2276 IEEE TRANSACTIONS ON ELECTRON DEVICES, VOL. 45, NO. 11, NOVEMBER 1998 Small-Scaled InGaP/GaAs HBT’s with WSi/Ti Base Electrode and Buried SiO Tohru Oka, Member, IEEE, Koji Hirata, Kiyoshi Ouchi, Hiroyuki Uchiyama, Kazuhiro Mochizuki, and Tohru Nakamura, Senior Member, IEEE Abstract—This paper describes the fabrication and characteristics of small-scaled InGaP/GaAs HBT’s with high-speed as well as low-current operation. To reduce both the emitter size SE and the base–collector capacitance CBC simultaneously, the HBT’s are fabricated by using WSi/Ti as the base electrode and by burying SiO2 in the extrinsic base–collector region under the base electrode. WSi/Ti simplifies and facilitates processing to fabricate a small base electrode, and makes it possible to reduce the width of the base contact to less than 0.4 m without the large increase in the base resistance. The DC current gain of 20 is obtained for an HBT with SE of 0.3 2 1.6 m2 due to the suppression of emitter size effect by using InGaP as the emitter material. An HBT with SE of 0.6 2 4.6 m2 exhibited fT of 138 GHz and fmax of 275 GHz at IC of 4 mA; and an HBT with SE of 0.3 2 1.6 m2 exhibited fT of 96 GHz and fmax of 197 GHz at IC of 1 mA. These results indicate the great potential of these HBT’s for high-speed and low-power circuit applications. Index Terms—Gallium materials, heterojunction bipolar transistors. I. INTRODUCTION G aAs-BASED heterojunction bipolar transistors (HBT’s) are more attractive for high-speed applications than Si bipolar-junction transistors (BJT’s) due to their superior carrier transport properties [1]. To date, GaAs-based HBT’s over 100 GHz [2] and high with high cutoff frequency over 200 GHz [3], [4] maximum oscillation frequency have been reported. However, these HBT’s have considerably large device dimensions compared to self-aligned and highspeed Si BJT’s [5]–[7]. This causes large power dissipation and thermal-management problems when they are applied in integrated circuits. On the other hand, small-scaled GaAsbased HBT’s whose emitter sizes were equal to or smaller than 1 m have been reported [8]–[10]. However, their highfrequency characteristics were degraded in decreasing emitter size. The main reason of this is the large base–collector capacitance resulting from the large base–collector junction area. To achieve high-speed and low-power operation in HBT’s, therefore, it is essential to reduce both the emitter size and the parasitic capacitance simultaneously. The conventional method to reduce the parasitic capacitance of the base–collector junction is proton- or oxygen-ion implantation into the region under the extrinsic base [11], [12]. Manuscript received March 17, 1998; revised June 15, 1998. The review of this paper was arranged by Editor M. F. Chang. T. Oka, K. Ouchi, H. Uchiyama, K. Mochizuki, and T. Nakamura are with the Central Research Laboratory, Hitachi, Ltd., Tokyo 185-8601, Japan. K. Hirata is with Hitachi ULSI Systems Coompany, Tokyo 185-8601, Japan. Publisher Item Identifier S 0018-9383(98)07993-3. Fig. 1. Schematic cross section of the HBT with a WSi/Ti base electrode and buried SiO2 : This compensates the relatively low doping of the collector and thus fully depletes the extrinsic collector. However, the dielectric constant of the implanted regions are still as large as that of GaAs, and this limits the reduction of the parasitic capacitance. Ion implantation also induces the increase of the base resistance [13], which also degrades high-frequency characteristics. In this paper, we describe high-performance InGaP/GaAs HBT’s capable of high-speed as well as low-current operation. In the HBT’s, simultaneous reduction of emitter area and base–collector capacitance were achieved by using WSi/Ti as the base electrode and by burying SiO in the extrinsic base–collector region under the base electrode. Excellent high-frequency characteristics at low collector currents are demonstrated in small-scaled HBT’s. II. DEVICE STRUCTURE The schematic cross section of the device structure is illustrated in Fig. 1. The structure has two main features. First, the width of the base contact is reduced to 0.3 m by using a self-aligning process, and the extrinsic base–collector region is buried by SiO The buried SiO reduces the parasitic capacitance under the base electrode because the dielectric constant of SiO is about 1/3 of that of GaAs [14]. Narrowing the width of the base contact decreases the base–collector junction area and thus reduces the base–collector capacitance. Second, WSi/Ti is used as the base electrode. These materials have definite advantages over the conventional gold-based electrode metals. Both WSi and Ti can be deposited by a sputtering method with good step coverage and selectively patterned on GaAs and SiO by using reactive ion etching (RIE). This simplifies and facilitates processing to fabricate a small base electrode. In addition, a thin Ti film inserted between WSi and p-type GaAs effectively reduces the contact 0018–9383/98$10.00 1998 IEEE OKA et al.: SMALL-SCALED InGaP/GaAs HBT’S 2277 Fig. 3. Calculated results of the product of base resistance RB and base–collector capacitance CBC as a function of base–contact width WBC : B. Optimization of Contact Width Fig. 2. Specific contact resistance for WSi and WSi/Ti as a function of carrier concentration in p-GaAs layers. resistance compared to using WSi only. This suppresses the large increase in the base resistance that occurs when reducing the width of the base contact, and therefore, makes it possible to achieve much higher frequency performance than in our earlier work [15]. III. CHARACTERISTICS AND OPTIMIZATION OF BASE CONTACT In advance of the device fabrication, we investigated the influence of Ti insertion on the contact resistance for the base. We also estimated the optimum width of the base contact for and high designing HBT’s with both high cutoff frequency maximum oscillation frequency A. Influence of Ti Insertion between We evaluated the specific contact resistance GaAs and the ohmic metals of WSi or WSi/Ti by using transmission line model (TLM) measurement [16], [17]. WSi(300 nm)/Ti(5 nm) or WSi(300 nm) films were deposited by sputtering method on 30-nm-thick p-GaAs actual HBT base layers. These were not alloyed after deposition. The composition ratio of WSi was 0.3 and the sheet resistance of the 300-nm-thick WSi was about 7 The specific contact resistance as a function of the base carrier concentration is shown in Fig. 2. The dashed lines are the calculated theoretical curves based on a tunneling model [18]. These calculations were carried out for various potential assuming that the effective tunneling hole barrier heights where is the free electron mass. The of mass is of 0.8 eV at lower carrier WSi fits the theoretical curve for concentration and it deviates as the carrier concentration of WSi/Ti, in contrast, agrees well with the increases. The of 0.6 eV at any carrier concentration. The value curve for is about one order of magnitude lower than that of WSi. At 10 cm for example, a carrier concentration of 1 was reduced from 2 10 cm to 3 10 cm . This result indicates that an inserted thin Ti film effectively decreases the potential barrier height and thus dramatically reduces the contact resistance. decreases Narrowing the width of the base contact and thus increases both the base–collector capacitance and maximum oscillation frequency cutoff frequency However, it simultaneously increases base resistance which degrades This means that has an optimum and Thus, we estimated value for both high dependence of the product of and In this estimation, the dependence was calculated by assuming that the device structure was the same as described in the next section. Fig. 3 shows the calculated results for the device with of 0.5 5 m and a base doping an emitter size The product of and concentration of 1 10 cm for the WSi base electrode reaches its minimum at of is below 0.4 m. 0.55 m and rapidly increases when On the other hand, the product for the WSi/Ti electrode is about 1/2 to 1/3 smaller than that for WSi and the remarkable is less than 0.4 m. increase is not shown even when of 0.25 m. The The product shows the minimum at of WSi/Ti and suggests result is due to the extremely low can be reduced to less than 0.4 m without the large that increase in the base resistance. Although the optimum value is slightly changed by the emitter size, the highest of and for the HBT would be obtained by reducing to around 0.2–0.3 m when using WSi/Ti as the base electrode. IV. DEVICE FABRICATION The epitaxial layers of the HBT’s were grown on a semiinsulating GaAs(100) substrate by gas-source molecular beam epitaxy (MBE) [19]. The group III sources were elemental Ga and In, and the group V sources were cracked arsine (AsH ) and phosphine (PH ). The n- and p-type dopant sources were solid Si and carbontertabromide (CBr ), respectively. The parameters of the epitaxial layer structure are listed in Table I. The emitter-cap layers consist of highly doped cm ), -GaAs (100 nm, InGaAs (50 nm, cm ), and n-InGaP (50 nm, cm ) to reduce emitter resistance. The emitter layer is 10010 cm The p-GaAs base layer nm InGaP doped to 5 10 cm to reduce the contact is highly doped to 1.3 resistance with the WSi/Ti base electrode, and the thickness is 30 nm to obtain appropriate current gain at the high base 2278 IEEE TRANSACTIONS ON ELECTRON DEVICES, VOL. 45, NO. 11, NOVEMBER 1998 (a) (d) (b) (e) (c) (f) Fig. 4. Fabrication steps for the HBT with a WSi/Ti base electrode and buried SiO2 : TABLE I EPITAXIAL LAYER STRUCTURE PARAMETERS OF FABRICATED HBT’S doping level. The -GaAs collector layer is 200 nm thick and 10 cm The relatively thick subcollector doped to 2 layer was used in order to bury the thick SiO in the extrinsic collector. The -GaAs subcollector layer is 800 nm thick and 10 cm doped to 8 The main steps in the fabrication process are schematically shown in Fig. 4. Device fabrication starts with W/WSi deposition on the InGaAs emitter-cap layer by RF sputtering. These metals are formed into a nonalloyed emitter electrode by RIE using CHF and SF By using this electrode as a mask, the InGaAs and GaAs layers are etched by using Cl /CH electron cyclotron resonance (ECR) plasma [Fig. 4(a)]. This is followed by a thick SiO sidewall formation around the emitter electrode. By using this sidewall as a masking layer, the self-aligned base and collector mesas are formed by ECR plasma etching. After F ions are implanted to isolate each device, the outsides of the base and collector mesas are buried by SiO by using planarization and an etchback process [Fig. 4(b)]. The InGaP layers are etched by the ECR plasma, leaving at least 50 nm unetched so that the plasma does not damage the base surface. The remaining InGaP layer is removed by selective wet-chemical etching using a solution of dilute HCl. During this etching, the side of the emitter layer is hardly etched due to the orientation dependence of the etching rate. A thin sidewall of SiO is then formed to avoid a short between the emitter and the base [Fig. 4(c)]. According to the result discussed in the previous section, the proper width of the base contact is 0.3 m. Thus, the thickness of this sidewall was chosen as 0.1 m and the thickness of the sidewall for the base and collector mesa-etching was chosen as 0.4 m. WSi/Ti is deposited by RF sputtering and etched by RIE to define the base electrode [Fig. 4(d)]. Then, AuGe/W/Ni/Au/Mo is deposited on the subcollector as a collector electrode, and alloyed. Subsequently, the WSi on the emitter electrode is selectively etched by RIE with CF by using a photoresist mask, and the Ti on the emitter electrode is removed by dilute HF [Fig. 4(e)]. Finally, a metallization process follows and the device structure is completed [Fig. 4(f)]. A cross-sectional SEM photograph of the fabricated HBT with a WSi/Ti base electrode and a buried SiO structure is shown in Fig. 5. The base–contact width is 0.3 m and the OKA et al.: SMALL-SCALED InGaP/GaAs HBT’S Fig. 5. SEM cross section of the fabricated HBT with a WSi/Ti base electrode and buried SiO2 : Fig. 6. Common-emitter IC with emitter size SE of 0.3 0 VCE characteristics for the fabricated HBT 2 1.6 m2 . sidewall thickness is 0.1 m. The final thickness of the buried SiO is about 0.4 m. The WSi/Ti base electrode covers both the narrow base–contact surface and the buried SiO outside the base–collector junction. This indicates that WSi and Ti are useful materials in fabricating small base electrodes for our HBT’s. V. DEVICE PERFORMANCE A. DC Characteristics We evaluated dc characteristics of the fabricated HBT’s with various emitter sizes by using an HP4145B semiconductor parameter analyzer. characteristics for an HBT The common-emitter of 0.3 1.6 m are shown in with an emitter size Fig. 6. The offset voltage is about 0.25 V and the collectoris 10–11 V. Fig. 7 shows emitter breakdown voltage of 0.3 1.6 m . The a Gummel plot for an HBT with of 20 is achieved at a collector current DC current gain 10 A/cm and decreases for current density density of 1 10 A/cm due to the base push-out effect at above 2 high current. The ideality factors of the collector and the base currents are 1.0 and 1.6, respectively. In AlGaAs/GaAs HBT’s, the current gain is decreased when scaling down the emitter size, which is known as the emitter size effect on current gain [20]. We investigate the emitter 2279 Fig. 7. Gummel plot for the fabricated HBT with emitter size 1.6 m2 . 2 SE of 0.3 Fig. 8. Dependence of 1=hFE on LE =SE for fabricated HBT’s with various emitter sizes at collector current density JC of 5 104 A/cm2 : 2 size effect in our InGaP/GaAs HBT’s. The current gain and the emitter size have the relationship approximately expressed as [21] (1) where intrinsic bulk current gain; base current density due to surface recombination; collector current density; length of the emitter periphery. on for the fabFig. 8 shows the dependence of ricated HBT’s at a collector current density of 5 10 A/cm The current gain is slightly decreased when the emitter size is scaled down. From the slope of the line in Fig. 8, the peripheral component of the base current was estimated to be A/ m. Although our HBT’s do not have a thin emitter layer on the extrinsic base regions for surface passivation, the leakage current is comparable to that of AlGaAs/GaAs HBT’s with an AlGaAs surface passivation layer [9]. This suggests that the low surface recombination velocity of InGaP effectively suppresses the degradation of the current gain. The relatively large ideality factor of the base current is, therefore, primarily attributed to the recombination in the intrinsic base region caused by the high doping concentration of the base layer. 2280 IEEE TRANSACTIONS ON ELECTRON DEVICES, VOL. 45, NO. 11, NOVEMBER 1998 j j Fig. 9. Frequency dependence of small-signal current gain h21 2 ; unilateral power gain UG; and maximum stable gain MSG for the fabricated HBT with SE of 0.6 4.6 m2 at VCE = 1:6 V and IC = 4 mA. The dashed lines are extrapolations of h21 2 and UG with a 20 dB/decade slope. 2 j j (a) 0 B. Microwave Characteristics We investigated the high-frequency characteristics of the fabricated HBT’s by using on-wafer -parameter measurements with an HP85107A network analyzer system and cascade microwave probes. The measurements were carried out in the frequency range of 100 MHz to 40 GHz. The pad parasitics were de-embedded using the method presented by Costa et al. [22]. Fig. 9 shows the frequency dependence of the small-signal unilateral power gain and maximum current gain of 0.6 stable gain MSG for an HBT with an emitter size 4.6 m . The collector-emitter bias voltage was 1.6 was 4 mA. The and V and the collector current as estimated with 20 dB/decade extrapolations from and were 138 and 275 GHz, respectively. These are the highest values ever reported for a GaAs-based HBT operating at such a low collector current. and Fig. 10 shows the collector current dependence of for the fabricated HBT with of 0.6 4.6 m at of 1.6 V. The HBT exhibits the peak of 138 GHz of 275 GHz at the same of 4 mA. and the peak The figure also shows the results for our conventional HBT m without using buried SiO [23]. The and for fabricated HBT operates at much higher lower collector currents than the conventional HBT. This much more than performance was achieved by reducing Several characteristics of the fabricated HBT and the of conventional HBT are summarized in Table II. The the fabricated HBT was reduced to 7.6 fF, which is about of one-third of that of the conventional HBT, while the the fabricated HBT is about 2/3 of that of the conventional by HBT. In Fig. 10, it is also shown that the increase of implementing the buried SiO structure is less than that of This is ascribed to the increase of the parasitic resistance and resulting from the reduction of the device size, which increases the parasitic delay time and thus interferes the increase of Fig. 11 shows the collector current dependence of and for the HBT with of 0.3 1.6 m at of 1.6 V. The high frequency performance is degraded compared to the larger device because the capacitance is not reduced in proportion to the device size due to the fringe capacitance. (b) Fig. 10. Collector current dependence of (a) fT and (b) fmax for the fabricated HBT with SE of 0.6 4.6 m2 and our conventional HBT (SE = 1:2 3:4 m2 ) without using buried SiO2 [23] at VCE of 1.6 V. 2 2 TABLE II DEVICE PARAMETERS OF THE FABRICATED HBT AND THE CONVENTIONAL HBT However, a peak of 96 GHz and a peak of 197 GHz of 1 mA. Furthermore, the device operates are achieved at as high as 40 GHz and as high as 100 GHz at with as low as 0.1 mA. To our knowledge, these values are the highest of previously reported GaAs-based HBT’s operating at submilliampere collector currents. In Fig. 11, our results are compared with the results for a Si of 0.2 2.0 m which exhibited high-frequency BJT with operation at a low collector current [24]. At any range of and the for the fabricated small collector currents, the HBT are higher than those for the Si BJT. This excellent highfrequency performance for low corrector currents is due to the simultaneous reduction of the emitter size and base–collector capacitance. This result indicates that our HBT’s will enable OKA et al.: SMALL-SCALED InGaP/GaAs HBT’S 2281 ACKNOWLEDGMENT The authors would like to thank Dr. Y. Imamura and his process staff for their contribution to the device fabrication. They also wish to thank Dr. O. Kanehisa for his encouragement and support throughout this work. REFERENCES (a) (b) Fig. 11. Collector current dependence of (a) fT and (b) fmax for the fabricated HBT with SE of 0.3 1.6 m2 at VCE of 1.6 V. Also shown are results for a Si BJT with SE of 0.2 2.0 m2 [24]. 2 2 the fabrication of integrated circuits with higher speed and lower power than Si BJT’s. VI. CONCLUSION We have demonstrated high-speed and low-current operation of small-scaled InGaP/GaAs HBT’s. The simultaneous reduction of the emitter size and the base–collector capacitance were achieved in the HBT’s by using WSi/Ti as the base electrode and by burying SiO in the extrinsic base–collector region under the base electrode. Inserting a thin Ti film between WSi and p-type GaAs dramatically reduced the contact resistance to cm at a carrier concentration of 1 10 cm 3 10 and made it possible to reduce the width of the base contact to less than 0.4 m without the large increase in the base resistance. The dc current gain of 20 is achieved for an HBT of 0.3 1.6 m . The emitter size effect on current with gain was suppressed by using InGaP as the emitter material. The base leakage current for the fabricated HBT’s without a thin emitter layer for surface passivation was comparable to that of AlGaAs/GaAs HBT’s with an AlGaAs surface passivation layer. Excellent high-frequency characteristics at low collector currents were achieved: an HBT with an emitter of 0.6 4.6 m provided of 138 GHz and size of 275 GHz at of 4 mA; and an HBT with of 0.3 1.6 m provided of 96 GHz and of 197 GHz at of 1 mA. These HBT’s will enable us to fabricate integrated circuits with higher speed and lower power than currently possible with Si BJT’s. [1] H. Kroemer, “Heterostructure bipolar transistors and integrated circuits,” Proc. IEEE, vol. 70, pp. 13–25, 1982. [2] T. Ishibashi, H. Nakajima, H. Ito, S. Yamahata, and Y. Matsuoka, “Suppressed base-widening in AlGaAs/GaAs balistic collection transistors,” in 48th Annu. Device Research Conf., VIIB-3, 1990. [3] H. Simawaki, Y. Amamiya, N. Furuhata, and K. Honjo, “High-fmax AlGaAs/InGaAs and AlGaAs/GaAs HBT’s fabricated with MOMBE selective growth in extrinsic base regions,” in 51st Annu. Device Research Conf., IVA-6, 1993. [4] M. Yanagihara, H. Sakai, Y. Ota, M. Tanabe, K. Inoue, and A. 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Nakamura, “High-speed InGaP/GaAs HBT’s with fmax of 159 GHz,” Solid-State Electron., vol. 41, pp. 1611–1614, 1997. [24] Y. Kiyota, E. Ohue, T. Onai, K. Washio, M. Tanabe, and T. Inada, “Lamp-heated rapid vapor-phase doping technology for 100-GHz Si bipolar transistors,” in Proc. IEEE BCTM, 1996, pp. 173–176. Tohru Oka (M’98), for a photograph and biography, see this issue, p. 2275. Koji Hirata, for a photograph and biography, see this issue, p. 2274. Kiyoshi Ouchi, for a photograph and biography, see this issue, p. 2274. Hiroyuki Uchiyama was born in Chiba, Japan, in 1962. He received the B.S. and M.S. degrees in chemistry from Chiba University in 1987 and 1989, respectively. In 1989, he joined the Central Research Laboratory, Hitachi Ltd., Tokyo, Japan, where he has been engaged in the research and development of dry etching processes for III–V compound semiconductor devices. Since 1996, he has been working on the development of MMIC’s operating at 77GHz. Mr. Uchiyama is a member of the Japan Society of Applied Physics. Kazuhiro Mochizuki, for a photograph and biography, see this issue, p. 2274. Tohru Nakamura (M’79–SM’90) received the M.S. and Ph.D. degrees in electrical engineering from Waseda University, Tokyo, Japan, in 1971 and 1979, respectively. In 1975, he joined the Central Research Laboratory, Hitachi Ltd., Tokyo. He has worked in the areas of integrated injection logic circuits, self-aligned bipolar device technologies and high speed silicon bipolar integrated circuit technology. His key emphasis was directed to development on new self-aligned bipolar device, SICOS (sidewall base contact structure), technologies and their application for high speed bipolar memory LSI’s. He has also worked in the area of high speed HEMT’s and HBT’s for telecommunication and mobile communication use, as a Chief Researcher in the Central Research Laboratory, Hitachi Ltd., Tokyo. During 1992–1993, he was a Visiting Professor at University of California, San Diego, where he taught a course on the high speed bipolar device and circuit technologies. He has authored or co-authored over 100 research papers on Si bipolar and compound semiconductor devices, circuits, process and technologies. He has been working at Department of Electronics and Electrical Engineering, Hosei University, Koganei, Tokyo, since 1998. Dr. Nakamura served as a IEDM subcommittee member of IC from 1989 to 1991. He has also been serving as a BCTM subcommittee member of process/technology since 1994 and an editor for the IEEE TRANSACTIONS ON ELECTRON DEVICES since 1993. He is a member of the Institute of Electronics, Information and Communication Engineers of Japan and the Japan Society of Applied Physics.