4. Incandescent and Halogen Lamps Contents 44.1 1 History 4.2 Physical Fundamentals 4.33 Co Construction s uc o 4.4 Lifetime 4.5 Halogen Incandescent Lamp 4.6 Interference Filter 4.7 Types of Halogen Lamps 4 8 New Developments 4.8 Incoherent Light Sources Prof. Dr. T. Jüstel Chapter Incandescent and Halogen Lamps Slide 1 4.1 History 1820 1840 1854 1868 1879 1881 1900 1902 1911 1912 1936 1958 1960 1971 1973 2010 Arthur A th d de lla Ri Rive observes b a glowing l i Pt Pt-wire i in i vacuum Joseph Wilson Swan experiments with carbonised paper wires Heinrich Goebel constructs the first incandescent lamp with a bamboo fiber, which finallyy leads to the carbon filament lamp p Problem: still not sufficiently well evacuated C + O2 CO2 First fabrication of incandescent lamps by Swan (low lifetime) Patent of Thomas Alva Edison Edison improves incandescent lamps by better evacuation of the lamp bulb higher lifetime Demonstration (Presentation) of Edison Lamp at the World Exhibition in Paris Coil still made from C S Searching hi ffor high hi h melting lti metals t l Ta, T W, W Re, R O Os Winner: Tungsten because of the lowest vapour pressure lowest blackening Max Planck: Theoretical basis (Planck's law) Osmium wire ((Auer and Welsbach)) Ar/N2 filling Tungsten wire First lamp with a double coiled filament First application of Xenon as a filling gas Halogen cycle (Zubler and Mosby, GE) First H4 automotive lamp (today also H7) First halogen lamp with interference filter I Incandescent d t llamps marketed k t d as h heatt b balls ll Incoherent Light Sources Prof. Dr. T. Jüstel Chapter Incandescent and Halogen Lamps Slide 2 4.2 Physical Fundamentals Energy balance of an incandescent lamp Input Power Electromagnetic radiation Electric current I IR Visible 1.2 Gas losses Conductivity losses UV Tungsten filament with the electrical 1 resistance R I( ) V( z) Electric loss for current I 0.5 P = U*I = R*I2 V() = Spectral S t l sensitivity iti it curve 0. 0 500 1000 1500 200 380 Incoherent Light Sources Prof. Dr. T. Jüstel 780 z nm nm Wavelength [nm] Wellenlänge in nm Spectrum of a glowing filament at about 2000 2000. T = 2700 K (incandescence) Chapter Incandescent and Halogen Lamps Slide 3 4.2 Physical Fundamentals The black Th bl k body b d radiation di ti can be b defined d fi d as th the li light ht emission i i iin th thermall equilibrium (thermal radiation) Spectrum of a black body radiator c1 c2 Le T 2hc2 3.741832.10-16 Wm2 = = = hc/k = 1.438786.10-2 Km = Wavelength [m] = Spectral irradiance (radiation density) = Temperature [K] 4x10 3x10 3 3x10 3 2x10 3 2x10 3 1x10 3 5x10 2 3000K -1 e -2 L c1 1 5 c 2 / T λ e 1 L e [W m nm ] Planck's radiation law (1900) 3 2500K 2000K 0 200 400 600 800 1000 1200 1400 1600 1800 2000 W avelength [nm] Light source Color temperature S Sun 5800 K Studio halogen lamp 3400 K Halogen lamp 3000 K Incandescent lamp (bulb) (b lb) 2700 K Incoherent Light Sources Prof. Dr. T. Jüstel Wien's displacement law λ max T 2880 [μm K] Chapter Incandescent and Halogen Lamps Slide 4 4.2 Physical Fundamentals Incandescent and halogen lamps are spatially and temporally incoherent light sources Incoherence A light bulb radiates incoherent: the wavelengths of the individual waves are different or between the various points of the radiating surface, there is no fixed phase relationship Incoherent Light Sources Prof. Dr. T. Jüstel Temporally coherence A color filter allows only light of a certain wavelength to pass through: the radiation is temporally coherent (monochromatic) Spatially and temporally coherence Through color filter and pinhole a small-area, t temporally ll and d spatially ti ll coherent light source of very low intensity is created Chapter Incandescent and Halogen Lamps Slide 5 4.3 Construction Tungsten filament Filament is double coiled Fill gas = noble gas (Ar, (Ar Kr, Kr Xe) + N2 (pressure = 1 bar) Typical: 80% N2 + 20% Ar (Mo) It is coiled initially on Mo, then Mo is removed C t t Contact Incoherent Light Sources Prof. Dr. T. Jüstel Ar 39,9 g/mol Kr 83,8 g/mol X Xe 131 3 g/mol 131,3 / l Screw thread = Edison-Type Bajonett-Type Diameter in mm Europe E10 E14 E27 E40 USA E12 E17 E26 E39 Chapter Incandescent and Halogen Lamps Slide 6 4.3 Construction From a glass bulb to an incandescent lamp Incoherent Light Sources Prof. Dr. T. Jüstel Chapter Incandescent and Halogen Lamps Slide 7 4.3 Construction Production of tungsten filament Tungsten production Filament production Ores: W-staves CaWO4 or (Fe,Mn)WO4 “Scheelite” “Wolframite” Di ti with Digestion ith HCl MeCl2 + WO3.H2O “Tungstite” Leaching with NH3 (NH4)10[H2W12O42] “Paratungstate” 600 °C WO3 Hammering, rolling W-plates Pullingg W-wires Winding/coiling W-filament Doping, H2, 450 °C -W-metal powder Pressing + sintering to W-staves Incoherent Light Sources Prof. Dr. T. Jüstel Chapter Incandescent and Halogen Lamps Slide 8 4.4 Lifetime Blackening of incandescent lamps Tungsten which evaporates from the filament condenses i id off the inside th glas l bulb b lb T Wasser Os Re Ta W Tungsten has the lowest vapour pressure of all metals and the highest melting point of all metals (Tm = 3410 °C), °C) Carbon (graphite) melts at 3550 °C Incoherent Light Sources Prof. Dr. T. Jüstel Chapter Incandescent and Halogen Lamps Slide 9 4.4 Lifetime The hotter is the filament, the more efficient is an incandescent lamp, however blackening is then also stronger Operating conditions of an incandescent lamp represent a compromise between the energy efficiency and lifetime t. Typical values for operation at nominal voltage: = 13 lm/W and t = 1000 h in K W „Hot spot“- mechanism W i becomes W-wire b thinner thi Resistance increases Local output and temperature increase Vapour pressure increases Burning-out at „hot spot“ Incoherent Light Sources Prof. Dr. T. Jüstel Chapter Incandescent and Halogen Lamps Slide 10 4.5 Halogen Incandescent Lamp Functional principle In halogen incandescent lamp tungsten is transported back to the filament from glass bulb via chemical transport Glass bulb remains clear W Filling gas = nobel gas + O2 + X2 (X = Br, I) = Solubility curve = pW+ pWO+ pWBr+ ..... Incoherent Light Sources Prof. Dr. T. Jüstel Chapter Incandescent and Halogen Lamps Slide 11 4.5 Halogen Incandescent Lamp Chemical transport in halogen incandescent lamps The position of the chemical equilibrium is temperature dependent: W + O2 + X2 ⇌ WO2X2 Halogen-cycle ΔH 0 ΔS0 l K lnK R T R van‘t Hoff W + O2 + X2 ⇌ WO2X2 Chemical transport lnK T2 = Wall WO2X2(g) lnK2 > 0 W Br =OFilament lnK = 0 T1 W(s) + O2(g) + X2(g) lnK1 < 0 Wendel 1/T1 Incoherent Light Sources Prof. Dr. T. Jüstel 1/T2 1/T Chapter Incandescent and Halogen Lamps Slide 12 4.5 Halogen Incandescent Lamp Limitation of the W-Recycling • Although g W back transport p is efficient, no curing g of the W-filament occurs • Gaseous W condenses at the cold spot (thickest section due to lowest resistance) W + ½ O2 ⇌ WO WO + ½ O2 ⇌ WO2 WO2 + ½ O2 ⇌ WO3 Tungsten crystals 2 W(s) + 3 O2(g) ⇌ 2 WO3(s) ΔH = -764 764 kJ/mol kJ/ l Incoherent Light Sources Prof. Dr. T. Jüstel Chapter Incandescent and Halogen Lamps Slide 13 4.5 Halogen Incandescent Lamp Set of problems with UV-radiation Due to the higher filament filament’ss temperature temperature, halogen incandescent lamps emit also some of UV-A and UV-B radiation, since the quartz bulb is transparent to UV radiation. Transmission spectrum of quartz glass Transmission and emission spectrum of Ce3+ doped silica glass 100 Transmission T i i spectrum t Emission spectrum 1,0 Em mission intensitty [a.u.] Transmissio on (%) 80 60 40 20 0 120 0,8 0,6 0,4 0,2 0,0 140 160 W Wavelength l th nm Incoherent Light Sources Prof. Dr. T. Jüstel 180 200 300 400 500 600 700 800 W Wavelength l th [[nm]] Chapter Incandescent and Halogen Lamps Slide 14 4.5 Halogen Incandescent Lamp Advantages over incandescent lamps In halogen g incandescent lamp p remains the (bulb) wall, during g the chemical transport, clear Reduction of bulb size Increase the noble gas pressure Lower evaporation rate of tungsten gives a higher lifetime, what gives partly higher efficiency (higher filament temperature) T [K] [lm/W] [%] 2700 2800 3000 3200 3400 13 16 22 29 36 10 11 13 16 20 Incoherent Light Sources Prof. Dr. T. Jüstel Incandescent lamp Typical halogen lamp Special halogen lamp ((Projectors, j TV-studios) Chapter Incandescent and Halogen Lamps Slide 15 4.6 Interference Filter Since incandescent lamps and halogen incandescent lamps emit substantially IRradiation, even higher efficiencies can be achieved by IR filter Principle on the example of the halogen lamp Visible light is transmitted IR light is reflected back to the filament = 20 lm/W 40 lm/W Reflecctance Selective mirror Interference filter UV 380 Incoherent Light Sources Prof. Dr. T. Jüstel Visible 780 IR [nm] Chapter Incandescent and Halogen Lamps Slide 16 4.6 Interference Filter Interference filters consist of a sequence of low-and highly refractive inorganic layers m. Constructive interference High reflectance Path difference = 2nd - /2 (k+1/2) Destructive interference Low reflectance TiO2, ZnS, ... (n = 2.3 – 2.7) Glass (n = 1.5) d ...... Incoherent Light Sources Prof. Dr. T. Jüstel Visible Reflection n Example: 2nd = 500 nm Low reflectance k=0 = 500 nm k=1 = 500/2 = 250 nm k=2 = 500/3 = 167 nm ...... High reflectance m=0 = 500/0.5 = 1000 nm m=1 = 500/1.5 = 333 nm m=2 = 500/2.5 = 200 nm IR 1 Layer U tto 40 layers Up l 200 400 600 800 1000 [nm] Chapter Incandescent and Halogen Lamps Slide 17 4.6 Interference Filter Energy saving filter VIS IR Cold light mirror Cold C ld li light ht mirror i is i an inverse i energy saving i filter: filt It reflects visible light and let IR radiation pass through. IR VIS C ld li Cold light ht reflector fl t are nott perfect, f t i.e. i deep d red d and dd deep bl blue are visible i ibl b behind hi d th the llamp Incoherent Light Sources Prof. Dr. T. Jüstel Chapter Incandescent and Halogen Lamps Slide 18 4.6 Interference Filter Interference filter as colour filter Refflexion Application in light sources and spectrometers 380 780 IR [nm] Lack of blue in emission spectrum yellow filter Incoherent Light Sources Prof. Dr. T. Jüstel Chapter Incandescent and Halogen Lamps Slide 19 4.7 Types of Halogen Lamps Halogen lamps for general lighting Low-voltage halogen lamps U = 12, 24 V (Transformator is required) P = 20 - 50 W Incoherent Light Sources Prof. Dr. T. Jüstel P = 200 - 500 W U = 230 V P = U2/R,, i. e. U R R = *l/A Longer and thinner filament Filament is less stable Tfilament is lowered decreases in comparison with low voltage lamps High-voltage halogen lamps Outer envelope (hot & fingerprints) PAR = Parabolic reflector lamp Chapter Incandescent and Halogen Lamps Slide 20 4.7 Types of Halogen Lamps Low Voltage vs. High Voltage Halogen Lamps Lamp type Low voltage High voltage Voltage U [V] 12 230 Power P [W] 20 20 Filament length l [[cm]] 2,21 15,81 Diameter d [μm] 54,1 7,558 Incoherent Light Sources Prof. Dr. T. Jüstel Chapter Incandescent and Halogen Lamps Slide 21 4.7 Types of Halogen Lamps Car head lights Drive light (high beam) Di Dimmed dh head d li lights ht (l (low b beam)) Drive light (high beam) Dimmed head lights (low beam) High beam H7-Lamps (1 Filament) Incoherent Light Sources Prof. Dr. T. Jüstel Low beam H4-Lamps (2 Filaments) Chapter Incandescent and Halogen Lamps Slide 22 4.7 Types of Halogen Lamps Halogen lamps SSTV Market (Stage-Studio-TV) Headlamp Spherical mirror f Fresnel lens Original filament Incoherent Light Sources Prof. Dr. T. Jüstel Picture of a filament Chapter Incandescent and Halogen Lamps Slide 23 4.8 New Developments White LEDs are becoming strong competition for halogen incandescent lamp Light source Luminous flux [lm] Incandescent 60 W 900 Halogen 50 W 1000 LED 2002 125 LED 2013 1000 Efficiency Brightness CRI [lm/W] [Mcd/m2] 15 10 100 20 20 100 25 3 75 250 10 90 Lifetime [kh] 1 2 60 60 Costs [$/Mlm.h] 7.2 63 6.3 6.0 < 1.0 Further development of incandescent and halogen bulbs Tungsten filament with photonic band structure via 3D-structuring. Aim: Reduction of the IR-emission and therefore increasingg the light efficiency. Incoherent Light Sources Prof. Dr. T. Jüstel Chapter Incandescent and Halogen Lamps Slide 24 4.8 New Developments Specialties High performance lamps (up to 20 kW) Colored incandescent lamp (coated with inorganic metal oxides ) with i h CoAl C Al2O4 Incoherent Light Sources Prof. Dr. T. Jüstel with i h Fe F 2O3 Chapter Incandescent and Halogen Lamps Slide 25 4.8 New Developments Specialties op g oof thee lamp p gglass, ss, e.g. by Nd2O3 (G (GE Lighting: g g: Reveal eve ®) Doping Aim: Increase of the color temperature without loss of color rendering Enhancement of the contrast between red and green Incoherent Light Sources Prof. Dr. T. Jüstel Chapter Incandescent and Halogen Lamps Slide 26 4.8 New Developments Specialties 2010: Marketing of incandescent lamps as heatballs, heatballs as a reaction on the ban of incandescent lamps driven by the EU 2016: Ban of halogen lamps implemented Incoherent Light Sources Prof. Dr. T. Jüstel Chapter Incandescent and Halogen Lamps Slide 27