for use in the State Examinations Page 1 PDF Watermark Remover DEMO : Purchase from www.PDFWatermarkRem Formulae and Tables PDF Watermark Remover DEMO : Purchase from www.PDFWatermarkRem Draft for consultation Observations are invited on this draft booklet of Formulae and Tables, which is intended to replace the Mathematics Tables for use in the state examinations. In 2007, the State Examinations Commission convened a working group to review and update the Mathematics Tables booklet, which is provided to candidates for use in the state examinations. The Department of Education and Science and the National Council for Curriculum and Assessment are represented on the working group. The group has carried out some consultation and now presents this draft for wider consultation. This draft is available in English only. The final booklet will be provided in both Irish and English. Anyone receiving this document should note its draft status, and should not assume that content currently in the draft will be included in the final version. The final version will be circulated to all schools in advance of its introduction in the state examinations. The working group recognises that the Mathematics Tables booklet is used by other institutions in their own examinations and by various individuals for other purposes. Whereas the needs of such users will be noted, final decisions will be taken in the context of the booklet’s primary purpose as a reference for candidates taking examinations conducted by the State Examinations Commission. Comments should be forwarded by e-mail to tables@examinations.ie before 31 May 2008. Page 2 PDF Watermark Remover DEMO : Purchase from www.PDFWatermarkRem Contents Length and area ....................................................................................................................................................4 Surface area and volume.......................................................................................................................................5 Area approximations.............................................................................................................................................6 Trigonometry ........................................................................................................................................................7 Co-ordinate geometry .........................................................................................................................................10 Geometry ............................................................................................................................................................11 Algebra ...............................................................................................................................................................12 Sequences and series ..........................................................................................................................................12 Number sets – notation .......................................................................................................................................13 Calculus ..............................................................................................................................................................14 Financial mathematics ........................................................................................................................................16 Statistics and probability.....................................................................................................................................18 Units of measurement .........................................................................................................................................26 Common quantities, their symbols and units of measurement ...........................................................................28 Frequently used constants...................................................................................................................................33 Particle physics ...................................................................................................................................................34 Mechanics...........................................................................................................................................................36 Heat and temperature..........................................................................................................................................41 Waves .................................................................................................................................................................41 Electricity............................................................................................................................................................43 Modern physics...................................................................................................................................................45 Electrical circuit symbols ...................................................................................................................................46 The elements.......................................................................................................................................................51 . Page 3 PDF Watermark Remover DEMO : Purchase from www.PDFWatermarkRem Length and area Parallelogram b h C Arc / Sector Triangle c θ h r a Perimeter = 2a + 2b Area = ah = ab sin C When θ is in radians: Length of arc = rθ Circle / Disc Area of sector = r Length of circle = 2 π r Area of disc = πr 2 1 2 r 2θ a Perimeter = a + b + c Area = 1 2 ah = 1 2 ab sin C When θ is in degrees: ⎛ θ ⎞ Length of arc = 2 π r ⎜ ⎟ ⎝ 360° ⎠ ⎛ θ ⎞ ⎟ ⎝ 360° ⎠ Area of sector = π r 2 ⎜ b = C s ( s − a)( s − b)( s − c) , where s = a+b+c . 2 Page 4 PDF Watermark Remover DEMO : Purchase from www.PDFWatermarkRem Surface area and volume Cylinder Sphere Solid of uniform cross-section (prism) r r h h Curved surface area = 2 π rh Volume = π r 2 h A Surface area = 4 π r 2 Volume = 4 3 πr Volume = Ah , where A is the area of the base. 2 Pyramid on any base Cone Frustum of a cone l h r 1 3 πr 2 h h R Curved surface area = π rl Volume = h r Volume = 1 3 ( 2 π h R + Rr + r A 2 ) Volume = 1 3 Ah , where A is the area of the base. Page 5 PDF Watermark Remover DEMO : Purchase from www.PDFWatermarkRem Area approximations Trapezoidal rule: Area ≈ h [ y1 + y n + 2( y 2 + y3 + y 4 + L + y n−1 )] 2 or ≈ h [first + last + twice the rest ] 2 y1 y2 y3 y4 … yn h Simpson’s rule: Area ≈ h [ y1 + y n + 2( y3 + y5 + L + y n−2 ) + 4( y 2 + y 4 + L + y n−1 )] , (where n is odd) 3 or ≈ h [first + last + twice the odds + four times the evens] 3 Page 6 PDF Watermark Remover DEMO : Purchase from www.PDFWatermarkRem Trigonometry 1 Definitions sin A tan A = cos A 1 cot A = tan A 1 sec A = cos A 1 cosec A = sin A –1 (cos A, sin A) A 1 –1 Trigonometric ratios of certain angles A (degrees) 0° 90° 180° 270° 30° 45° 60° A (radians) 0 π 2 π 3π 2 π 6 cos A 1 0 –1 0 π 4 1 π 3 1 2 sin A 0 1 0 –1 tan A 0 not defined 0 not defined 3 2 1 2 1 3 2 1 2 3 2 1 3 Basic identities cos 2 A + sin 2 A = 1 cos(− A) = cos A sin( − A) = − sin A tan(− A) = − tan A Page 7 PDF Watermark Remover DEMO : Purchase from www.PDFWatermarkRem Compound angle formulae Double angle formulae cos( A + B ) = cos A cos B − sin A sin B cos 2 A = cos 2 A − sin 2 A cos( A − B ) = cos A cos B + sin A sin B sin 2 A = 2 sin A cos A sin( A + B ) = sin A cos B + cos A sin B tan 2 A = 2 tan A 1 − tan 2 A cos 2 A = 1 − tan 2 A 1 + tan 2 A sin 2 A = 2 tan A 1 + tan 2 A cos 2 A = 1 2 (1 + cos 2 A) sin 2 A = 1 2 (1 − cos 2 A) sin( A − B ) = sin A cos B − cos A sin B tan( A + B) = tan A + tan B 1 − tan A tan B tan( A − B) = tan A − tan B 1 + tan A tan B Page 8 PDF Watermark Remover DEMO : Purchase from www.PDFWatermarkRem Products to sums and differences Trigonometry of the triangle 2 cos A cos B = cos( A + B) + cos( A − B ) 2 sin A cos B = sin( A + B ) + sin( A − B ) 2 sin A sin B = cos( A − B) − cos( A + B) cos A + cos B = 2 cos A+ B A− B cos 2 2 cos A − cos B = −2 sin A+ B A− B sin 2 2 b Area = B 2 cos A sin B = sin( A + B ) − sin( A − B ) Sums and differences to products A c ab sin C C a Sine rule: 1 2 a b c = = sin A sin B sin C Cosine rule: a 2 = b 2 + c 2 − 2bc cos A In a right-angled triangle, A+ B A− B sin A + sin B = 2 sin cos 2 2 sin = opposite hypotenuse A+ B A− B sin A − sin B = 2 cos sin 2 2 cos = adjacent hypotenuse tan = opposite adjacent Page 9 PDF Watermark Remover DEMO : Purchase from www.PDFWatermarkRem Co-ordinate geometry Line Slope: m = Distance = y 2 − y1 x 2 − x1 ( x1 , y1 ) ( x 2 − x1 ) 2 + ( y 2 − y1 ) 2 ( x2 , y 2 ) ⎛ x + x 2 y1 + y 2 ⎞ , Midpoint = ⎜ 1 ⎟ 2 ⎠ ⎝ 2 Equation of a line: y − y1 = m( x − x1 ) or y = mx + c Area of a triangle with one vertex at the origin = 1 2 x1 y 2 − x 2 y1 ⎛ bx + ax 2 by1 + ay 2 ⎞ , Point dividing a line segment in the ratio a : b = ⎜ 1 ⎟ a+b ⎠ ⎝ a+b Distance from a point to a line = ax1 + by1 + c a2 + b2 Page 10 PDF Watermark Remover DEMO : Purchase from www.PDFWatermarkRem Circle Equation of a circle, centre (h, k ) , radius r: ( x − h) 2 + ( y − k ) 2 = r 2 Circle x 2 + y 2 + 2 gx + 2 fy + c = 0 has centre (− g ,− f ) and radius Tangent to circle through given point: g2 + f 2 −c ( x − h)( x1 − h) + ( y − k )( y1 − k ) = r 2 or xx1 + yy1 + g ( x + x1 ) + f ( y + y1 ) + c = 0 Geometry Notation Line through A and B: AB Vector operations v 1 = x1i + y1 j , v 2 = x 2 i + y 2 j Line segment from A to B: AB Scalar product: Distance from A to B: AB Vector from A to B: AB Vector from origin O to A: OA = a v 1 ⋅ v 2 = x1 x 2 + y1 y 2 = v 1 v 2 cos θ Norm: v = x2 + y2 Page 11 PDF Watermark Remover DEMO : Purchase from www.PDFWatermarkRem Algebra Roots of quadratic equation: x = − b ± b 2 − 4ac 2a n Binomial theorem: ( x + y ) n = ∑ r =0 ⎛ n ⎞ n − r r ⎛ n ⎞ n ⎛ n ⎞ n −1 ⎛n⎞ ⎛n⎞ ⎛n⎞ ⎜⎜ ⎟⎟ x y = ⎜⎜ ⎟⎟ x + ⎜⎜ ⎟⎟ x y + ⎜⎜ ⎟⎟ x n − 2 y 2 + L ⎜⎜ ⎟⎟ x n − r y r + L + ⎜⎜ ⎟⎟ y n ⎝r⎠ ⎝0⎠ ⎝1⎠ ⎝ 2⎠ ⎝r⎠ ⎝n⎠ De Moivre’s theorem: [r (cos θ + i sin θ )] = r n (cos nθ + i sin nθ ) = r n e inθ or (r cis θ ) = r n cis(nθ ) n ⎛a b ⎞ ⎟⎟ : Inverse of matrix A = ⎜⎜ ⎝c d ⎠ n 1 ⎛ d − b⎞ ⎜ ⎟ , where det A = ad − bc det A ⎜⎝ − c a ⎟⎠ Sequences and series Arithmetic sequence or series Tn = a + (n − 1)d Sn = n [2a + (n − 1)d ] 2 Geometric sequence or series Tn = ar n −1 Sn = a (1 − r n ) 1− r S∞ = a , where r < 1 1− r Page 12 PDF Watermark Remover DEMO : Purchase from www.PDFWatermarkRem Number sets – notation Natural numbers: Whole numbers: Integers: Rational numbers: Real numbers: Complex numbers: N = {1, 2, 3, 4, L} W = {0, 1, 2, 3, 4, L} Z = {L − 3, − 2, − 1, 0, 1, 2, 3, L} ⎧p ⎫ p ∈ Z, q ∈ Z , q ≠ 0 ⎬ Q=⎨ ⎩q ⎭ R C = a + bi a ∈ R, b ∈ R, i 2 = −1 { } Page 13 PDF Watermark Remover DEMO : Purchase from www.PDFWatermarkRem Calculus Differentiation f (x) f ′(x) xn ex nx n −1 1 x ex e ax ae ax ax cos x a x ln a − sin x sin x cos x tan x sec 2 x 1 ln x cos −1 x a x a x tan −1 a sin −1 − 2 a −x 1 a2 − x2 a 2 a + x2 Product rule y = uv ⇒ Quotient rule dy dv du =u +v dx dx dx u y= v ⇒ dy = dx v du dv −u dx dx 2 v Chain rule y = u (v( x)) ⇒ dy du dv = dx dv dx Newton-Raphson Iteration f ( xn ) x n +1 = x n − f ′( x n ) Maclaurin series 2 f ( x) = f (0) + f ′(0) x + f ′′(0) 2 f ( r ) ( 0) r x +L + x +L r! 2! Taylor series f ( x + h) = f ( x) + hf ′( x) + h2 hr f ′′( x) + L + f 2! r! (r ) ( x) + L Page 14 PDF Watermark Remover DEMO : Purchase from www.PDFWatermarkRem Integration Constants of integration omitted. Integration by parts f (x) ∫ f ( x)dx x n , (n ≠ −1) x n +1 n +1 1 x ex ln x cos x sin x − cos x tan x ln sec x a x (a > 0) 1 2 a −x 1 2 x + a2 2 (a > 0) (a > 0) sin −1 Solid of revolution about x-axis Volume = ex 1 ax e a ax ln a sin x e ax ∫ udv = uv − ∫ vdu ∫ x =b π y 2 dx x =a x a 1 x tan −1 a a Page 15 PDF Watermark Remover DEMO : Purchase from www.PDFWatermarkRem Financial mathematics In all of the following, t is the time in years and i is annual rate of interest, depreciation or growth, expressed as a decimal or fraction (so that, for example, i = 0·08 represents a rate of 8%)1. Compound interest: F = P(1 + i ) t Present value: P = F (1 + i )t (F = final value. P = principal) (F = final value. P = present value) Depreciation – reducing balance method: F = P(1 − i ) t (P = initial value. F = later value.) Depreciation – straight line method: Annual depreciation = initial cost − residual value useful economic life Amortisation (mortgages and loans – equal repayments at equal intervals): R=A 1 i (1 + i ) t (1 + i ) t − 1 (R = repayment amount, A = amount advanced) The formulae also apply when compounding at equal intervals other than years. In such cases, t is measured in the relevant periods of time, and i is the period rate. Page 16 PDF Watermark Remover DEMO : Purchase from www.PDFWatermarkRem Annual percentage rate (APR) – statutory formula The APR is the value of i (expressed as a percentage) for which the sum of the present values of all advances is equal to the sum of the present values of all repayments. That is, the value of i for which the following equation holds: k =M ∑ k =1 Ak = (1 + i )Tk j =m Rj ∑ (1 + i) j =1 tj where: M is the number of advances Ak is the amount of advance k Tk is the time in years from the relevant date to advance k m is the number of repayments Rj is the amount of repayment j tj is the time in years from the relevant date to instalment j. Converting period rate to APR/AER i = (1 + r ) m − 1 where: i is the APR or AER (expressed as a decimal) r is the period rate (expressed as a decimal) m is the number of periods in one year. Page 17 PDF Watermark Remover DEMO : Purchase from www.PDFWatermarkRem Statistics and probability Mean From list: μ = Σx n From frequency table: μ = The standard error of the mean is Σfx Σf From list: σ = Σ( x − μ ) 2 n From frequency table: σ = Σf ( x − μ ) 2 Σf Sampling The sample mean x is an unbiased estimator of the population mean μ. The adjusted sample standard Σ( x − μ ) 2 is an unbiased estimator deviation s = n −1 of the population standard deviation σ. n standard error of the proportion is Hypothesis testing Tukey quick test: Significance level Critical value of tail-count Standard deviation σ t-test: t= χ -test: 2 pq . n 1% 10 0.1% 13 X −μ ⎛ s ⎞ ⎜⎜ ⎟⎟ ⎝ n⎠ k 2 5% 7 and the χ = ∑ i =1 (Oi − E i ) 2 Ei Page 18 PDF Watermark Remover DEMO : Purchase from www.PDFWatermarkRem Probability distributions Binomial distribution: ⎛n⎞ P (r ) = ⎜⎜ ⎟⎟ p r q n − r ⎝r⎠ μ = np Binomial coefficients ⎛n⎞ n n! ⎜⎜ ⎟⎟= C r = C (n, r ) = r!(n − r )! ⎝r⎠ n Some values of C r : σ = npq n Poisson distribution: P(r ) = e −λ λr r! μ =λ , λ = np σ= λ Normal (Gaussian) distribution: f ( x) = 1 σ 2π e − ( x−μ )2 2σ 2 Standard normal distribution: 1 1 − 2 z2 f ( z) = e 2π x−μ Standardising formula: z = σ r 0 1 2 3 4 5 6 7 0 1 1 1 1 2 1 2 1 3 1 3 3 1 4 1 4 6 4 5 1 5 10 10 5 1 6 1 6 15 20 15 6 7 1 7 21 35 35 21 7 1 8 1 8 28 56 70 56 28 8 8 1 1 1 9 1 9 36 84 126 126 84 36 9 10 1 10 45 120 210 252 210 120 45 11 1 11 55 165 330 462 462 330 165 12 1 12 66 220 495 792 924 792 495 13 1 13 78 286 715 1287 1716 1716 1287 14 1 14 91 364 1001 2002 3003 3432 3003 15 1 15 105 455 1365 3003 5005 6435 6435 Page 19 PDF Watermark Remover DEMO : Purchase from www.PDFWatermarkRem Area under the standard normal curve P ( z ≤ z1 ) = 1 2π ∫ z1 − 1 z 2 e 2 dz −∞ -3 -2 -1 0 1 z 2 1 z1 0·00 0·01 0·02 0·03 0·04 0·05 0·06 0·07 0·08 0·09 0·0 0·5000 5040 5080 5120 5160 5199 5239 5279 5319 5359 0·1 0·2 0·3 0·4 0·5398 0·5793 0·6179 0·6554 5438 5832 6217 6591 5478 5871 6255 6628 5517 5910 6293 6664 5557 5948 6331 6700 5596 5987 6368 6736 5636 6026 6406 6772 5675 6064 6443 6808 5714 6103 6480 6844 5753 6141 6517 6879 0·5 0·6915 6950 6985 7019 7054 7088 7123 7157 7190 7224 0·6 0·7 0·8 0·9 0·7257 0·7580 0·7881 0·8159 7291 7611 7910 8186 7324 7642 7939 8212 7357 7673 7967 8238 7389 7704 7995 8264 7422 7734 8023 8289 7454 7764 8051 8315 7486 7794 8078 8340 7517 7823 8106 8365 7549 7852 8133 8389 1·0 0·8413 8438 8461 8485 8508 8531 8554 8577 8599 8621 3 Page 20 PDF Watermark Remover DEMO : Purchase from www.PDFWatermarkRem Area under the standard normal curve (continued) z1 0·00 0·01 0·02 0·03 0·04 0·05 0·06 0·07 0·08 0·09 1·1 1·2 1·3 1·4 0·8643 0·8849 0·9032 0·9192 8665 8869 9049 9207 8686 8888 9066 9222 8708 8907 9082 9236 8729 8925 9099 9251 8749 8944 9115 9265 8770 8962 9131 9279 8790 8980 9147 9292 8810 8997 9162 9306 8830 9015 9177 9319 1·5 0·9332 9345 9357 9370 9382 9394 9406 9418 9429 9441 1·6 1·7 1·8 1·9 0·9452 0·9554 0·9641 0·9713 9463 9564 9649 9719 9474 9573 9656 9726 9484 9582 9664 9732 9495 9591 9671 9738 9505 9599 9678 9744 9515 9608 9686 9750 9525 9616 9693 9756 9535 9625 9699 9761 9545 9633 9706 9767 2·0 0·9772 9778 9783 9788 9793 9798 9803 9808 9812 9817 2·1 2·2 2·3 2·4 0·9821 0·9861 0·9893 0·9918 9826 9864 9896 9920 9830 9868 9898 9922 9834 9871 9901 9925 9838 9875 9904 9927 9842 9878 9906 9929 9846 9881 9909 9931 9850 9884 9911 9932 9854 9887 9913 9934 9857 9890 9916 9936 2·5 0·9938 9940 9941 9943 9945 9946 9948 9949 9951 9952 2·6 2·7 2·8 2·9 0·9953 0·9965 0·9974 0·9981 9955 9966 9975 9982 9956 9967 9976 9982 9957 9968 9977 9983 9959 9969 9977 9984 9960 9970 9978 9984 9961 9971 9979 9985 9962 9972 9979 9985 9963 9973 9980 9986 9964 9974 9981 9986 3·0 0·9987 9987 9987 9988 9988 9989 9989 9989 9990 9990 Page 21 PDF Watermark Remover DEMO : Purchase from www.PDFWatermarkRem Chi-squared distribution – inverse values The table gives the value of k corresponding to the indicated area A. That is, given a required probability A, the table gives the value of k for which P χ 2 > k = A . ( Degrees of A = 0·995 freedom 0·0000 1 0·0100 2 0·0717 3 0·2070 4 0·4117 5 0·6757 6 0·9893 7 1·3444 8 1·7349 9 2·1559 10 2·6032 11 3·0738 12 3·5650 13 4·0747 14 A ) k 0·99 0·975 0·95 0·05 0·025 0·01 0·005 0·0002 0·0201 0·1148 0·2971 0·5543 0·8721 1·2390 1·6465 2·0879 2·5582 3·0535 3·5706 4·1069 4·6604 0·0010 0·0506 0·2158 0·4844 0·8312 1·2373 1·6899 2·1797 2·7004 3·2470 3·8157 4·4038 5·0088 5·6287 0·0039 0·1026 0·3518 0·7107 1·1455 1·6354 2·1673 2·7326 3·3251 3·9403 4·5748 5·2260 5·8919 6·5706 3·8415 5·9915 7·8147 9·4877 11·070 12·592 14·067 15·507 16·919 18·307 19·675 21·026 22·362 23·685 5·0239 7·3778 9·3484 11·143 12·833 14·449 16·013 17·535 19·023 20·483 21·920 23·337 24·736 26·119 6·6349 9·2103 11·345 13·277 15·086 16·812 18·475 20·090 21·666 23·209 24·725 26·217 27·688 29·141 7·8794 10·597 12·838 14·860 16·750 18·548 20·278 21·955 23·589 25·188 26·757 28·300 29·819 31·319 Page 22 PDF Watermark Remover DEMO : Purchase from www.PDFWatermarkRem Chi-squared distribution – inverse values (continued) Degrees of A = 0·995 freedom 4·6009 15 5·1422 16 5·6972 17 6·2648 18 6·8440 19 7·4338 20 8·0337 21 8·6427 22 9·2604 23 9·8862 24 10·520 25 11·160 26 11·808 27 12·461 28 13·121 29 13·787 30 20·707 40 27·991 50 35·534 60 43·275 70 51·172 80 59·196 90 67·328 100 0·99 0·975 0·95 0·05 0·025 0·01 0·005 5·2293 5·8122 6·4078 7·0149 7·6327 8·2604 8·8972 9·5425 10·196 10·856 11·524 12·198 12·879 13·565 14·256 14·953 22·164 29·707 37·485 45·442 53·540 61·754 70·065 6·2621 6·9077 7·5642 8·2307 8·9065 9·5908 10·283 10·982 11·689 12·401 13·120 13·844 14·573 15·308 16·047 16·791 24·433 32·357 40·482 48·758 57·153 65·647 74·222 7·2609 7·9616 8·6718 9·3905 10·117 10·851 11·591 12·338 13·091 13·848 14·611 15·379 16·151 16·928 17·708 18·493 26·509 34·764 43·188 51·739 60·391 69·126 77·929 24·996 26·296 27·587 28·869 30·144 31·410 32·671 33·924 35·172 36·415 37·652 38·885 40·113 41·337 42·557 43·773 55·758 67·505 79·082 90·531 101·88 113·15 124·34 27·488 28·845 30·191 31·526 32·852 34·170 35·479 36·781 38·076 39·364 40·646 41·923 43·195 44·461 45·722 46·979 59·342 71·420 83·298 95·023 106·63 118·14 129·56 30·578 32·000 33·409 34·805 36·191 37·566 38·932 40·289 41·638 42·980 44·314 45·642 46·963 48·278 49·588 50·892 63·691 76·154 88·379 100·43 112·33 124·12 135·81 32·801 34·267 35·718 37·156 38·582 39·997 41·401 42·796 44·181 45·559 46·928 48·290 49·645 50·993 52·336 53·672 66·766 79·490 91·952 104·21 116·32 128·30 140·17 Page 23 PDF Watermark Remover DEMO : Purchase from www.PDFWatermarkRem Student’s t-distribution – two-tailed inverse values The table gives the value of k corresponding to the indicated area A in the two tails of the distribution. A 2 That is, the table gives the value of k for which P ( t > k ) = A . degrees of freedom A 2 -k k Significance level 20% 10% 5% 2% 1% 0·2% 0·1% 0·02% 0·01% 1 2 3 4 3·078 6·314 12·71 31·82 63·66 318·3 636·6 3183 6366 1·886 1·638 1·533 2·920 2·353 2·132 4·303 3·182 2·776 6·965 4·541 3·747 9·925 5·841 4·604 22·33 10·21 7·173 31·60 12·92 8·610 70·70 22·20 13·03 99·99 28·00 15·54 5 1·476 2·015 2·571 3·365 4·032 5·893 6·869 9·678 11·18 6 7 8 9 1·440 1·415 1·397 1·383 1·943 1·895 1·860 1·833 2·447 2·365 2·306 2·262 3·143 2·998 2·896 2·821 3·707 3·499 3·355 3·250 5·208 4·785 4·501 4·297 5·959 5·408 5·041 4·781 8·025 7·063 6·442 6·010 9·082 7·885 7·120 6·594 10 1·372 1·812 2·228 2·764 3·169 4·144 4·587 5·694 6·211 11 12 13 14 1·363 1·356 1·350 1·345 1·796 1·782 1·771 1·761 2·201 2·179 2·160 2·145 2·718 2·681 2·650 2·624 3·106 3·055 3·012 2·977 4·025 3·930 3·852 3·787 4·437 4·318 4·221 4·140 5·453 5·263 5·111 4·985 5·921 5·694 5·513 5·363 15 1·341 1·753 2·131 2·602 2·947 3·733 4·073 4·880 5·239 Page 24 PDF Watermark Remover DEMO : Purchase from www.PDFWatermarkRem Student’s t-distribution – two-tailed inverse values (continued) Significance level degrees of freedom 20% 10% 5% 2% 1% 0·2% 0·1% 0·02% 0·01% 16 17 18 19 1·337 1·333 1·330 1·328 1·746 1·740 1·734 1·729 2·120 2·110 2·101 2·093 2·583 2·567 2·552 2·539 2·921 2·898 2·878 2·861 3·686 3·646 3·610 3·579 4·015 3·965 3·922 3·883 4·790 4·715 4·648 4·590 5·134 5·043 4·966 4·899 20 1·325 1·725 2·086 2·528 2·845 3·552 3·850 4·539 4·838 21 22 23 24 1·323 1·321 1·319 1·318 1·721 1·717 1·714 1·711 2·080 2·074 2·069 2·064 2·518 2·508 2·500 2·492 2·831 2·819 2·807 2·797 3·527 3·505 3·485 3·467 3·819 3·792 3·768 3·745 4·492 4·452 4·416 4·382 4·785 4·736 4·694 4·654 25 1·316 1·708 2·060 2·485 2·787 3·450 3·725 4·352 4·619 26 27 28 29 1·315 1·314 1·313 1·311 1·706 1·703 1·701 1·699 2·056 2·052 2·048 2·045 2·479 2·473 2·467 2·462 2·779 2·771 2·763 2·756 3·435 3·421 3·408 3·396 3·707 3·689 3·674 3·660 4·324 4·299 4·276 4·254 4·587 4·556 4·531 4·505 30 1·310 1·697 2·042 2·457 2·750 3·385 3·646 4·234 4·482 40 50 60 1·303 1·299 1·296 1·684 1·676 1·671 2·021 2·009 2·000 2·423 2·403 2·390 2·704 2·678 2·660 3·307 3·261 3·232 3·551 3·496 3·460 4·094 4·014 3·962 4·321 4·228 4·169 80 100 1·292 1·290 1·664 1·660 1·990 1·984 2·374 2·364 2·639 2·626 3·195 3·174 3·416 3·390 3·899 3·861 4·095 4·054 ∞ 1·282 1·645 1·960 2·326 2·576 3·090 3·290 3·719 3·891 Page 25 PDF Watermark Remover DEMO : Purchase from www.PDFWatermarkRem Units of measurement Base units The International System of Units (Système International d’Unités) is founded on seven base quantities, which are assumed to be mutually independent. These base units are: Base quantity SI base unit Symbol for unit length (l) metre m mass (m) kilogram kg time (t) second s electric current (I) ampere A temperature (T) kelvin K amount of substance (n) mole mol luminous intensity candela cd Page 26 PDF Watermark Remover DEMO : Purchase from www.PDFWatermarkRem Prefixes Prefixes are used to form decimal multiples and submultiples of SI units. The common prefixes are: Factor Prefix Symbol Factor Prefix Symbol 1012 tera T 10–12 pico p 109 giga G 10–9 nano n 106 mega M 10–6 micro μ 103 kilo k 10–3 milli m h –2 centi c –1 deci d 10 2 10 1 hecto deka da 10 10 The symbol for a prefix is combined with the unit symbol to which it is attached to form a new unit symbol, e.g. kilometre (km), milligram (mg), microsecond (μs). Page 27 PDF Watermark Remover DEMO : Purchase from www.PDFWatermarkRem Common quantities, their symbols and units of measurement Quantity Symbol SI unit Symbol for SI unit Non-SI unit used absorbed dose D gray Gy = J kg–1 acceleration a metre per second squared m s–2 acc. due to gravity g metre per second squared m s–2 activity A becquerel Bq amount of substance n mole mol amplitude A metre m angle θ radian rad degree (º) minute (') second ('') angular velocity ω radian per second rad s–1 rpm area A metre squared m2 are (a) = 100 m2 hectare (ha) =100 a = 10 000 m2 atomic number Z capacitance C farad F = C V–1 charge q coulomb C=As Page 28 PDF Watermark Remover DEMO : Purchase from www.PDFWatermarkRem Quantity Symbol for SI unit Non-SI unit used mole per litre mol l–1 ppm; %(w/v), %(v/v) g cm–3 Symbol SI unit concentration c critical angle C density ρ kilogram per metre cubed kg m–3 displacement s metre m dose equivalent H sievert Sv = J kg–1 electric current I ampere A electric field strength E volt per metre V m–1 = N C–1 electronic charge e coulomb C=As energy (electrical) W joule J=Nm energy (heat) Q joule J energy (kinetic) Ek joule J energy (potential) Ep joule J joule J energy (food) enthalpy h joule J focal length f metre m force F newton N = kg m s–2 kW h kcal = 4182 J = 1 Cal Page 29 PDF Watermark Remover DEMO : Purchase from www.PDFWatermarkRem Quantity Symbol frequency f SI unit Symbol for SI unit hertz Hz = s–1 half-life T1/2 second s length (distance) l, s metre m magnetic flux Φ weber Wb magnetic flux density B tesla T = Wb m–2 magnification m mass m kilogram kg mass number A mole per litre mol l–1 molarity moment of a force M newton metre Nm moment of inertia I kilogram metre squared kg m2 momentum p kilogram metre per second kg m s–1 permittivity ε farad per metre F m–1 periodic time T second s power P watt W = J s–1 pascal Pa = N m–2 pressure P, p Non-SI unit used tonne (t) = 1000 kg bar = 105 Pa Page 30 PDF Watermark Remover DEMO : Purchase from www.PDFWatermarkRem Quantity Symbol SI unit Symbol for SI unit refractive index n resistance R ohm Ω = V A–1 resistivity ρ ohm metre Ωm metre per second m s–1 watt per metre squared W m–2 speed sound intensity sound intensity level u, v I knot = 0.514 m s–1 bel (1 B = 10 dB) I.L. specific heat capacity c strain ε stress Non-SI unit used –1 –1 joule per kilogram per kelvin J kg K σ Newton per metre squared Pa = N m –2 temperature T kelvin K temperature t, θ degree Celsius °C change in temperature Δθ kelvin K tension T newton N thermal conductivity k watt per metre per kelvin W m–1 K–1 Page 31 PDF Watermark Remover DEMO : Purchase from www.PDFWatermarkRem Quantity Symbol SI unit Symbol for SI unit time t second s torque T newton metre Nm metre per second m s–1 volt V = J C–1 watt per metre squared per kelvin W m–2 K–1 velocity voltage potential difference u, v V U-value volume V metre cubed m3 wavelength λ metre m weight W newton N = kg m s–2 work W joule J=Nm Young’s modulus E Newton per metre squared Pa = N m –2 Non-SI unit used minute (min) day (d) hour (h) year (y) litre (l) = 1000 cm3 Page 32 PDF Watermark Remover DEMO : Purchase from www.PDFWatermarkRem Frequently used constants Constant alpha particle mass Avogadro constant Boltzmann constant electron mass electron volt electronic charge Faraday constant gravitational constant neutron mass permeability of free space Symbol mα NA k me eV e F G mn μ0 permittivity of free space ε0 Planck constant proton mass proton-electron mass ratio speed of light in vacuo h mp mp/me c, c0 universal gas constant R Value 6.644 6565 × 10–27 kg 6.022 1415 × 1023 mol–1 1.380 6505 × 10–23 J K–1 9.109 3826 × 10–31 kg 1.602 176 53 × 10–19 J 1.602 176 53 × 10–19 C 96 485.3383 C mol–1 6.6742 × 10–11 m3 kg–1 s–2 1.674 927 28 × 10–27 kg 4π × 10–7 N A–2 8.854 187 817 × 10–12 F m–1 6.626 0693 × 10–34 J s 1.672 621 71 × 10–27 kg 1836.182 672 16 2.997 924 58 × 108 m s–1 8.314 472 J K–1 mol–1 Page 33 PDF Watermark Remover DEMO : Purchase from www.PDFWatermarkRem Particle physics Class Leptons Symbol electron e 1 stable ν –3 stable neutrino muon tau pi meson (mass of electron = 1) < 10 + μ μ – + – + – τ τ π π 207 3500 πo Mesons Baryons Mass Name + – o Mean life Year of discovery 1897 1956 –6 2 × 10 s –12 1 × 10 s –8 1937 1975 273 2.6 × 10 s 1947 264 8.4 × 10–17 s 1947 ? 1947 K meson K K K ≈ 970 proton p 1836 > 1032 y 1897 neutron n 1839 960 s 1932 lambda Λo 2183 2.6 × 10–10 s 1947 sigma Σ o 2327 ~ 10 s 1953 chi Ξ+ Ξ– Ξo 2573 ~ 10–10 s 1954 omega + Ω – – Σ Σ 3272 ~ 10 –10 –10 s 1964 Page 34 PDF Watermark Remover DEMO : Purchase from www.PDFWatermarkRem quark u s t d c b up strange top down charmed bottom antiquark ū s̄ t̄ d̄ c̄ b̄ Page 35 PDF Watermark Remover DEMO : Purchase from www.PDFWatermarkRem Mechanics Linear motion with constant acceleration v = u + at s = ut + 2 1 2 2 at 2 v = u +2as ⎛u + v⎞ ⎟t ⎝ 2 ⎠ s= ⎜ average speed = Relative motion distance time sbc = sb − sc vbc = vb − vc abc = ab − ac Momentum of a particle mv Newton’s experimental law (NEL) v1 – v2 = – e(u1 – u2) Conservation of momentum m1 u 1 + m2 u 2 = m1 v 1 + m2 v 2 Impulse (change in momentum) mv – mu Page 36 PDF Watermark Remover DEMO : Purchase from www.PDFWatermarkRem s r Angle in radians θ= Angular velocity ω= Linear velocity and angular velocity v = rω Centripetal acceleration a = rω 2= Centripetal force F = mrω = Newton’s law of gravitation F= Force and acceleration F = ma Weight and acceleration due to gravity W = mg = Vρg ; Period of a satellite T2 = Moment of a force M = Fd Torque of a couple T = Fd θ t v2 r 2 mv 2 r Gm1m2 d2 g= GM R2 4π 2 R 3 GM Page 37 PDF Watermark Remover DEMO : Purchase from www.PDFWatermarkRem Centres of gravity Hemisphere, radius r 3 8 r from centre Hemispherical shell, radius r 1 2 r from centre Right circular cone 1 4 h from the base Triangular lamina 1 3 Arc, radius r, angle 2θ Sector of disc, radius r, angle 2θ ⎛ x + x 2 + x3 y1 + y 2 + y 3 ⎞ , from base along median = ⎜ 1 ⎟ 3 3 ⎠ ⎝ r sin θ θ 2r sin θ 3θ Moments of Inertia Uniform rod, length 2l Centre: 1 3 ml 2 One end: 4 3 ml 2 Uniform disc, radius r Centre: 1 2 mr 2 Diameter: 1 4 mr 2 Page 38 PDF Watermark Remover DEMO : Purchase from www.PDFWatermarkRem Uniform hoop, radius r Centre: mr 2 Diameter: Uniform solid sphere, radius r Diameter: Parallel axis theorem 2 2 mr 5 2 I b = I c + m bc Perpendicular axis theorem IZ = I X + I y Hooke’s law F = – ks Simple harmonic motion a=–ωs 1 2 mr 2 2 T= 1 f = 2π ω s = A sin (ω t + α ) 2 2 v = ω ( A 2 – s2) Simple pendulum T = 2π l g Compound pendulum T = 2π I mgh Work W = Fs = ∫ Fds Page 39 PDF Watermark Remover DEMO : Purchase from www.PDFWatermarkRem Potential (gravitational) energy Ep = mgh Kinetic energy Ek = Principle of conservation of mechanical energy Ep + Ek = constant Mass-energy equivalence E = mc 2 Power P= 1 2 mv 2 W = Fv t power output × 100 Percentage efficiency power input Young’s modulus E= σ ε Stress σ= F A Strain ε= Δl l Density ρ= m V Page 40 PDF Watermark Remover DEMO : Purchase from www.PDFWatermarkRem F A Pressure p= Pressure in a fluid p = ρgh Thrust on an immersed plane surface T = A pcentroid Boyle’s law pV = constant Heat and temperature Celsius temperature t / ˚C = T /K – 273.15 Energy needed to change temperature ∆ E = mc ∆ θ ∆E = C∆θ Energy needed to change state ∆ E = ml ∆E = L Waves Velocity of a wave c = fλ Doppler effect f ′= Fundamental frequency of a stretched string f = fc c±u 1 T 2l μ Page 41 PDF Watermark Remover DEMO : Purchase from www.PDFWatermarkRem Mirror and lens formula 1 f = 1 u + 1 v v u Magnification m= Power of a lens P= Two lenses in contact P = P1 + P2 Refractive index n= n= Diffraction grating 1 f sin i real depth = sin r apparent depth 1 sin C = c1 c2 nλ = d sin θ Page 42 PDF Watermark Remover DEMO : Purchase from www.PDFWatermarkRem Electricity Coulomb’s law F= q1 q2 4 πε d 2 Electric field strength E= F q Potential difference V= W q Ohm’s law V = IR Resistivity ρ= Resistors in series R = R1 + R2 Resistors in parallel 1 R = 1 RA l 1 R1 + Wheatstone bridge R 1 R3 = R2 R4 Joule’s law P = RI 2 1 R2 Page 43 PDF Watermark Remover DEMO : Purchase from www.PDFWatermarkRem Force on a current-carrying conductor F = IlB Force on a charged particle F = qvB Induced emf E=− Alternating voltage and current Vrms = Capacitance C= q V Parallel-plate capacitor C= Aε 0 d Energy stored in capacitor W= Power P = VI Magnetic flux Φ = BA Transformer Vi N p = Vo N s dΦ dt 1 2 V0 2 I rms = I0 2 CV 2 Page 44 PDF Watermark Remover DEMO : Purchase from www.PDFWatermarkRem Modern physics Energy of a photon E = hf Einstein’s photoelectric equation 2 h f = Φ + mvmax Law of radioactive decay A = λN Half-life T1 2 = Mass-energy equivalence 1 2 ln 2 λ 2 E = mc Page 45 PDF Watermark Remover DEMO : Purchase from www.PDFWatermarkRem Electrical circuit symbols Conductors junction of conductors conductors crossing with no connection Switches push-to-make switch push-to-break switch two-way switch (SPDP) dual on-off switch (DPST) normally open on-off switch (SPST) normally closed on-off switch (SPST) dual two-way switch (DPDT) relay (SPST) Page 46 PDF Watermark Remover DEMO : Purchase from www.PDFWatermarkRem Power cell photovoltaic cell battery d.c. supply a.c. supply transformer fuse earth variable resistor (rheostat) preset variable resistor potential divider Resistors fixed resistor thermistor light-dependent resistor Page 47 PDF Watermark Remover DEMO : Purchase from www.PDFWatermarkRem Capacitors capacitor electrolytic capacitor (polarised capacitor) variable capacitor preset variable capacitor (trimmer) diode Zener diode photodiode light-emitting diode (LED) Diodes Meters Ω voltmeter galvanometer ammeter ohmmeter oscilloscope Page 48 PDF Watermark Remover DEMO : Purchase from www.PDFWatermarkRem Amplification pnp-junction transistor light-sensitive transistor amplifier (block symbol) microphone earphone loudspeaker bell buzzer piezoelectric transducer aerial (antenna) filament lamp signal lamp neon lamp npn-junction transistor Audio Lamps Page 49 PDF Watermark Remover DEMO : Purchase from www.PDFWatermarkRem Other devices M motor heater inductor inductor with ferromagnetic core AND NOT (inverter) NAND Logic gates OR NOR Page 50 PDF Watermark Remover DEMO : Purchase from www.PDFWatermarkRem The elements Periodic table of the elements 1 18 1 2 H He 1.008 2 13 14 15 16 17 3 4 5 6 7 8 9 10 Li Be B C N O F Ne 6.941 9.012 10.81 12.01 14.01 16.00 19.00 20.18 11 12 13 14 15 16 17 18 4.003 Na Mg A1 Si P S Cl Ar 22.99 24.31 3 4 5 6 7 8 9 10 11 12 26.98 28.09 30.97 32.07 35.45 39.95 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr 39.10 40.08 44.96 47.87 50.94 52.00 54.94 55.85 58.93 58.69 63.55 65.41 69.72 72.64 74.92 78.96 79.90 83.80 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 Rb Sr Y Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb Te I Xe 85.47 87.62 88.91 91.22 92.91 95.94 (97.90) 101.1 102.9 106.4 107.9 112.4 114.8 118.7 121.8 127.6 126.9 131.3 55 56 57 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86 Cs Ba La Hf Ta W Re Os Ir Pt Au Hg Tl Pb Bi Po At Rn 132.9 137.3 138.9 178.5 180.9 183.8 186.2 190.2 192.2 195.1 197.0 200.6 204.4 207.2 209.0 87 88 89 104 105 106 107 108 109 110 111 112 113 114 115 Fr Ra Ac Rf Db Sg Bh Hs Mt Ds Rg (209.0) (210.0) (222.0) 116 117 118 Uub Uut* Uuq Uup* Uuh Uus* Uuo (223.0) (226.0) (227.0) (261.1) (262.1) (266.6) (264.1) (277.0) (268.1) (271.0) (272.2) (285.0) (289.0) (289.0) (293.0) * These elements have not yet been detected (2008). See page 54 for the Lanthanoid and the Actinoid Series. Page 51 PDF Watermark Remover DEMO : Purchase from www.PDFWatermarkRem First ionisation energies of the elements (in kJ mol–1) 1 18 1 2 H He 1312 2 13 14 15 16 17 2372 3 4 5 6 7 8 9 10 Li Be B C N O F Ne 520.2 899.5 800.6 1087 1402 1314 1681 2081 11 12 13 14 15 16 17 18 Na Mg 495.8 737.7 3 4 5 6 7 8 9 10 11 12 A1 Si P S Cl Ar 577.5 786.5 1012 999.6 1251 1521 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr 418.8 589.8 633.1 658.8 650.9 652.9 717.3 762.5 760.4 737.1 745.5 906.4 578.8 762.0 947.0 941.0 1140 1351 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 Rb Sr Y Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb Te I Xe 403.0 549.5 600.0 640.1 652.1 684.3 702.0 710.2 719.7 804.4 731.0 867.8 558.3 708.6 834.0 869.3 1008 1170 55 56 57 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86 Cs Ba La Hf Ta W Re Os Ir Pt Au Hg Tl Pb Bi Po At Rn 375.7 502.9 538.1 658.5 761.0 770.0 760.0 840.0 880.0 870.0 890.1 1007 589.4 715.6 703.0 812.1 890±40 1037 87 88 89 104 105 106 107 108 109 110 111 112 113 114 115 116 117 118 Fr Ra Ac Rf Db Sg Bh Hs Mt Ds Rg 380.0 509.3 499.0 580.0 –– –– –– –– –– –– –– Uub Uut* Uuq Uup* Uuh Uus* Uuo –– –– –– –– * These elements have not yet been detected (2008). See page 54 for the Lanthanoid and the Actinoid Series. Page 52 PDF Watermark Remover DEMO : Purchase from www.PDFWatermarkRem Electronegativity values of the elements (Using the Pauling scale) 1 18 1 2 H He 2.20 2 13 14 15 16 17 3 4 5 6 7 8 9 10 Li Be B C N O F Ne 0.98 1.57 2.04 2.55 3.04 3.44 3.98 –– 11 12 13 14 15 16 17 18 –– Na Mg A1 Si P S Cl Ar 0.93 1.31 3 4 5 6 7 8 9 10 11 12 1.61 1.90 2.19 2.58 3.16 –– 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr 0.82 1.00 1.36 1.54 1.63 1.66 1.55 1.83 1.88 1.91 1.90 1.65 1.81 2.01 2.18 2.55 2.96 –– 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 Rb Sr Y Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb Te I Xe 0.82 0.95 1.22 1.33 1.60 2.16 2.10 2.20 2.28 2.20 1.93 1.69 1.78 1.96 2.05 2.10 2.66 2.60 55 56 57 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86 Cs Ba La Hf Ta W Re Os Ir Pt Au Hg Tl Pb Bi Po At Rn 0.79 0.89 1.10 1.30 1.50 1.70 1.90 2.20 2.20 2.20 2.40 1.90 1.80 1.80 1.90 2.00 2.20 –– 87 88 89 104 105 106 107 108 109 110 111 112 113 114 115 116 117 118 Fr Ra Ac Rf Db Sg Bh Hs Mt Ds Rg 0.70 0.90 1.10 –– –– –– –– –– –– –– –– Uub Uut* Uuq Uup* Uuh Uus* Uuo –– –– –– –– * These elements have not yet been detected (2008). See page 54 for the Lanthanoid and the Actinoid Series. Page 53 PDF Watermark Remover DEMO : Purchase from www.PDFWatermarkRem Periodic table of the elements Lanthanoid Series Actinoid Series 58 59 60 61 62 63 64 65 66 67 68 69 70 71 Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb Lu 140.1 140.9 144.2 (144.9) 150.4 152.0 157.3 158.9 162.5 164.9 167.3 168.9 173.0 175.0 90 91 92 93 94 95 96 97 98 99 100 101 102 103 Th Pa U Np Pu Am Cm Bk Cf Es Fm Md No Lr 232.0 231.0 238.0 (237.0) (244.1) (243.1) (247.1) (247.1) (251.1) (252.1) (257.1) (256.0) 67 68 69 (259.1) (262.1) First ionisation energies of the elements (in kJ mol–1) 58 Lanthanoid Series Actinoid Series 59 60 61 62 63 64 65 66 70 71 Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb Lu 534.4 527.0 533.1 540.0 544.5 547.1 593.4 565.8 573.0 581.0 589.3 596.7 603.4 523.5 90 91 92 93 94 95 96 97 98 99 100 101 102 103 Th Pa U Np Pu Am Cm Bk Cf Es Fm Md No Lr 587.0 568.0 597.6 604.5 584.7 578.0 581.0 601.0 608.0 619.0 627.0 635.0 642.0 470.0 66 67 68 69 70 71 Electronegativity values of the elements (Using the Pauling scale) 58 Lanthanoid Series Actinoid Series 59 60 61 62 63 64 65 Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb Lu 1.12 1.13 1.14 –– 1.17 –– 1.20 –– 1.22 1.23 1.24 1.25 –– 1.00 90 91 92 93 94 95 96 97 98 99 100 101 102 103 Th Pa U Np Pu Am Cm Bk Cf Es Fm Md No Lr 1.30 1.50 1.70 1.30 1.30 1.30 1.30 1.30 1.30 1.30 1.30 1.30 1.30 1.30 Page 54 PDF Watermark Remover DEMO : Purchase from www.PDFWatermarkRem Page 55