Junior Certificate Chemistry Chapter 26 – The Atom An atom is made up of protons, neutrons and electrons. The protons and neutrons are found in a small, dense nucleus in the centre of the atom with the electrons orbiting the nucleus in circular orbits rather like the planets orbiting the sun. This is often referred to as the Bohr model of the atom as it was Neils Bohr (a Danish scientist) who first proposed it. Name Found Proton Neutron Electron Nucleus Nucleus Cloud Mass [amu] 1 1 1/1850 4. The electrons are arranged in circular orbits around the nucleus. These orbits are sometimes called shells. The electrons are arranged in these shells as follows. 1st 2nd 3rd 4th 2 electrons 8 electrons 8 electrons Remainder Example; Draw an atom of sodium given the following information, 23 11 Charge shell shell shell shell Na From the two numbers given with this element we can get all of the information we need to draw an atom of sodium. +1 0 -1 You must be able to draw a simple diagram of an atom if given the necessary information. The information you need to know can be summarised as follows. 1. Atomic Number is the number of protons in the nucleus of an atom. This number can be obtained from the periodic table. Every element has two numbers assigned to them in this table, the smaller one is the atomic number. 2. Mass number is the number of protons and neutrons in the nucleus of an atom. This number is the bigger number beside the element in the P.T.E. 3. Number of protons = number of electrons in a neutral atom. Number of protons in nucleus 11 Number of electrons 11 Number of neutrons in the nucleus 23 – 11 = 12 We can now draw the atom of sodium in the following manner. The nucleus is drawn at the centre with the number of protons and neutrons indicated. The electrons are drawn as dots and are arranged in circles (also called orbits or shells) with two electrons in the first shell, eight in the second and the remaining one in the third shell. 1 G. Nugent Junior Certificate Chemistry The electron configuration can written very simply as, Cl; 2, 8,7 The configurations for the first twenty elements can be written in a similar fashion. 11P 12N Element Symbol Configuration Hydrogen H 1 Helium He 2 Lithium Li 2,1 Beryllium Be 2,2 Boron B 2,3 Carbon N 2,4 Nitrogen C 2,5 Oxygen O 2,6 Fluorine Fl 2,7 Neon Ne 2,8 Sodium Na 2,8,1 Magnesium Mg 2,8,2 Aluminium Al 2,8,3 Silicon Si 2,8,4 Phosphorus P 2,8,5 Sulphur S 2,8,6 Chlorine Cl 2,8,7 Argon Ar 2,8,8 Potassium K 2,8,8,1 Calcium Ca 2,8,8,2 Isotopes Not all atoms of an element are identical. The number of protons and electrons present in an atom never varies for an atom of an element but, sometimes, there are small differences in the number of neutrons in the nucleus. Isotopes are atoms of the same element which have different numbers of neutrons in their nuclei. This type of drawing of an atom is often referred to as the Bohr model of the atom. The electronic configuration of an element The arrangement of electrons in an atom is called its electronic configuration. This configuration may be shown using ‘circle-and-dots’ diagrams like the one above but a simpler method is often used. Example; Write the electronic configuration of chlorine. Solution; Chlorine is element number 17 in the periodic table. This means that it contains 17 electrons. The electrons will be arranged as follows, Shell number 1 2 3 Number of electrons 2 8 7 2 G. Nugent