ABS are ideal housing materials for LED applications, capable of attaining UL 5VA flammability ratings, providing heat resistance and offering excellent processability into complex shapes. Another example is in the area of reflective materials. Since LED sources are unidirectional, it is important to have a material that will direct the light emitted from the LED light source to maximize light output and minimize light loss. Additionally reflective resins must be designed with long-term heat performance properties to ensure product safety. Polycarbonate is an excellent material for this purpose. Polycarbonate reflective materials can achieve greater than 96 percent reflectivity. As always, and in summary, it is important to consider an application in its entirety while choosing materials. Careful analysis of an application will save money in the long run. By focusing on the total system cost, materials can be selected for specific components and modules preventing over engineering and providing for the most cost-effective solution. About Styron 4 Styron is a leading global materials company and manufacturer of plastics, latex and rubber, dedicated to collaborating with customers to deliver innovative and sustainable solutions. Styron’s technology is used by customers in industries such as home appliances, automotive, building & construction, carpet, consumer electronics, consumer goods, electrical & lighting, medical, packaging, paper & paperboard, rubber goods and tires. Styron had approximately USD 5.5 billion in revenue in 2012, with 20 manufacturing sites around the world, and 2100 employees. More information can be found at www.styron.com. ©2014 5