Self-healing and self-reporting assets Improving the resilience of the energy distribution networks Self-healing and self-reporting concepts Gnosys is developing the next generation of materials for energy distribution networks. These possess the ability to alert the network operator to the condition of the asset, the development of faults or imminent failure (self-reporting). They may also have the ability to autonomously repair themselves to restore full functionality (self-repair). Self-reporting materials provide important information about asset health to the network operator, allowing them to make informed decisions about where to focus their attention. Self-healing materials are capable of efficient self-maintenance, effecting self-repair of assets to substantially extend asset lifetimes by preventing the development of defects leading to failure. Self-healing and self-reporting materials are of interest to companies operating high value assets, where unexpected failures can lead to costly and lengthy repair processes that disrupt supply. Self-reporting materials A simple, effective evaluation of asset health Gnosys has already developed asset measurements which report on the condition of materials. Further developments are investigating the incorporation of reporting molecules that can undergo a change in properties in response to changing conditions, such as an increase in mechanical strain, temperature, or pressure. When selecting a suitable “reporter”, consideration should be given to determining what asset changes represent a critical state, as this will inevitably influence the reporting component used. The same consideration must also be given to the manner in which the material relays information to inspection teams; while a change in colour may be an obvious solution, many assets are not readily accessible and so changes in electrical resistivity or frequency of transmitted light may prove to be more suitable. Gnosys has investigated a wide range of materials that can be incorporated into assets either during processing or later, as self-reporting paints and coatings. Routes to stimulate self-reporting materials Self-healing polymeric materials 50 μm Improved resilience, enhanced lifetimes Self-healing materials have great potential for many utility assets, particularly those of high value or where the asset is hard to access or maintain. If the asset is damaged, the self-healing material is capable of undergoing a response that can lead to repair and restore asset health and functionality. This capability confers a number of benefits to an asset and its operators, as the ability to autonomously repair minor defects improves resilience, reduces maintenance requirements, and extends asset lifetime by preventing the development of major faults from minor defects. Example: Within the UK, underground cables represent between 60 and 70% of the distribution network, and there is a rapidly growing network of subsea cables servicing offshore wind-farms and islands. In these instances, the location of the asset renders it inaccessible, and so routine maintenance is rare. If the protective sheath is damaged water can enter and degrade the cable over the course of several years, resulting in premature failure. A cablethreatening defect can develop from holes in the sub-millimetre range to much larger externally inflicted damage, and also damage that occurs during manufacturing or installation – this damage may well go undetected. Cable makers currently protect cables from water incursion with the addition of ‘water blocking tape’, which consists of a fabric scaffold containing an additive that swells strongly in water. However, investigations carried out by Gnosys have found that this material can be ineffective and be dissolved or stripped from the cable by a sufficient quantity of water, limiting the intended protection. Moreover, common water blocking tapes must be wound onto the cable using specialist machinery, which is a time consuming and expensive process. In the search for alternatives, Gnosys has investigated a range of selfhealing and water blocking materials that can be incorporated into cable designs. The requirements on potential candidates are highly demanding, as they must be capable of undertaking cable repair over a range of temperatures and pressures in highly aggressive environments. It is also very important that these materials be compatible with current cable processing techniques and can be incorporated into a wide range of designs without negatively affecting the cable performance. Finally, a successful system must have a price point commensurate with currently used water blocking systems and also replace these systems. Potential candidate materials have been selected that possess different repair mechanisms. One type are supramolecular materials that derive structural support from labile hydrogen bonds. When broken, the hydrogen bonds can quickly reform and generate a new matrix mechanically identical to the pre-damage system. Another is an advanced water-blocking material that combines an excellent water blocking response with strong material integrity, thereby avoiding the problems related to dissociation and additive stripping in water blocking tapes. Although this material does not truly self-repair, the swelling response serves to restore the integrity of the cable sheath and prevent further ingress of water, and so provides a ‘cable repair’. Further, these materials possess excellent water blocking capabilities that far surpass those of contemporary water blocking tapes in every aspect. Importantly, these materials can be incorporated into cables using conventional extrusion and melt spray deposition techniques. Both methods avoid the use of expensive tape-winding machines, resulting in substantial capital savings and increased production efficiency without sacrificing speed or final quality. Self-healing fluid systems Another aspect of self-repair that has been explored by Gnosys is that of self-healing reactive oils for fluid filled cables (or FFCs). FFCs have been in use throughout the UK power network since the 1950s, and until the 1980s paper and oil insulation systems substantially outperformed solid polymeric cables. While these cables are currently being replaced by XLPE-insulated circuits, there are still approximately 8,500 km of FFC remaining in the UK. In some cases, these have exceeded their anticipated operational lifetime by 30 to 40 years. In the event of a breach on a fluid filled cable, the insulation oil will leak into the surrounding environment. While this can be replaced, the leaked oil represents an environmental hazard and can potentially contaminate water supplies. Information from Ofgem (left) shows that approximately 400,000 litres of oil is replaced annually across the entire UK FFC network, which represents substantial costs in replacing oil and environmental remediation. In cables with multiple severe leaks, it is often more cost effective to replace the system in its entirety. Unlike solid polymeric cables, fluid filled cables are no longer being produced on a large scale, but stock is being held by network operators to replace damaged sections. Instead, Gnosys has developed additives and reactive replacements to the insulation oil to limit the risks of leaking cables. The aim of this is to generate oils that possess similar fluid and electrical properties currently used insulation oils that would solidify within damaged regions, thereby preventing the further loss of oil. Gnosys have investigated a wide range of potential approaches which have yielded a number of different compositions that can be considered as potential candidates. We have also developed a range of ‘containment oil’ blends, which act to minimise environmental contamination by curing within the soil. These form large pockets that can entrap insulation oils in the region immediately surrounding the cable, thereby minimising the volume of oil that can enter groundwater and simplifying environmental remediation. All potential oil blends are currently undergoing optimisation and cable trialling in the near future before being trialled in network tests with participating DNOs, prior to full deployment. Summary With the help of Electricity Network Innovation Allowance support, Gnosys is developing several technology platforms that are aimed to substantially enhance the resilience of power distribution networks. Our interest in gas pipeline materials are also driving novel, self-reporting materials for new assets and coatings development for existing assets. It is hoped that these will be used to improve asset health monitoring in the future. Self-healing materials which confer asset self-repair is a second technology platform. We have found that it is possible to incorporate materials with excellent water blocking materials into current cable designs with no change to existing cable manufacturing processes. Improved cable repair technologies should substantially extend the operational life of cables and reduce the number of premature failures. This represents substantial operational savings for cable operators, who would otherwise have to invest significant time and money in locating, diagnosing, and resolving faults that could be rectified autonomously. Similarly, our work with legacy fluid-filled circuits promises to substantially reduce the volume of oil lost to the surrounding environment. This is of substantial benefit to the operators of the circuits, who are required to report leakages and take immediate action in severe cases. Testing suggests that some of the proposed additive systems will enhance the breakdown strength of the insulation oil, which in turn would improve the quality of the insulation alongside providing the selfhealing function. Gnosys Global Ltd 17 Frederick Sanger Road The Surrey Research Park Guildford, Surrey GU2 7YD UK Tel: +44(0) 1483 689 599 enquiries@gnosysgroup.com For more information visit http://www.gnosysglobal.com/