Product guide cover & back_2014_Layout 1 06/06/2014 15:37 Page 2
Product Guide
Explosives and Accessories
2014/15
Product guide cover & back_2014_Layout 1 06/06/2014 15:50 Page 3
EPC-UK safety data sheets
are designed to give
‘at a glance’ information
and product profile
Introduction page_2014_Layout 1 06/06/2014 16:02 Page 1
EPC United Kingdom plc was established in
1905 and is a leading UK force in the field of
commercial explosives and blasting services.
The company operates through five divisions
covering explosives, blasting services,
fuel additives, transport and defence (EDSL).
The EPC Groupe has a strategy of becoming a full service
provider, which can be seen in the company’s growing activities
in the UK’s quarrying, mining and civil engineering industries.
The Explosives and Services divisions offer a full range of
products and support services including consultancy, training
and an integrated on-site blasting. These services are supported
by the supply of bulk emulsion explosives, through the Multiblend
brand and a growing drilling and blasting provision.
SAFETY FIRST
Safety is at the forefront of everything
we do. EPC-UK has introduced the
DuPont Safety programme, which
was originally initiated by the EPC
Groupe. The DuPont programme
is focused on reducing the risk of
accidents by monitoring behaviour
patterns and improving the safety
culture within an organisation.
DELIVERING
PROFESSIONALISM
EPC-UK’s ‘know-how’ and ‘can-do’
attitude continues to deliver
an unrivalled capability and
professionalism to every
project and challenge.
SAFETY
EVERYDAY
Product guide content page_2014_Layout 1 06/06/2014 16:05 Page 1
CONTENTS
1-
AMMONIUM NITRATE
2-
ANFO
4-
BOOSTERS
6-
DETONATING CORD
3-
5-
7-
8-
9-
BLACK POWDER
BULK EMULSIONS
ELECTRIC DETONATORS
ELECTRONIC DETONATORS
NON-ELECTRIC DETONATORS
10 - EMULSION EXPLOSIVES
11 - AUTHORISED NITROGLYCERINE
EXPLOSIVES
12 - P5 PERMITTED
NITROGLYCERINE EXPLOSIVES
13 - PACKAGED EXPLOSIVES
14 - BLASTING ACCESSORIES
Product guide covers_2014_Layout 1 09/06/2014 10:50 Page 1
1
AMMONIUM
NITRATE
Ammonium nitrate is a white
crystalline, dry prill with the
chemical formula NH4NO3. It is
made by reacting nitric acid with
anhydrous ammonia under very
carefully controlled conditions.
The resulting material is
further processed to form
granular prills.
Pure ammonium nitrate is
water soluble. Conditioning
agents are added to ammonium
nitrate so a typical analysis is
34.5% nitrogen by weight.
The particle density of the prills
is such that, when liquid fuel is
properly applied to and mixed
with them, the prills absorb
the fuel uniformly which
enhances reactivity.
Ammonium nitrate (oxidiser) is
used extensively in the mining
industry and is intentionally made
very porous to allow for the rapid
uptake of liquid fuel oil (fuel).
This ANFO mixture then becomes
an explosive product.
A range of explosive grade porous
prilled ammonium nitrates are sold
by EPC-UK Explosives.
Ammonium Nitrate can be supplied
in either 25kg bags or 1 tonne bags
depending on the grade supplied.
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AMMONIUM NITRATE
AMMONIUM NITRATE
POROUS PRILLS 5-7-1, AN-PP
Typical Analysis
NH4NO3
> 99%
Total nitrogen (N)
> 34.5%
Moisture
≤ 0.23%
Bulk density
Organic coating
Oil absorption
Size distribution
0.78 - 0.83 kg/I
< 0.1%
> 7%
Greater than 2.0mm
< 20%
Product code
PA113P
Smaller than 1.0mm
Product produced in Sweden
< 2%
Variations of the typical analysis may occur
Ammonium Nitrate_2014_Layout 1 06/06/2014 16:18 Page 2
DATA
PRODUCT AND COMPANY IDENTIFICATION
Product Type
Ammonium Nitrate
Product Description
Porous Prilled Ammonium Nitrate
Address
ROUGH CLOSE WORKS
SOUTH NORMANTON
ALFRETON
DERBYSHIRE, DE55 2BE
Trade Names
Manufacturer / Supplier
Telephone Number
Emergency Tel Number
e-mail
Prillex, Ammonium Nitrate,
Yara 5-7
EPC-UK EXPLOSIVES
00-44-1773 832253
00-44-1773 832253
info@epc-groupe.co.uk
Ammonium Nitrate_2014_Layout 1 06/06/2014 16:18 Page 3
AMMONIUM NITRATE
HAZARD IDENTIFICATION
Main Hazards
Health Effects – Eyes
Health Effects – Skin
Health Effects – Ingestion
Health Effects – Inhalation
Fire/Explosion Hazard
OXIDISING AGENT
The substance is classified as
dangerous according to EU
Directives 67/548/EEC.
May cause irritation
May cause irritation
Small quantities unlikely to cause
toxic effects. In larger quantities,
may give rise to Gastro Intestinal
Disorders and in extreme cases,
particularly in children, formation
of Methaemoglobin (Blue Baby
Syndrome) and Cyanosis (indicated
by blueness around the mouth)
Low toxicity dust but high
concentration may cause irritation
of the upper respiratory tract such
as sore throat and coughing.
When strongly heated/in a fire,
ammonium nitrate will decompose
giving off toxic fumes containing
oxides of nitrogen. Heating under
strong confinement can lead to
explosive behaviour
COMPOSITION / INFORMATION ON THE COMPONENTS
Chemical Name
Ammonium Nitrate
CAS Number
6484-52-2
Composition
EC Number
FIRST AID MEASURES
First Aid – Eyes
First Aid – Skin
Ammonium Nitrate (99.5%)
Organic material (<0.1%)
229-347-8
The nitrate is classified as an
oxidiser in accordance with EU
Directives 67/548/EEC
Irrigate thoroughly with water for
at least 15 minutes
Wash thoroughly with soap and water
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DATA
FIRST AID MEASURES Continued...
First Aid – Ingestion
Drink some water or milk.
Seek medical advice.
Advice to Physicians
Eyes – Continue irrigation treatment
as for chemical burns
Ingestion – Mild cases of
methaemoglobinaemia will lead to
cyanosis and in more severe cases
may produce unconsciousness.
First Aid – Inhalation
FIRE FIGHTING MEASURES
Extinguishing Media
Special Hazards of Product
Protective Equipment
for Fire Fighting
Incompatibility
Seek medical advice if fumes are
inhaled from decomposition.
Large quantities of water. Do not use
a chemical extinguisher or foam or
attempt to smother the fire with
steam or sand.
Avoid breathing dusts, vapours or
fumes from burning material. The
product itself is not combustible but it
can support combustion,even in the
absence of air. Decomposes when
heated giving off Oxides of Nitrogen.
Strong oxidising agent which reacts
violently with combustible substances.
May react violently with metal powders
with risk of fire and explosion.
Full protective clothing
and breathing apparatus
Contamination by substances such
as organic materials, metallic powders,
chlorine containing compounds,
alkalis, hypochlorites and reducing
agents all decrease the resistance
to detonation.
ACCIDENTAL RELEASE MEASURES
Personal Precautions
Environmental Precautions
Eliminate all ignition sources. Keep
all unnecessary personnel away.
Wear gloves and overalls. Do not
touch or walk through spilt material.
Avoid contamination by any source
including metal powder and organic
materials. Do not allow to enter a
water course.
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AMMONIUM NITRATE
ACCIDENTAL RELEASE MEASURES Continued...
Spillages
Products:
HANDLING AND STORAGE
Handling
Storage
Do not allow spills to mix with organic
substances (oil, paper, sawdust) or
other chemicals. If emergency
personnel not present, sweep up
small spillages, avoiding making dust
and place in a suitable clean container
for disposal. Avoid creating a dusty
condition and prevent wind dispersal.
Handle with care. No smoking –
no sources of ignition. Keep product
clean and free from contamination.
Avoid contact with eyes, skin
and clothing.
Store away from combustible
materials. Handle bags with care.
Keep the materials clean and free
from contamination. Do not store in
direct sunlight. For further information,
refer to Health and Safety Guidance
INDG230 and also Yara’s “
Safety Aspects”
Products:
EXPOSURE CONTROL / PERSONAL PROTECTION
UK Occupational Exposure
Standards
Dust : 10 mg m-3 TWA total inhalable
5 mg m-3 TWA total respirable
Respiratory Protection
Wear dust masks
Eye Protection
When required – when dust is
generated
Hand Protection
Body Protection
Skin Protection
Wear gloves that are
chemical-resistant.
Wear overalls
Wash hands, forearms and face
thoroughly after handling chemical
products, before eating, smoking
and using the lavatory and at the
end of the working period.
Wash contaminated clothing.
Ammonium Nitrate_2014_Layout 1 06/06/2014 16:18 Page 6
DATA
PHYSICAL AND CHEMICAL PROPERTIES
Physical State
Solid prills. Hygroscopic.
Odour
None
Colour
pH
Melting Point (deg C)
Solubility in Water
(at 20 ̊C)
Density (kg/m3)
White
5.0 – 7.0
170°C
Easily soluble in cold water
1877g/l
680 – 900
Range quoted is for the bulk density
of the ammonium nitrate (not the
particle density of the prill).
Actual values vary depending on the
grade and whether the sample is
“loose” or “tapped”
For example, some typical values:
Loose
Tapped
Yara 5-7
780-830
790-890
Yara 7-7
680-740
700-780
Decomposition Temp. (deg C) >170oC
STABILITY AND REACTIVITY
Stability
Stable
Materials to Avoid
Combustible substances, metals,
reducing agents, alkalis and acids
Conditions to Avoid
Hazardous Decomposition
Products
Incompatibility
Prills may break down when exposed
to temperatures greater than 32°C.
Avoid damp storage conditions
Oxides of Nitrogen if heated to
decomposition. May give off ammonia
in contact with alkaline materials.
Contamination by substances such
as organic materials,metallic powders,
chlorine containing compounds,
alkalines, hypochlorites and
reducing agents decrease the
resistance to detonation.
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AMMONIUM NITRATE
TOXICOLOGICAL INFORMATION
Irritancy - Eyes
Mildly irritant
Inhalation
Adverse health effects are
considered unlikely when product
is used according to directions
Irritancy - Skin
Ingestion
Mildly irritant
Adverse health effects are
considered unlikely when product
is used according to directions
LD50 Oral rat
2217 mg/kg
Mobility
Free flowing granular solid
Adverse effects
The product is not expected to harm
the environment when used properly
according to directions
Over-exposure
May cause methaemoglobinaemia
signs / symptoms
and cyanosis
Products:
ECOLOGICAL INFORMATION
Persistence / Degradability
Remarks
Very soluble in water. Serves as a
nutrient. Contributes to eutrophication
The product does not show any
bio-accumulation phenonoma
LC50 (96 hrs) various species > 5,000 mg/l
Products:
DISPOSAL
Product Disposal
Container Disposal
European Waste Catalogue
(EWC)
Hazardous Waste
Contact authorised hazardous waste
disposal operative and dispose of in
accordance with all applicable local
and national regulations
Use locally available facilities
for disposal
06 03 14 solid salts and solutions
other than those mentioned in
06 03 11 and 06 03 13.
This material and its container must
be disposed of as a hazardous waste
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DATA
TRANSPORT INFORMATION
UK Transport Information
Subject to Carriage of Dangerous
Goods by Road etc Regulations
UN Class
5.1
UN Number
UN Packaging Group
ADR/RID Substance ID No
ADR/RID – Description
ADR/RID – Class
Limited Quantity
UN 1942
III
UN 1942
Ammonium Nitrate
5.1
5 kg
IMDG – Proper Shipping Name AMMONIUM NITRATE –
with not more than 0.2% combustible
substances including any organic
substance calculated as carbon
to the exclusion of any other
added substance
IMDG – Packaging Group
IMDG Class
REGULATORY INFORMATION
III
5.1
Classification (CHIP)
O Oxidising
R Phrases
R8, R9
Product use
Industrial applications.
Classification and labelling have
been performed according to EU
Directives 67/548/EEC and
1999/45/EC (including amendments)
and the intended use.
S Phrases
OTHER INFORMATION
UK Legislation
S17, S41
Ammonium Nitrate Materials (high
nitrogen content) Regulations 2003
COMAH Regulations 1999, as amended.
Planning (Hazardous substances)
Regulations 1992, as amended.
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AMMONIUM NITRATE
OTHER INFORMATION Continued...
Other documents
Meaning of Risk
and Safety phrases
“Storing and Handling Ammonium
Nitrate” HSE Guidance INDG230,
reprinted November 2004
“Safety Aspects” Yara guide to safe
storage, handling and use of
technical grade ammonium nitrate
R8
R9
S17
S41
MSDS first issued
Issue 6
03/96
Contact with combustible
material may cause fire
Explosive when mixed with
combustible material
Keep away from combustible
materials.
In case of fire or explosion,
do not breathe fumes
General minor updates
NOTICE:FOR FURTHER INFORMATION CONTACT
EPC-UK EXPLOSIVES ENGINEERING DEPARTMENT
Tel :00-44-1773-832253
Product guide covers_2014_Layout 1 09/06/2014 10:50 Page 2
2
ANFO
ANFO explosives are supplied
either in cartridge or bulk form and
are suitable for use in dry borehole
conditions. EPC-UK’s range of
ANFO explosives includes
Ammospex and Ammoblast.
Ammospex and ammoblast are
oxygen balanced, free flowing
mixture of ammonium nitrate
prills and fuel oil. The lack of
water resistance and low bulk
strength of ANFO have to be
recognised when designing
blasts using these product.
Bulk ANFO may be delivered
in a variety of approved
containers and weights.
These products are available in the
following packaging:
Ammospex – 2.5Kg cartridges, 10
cartridges per box
Ammoblast – 25Kg bags, 1 bag
per box.
The classification for those products
is UN 0082 and the hazard class
compatibility group is 1.1D.
ANFO_2014_Layout 1 06/06/2014 16:28 Page 1
AMMONIUM NITRATE
/ FUEL OIL MIXTURES
PRODUCT AND COMPANY IDENTIFICATION
Product Type
Ammonium Nitrate / Fuel Oil
(ANFO) mixtures.
Product Description
A mixture of ammonium nitrate prills
and fuel oil. The product is an
explosive used as a column charge
in blasting
Trade Names
Ammospex, Ammoblast.
Manufacturer / Supplier
EPC-UK EXPLOSIVES
Telephone Number
00-44-1773 832253
Address
Emergency Tel Number
e-mail
ROUGH CLOSE WORKS
SOUTH NORMANTON
ALFRETON
DERBYSHIRE, DE55 2BE
00-44-1773 832253
info@epc-groupe.co.uk
ANFO_2014_Layout 1 06/06/2014 16:28 Page 2
DATA
HAZARD IDENTIFICATION
Main Hazards
Health Effects – Eyes
Health Effects – Skin
Health Effects – Ingestion
Environmental Effects
EXPLOSIVE: mass explosion hazard.
Risk of explosion by shock, fire or
other sources of ignition Once
detonated, explosives release large
quantities of gas. If in a confined
area, care should be taken to ensure
that there is sufficient oxygen in the
air before approaching the site of an
explosion. The gases released may
contain some carbon monoxide –
TOXIC (T) - nitrogen monoxide and
nitrogen dioxide - VERY TOXIC (T+).
May cause irritation.
May cause irritation.
CARCINOGENIC CAT 3 (Xn):
The product may contain
polycyclic aromatic hydrocarbons,
some of which are skin
carcinogens in animals. The risk
is very low if prolonged and
repeated skin contact is avoided.
Small quantities unlikely to cause
toxic effects. In larger quantities,
may give rise to gastro intestinal
disorders and in extreme cases,
particularly in children, formation
of Methaemoglobin (Blue Baby
Syndrome) and Cyanosis
(indicated by blueness around
the mouth).
Heavy spillage may cause adverse
environmental impact from the
ammonium nitrate such as
eutrophication in confined surface
waters or nitrate contamination of
ground or surface water.
Studies on gas oils indicate toxicity
to invertebrates and slight toxicity
to fish.
ANFO_2014_Layout 1 06/06/2014 16:28 Page 3
AMMONIUM NITRATE
/ FUEL OIL MIXTURES
COMPOSITION / INFORMATION ON THE COMPONENTS
Name
Ammonium
Nitrate
Gas Oil
/Diesel fuel
Concentration
92.5-95.0%
5.0-7.5%
EINECS/EC
Number
Hazard
229-347-8
CAS
Number
6484-52-2
269-822-7
27247-96-7
Xn, Carc
Cat 3:R40
R51/53
O
Gas oil /diesel fuel may contain small quantities of flow improver,
cetane improver, dye / chemical marker, and fatty acid methyl ester.
Products:
FIRST AID MEASURES
First Aid – Eyes
First Aid – Skin
First Aid – Ingestion
First Aid –Inhalation
Irrigate thoroughly with water for
at least 15 minutes. If irritation
persists seek medical advice
Wash thoroughly with soap
and water.
Wash mouth with water.
Seek medical advice.
Remove to well ventilated area. If
problems persist, seek medical advice.
A person suffering from inhalation of
after detonation fumes must be
removed to fresh air, receive medical
attention and stay under medical
observation for at least 48 hours.
The person should lie down until
the doctor arrives.
Eyes - Continue irrigation treatment
as for chemical burns.
Ingestion - Mild cases of
methaemoglobinaemia will lead to
cyanosis and in more severe cases
may produce unconsciousness.
Never give anything by mouth to an
unconscious person. Do not induce
vomiting unless directed to do so by
medical personnel.
ANFO_2014_Layout 1 06/06/2014 16:28 Page 4
DATA
FIRE FIGHTING MEASURES
Extinguishing Media
Special Hazards of Product
Use water based extinguishers to
prevent fire reaching the ANFO.
Explosive - may burn to detonation.
If the fire looks likely to reach the
ANFO retire to a safe distance and
cordon off the area. A minimum
distance of 300 m is recommended
and a greater distance may be
required depending on the quantity
of explosives. DO NOT attempt to
fight a fire engulfing the ANFO.
ACCIDENTAL RELEASE MEASURES
Personal Precautions
Wear gloves and overalls.
Spillages
Be careful to avoid shock, friction,
and contact with grit. Avoid the use
of metal tools containing iron and/or
copper. Collect product for recovery
or disposal and wash contaminated
area with water. Prevent access by
unauthorised persons.
Environmental Precautions
HANDLING AND STORAGE
Handling
Storage
Do not allow to enter a water course.
Keep away from heat/sparks/open
flames/hot surfaces - no smoking.
-no sources of ignition. Keep product
clean and free from contamination.
Must be stored in accordance with
the Manufacture and Storage of
Explosives Regulations 2005. Handle
cases with care. Do not open cases
in magazines or whilst in transit or
when loading or unloading from
vehicles. Keep the product clean
and free from contamination.
Do not store in damp or humid
conditions. Avoid thermal cycling.
Keep boxes closed prior to use.
The shelf life of the explosive is
12 months when stored under
recommended conditions.
ANFO_2014_Layout 1 06/06/2014 16:28 Page 5
AMMONIUM NITRATE
/ FUEL OIL MIXTURES
EXPOSURE CONTROL / PERSONAL PROTECTION
Occupational Exposure Standards
Mineral oil mist
Ammonium Nitrate
(nuisance dust level)
8-hour TWA
5 mgm-3
10 mgm-3
STEL
10 mgm-3
Note, after detonation fumes will contain carbon dioxide,
carbon monoxide and oxides of nitrogen
Hand Protection
Wear chemical resistant
impervious gloves
Physical State
Solid.
Odour
Slight diesel smell.
Body Protection
Wear overalls.
Products:
PHYSICAL AND CHEMICAL PROPERTIES
Colour
pH
Flash Point
Solubility in Water (kg/m3)
Density (kg/m3)
Slightly pink granules
10% solution will have a pH of 4.5-7.
The flash point of the oil in the
ANFO is > 55°C.
Mostly soluble, leaving the oil and
additives in the ammonium nitrate
to float.
ca 800.
Decomposition Temp. (deg C) > 150°C.
Products:
STABILITY AND REACTIVITY
Stability
Conditions to Avoid
Materials to Avoid
Stable under normal conditions.
As an explosive it is detonable
under the right conditions.
High temperatures, impact, friction,
flames, sparks and static discharge.
Copper and its alloys, bromates,
chlorates, chlorites, hypochlorites,
nitrites, perchlorates, permanganates,
powdered metals, acids and bases.
ANFO_2014_Layout 1 06/06/2014 16:28 Page 6
DATA
STABILITY AND REACTIVITY Continued...
Hazardous Decomposition
Products
Nitrogen Oxides, Oxides of Carbon,
including Carbon Monoxide may be
produced when the product is used.
However the amounts of toxic gases
produced will depend on many
variables such as method of
initiation, rock type, humidity etc.
TOXICOLOGICAL INFORMATION
Acute toxicity
Ammonium Nitrate
Gas Oil
LD50 Oral
2217 mg/kg (rat)
>5000 mg/kg
LD50 Dermal LC50 Inhalation
>2000 mg/kg
Eyes
Mildly irritant.
Inhalation
Inhalation of the oil vapour or mist in
high concentrations is irritating to the
mucous membranes, and may cause
headaches and dizziness.
Skin
Skin Sensitisation
ECOLOGICAL INFORMATION
Mobility
Persistence/Degradability
Mildly irritant, low order of acute
toxicity. Prolonged or repeated
contact with the oil may lead to
more serious skin disorders
including skin cancer.
May sensitise skin to other chemicals.
Free flowing prills - pourable. The
ammonium nitrate dissolves readily in
water. The gas oil has some mobility
in soil.
The ammonium nitrate follows the
natural nitrification/denitrification
cycle. For the gas oil hydrocarbon
components are degraded by microorganisms. Light components
volatilise and in air undergo photolysis.
Photoxidation of oil on the liquid
surface also contributes to the loss
process. Adsorbed oils will degrade
slowly. Gas oils have a tendency to
bio-accumulate.
ANFO_2014_Layout 1 06/06/2014 16:28 Page 7
AMMONIUM NITRATE
/ FUEL OIL MIXTURES
DISPOSAL
Product Disposal
Container Disposal
Products:
TRANSPORT INFORMATION
UK Transport Information
UN Number
UN Class
Under the supervision of an expert,
the product may be destroyed by
detonation in a borehole or by
burning at an approved site.
Dissolving is also a possibility.
For more guidance see the HSE/CBI
Explosives Industry Group publication:
“Guidance for the Safe management
of the disposal of Explosives”,
January 2007.
The accepted method for destroying
empty boxes is burning.
Must be in accordance with the
Carriage of Dangerous Goods,
etc Regulations 2011
UN0082.
1.1 D.
ADR/RID/IMDG name
EXPLOSIVE, BLASTING, TYPE B
Products:
REGULATORY INFORMATION
UK Legislation
EC Regulations
Manufacture and Storage of Explosives
Regulations 2005, (as amended), The
Control of Explosives Regulations 1991
(as amended). Placing on the Market
and Supervision of Transfers of
Explosives Regulations 1993
(as amended). Carriage of Dangerous
Goods, etc Regulations 2011.
Explosives Act 1875 (what
remains) Quarries Regulations 1999.
The Chemical Hazard Information and
Packaging for Supply Regulations 2009
(note regs 6-11 do not apply to the
explosives covered by this MSDS)
The Control of Substances
Hazardous to Health Regulations,
2002 (as amended)
Registration, Evaluation, Authorisation
and Restriction of Chemicals, EC Reg
1907/2006 (as amended).
ANFO_2014_Layout 1 06/06/2014 16:28 Page 8
DATA
REGULATORY INFORMATION Continued...
EC Regulations
Continued...
CHIP Classification
Risk and Safety Phrases
OTHER INFORMATION
MSDS first issued
Meaning of R & S phrases
Classification, Labelling and
Packaging of Substances and
Mixtures, EC Reg 1272/2008. Note
this does not apply to mixtures until
June 2015, as such this data sheet
does not show the labelling
requirements under this regulation
E, Xn Carcinogenic Cat 3, N
R phrases: R2, R40, R52/53
S Phrases: S35, S36/37
03/96 For issue 7 minor changes
have been made
R2:
Risk of explosion by shock,
friction fire or other sources
of ignition
R40:
Limited evidence of a
carcinogenic effect
R51/53: Toxic to aquatic organisms,
may cause long term
adverse affects in the
aquatic environment
R52/53: Harmful to aquatic
organisms, may cause long
term adverse affects in the
aquatic environment
S35:
This material and its
container must be disposed
of in a safe way.
S36/37: Wear suitable protective
clothing and gloves
NOTICE:FOR FURTHER INFORMATION CONTACT
EPC-UK EXPLOSIVES ENGINEERING DEPARTMENT
Tel :00-44-1773-832253
Product guide covers_2014_Layout 1 09/06/2014 10:50 Page 3
BLACK
POWDER
For specialist blasting,
EPC-UK can provide a
suitable grade of black
powder that can produce
effective blasted rock.
3
Blackpowder_2014_Layout 1 06/06/2014 16:55 Page 1
BLACKPOWDER
PRODUCT AND COMPANY IDENTIFICATION
Product Type
Blackpowder
Product Description
Grey to black powder or granules.
For specialist blasting, EPC-UK can
provide a suitable grade of black
powder that can produce effective
blasted rock.
Black powder is a low order
explosive. It is sensitive to accidental
initiation by flame, spark or friction.
When initiated it burns at a rapid
rate. This rapid burning is called
deflagration. The speed of reaction
is much slower than high explosives.
Black powder can be used in
dimension stone blasting where a
minimum amount of shattering is
required. Different grades of black
powder can be made available on
request. Black Powder classification
is UN 0027 and hazard class /
compatibility is 1.1D.
Trade Names
Manufacturer / Supplier
Address
Telephone Number
Emergency Tel Number
e-mail
Blackpowder or Gunpowder
EPC-UK EXPLOSIVES
ROUGH CLOSE WORKS
CARNFIELD HILL
SOUTH NORMANTON
ALFRETON
DERBYSHIRE, DE55 2BE
00-44-1773 832253
00-44-1773 832253
info@epc-groupe.co.uk
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DATA
HAZARD IDENTIFICATION
Main Hazards
EXPLOSIVE
Health Effects – Skin
Irritant.
Health Effects – Eyes
Health Effects – Ingestion
Irritant.
Large quantities may cause
gastroenteritis.
COMPOSITION/INFORMATION ON THE COMPONENTS
Product Formal Name
Blackpowder – coarse, medium
and fine grain.
CAS Number
Potassium Nitrate 7757-79-1
Sulphur
7704-34-9
Carbon
7740-44-0
Product Chemical Family
FIRST AID MEASURES
Contains Potassium Nitrate,
Charcoal and Sulphur.
Eyes
Irrigate thoroughly with water
for at least 15 minutes.
Ingestion
Drink plenty of water.
Advice to Physicians
Explosive.
Skin
Inhalation
FIRE FIGHTING MEASURES
Extinguishing Media
Special Hazards of Product
Wash thoroughly with soap
and water.
Remove to fresh air.
After breathing after-detonation
fumes seek medical advice
Use water based extinguishers
to prevent fire reaching the
Blackpowder if it is safe to do so.
Black powder is a deflagrating
explosive. If fire reaches the
Blackpowder, retire to a safe
distance (at least 300m) and
cordon off the area.
Gases produced by detonation
/ burning may be toxic.
It is adviseable to stay upwind.
Blackpowder_2014_Layout 1 06/06/2014 16:56 Page 3
BLACKPOWDER
ACCIDENTAL RELEASE MEASURES
Personal Precautions
Avoid any flame or heat sources
capable of causing sparks.
Do not smoke. Avoid any kind of
impact or friction. Do not walk on
any spilled product. Avoid wearing
attire that may induce static. Isolate
the spillage area. Wear impervious
rubber gloves.
Spillages
HANDLING AND STORAGE
Handling
Storage
Sprinkle with damp sawdust and
sweep up. Only competent people
should attempt to clean up a spillage
and you are recommended to seek
advice from your supplier.
Blackpowder is sensitive to shock,
friction, fire and static.
Handle cases with care.
No smoking, no naked lights.
Storage area must be kept clean,
free from grit and spillage.
Do not store near flammable
substances or detonators.
Products:
EXPOSURE CONTROL / PERSONAL PROTECTION
UK Occupational
Exposure Standards
None assigned.
Hand Protection
Wear impervious rubber gloves.
Respiratory Protection
Dust mask.
Body Protection
Wear overalls.
Products:
PHYSICAL AND CHEMICAL PROPERTIES
Physical State
Solid.
Odour
None.
Colour
pH
Grey – black.
Solubility in Water (kg/m )
Density (kg/m )
3
3
Neutral.
(Potassium Nitrate is soluble).
Particle density: 1700 – 1800.
Bulk density 1100-1125
Blackpowder_2014_Layout 1 06/06/2014 16:56 Page 4
DATA
PHYSICAL AND CHEMICAL PROPERTIES continued...
Decomposition Temp. (deg C) >185°C
Explosion point
>250°C
Friction sensitivity
> 282 N
Impact sensitivity
STABILITY AND REACTIVITY
> 14.7 J
Stability
Stable.
Materials to Avoid
Grit.
Conditions to Avoid
Hazardous Decomposition
Products
High temperature, impact, friction,
flames, sparks and static discharge.
Oxides of Sulphur, Carbon and
Nitrogen may be produced when
the product is used. However the
amounts of toxic gases produced
will depend on many variables such
as method of initiation, rock type,
humidity etc
TOXICOLOGICAL INFORMATION
Irritancy - Eyes
Irritancy - Skin
ECOLOGICAL INFORMATION
Ecotoxicity values
Irritant.
Irritant.
Potassium nitrate reference value:
Toxicity in fish: 191,000 g / l
96 months LC50 (Lethal).
Toxicity in invertebrates: 2,650 g / l
28 hours LC50 (Lethal).
Toxicity in algae: 1,400 g / l
96 hours (Waste).
Sulphur reference value:
Toxicity in fish: 10,000,000 g/ l
96 hours (Lethal).
Toxicity in invertebrates: 160 g/l
24 days LC50 (Lethal).
Mobility
Solid granules.
Bioaccumulation potential
No data available. Parameter under study
Persistence and degradability No data available. Parameter under study
Other harmful effects
No data available.
Blackpowder_2014_Layout 1 06/06/2014 16:56 Page 5
BLACKPOWDER
DISPOSAL
Product Disposal
Container Disposal
TRANSPORT INFORMATION
UK Transport Information
Destroy preferably by detonation at
point of use. If in doubt contact
supplier.
The recommended method of
destruction for empty boxes is
by burning.
Must be in accordance with
Carriage of Dangerous Goods
Regulations 2011.
UN Number
UN0027.
ADR/RID Substance ID No
UN0027.
UN Class
ADR/RID Description
1.1 D.
1.1 D.
IMDG Proper Shipping Name BLACKPOWDER, (GUNPOWDER),
granular or as a meal.
IMDG Class
1.1 D.
Labelling Information
Labelled in accordance with the
Carriage of Dangerous Goods
Regulations 2011.
REGULATORY INFORMATION
R Phrases
S Phrases
OTHER INFORMATION
UK Legislation
MSDS first issued
R3.
S35.
Subject to Explosives Act 1875
and Associated Legislation and
Approved Codes of Practice.
03/96
Issue 6 incorporated minor changes
NOTICE:FOR FURTHER INFORMATION CONTACT
EPC-UK EXPLOSIVES ENGINEERING DEPARTMENT
Tel :00-44-1773-832253
Product guide covers_2014_Layout 1 09/06/2014 10:50 Page 4
BOOSTERS
Boosters are available from
EPC-UK in a variety of sizes.
Due to their high density and velocity of detonation, boosters
supplied by EPC-UK offer the best priming characteristics for use
with slurries, emulsions and bulk emulsion/ANFO blends. EPC-UK
recommends their use when firing these non-detonator sensitive
compositions. The composition of boosters supplied is extremely
stable and provides consistent, reliable results.
The velocity of detonation is greater than 7500m/s resulting in
a detonation pressure of more than 25GPa, enabling them to
be used in the most arduous of conditions encountered in quarries
or surface mines. Smaller boosters have a single detonator pocket
to accommodate a single detonator, whilst the larger, 410g boosters
have two pockets. Initiation can be achieved using a single
No 8 strength detonator or by 12g detonating cord.
Sizes available include: 150g, 250g and 410g. Other sizes may
be available on request.
Classification and Labelling
Cast primers are packaged as Class 1.1D Articles. UN No. 0042
4
Boosters_2014_Layout 1 09/06/2014 09:45 Page 1
BOOSTERS
PRODUCT AND COMPANY IDENTIFICATION
Product Type
Boosters
Product Description
Pressed Booster containing RDX and
Stearic acid. The articles are filled
into rigid yellow plastic containers.
The Boosters have through holes
along the long axis to facilitate their
use with detonating cords or leading
wires and/or have cylindrical wells
long enough to accommodate
detonators.
The Booster weights are either 250g
or 410g NEQ. The density of the
composition is 1.25 g/cc. Packaging
is in fibreboard boxes.
Trade Names
Manufacturer / Supplier
Address
Telephone Number
Emergency Tel Number
e-mail
EPC Boost A
SEI Societả Esplosivi Industriali
S.p.A/EPC UK Explosives
ROUGH CLOSE WORKS
CARNFIELD HILL
SOUTH NORMANTON
ALFRETON
DERBYSHIRE, DE55 2BE
00-44-1773 832253
00-44-1773 832253
info@epc-groupe.co.uk
Boosters_2014_Layout 1 09/06/2014 09:45 Page 2
DATA
HAZARD IDENTIFICATION
Main Hazards
EXPLOSIVE
Health Effects – Skin
Toxic. However this is unlikely
as the material is encased in a
plastic tube.
Health Effects – Eyes
Not applicable
Health Effects –
Ingestion and Inhalation
Toxic. Inhalation and ingestion may
cause headaches. However this
is unlikely as the material is encased
in a plastic tube.
COMPOSITION/INFORMATION ON THE COMPONENTS
Product Formal Name:
Compound Hazardous
Substance
A5
%
RDX–Perhydro 98-99
1,3,5 trinitro
1,3,5-triazine
Stearic Acid
2-1
CAS No.
Boosters
EINECS
-No.
121-82-4
204-500-1
57-11-3
200-313-4
FIRST AID MEASURES
Eyes
Skin
REACH
Pre –
Registering
No.
QZ456531-99
Risk
Symbol
R risk
Phrases
E-T
2-23/24/25
QB456798-23 N.A.
Irrigate thoroughly with water
for at least 15 minutes.
Wash thoroughly with soap and
water. Absorption of the components
by the human body may induce the
formation of methahaemoglobin
and cause cyanosis.
Ingestion
Seek medical advice.
Advice to Physicians
This material is explosive
Inhalation
FIRE FIGHTING MEASURES
Extinguishing Media
N.A.
Seek medical advice.
Use water based extinguishers to
prevent fire reaching the boosters.
If the product is enveloped by flames,
leave the area immediately as there
Boosters_2014_Layout 1 09/06/2014 09:45 Page 3
BOOSTERS
FIRE FIGHTING MEASURES continued...
Extinguishing Media
continued...
is a real risk of explosion.
Keep at least 300m from the flames,
and preferably seek shelter behind a
natural or artificial barrier. Products of
combustion releases vapours and
toxic gases (mainly carbon monoxide
and nitrous fumes). If safe to do so,
move the product away from the area
affected by the fire. If in any doubt
leave area immediately.
ACCIDENTAL RELEASE MEASURES
Spillages
HANDLING AND STORAGE
Handling
Any cartridges spilled may be picked
up by hand, contaminating debris
removed and placed in a suitable
box. In the unlikely event that a
container breaks and the contents
being dispersed:Wear suitable PPE and shovel up
solid spill using anti-spark
tools and equipment (wood or
plastic). Eliminate any potential
sources of ignition and avoid any
action that may generate shocks,
friction, sparks or a sudden increase
in temperature.The contents should
be place in a suitable receptacle, a
cardboard box or drum that can be
sealed. Keep anyone not involved in
the operation well away from the area
and inform them of the potential risk
of explosion. Do not contaminate the
soil and surface or underground
waters. If this does happen, summon
the fire brigade immediately.
No smoking – no sources of ignition.
Keep product clean and free from
contamination. Avoid any action that
is likely to generate shock or friction.
Do not drink or eat when handling
the product.
Boosters_2014_Layout 1 09/06/2014 09:45 Page 4
DATA
HANDLING AND STORAGE continued...
Storage
Must be stored in accordance with
Manufacture and Storage of
Explosives Regulations 2005. Handle
cases with care. Do not open cases
in magazines or whilst in transit or
when loading or unloading from
vehicles. Keep the product clean
and free from contamination.
EXPOSURE CONTROL / PERSONAL PROTECTION
UK Occupational
Exposure Standards
Respiratory Protection
Hand Protection
Eye Protection
None assigned
Not required under normal
conditions of use. Do not inhale
combustion fumes.
Wear gloves
Not required under normal
conditions of use.
Body Protection
Wear overalls
Products:
PHYSICAL AND CHEMICAL PROPERTIES
Physical State
Components are sealed in a rigid
plastic container
Colour
Yellow container
Melting Point (deg C)
A5 (RDX) melts and decomposes
at about 200˚C
Odour
None
Solubility in Water (kg/m3)
Insoluble
Decomposition Temp. (deg C)
Products:
STABILITY AND REACTIVITY
200˚C
Conditions to Avoid
High temperatures, impact, friction,
flames, sparks and static discharge
Vapour Density
Relative vapour density
(explosive)1000 for A5
Stability
Stable at ambient temperatures
Materials to Avoid
Acids and Alkalis
Boosters_2014_Layout 1 09/06/2014 09:45 Page 5
BOOSTERS
STABILITY AND REACTIVITY continued...
Hazardous
Decomposition Products
Nitrogen Oxides, Oxides of Carbon,
including Carbon Monoxide may be
produced when the product is used.
Carbon Monoxide OEL = 50ppm,
58 mgm-3; Carbon Dioxide = 5000
ppm 9150 mgm-3; However the
amounts of toxic gases produced will
depend on many variables such as
method of initiation, rock type,
humidity etc.
TOXICOLOGICAL INFORMATION
Acute toxicity
Irritancy - Eyes
ECOLOGICAL INFORMATION
Mobility
In case of accidental breach of the
container, the toxicity of the
dispersed product is to be considered
similar to the main ingredient (RDX).
This can cause poisoning via the
respiratory way, ingestion and
absorption through the skin.
Symptoms: nervous fatigue with
oppression, insomnia, headache,
vomiting and possible epileptic crisis.
LD50 oral: 100mg/kg
TDLo mouse (female) 20mg/kg
Teratogenic Effect
TDLo mouse (male) 3g/kg
TLV: 1.5mg/m3 (Hexogen Powder)
Irritant
In normal use, the product is in a
plastic container. In case of
accidental breach of the container,
Eco-Toxicological properties have to
be considered as similar to RDX:
Micro-Toxicity mg/ml, EC50
Degradability Persistence: BOD7
0,02 g/g, COD 0,35 g/g BOD7/COD7
0,057
Bio-Adding Potential LogPow=1,62
Toxicity for the water and other data.
Harmful for the aquatic organisms.
Boosters_2014_Layout 1 09/06/2014 09:45 Page 6
DATA
DISPOSAL
Product Disposal
Container Disposal
TRANSPORT INFORMATION
UK Transport Information
UN Number
UN Class
ADR/RID Substance Id No
ADR/RID – Description
ADR/RID – Class
IMDG – Proper Shipping Name
Contact supplier
The recommended method of
destruction for empty boxes is
by burning
Must be in accordance with the
Carriage of Dangerous Goods
by Road 2009 (as amended)
UN0042
1.1D
UN0042
BOOSTERS without detonator
1.1D
BOOSTERS without detonator
IMDG – Class
1.1D
Labelling Information
Labelled in accordance with
Carriage of Dangerous Goods
Regulations 2011
REGULATORY INFORMATION
R Phrases
S Phrases
OTHER INFORMATION
UK Legislation
MSDS first issued
R2
S35, S41, S45
Subject to Explosives Act 1875,
Manufacture and Storage of
Explosives Regs 2005 and
Associated Legislation and
Approved Codes of Practice
04/12
NOTICE:FOR FURTHER INFORMATION CONTACT
EPC-UK EXPLOSIVES ENGINEERING DEPARTMENT
Tel :00-44-1773-832253
Product guide covers_2014_Layout 1 09/06/2014 10:50 Page 5
BULK
EMULSIONS
Complete range of pumpable
waterproof emulsions for every
application delivered directly to
the shot hole via bespoke
delivery systems.
Gassed products: Blendex 70 - 100 and aluminised Blendex are gassed to a density
of 1.00 - 1.15 kg / I, depending on the diameter and depth of hole.
The average product density down the hole is higher due to compression of the product.
The velocity of detonation is the median value from measurements down shot holes in normal blasts.
This information is given without warranty and can not cover all conditions of use.
Users should undertake their own tests to ensure the suitability of the products for their own particular purposes.
5
Bulk Emulsions_2014_Layout 1 09/06/2014 09:49 Page 1
BULK EMULSIONS
BLENDEX 70 and BLENDEX 80
BLENDEX 70 and BLENDEX 80 are medium
density bulk products that are pumped directly into
shotholes from Multiblend mixer trucks. Both
products are suitable for use in hole diameters
greater than or equal to 85 mm even where ground
water and strata conditions are severe.
BLENDEX 100
BLENDEX 100 is a medium/ high density bulk
product pumped direct into the shothole. This
product is suitable for use in hard rock conditions
or where less gas yield is desired.
All Blendex products are booster sensitive only,
and to optimise performance it is recommended
that 400/450g cast pentolite primers are used to
initiate the products. The sensitivity of BLENDEX
emulsion blends is achieved by adding gassing
agents and as such the product is not fully
sensitised until gassing has taken place.
Bulk Emulsions_2014_Layout 1 09/06/2014 09:49 Page 2
Multiblend vehicles are mixer trucks capable
of mixing and delivering the BLENDEX range
of explosives. Each Multiblend truck is
optimised to deliver specific products within
the BLENDEX range.
All Blendex compositions are gassed to a
density range shown in the table.
The actual density used depends on the
diameter and depth of hole. The average
product density at the bottom of drillholes
may be higher due to static compression of
the product.
All of the velocity of detonation figures
quoted are the median value from
measurements taken down shot holes in
actual blast conditions.
Bulk Emulsions_2014_Layout 1 09/06/2014 09:51 Page 3
BULK EMULSIONS
PRODUCT AND COMPANY IDENTIFICATION
Trade Names
Product Description
Recommended Use
Blendex 30, 50, 70, 75, 80, 85 & 100
and Aluminised Blendex.
The number after Blendex indicates
the approximate percentage of
emulsion matrix in the product.
Blendex products are site mixed bulk
emulsion explosives produced
from RC7192 emulsion matrix.
Emulsion matrix is essentially an
aqueous solution of ammonium
nitrate emulsified in oil. Blendex
products may also contain
ammonium nitrate prills, fuel oil,
aluminium and/or gassing agents
Blendex explosives are mixed on-site
and intended for immediate use as a
general explosive column charge.
Aluminised Blendex may also be
used as a base charge. Blendex
products described here are suitable
for use in diameters greater than or
equal to 85 mm, depending on
primer/use conditions. Other products
are available for use in small
diameters.
Blendex 30 and 50 are augured into
the shot hole while Blendex 70 and
above are pumped.
Manufacturer / Supplier
EPC-UK EXPLOSIVES
Telephone Number
00-44-1773 832253
Address
Emergency Tel Number
e-mail
ROUGH CLOSE WORKS
CARNFIELD HILL
SOUTH NORMANTON
ALFRETON
DERBYSHIRE, DE55 2BE
00-44-1773 832253
info@epc-groupe.co.uk
Bulk Emulsions_2014_Layout 1 09/06/2014 09:52 Page 4
DATA
HAZARD IDENTIFICATION
Main Hazards
All products are EXPLOSIVE (E): Mass
explosion hazard. Risk of explosion by
shock, friction or fire. Blendex 30, 50
and 70, and aluminised Blendex 70
are also HARMFUL (Xn) containing
ingredients with a limited evidence of
a carcinogenic effect (diesel fuel and
thiourea). Blendex 30 and 50 also
contain ingredients harmful to aquatic
organisms and which may cause a
long term adverse effect in the
aquatic environment.
After Detonation Fumes
Detonation of the explosive produces
large quantities of suffocating gas.
Toxic gases may also be formed.
Health Effects – Eyes
Irritant.
Health Effects – Skin
Repeated skin contact may de-fat
the skin resulting in possible irritation
and dermatitis.
Health Effects – Ingestion
Ingestion in larger quantities, may
give rise to Gastro Intestinal
Disorders and in extreme cases,
particularly in children, formation
of Methaemoglobin (Blue Baby
Syndrome) and Cyanosis (indicated
by blueness around the mouth).
COMPOSITION / INFORMATION ON THE COMPONENTS
Product’s Significant Hazardous Ingredients
COMPOSITION/INFORMATION ON THE C
EINECS/CAS
Number
Ammonium
Nitrate
Thiourea
Process oil
Gas Oil /
Diesel
Sodium
Nitrite
Aluminium
Hazard
Symbols
Risk
Phrases
EINECS 229-347-8
O
R8, R9
CAS 6484-52-2
R22, R40
EINECS 200-543-5
Xn, N
CAS 62-56-6
R51/53, R63
EINECS 265-148-2
CAS 64742-46-7, or
Xn
R65
EINECS 265-158-7
CAS 64742-55-8
EINECS 269-822-7
R40, R51/53
Xn, N
CAS 068334-30-5
EINECS 231-555-9
O, T, N R8, R25, R50
EINECS 231-511-9
EINECS 231-072-3
Non–
CAS 7429-90-5
hazardous
30
50
(%)
Blendex
70
(%)
80100
(%)
Aluminised
Blendex
From From
B70
B80
(%)
(%)
>75
>75
<0.5
<0.5
>80
>80
>75
<0.2
<0.5
<0.5
1.53.0
2.53.5
3.56.5
3.04.0
0.51.5
Up to
0.2
Up to
0.2
N/A
N/A
N/A
2.5-4.5 3.5-5.0
–
0.5-1.0
N/A
≤8
Up to
0.2
Other ingredients which are non hazardous or present in quantities below their
hazardous significant level are not shown.
–
Up to
0.2
≤8
Bulk Emulsions_2014_Layout 1 09/06/2014 09:52 Page 5
BULK EMULSIONS
FIRST AID MEASURES
Eyes
Skin
Ingestion
Inhalation
Advice to Physicians
FIRE FIGHTING MEASURES
Extinguishing Media
Special Hazards of Product
Irrigate thoroughly with water
for at least 15 minutes.
Wash thoroughly with soap
and water.
Immediately drink plenty of water
and seek medical advice
Remove person to fresh air. If
symptoms persist seek medical
advice. A person suffering from
inhalation of after detonation fumes
must be removed to fresh air, receive
medical attention and stay under
medical observation for at least 48
hours. The person should lie down
until the doctor arrives
Eyes – Continue irrigation treatment
as for chemical burns.
Ingestion - Mild cases of
methaemoglobinaemia will lead to
cyanosis and in more severe cases
may produce unconsciousness.
Use water based extinguishers to
prevent fire reaching the Blendex
This material is explosive and may
burn to detonation. If the fire looks
likely to reach the Blendex retire to a
safe distance of at least 300 m and
cordon off the area.
Toxic and irritating gasses may be
produced in a fire.
ACCIDENTAL RELEASE MEASURES
Personal Precautions
Wear gloves and overalls
Spillages
Spillages at the point of use should
be scooped up, e.g. with a plastic
shovel and included with the
explosives in a borehole.
Environmental Precautions
Do not allow to enter a water course
Bulk Emulsions_2014_Layout 1 09/06/2014 09:52 Page 6
DATA
HANDLING AND STORAGE
Handling
Storage
No smoking – no sources of ignition.
Keep product clean and free from
contamination
Should not be stored - bulk loaded at
point of use. If loaded holes are left
overnight, a sentry should be placed.
Any storage of product samples in a
container or package would need to
comply with the Manufacture and
Storage of Explosives Regulations.
Products:
EXPOSURE CONTROL / PERSONAL PROTECTION
UK Occupational
Exposure Standards
There is no occupational exposure
standard for the products themselves.
The ingredients in the products include
Oil: 8hr TWA for oil mist 5mg/m3.
Respiratory Protection
Not applicable
Eye Protection
Wear safety glasses
Hand Protection
Body Protection
Wear gloves. Suitable gloves may
include: Nitrile, Neoprene,
Fluor-elastomer or PVC
Wear overalls, preferably with
Velcro closures.
Products:
PHYSICAL AND CHEMICAL PROPERTIES
Physical State
Colour
Odour
Viscous fluid containing varying
amounts of suspended solids.
(ammonium nitrate and aluminium)
Light brown/white.
(Aluminised Blendex is grey)
Slightly oily/diesel smell. May also
smell of vinegar
pH
Ca 4-5
Solubility in Water (kg/m3)
Essentially insoluble, though water
will leach ammonium nitrate out of
the Blendex over time.
Explosive Properties
Blendex is a UN Class 1 explosive
Bulk Emulsions_2014_Layout 1 09/06/2014 09:52 Page 7
BULK EMULSIONS
PHYSICAL AND CHEMICAL PROPERTIES Continued...
Density (kg/m3)
Ca 1000-1200 when gassed in
density pot. May compress to higher
densities in the borehole.
Decomposition Temp. (deg C)
>150 oC
Stability
Stable at normal temperatures, but
may crystallise within 1 month.
STABILITY AND REACTIVITY
Conditions to Avoid
Materials to Avoid
Hazardous Decomposition
Products
High temperatures, impact, friction,
flames, sparks and static discharge
Acids and Bases
Besides residual amounts of
unreacted product, the after
detonation fumes may include the
following gases (figures are their
workplace exposure limits):
Carbon Dioxide: 8 hr=5000 ppm,
9150 mg/m3; 15 min = 15,000 ppm,
27,400 mg/m3.
Carbon Monoxide: 8 hr=30 ppm,
35 mg/m3; 15 min = 200 ppm,
232 mg/m3.
Nitrogen Monoxide: The previous
OES for nitrogen monoxide (8hr =25
ppm, 31 mg/m3) was withdrawn, as it
may not be adequate to protect
occupational health. The CHAN
where the HSE recommended that
exposure to nitrogen monoxide
should not exceed 1 ppm has been
suspended. Users should aim to
follow ALARP (as low as reasonably
practical) principles (see ref [1]).
Nitrogen Dioxide: The previous OES
for nitrogen dioxide (8hr = 3 ppm, 5.7
mg/m3) has been withdrawn, as it
may not be adequate to protect
occupational health. The CHAN
where the HSE recommended that
exposure to nitrogen dioxide should
not exceed 1 ppm has been
Bulk Emulsions_2014_Layout 1 09/06/2014 09:52 Page 8
DATA
STABILITY AND REACTIVITY continued...
suspended. The amounts of toxic
gases produced will depend on many
variables such as method of
initiation, rock type, humidity etc.
Generally do not approach the blast
area until the fumes have dissipated.
TOXICOLOGICAL INFORMATION
Eyes
May cause irritation following contact.
Inhalation
Avoid breathing vapours as in high
concentration these may be irritating
Skin
Ingestion
CMR Effects
ECOLOGICAL INFORMATION
Ecotoxicity
Mildly irritant. Prolonged and
repeated contact may be harmful to
the skin. Prolonged and repeated
contact with the fuel oil/gas oil
present in Blendex 30-70 may lead
to more serious skin disorders
including skin cancer.
The following are LD50 values for
ingredients in Blendex
All Blendex:
Ammonium Nitrate >2,000 mg/kg (rat)
Process Oil
>5,000 mg/kg (rat)
Thiourea
1,750 mg/kg (rat)
Blendex 30-70:
>5,000 mg/kg (rat)
Fuel Oil/gas Oil
Blendex 50-100:
Sodium nitrite
85 mg/kg
Acetic acid
3310 mg/kg (rat)
The ingestion of ammonium nitrate can produce
methaemoglobinaemia.
Thiourea has limited evidence of a
carcinogenic effect and is classified
as carcinogenic Cat 3.
Gasoil also has limited evidence
of a carcinogenic effect (R40).
Blendex 30 and 50 contain sufficient
fuel oil/gas oil and thiourea to be
classified by the conventional
method as R52/53: Harmful to
Bulk Emulsions_2014_Layout 1 09/06/2014 09:52 Page 9
BULK EMULSIONS
ECOLOGICAL INFORMATION Continued...
Ecotoxicity
Continued...
Mobility
Persistence/Degradability
Bioaccumulation Potential
aquatic organisms, may cause long
term adverse effects in the aquatic
environment
Blendex is a viscous liquid.
The water soluble Ammonium nitrate
will be leached out of the Blendex by
water over time.
The mobility of the various ingredients:
Ammonium Nitrate: When not
protected by the emulsion, the
ammonium nitrate dissolves freely
in water.
Thiourea: Soluble in water when not
protected by the emulsion
Sodium Nitrite: readily soluble in
water when not protected by the
emulsion.
Gas Oil: Some mobility in soils
Ammonium Nitrate: The ammonium
nitrate follows the natural
nitrification/denitrification cycle.
Process oil: Readily biodegradable
Gas oil: Inherently biodegradable
with hydrocarbon components
degraded by microorganisms. Lighter
components volatilise, and in air
undergo photolysis to give half lives
of less than a day. Photoxidation of
liquid hydrocarbons on water
surfaces also contributes to the loss
process. Adsorbed hydrocarbons
from gas oils will slowly degrade,
both in water and soil.
Ammonium nitrate does not show
any bioaccumulation potential
Gas oils: have the potential to bio
accumulate, but metabolic processes
may reduce this tendency
Bulk Emulsions_2014_Layout 1 09/06/2014 09:52 Page 10
DATA
DISPOSAL
Product Disposal
TRANSPORT INFORMATION
UK Transport Information
EU Transport
The product is an explosive and must
be treated as such. Under the
supervision of an expert, the product
may be destroyed by detonation in a
borehole or by burning at an
approved site. For more guidance
see the HSE/CBI Explosives Industry
Group publication: “Guidance for the
Safe Management of the Disposal of
Explosives”, January 2007.
The product is produced by mixing on
site for immediate use, so it would
not be transported. Transport of
samples will be as an explosive in
accordance with the appropriate
regulations. For road/rail there is the
Carriage of Dangerous Goods, etc
Regulations 2011
These are aligned with ADR, as
required by Council directive
2008/68/EC, but may have additional
requirements /modifications (see also
“The Secretary of State’s document”).
Road transport must be in
accordance with ADR 2009
UN Number
UN 0241
UN Name
Explosive, Blasting, Type E
UN Class
Labelling Information
1.1 D
Labelled in accordance with
Carriage of Dangerous Goods
and Use of Transportable Pressure
Equipment Regulations 2011.
Bulk Emulsions_2014_Layout 1 09/06/2014 09:52 Page 11
BULK EMULSIONS
TRANSPORT INFORMATION continued..
Labelling Information
REGULATORY INFORMATION
The Chemical Hazard Information
and Packaging for Supply
Regulations 2009, SI 0716
(note regs 6-11 do not apply to the
explosives covered by this MSDS)
Hazard Symbols, Risk Phrases and Safety Phrases
Product
Blendex 30, 50
Blendex 70
Blendex 80-100
Aluminised Blendex 70
Aluminised Blendex 80
UK Legislation continued
EC Regulations
Hazard
Symbols
E, Xn
E, Xn
E,
E, Xn
E
Risk
Phrases
R2, R40,
R52/53
R2, R40
R2
R2, R40
R2
Safety
Phrases
S35, S36/37,
S61
S35, S36/37
S35,
S35, S36/37
S35
Manufacture and Storage of
Explosive Regulations 2005,
(as amended). The Control of
Explosives Regulations 1991
(as amended). Placing on the Market
and Supervision of Transfers of
Explosives Regulations 1993
(as amended). Carriage of
Dangerous Goods, etc Regulations
2011. Explosives
Act 1875 (what remains). Quarries
Regulations 1999. The Chemical
Hazard Information and Packaging
for Supply Regulations 2009 Si 2009
No 716. The Control of Substances
Hazardous to Health Regulations,
2002 (as amended)
Registration, Evaluation, Authorisation
and Restriction of Chemicals, EC Reg
1907/2006, as amended.
Classification, Labelling and
Packaging of Substances
and Mixtures, EC Reg 1272/2008.
Note this does not apply to mixtures
until June 2015, as such this data
sheet does not show the labelling
requirements under this reg.
Bulk Emulsions_2014_Layout 1 09/06/2014 09:52 Page 12
DATA
OTHER INFORMATION
MSDS first issued
Meaning of R phrases
R2
R8
R9
R22
R25
R26/27/28
R33
R36/37/38
R40
R50
R50/53
R51/53
R52/53
R63
R65
OTHER INFORMATION
Meaning of S phrases
S35
S36/37
S61
03/96 Issue 11
Deleted references to CLER.
Risk of explosion by shock, friction,
fire or other sources of ignition
Contact with combustible material
may cause fire.
Explosive when mixed with
combustible material.
Harmful if swallowed.
Toxic if swallowed.
Very toxic by inhalation, in contact
with the skin and if swallowed.
Danger of cumulative effect.
Irritating to eyes, respiratory system
and skin.
Limited evidence of a carcinogenic effect.
Very toxic to aquatic organisms.
Very toxic to aquatic organisms, may
cause long term adverse effect in the
aquatic environment.
Toxic to aquatic organisms, may
cause long term adverse effect in the
aquatic environment.
Harmful to aquatic organisms,
may cause long term adverse effect
in the aquatic environment.
Possible risk of harm to the
unborn child.
Harmful may cause lung damage
if swallowed
This material and its container must
be disposed of in a safe way.
Wear suitable protective clothing
and gloves.
Avoid release to the environment.
Refer to special instruction/safety
data sheets.
Bulk Emulsions_2014_Layout 1 09/06/2014 09:52 Page 13
BULK EMULSIONS
OTHER INFORMATION Continued...
References 1.
“Occupational Exposure To Nitrogen
Monoxide in a Tunnel Environment –
Best Practice Guide” First edition,
British Tunnelling Society, 2008
NOTICE:FOR FURTHER INFORMATION CONTACT
EPC-UK EXPLOSIVES ENGINEERING DEPARTMENT
Tel :00-44-1773-832253
Product guide covers_2014_Layout 1 09/06/2014 10:50 Page 6
DETONATING
CORD
EPC-UK supply a
comprehensive range
of detonating cords
sourced in Europe.
6
Detonating Cord_2014_Layout 1 09/06/2014 10:00 Page 1
DETONATING CORD
These cords can be used to initiate conventional
small diameter nitroglycerine based cartridged
explosives. The 20g/m intermediate cord has
been developed for use in demolitions. The higher
energy cords 40g/m to 100g/m can be used for
pre-splitting and smooth blasting, and in some
demolition operations.
Classification and Labelling
Detonating Cords are packaged as Class 1.1D
Articles UN No. 0065.
Name
Core load
in g/m
Velocity of
detonation
Green
12
7000
Daveycord 20
Green
20
7000
Daveycord 40
Green
40
6500
SElcord 100
Peach
100
>7000
Daveycord 12
Colour
i
Detonating Cord_2014_Layout 1 09/06/2014 10:01 Page 2
DATA
Tensile Strength
in kg
Outer Diameter
in mm
Length (m) / reel
Reels/box
80
5.2
125
4
80
6.2
100
4
80
8.3
100
4
>270
12.5
50
1
Detonating Cord_2014_Layout 1 09/06/2014 10:01 Page 3
DETONATING CORD
PRODUCT AND COMPANY IDENTIFICATION
Product Type
Detonating Cord
Product Description
The products contain Pentaerythritol
Tetranitrate (PETN), a white powder
enclosed in plastic tapes, wrapped
with man-made textile yarns, coated
with colour coded plastics, wound on
reels. The colour codings include
white, yellow, green and peach.
Finished cord diameters vary from
4.5 mm to 12.5 mm. Reels vary in
length from 100m to 200m, weighing
from 1.5 kgs to 14.5 kgs. Products
are packed in UN approved,
corrugated cardboard boxes.
All products are reliably initiated
by a standard No 8 detonator.
Trade Names
SEI Cord/Daveycord
Manufacturer/Supplier
EPC-UK EXPLOSIVES
Telephone Number
00-44-1773 832253
Address
Emergency Tel Number
e-mail
ROUGH CLOSE WORKS
CARNFIELD HILL
SOUTH NORMANTON
ALFRETON
DERBYSHIRE, DE55 2BE
00-44-1773 832253
info@epc-groupe.co.uk
Detonating Cord_2014_Layout 1 09/06/2014 10:01 Page 4
DATA
HAZARD IDENTIFICATION
Main Hazards
EXPLOSIVE
Health Effects – Skin
Unlikely to be absorbed under
normal conditions of use.
Health Effects – Eyes
Health Effects – Ingestion
The core contains a mildly
irritating dust.
Can cause headaches.
PETN is harmful if swallowed,
seek medical advice.
Health Effects – Inhalation
Can cause headaches.
Product Formal Name
Products include Daveycord 5g, 12g,
20g, 40g, 70g per metre and SEI
Cord 100g per metre. Other products
may be available on request.
COMPOSITION/INFORMATION ON THE COMPONENTS
Product Chemical Family
PETN based detonating cord.
R Phases
R2, R22, R44, R51
CAS Number
S Phases
FIRST AID MEASURES
Eyes
Skin
78-11-5 of PETN
S1, S15, S24, S28, S33, S35,
S40, S41, S45, S61
Irrigate thoroughly with water
for at least 15 minutes.
Wash thoroughly with soap and
water. If signs of strong skin
irritation seek medical advice.
Ingestion
Seek medical advice.
Advice to Physicians
This material is explosive. PETN
can lower blood pressure.
Inhalation
FIRE FIGHTING MEASURES
Extinguishing Media
Special Hazards of Product
Seek medical advice.
Use water based extinguishers
to prevent fire reaching the
detonating cord.
Explosive – burns to detonation. If
the fire reaches the detonating cord,
retire to a safe distance (at least
300m) and cordon off the area.
Detonating Cord_2014_Layout 1 09/06/2014 10:01 Page 5
DETONATING CORD
ACCIDENTAL RELEASE MEASURES
Spillages
HANDLING AND STORAGE
Handling
Storage
Sweep up any small spillages, wet
with water , place into a receptacle
and contact suppliers. Make sure
impact, friction and any source of
spark is avoided.
No smoking – no sources of
ignition. Keep product clean and
free from contamination. Only cut
detonating cord with a sharp knife
on a wooden anvil or using
proprietary cutters.
Must be stored in accordance
with Manufacture and Storage of
Explosives Regulations 2005. Handle
cases with care. Do not open cases
in magazines or whilst in transit or
when loading or unloading from
vehicles. Keep the product clean
and free from contamination.
Storage temperature -30 C to+50 C.
Keep in a dry place.
O
O
EXPOSURE CONTROL / PERSONAL PROTECTION
UK Occupational
Exposure Standards
None assigned.
Respiratory Protection
Not applicable. Avoid breathing
fumes from detonation.
Eye Protection
Not applicable under normal
conditions of use.
Hand Protection
Wear gloves.
PHYSICAL AND CHEMICAL PROPERTIES
Physical State
PETN crystalline powder inside
twines of fabric and coated in plastic.
Odour
None.
Colour
Melting Point
White powder inside the cord.
Colour of outer plastic will depend
on product.
140°C.
Detonating Cord_2014_Layout 1 09/06/2014 10:01 Page 6
DATA
PHYSICAL AND CHEMICAL PROPERTIES continued...
Solubility in Water (kg/m3)
Insoluble.
Density (kg/m3)
1760.
Vapour Pressure (kPa)
Decomposition Temp. (deg C)
Zero.
190°C
Spontaneous Combustibility
Temp. (deg C)
200 - 205°C
Resistance to Friction
60 N
Conditions to Avoid
High temperatures, impact, friction,
flames, sparks and static discharge.
Resistance to impact
STABILITY AND REACTIVITY
Materials to Avoid
Hazardous Decomposition
3 Nm
Acids and bases.
Oxides of Carbon,
including Carbon Monoxide may be
produced when the product is used.
Occupational exposure limits are
Nitrous Oxide = 100ppm,
183 mgm¯3;Carbon Monoxide =
50ppm, 58 mgm¯3; Carbon Dioxide
= 5000 ppm, 9150 mgm¯3; However
the amounts of toxic gases produced
will depend on many variables such
as method of initiation, rock type,
humidity etc.
Products:
TOXICOLOGICAL INFORMATION
PETN
The PETN is contained in a
plastic sheath,
Acute effects high toxicity
For PETN Only in case of ingestion
irritation and corrosion effects LD50 rat (oral) = 19,500 mg/kg
Products:
ECOLOGICAL INFORMATION
Mobility
PETN; Powdery solid.
Insoluble in water
Product Disposal
Contact supplier.
Products:
DISPOSAL
Detonating Cord_2014_Layout 1 09/06/2014 10:01 Page 7
DETONATING CORD
DISPOSAL continued...
Container Disposal
TRANSPORT INFORMATION
UK Transport Information
UN Number
UN Class
The recommended method of
destruction for empty boxes is
by burning.
Must be in accordance with
Carriage of Dangerous Goods
Regulations 2011.
UN0065.
1.1 D
UN Packaging Group
Not applicable
ADR/RID Description
CORD, DETONATING, flexible.
ADR/RID Substance Id No
ADR/RID – Class
IMDG Proper Shipping Name
IMDG Class
REGULATORY INFORMATION
Labelling Information
R Phrases
S Phrases
EINECS Number
EC Annex 1 Number
OTHER INFORMATION
UK Legislation
MSDS first issued
UN0065
1.1 D.
CORD, DETONATING, flexible
1.1 D
Labelled in accordance with the
Carriage of Dangerous Goods
Regulations 2011
R2, R22, R44, R51.
S1, S15, S24, S28, S33, S35,
S40, S41, S45, S61.
201-084-3 for PETN.
201-084-3 for PETN.
Subject to Explosives Act 1875 and
Associated Legislation and
Approved Codes of Practice.
03/96
NOTICE:FOR FURTHER INFORMATION CONTACT
EPC-UK EXPLOSIVES ENGINEERING DEPARTMENT
Tel :00-44-1773-832253
Product guide covers_2014_Layout 1 09/06/2014 10:50 Page 7
ELECTRIC
DETONATORS
EPC-UK supply standard
electric detonators manufactured
by Davey Bickford in France.
The Daveydet Short Delay range consists of 21
delay numbers with a time interval of 25ms between
successive numbers in the range to give better
breakage and controlled vibration.
The Daveydet Half-Second range consists of 13
delay numbers with a time interval of 0.5 seconds
between successive numbers in the range.
Daveydet Medium Intensity detonators are suitable
for general blasting operations. For situations where
a higher degree of protection from electrical sources
such as radios, mobile phones etc. is required, the
Daveydet High Intensity detonators are more
suitable. The High Intensity detonator requires the
use of a high output exploder.
7
Electric detonators_2014_Layout 1 09/06/2014 10:04 Page 1
ELECTRIC
DETONATORS
Common features for standard
electric detonators
The detonator shell is made of Aluminium. The base of the
detonator tube is stamped with a letter Y to identify the
manufacturer. The delay period number Is printed on the
side of the detonator. Instantaneous detonators have no
markings on the base of the aluminium tube. The initiating
power of these detonators is equivalent to no. 10 strength
as a result of the compression of the 0.8g base charge.
Triple crimping of the detonator shell ensures excellent water
resistant characteristics:
2 days at 25 bars
8 days at 10 bars
28 days at 5 bars.
The twinned copper wires can support a tensile strength
of 10daN without internal disturbance of the fusehead assembly.
The resistance per unit length of twinned wires is 0.14W/m
for 0.56mm diameter copper wire and 0.095W/m for 0.7mm
diameter copper wire.
The lead wires of the detonator are copper and have
colour-coded insulation.
The wire coating is formed from PVC, which offers a
good resistance to abrasion.
Delayed action Daveydet detonators are available in the
following delay numbers:
• Short Delay series 1 to 20 inclusive
– delay interval 25 milliseconds
• Half Second series 1 to 10 inclusive
– delay interval 500 milliseconds.
Electric detonators_2014_Layout 1 09/06/2014 10:04 Page 2
DATA
The detonators have a plastic tag on one of the wires
that indicates the delay number of the detonator.
Detonator Type
Wire Colours
High Intensity
Instantaneous Detonators
Medium Intensity
Instantaneous Detonators
Medium Intensity
Short Delay Detonators
White
White
Yellow
White
Pink
Green
Red
Yellow
Medium Intensity Half
Second Detonators
The fuseheads in Daveydet detonators have the
following electrical characteristics:
Fusehead Resistance
Guaranteed
no fire current
Guaranteed all fire
current for one
detonator
Recommended
series firing current
Maximum no
fire energy
Minimum
operating energy
Medium Intensity
0.45 ohms
High Intensity
0.05 ohms
1.0 amps
7.0 amps
1.7 amps
13 amps
8mj/W
500mj/W
15mj/W
1000mj/W
0.65 amps
4.2 amps
The fuseheads in Daveydet detonators have the
following electrical characteristics:
• Short circuited lead
wires and shell
11kV
with 2000pF
28kV
with 3000pF
• Two ends of the
detonator lead wires
5kV
with 2000pF
28kV
with 3000pF
• One lead wire
and the shell
6kV with
2000pF
28kV
with 3000pF
Electric detonators_2014_Layout 1 09/06/2014 10:04 Page 3
DATA
ELECTRIC
DETONATORS
Behaviour to static electric discharge between:
Each fusehead is protected by an insulating anti-static sleeve.
EPC-UK also supply the Daveydet P instantaneous
and short delay range of detonators. These are approved for use in
coal and other safety lamp mines. The half second permitted range of
detonators is approved for use in certain circumstances underground
in coal and other safety lamp mines. The electrical characteristics of
these detonators are different to Medium Intensity Detonators.
For Seismic prospecting EPC-UK supply the Daveydet SR range of
detonators. These detonators have unique electrical characteristics
and cannot be fired in the same circuit as other detonators.
Classification and Labelling
Electric detonators with lead wire lengths between
2m and 12m are presented as twinned folded wires.
These detonators are classified 1.1B. The UN No. for transportation
is UN.0030.
Upon request detonators can also be packaged as 1.4B and the UN
No. for transportation is UN.0459.
Plain Detonators
Herica plain detonators for use with safety fuse can be supplied by
EPC-UK
For further details on these products please contact the Technical
Services department of EPC-UK
Electric detonators_2014_Layout 1 09/06/2014 10:05 Page 4
DATA
PRODUCT AND COMPANY IDENTIFICATION
Product Type
Electric Detonators various
Products Include
Davey Bickford Inst Electric Dets,
Davey Bickford Medium Firing
Current SD & Delay Electric Dets,
Davey Bickford High Firing Current
Davey Bickford Seismic Electric Dets,
Davey Bickford Daveydet P Inst
Permitted Dets, Daveydet P SD
Permitted Dets, Daveydet P Half
Second Permitted Dets,
Trade Names
Electric Detonators
Manufacturer / Supplier
EPC-UK EXPLOSIVES
Telephone Number
00-44-1773 832253
Address
Emergency Tel Number
e-mail
ROUGH CLOSE WORKS
CARNFIELD HILL
SOUTH NORMANTON
ALFRETON
DERBYSHIRE, DE55 2BE
00-44-1773 832253
info@epc-groupe.co.uk
Electric detonators_2014_Layout 1 09/06/2014 10:05 Page 5
ELECTRIC
DETONATORS
HAZARD IDENTIFICATION
Main Hazards
EXPLOSIVE ARTICLE
Physical Data
Components used in the
manufacturing of Davey Bickford
electric detonators are: Primary
explosives 2g max and / or Secondary
explosives 2g max and / or Delay
composition. They are not directly in
contact with users. If case of accidental
contact with one of those components,
please contact EPC-UK immediately
for further information.
COMPOSITION/INFORMATION ON THE COMPONENTS
FIRST AID MEASURES
General instructions
Not applicable
Contact with skin
Not applicable
Inhalation
Contact with Eyes
Ingestion
Other information
FIRE FIGHTING MEASURES
Extinguishing Media
Hazards
Special firefighting
Equipment
Not applicable
Not applicable
Not applicable
Components are contained in a
metallic shell. Do not put into a
waste bin or dump.
Use water based
extinguishers to prevent fire
reaching the detonators
Can explode with variable effects
according to the packaging – risk
division 1.1 : risk of mass explosion;
Risk division 1.4S no instantaneous
mass explosion of a whole box.
Use water based extinguishers to
prevent fire reaching the detonators
Upon intervention, use a filter mask
with cartridge or breathing apparatus.
WARNING the risk of explosion may
remain latent even after the fire has
stopped, depending on the condition
of products.
Electric detonators_2014_Layout 1 09/06/2014 10:05 Page 6
DATA
FIRE FIGHTING MEASURES Continued...
Other information
In case of fire near the products:
use extinguishers and all available
watering means. In case of fire in a
magazine or during transportation:
do not fight fire but withdraw
personnel immediately, up to the
necessary safety distance (300 m).
Evacuate the immediate perimeter
of the fire and block accesses
ACCIDENTAL RELEASE MEASURES
Individual precautions
Isolate the area
Collection method
Never handle damaged detonators.
Undamaged detonators can be
repacked in packagings similar to
original boxes. Never use damaged
products or partially damaged
products (that have been shocked
or submitted to excessive
temperatures, etc.)
Precautions for
environment protection
Other information
HANDLING AND STORAGE
Handling
Storage
Not applicable
In case of potentially or visibly
damaged products, contact
immediately EPC-UK to obtain
the necessary information to
handle those detonators.
Handle with care, avoid all forms of
commotion (impact and friction on
products and their packagings, keep
products and packagings away from
heat, flames and sparks. Keep out of
reach of children. The control and
implementation of pyrotechnic
articles must be done by
authorized staff. Max measuring
current for testing circuits : 10 mA.
Storage temperature : -10°C +50°C
Keep away from damp. Respect all
regulations on the storage of
Electric detonators_2014_Layout 1 09/06/2014 10:05 Page 7
ELECTRIC
DETONATORS
HANDLING AND STORAGE Continued...
Storage
Continued...
hazardous goods. Do not store with
other dangerous goods not being of
Class 1, nor with uncompatible goods
of Class 1.
EXPOSURE CONTROL / PERSONAL PROTECTION
Individual Protection
Respiratory protection: Avoid
breathing fumes from detonation.
- Protective gloves: Not applicable
- Eye protection: Not applicable
- Ear protection: Use ear protectors
if close to the detonation.
PHYSICAL AND CHEMICAL PROPERTIES
Physical State
Solid
Decomposition Temp. (deg C)
Avoid temperatures above 50°C.
Appearance
Odour
pH
Boiling point
Flash point
Flammable limits
Explosive properties
Copper or aluminium tubes with
different coloured wires (depending
on product type) leading from them.
Vapor pressure
Density
Solubility
Solubility in water
Coeff of share
n-octanol/ water
Viscosity vapor density
Evaporation rate
Not applicable
Not applicable
Not applicable
Not applicable
Not applicable
Explosive detonator, designed
for initiating explosives.
Not applicable
Not applicable
Not applicable
Not applicable
Not applicable
Not applicable
Not applicable
Not applicable
Stability
Shelf life is shown on packaging
STABILITY AND REACTIVITY
Conditions to Avoid
Avoid any exposure to high
temperature, to impact, friction
and electrostatic discharges or
stray currents
Electric detonators_2014_Layout 1 09/06/2014 10:05 Page 8
DATA
STABILITY AND REACTIVITY Continued...
Materials to Avoid
Hazardous Decomposition
Products
TOXICOLOGICAL
Toxicinetics : metabolism
and distribution
Acute effects, high toxicity,
irritation, corrosive effects
Sensitization
Toxicity by repeated ingestion
CMR effects (carcinogenicicity,
mutagenicity, reprotoxicity)
Other information
ECOLOGICAL
Acids or alkalis. Dangerous goods
outside Class1 and all uncompatible
materials of class 1.
Lead fumes and possibility of
Oxides of carbon and nitrogen.
Shrapnel is ejected with force.
Not applicable
Not applicable
Not applicable
Not applicable
Not applicable
Object made to detonate
Ecotoxicity
Not applicable
Persistency and wearing away
Not applicable
Mobility
Not applicable
Bioaccumulation potential
Not applicable
Other notable effects
Not applicable
Result of PBT evaluation
DISPOSAL
Product Disposal
Container Disposal
TRANSPORT INFORMATION
UK Transport Information
UN Number
UN Class
Not applicable
Contact EPC-UK
Empty containers may be burnt
on site by authorised staff.
Ensure boxes are empty.
Must be in accordance with
Carriage of Dangerous Goods,
etc Regulations 2011.
UN0030, UN0255, UN0456.
1.1B, 1.4B, 1.4S
Electric detonators_2014_Layout 1 09/06/2014 10:05 Page 9
ELECTRIC
DETONATORS
TRANSPORT INFORMATION Continued...
ADR/RID Substance Id No
UN0030, UN0255, UN0456.
ADR/RID – Class
1.1B, 1.4B, 1.4S
ADR/RID – Description
IMDG – Proper Shipping Name
IMDG Class
REGULATORY INFORMATION
Labelling Information
R Phrases
S Phrases
OTHER INFORMATION
UK Legislation
MSDS first issued
Detonators electric for blasting
DETONATORS, ELECTRIC FOR
BLASTING.
1.1B, 1.4B, 1.4S
In accordance with the Carriage
of Dangerous Goods,
etc Regulations 2011.
R2
S47 (50°C)
Subject to Explosives Act 1875,
the Manufacture and Storage
of Explosives Regs 2005 and
associated Legislation and Approved
Codes of Practice.
05/12
NOTICE:FOR FURTHER INFORMATION CONTACT
EPC-UK EXPLOSIVES ENGINEERING DEPARTMENT
Tel :00-44-1773-832253
Product guide covers_2014_Layout 1 09/06/2014 10:50 Page 8
ELECTRONIC
DETONATORS
EPC-UK can supply detonators
containing a fully programmable
electronic delay.
The use of these detonators will
allow the user to more accurately
control the firing time of individual
explosive charges thus enabling
the firing of very sophisticated blast
designs offering the user a much
greater degree of control
over environmental disturbance
and fragmentation.
8
Electronic Detonators_2014_Layout 1 09/06/2014 11:12 Page 1
ELECTRONIC
DETONATORS
Digishot
The Digishot system is a fully programmable detonation system
manufactured by Detnet suitable for use in most surface
blasting applications. Available in a range of cable lengths each
detonator can be programmed to initiate at intervals of 1
millisecond, up to a maximum delay of 20,000 milliseconds
across 63 rows and 15 decks. Each detonator benefits from a
rugged over extruded down hole cable with a simple quick
release plug used for programming. Each detonator is
connected using a lightweight two wire surface cable attached
to the detonator using a clip connection.
Simple and safe to operate the system can be programmed
manually using the modern, intuitive tagger or initiation patterns
can be created in advance and uploaded to the circuit on the
blast day using stand-alone computer software. This complete
flexibility means Digishot is suitable for use in ‘Hybrid’ initiation
systems ensuring both excellent fragmentation and cost control.
Detonators are manufactured to the highest standards and
have a number of safety features including;
• 550N cable tensile strength
• Pressure tested to 500Kpa over a 7 day period
• Very high resistance to electrical currents
During development phase detonators were exposed to
110MPa pressure and subsequently fired safely, in a separate
test circuit boards were exposed to 10,000V without detonation.
The Digishot system is simple, safe and flexible, capable of
meeting all the demands for modern efficient blast design.
Electronic Detonators_2014_Layout 1 09/06/2014 11:14 Page 2
DATA
PRODUCT AND COMPANY IDENTIFICATION
Product Type
Electronic Detonators
Manufacturer / Supplier
EPC-UK EXPLOSIVES
Trade Names
Address
Telephone Number
Emergency Tel Number
e-mail
Digishot detonators
ROUGH CLOSE WORKS
CARNFIELD HILL
SOUTH NORMANTON
ALFRETON
DERBYSHIRE, DE55 2BE
00-44-1773 832253
00-44-1773 832253
info@epc-groupe.co.uk
Electronic Detonators_2014_Layout 1 09/06/2014 11:14 Page 3
ELECTRONIC
DETONATORS
HAZARD IDENTIFICATION
Main Hazards
EXPLOSIVE
Electronic Detonators are designed
to explode with a substantial release
of energy and should therefore be
handled with care. Detonators must
not be subjected to impact, friction
or exposed to heat or flame.
Classification: E; R3
Additional Hazards: After detonation
dust and fumes may be harmful by
inhalation on repeated exposure
(lead poisoning) Effects and
symptoms: Pre use: Hazardous
materials are encapsulated, no
exposure during normal handling is
therefore expected.
Post use: Minimal exposure risk is
expected as quantities of hazardous
components used are small.
COMPOSITION / INFORMATION ON THE COMPONENTS
Explosive Ingredients
Other Ingredients
Lead azide, PETN (pentaerythritol
tetranitrate), Fusehead composition.
Glass, quartz, phosphor bronze,
PVC, Nitrile, ink, resin, silicon,
tantalum, ceramic, copper,
aluminium, gold, tin, Santoprene,
Arnite, polypropylene, nickel,
chromium, iron.
Chemical Name
Lead Compounds
CAS No.
7439-92-1
%
<1
EC Number
231-100-4
Lead Azide
13424-46-9
<1
236-542-1
<2
201-084-3
Pentaerythritol
78-11-5
Tetranitrate (PETN)
Classification
Repr. Cat. 1;R61
Repr. Cat. 3;R62
Xn; R20/22
R33
N; R50/53
E; R3
Repr. Cat. 1;R61
Repr. Cat. 3;R62
Xn; R20/22
R33
N; R50/53
E; R3
Electronic Detonators_2014_Layout 1 09/06/2014 11:14 Page 4
DATA
COMPOSITION / INFORMATION ON THE COMPONENTS Continued..
Recommended use
Appearance
FIRST AID MEASURES
Ingestion
Eye Contact
Skin Contact
Inhalation
Notes to physician
FIRE FIGHTING MEASURES
Extinguishing Media
Special Hazards of Product
A precision initiation system for
explosive charges used in
commercial mining.
A copper tube of 7.5mm OD and
94±0.25mm in length and may have
the wording DANGEROUS –
BLASTING CAP - EXPLOSIVE and
DANGER – DETONATEUR EXPLOSIF printed on the tube.
A coloured yellow or red cable is
secured in the tube by means of a
compliant PVC crimp plug.
Not normal route of entry, but obtain
medical attention A.S.A.P. Make
physician aware of explosive
properties of ingested material.
Unlikely, unless detonator is fired.
Obtain medical attention immediately.
Not harmful, unless detonator is fired.
Treat for high velocity trauma, stop
bleeding and obtain medical
attention A.S.A.P.
Unlikely, unless detonator is fired.
Remove patient from NO2 exposure
to clean air and obtain medical
attention ASAP.
Treat symptomatically. Keep under
observation for Lead poisoning.
Use water based extinguishers to
prevent fire reaching the detonators
Explosive – If the fire looks likely to
reach the detonators, retire to a safe
distance (300 m) and cordon off the
area. If a detonation occurs within
the mass, this may be transferred to
other detonators. Severe explosion
when exposed to heat. Evolves toxic
fumes (hydrogen chloride and
Electronic Detonators_2014_Layout 1 09/06/2014 11:14 Page 5
ELECTRONIC
DETONATORS
FIRE FIGHTING MEASURES Continued...
Special Hazards of Product
Continued...
phosgene) from the PVC when
heated to the decomposition state.
Fire fighting further advice
Withdraw from fire and let it burn.
Promptly isolate the scene by
removing all persons from the
vicinity of the incident if there is
a fire. First move people out of
line-of-sight of the scene and
away from windows.
DO NOT FIGHT FIRES
INVOLVING EXPLOSIVES.
ACCIDENTAL RELEASE MEASURES
Spillages
Products:
HANDLING AND STORAGE
Handling
Collect up undamaged articles, wipe
carefully with clean, damp cloths,
repack into cardboard boxes. Seal
with adhesive tape. Seek advice
from the supplier. Damaged or
cracked detonators may be very
sensitive to sources of ignition.
Do not pick up or move damaged
detonators. Shut off all possible
sources of ignition.
Evacuate the area and then inform
the relevant Authorities or
responsible person immediately.
In the case of a transport accident,
notify the local Authorities/Police
Station, the transporting company
and supplier.
No smoking, no sources of ignition.
Handle carefully. Do not open cases
in magazine or whilst in transit or
when loading or unloading from
vehicles. Keep the articles clean and
free from contamination. Static
electricity, stray electric currents and
use near CB radios and transmitters
should be avoided. Do not carry in
plastic bags. Do not exert force on
detonator lead wires.
Electronic Detonators_2014_Layout 1 09/06/2014 11:14 Page 6
DATA
HANDLING AND STORAGE Continued...
Handling
Continued...
Storage
Handle with great care. Impact, heat
or flame may cause an explosion
In a well-ventilated magazine suitably
licensed for UN Class 1.1B or 1.4S
(specified on packaging) and in
accordance with the Manufacture and
Storage of Explosives Regulations 2005.
EXPOSURE CONTROL / PERSONAL PROTECTION
Occupational exposure limits
Ingredient Name
Lead and lead
inorganic compounds
Occupational Exposure Limits
TWA: 0.15 mg/m3 (8 hours)
80/1107/EEC (Europe, 1998)
STEL: 10mg(PB)/m3 (OSHA)
TWA - the Time-Weighed Average airborne concentrations over an
eight-hour working day, for a five-day working week over an entire
working life. Short term OEL (STEL) - the average airborne
concentration over a 15-minute period, which should not be exceeded
at any time during a normal eight hour working day. According to
current knowledge these concentrations should neither impair the
health of, nor cause undue discomfort to nearly all workers.
Absorption through the skin may be a significant source of exposure.
The exposure standard is invalidated if such contact should occur.
Engineering measures
Eye Protection
Other protection
Keep materials in their original
packaging to prevent exposure.
Provide adequate ventilation
and where possible ear protection
when firing.
Where possible wear eye protection
when handling detonators
Where possible, wear safety
non-static producing clothing while
handling the detonators.
PHYSICAL AND CHEMICAL PROPERTIES
Appearance
A copper detonator with either yellow
or red wiring. There may be printed
Electronic Detonators_2014_Layout 1 09/06/2014 11:14 Page 7
ELECTRONIC
DETONATORS
PHYSICAL AND CHEMICAL PROPERTIES Continued...
Appearance
Continued...
on the side of the body, the words
DANGEROUS- BLASTING CAP EXPLOSIVE and DANGER –
DETONATEUR - EXPLOSIF in black.
Specific Gravity (20 C): Melting Point ( C)
N App
N App
o
Boiling Point ( C):
N App
Vapour Pressure (20 C):
o
N App
Flash Point ( C):
N App
o
Sublimation Point (20 C):
o
pH:
N App
o
o
N App
Auto-ignition Temp ( C):
% Volatile by volume:
N Av
100
o
Evaporation Rate:
N App
Rel Vapour Density (air=1):
N App
Decomp.Point ( C):
100
o
Flammability Limits (%):
N App
Viscosity:
N App
Solubility in water:
N App
N AV = Not available, N App = Not applicable
STABILITY AND REACTIVITY
Stability
Shelf life is shown on packaging.
Contains explosive material. Do not
expose to temperatures higher than
100 degrees Celsius.
Conditions to Avoid
Heat, static, sparks, flames, shock,
friction - may cause an explosion.
Materials to Avoid
Acids and alkalis.
Hazardous Decomposition
Oxides of carbon, nitrogen and lead.
Products
Shrapnel is ejected with force.
TOXICOLOGICAL INFORMATION
Inhalation
Skin contact
Eye contact
Ingestion
Lead and fumes may cause effects
similar to those described in long
term exposure.
When explosion occurs, treat for high
velocity trauma,stop bleeding and
obtain medical attention A.S.A.P.
Fumes from firing may cause eye
irritation.
Fumes from firing may cause
irritation to gastrointestinal tract.
Electronic Detonators_2014_Layout 1 09/06/2014 11:14 Page 8
DATA
TOXICOLOGICAL INFORMATION Continued...
Ingestion
Continued...
Keep under observation for possible
lead poisoning.
Long-term exposure
Long-term exposure to low
concentrations of Lead fumes may
result in altered haemoglobin
breakdown, kidney damage,
anaemia, and central and peripheral
nervous system damage.
Acute Toxicity:
Ingredient Name
Test
Lead and inorganic
compounds
Pentaerythritol
Tetranitrate
Result
Route
Species
LDLo
160mg/kg
Oral
Pigeon
LD50
1660mg/kg
Oral
Rat
LDLo
7000mg/kg
Oral
Mouse
Special Remarks on Toxicity to Animals: No additional remark.
Specific Effects
Ingredient Name
Lead and inorganic
compounds
Carcinogenic
Effects
Lead azide
ECOLOGICAL INFORMATION
Mobility,
persistence/degradation,
bioaccumulation and
ecotoxocity:
Mutagenic
Effects
Developmental
Toxicity
Repr. Cat.
1;R61
Repr. Cat.
1;R61
Impairs
Fertility
Repr. Cat.
1;R62
Repr. Cat.
3;R62
Material as supplied and undamaged,
presents no ecological problems
provided any waste are correctly
disposed of. Components are
explosive and toxic to aquatic life.
Electronic Detonators_2014_Layout 1 09/06/2014 11:14 Page 9
ELECTRONIC
DETONATORS
ECOLOGICAL INFORMATION Continued...
Ecotoxicity Data
Ingredient Name
Species
Period
Result
Lead and inorganic
compounds
Trout
(LC50)
96 hours
0.14 ppm
48 hours
375 ppm
Pentaerythritol
tetranitrate
Pimephales
promelas
(LC50)
96 hours
27000 mg/I
Ecological information
Shrimp
(LC50)
Mobility
Not available
Persistence/degradability
Not readily biodegradable
Soil/Water Partition
Coeffiecient (Koc)
Not available
Bioaccumulative potential
Ingredient
Name
POSSIBLE
Persistence/degradability
BOD5 COD ThOD Aquatic Half-life
Photolysis
Biodegradability
Lead and lead
inorganic
compounds
Pentaerythritol
Tetranitrate
Bio-accumulative
potential
LogPOWBCE
potential
Not readily
92000 high
< 28 day(s).
74
low
Remarks: May be harmful to environment if released in large amounts.
DISPOSAL CONSIDERATIONS
Product Disposal:
Container Disposal:
Contact supplier. Disposal should
be in accordance with the local
Regulations.
Empty containers may be burnt by an
authorised person. Boxes must be
examined to ensure they are empty.
Electronic Detonators_2014_Layout 1 09/06/2014 11:14 Page 10
DATA
TRANSPORT INFORMATION
UK Transport Information
UN Number
UN Class
ADR/RID Substance Id No
ADR/RID – Description
ADR/RID – Class
IMDG – Proper Shipping Name
Must be in accordance with the
Carriage of Dangerous Goods,
etc Regulations 2011.
UN0030, UN0456.
1.1B, 1.4S
UN0030, UN0456.
Detonators electric for blasting
1.1B, 1.4S
DETONATORS, ELECTRIC
FOR BLASTING.
IMDG Class
1.1B, 1.4S
Labelling Information
In accordance with the Carriage of
Dangerous Goods, etc Regulations
2011 and Packaging of Explosives
Regulations 1991.
REGULATORY INFORMATION
R Phrases
S Phrases
OTHER INFORMATION
UK Legislation
MSDS First Issued
Full text of R-Phrases with no
Appearing in Section 2
R3
S47 (100°C)
Subject to Explosives Act 1875 and
associated Legislation and Approved
Codes of Practice.
05/96
R3- Extreme risk of explosion by
shock friction, fire or other sources
of ignition.
R11- Highly flammable.
R61- May cause harm to the
unborn child.
R62- Possible risk of impaired
fertility.
R20/22- Harmful by inhalation and
if swallowed
R36/37- Irritating to eyes and
respiratory system.
Electronic Detonators_2014_Layout 1 09/06/2014 11:14 Page 11
ELECTRONIC
DETONATORS
OTHER INFORMATION Continued...
Full text of R-Phrases with no
Appearing in Section 2
Continued...
R36/37- Irritating to eyes and
respiratory system.
R36/38- Irritating to eyes and skin
R33- Danger of cumulative effects.
R50/53- Very toxic to aquatic
organisms, may cause long-term
adverse effects in the aquatic,
environment.
R51/53- Toxic to aquatic organisms,
may cause long-term adverse effects
in the aquatic environment.
NOTICE:FOR FURTHER INFORMATION CONTACT
EPC-UK EXPLOSIVES ENGINEERING DEPARTMENT
Tel :00-44-1773-832253
Product guide covers_2014_Layout 1 09/06/2014 10:50 Page 9
NON - ELECTRIC
DETONATORS
EPC-UK supplies non-electric
detonator systems for initiation of
surface blasts, long delay tunnel
detonators for underground and
demolition blasting.
The surface blasting system consists of a set of
detonators with three available in-hole delay times of
450ms, 475ms and 500ms together with a range of
delayed action surface connectors.
By using combinations of downhole detonators
and the various surface delayed action connectors,
the simplest to most complicated blast designs can
be achieved.
The tunnel series of non electric detonators has delay
intervals suitable for use in tunnelling, underground
mining and demolition applications. There are
up to 23 delay numbers in the tunnel range
from 0 to 7000 milliseconds.
9
Non Electric Detonators_2014_Layout 1 09/06/2014 10:11 Page 1
NON - ELECTRIC
DETONATORS
Euronel Range and Packaging
In-hole Detonators
1.1B Packaging
Tube length in
metres
Qty/box
Qty/box
7.8
10
100
6.0
10.2
12.0
15.0
18.0
21.0
24.0
27.0
10
10
100
70
10
50
10
50
5
40
5
30
5
25
5
25
Connector Detonators
1.1B Packaging
Tube length in
metres
Qty/bag
Qty/box
6.0
10
80
4.8
7.8
9.0
Starter lines
10
100
10
70
10
60
1.1B Packaging
Tube length in
metres
Qty/bag
Qty/box
50
2
10
30
100
Lead in line
Tube length in
metres
250
4
1
Pre pack
1
Other lead
lengths can
be supplied
by special
request.
20
5
Hazard
None
Other lead
lengths can
be supplied
by special
request.
Non Electric Detonators_2014_Layout 1 09/06/2014 10:11 Page 2
DATA
Technical Data
Euronel In-hole:
Body:
Diameter:
Length:
Strength:
Shock tube colour:
Euronel Connector:
Body:
Diameter:
Length:
Strength:
Capacity:
Shock tube colour:
Euronel Duo:
Body:
Diameter:
In-hole length:
Strength:
Connector length:
Strength:
Shock tube colour:
Euronel Tunnel:
Body:
Diameter:
In-hole length:
Strength:
Shock tube colour:
Aluminium
shell
7.5mm
83-99mm
No. 8D
Yellow
Aluminium
shell
7.5mm
53mm
No. 4D
6 shock
tubes
Red
Aluminium
shell (2 off)
7.5mm
83-99mm
No. 8D
53mm
No. 4D
Yellow
Aluminium
shell
7.5mm
53-99mm
depending
on delay
No. 8D
Yellow
Surface connectors
are available in time
delays as follows:
Nominal
Delay
in ms
0
17
25
33
42
75
100
175
Colour
of block
Green
Yellow
Red
Purple
White
Blue
Grey
Orange
Non Electric Detonators_2014_Layout 1 09/06/2014 10:11 Page 3
NON - ELECTRIC
DETONATORS
PRODUCT AND COMPANY IDENTIFICATION
Product Type
Trade Names
Products Include
Products use
In-Hole
Connector
Tunnel
Duo
Manufacturer/Supplier
Address
Telephone Number
Emergency Tel Number
email
Euronel / Daveynel Detonator
Assemblies
Euronel / Daveynel
Euronel In-hole, Connector, Tunnel,
Duo Daveynel Connector
A down-hole initiation system for
explosive charges, particularly in
open cast, open pit mining and
quarry blasting.
A surface initiation system for
explosive charges, particularly in
open cast, open pit mining, quarry
blasting and underground mining
applications.
An in-hole initiation system for
explosive charges, particularly in
development tunnelling in
underground mining.
A combined down-hole and surface
initiation system for explosive
charges used in open pit/cast mining,
quarry blasting and underground
applications.
EPC-UK
VENTURE CRESCENT
ALFRETON,
DERBYSHIRE DE55 7RA
00-44-1773 832253
00-44-1773 832253
info@epc-groupe.co.uk
Non Electric Detonators_2014_Layout 1 09/06/2014 10:12 Page 4
DATA
HAZARD IDENTIFICATION
The preparation is classified as dangerous according to
Directive1999/45/EC and its amendment
Classification
E: R3
Effects and symptoms
Pre-use: Hazardous materials are
encapsulated, no exposure during
normal handling is therefore expected.
Post-use: Minimal exposure risk is
expected as quantities of hazardous
components used are small
Additional Hazards
After detonation, dust and fumes
may be harmful by inhalation on
repeated exposure (lead poisoning)
Aggravating conditions
No additional remark
COMPOSITION / INFORMATION ON THE COMPONENTS
Aluminium
CAS No
7429-90-5
%
5-10
EC Number
231-072-3
Lead Compounds
7439-92-1
2.7-8.1
231-100-4
Barium Sulphate
7727-43-7
1-5
231-784-4
Silicon
7440-21-3
1-3
231-130-8
HMX
2691-41-0
small
220-260-0
Lead Azide
13424-46-9
0.3-0.5
236-542-1
PETN
78-11-3
0-3%
201-084-3
Classification
F;R15
R10
Repr. Cat 1: R61
Repr. Cat 3: R62
Xn: R20/22
R33
N: R50/53
Xi: R36/37
E, Xn R2, R22,
R52/53
F: R11
Xi: R36/38
E : R3
Repr. Cat. 1 : R61
Repr. Cat. 3 : R62
Xn : R20/22
R33
N: R50/53
E, R2, R22, R44
These materials are enclosed in a metal/plastic shell. The balance of the mass
of this product is made up of inert plastics and metals.
Non Electric Detonators_2014_Layout 1 09/06/2014 10:12 Page 5
NON - ELECTRIC
DETONATORS
FIRST AID MEASURES
Inhalation
Ingestion
Skin Contact
Eye Contact
Note to Physician
Protection of First-Aiders
In case of accidental initiation
FIRE FIGHTING MEASURES
Extinguishing Media
Suitable
Not Suitable
Pre-use: Hazardous materials are
encapsulated, no exposure during
normal handling is therefore expected
Post use: Minimal exposure is
expected as quantities of hazardous
components used are small
Not the normal route of entry
Not the normal route of entry
Not the normal route of entry
No specific treatment,
treat symptomatically
No additional remark
For any injury due to shrapnel
proceed with first aid treatment
and evacuate to hospital. In all cases
have ears and hearing checked
immediately by a specialist
Do not fight fire
No additional remark
Unusual fire/explosion
Hazards
Explodes when heated
Special fire-fighting
Procedures
When controlling fire before
involvement of explosives, fire-fighters
should wear positive pressure
self-contained breathing apparatus
(SCBA) and full turnout gear.
Fire-fighters’ protective clothing will
provide limited. protection
DO NOT FIGHT FIRE WHEN IT
REACHES MATERIAL.
Withdraw from fire and let it burn.
Hazardous Thermal
Decomposition Products
These products are carbon oxides
(CO, CO2) nitrogen oxides (NO,
NO2…) sulphur oxides (SO2, SO3..)
some metallic oxides
Non Electric Detonators_2014_Layout 1 09/06/2014 10:12 Page 6
DATA
FIRE FIGHTING MEASURES Continued...
Special fire-fighting
Procedures
Continued...
Protection of Fire-Fighters
Promptly isolate the scene
by removing all persons from the
vicinity of the incident if there is a
fire. First move people out of line
of the sight of the scene away
from windows.
No additional remark
ACCIDENTAL RELEASE MEASURES
Personal Precautions
Environmental Precautions
Products: AND STORAGE
HANDLING
Handling
Storage
Packaging Materials
Recommended use
Not suitable
Evacuate surrounding areas
Do not touch damaged article or
spilled material. Do not clean-up or
dispose except under supervision of
a specialist. Eliminate all ignition
sources.Call for assistance on disposal.
Keep locked up. Keep away from heat.
Keep away from sources of ignition.
Ground all equipment containing
material. Do not ingest. Do not
breathe dust. Take precautionary
measures against electrostatic
discharges. Wear suitable protective
clothing. If ingested, seek medical
advice immediately and show the
container or the label.
Store in segregated, approved and
labelled area. Keep container in a
cool, well ventilated area. Keep
container tightly closed and sealed
until ready for use. Avoid all possible
sources of ignition (spark or flame).
Under these conditions storage life
up to 18 months.
Dispose of in approved manner
Use original container
No additional remark
Non Electric Detonators_2014_Layout 1 09/06/2014 10:12 Page 7
NON - ELECTRIC
DETONATORS
EXPOSURE CONTROL / PERSONAL PROTECTION
Engineering Measures
Hygiene measures
Use explosion-proof electrical
(ventilating, lighting and material
handling) equipment. Use process
enclosures, local exhaust ventilation
or other engineering controls to keep
airborne levels below recommended
exposure limits. If user operations
generate dust, fume or mist, use
ventilation to keep exposure to
airborne contaminants below the
exposure limit.
Wash hands, forearms and face
thoroughly after handling compounds
and before eating, smoking, using
lavatory and at the end of the day.
Occupational Exposure Limits of materials contained in the detonator:
Ingredient Name
Aluminium Powder
(stabilised)
Barium Sulphate
Lead Monoxide
Silicon
Lead Azide
Pentaerythritol Tetranitrate
Occupational Exposure Limits:
ACGIH (United States) Notes:
Respirable
TWA: 5 mg/m3
TWA: 15
ACGIH TLV (United States, 2001)
TWA: 2 mg/m3 8 hour(s)
TWA: 10 mg/m3 8 hour(s) Form: Dust
TWA: 5 mg/m3 8 hour(s) Form: Fume
EU OEL (Europe, 1991) Notes: Indicative
TWA: 0.5 mg/m3 8 hour(s)
80/1107/EEC (Europe, 1998) Notes: Binding
TWA: 0.15 mg/m3 8 hour(s)
ACGIH (United States)
TWA: 10 mg/m3
ACGIH TLV (United States, 2001)
Notes: The value is for total dust containing
no asbestos <1% crystalline silica.
EU OEL (Europe, 1998) Notes: Binding
TWA : 0.15 mg/m3 8 hour(s)
Not available
Non Electric Detonators_2014_Layout 1 09/06/2014 10:12 Page 8
DATA
EXPOSURE CONTROL / PERSONAL PROTECTION Continued...
Recommended Monitoring
Procedures
Personal Protective Equipment:
Respiratory system
Skin and body
Hands
Eyes
None identified
None required; however, use of
adequate ventilation is good
industrial practice
No special protection is required
No special protection is required
Safety Glasses with side shields
PHYSICAL AND CHEMICAL PROPERTIES
Physical State
In-Hole and
Tunnel
Connector
Duo
A piece of plastic shock tube with an
aluminium detonator at one end
and heat sealed at the other end.
A piece of plastic shock tube with an
aluminium detonator encapsulated
in a plastic block at one end and
heat seal at the other end.
A length of plastic shock tube with
an aluminium down-hole detonator
fitted to the one side and an
aluminium surface detonator
encapsulated by a plastic block
fitted to the other side.
Colour
Not applicable
Odour Threshold
Not applicable
Odour
Boiling Point
Melting Point
Density
Vapour Density
Not applicable
Not applicable
Not applicable
Not applicable
Not applicable
Vapour Pressure
Not applicable
Solubility
Not applicable
Coefficient
Not applicable
Evaporation Rate
(butyl acetate = 1)
Octanol/Water Partition
Not applicable
Non Electric Detonators_2014_Layout 1 09/06/2014 10:12 Page 9
NON - ELECTRIC
DETONATORS
PHYSICAL AND CHEMICAL PROPERTIES Continued...
pH
Not applicable
Fire Hazards in Presence of
Various Substances
Not applicable
Flash Point
Not applicable
Auto-ignition Temperature
120°C
Lower Explosion Limit
Not applicable
Explosive Properties
Viscosity
STABILITY AND REACTIVITY
Stability
Conditions to Avoid
Materials to Avoid
Hazardous Decomposition
Products
Hazardous Polymerisation
Explosives article, detonation
possible by open flames, sparks,
static discharge or shocks
Not applicable
Explosives article, detonation
possible by open flames, sparks,
static discharge
Heating may cause an
explosion, shock
No additional remark.
These products are carbon oxides
(CO, CO2) nitrogen oxides (NO,
NO2...) Sulphur oxides (SO2, SO3…).
Some metallic oxides.
Will not occur
TOXICOLOGICAL INFORMATION
- Non-toxic if article is undamaged, contents of article as follows:
Eyes
Skin
Inhalation
Ingestion
Target Organs
Hazardous ingredients, Slightly
hazardous in case of eye contact
(irritant),
Hazardous ingredients:
Non-irritant for skin
Hazardous ingredients:
hazardous in case of inhalation
Hazardous ingredients:
Hazardous in case of ingestion
Contains material which causes
damage to the following organs:
Non Electric Detonators_2014_Layout 1 09/06/2014 10:12 Page 10
DATA
TOXICOLOGICAL INFORMATION Continued...
Target Organs
Continued...
blood, kidneys, brain, gastro-intestinal
tract, upper respiratory tract, skin,
central nervous systems (CNS), eye,
lens or cornea, the reproductive
system, muscle tissue
Acute Toxicity
Ingredient Name
Test
Result
Lead Monoxide
LDLo
1400 mg/kg
Pentaerythritol
Tetranitrate
LD50
LDLo
1660 mg/kg
7000 mg/kg
Silicon
LD50
Mutagenic Developmental
Effects
Toxicity
Repr. Cat. 2:
R61
Lead Azide
Repr. Cat. 1:
R61
Special remarks on other
toxic effects on humans
Ecotoxicity Data
Chemicals contained
within the Article
Aluminium powder
(stabilised)
Lead and lead
inorganic compounds
Barium Sulphate
Pentaerythritol
Tetranitrate
Oral
Rat
Oral
Oral
Rat
Mouse
No additional remark
Carcinogenic
Effects
Special remarks on chronic
effects on humans
Dog
No additional remark
Specific remarks on other
toxic effects on humans
Lead Monoxide
Species
Oral
3160 mg/kg
Special remarks on toxicity
Ingredient
Name
Route
Impairs
Fertility
Repr. Cat. 3:
R62
Repr. Cat. 3:
R62
May cause harm to the unborn
child (lead compounds)
Bio accumulative potential
(lead compounds)
Species
Oncorhynchus mykiss (LC50)
Oncorhynchus mykiss (LC50)
Oncorhynchus mykiss (LC50)
Period
96 hours
96 hours
96 hours
Result
0.12 mg/l
0.16 mg/l
0.31 mg/l
Trout (LC50)
Shrimp (LC50)
96 hours
48 hours
0.14 ppm
375 ppm
Pimephales promelas (LC50)
96 hours
27000 mg/l
Daphnia magna (LC50)
48 hours
32 mg/l
Non Electric Detonators_2014_Layout 1 09/06/2014 10:12 Page 11
NON - ELECTRIC
DETONATORS
TOXICOLOGICAL INFORMATION Continued...
Ecological information
Mobility
Not available
Persistence/degradability
Not readily biodegradable
Soil/Water Partition
Coeffcient (Koc)
Not available
Bio Accumulative Potential
Ingredient
name
Lead & lead
High bio accumulative potential
Persistence/degradability
Bioaccumulative
potential
BOD5 COD ThOD Aquatic Photolysis Biodergradability LogPow BCF Potential
Half-life
Not readily
inorganic
compounds
Pentaerythritol
tetranitrate
<28 day(s)
Remark: May be harmful to environment if realesed in large amounts
DISPOSAL CONSIDERATIONS
Methods of Disposal
Waste Classification
The United Kingdom
TRANSPORT INFORMATION
92000 High
74
Low
Waste must be disposed of in
accordance with national and local
environmental control regulations.
Disposal of this product should only
be done by trained personnel.
If in doubt contact EPC-UK for
further advice
HAZARDOUS WASTE
The HSE and the CBI EIG have
issued “Guidance for the Safe
Management of the Disposal
of Explosives”
International Transport Regulations:
Regulatory
Information
UN Number
Proper Shipping Name
Class
ADR/RID Class
UN0360
1.1B
ADR/RID Class
UN0500
Detonator assemblies,
non-electric, for blasting
Detonator assemblies,
non-electric, for blasting
1.4S
Non Electric Detonators_2014_Layout 1 09/06/2014 10:12 Page 12
DATA
TRANSPORT INFORMATION Continued...
International Transport Regulations Continued...
Regulatory
Information
UN Number
Proper Shipping Name
Class
IMDG Class
UN0360
1.1B
IMDG Class
UN0500
Detonator assemblies,
non-electric, for blasting
UN0500 - Daveynel connectors
Detonator assemblies,
non-electric, for blasting
1.4S
REGULATORY INFORMATION
EU Regulations
Hazard Symbol(s)
Indicator of Danger
Risk Phrases
Safety Phrases
Product Use
OTHER INFORMATION
Full text of R-Phrases
with No
R3 – Extreme risk of explosion by
shock, friction, fire or other sources
of Ignition
S16 – Keep away from sources of
ignition – No Smoking
S34 – Avoid shock and friction
S35 – This material and its container
must be disposed of in a safe way
S33 – Take precautionary measures
against static discharges
Classification and labelling have
been performed according to EU
directives 67/548/EEC, 199/45/EC
including amendments and intended
use – Industrial applications
R3 - Extreme risk of explosion by
shock, friction, fire or other
sources of ignition
R9 - Explosive when mixed with
combustible material
R10 - Flammable
R61 - May cause harm to the
unborn child
R62 - Possible risk of impaired
fertility
Non Electric Detonators_2014_Layout 1 09/06/2014 10:12 Page 13
NON - ELECTRIC
DETONATORS
OTHER INFORMATION Continued...
Text of Classifications
Appearing in Section 2
Other Special Considerations
MSDS First Issued
R20/22 - Harmful by inhalation and
if swallowed
R22 - Harmful if swallowed
R36/38 - Irritating to eyes and skin
R33 - Danger of cumulative effects
R50/53 - Very toxic to aquatic
organisms, my cause long-term
adverse effects in the aquatic
environment
E – Explosives
O - Oxidising
F – Highly flammable
Repr. Cat. 1 –
Toxic for reproduction Category 1
Repr. Cat. 3 –
Toxic for reproduction Category 3
Xn – Harmful
Xi – Irritant
N – Dangerous for the environment
International users should comply
with the Acts and Regulations as
applicable in their respective countries.
Placing on the Market and
Supervision of Transfers of
Explosives Regulations (POMSTER),
Manufacture and Storage of
Explosives Regulations (MSER)
Control of Explosives Regulations
(COER) Explosives and Uses
Directives 93/15/EEC
PM82 – The Selection, Installation
and Maintenance of Electrical
Equipment for Use in and around
Buildings Containing Explosives.
May 2012
Non Electric Detonators_2014_Layout 1 09/06/2014 10:12 Page 14
DATA
OTHER INFORMATION Continued..
the context of how the user intends to handle and use the product in
the workplace. In the event of uncertainty or for further information on
these products and their safe storage and use, please contact
Explosives Engineering Dept of EPC-UK.
NOTICE:FOR FURTHER INFORMATION CONTACT
EPC-UK EXPLOSIVES ENGINEERING DEPARTMENT
Tel :00-44-1773-832253
Product guide covers_2014_Layout 1 09/06/2014 10:50 Page 10
EMULSION
EXPLOSIVES
EPC-UK supply Explus TSR primers
in 50mm and 35mm diameter
cartridges. This explosive is
suitable for use as a primer for
initiating Ammonium Nitrate based
explosives in shallow large
diameter holes as experienced in
opencast coal sites.
Packaged emulsions contains water in oil compositions,
i.e. where the water solution of oxidisers is dispersed evenly
between the oil phase. A surfactant (emulsifier) is used to ensure
that the oxidiser remains dispersed in the fuel. A density reducing
agent is added to make the product detonator sensitive.
As a result of the intimate blend of the oxidiser and fuel and the
fine particle size, emulsions have a relatively high velocity of
detonation in comparison to other products. These products have
excellent water resistant properties.
Packaged emulsion classification is UN 0241
and hazard class / compatibility group is 1.1 D.
10
Emulsion Explosives_2014_Layout 1 09/06/2014 10:22 Page 1
EMULSION EXPLOSIVES
PRODUCT AND COMPANY IDENTIFICATION
Product Type
Emulsion
Product Description
Water in oil emulsion explosive.
Trade Names
Explus TS R
Manufacturer / Supplier
EPC-UK EXPLOSIVES
Telephone Number
00-44-1773 832253
Address
Emergency Tel Number
e-mail
ROUGH CLOSE WORKS
CARNFIELD HILL
SOUTH NORMANTON
ALFRETON
DERBYSHIRE, DE55 2BE
00-44-1773 832253
info@epc-groupe.co.uk
Emulsion Explosives_2014_Layout 1 09/06/2014 10:22 Page 2
DATA
HAZARD IDENTIFICATION
Main Hazards
EXPLOSIVE
Health Effects – Skin
May cause dermatitis by de-fatting
the skin.
Health Effects – Eyes
Health Effects – Ingestion
Health Effects – Inhalation
May cause irritation.
Small quantities unlikely to cause
toxic effects
Not applicable.
COMPOSITION/INFORMATION ON THE COMPONENTS
EINECS/CAS
Number
Hazard
Symbols
Risk
Phrases
Explus
TS R
EINECS 231-554-3
CAS 7631-99-4
O
R8
5-20%
O
R9, R22
<5%
Ammonium
Nitrate
EINECS 229-347-8
CAS 6484-52-2
Sodium
perchlorate
EINECS 231-511-9
CAS 7601-89-0
Sodium Nitrate
FIRST AID MEASURES
Eyes
Skin
Ingestion
Inhalation
Advice to Physicians
FIRE FIGHTING MEASURES
O
R8
30-70%
Irrigate thoroughly with water
for at least 15 minutes.
Wash thoroughly with soap
and water.
Physically clear throat and mouth.
Drink copious amounts of water and
seek medical advice.
Physically clear airways to aid
breathing then seek medical advice.
Ingestion - Mild cases of
methaemoglobinaemia will lead to
cyanosis and in more severe cases
may produce unconsciousness.
Emulsion Explosives_2014_Layout 1 09/06/2014 10:22 Page 3
EMULSION EXPLOSIVES
FIRE FIGHTING MEASURES
Extinguishing Media
Special Hazards of Product
Protective Equipment
for Fire-Fighting
Large quantities of water.
Although non flammable the matrix
will assist fire. If the fire looks likely
to reach the emulsion retire to a safe
distance of at least 300 m and
cordon off the area.
Full protective clothing and
breathing apparatus.
ACCIDENTAL RELEASE MEASURES
Personal Precautions
Wear gloves and overalls.
Spillages
Pick up any loose cartridges, remove
any contaminating material. Contact
supplier for advice if explosives
are damaged.
Environmental Precautions
HANDLING AND STORAGE
Handling
Storage
Do not allow to enter a water course.
No smoking – no sources of ignition.
Keep product clean and free from
contamination.
Must be stored in accordance with
Manufacture and Storage of
Explosives Regulations 2005. Store
in a well ventilated magazine, in
which the temperature is no higher
than 35-40°C. Product is safe up to
65°C, where it may harden. Handle
cases with care. Do not open cases
in magazines or whilst in transit or
when loading or unloading from
vehicles. Keep the product clean
and free from contamination.
EXPOSURE CONTROL / PERSONAL PROTECTION
UK Occupational
Exposure Standards
None assigned.
Hand Protection
Wear leather or plastic gloves.
Body Protection
Wear overalls.
Eye Protection
Wear goggles/glasses.
Emulsion Explosives_2014_Layout 1 09/06/2014 10:22 Page 4
DATA
EXPOSURE CONTROL / PERSONAL PROTECTION Continued...
Physical State
Gel
Odour
Very slight “oily” smell.
Colour
pH
Grey
Neutral.
Solubility in Water (kg/m3)
Insoluble.
Decomposition Temp. (deg C)
>150°C.
Friction sensitivity (N)
Products:
STABILITY AND REACTIVITY
No reaction at 353 N
Density (kg/m3)
Shock sensitivity (J)
Stability
Conditions to Avoid
Materials to Avoid
Hazardous Decomposition
Products
1270±0050.
No reaction at 50 J
Stable. Recommended life time is
1 year. After this period reliability is
no longer guaranteed. The product is
not dangerous.
High temperatures, impact, friction,
flames, sparks and static discharges.
Acids, Bases and combustible
materials.
Oxides of Carbon,
including Carbon Monoxide may be
produced when the product is used.
Occupational exposure limits are
Nitrous Oxide = 100ppm, 183
mgm-3;Carbon Monoxide = 50ppm,
58 mgm-3; Carbon Dioxide = 5000
ppm 9150 mgm-3; However the
amounts of toxic gases produced will
depend on many variables such as
method of initiation, rock type,
humidity etc.
Products:
TOXICOLOGICAL INFORMATION
Irritancy - Eyes
Irritant.
Skin Sensitisation
May sensitise skin to other
chemicals.
Irritancy - Skin
Products:
ECOLOGICAL INFORMATION
Mobility
Irritant.
Waxy solid.
Emulsion Explosives_2014_Layout 1 09/06/2014 10:22 Page 5
EMULSION EXPLOSIVES
ECOLOGICAL INFORMATION Continued...
Persistence/Degradability
Ecotoxicological values
Ammonium Nitrate
Daphnia
Fish
Algae
Material is waterproof, but
Ammonium Nitrate may leach
out over time.
IC 50%=24 hr
Brachydanio rerio
Scenedesmus subspicatus
DISPOSAL
Product Disposal
Container Disposal
TRANSPORT INFORMATION
UK Transport Information
LC 50%-24 hr
LC50% 5 days
Must be in accordance with
Carriage of Dangerous Goods
Regulations 2011.
ADR/RID Substance ID No
UN0241.
ADR/RID Class
IMDG Proper Shipping Name
IMDG Class
REGULATORY INFORMATION
Labelling Information
2.5 mg/l
The accepted method for the empty
boxes is burning.
UN 0241.
ADR/RID Description
650 mg/l
Under the supervision of an expert,
the product may be destroyed by
detonation in a borehole or by
burning at an approved site. For
more guidance see the HSE/CBI
Explosives Industry Group publication:
“Guidance for the Safe Management
of the Disposal of Explosives”,
January 2007.
UN Number
UN Class
324 mg/l
1.1 D.
Explosive, blasting, type E
1.1 D.
EXPLOSIVE, BLASTING, TYPE E
1.1 D.
Labelled in accordance with Carriage
of Dangerous Goods Regs 2011
Emulsion Explosives_2014_Layout 1 09/06/2014 10:22 Page 6
DATA
REGULATORY INFORMATION Continued...
R Phrases
R2.
S Phrases
OTHER INFORMATION
UK Legislation
MSDS first issued
Meaning of R phrases
R2
R8
R9
Meaning of S phrases
S16
S24
S34
S41
S16, S24, S34, S41.
Subject to Explosives Act 1875,
Manufacture and Storage of
Explosives Regulations 2005 and
Associated Legislation and Approved
Codes of Practice.
03/96, Updated April 2012
Risk of explosion by shock, friction,
fire or other sources of ignition
Contact with combustible material
may cause fire.
Explosive when mixed with
combustible material.
Keep away from sources of ignition,
no smoking
Avoid contact with skin
Avoid shocks and friction
In case of fire and/or explosion do
not breathe fumes
NOTICE:FOR FURTHER INFORMATION CONTACT
EPC-UK EXPLOSIVES ENGINEERING DEPARTMENT
Tel :00-44-1773-832253
Product guide covers_2014_Layout 1 09/06/2014 10:50 Page 11
AUTHORISED
NITROGLYCERINE
EXPLOSIVES
EPC-UK supply a nitroglycerine
based explosive in a range of
diameters suitable for use in the
civil engineering, demolition,
tunnelling and quarrying
industries. The product currently
supplied is Perunit 28E.
Nitroglycerine explosives generally have good
waterproof characteristics, depending on their
application and exposure to water.
Reliable initiation can be provided with standard
detonating cord, electric, non-electric or
electronic detonators.
As a group, the nitroglycerine explosives are one of
the most sensitive commercial products used today
(excluding detonators).
The classification of Perunit is UN 0081 and
hazard class / compatibility group is 1.1D.
11
Authorised Nitroglycerine Explosives_2014_Layout 1 09/06/2014 10:28 Page 1
AUTHORISED
NITROGLYCERINE
EXPLOSIVES
PRODUCT AND COMPANY IDENTIFICATION
Product Description
Trade Name
Recommended Use
Nitroglycerine / ethylene glycol
dinitrate based explosives: Blasting
Explosives Type A
Perunit 28E
This explosive is intended for blasting
in rock in a variety of conditions.
Perunit 28E, cartridged in small
diameters, is particularly suited for
drifting, tunnelling and shaft sinking.
Perunit 28E may also be used as a
general purpose primer or booster
charge.
Manufacturer / Supplier
EPC-UK EXPLOSIVES
Telephone Number
00-44-1773 832253
Address
Emergency Tel Number
e-mail
ROUGH CLOSE WORKS
SOUTH NORMANTON
ALFRETON
DERBYSHIRE, DE55 2BE
00-44-1773 832253
info@epc-groupe.co.uk
Authorised Nitroglycerine Explosives_2014_Layout 1 09/06/2014 10:28 Page 2
DATA
HAZARD IDENTIFICATION
Main Hazards
EXPLOSIVE (E): Mass explosion
hazard. Risk of explosion by shock,
friction or fire VERY TOXIC (T+) by
inhalation, on contact with skin and
if swallowed. HARMFUL TO THE
ENVIRONMENT (N) Toxic to aquatic
organisms, may cause long term
adverse effects in the aquatic
environment. Once detonated,
explosives release large quantities
of gas. If in a confined area, care
should be taken to ensure that there
is sufficient oxygen in the air before
approaching the site of an
explosion. The gases released may
contain some carbon monoxide –
TOXIC (T) - nitrogen monoxide and
nitrogen dioxide - VERY TOXIC (T+).
The HSE issued Chemical Hazard
Alert Notices (CHANs) covering
nitrogen monoxide and nitrogen
dioxide. These have now been
suspended.
COMPOSITION / INFORMATION ON THE COMPONENTS
Nitroglycerine
Ethylene Glycol
Dinitrate
Trinitrotoluene
Dinitroethylbenzene
Nitrocellulose
Ammonium Nitrate
EINECS/CAS
Number
Hazard
Symbols
EINECS 200-240-8
CAS 000055-63-0
E, T+, N
EINECS 204-289-6
CAS 118-96-7
E, T, N
EINECS 211-063-0
CAS 000628-96-6
E, T+
EINECS 250-576-4
CAS 31344-57-7
Xn
EINECS 229-347-8
CAS 6484-52-2
O
CAS 009004-70-0
E
Risk Phrases
Perunit 28E
R3, R26/27/28,
R33, R51, R53
ca 18.5%
R2, R26/27/28,
R33
ca 9.5%
R33, R20/21/22,
R52/53
0-8.4%
R2, R23/24/25,
R33, R51/53
R1, R3
R8, R9
0-8.4%
ca 1.3%
Max 69.0%
1 The manufacturer of Perunit 28E also classifies the ammonium nitrate in it as
irritant (Xi) with Risk phrase R36/37/38. See the heading “Other information” for the
full text of each R phrase Note: The HSE issued CHANs regarding Nitroglycerine
and Ethylene Glycol Dinitrate. These have been suspended.
Authorised Nitroglycerine Explosives_2014_Layout 1 09/06/2014 10:28 Page 3
AUTHORISED
NITROGLYCERINE
EXPLOSIVES
FIRST AID MEASURES
First Aid – Eyes
First Aid – Skin
First Aid –
Inhalation
First Aid – Ingestion:
Advice to Physicians
FIRE FIGHTING MEASURES
Extinguishing Media
Special Hazards Of Product
Wash eyes with copious amounts
of water for at least 15 minutes.
Seek medical attention.
Wash thoroughly with soap and
water. Remove contaminated clothing.
Remove person to fresh air.
A person suffering from inhalation
of after detonation fumes must be
removed to fresh air, receive
medical attention and stay under
medical observation for at least 48
hours. The person should lie down
until the doctor arrives.
Immediately drink plenty of water
and seek medical attention.
Absorption of the product in the
body may cause formation of
methaemoglobin, which, in sufficient
concentration, causes cyanosis.
Use water based extinguishers to
prevent fire reaching the explosive.
If the fire looks likely to reach the
explosive, retire to a safe distance
and cordon off the area. A minimum
distance of 300 m is recommended
for road transport and may need to
be greater, dependant on the quantity
of explosives involved. Explosive –
may burn to detonation. Toxic and
irritating gases may be formed during
a fire.
ACCIDENTAL RELEASE MEASURES
Personal Precautions
Wear gloves and overalls. Keep the
area well ventilated. If explosive has
come out of the cartridge, wear an
organic vapour mask. Prevent access
by unauthorised persons.
Authorised Nitroglycerine Explosives_2014_Layout 1 09/06/2014 10:28 Page 4
DATA
ACCIDENTAL RELEASE MEASURES Continued...
Spillages
HANDLING AND STORAGE
Handling
Storage
Avoid all sources of flame, heat and
anything that might cause a spark.
Avoid impact and friction. Complete
cartridges may be picked up
manually. Ensure that the cartridges
are free of grit and dirt. Loose
powder from cartridges should be
carefully picked up with a nonsparking tool, put in a plastic bag
and this placed in a fibreboard box.
No smoking - no sources of ignition.
Keep product clean and free from
contamination. Avoid shock, friction
and static discharges. When using
do not eat or drink. Do not open
cartridges.
Must be stored in accordance with
the Manufacture and Storage of
Explosives Regulations, 2005.
Handle cases with care. Do not
open cases in magazines or whilst
in transit or when loading or
unloading from vehicles. Keep the
product clean and free from
contamination. Storage rooms
should be dry and well ventilated.
The shelf life of the Perunit is 9
months when stored under
recommended conditions.
Products:
EXPOSURE CONTROL / PERSONAL PROTECTION
Product UK Standards
Nitroglycerine (NG) - The previous
Occupational Exposure Standard
(OES) for NG (1.9 mg/m3, 0.2 ppm,)
has been withdrawn as it may not
be adequate to protect occupational
health. Exposures to NG should be
kept as low as is reasonably practical
and certainly to below 0.2 ppm.
Authorised Nitroglycerine Explosives_2014_Layout 1 09/06/2014 10:28 Page 5
AUTHORISED
NITROGLYCERINE
EXPLOSIVES
EXPOSURE CONTROL / PERSONAL PROTECTION Continued...
Product UK Standards
Continued...
After Detonation Fumes
UK Standards
The HSE has developed a biological
guidance monitoring value for NG.
This is 15 µmol nitroglycols/mol
creatinine based on measurement of
total urinary nitroglycols.
Ethylene Nitrate (EGDN) - The
previous OES for EGDN (1.3 mg/m3,
0.2 ppm) has been withdrawn as it
may not be adequate to protect
occupational health. Exposures to
EGDN should be kept as low as is
reasonably practical and certainly to
below 0.2 ppm.
Trinitrotoluene - 8 hr TWA = 0.5 ppm.
Besides residual amounts of unreacted
product, the after detonation fumes
may include the following gases:
Carbon Dioxide: 8 hr=5000 ppm,
9150 mg/m3; 15 min = 15,000 ppm,
27,400 mg/m3.
Carbon Monoxide: 8 hr=30 ppm,
35 mg/m3; 15 min = 200 ppm,
232 mg/m3.
Nitrogen Monoxide: The previous
OES for nitrogen monoxide (8hr =25
ppm, 31 mg/m3) was withdrawn, as it
may not be adequate to protect
occupational health. The CHAN
where the HSE recommended that
exposure to nitrogen monoxide
should not exceed 1 ppm has been
suspended. Users should aim to
follow ALARP (as low as reasonably
practical) principles (see ref [1].
Nitrogen Dioxide: The previous OES
for nitrogen dioxide (8hr = 3 ppm, 5.7
mg/m3) has been withdrawn, as it
may not be adequate to protect
occupational health. The CHAN
where the HSE recommended that
exposure to nitrogen dioxide should
not exceed 1 ppm has been suspended.
Authorised Nitroglycerine Explosives_2014_Layout 1 09/06/2014 10:28 Page 6
DATA
EXPOSURE CONTROL / PERSONAL PROTECTION Continued...
Respiratory Protection
Hand Protection
Body Protection
For unopened cartridges in a well
ventilated area normally no personal
respiratory protection is necessary.
However an organic vapour mask
should be used in some cases, e.g.
insufficiently ventilated magazine.
Wear appropriate non-permeable
gloves, e.g. nitrile rubber. EPC-UK
Explosives will be happy to advise on
this, please contact our Explosives
Engineering Department.
Wear overalls. Do not continue to
wear overalls which are contaminated
with explosives.
PHYSICAL AND CHEMICAL PROPERTIES
Physical State
Solid, plastic gelatine.
Odour
Slightly sweet smell.
Colour
Solubility in Water
Density (kg/m3)
Impact Sensitivity Test
STABILITY AND REACTIVITY
Stability
Conditions to Avoid
Materials to Avoid
Hazardous Decomposition
Products
Red
Partly soluble, depending on
immersion time
1.38 kg/l
Unless otherwise noted, we would
expect a density variation of ±0.05
kg/l on the value stated.
10 J.
The explosive is stable when stored
under normal conditions in a dry
magazine.
High temperatures, direct sunlight,
impact, friction, flames, sparks and
static discharge.
Acids and Bases.
Nitrogen Oxides, Oxides of Carbon,
including Carbon Monoxide may be
produced when the product is used.
Authorised Nitroglycerine Explosives_2014_Layout 1 09/06/2014 10:28 Page 7
AUTHORISED
NITROGLYCERINE
EXPLOSIVES
STABILITY AND REACTIVITY Continued...
Hazardous Decomposition
Products:
Continued...
The amounts of toxic gases
produced will depend on
many variables such as method of
initiation, rock type, humidity etc.
TOXICOLOGICAL INFORMATION
Acute Toxicity
Lethal Doses
Eco-toxicity
DISPOSAL
Product Disposal
Product classified by conventional
calculation methods. All products
within the cartridge contain sufficient
nitroglycerine and/or ethylene glycol
dinitrate to remain very toxic.
Inhalation of vapours, ingestion or
absorption through the skin causes a
lowering of blood pressure.
This may cause headaches.
The following list gives LD50 oral
(rat) values for various of the raw
materials used in these products
Nitroglycerine
105 mg/kg
Ethylene Glycol dinitrate 616 mg/kg
Ammonium nitrate
2400 mg/kg
Trinitrotoluene
795 mg/kg
Sodium nitrate
3430 mg/kg
Perunit 28E contains sufficient
nitroglycerine and TNT to remain
classified as harmful to the aquatic
environment as calculated by the
conventional method. Toxic to aquatic
organisms, may cause long-term
adverse effects in the aquatic
environment.
Under the supervision of an expert,
the product may be destroyed by
detonation in a borehole or by
burning at an approved site. For
more guidance see the HSE/CBI
Explosives Industry Group
publication: “Guidance for the Safe
Management of the Disposal of
Explosives”, January 2007.
Authorised Nitroglycerine Explosives_2014_Layout 1 09/06/2014 10:28 Page 8
DATA
DISPOSAL Continued...
Container Disposal
TRANSPORT INFORMATION
UK Transport Information
UN Number
The accepted method for disposing
of the empty boxes is burning on site.
Double check that the boxes are empty
Must be in accordance with the
Carriage of Dangerous Goods and
Use of Transportable Pressure
Equipment Regulations 2011
UN0081
UN Class/ Compatibility Group
1.1 D.
ADR/RID Substance ID. No
UN0081
UN & ADR Name
ADR/RID – Class/Compatibility
Group
REGULATORY INFORMATION
Labelling Information
Risk and Safety Phrases
Explosive
Risk Phrases
Safety Phrases
Other UK Legislation
EXPLOSIVE, BLASTING, TYPE A.
1.1 D.
Labelled in accordance with the
Carriage of Dangerous Goods and
Use of Transportable Pressure
Equipment Regulations 2011
The Chemical Hazard Information
and Packaging for Supply Regulations
2009 (note regs 6-11 do not apply to
the explosives covered by this MSDS)
Perunit 28E
R2, R26/27/28,
R33, R51/53
S27, S28, S33, S35,
S36/37, S41, S45, S61
Subject to The Manufacture and
Storage of Explosives Regulations
2005 and its approved codes of
practice. (as amended), The Control
of Explosives Regulations 1991 (as
amended) Placing on the Market and
Supervision of Transfers of
Explosives Regulations 1993 (as
amended)
Authorised Nitroglycerine Explosives_2014_Layout 1 09/06/2014 10:28 Page 9
AUTHORISED
NITROGLYCERINE
EXPLOSIVES
REGULATORY INFORMATION Continued...
EC Regulations
OTHER INFORMATION
MSDS first issued
Meaning of R phrases
Explosives Act 1875 (what remains)
Quarries Regulations 1999.
The Control of Substances
Hazardous to Health regulations
Registration, Evaluation, Authorisation
and Restriction of Chemicals, EC
Reg 1907/2006. Classification,
Labelling and Packaging of
Substances and Mixtures, EC Reg
1272/2008. Note this does not apply
to mixtures until June 2015, as such
this data sheet does not show the
labelling requirements under this reg.
Issue 1 April 2012
R1
R2
Explosive when dry
Risk of explosion by
shock, friction, fire or other
sources of ignition.
R3 Extreme risk of explosion
by shock, friction, fire or other
sources of ignition
R8 Contact with combustible
material may cause fire
R9 Explosive when mixed
with combustible material
R20/21/22 Harmful by inhalation, in
contact with the skin and if swallowed
R23/24/25 Toxic by inhalation, in
contact with the skin and if swallowed
R26/27/28 Very toxic by inhalation, in
contact with the skin and if swallowed
R33 Danger of cumulative effect
R51 Toxic to aquatic organisms.
R51/53
Toxic to aquatic
organisms, may cause long term
adverse effect in the aquatic
environment.
R52/53
Harmful to aquatic
organisms, may cause long term
adverse effect in the aquatic
environment.
R53 May cause long term adverse
effect in the aquatic environment.
Authorised Nitroglycerine Explosives_2014_Layout 1 09/06/2014 10:29 Page 10
DATA
OTHER INFORMATION Continued...
Meaning of R phrases
Continued...
References 1.
S27 Take off immediately all
contaminated clothing.
S28 After contact with skin wash
immediately with plenty of
water and soap.
S35 This material and its
container must be disposed
of in a safe way.
S36/37 Wear suitable protective
clothing and gloves.
S41 In case of fire and/or explosion
do not breathe fumes.
S45 In case of accident or if you
feel unwell seek medical
advice immediately.
“Occupational Exposure To Nitrogen
Monoxide in a Tunnel Environment –
Best Practice Guide” First edition,
British Tunnelling Society, 2008
NOTICE:FOR FURTHER INFORMATION CONTACT
EPC-UK EXPLOSIVES ENGINEERING DEPARTMENT
Tel :00-44-1773-832253
Product guide covers_2014_Layout 1 09/06/2014 10:50 Page 12
P5
PERMITTED
NITROGLYCERINE
EXPLOSIVES
EPC-UK supplies nitroglycerine
based explosives in a range of
diameters suitable for use in
underground coal mines
As a group, the nitroglycerine explosives are one of
the most sensitive commercial products used today
(excluding detonators).
12
P5 Permitted NITROGLYCERINE EXPLOSIVES_2014_Layout 1 09/06/2014 10:17 Page 1
P5 NITROGLYCERINE
EXPLOSIVES
PRODUCT AND COMPANY IDENTIFICATION
Product Type
Trade Names
Recommended Use
Nitroglycerine / ethylene glycol
dinitrate based explosives:
Blasting Explosives Type A
Seguridad 20SR
Seguridad 20SR is approved as a
P5 permitted explosive and may
be used where a P5 type explosive
is required.
Manufacturer / Supplier
EPC-UK EXPLOSIVES
Telephone Number
00-44-1773 832253
Address
Emergency Tel Number
e-mail
ROUGH CLOSE WORKS,
CARNFIELD HILL
SOUTH NORMANTON,
ALFRETON
DERBYSHIRE, DE55 2BE
00-44-1773 832253
info@epc-groupe.co.uk
P5 Permitted NITROGLYCERINE EXPLOSIVES_2014_Layout 1 09/06/2014 10:17 Page 2
DATA
HAZARD IDENTIFICATION
Main Hazards
EXPLOSIVE (E): Mass explosion
hazard. Risk of explosion by shock,
friction or fire VERY TOXIC (T+) by
inhalation, on contact with skin and if
swallowed. Once detonated,
explosive releases large quantities of
gas. If in a confined area, care
should be taken to ensure that there
is sufficient oxygen in the air before
approaching the site of an explosion.
The gases released may contain
some carbon monoxide – TOXIC (T) nitrogen monoxide and nitrogen
dioxide - VERY TOXIC (T+). The
HSE issued Chemical Hazard Alert
Notices (CHANs) covering nitrogen
monoxide and nitrogen dioxide.
These have now been suspended.
COMPOSITION / INFORMATION ON THE COMPONENTS
Products’ Hazardous Ingredients
Nitroglycerine
Ethylene Glycol
Dinitrate
Sodium Nitrate
EINECS/CAS
Number
EINECS 200-240-8
CAS 000055-63-0
EINECS 211-063-0
CAS 000628-96-6
EINECS 231-554-3
CAS 7631-99-4
Hazard
Symbols
E, T+, N
Risk Phrases
R3, R26/27/28,
R33, R51, R53
E, T+
R2, R26/27/28,
R33
O
R8
Note: The HSE issued CHANs regarding Nitroglycerine and Ethylene Glycol
Dinitrate. These have now been suspended.
FIRST AID MEASURES
First Aid – Eyes
First Aid – Skin
Wash eyes with copious amounts of
water for at least 15 minutes. Seek
medical attention.
Wash thoroughly with soap and
water. Remove contaminated clothing.
P5 Permitted NITROGLYCERINE EXPLOSIVES_2014_Layout 1 09/06/2014 10:17 Page 3
P5 NITROGLYCERINE
EXPLOSIVES
FIRST AID MEASURES Continued...
First Aid – Inhalation
First Aid – Ingestion
Advice to Physicians
FIRE FIGHTING MEASURES
Extinguishing Media
Special Hazards Of Product
Remove person to fresh air.
A person suffering from inhalation of
after detonation fumes must be
removed to fresh air, receive medical
attention and stay under medical
observation for at least 48 hours.
The person should lie down until the
doctor arrives.
Immediately drink plenty of water
and seek medical attention.
Absorption of the product in the body
may cause formation of
methaemoglobin, which, in sufficient
concentration, causes cyanosis.
Use water based extinguishers to
prevent fire reaching the explosive.
If the fire looks likely to reach the
explosive, retire to a safe distance
and cordon off the area. A minimum
distance of 300 m is recommended
for road transport and may need to
be greater dependant on the quantity
of explosives involved. Explosive –
may burn to detonation. Toxic and
irritating gases may be formed
during a fire.
ACCIDENTAL RELEASE MEASURES
Personal Precautions
Spillages
Wear gloves and overalls. Keep the
area well ventilated. If explosive
has come out of the cartridge, wear
an organic vapour mask. Prevent
access by unauthorised persons
Avoid all sources of flame, heat and
anything that might cause a spark.
Avoid impact and friction. Complete
cartridges may be picked up
manually. Ensure that the cartridges
are free of grit and dirt. Loose
powder from cartridges should be
P5 Permitted NITROGLYCERINE EXPLOSIVES_2014_Layout 1 09/06/2014 10:17 Page 4
DATA
ACCIDENTAL RELEASE MEASURES Continued...
Spillages
Continued...
HANDLING AND STORAGE
Handling
Storage
carefully picked up with a nonsparking tool, put in a plastic bag
and this placed in a fibreboard box.
No smoking - no sources of ignition.
Keep product clean and free from
contamination. Avoid shock, friction
and static discharges. When using
do not eat or drink. Do not open
cartridges.
Must be stored in accordance with
the Manufacture and Storage of
Explosives Regulations, 2005.
Handle cases with care. Do not open
cases in magazines or whilst in
transit or when loading or unloading
from vehicles. Keep the product
clean and free from contamination.
Storage rooms should be dry and
well ventilated. The shelf life of
Seguridad is 6 months after date of
manufacture.
Products:
EXPOSURE CONTROL / PERSONAL PROTECTION
Product UK Standards
Nitroglycerine (NG) - The previous
Occupational Exposure Standard
(OES) for NG (1.9 mg/m3, 0.2 ppm,)
has been withdrawn as it may not be
adequate to protect occupational
health. Exposures to NG should be
kept as low as is reasonably practical
and certainly to below 0.2 ppm. The
HSE has developed a biological
guidance monitoring value for NG.
This is 15 µmol nitroglycols/mol
creatinine based on measurement of
total urinary nitroglycols. Ethylene
Nitrate (EGDN) - The previous OES
for EGDN (1.3 mg/m3, 0.2 ppm) has
been withdrawn as it may not be
adequate to protect occupational
health.
P5 Permitted NITROGLYCERINE EXPLOSIVES_2014_Layout 1 09/06/2014 10:17 Page 5
P5 NITROGLYCERINE
EXPLOSIVES
EXPOSURE CONTROL / PERSONAL PROTECTION Continued...
After Detonation Fumes
UK Standards
Respiratory Protection
Exposures to EGDN should
be kept as low as is reasonably
practical and certainly to below
0.2 ppm.
Besides residual amounts of
unreacted product, the after
detonation fumes may include the
following gases:
Carbon Dioxide: 8 hr=5000 ppm,
9150 mg/m3; 15 min = 15,000 ppm,
27,400 mg/m3.
Carbon Monoxide: 8 hr=30 ppm,
35 mg/m3; 15 min = 200 ppm,
232 mg/m3.
Nitrogen Monoxide: The previous
OES for nitrogen monoxide (8hr =25
ppm, 31 mg/m3) was withdrawn, as it
may not be adequate to protect
occupational health. The CHAN
where the HSE recommended that
exposure to nitrogen monoxide
should not exceed 1 ppm has been
suspended. Users should aim to
follow ALARP (as low as reasonably
practical) principles (see ref [1].
Nitrogen Dioxide: The previous OES
for nitrogen dioxide (8hr = 3 ppm, 5.7
mg/m3) has been withdrawn, as it
may not be adequate to protect
occupational health. The CHAN
where the HSE recommended that
exposure to nitrogen dioxide should
not exceed 1 ppm has been suspended.
For unopened cartridges in a well
ventilated area normally no personal
respiratory protection is necessary.
However an organic vapour mask
should be used in some cases, e.g.
insufficiently ventilated magazine.
P5 Permitted NITROGLYCERINE EXPLOSIVES_2014_Layout 1 09/06/2014 10:17 Page 6
DATA
EXPOSURE CONTROL / PERSONAL PROTECTION Continued...
Hand Protection
Body Protection
Wear appropriate non-permeable
gloves, e.g. nitrile rubber. EPC-UK
Explosives will be happy to advise on
this, please contact our Explosives
Engineering Department.
Wear overalls. Do not continue to
wear overalls which are contaminated
with explosives.
PHYSICAL AND CHEMICAL PROPERTIES
Physical State
Colour
Odour
Solid, powder.
White with beige particles
Slightly sweet smell.
Solubility in Water (kg/m3)
Explosive is not water resistant.
Impact Sensitivity Test
≥4.9 J
Stability
This explosive is stable when stored
under normal conditions in a
dry magazine.
Density (kg/m3)
STABILITY AND REACTIVITY
Conditions to Avoid
Materials to Avoid
Hazardous Decomposition
Products
1.2 kg/l.
High temperatures, direct sunlight,
impact, friction, flames, sparks and
static discharge.
Acids and Bases.
Nitrogen Oxides, Oxides of Carbon,
including Carbon Monoxide may be
produced when the product is used.
The amounts of toxic gases
produced will depend on many
variables such as method of
initiation, rock type, humidity etc
TOXICOLOGICAL INFORMATION
Acute Toxicity
Product classified by conventional
calculation methods. All products
within the cartridge contain sufficient
nitroglycerine and/or ethylene glycol
P5 Permitted NITROGLYCERINE EXPLOSIVES_2014_Layout 1 09/06/2014 10:17 Page 7
P5 NITROGLYCERINE
EXPLOSIVES
TOXICOLOGICAL INFORMATION Continued...
Acute Toxicity
Continued...
Lethal Doses
Eco-toxicity
DISPOSAL
Product Disposal
Container Disposal
TRANSPORT INFORMATION
UK Transport Information
UN Number
dinitrate to remain very toxic.
Inhalation of vapours, ingestion or
absorption through the skin causes
a lowering of blood pressure. This
may cause headaches.
The following list gives LD50 oral
(rat) values for various of the raw
materials used in these products
Nitroglycerine
105 mg/kg
Ethylene Glycol dinitrate 616 mg/kg
Sodium nitrate
3430 mg/kg
Classification by conventional
calculation method
Under the supervision of an expert,
the product may be destroyed by
detonation in a borehole or by
burning at an approved site. For
more guidance see the HSE/CBI
Explosives Industry Group
publication: “Guidance for the Safe
Management of the Disposal of
Explosives”, January 2007.
The accepted method for disposing
of the empty boxes is burning on site.
Double check that the boxes are empty.
Must be in accordance with the
Carriage of Dangerous Goods and
Use of Transportable Pressure
Equipment Regulations 2011
UN0081
UN Class/Compatibility Group
1.1 D.
ADR/RID Substance ID. No
UN0081.
UN & ADR Name
ADR/RID –
Class/Compatibility Group
IMDG - Proper
Shipping Name
EXPLOSIVE, BLASTING, TYPE A.
1.1 D.
EXPLOSIVE, BLASTING, TYPE A.
P5 Permitted NITROGLYCERINE EXPLOSIVES_2014_Layout 1 09/06/2014 10:17 Page 8
DATA
TRANSPORT INFORMATION Continued...
IMDG –
Class/Compatibility Group
REGULATORY INFORMATION
Labelling Information
Risk and Safety Phrases:
Explosive
Risk Phrases
Safety Phrases
Other UK Legislation
EC Regulations
1.1 D.
Labelled in accordance with the
Carriage of Dangerous Goods and
Use of Transportable Pressure
Equipment Regulations 2009.
The Chemical Hazard Information
and Packaging for Supply
Regulations 2009 (note regs 6-11 do
not apply to the explosives covered
by this MSDS)
Serguridad 20SR
R2, R26/27/28,
R52/53
S27, S28, S35
S36/37, S41, S45,
Subject to The Manufacture and
Storage of Explosives Regulations
2005 and its approved codes of
practice. (as amended), The Control
of Explosives Regulations 1991 (as
amended) Placing on the Market
and Supervision of Transfers of
Explosives Regulations 1993 (as
amended) Explosives Act 1875
(what remains) Quarries Regulations
1999. The Control of Substances
Hazardous to Health Regulations
Registration, Evaluation,
Authorisation and Restriction of
Chemicals, EC Reg 1907/2006.
Classification, Labelling and
Packaging of Substances and
Mixtures, EC Reg 1272/2008. Note
this does not apply to mixtures until
June 2015, as such this data sheet
does not show the labelling
requirements under this reg.
P5 Permitted NITROGLYCERINE EXPLOSIVES_2014_Layout 1 09/06/2014 10:17 Page 9
P5 NITROGLYCERINE
EXPLOSIVES
REGULATORY INFORMATION Continued...
MSDS first issued
Meaning of R phrases
References
04/2012
R2 Risk of explosion by shock,
friction, fire or other sources
of ignition.
R3 Extreme risk of explosion by
shock, friction, fire or other sources
of ignition
R8 Contact with combustible
material may cause fire
R26/27/28 Very toxic by inhalation,
in contact with the skin and if
swallowed
R33 Danger of cumulative effect
R51 Toxic to aquatic organisms.
R52/53 Harmful to aquatic
organisms, may cause long term
adverse effect in the aquatic
environment.
S27 Take off immediately all
contaminated clothing.
S28 After contact with skin wash
immediately with plenty of water
and soap.
S35 This material and its container
must be disposed of in a safe way.
S36/37 Wear suitable protective
clothing and gloves.
S41 In case of fire and/or explosion
do not breathe fumes.
S45 In case of accident or if you
feel unwell seek medical advice
immediately.
1.“Occupational Exposure To
Nitrogen Monoxide in a Tunnel
Environment – Best Practice Guide”
First edition, British Tunnelling
Society, 2008
NOTICE:FOR FURTHER INFORMATION CONTACT
EPC-UK EXPLOSIVES ENGINEERING DEPARTMENT
Tel :00-44-1773-832253
Product guide covers_2014_Layout 1 09/06/2014 10:50 Page 13
PACKAGED
EXPLOSIVES
EXEM emulsion cartridges manufactured by
EPC Groupe in Europe are water in oil
emulsions, that is, oxidiser salts dispersed as
microscopically fine droplets, surrounded by
a continuous fuel phase.
The emulsion is stabilised against liquid separation by an emulsifier
(or surfactant). A density modifying agent is added to provide
sensitivity. Using the groupes advanced Emulsion technology Exem
is suitable for a wide range of applications across surface mining
and quarrying operations. The product provides the optimum
combination of safety, efficiency reliability and consistency and is
available in a range of cartridge sizes.
Key Features;
• High water resistance
• High Velocity of Detonation
• Good oxygen balance with low post blast fumes
• Good handling characteristics
• Available in two compositions (Exem 55 & Exem 100)
EPC-UK recommends the use of a booster for safe and efficient
priming when firing these compositions.
13
Packaged Explosives_2014_Layout 1 10/06/2014 15:12 Page 1
EXEM 55
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Packaged Explosives_2014_Layout 1 10/06/2014 15:12 Page 2
EXEM 100
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Packaged Explosives_2014_Layout 1 09/06/2014 10:34 Page 1
PACKAGED EXPLOSIVES
PRODUCT AND COMPANY IDENTIFICATION
Product Type
Emulsion
Product Description
Water in oil emulsion explosive.
Trade Names
EXEM 55 / EXEM 100
Manufacturer / Supplier
EPC-UK EXPLOSIVES
Telephone Number
00-44-1773 832253
Address
Emergency Tel Number
e-mail
ROUGH CLOSE WORKS
CARNFIELD HILL
SOUTH NORMANTON
ALFRETON
DERBYSHIRE, DE55 2BE
00-44-1773 832253
info@epc-groupe.co.uk
Packaged Explosives_2014_Layout 1 09/06/2014 10:34 Page 2
DATA
HAZARD IDENTIFICATION
Main Hazards
Health Effects – Eyes
Health Effects – Skin
Health Effects – Ingestion
Health Effects – Inhalation
Explosive E, R2
Irritant Xi, R36
May cause irritation.
Will cause skin irritation in case of
prolonged contact.
Small quantities unlikely to cause
toxic effect.
No direct effects from product.
After-detonation fumes contain
toxic gases.
COMPOSITION/INFORMATION ON THE COMPONENTS
EC/CAS
Number
Classification Classification Concentration
67/548/CE 1272/2008
Ammonium
Nitrate
EC 229-347-8
CAS 6484-52-2
Sodium Nitrate
EC 231-554-3
CAS 7631-99-4
0; R8
Sodium
perchlorate
EC 231-511-9
CAS 7601-89-0
0, R8; Xi, R36;
Xn, R22;
Xn, R48/R22
FIRST AID MEASURES
Eyes
Skin
Ingestion
Inhalation
Advice to Physicians
0, R8;
Xi, R36
0x. Liq.3, H272
Eye Dam./Irrit.2,
H319
0x. Liq.2, H272
Eye Dam./Irrit.2,
H319
50-70%
5-20%
<10%
Flush immediately with plenty
of water.
Wash immediately with plenty
of water.
Do not give anything to drink. If large
quantities have been swallowed,
do not induce vomiting.
Seek medical advice.
Physically clear airways to aid
breathing and then seek medical
advice. If after-detonation fumes are
inhaled, remove to fresh air and seek
medical advice.
Ingestion - mild cases of
methaemaglobinaemia will lead to
cyanosis and more severe cases
may produce unconsciousness.
Packaged Explosives_2014_Layout 1 09/06/2014 10:34 Page 3
PACKAGED EXPLOSIVES
FIRE FIGHTING MEASURES
Fire extinguishing means
Specific hazards resulting
from the mixture
Large quantities of water.
Product, depot or truck on fire:
Do not try to extinguish the fire,
evacuate the hazardous area
immediately and move all personnel
to a safe place sheltered from the
effects of an explosion. Isolate the
area and report the risk of explosion
to local authorities. In addition to the
explosion hazard, in case of fire,
fumes may be released with
emission of harmful gases (nitrogen
oxides and carbon monoxide).
Advice to fire-fighting personnel Immediately report the explosion
hazard to local authorities and firefighting personnel. If the fire looks
likely to reach the packaging, go away
from the area, evacuate immediately
all persons in the vicinity and isolate
the area in question. Go to a safe
distance and/or to a safe place.
Use powerful streams of water from a
safe position. If this can be
done without risks, move the emulsion
containers away before they are
reached by the fire. Protection of
fire-fighting personnel:
Wear self-contained breathing
apparatuses due to possible
release of harmful gases (nitrogen
oxides and carbon monoxide).
ACCIDENTAL RELEASE MEASURES
Personal Precautions
Avoid shocks, friction and everything
which may cause a spark. Move all
sources of heat and naked flames
away, move other pyrotechnical or
flammable materials away.
Wash hands immediately
in case of contact.
Packaged Explosives_2014_Layout 1 09/06/2014 10:34 Page 4
DATA
ACCIDENTAL RELEASE MEASURES Continued...
Environmental Precautions
Spillages
Products:
HANDLING AND STORAGE
Handling
Do not dispose of in sewers or in the
natural environment. Do not dispose
of with garbage or in a waste dump
or a furnace.
Wear rubber gloves, recover spilled
products and put them in plastic
bags. Do not mix the products in
particular with initiating devices.
Close the bags with adhesive tape or
elastic bands and put them in
cardboard boxes with adhesive tape.
During transport or handling: Inform
the manufacturer, its representative
or the consignee who are the only
ones authorised for waste disposal.
On operations site: Recover
explosive products, place them in
plastic bags, as indicated above, and
hand products over to the blaster
who will comply with the destruction
procedure set forth by the works site
instructions. Do not store with
flammable products or initiating
devices. Seek information from
expert personnel or the supplier.
Do not smoke or ignite
naked flames in the vicinity of the
products. Handle explosive
emulsions with care, avoid shocks
and contact with heat sources.
Do not open packages inside depots
or on handling areas. Avoid
contamination of the products. Use
antistatic and spark-proof tools and
accessories. Check preservation
condition before use. In case of
anomalies, the explosive emulsions
must not be used, they must be
returned to the supplier or destroyed
under supplier’s supervision.
Packaged Explosives_2014_Layout 1 09/06/2014 10:34 Page 5
PACKAGED EXPLOSIVES
HANDLING AND STORAGE Continued...
Storage
Do not exceed authorised quantities.
Only store together products from the
same compatibility group or from
compatible groups. Do not store with
flammable products or initiating
devices. Store in a cool, dry
magazine with average temperature
not exceeding 35 to 40°C. Storage
remains safe up to a temperature of
65°C, the product can only harden.
In such a case, contact our technical
department. Smoking and lighting a
fire in a storage place are strictly
prohibited. Do not use beyond the
shelf life. Do not cut the cartridges.
EXPOSURE CONTROL / PERSONAL PROTECTION
Control parameters
Exposure control
There is no occupational exposure
limit (OEL) for the substances of
the mixture.
Respiratory tract protection:
Not necessary. Hand protection:
All handling operations must be
carried out with plastic,
rubber or leather gloves. Eye
protection: Protective goggles are
strongly recommended to prevent
any possible splashes into the eyes
should the cartridge envelope break.
PHYSICAL AND CHEMICAL PROPERTIES
Physical state:
Grey plastic emulsion
Odour threshold:
Unknown
Odour:
pH:
Melting point:
Boiling point:
Flash point:
Evaporation rate:
Odourless
5.8 (dilution to 10%)
Not applicable
Not applicable
Not applicable
Not available
Packaged Explosives_2014_Layout 1 09/06/2014 10:34 Page 6
DATA
PHYSICAL AND CHEMICAL PROPERTIES Continued...
Flammability:
Not available
Upper/Lower flammability limits: Not available
Vapour pressure, Vapour density:
Not available
Relative density:
1.27
Partition coefficient
(n-octanol/water):
Not available
Solubility:
Viscosity:
Explosive properties
Shock sensitivity:
Friction sensitivity:
STABILITY AND REACTIVITY
Reactivity
Chemical stability
Conditions to be avoided
Not soluble
>3,000,000 cPs
No reaction at 50 J (Dry explosive:
Reaction at 28.6 J)
No reaction at 353 N (Dry explosive:
No reaction at 353 N).
Shock and friction sensitivity
increases in case of presence of hard
materials (dust, sand, etc.). Risk of
explosion in case of heavy shocks or
friction on material in confined state.
Explosion hazard, in case of
confinement, under the effect of
sudden increase in the temperature
(for example: a fire). Risk of instant
transmission to the entire explosive
mass. The sensitivity of the dry
product is higher than that of the
original product.
In normal storage conditions, the
product is chemically stable. The
recommended shelf life is one year.
Beyond that time, the product will not
be more dangerous but its reliability
of use is no longer guaranteed.
The limits for use of the product are
described in the technical data
sheets. Recommended climatic
conditions for use:
From -10°C to +60°C.
Refer to explosive properties related
to shock and friction sensitivity.
Packaged Explosives_2014_Layout 1 09/06/2014 10:34 Page 7
PACKAGED EXPLOSIVES
STABILITY AND REACTIVITY Continued...
Incompatible materials
Hazardous decomposition
products
Avoid contact with alkalis, amines,
strong acids, alkali metals, copper,
zinc. Store only with Class 1.1.D or
1.4.S products.
Combustion or explosion fumes
contain carbon oxides (COx) and
nitrogen oxides (NOx).
TOXICOLOGICAL INFORMATION
Acute Toxicity
Irritation/Corrosion
ECOLOGICAL INFORMATION
Ecotoxicity
The mixture is not classified as
harmful by the conventional method.
Information on components:
Ammonium Nitrate, LD50,
oral, rat, 2950 mg/kg.
Ammonium Nitrate, LD50,
dermal, rat, >5,000 mg/kg.
Sodium Nitrate, LD50,
oral, rat, 3430 mg/kg.
Sodium Nitrate, LD50,
dermal, rat, >5,000 mg/kg.
Ammonium Nitrate: Causes severe
eye irritation, may cause respiratory
tract irritation.
Ammonium nitrate
Acute toxicity, LC50, Fresh water
Fish 48 hours 447 mg/l
Acute toxicity, EC50, Fresh water
Daphnia 48 hours, 490 mg/l
Acute toxicity, EC50 Salt water
Aquatic plants 10 days, 1,700 mg/l
Sodium Nitrate
Acute toxicity, LC50 7, Oncorhynchus
tschawytscha 96 hours, 950 mg/l
Acute toxicity, EC50 Daphnia
24 hours, 8,609 mg/l
Acute toxicity, EC10 Microorganisms
3 hours 180 mg/l
Packaged Explosives_2014_Layout 1 09/06/2014 10:34 Page 8
DATA
ECOLOGICAL INFORMATION Continued...
Sodium perchlorate
Acute toxicity, LC50 Zebrafish
1,000 mg/l
Acute toxicity, EC50 Daphnia
48 hours >100 mg/l
Acute toxicity, Cl r50 Green algae
72 hours >436 mg/l
Acute toxicity, Bacteria 3 hours
EC50 >1,000 mg/l
NOEC Zebrafish 84 days 10 mg/l
NOEC Cerodaphnia dubia 7 days
12 mg/l
LC 50 earthworms 14 days
4.45 mg/kg
Persistence and degradability
Sodium perchlorate:
Not biodegradable in water.
Land mobility
Ammonium nitrate: Not available.
Sodium perchlorate:
Absorption/desorption: log Koc <2
Bioaccumulation potential
Results of the PBT
and vPvB assessments
DISPOSAL
Ammonium nitrate: Not available.
Sodium perchlorate: Not applicable.
Bioconcentration factor (BCF): 0.35
(OECD Method, Test Guideline 305,
Fish - Test substance: active material).
Ammonium nitrate, sodium nitrate
and sodium perchlorate: These
substances do not meet the definition
of PBT or vPvB in annexe XIII of the
REACH regulations.
The use of an emulsion does not
generate any other waste than the
cardboard boxes and polythene bags
which must be destroyed in
accordance with the regulations in
force. Never dispose of residues in
garbage bin or in rubbish dump.
Destroy residues in approved
facilities. Treatment of waste after
accidental spillage is dealt with in
the spillage section.
Packaged Explosives_2014_Layout 1 09/06/2014 10:34 Page 9
PACKAGED EXPLOSIVES
DISPOSAL Continued...
TRANSPORT INFORMATION
UK Transport Information
UN Number
UN Class
ADR/RID Substance ID No
ADR/RID Description
ADR/RID Class
IMDG Proper Shipping Name
IMDG Class
Contact the supplier’s distribution
depot to know the recovery
conditions. Packages contaminated
with explosive traces shall be
examined carefully to make sure they
are empty and laid flat. They may be
either burned on the place of use (if
the facility is approved). For more
guidance on the safe disposal of
explosives, see the HSE /CBI
Explosives Industry Group, Guidance
for the Safe Management of the
Disposal of Explosives January 2007.
Must be in accordance with
Carriage of Dangerous Goods
Regulations 2011.
UN 0241.
1.1 D.
UN0241.
Explosive, blasting, type E
1.1 D.
EXPLOSIVE, BLASTING, TYPE E
1.1 D.
REGULATORY INFORMATION
“The Manufacture and Storage of Explosives Regulations” 2005, SI 2005/1082 as amended.
“The Carriage of Dangerous Goods and Use of Transportable Pressure Equipment Regulations
2009” SI 2009/1348, as amended.
“The Placing on the Market and Supervision of Transfer of Explosives Regulations”
SI 1993/2714, as amended.
“The Control of Explosives Regulations” SI 1991/1531, as amended.
“The Identification and Traceability of Explosives Regulations” SI 2013/449.
Regulation (EC) no. 1907/2006 of the European Parliament and Council of
18th December 2006, concerning REACH;
ADR “European Agreement regarding the International Carriage of Dangerous Goods by Road”.
NOTICE:FOR FURTHER INFORMATION CONTACT
EPC-UK EXPLOSIVES ENGINEERING DEPARTMENT
Tel :00-44-1773-832253
Product guide covers_2014_Layout 1 09/06/2014 10:50 Page 14
BLASTING
ACCESSORIES
EPC-UK supply a complete
range of complementary
blasting accessories.
14
BLASTING ACCESSORIES_2014_Layout 1 09/06/2014 09:40 Page 1
BLASTING ACCESSORIES
Blasting Accessories Include
●
●
●
●
●
●
●
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Seismographs
Exploders
Ohmmeters
Plystem clay
stemming material
Stemming rods
Shotfiring cable
Connecting wire
Shotfirer’s tapes
Hand tools
BLASTING ACCESSORIES_2014_Layout 1 09/06/2014 09:40 Page 2
TEAMWORK
Nationwide Distribution
EPC-UK offers a
comprehensive network of
Explosives and Multiblend
Depots throughout the UK.
Shetland
Islands
Scotland
Settle
South
Wales
Cornwall
Alfreton
Whatley
Great
Oakley
Product guide cover & back_2014_Layout 1 06/06/2014 15:52 Page 4
Terms and Conditions
"The products and services that we supply to you are sold
subject to our standard Terms and Conditions of Supply
and any other Special Conditions that we notify to you.
Copies of these conditions are available on request."
The information contained in this booklet is given without
warranty and cannot cover all conditions of use. Users
should undertake their own tests to ensure the suitability
of the products for their own particular application.
Product guide cover & back_2014_Layout 1 06/06/2014 15:42 Page 1
Head Office
Unit 1, Venture Crescent
Alfreton
Derbyshire DE55 7RA
Telephone: 01773 832253
Rough Close Works
Carnfield Hill
South Normanton
Alfreton
Derbyshire DE55 2BE
Telephone: 01773 832253
Scotland Depot
Portcullis Estate
Milton Of Campsie
Glasgow G66 8AQ
Telephone: 0141 776 7196
www.epc-groupe.co.uk